Heat and Mass Transfer
Heat and Mass Transfer
Heat and Mass Transfer
By far the largest number of industrial evaporators employs tubular heating surfaces.
Circulation of liquid past the heating surface may be induced by boiling or by mechanical
means. In the latter case, boiling may or may not occur at the heating surface.
A: Product
B: Vapor out
C: Concentrate out
D: Heating System
E: Condensate
1: Calandria
2: Separator (Flash Cooler)
3: Circulation Pump
4: Concentrate Pump
The main applications for a forced circulation evaporator are in the concentration of
inversely soluble materials, crystallizing duties, and in the concentration of thermally degradable
materials which result in the deposition of solids. In all cases, the temperature rise across the
tube bundle is kept as low as possible, often as low as 3F to 5F (2C to 3C). This results in a
recirculation ratio as high as 220 pounds to 330 pounds (100 kg to 150 kg) of liquor per pound
(kilogram) of water evaporated. These high recirculation rates result in high liquor velocities
through the tube which help to minimize the buildup of deposits or crystals along the heating
surface. Forced circulation evaporators normally are more expensive than film evaporators
because of the need for large bore circulating pipework and large recirculating pumps.
Operating costs of such a unit also are considerably higher.
The liquid velocity above the heating surface is limited only by the pumping power
needed or available and by accelerated corrosion and erosion at the higher velocities. Tube
velocities normally range from a minimum of about 1.2 m/s in salt evaporators with copper or
brass tubes and liquid containing 5% or more solids up to about 3 m/s in caustic evaporators
having nickel tubes and liquid containing only a small amount of solids. Even higher velocities
can be used when corrosion is not accelerated by erosion.
4. Mild scaling solutions requiring mechanical cleaining, since tubes are short and large in
diameter.
The largest use of LTV evaporators is for concentrating black liquor in the pulp and
paper industry. Because of the long tubes and relatively high heat-transfer coefficients, it is
possible to achieve higher single-unit capacities in this type of evaporator than in any other.
The LTV evaporator shown is typical of those commonly used, especially for black liquor.
Feed enters at the bottom of the tube and starts to boil partway up the tube, and the mixture of
liquid and vapor leaving at the top at high velocity impinges against a deflector placed above
the tube sheet. This deflector is effective both as a primary separator and as a foam breaker.
Low Cost
Large heating surface in one body
Low holdup
Small floor space
Good heat-transfer coefficients at reasonable temperature differences(rising film)
Good heat transfer coefficient at all temperature differences (falling film)
High headroom
Generally unsuitable for salting and severely scaling liquids
Poor heat-transfer coefficients of rising-film version at low temperature differences
Recirculation usually required for falling-film version
Clear liquids
Foaming liquids
Corrosive solutions
Large evaporation loads
High temperature differencesrising film, low temperature differencesfalling film
Low-temperature operationfalling film
Vapor compression operationfalling film
In this type, the steam is inside and the liquor outside the tubes. Low entrainment loss is
the primary aim: the horizontal cylindrical shell yields a large disengagement area per unit of
vessel volume. Special versions use deformed tubes between restrained tube sheets that crack
off much of a scale deposit when sprayed with cold water. Originally called the Lillie, this
evaporator is now also called the spray-film or horizontal tube evaporator. Liquid distribution
over the tubes is accomplished by sprays or perforated plates above the topmost tubes.
Maintaining this distribution through the bundle to avoid over-concentrating the liquor is a
problem unique to this type of evaporator. It is now used primarily for seawater evaporation.
VAPOR-LIQUID SEPARATION
FOAMING
LOSSES
SPLASHING
LOSSES
ENTRAINMEN
T LOSSES BY
FLASHING
ENTRAINMEN
T
SEPARATORS
KNITTED
WIRE
MESH
Product losses in evaporator may result from foaming, splashing losses, and
entrainment losses by flashing. Primary separation of liquid from vapour is
accomplished in the vapour head by making the horizontal plan area large enough so
that most of the entrained droplets can settle out against the rising flow of vapour.
FOAMING LOSSES
Usually result from the presence in the evaporating liquid of colloids or surface-tension
depressants and finely divided solids. Solutions for this may include antifoam agents, other
means of combating foam include the removal of product at the surface layer, where the
foaming agents seem to concentrate, and operation at a very low liquid level so that the hot
surfaces can break the foam. Operating at lower temperatures and/or higher-dissolve solids
concentrations may also reduce foaming tendencies.
