Propylene From Biomass

University of Pennsylvania
ScholarlyCommons
Senior Design Reports (CBE)
Department of Chemical & Biomolecular

Engineering
4-1-2011
PROPYLENE FROM BIOMASS

Matthew Gay
Bryan Pope
Jake Wharton
This paper is posted at ScholarlyCommons. http://repository.upenn.edu/cbe_sdr/23

For more information, please contact [email protected].
PROPYLENE FROM BIOMASS

Abstract
The proposed design utilizes 750,000 metric dry tons per year of woodchip biomass obtained from the local
sawmill and forestry industries. The woodchips are processed and dried before being fed to a gasification
system. The gasifiers produce a hydrogen-rich syngas, which is routed through a monoethanol amine (MEA)
absorption section to remove the coproduced CO2. The syngas then enters a novel microchannel reactor
where the equilibrium between the synthesis gas, methanol, and dimethyl ether results in a high overall
conversion and efficient heat removal. Conversions were modeled using recent experimental data from
PNNL. The DME product is removed from the reactor effluent using a water absorption tower and separated
from the water via distillation. The DME and methanol byproduct are then routed to another reactor section
where propylene, ethylene, and other hydrocarbon byproducts are produced. This reactor section was
designed with near 100% feed conversion. Propylene and ethylene are separated from the other effluents to be
sold as products. The byproduct hydrocarbons are routed back to a steam cracking reactor to form additional
propylene and ethylene, which are also feed to the separation train.
145,000 metric tons per year of propylene and 35,000 metric tons per year of ethylene are produced. An initial
total permanent investment of $525 million is required, as well as annual fixed and variable costs amounting to
$62 million. The project has an NPV of $88 million at a 15% discount rate and an IRR of 17.5%.
The materials handling and gasification sections of the project require large initial investments and continuing
operating and maintenance expenses. The project is sensitive to the price and availability of biomass, requiring
further detailed siting and supply contracts. The economics of this plant are compared to the economics of a
traditional methanol-to-olefin (MTO) process.
This working paper is available at ScholarlyCommons: http://repository.upenn.edu/cbe_sdr/23
1.
Letter of Transmittal
Professor Wen Shieh

Professor Leonard Fabiano
Mr. John Wismer
Dept. of Chemical & Biomolecular Engineering
Philadelphia, PA 19104
April 12th, 2011
Dear Professor Shieh, Professor Fabiano, and Mr. Wismer,

The following contains our report addressing Propylene From Biomass, proposed by
Mr. John Wismer, in fulfillment of the requirements of CBE 459. The proposed design gasifies
woodchips to create a synthesis gas (syngas), converts the syngas to dimethyl ether (DME) using
a novel microchannel reactor, and ultimately converts the DME to propylene and ethylene
products. The process serves to satiate the growing need for on-purpose propylene production,
using a low-cost, environmentally-friendly feedstock.
The primary focus of the report was overall process design and economic analysis. The
plant consumes 750,000 metric dry tons of woodchips per year to produce 145,000 metric tons of
polymer-grade propylene and 35,000 metric tons of chemical-grade ethylene. In the short term,
with a production period of 15 years, the project results in an NPV of $88 million and an IRR of
17.5%. In the long term, approximately 40% of the carbon in the woodchip feed is sequestered
in the final products.
Based on our analysis, further exploration and optimization of the biomass to propylene
process is warranted. Remaining key steps include locating the plant and securing biomass
supply contracts with sawmills, designing a specific biomass gasification system that satisfies
our quantities and syngas composition required, and obtaining experimental information about
operating the microchannel reactor at scale.
Sincerely,
__________________
Matthew Gay
__________________
Bryan Pope
__________________
Jake Wharton
2.
Tile Page
PROPYLENE FROM
BIOMASS
Matthew Gay
Bryan Pope
Jake Wharton
Chemical & Biomolecular Engineering
April 5th, 2011
Project Originator: Mr. John Wismer

Faculty Advisor: Dr. Wen Shieh
3.
Table of Contents
1.
Letter of Transmittal ................................................................................................................ 1
2.
Tile Page .................................................................................................................................. 2
3.
Table of Contents..................................................................................................................... 3
4.
Abstract .................................................................................................................................... 7
5.
Introduction and Project Charter ............................................................................................. 9

Introduction ................................................................................................................................. 9
Project Charter........................................................................................................................... 12
6.
Innovation Map...................................................................................................................... 15
7.
Market Analysis ..................................................................................................................... 17
8.
Process Flow Diagram and Material Balances ...................................................................... 20

Block 100 Solids Handling .................................................................................................... 20
Block 200 Gasification ........................................................................................................... 22
Block 300 MEA Absorption .................................................................................................. 26
Block 400 DME Formation .................................................................................................... 30
Block 500 DME Separation ................................................................................................... 32
Block 600 Olefin Reactor Train ............................................................................................. 34
Block 700 Steam Cracking..................................................................................................... 38
Block 800 Water Removal ..................................................................................................... 40
Block 900 Compression Sequence ......................................................................................... 42
Block 1000 Product Separation .............................................................................................. 44
9.
Process Description ............................................................................................................... 47

Block 200 - Gasification ........................................................................................................... 50
Block 600 Olefin Reactor Train ............................................................................................. 66
Block 700 Steam Cracking..................................................................................................... 70
Block 800 Water Removal ..................................................................................................... 72
Block 900 Compression Sequence ......................................................................................... 73
Block 1000 Product Separation .............................................................................................. 74
10.
Equipment List and Unit Descriptions ............................................................................... 76

3
Block 200 - Gasification ........................................................................................................... 80

Block 600 Olefin Reactor Train ........................................................................................... 102
Block 700 Steam Cracking................................................................................................... 107
Block 800 Water Removal ................................................................................................... 109
Block 900 Compression Sequence ....................................................................................... 113
Block 1000 Product Separation ............................................................................................ 117
11.
Specification Sheets ......................................................................................................... 125
12.
Equipment Cost Summary ............................................................................................... 230
13.
Energy Balance and Utility Requirements ....................................................................... 235
Overview: ................................................................................................................................ 235

Electricity: ............................................................................................................................... 235
Boiler-Feed Water: .................................................................................................................. 237
Chilled Water: ......................................................................................................................... 237
Cooling Water: ........................................................................................................................ 238
Steam: ...................................................................................................................................... 238
Natural Gas:............................................................................................................................. 240
Wastewater Treatment: ........................................................................................................... 240
14.
Fixed-Capital Investment Summary ................................................................................ 243
15.
Operating Cost and Economic Analysis .......................................................................... 247
Cash Flow and Profitability Analysis: .................................................................................... 251

Sensitivity Analysis: ................................................................................................................ 253
Competitive Analysis: ............................................................................................................. 257
16.
Other Considerations ....................................................................................................... 260
Plant Startup ............................................................................................................................ 260

