FDS-jotamastic 87 ALU Comp A

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Conforms to Regulation (EC) No.

1907/2006 (REACH), Annex II - United Kingdom (UK)

SAFETY DATA SHEET


Jotamastic 87 Aluminium - Comp. A

1.

Identification of the preparation and of the company

Product name and/or code


Label No.
Supplier/Manufacturer

: Jotamastic 87 Aluminium - Comp. A


: 523
: Jotun Paints (Europe) Ltd.
Stather Road
Flixborough, Scunthorpe
North Lincolnshire
DN15 8RR
England
Tel: +44 17 24 40 00 00
Fax: +44 17 24 40 01 00
[email protected]

Emergency telephone
number
Product use

2.

: Contact National Poison Centre via Hospital or Registered Medical Practitioner


: Coatings: Epoxy. / Solvent-borne.

Hazards identification

The product is classified as dangerous according to Directive 1999/45/EC and its amendments.
Flammable.
Irritating to eyes and skin. May cause sensitisation by skin
contact.
Harmful to aquatic organisms, may cause long-term adverse
effects in the aquatic environment.
Irritant
: Contains epoxy constituents. See information supplied by the manufacturer. This
information is provided by the present Safety Data Sheet.
The preparation may be a skin sensitiser. It may also be a skin irritant and repeated contact may increase this effect.
Additional warning phrases

3.

Composition/information on ingredients

Substances presenting a health or environmental hazard within the meaning of the Dangerous Substances
Directive 67/548/EEC.
Chemical name*

CAS
number

EC
number

reaction product: bisphenol-A-(epichlorhydrin) and epoxy


resin (number average molecular weight <= 700)

25068-38-6 500-033-5

10 - 25

xylene

1330-20-7

2.5 - 10

epoxy resin (MW 700-1200)

25036-25-3

2.5 - 10

benzyl alcohol
Naphtha (petroleum), hydrotreated heavy

100-51-6
202-859-9
64742-48-9 265-150-3

1 - 2.5
1 - 2.5

2-methylpropan-1-ol

78-83-1

201-148-0

1 - 2.5

ethylbenzene

100-41-4

202-849-4

1 - 2.5

215-535-7

% by
weight

Classification
Xi; R36/38
R43
N; R51/53
R10
Xn; R20/21
Xi; R38
Xi; R36/38
R43
Xn; R20/22
R10
Xn; R65
R66
R10
Xi; R41, R37/38
R67
F; R11
Xn; R20

See section 16 for the full text of the R-phrases


declared above

Occupational exposure limits, if available, are listed in section 8.


Date of issue

: 02.06.2008.

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Jotamastic 87 Aluminium - Comp. A

4.

First-aid measures

First-aid measures
General
Inhalation

Skin contact
Eye contact
Ingestion

5.

: Remove contaminated clothing and shoes. Wash skin thoroughly with soap and
water or use recognised skin cleanser. Do not use solvents or thinners.
: Check for and remove any contact lenses. Immediately flush eyes with running water
for at least 15 minutes, keeping eyelids open.
: If swallowed, seek medical advice immediately and show the container or label.
Keep person warm and at rest. Do not induce vomiting.

Fire-fighting measures

Extinguishing media
Recommendations

6.

: In all cases of doubt, or when symptoms persist, seek medical attention. Never give
anything by mouth to an unconscious person.
: Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing is
irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by
trained personnel. Give nothing by mouth. If unconscious, place in recovery position
and seek medical advice.

: Recommended: alcohol-resistant foam, CO 2, powders, water spray.


Not to be used : water jet.
: Fire will produce dense black smoke. Exposure to decomposition products may
cause a health hazard. Appropriate breathing apparatus may be required. Cool
closed containers exposed to fire with water. Do not release runoff from fire to
sewers or waterways.

Accidental release measures

Personal precautions
Spill

: Exclude sources of ignition and ventilate the area. Avoid breathing vapour or mist.
Refer to protective measures listed in sections 7 and 8.
: Contain and collect spillage with non-combustible, absorbent material e.g. sand,
earth, vermiculite or diatomaceous earth and place in container for disposal
according to local regulations (see section 13). Do not allow to enter drains or
watercourses. Preferably clean with a detergent. Avoid using solvents. If the product
contaminates lakes, rivers, or sewers, inform the appropriate authorities in
accordance with local regulations.