SPLASHING LOSSES
Splashing Losses are usually insignificant if a reasonable height has been provided
between the liquid level and the top of the vapor head. The height required depends on the
violence of boiling. Heights of 2.4 to 3.6 m (8 to 12 ft) or more are provided in short-tube
vertical evaporators, in which the liquid and vapor leaving the tubes are projected upward. Less
height is required in forced-circulation evaporators, in which the liquid is given a centrifugal
motion or is projected downward as by a baffle. The same is true of long-tube vertical
evaporators, in which the rising vapor-liquid mixture is projected against a baffle.
ENTRAINMENT SEPARATORS
When a bubble of vapor rises to the surface of liquid and
bursts, the liquid film that forms the top of the bubble is usually
sprayed as very fine droplets along with the stream of vapor.
These droplets greatly vary in size. Some of them drop back
quickly into the liquid from which they came; some settle more
slowly; and some will not settle at all, at any vapor velocity (that is
practicable to maintain). Such finely divided liquid carried along with
the stream of vapor is called entrainment, and may cause serious
losses from the liquid being evaporated and contamination of the
condensate.
Entrainment Separators are frequently used to reduce
product losses. The most common separator is the cyclone, which
may have either a top or a bottom outlet or may even be wrapped
around the heating element of the next effect. The separation
efficiency of a cyclone increases with an increase in inlet velocity,
although at the cost of some pressure drop, which means a loss in
available temperature difference. Pressure drop in a cyclone is from
10 to 16 velocity heads, based on the velocity in the inlet pipe. Such
Cyclone Separator
cyclones can be sized in the same manner as a cyclone dust collector
(using velocities of about 30 m/s (100 ft/s) at atmospheric pressure)
although sizes may be increased somewhat in order to reduce losses in available temperature
difference.
Batch evaporators- are the ones in which the filling, evaporating and emptying are consecutive
steps. This method of of operation is rarely used since it requires that the body be large enough
to hold the entire charge of feed and the heating element be placed low enough so as not to be
uncovered when the volume is reduced so that of the product.
Continuously batch evaporators- usually have a continuous feed and over at least part of the
cycle, continuous discharge. One method of operation is to circulate from a storage tank to the
evaporator and back until the entire tank is up to desired concentration and then finish in
batches.
Continuous Evaporators- have essentially continuous feed and discharge, and concentrations
of both feed and product remain substantially constant.
THERMOCOMPRESSION
The simplest means of reducing the
energy requirements of evaporation is to
compress the vapour from a single effect
evaporator. In order to keep the
compressor cost and power requirements
within reason, the evaporator must work
with a fairly narrow temperature difference
usually from about 5.5 to 11 . o reduce
energy consumption, water vapor from an
evaporator is entrained and compressed
with
high
pressure
steam
in
a
thermocompressor so it can be condensed
in the evaporator heat exchanger. The
MECHANICAL THERMOCOMPRESSION
In Mechanical recompression, it
employs a reciprocating rotary
positive displacement, centrifugal or
axial flow compressors. Positive
displacement
compressors
are
impractical for all but the smallest
capacities, such as portable seawater
evaporators, axial-flow compressors
can be built for capacities of more
than 472
Centrifugal compressors
are usually the cheapest for the
intermediate capacity ranges that are
normally encountered. The principle
of this is that, cold feed is preheated
almost to its boiling point by
exchange with hot liquor and is
pumped through a heater as in a
conventional forced0circulation evaporator. The vapour evolve however is not
condensed; instead it is compressed to somewhat higher pressure by a positivedisplacement or centrifugal compressor and becomes the steam is fed to the heater.
Since the saturation temperature of the compressed vapour is higher than the boiling
point of the feed, heat flows from the vapour to the solution, generating more vapour.
The optimum temperature drop for a typical system is about 5 .
MULTIPLE-EFFECT EVAPORATION
Forward Feed
In forward-feed operation, raw
feed is introduced in the first effect and
passed from effect to effect parallel to the
steam flow. Product is withdrawn from the
last effect. This method of operation is
advantageous when the feed is hot or when
the concentrated product would be
damaged or would deposit scale at high
temperature. Forward feed simplifies
operation when liquor can be transferred
by
pressure
difference
alone,
thus
eliminating all intermediate liquor pumps.