Plantwide Control.................................................................................................................... 260
Plant Layout ............................................................................................................................ 260
17.
Conclusions and Recommendations ................................................................................ 262
18.
Acknowledgements .......................................................................................................... 264
19.
Bibliography .................................................................................................................... 266
20.
Appendices ....................................................................................................................... 273
Sample Calculations ................................................................................................................ 273

4
R-401 Costing Calculations Microchannel Reactor: ............................................................ 294

DME Reactor Sizing ............................................................................................................... 301
Simulation Results................................................................................................................... 302
ABSTRACT
4.
Abstract
The proposed design utilizes 750,000 metric dry tons per year of woodchip biomass
obtained from the local sawmill and forestry industries. The woodchips are processed and dried
before being fed to a gasification system. The gasifiers produce a hydrogen-rich syngas, which
is routed through a monoethanol amine (MEA) absorption section to remove the coproduced
CO2. The syngas then enters a novel microchannel reactor where the equilibrium between the
synthesis gas, methanol, and dimethyl ether results in a high overall conversion and efficient heat
removal. Conversions were modeled using recent experimental data from PNNL. The DME
product is removed from the reactor effluent using a water absorption tower and separated from
the water via distillation. The DME and methanol byproduct are then routed to another reactor
section where propylene, ethylene, and other hydrocarbon byproducts are produced. This reactor
section was designed with near 100% feed conversion. Propylene and ethylene are separated
from the other effluents to be sold as products. The byproduct hydrocarbons are routed back to a
steam cracking reactor to form additional propylene and ethylene, which are also feed to the
separation train.
145,000 metric tons per year of propylene and 35,000 metric tons per year of ethylene are
produced. An initial total permanent investment of $525 million is required, as well as annual
fixed and variable costs amounting to $62 million. The project has an NPV of $88 million at a
15% discount rate and an IRR of 17.5%.
The materials handling and gasification sections of the project require large initial
investments and continuing operating and maintenance expenses. The project is sensitive to the
price and availability of biomass, requiring further detailed siting and supply contracts. The
economics of this plant are compared to the economics of a traditional methanol-to-olefin
(MTO) process.
INTRODUCTION
5.
Introduction and Project Charter
Introduction
Building hydrocarbons from biomass feedstock has been a subject of interest in the
chemical industry. Biomass sources provide relatively inexpensive feedstock, but are of low
grade energetically. Biomass must first be broken down into a synthesis gas via gasification, and
then reconstructed into the desired compound. The gasification process is expensive because of
extensive pre-processing, the highly endothermic nature of the reaction, and the high temperature
and pressure at which the optimal syngas composition is produced. Up until recently, these costs
have been prohibitive when compared to conventional hydrocarbon feeds. However, as the
prices of conventional reactants increase and biomass technologies progress, using biomass as a
feedstock becomes more feasible.
Meanwhile, propylene demand has been steadily increasing and driving up prices.
Conventional methods of propylene production result in high ethylene/propylene ratios being
produced. However, ethylene demand has not kept pace with propylene demand, making these
processes costly to operate. This change in relative supply and demand has created a need for
on-purpose propylene production.
Gasification of biomass processes are an increasingly common topic of study and
continuously improving. Additionally, recent catalyst and reactor technology innovations have
shown the potential of high conversions from syngas to DME. Finally, DME, previously an
intermediate in the methanol-to-olefins process, can be used as a feedstock. Halder Topsoe, in
conjunction with the DOE and several other companies, recently embarked on a project to
convert wood to methanol and DME. Simultaneously, JGC Corp. has created a pilot plant that
creates propylene from a DME feed. Combining these innovations, a route from biomass to onpurpose propylene production has been proposed.
Biomass to synthesis gas processes are driven by solids handling. Biomass (in this case
woodchips) costs are largely composed of transportation expenses. Once transported to the site,
the woodchips must be conveyed to and from storage, processed to remove metal and decrease
size, dried to lower moisture content, and pressurized and pneumatically fed to the gasifiers.
Biomass gasifiers on the scale required by our process and that produce the desired H2/CO2 ratio
are uncommon, expensive, and have large operation costs. The resulting syngas must be treated
9
and the heat recovered. After being cooled, the excess CO2 in the syngas must be removed via
an MEA absorption process.
Microchannel reactors offer new operation methods for highly exothermic reactions.
Previously, the syngas to DME reaction had to take place in an oil-slurry heat transfer medium to
adequately remove the heat of reaction. Microchannel reactors use a combination of reaction
and heat removal channels with minimal heat transfer resistances between. The dimensions of
the channels lend themselves to high conversions, minimal fouling, and decreased volumes of
catalyst required. Recently, the syngas to DME reaction has been shown to benefit from the use
of microchannel reactors at the lab scale. To separate the DME intermediate from the unreacted
syngas, a large water absorption column is used. The syngas is recycled, while the DME is
distilled from the water.
DME is fed with a steam diluent to the olefin reactor. The olefin reactor contains a
shape-selective zeolite catalyst that has been optimized for propylene selectivity. To avoid the
requirement of a second water absorption column, the reaction is operated at above 99% DME
conversion. The water produced by the reaction and the steam diluent are removed from the
propylene product. The propylene, along with ethylene and other byproducts, is then fed to a
compression train, condensed, pressurized, and then fed to a separation train. The propylene and
ethylene products are removed from the heavier byproducts, then separated and sold as products.
Meanwhile, the heavier byproducts are rerouted to a steam cracking reactor to produce additional
propylene and other olefins, which are fed to the same water removal, compression, and
separation train. By recycling the byproducts back to the steam cracking reactor and using a
catalyst with high propylene selectivity, an overall conversion of greater than 70% propylene
was obtained.
10
11
Project Charter
Project name: Propylene from Biomass
Project team: Matt Gay, Bryan Pope, Jake Wharton
Specific Goals:
Convert biomass, specifically wood chips, to propylene via a synthesis gas to dimethyl
ether route. The DME to propylene process must achieve 70% propylene yield, the
minimum capacity is a processing rate of 750,000 metric tons of dry biomass per year,
and the overall process should be economically competitive with fossil fuel-based
processes.
Project Scope:
In scope:
Determine suitable biomass feed and feasibility of process scale
Design and basic optimization of the propylene production process using