Note: see section 8 for personal protective equipment and section 13 for waste disposal.

7.

Handling and storage

Handling

: Vapours are heavier than air and may spread along floors. Vapours may form
explosive mixtures with air. Prevent the creation of flammable or explosive
concentrations of vapours in air and avoid vapour concentrations higher than the
occupational exposure limits.
In addition, the product should only be used in areas from which all naked lights and
other sources of ignition have been excluded. Electrical equipment should be
protected to the appropriate standard.
To dissipate static electricity during transfer, earth drum and connect to receiving
container with bonding strap. Operators should wear antistatic footwear and clothing
and floors should be of the conducting type.
Keep container tightly closed. Keep away from heat, sparks and flame. No sparking
tools should be used.
Avoid contact with skin and eyes. Avoid the inhalation of dust, particulates, spray or
mist arising from the application of this preparation. Avoid inhalation of dust from
sanding.
Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking.
Put on appropriate personal protective equipment (see section 8).
Never use pressure to empty. Container is not a pressure vessel. Always keep in
containers made from the same material as the original one.

Date of issue

: 02.06.2008.

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Jotamastic 87 Aluminium - Comp. A


Comply with the health and safety at work laws.
When operators, whether spraying or not, have to work inside the spray booth,
ventilation is unlikely to be sufficient to control particulates and solvent vapour in all
cases. In such circumstances they should wear a compressed air-fed respirator
during the spraying process and until such time as the particulates and solvent
vapour concentration has fallen below the exposure limits.
Storage

: Store in accordance with local regulations. Observe label precautions. Store in a


cool, well-ventilated area away from incompatible materials and ignition sources.
Keep away from: oxidising agents, strong alkalis, strong acids.
No smoking. Prevent unauthorised access. Containers that have been opened must
be carefully resealed and kept upright to prevent leakage.
Do not empty into drains.

8.

Exposure controls/personal protection

Engineering measures

: Provide adequate ventilation. Where reasonably practicable, this should be achieved


by the use of local exhaust ventilation and good general extraction. If these are not
sufficient to maintain concentrations of particulates and solvent vapours below the
OEL, suitable respiratory protection must be worn.

Ingredient name
xylene

Naphtha (petroleum), hydrotreated


heavy
2-methylpropan-1-ol

ethylbenzene

Occupational exposure limits


EH40-WEL (United Kingdom (UK), 9/2006). Skin
WEL 15 min limit: 441 mg/m 15 minute(s).
WEL 8 hrs limit: 220 mg/m 8 hour(s).
EH40-WEL (United Kingdom (UK), 1/2005).
STEL: 850 mg/m 15 minute(s). Form: All forms
TWA: 566 mg/m 8 hour(s). Form: All forms
EH40/2005 WELs (United Kingdom (UK), 8/2007).
STEL: 231 mg/m 15 minute(s).
TWA: 154 mg/m 8 hour(s).
EH40/2005 WELs (United Kingdom (UK), 8/2007). Skin
STEL: 552 mg/m 15 minute(s).
TWA: 100 ppm 8 hour(s).

Personal protective equipment


Respiratory system
: If workers are exposed to concentrations above the exposure limit, they must use
appropriate, certified respirators. Use respiratory mask with charcoal and dust filter
when spraying this product.(as filter combination A2-P2). In confined spaces, use
compressed-air or fresh-air respiratory equipment. When use of roller or brush,
consider use of charcoalfilter.
Skin and body
Hands

: Personnel should wear antistatic clothing made of natural fibres or of hightemperature-resistant synthetic fibres.
: For prolonged or repeated handling, use the following type of gloves: gloves:
polyvinyl alcohol or nitrile.
Barrier creams may help to protect the exposed areas of the skin but should not be
applied once exposure has occurred.
For right choice of glove materials, with focus on chemical resistance and time of
penetration, seek advice by the supplier of chemical resistant gloves.
The user must check that the final choice of type of glove selected for handling this
product is the most appropriate and takes into account the particular conditions of
use, as included in the user's risk assessment.
: Use safety eyewear designed to protect against splash of liquids.