When the feed is cold, forward feed gives a low steam economy since an appreciable part of the
prime steam is needed to heat the feed to the boiling point and thus accomplishes no
evaporation. If forward feed is necessary and feed is cold, steam economy can be improved
markedly by preheating the feed in stages with vapor bled from intermediate effects of the
evaporator. This usually represents little increase in total heating surface or cost since the feed
must be heated in any event and shell-and-tube heat exchangers are generally less expensive
per unit of surface area than evaporator heating surface.
Forward Feed Operation
Mixed-Feed
Mixed-feed operation is used only
for special applications, as when liquor at
an intermediate concentration and a
certain temperature is desired for
additional processing. In the mixed feed
operation, the dilute feed liquid enters at
an intermediate effect and flows in the
next higher effect till it reaches the last
effect of the series. In this section, liquid
flows in the forward feed mode. Partly
concentrated liquor is then pumped back
Mixed-Feed Operation
to the effect before the one to which the
fresh feed was introduced for further concentration. Mixed feed arrangement eliminates some of
Heat-Recovery Systems
Heat-recovery systems are frequently incorporated in an evaporator to increase the
steam economy. Ideally, product and evaporator condensate should leave the system at a
temperature as low as possible. Also, heat should be recovered from these streams by exchange
with feed or evaporating liquid at the highest possible temperature. This would normally require
separate liquid-liquid heat exchangers, which add greatly to the complexity of the evaporator
and are justifiable only in large plants. Normally, the loss in thermodynamic availability due to
flashing is tolerated since the flash vapor can then be used directly in the evaporator effects.
The most commonly used is a condensate flash system in which the condensate from each
effect but the first (which normally must be returned to the boiler) is flashed in successive stages
to the pressure in the heating element of each succeeding effect of the evaporator. Product
flash tanks may also be used in a backward- or mixed-feed evaporator. In a forward-feed
evaporator, the principal means of heat recovery may be by use of feed pre heaters heated by
vapor bled from each effect of the evaporator. In this case, condensate may be either flashed as
before or used in a separate set of exchangers to accomplish some of the feed preheating. A
feed preheated by last-effect vapor may also materially reduce condenser water requirements.
SEAWATER EVAPORATORS
The production of potable water from saline waters represents a large and growing field
of application for evaporators. Steam economies on the order of 10 kg evaporation/kg steam
are usually justified because (1) unit production capacities are high, (2) fixed charges are low on
capital used for public works, (3) heat-transfer performance is comparable with that of pure
water, and (4) properly treated seawater causes little deterioration due to scaling or fouling.
Figure (a) shows a multiple-effect (falling-film) flow sheet as used for seawater. Seawater
is used to condense last-effect vapor, and a portion is then treated to prevent scaling and
corrosion. Treatment usually consists of acidification to break down bicarbonates, followed by
deaeration, which also removes the carbon dioxide generated. The treated seawater is then
heated to successively higher temperatures by a portion of the vapor from each effect and
finally is fed to the evaporating surface of the first effect. The vapor generated therein and the
partially concentrated liquid are passed to the second effect, and so on until the last effect. The
feed rate is adjusted relative to the steam rate so that the residual liquid from the last effect can
carry away all the salts in solution, in a volume about one-third of that of the feed. Condensate
formed in each effect but the first is flashed down to the following effects in sequence and
constitutes the product of the evaporator.
As the feed-to-steam ratio is increased in the flow sheet of Figure (a), a point is reached
where all the vapor is needed to preheat the feed and none is available for the evaporator
tubes. This limiting case is the multistage flash evaporator, shown in its simplest for in Figure
(b). Seawater is treated as before and then pumped through a number of feed heaters in series.
It is given a final boost in temperature with prime steam in a brine heater before it is flashed
down in series to provide the vapor needed by the feed heaters. The amount of steam required
depends on the approach-temperature difference in the feed heaters and the flash range per
stage. Condensate from the feed heaters is flashed down in the same manner as the brine.