existing technology
Utilize basic heat integration to minimize plant operating costs
Out-of-scope:
Development or testing of new technologies including catalysts, reactors, etc.
Specific handling and optimization of fuel byproducts or steam produced
Detailed solids handling and gasification reactor design
Detailed optimization, sensitivity analysis, or process control design
Deliverables:
Mass and energy balances of the process
Equipment specifications, designs, and cost estimates
Flowsheet diagrams and simulation results
Economic and profitability analyses, with an emphasis on overall feasibility
Time Line:
February 1st: Preliminary material balance and block flow diagram
February 22nd: Material balance and process flow diagram
March 15th: Syngas to DME reactor design
March 22nd: All major equipment designs
March 29th: Financial analysis
April 5th: All analyses and reports completed
12
13
INNOVATION MAP
14
6.
Innovation Map
15
MARKET ANALYSIS
16
7.
Market Analysis
Propylene is sold in three different grades. Polymer grade propylene requires a purity of
at least 99.5%, chemical grade propylene requires a purity of 93%, and refinery grade propylene
requires a purity of 70%. Although global demand and production totals do not distinguish
between purities, there is a significant price differential between the three grades. This plant
produces 99.5% pure propylene, and therefore it can be sold as polymer grade at the highest
possible price.
In 2010, the global production of propylene was 184 billion pounds, and it is estimated
that demand for propylene will continue to grow at a rate of 6% per year. Nearly two-thirds of all
propylene is used to produce polypropylene. Other major uses include production of propylene
oxide, acrylonitrile, and alcohols. Although propylene production capacity is increasing yearly, it
is not enough to keep pace with demand, which is causing propylene prices to skyrocket. From
December 2010 to January 2011, the price of propylene increased by 15%, and, in February, it
increased by another 25% to reach a record high of $0.805/lb for polymer grade propylene.
Unless propylene production increases, this rapidly increasing price trend is expected to
continue.
Propylene is in tight supply due to the typical production methods. Currently, the main
source of propylene comes from steam cracking of liquid petroleum-based feeds, such as naphtha
and gas oil. However, the main product from steam cracking is actually ethylene, with propylene
as a byproduct, typically in a molar ratio of approximately 1:2 propylene:ethylene. Throughout
2009 there was a huge drop in demand for ethylene, and by the beginning of 2010, many steam
crackers had been taken offline because there was insufficient demand to consume all of the
ethylene produced. Furthermore, many chemical plants have switched from using steam crackers
to ethane crackers to generate ethylene because ethane cracking has a much higher ethylene
selectivity. However, ethane cracking does not produce any propylene. With steam crackers
going offline or being switched to ethane crackers, the production of propylene has declined.
Another major source of propylene comes from the off-gases of fluid catalytic crackers (FCC) in
refineries. However, this method only produces refinery grade propylene, and needs to undergo
purification to obtain either chemical or polymer grade. Therefore, in most cases the additional
production of propylene from FCC does not make up for the loss of propylene from steam
17
cracking. Additionally, even if the demand for ethylene does recover (which it has started to), the
demand for propylene will be too large to be completely satisfied by these byproduct methods.
The demand for ethylene is expected to grow at only 3.4% per year, compared to the 6% growth
of propylene demand. With the demand for propylene increasing more rapidly than ethylene
demand, there is no way that steam cracking production of propylene can viably keep up with the
demand.
With the decline in propylene production as a byproduct of petroleum processing,
companies have begun constructing on-purpose propylene plants. The main on-purpose method
is propane dehydrogenation. This is a well established technology whereby propane and other
liquefied petroleum gases (LPG) are converted to propylene in a 1200F reactor with a noblemetal catalyst. Propane dehydrogenation is only viable when a long-term, low cost LPG source is
readily available. Furthermore, the capital cost relative to other propylene production methods is
very high. Therefore, companies have continued exploring other methods including Superflex by
Arco Chemical, deep catalytic cracking by Sinopec, olefins inter-conversion by ExxonMobil,
and methanol-to-propylene (MTP) by Lurgi.
Out of these new methods being explored, the closest to the propylene from biomass
(PFB) process investigated in this report is Lurgis MTP process. The MTP process begins with a
methanol feedstock and converts it to propylene through a DME intermediate. Similarly, in PFB,
propylene is obtained by going through both a methanol and DME intermediate. The main
differences between the PFB process are that biomass is the initial feedstock, both the conversion
to methanol and the conversion to DME take place in a single reactor, and the reactor that creates
DME in PFB utilizes novel microchannel technology to increase the DME yield and selectivity.
Furthermore, the MTP process assumes methanol comes from the steam reformation of natural
gas, rather than from a biomass source. Lurgi, along with SRI Consulting, performed a study for
a 570,000 ton/yr propylene plant, and the results are summarized in Table 1. A detailed
comparison of the economics of the PFB plant versus the Lurgi plant is presented on page 250.
Another plant for comparison is a 385,000 ton/yr plant that utilizes an Olefin Conversion
Technology, created by Lummus Technologies. This plant has an estimated total fixed capital
investment cost of $141 million and a production cost of $0.42/lb propylene.
18
PROCESS FLOW
DIAGRAMS
19
8.
Process Flow Diagram and Material Balances
Block 100 Solids Handling
20
Temperature F
Pressure psia
Vapor Frac
Mass Flow lb/hr
Mass Frac
WOODCHIP
WATER
Total Flow [lb/hr]
417538
S-101
75
14.7
0
125261.4
S-104
154.4
14.7
0
144050.4
0.5
0.5
0.85
0.15
Total Flow, 15% Moisture Chips [lb/hr]

240084
Moisture Removed [lb/hr]

177454
21
Block 200 Gasification
22
S-207 S-207 Moisture S-205

S-206
S-208
S-209
Temperature F
154.4
154.4
180
572
1700
1370.5
Pressure psia
464.7
464.7
450
1250
464.7
461.21
Vapor Frac
0
0
1
0
1
1
Mole Flow lbmol/hr
NA
1738.247
1755.651
2600
19326.02 19326.02
Mass Flow lb/hr
208769
31315
56667 46839.73 343590.7 343590.7
Volume Flow cuft/hr
NA
511.738
26560.4 1053.373 969969.2 828774.8
Enthalpy MMBtu/hr -637.761
-211.148
1.132
-294.538 -675.481 -732.939
S-210 S-210 filtered