Eyes

9.

Physical and chemical properties


Liquid.
Characteristic.
Various colours.

Physical state
Odour
Colour
Flash point
Density

:
:
:
:
:

Date of issue

: 02.06.2008.

Closed cup: 40C (104F)


1.5 g/cm3
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Jotamastic 87 Aluminium - Comp. A


Solubility

: Insoluble in the following materials: cold water and hot water.

10. Stability and reactivity


Stable under recommended storage and handling conditions (see section 7).
Hazardous decomposition products: carbon monoxide, carbon dioxide, smoke, oxides of nitrogen.
Keep away from the following materials to prevent strong exothermic reactions: oxidising agents, strong alkalis, strong
acids.

11. Toxicological information


There is no data available on the preparation itself. The preparation has been assessed following the conventional
method of the Dangerous Preparations Directive 1999/45/EC and classified for toxicological hazards accordingly. See
sections 2 and 15 for details.
Exposure to component solvent vapour concentrations in excess of the stated occupational exposure limit may result in
adverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the kidneys,
liver and central nervous system. Solvents may cause some of the above effects by absorption through the skin.
Symptoms and signs include headache, dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, loss
of consciousness. Repeated or prolonged contact with the preparation may cause removal of natural fat from the skin,
resulting in non-allergic contact dermatitis and absorption through the skin. If splashed in the eyes, the liquid may cause
irritation and reversible damage.
Based on the properties of the epoxy constituent(s) and considering toxicological data on similar preparations, this
preparation may be a skin sensitiser and an irritant. It contains low molecular weight epoxy constituents which are
irritating to eyes, mucous membrane and skin. Repeated skin contact may lead to irritation and to sensitisation, possibly
with cross-sensitisation to other epoxies. Skin contact with the preparation and exposure to spray mist and vapour
should be avoided.
Contains: reaction product: bisphenol-A-(epichlorhydrin) and epoxy resin (number average molecular weight <= 700),
epoxy resin (MW 700-1200). May produce an allergic reaction.

12. Ecological information


There is no data available on the preparation itself.
Do not allow to enter drains or watercourses.
The preparation has been assessed following the conventional method of the Dangerous Preparations Directive
1999/45/EC and is classified for eco-toxicological properties accordingly. See Sections 2 and 15 for details.
Aquatic ecotoxicity
Product/ingredient name
epoxy resin (MW < 700)
xylene

Test
Mortality

Mortality

Result
Acute EC50 1,4 mg/l
Acute LC50 3,1 mg/l

Species
Daphnia
Fish - fathead
minnow
Acute LC50 8500 ug/L
Crustaceans Marine water
Daggerblade
grass shrimp
Palaemonetes
pugio
Acute LC50 3300 to 4093 Fish ug/L Fresh water
Rainbow

Exposure
48 hours
96 hours
48 hours

96 hours

trout,donaldson

benzyl alcohol

Mortality

Mortality

Date of issue

: 02.06.2008.

trout Oncorhynchus
mykiss
96 hours
Acute LC50 460000 ug/L Fish Fresh water
Fathead
minnow Pimephales
promelas
Acute LC50 15000 ug/L
Fish - Inland 96 hours
Marine water
silverside Menidia
beryllina
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Jotamastic 87 Aluminium - Comp. A

2-methylpropan-1-ol

ethylbenzene

Mortality

Acute LC50 10000 ug/L


Fresh water

Intoxication

Acute EC50 1439000 to


1933000 ug/L Fresh
water

Mortality

Acute LC50 1330000 to


1520000 ug/L Fresh
water

Intoxication

Mortality

Fish - Bluegill 96 hours


- Lepomis
macrochirus
48 hours
Daphnia Water flea Daphnia
magna
Fish 96 hours
Rainbow
trout,donaldson

trout Oncorhynchus
mykiss
48 hours
Acute EC50 2930 to 4400 Daphnia ug/L Fresh water
Water flea Daphnia
magna
Acute LC50 4200 ug/L
Fish 96 hours
Fresh water
Rainbow
trout,donaldson

trout Oncorhynchus
mykiss
Ecological information
Biodegradability
Product/ingredient name
epoxy resin (MW < 700)
xylene
benzyl alcohol
Bioaccumulative potential
Product/ingredient name
epoxy resin (MW < 700)
xylene
benzyl alcohol