Since the flow being heated is identical to the total flow being flashed, the temperature
rise in each heater is equal to the flash range in each flasher. This temperature difference
represents a loss from the temperature difference available for heat transfer. There are thus two
ways of increasing the steam economy of such plants: increasing the heating surface and
increasing the number of stages. Whereas the number of effects in a multiple-effect plant will
be about 20 percent greater than the steam economy, the number of stages in a flash plant will
be 3 to 4 times the steam economy. However, a large number of stages can be provided in a
single vessel by means of internal bulkheads.
In the flow sheet of Figure (b) all this seawater must be deaerated and treated for scale
prevention. In addition, the last stage vacuum varies with the ambient seawater temperature,
and ejector equipment must be sized for the worst condition. These difficulties can be
eliminated by using the recirculating multistage flash flow sheet of Figure (c). The last few
stages, called the reject stages, are cooled by a flow of seawater that can be varied to maintain a
reasonable last-stage vacuum. A small portion of the last-stage brine is blown down to carry
away the dissolved salts, and the balance is recirculated to the heat-recovery stages. This
arrangement requires a much smaller makeup of fresh seawater and hence a lower treatment
cost.
The multistage flash evaporator is similar to a multiple-effect forced-circulation
evaporator, but with all the forced-circulation heaters in series. This has the advantage of
EVAPORATOR ACCESSORIES
CONDENSER
The vapor from the last effect of an evaporator is usually removed by a condenser.
Surface condensers are employed when mixing of condensate with condenser cooling water is
not desired. Tubular condensers used in power plant to condense exhaust steam are known
as surface condensers. They are for the most part shell-and-tube condensers with vapor on the
shell side and a multi-pass flow of cooling water on the tube side. Heat loads, temperature
differences, sizes, and costs are usually of the same order of magnitude as for another effect of
the evaporator. Surface condensers use more cooling water and are so much more expensive
that they are never used when a direct-contact condenser is suitable.
In direct contact condensers, the exhaust steam and cooling water come in direct
contact and mix together. The steam condenses suddenly, achieving the temperature of the
cooling water. Then, the condensate and cooling water are continuously taken out. Direct
contact condenser is used when the dry cooling towers are used, in geothermal power plants
and in plants that use temperature differences as in ocean waters.
Jet condenser makes use of high-velocity jets of water both to condense the vapor and
to force non-condensable gases out the tailpipe. This type of condenser is frequently placed
below barometric height and requires a pump to remove the mixture of water and gases. Jet
condensers usually require more water than the more common barometric-type condensers and
cannot be throttled easily to conserve water when operating at low evaporation rates. It is a
kind of direct contact condenser in which cooling water and steam mix in a series of combining
cones. The kinetic energy of steam is expended to drain off the condensate and cooling water
from the condenser. It reduces the tail pipe height in barometric condenser. Jet condenser also
removes the need of air pump. The condensate cannot be reused in boiler since it is
contaminated by cooling water. Water enters from the top through nozzles. The steam entering
from the side is guided on to the surface of water through guiding cones. Due to decreasing
area of guide cones, the potential energy is converted into kinetic energy. Decrease in potential
energy causes pressure drop resulting in suction. Suction pulls more and more steam for
condensation. Water and condensate then, enter diverging section where the velocity decreases
and pressure increases. The built up pressure enable the mixture of condensate and water to be
discharged automatically in the hot well.
VENT SYSTEMS
Noncondensable gases may be present in the
evaporator vapor as a result of leakage, air dissolved in the
feed, or decomposition reactions in the feed. When the
vapor is condensed in the succeeding effect, the
noncondensables increase in concentration and impede
heat transfer. This occurs partially because of the reduced
partial pressure of vapor in the mixture but mainly because
the vapor flow toward the heating surface creates a film of
Vent Valve
SALT REMOVAL
When an evaporator is used to make a crystalline product, a number of means
are available for concentrating and removing salt from the system. The simplest is to
provide a settling space in the evaporator itself. Sufficiently high slurry densities can
usually achieved in this manner to reach the limit of pumpability. The evaporators are
usually placed above barometric height so that the slurry can be discharged
intermittently on a short time cycle. If the amounts of salt
crystallized is on the order of a ton an hour or less, a salt
trap may be used. This is simply a receiver that is
connected at the bottom of the evaporator and is closed of
the evaporator and is closed off from the evaporator
periodically for emptying. Such traps are useful when
insufficient headroom is available for gravity removal of the
solids.
REFERENCES
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