924.7
924.7
457.59
432.59
1
1
19326.02 19326.019
343590.7 343590.728
632536.7 668819.951
-807.606
-807.606
S-211
S-212
747.4
372.4
429.13
429.13
1
1
19326.02 19326.02
343590.7 343590.7
588004.8 404951
-836.245 -894.84
Mole Frac
HYDROGEN
C
OXYGEN
NITROGEN
CO
CO2
METHANE
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0.95
0.01
0
0
0
0
0
0
0
0
0
0
0.518
0
0
0.001
0.24
0.215
0.022
0.518
0
0
0.001
0.24
0.215
0.022
0.518
0
0
0.001
0.24
0.215
0.022
0.518
0
0
0.001
0.24
0.215
0.022
0.518
0
0
0.001
0.24
0.215
0.022
0.518
0
0
0.001
0.24
0.215
0.022
WATER
SULFUR
MEA
ARGON
NITRO-01
NITRO-02
WOODCHIP
0
0
0
0
0
0
1
1
0
0
0
0
0
0
0
0
0
0.04
0
0
0
1
0
0
0
0
0
0
0
0
0
0.004
0
0
0
0
0
0
0.004
0
0
0
0
0
0
0.004
0
0
0
0
0
0
0.004
0
0
0
0
0
0
0.004
0
0
0
0
0
0
0.004
0
0
0
23
24
S-213
S-214
S-215
S-216
S-217
S-218
S-219
S-220
S-221
S-222
S-223
S-224
S-225
S-226
Temperature F
341.6
254.4
77
77.5
280
350
393.5
77
80.5
400
600
620.7
1400
854.4
Pressure psia
425.93 423.05
14.7
230
229.56 229.11 229.11
14.7
1800
1800 1799.69 1798.99 1797.86 298.79
Vapor Frac
1
1
0
0
0
0
1
0
0
0
0
1
1
1
Mole Flow lbmol/hr 19326 19326
3608
3608
3608
3608
3608
6661
6661
6661
6661
6661
6661
6661
Mass Flow lb/hr
343590 343590
65000 65000 65000 65000 65000 120000 120000 120000 120000 120000 120000 120000
Volume Flow cuft/hr 392710 351756
1044
1043
1121
1168 135349
1927
1918
2215
2814
29743 70789 307273
Enthalpy MMBtu/hr -899.54 -912.736 -443.363 -443.29 -430.095 -425.395 -366.799 -818.516 -817.521 -778.744 -750.106 -675.437 -617.979 -649.784
Mole Frac
HYDROGEN
0.518
0.518
0
0
0
0
0
0
0
0
0
0
0
0
C
0
0
0
0
0
0
0
0
0
0
0
0
0
0
OXYGEN
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NITROGEN
0.001
0.001
0
0
0
0
0
0
0
0
0
0
0
0
CO
0.24
0.24
0
0
0
0
0
0
0
0
0
0
0
0
CO2
0.215
0.215
0
0
0
0
0
0
0
0
0
0
0
0
METHANE
0.022
0.022
0
0
0
0
0
0
0
0
0
0
0
0
WATER
SULFUR
MEA
ARGON
NITRO-01
NITRO-02
WOODCHIP
0.004
0.004
25
Block 300 MEA Absorption
26
CW-301
CW-302
Temperature F
Pressure psia
Vapor Frac
Mole Flow lbmol/hr
Mass Flow lb/hr
Volume Flow cuft/hr
90
64.7
0
213323.8
3.84E+06
61856.35
120
57.52
0
213323.845
3.84E+06
62263.621
90
123
90
120.3
100
64.7
62.93
64.7
58.76
300
0
0
0
0
1
27754.22 27754.22 113792.3 113792.3 19335
500000 500000 2.05E+06 2.05E+06 341103.3
8047.739 8106.872 32995.73 33215.52 386362.9
100
297.59
0
45715.361
1.33E+06
21964.931
Enthalpy MMBtu/hr
Mole Frac
HYDROGEN
OXYGEN
NITROGEN
CO2
MEA
WATER
-26180
-26064.973
-3406.12 -3389.63 -13965.1 -13903.1 -929.045
-5875.294
-17.111
-417.36
0
0
0
0
0
1
0
0
0
0
0
1
0
0
0
0
0
1
0
0
0
0
0
1
0
0
0
0
0
1
0
0
0
0
0
1
0.518
0
0.002
0.211
0
0
0
0
0
0
0.152
0.777
0
0
0
0
0.02
0.98
0.604
0
0.002
0.05
0
0.03
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0.245
0.024
0
0.036
0
0.034
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0.286
0.027
0
MEA+
H3O+
MEACOOHCO3CO3-SULFU-01
CO
METHANE
H2
CW-303
CW-304
CW-305
CW-306
S-214
S-302
S-304
S-305
100
204.1
300
300
0
1
139.743 16574.89
2637.375 206792
42.461 395873.5
27
28
S-306
Temperature F
125
Pressure psia
296.76
Vapor Frac
0.977
Mole Flow lbmol/hr 16573.77
Mass Flow lb/hr
206792
Volume Flow cuft/hr 344502.9
Enthalpy MMBtu/hr -433.843
Mole Frac
HYDROGEN
0.604
OXYGEN
0
NITROGEN
0.002
CO2
0.05
MEA
0
WATER
0.03
MEA+
H3O+
CO
METHANE
H2
S-307
S-308
S-309
S-310
S-311
S-312
S-313
S-314
S-315
S-316 S-316R S318
S319
124.9
124.9
193.6
193.7
242.7
290.4
218.7
249.4
120
215.1
214
118.4
216
296.76
296.76
300.02
85
80.22
43.05
39.74
43
39.27
43
39.27
39.27
300
0.012
0.537
384.899
16188.87 45844.45 45848.96 46370.87 42674.41 42669.929 6345.957 6331.8 45715.58 45597.79 3401.196 45715.59
7037.079
199754.9 1.48E+06 1.48E+06 1.48E+06 1.28E+06 1.28E+06
114.251
344388.7 26543.13 27282.73 79493.98 23447.84 22374.049 1.11E+06 532078.5 23259.25 23214.23 531201.5 23262.24
-47.209
-386.634 -6451.3
200000
200000 1.33E+06 1.33E+06 1.46E+05 1.33E+06
-6451.3 -6379.53 -5316.15 -5387.918 -864.006 -926.023 -5761.59 -5749.02 -564.925 -5760.26
0.619
0.001
0.002
0.051
0.002
0.002
0.014
0.516
0.515
0.957
0.019
0.019
0.04
0.164
0.164
0.002
0.153
0.153
0.153
0.994
0.007
0.77
0.77
0.764
0.761
0.761
0.482
0.481
0.777
0.776
0.042
0.777
0.003
0.105
0.105
0.092
0.038
0.038
0.002
0.036
0.036
0.036
0.099
0.099
0.088
0.036
0.036
0.034
0.034
0.034
0.003
0.005
0.005
0.003
0.001
0.002
0.286
0.293
0.027
0.028
29
Block 400 DME Formation
BLOCK 400 DME Formation
S-401
S-406
CW-IN
R-401
FROM-REC
C-401
H-402
S-403
S-402
TO-SEP
S-404
H-401
CW-OUT
S-405
Stream
FROM-REC
S-401
S-402
S-403
S-404
S-405
S-406
TO-SEP
Temperature F
172
99
254.8
200.5
465.5
536
250.5 166.94401
Pressure psia
200
300
270
270
265
240
235 231.62377
1 0.9020208
Vapor Frac
Mole Flow lbmol/hr
Mass Flow lb/hr
23763.219 15478.414 23763.219 39241.633 39241.633 29774.394 29774.394 29774.394

483004
483004
1.33E+06 957709.98
7.80E+05
H2
28577.899 20184.978 28577.899 48762.877 48762.877 29719.376 29719.376
29740.85
N2
21321.568
Vol. Flow cuft/hr
312814
483004
483004
803937.573 311745.67 675234.21
312814
170190
1.03E+06
1.48E+06
483004
Mass Flow lb/hr
CO
997.29 21321.568 22318.858 22318.858 22318.472 22318.472 22313.668
1287.051 132885.09
1287.051 134172.14 134172.14
1341.721 1341.7191
97462.458
7901.942 97462.458
CH4
62711.279
7300.505 62711.279 70011.783 70011.783 70000.243 70000.243 69910.614
WATER
13058.152
CH4O
C2H6O-01
2.624
88971.886
920.198 13058.152
0
2.624
105364.4
1341.721
CO2
13978.35
2.624
105364.4 105891.45 105891.45 105755.39