Aquatic half-life
LogPow
>3
3.12
1.1

Photolysis
BCF
<100

Biodegradability
Not readily
Readily
Readily
Potential
high
high
low

13. Disposal considerations


Do not allow to enter drains or watercourses. Material and/or container must be disposed of as hazardous waste.
European waste catalogue : 08 01 11* waste paint and varnish containing organic solvents or other dangerous
substances. If this product is mixed with other wastes, this code may no longer apply.
(EWC)
If mixed with other wastes, the appropriate code should be assigned. For further
information, contact your local waste authority.

14. Transport information


Transport within users premises: always transport in closed containers that are upright and secure. Ensure that
persons transporting the product know what to do in the event of an accident or spillage.
International transport regulations
Proper shipping name
: Paint.
UN number
: 1263
Class
: 3
Packing group
: III
Label
:

Additional information
ADR / RID

IMDG
Date of issue

: Hazard identification number: 30


Special provisions: 640E
ADR/RID: Viscous substance. Not restricted, ref. chapter 2.2.3.1.5 (applicable to
receptacles < 450 litre capacity).
: Emergency schedules (EmS): F-E, S-E
Marine pollutant: No.
: 02.06.2008.

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Jotamastic 87 Aluminium - Comp. A


IMDG: Viscous substance. Transport in accordance with paragraph 2.3.2.5
(applicable to receptacles < 30 litre capacity).
Transport in accordance with ADR/RID, IMDG/IMO and ICAO/IATA and national regulation.

15. Regulatory information


EU regulations
Hazard symbol or symbols

: The product is classified and labelled for supply in accordance with the Directive
1999/45/EC as follows:
:

Irritant

Risk phrases

: R10- Flammable.
R36/38- Irritating to eyes and skin.
R43- May cause sensitisation by skin contact.
R52/53- Harmful to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.

Safety phrases

: S23- Do not breathe vapour / spray.


S24- Avoid contact with skin.
S37- Wear suitable gloves.
S51- Use only in well-ventilated areas.

Contains:

: reaction product: bisphenol-A-(epichlorhydrin) and epoxy resin (number average


molecular weight <= 700)
epoxy resin (MW 700-1200)
: Contains epoxy constituents. See information supplied by the manufacturer. This
information is provided by the present Safety Data Sheet.

Additional warning
phrases
Industrial use

: The information contained in this safety data sheet does not constitute the users
own assessment of workplace risks, as required by other health and safety
legislation. The provisions of the national health and safety at work regulations apply
to the use of this product at work.

16. Other information


CEPE Classification
: 1
Full text of R-phrases
: R11- Highly flammable.
R10- Flammable.
referred to in sections 2 and
R20- Harmful by inhalation.
3 - United Kingdom (UK)
R20/21- Harmful by inhalation and in contact with skin.
R20/22- Harmful by inhalation and if swallowed.
R65- Harmful: may cause lung damage if swallowed.
R41- Risk of serious damage to eyes.
R38- Irritating to skin.
R36/38- Irritating to eyes and skin.
R37/38- Irritating to respiratory system and skin.
R43- May cause sensitisation by skin contact.
R66- Repeated exposure may cause skin dryness or cracking.
R67- Vapours may cause drowsiness and dizziness.
R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
R52/53- Harmful to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
The information in this Safety Data Sheet is required pursuant to EU Directive 91/155/EEC and its amendments.
: 02.06.2008.
Date of issue
: 2
Version
Indicates information that has changed from previously issued version.
Notice to reader

Date of issue

: 02.06.2008.

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Jotamastic 87 Aluminium - Comp. A


The information in this SDS is based on the present state of our knowledge and on current laws. The product
is not to be used for purposes other than those specified under section 1 without first obtaining written
handling instructions. It is always the responsibility of the user to take all necessary steps to fulfil the
demands set out in the local rules and legislation. The information in this SDS is meant to be a description of
the safety requirements for our product. It is not to be considered a guarantee of the product's properties.

Date of issue

: 02.06.2008.

Page: 7/7

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