13978.35 53398.959 53398.959 53347.113
2.624
10581.07
10581.07 10574.191
0 88971.886 88971.886 88971.886 190296.71 190296.71 190020.46
30
31
Block 500 DME Separation
BLOCK-500 DME Separation

TO-REC
PURGE
WASTE
FROM-800
S-512
S-513
CW-IN
H-501
S-515 S-514
S-502
H-503
P-507
CW-OUT
T-501
S-507
D-501
S-516
P-504
V-502
PRODUCT
S-501
FROM-REAC
S-509
S-506
V-501
S-508
S-504
P-502
P-501
S-511
STEAM
V-503
S-505
P-503
H-502
P-505
P-506
S-503
S-510
32
BLOCK-500 DME Separation
Stream
T emperature F
Pressure psia
Vapor Frac
Mole Flow lbmol/hr
Mass Flow lb/hr
Vol. Flow cuft/hr
Mass Flow lb/hr
H2
N2
CO
CO2
CH4
WAT ER
CH4O
C2H6O-01
FROM-REAC
166.944013
231.623773
0.90202076
29774.3938
483004
7.80E+05
S-501
S-502
167.1
172
230
200
1
1
26726.15 24498.16
418421.1 323085.5
781149.8 828801.6
PURGE
172
200
1
734.945
9692.564
24864.05
T O-REC
172
200
1
23763.219
313392.92
803937.57
S-503
167.1
235
0
2978.168
66524.376
1294.953
S-504
170.7
206.8
0
16227.988
347549.51
6606.367
S-505
170.2
201.8
0
19206.156
414073.88
7901.198
S-506
170.3
230
0
19206.156
414073.88
7901.917
29461.74
22142.44
1339.068
105312.2
69205.55
10528.76
6879.602
173551.8
29461.75
21981
1326.856
100476.8
64650.8
13462.01
2.705
91723.59
883.853
659.43
39.806
3014.303
1939.524
403.86
0.081
2751.708
28577.899
21321.568
1287.051
97462.458
62711.279
13058.152
2.624
88971.886
0.001
35.538
2.675
1195.523
1000.963
43071.995
3769.973
17447.709
0.003
161.454
12.212
4835.461
4554.769
249280.53
6876.893
81828.18
0.004
196.992
14.888
6030.983
5555.732
292352.53
10646.866
99275.888
0.004
196.992
14.888
6030.983
5555.732
292352.53
10646.866
99275.888
0.004
196.445
14.835
5533.94
5373.142
0
0.218
8881.366
0
0.548
0.052
497.062
182.609
2247.893
10634.812
88436.97
Stream
T emperature F
Pressure psia
Vapor Frac
Mole Flow lbmol/hr
Mass Flow lb/hr
Vol. Flow cuft/hr
Mass Flow lb/hr
H2
N2
CO
CO2
CH4
WAT ER
CH4O
C2H6O-01
S-509
384.5
207.4
0
4429.17
80121.123
1599.375
S-510
S-511
384.5
384.5
207.4
207.4
0
0
2211.237 9505.707
40000 171952.8
798.479 3432.516
ST EAM
280.5
50
1
1276.053
23397.98
198865.3
S-512
FROM-800
280.5
242.2
55
65
0
0
8229.654
9100
148554.78 163939.05
2717.545
2916.882
S-513
260.5
55
0
17329.654
312493.82
5632.887
S-514
110
45
0
17329.654
312493.82
5130.448
WAST E
110
45
0
3329.654
60041.375
985.745
S-515
110
40
0
14000
252213.92
4139.033
S-516
110.4
205
0
14000
252213.92
4140.012
0
0
0
0
0
79580.937
3.24
536.945
0
0
0
0
0
0
0
0
0
0
39730.32 170793.4
1.618
6.954
268.067 1152.371
0
0
0
0
0
22724.49
3.514
669.979
0
0
0
0
0
148068.94
3.44
482.392
0
0
0
0
0
312007.99
3.44
482.392
0
0
0
0
0
312007.99
3.44
482.392
0
0
0
0
0
59948.029
0.661
92.685
0
0
0
0
0
252213.92
0
0
0
0
0
0
0
252213.92
0
0
29740.8499
22313.6678
1341.71911
105755.39
69910.6142
53347.1133
10574.1905
190020.455
0
0
0
0
0
163939.05
0
0
S-507
PRODUCT
58.5
151.1
205
206.2
1
0
661.004
2399.038
19999.95 101999.95
16440.438
2672.163
S-508
384.5
212.4
0
16146.114
292073.88
5810.957
0
0
0
0
0
290104.69
11.812
1957.383
33
Block 600 Olefin Reactor Train

HP Steam
HP Steam
S-616
S-617
H-605
H-607
Boiler Water
S-611
Boiler Water
S-624
S-619
H-601
S-606
S-605
S-604
S-603
H-602
H-603
R-601
HP Steam
HP Steam
R-602
R-603
R-604
HP Steam
S-612
S-615
HP Steam
S-620
S-623
HP Steam
S-602
H-604
S-613
H-606
S-621
Boiler Water
Boiler Water
S-509
S-610
S-614
S-618
S-622
P-601
S-607
S-601
S-608
S-609
H-608
P-602
S-625
S-626
34
S-509
S-601
S-602
S-603
S-604
S-605
S-606
S-607
S-608
S-609
S-610
S-611
S-612
S-613
Temperature F
384.5
135.8
385.7
385.7
447.3
459.8
707.0
138.3
138.3
707.0
707.0
707.0
923.7
650.0
Pressure psia
207.4
206.2
500
475
470
465
460
485
460
455
450
450
420
415
Vapor Frac
Mole Flow lbmol/hr
Mass Flow lb/hr
Volume Flow cuft/hr
4429
2400
4429
4429
4429
4429
4429
2400
2400
2400
432
4861
5019
5019
79793
102028
79793
79793
79793
79793
79793
102028
102028
102028
18365
98158
98158
98158
1582
2606
1584
1584
1678
93982
120551
2616
2616
66030
12017
135247
177398
144009
498
498
498
498
90
90
90
90
Mass Flow lb/hr

CARBON-DIOXIDE
WATER
79793
2248
79793
79793
79793
79793
79793
2248
2248
2248
405
80197
86717
86717
METHANOL
10635
10635
10635
10635
1914
1914
DIMETHYL-ETHER
88464
88464
88464
88464
15924
15924
N-PROPIONALDEHYDE
385
385
METHACROLEIN
560
560
METHYL-ISOPROPYL-KETONE
350
350
DIETHYL-KETONE
232
232
METHYL-N-PROPYL-KETONE
673
673
DIETHYL-KETONE
232
232
673
673
METHANE
183
183
183
183
33
33
ETHYLENE
618
618
PROPYLENE
1828
1828
ISOBUTANE
1070
1070
N-BUTANE
1549
1549
TRANS-2-BUTENE
499
499
1-BUTENE
370
370
ISOBUTYLENE
918
918
CIS-2-BUTENE
406
406
2-METHYL-BUTANE
401
401
1,3-BUTADIENE
66
66
N-PENTANE
264
264
N-HEXANE
38
38
N-HEPTANE
BENZENE
35
36
S-614
S-615
S-616
S-617
S-618
S-619
S-620
S-621
S-622
S-623
S-624
S-625
S-626
Temperature F
707.0
661.6
895.6
650.0
707.0
663.9
910.5
650.0
707.0
658.4
786.8
730.0
231.8
Pressure psia
410
410
370
365
360
360
260
255
235
235
35
30
25
Vapor Frac
0.98170183
528
5547
5707
5707
840
6546
6863
6863
600
7462
7747
7747
7747
Mass Flow lb/hr
22446
120604
120604
120604
35710
156313
156313
156313
25507
181820
181820
181820
181820
Volume Flow cuft/hr
16121
162784
224312
186181
29209
219260
388100
320478
31961
381018
2960721
3296678
2257295
CARBON-DIOXIDE
109
199
199
199
174
373
373
373
124
498
498
498
498
WATER
495
87211
94977
94977
787
95764
108704
108704
562
109266
119067
119067
119067
2340
2343
3722
3726
2659
2664
Mole Flow lbmol/hr
Mass Flow lb/hr
METHANOL
DIMETHYL-ETHER
19462
19462
30962
30962
22116
22116
N-PROPIONALDEHYDE
385
680
680
680
1082
1082
1082
974
974
974
METHACROLEIN
560
1187
1187
1187
2380
2380
2380
3367
3367
3367
350
1009
1009
1009
1598
1598
1598
1854
1854
1854
DIETHYL-KETONE
232
652
652
652
1047
1047
1047
1080
1080
1080
673
1906
1906
1906
3047
3047
3047
3272
3272
3272
DIETHYL-KETONE
232
652
652
652
1047
1047
1047
1080
1080
1080
673
1906
1906
1906
3047
3047
3047
3272
3272
3272
METHANE
40
40
64
64
46
46
147
147
147
ETHYLENE
618
854
854
854
1824
1824
1824
2724
2724
2724
PROPYLENE
1828
3159
3159
3159
6806
6806
6806
16566
16566
16566
ISOBUTANE
1070
2526
2526
2526
4288
4288
4288
5675
5675
5675
N-BUTANE
1549
3553
3553
3553
6127
6127
6127
4596
4596
4596
TRANS-2-BUTENE
499
1072
1072
1072
2338
2338
2338
733
733
733
1-BUTENE
370
767
767
767
1705
1705
1705
908
908
908
ISOBUTYLENE
918
2009
2009
2009
4338
4338
4338
3178
3178
3178
CIS-2-BUTENE
406
868
868
868
1898
1898
1898
2904
2904
2904
2-METHYL-BUTANE
401
1127
1127
1127
1982
1982
1982
2160
2160
2160
1,3-BUTADIENE
66
128
128
128
359
359
359
649
649
649
N-PENTANE
264
727
727
727
1293
1293
1293
2094
2094
2094
N-HEXANE
38
124
124
124
228
228
228
371
371
371
N-HEPTANE
22
22
22
43
43
43
3601
3601
3601
BENZENE
408
408
408
37
Block 700 Steam Cracking

S-707
S-708
R-701
S-1005
S-701
S-704
S-703
H-701
S-705
S-706
H-702
S-710
S-709
Nat. Gas
F-701
IP Steam
R-702
S-702
S-510
S-712
S-711
R-703
S-713
S-714
38
S-1005
S-510
S-701
S-702
S-703
S-704
S-705
S-706
S-707
S-708
S-713
S-714
Temperature F
185
384.5
185.0004
331.5216
234.4126
296.452
665
932
920.1386
709.1246
705.4238
343.5152
Pressure psia
105
207
105
105
105
100
95
90
90
30
30
25
Vapor Frac
1905
2220
1905
2220
4126
4126
4126
4126
1361
1577
4638
4638
109301.1
40000
109301.1
40000
149301.1
149301.1
149301.1
149301.1
49269
49269
149301.1
149301.1
44809
793
44810
15070
61630
334760
524136
684599
222909
659266
1932878
1598971
WATER
4372
40000
4324
40000
44324
44324
44324
44324
14627
16072
47271
47271
N-PROPIONALDEHYDE
1312
1284
1284
1284
1284
1284
424
93
274
274
METHACROLEIN
656
670
670
670
670
670
221
N-BUTYRALDEHYDE
219
218
218
218
218
218
72
17
49
49
METHYL-ACETATE
109
115
115
115
115
115
38
2295
2328
2328
2328
2328
2328
768
131
384
384
DIETHYL-KETONE
1421
1384
1384
1384
1384
1384
457
84
246
246
4153
4163
4163
4163
4163
4163
1374
246
723
723
DIETHYL-KETONE
1421
1384
1384
1384
1384
1384
457
84
246
246
4153
4163
4163
4163
4163
4163
1374
246
723
723
328
276
276
276
276
276
91
17
49
49
Mole Flow lbmol/hr

Mass Flow lb/hr
Volume Flow cuft/hr
Mass Flow lb/hr
3-METHYL-2-PENTANONE
ETHYLENE
2408
7084
7084
PROPYLENE
219
273
273
273
273
273
90
8602
25300
25300
ISOBUTANE
25030
24993
24993
24993
24993
24993
8248
7156
21046
21046
N-BUTANE
30276
30224
30224
30224
30224
30224
9974
9970
29322
29322
TRANS-2-BUTENE
765
733
733
733
733
733
242
1-BUTENE
874
908
908
908
908
908
300
ISOBUTYLENE
3170
3178
3178
3178
3178
3178
1049
CIS-2-BUTENE
9618
9588
9588
9588
9588
9588
3164
2275
6692
6692
2-METHYL-BUTANE
11367
11372
11372
11372
11372
11372
3753
3038
8934
8934
1,3-BUTADIENE
1530
1571
1571
1571
1571
1571
518
310
911
911
N-PENTANE
2077
2094
2094
2094
2094
2094
691
N-HEXANE
328
371
371
371
371
371
123
N-HEPTANE
3607
3601
3601
3601
3601
3601
1188
36
36
36
36
36
12
BENZENE
39
Block 800 Water Removal

S-809
S-804
H-804
Cooling Water
C-801
S-805
V-802
S-808
P-804
V-801
S-803
S-807
S-806
D-801
LP Steam
LP Steam
S-626
S-802
S-801
H-801
S-714
Boiler Water
H-802
P-801
P-802
H-803
S-810
S-811
P-803
Cooling Water
40
S-801
S-802
S-803
S-804
S-805
S-806
S-807
S-808
S-809
S-810
S-811
Temperature F
268.9
235.0
140.0
138.4
235.1
138.4
138.6
159.5
133.2
248.1
248.4
Pressure psia
25
22
19
18
55
18
55
27
25
29
90
Vapor Frac
0.219908
0.219243
12384
12384
12384
2761
2761
9623
9623
12384
3384
9000
9000
331121
331121
331121
127660
127660
203462
203462
331121
166636
164485
164485
3873020
4196509
926238
984527
374308
3765
3766
672166
861354
2954
2955
662
498
498
481
481
17
17
498
498
166223
166338
166338
7068
7068
159270
159270
166338
5001
161337
161337
N-PROPIONALDEHYDE
1324
1248
1248
1081
1081
168
168
1248
1248
METHACROLEIN
3311
3367
3367
482
482
2885
2885
3367
782
2585
2585
331
210
210
147
147
63
63
210
210
2318
2239
2239
1742
1742
496
496
2239
2239
DIETHYL-KETONE
1324
1327
1327
1001
1001
326
326
1327
1327
3973
3994
3994
2829
2829
1165
1165
3994
3994
DIETHYL-KETONE
1324
1327
1327
1001
1001
326
326
1327
1327
3973
3994
3994
2829
2829
1165
1165
3994
3994
331
262
262
202
202
60
60
262
262
Mole Flow lbmol/hr

Mass Flow lb/hr
Volume Flow cuft/hr
Mass Flow lb/hr
CARBON-DIOXIDE
WATER
N-BUTYRALDEHYDE
METHANE
147
147
145
145
147
147
ETHYLENE
9934
9807
9807
9469
9469
338
338
9807
9807
PROPYLENE
41721
41866
41866
35450
35450
6416
6416
41866
41866
ISOBUTANE
26821
26721
26721
17457
17457
9264
9264
26721
26716
N-BUTANE
33774
33919
33919
19698
19698
14221
14221
33919
33885
34
34
TRANS-2-BUTENE
662
733
733
422
422
312
312
733
733
1-BUTENE
993
908
908
571
571
337
337
908
908
3311
3178
3178
1991
1991
1187
1187
3178
3177
ISOBUTYLENE
CIS-2-BUTENE
9603
9597
9597
5344
5344
4252
4252
9597
9582
14
14
11258
11094
11094
11086
11086
11094
11094
1,3-BUTADIENE
1656
1560
1560
956
956
604
604
1560
1559
N-PENTANE
1987
2094
2094
2091
2091
2094
2094
2-METHYL-BUTANE
N-HEXANE
331
371
371
370
370
371
371
N-HEPTANE
3642
3601
3601
3578
3578
24
24
3601
3601
331
408
408
41
41
367
367
408
47
361
361
BENZENE
41
Block 900 Compression Sequence

S-809
S-901
S-906
H-901
C-901
S-911
H-902
S-912
H-904
H-903
C-902
S-913
P-903
C-903
Cooling Water
Cooling Water
Cooling Water
Propylene
S-914
S-902
S-903
S-907
S-908
V-901
S-915
V-902
S-909
S-904
S-910
P-902
S-905
P-901
42
S-901
S-902
S-903
S-904
S-905
S-906
S-907
S-908
S-909
S-910
S-911
S-912
S-913
S-914
S-915
Temperature F
210.6
110.0
110.0
110.0
115.3
190.2
110.0
110.0
110.0
114.9
169.3
100.0
46.9
48.0
91.1
Pressure psia
65
60
57
60
557.9
150
145
142
145
557.9
270
265
260
557.9
557.9
Vapor Frac
0.6692
0.5961
0.39632
3384
3384
2265
1119
1119
2265
2265
1350
915
915
1350
1350
1350
1350
3384
Mass Flow lb/hr
166636
166636
107836
58801
58801
107836
107836
58391
49445
49445
58391
58391
58391
58391
166636
Volume Flow cuft/hr
374548
232264
242938
1473
1481
105306
58370
58131
1442
1452
33758
13334
1753
1756
4689
500
498
485
12
12
485
485
453
32
32
453
453
453
453
498
WATER
4999
5001
357
4645
4645
357
357
350
350
5001
N-PROPIONALDEHYDE
1166
1248
445
804
804
445
445
52
393
393
52
52
52
52
1248
METHACROLEIN
833
782
116
667
667
116
116
109
109
782
N-BUTYRALDEHYDE
167
210
37
173
173
37
37
35
35
210
2166
2239
249
1990
1990
249
249
243
243
2239
DIETHYL-KETONE
1333
1327
115
1211
1211
115
115
113
113
1327
3999
3994
311
3683
3683
311
311
306
306
3994
DIETHYL-KETONE
1333
1327
115
1211
1211
115
115
113
113
1327
3999
3994
311
3683
3683
311
311
306
306
3994
333
262
12
249
249
12
12
12
12
262
Mole Flow lbmol/hr
Mass Flow lb/hr

CARBON-DIOXIDE
METHANE
167
147
146
146
146
144
144
144
144
144
147
ETHYLENE
9832
9807
9566
241
241
9566
9566
8939
627
627
8939
8939
8939
8939
9807
PROPYLENE
41826
41866
36812
5054
5054
36812
36812
26633
10180
10180
26633
26633
26633
26633
41866
ISOBUTANE
26662
26716
18755
7961
7961
18755
18755
8596
10158
10158
8596
8596
8596
8596
26716
N-BUTANE
33827
33885
21264
12621
12621
21264
21264
8049
13216
13216
8049
8049
8049
8049
33885
TRANS-2-BUTENE
667
733
455
278
278
455
455
168
286
286
168
168
168
168
733
1-BUTENE
833
908
613
294
294
613
613
263
350
350
263
263
263
263
908
3166
3177
2143
1035
1035
2143
2143
914
1229
1229
914
914
914
914
3177
ISOBUTYLENE
CIS-2-BUTENE
9665
9582
5774
3808
3808
5774
5774
2041
3733
3733
2041
2041
2041
2041
9582
11165
11094
6996
4098
4098
6996
6996
1466
5530
5530
1466
1466
1466
1466
11094
1,3-BUTADIENE
1500
1559
1034
525
525
1034
1034
430
604
604
430
430
430
430
1559
N-PENTANE
2166
2094
1107
987
987
1107
1107
184
924
924
184
184
184
184
2094
2-METHYL-BUTANE
N-HEXANE
333
371
112
259
259
112
112
105
105
371
N-HEPTANE
3666
3601
458
3144
3144
458
458
10
448
448
10
10
10
10
3601
47
42
42
47
BENZENE
43
Block 1000 Product Separation

H-1002
H-1003
Cooling Water
H-1005
Chilled Water
Propylene
V-1001
S-915
V-1002
S-1001
S-1003
S-1002
H-1001
P-1002
S-1008
S-1007
P-1003
P-1004
P-1005
D-1002
D-1001
S-1009
IP Steam
S-1005
LP Steam
H-1004
S-1004
P-1001
P-1006
S-1006
H-1006
S-1010
P-1007
44
S-1001
S-1002
S-1003
S-1004
S-1005
S-1006
S-1007
S-1008
S-1009
S-1010
Temperature F
180.0
93.7
95.6
320.9
223.9
182.1
28.7
30
185.9
187
Pressure psia
528.54
525
652.56
529.52
100
100
650
670
654.1
705
Vapor Frac
0.895782
0.421758
3384
1310
1310
2074
2074
2074
345
345
965
965
166636
50006
50006
116631
116631
116631
9750
9750
40255
40255
Volume Flow cuft/hr
5429
1781
1791
4938
136617
62063
440
440
1943
1943
Enthalpy MMBtu/hr
-122.2
8.7
8.8
-116.5
-116.5
-128.7
4.2
4.2
8.1
8.1
500
498
498
460
460
38
38
WATER
4999
5001
5001
5001
N-PROPIONALDEHYDE
Mole Flow lbmol/hr

Mass Flow lb/hr
Mass Flow lb/hr

CARBON-DIOXIDE
1166
1248
1248
1248
METHACROLEIN
833
782
782
782
N-BUTYRALDEHYDE
167
210
210
210
METHYL-ACETATE
167
114
114
114
2166
2239
2239
2239
DIETHYL-KETONE
1333
1327
1327
1327
DIETHYL-KETONE
3999
1333
0
0
0
0
3994
1327
3994
1327
3994
1327
0
0
0
0
0
0
0
0
3999
3994
3994
3994
333
167
0
147
0
147
262
0
262
0
262
0
0
147
0
147
0
0
0
0
9832
9807
9807
9098
9098
709
709
PROPYLENE
ISOBUTANE
41826
26662
39551
1
39551
1
2315
26715
2315
26715
2315
26715
45
0
45
0
39506
1
39506
1
N-BUTANE
33827
33885
33885
33885
667
833
0
0
0
0
733
908
733
908
733
908
0
0
0
0
0
0
0
0
3166
3177
3177
3177
9665
11165
0
0
0
0
9582
11094
9582
11094
9582
11094
0
0
0
0
0
0
0
0
1,3-BUTADIENE
1500
1559
1559
1559
N-PENTANE
N-HEXANE
N-HEPTANE
2166
333
3666
0
0
0
0
0
0
2094
371
3601
2094
371
3601
2094
371
3601
0
0
0
0
0
0
0
0
0
0
0
0
47
47
47
METHANE
ETHYLENE
TRANS-2-BUTENE
1-BUTENE
ISOBUTYLENE
CIS-2-BUTENE
2-METHYL-BUTANE
BENZENE
45
PROCESS DESCRIPTION
46
9.
Process Description
The proposed process is separated into ten blocks. The first block (100) is the initial solids
handling of the biomass. The next two blocks (200, 300) are the syngas production and the
MEA stripping sections. Block 400 contains the DME formation reactor, and Block 500 is the
separation of the DME intermediate. Blocks 600 and 700 include olefin producing reactor
sections. Finally, blocks 800, 900, and 1000 are the water removal, compression, and product
separation sections.

Solids Handling Overview
The process to convert biomass to a synthesis gas begins with the logistics of upstream
solids handling. Solids handling poses many difficulties arising from the differences in moving a
solid phase as opposed to a liquid or gas in a typical chemical process. Handling solids requires
capital-intensive equipment and large areas of open space for bulky feedstock, machinery, and
maneuvering room. Thus, in a process that requires a solid feed, the logistics of handling
material is of high importance and cannot be overlooked.
It is significant to note that the scope of this project as a preliminary design considered
the entire process as a whole solution, and thus the solids handling upstream of the actual process
47
was mapped out for a general perspective of the expansive equipment and utility requirements to
arrive at a rough costing estimate. The scheme presented is not necessarily the optimal series or
arrangement of equipment for this task, but rather one potential permutation of many possible
options for moving the feed.
Feedstock Considerations
Woodchips were chosen as the biomass feedstock for this particular process. However,
there were many types of biomass to choose from, ranging from on-purpose short rotation crops
like hybrid poplar and switchgrass, to agricultural residues like corn stover. Woodchips were
ultimately chosen for their relatively high density and ease of processing, which was the primary
operational concern at the scale of this plant. Specifying a plant processing capacity of 750,000
metric tons of biomass per year eliminated the choice of using lighter materials like corn stover,
bagasse, or switchgrass, as their low density would make solids handling equipment
prohibitively large. Additionally, the availability of biomass was considered, and woodchips are
regularly available in large quantities year-round. Agricultural residues like corn stover are only
available once per year when the corn crops are harvested, thus creating a need for substantially
large on-site storage for a yearlong supply of feed. Furthermore, many agricultural wastes are
valuable to the farms that generate them, mainly for compost and reintroduction of nutrients into
the soil. If these residues are purchased at scale, the farms have to supplement the nutrients that
are being removed, and the costs of these feedstocks are often inflated accordingly.
Woodchips also have a slightly higher percentage of carbon by mass than other biomass
sources. Corn stover and bagasse are typically 40-45% carbon by mass. The ultimate analysis
assumed for the composition of this woodchip feed is 49.54% carbon, 6.11% hydrogen, 0.10%
nitrogen, 0.02% sulfur, and 43.73% oxygen. This composition is representative of a variety of
woods like poplar, oak, eucalyptus, and pine. The woodchips are assumed to be delivered with a
moisture content of 50% by mass, and are estimated to be available at $42 per bone dry ton,
including the cost of delivery for distances up to 50 miles.
The plant location was chosen to be in the state of Georgia due to large quantities of
forestry and mill residues available. According to studies focusing on the availability of
woodchip products in Georgia, approximately 5.314 million dry tons of harvesting residues, 8
million tons of mill residues, and 6,294 tons of isolated woodchip product are produced in
Georgia annually. The current state of these stocks of biomass suggests that about 95% of the
48
available harvesting residues are unutilized, and only 1% of the mill residues in Georgia are
unutilized. This yields an estimated 4,658,770 metric tons of unused forestry residue available
for feedstock. For a feed rate of 208,769 lb/hr of dry biomass (749,864 metric tons per year), the
plant requires approximately 16% of the unutilized forestry residues in the state of Georgia or
10% of the total mill residues, the majority of which are currently utilized for low-grade heat.
Solids Handling Logistics
For purposes of storing material on-site for continuous operation through times of no
delivery and to account for unexpected externalities, a covered building is necessary. With a feed
rate of 208,769 lb/hr of dry wood chips, a building of approximately 4.9 million cubic feet is
required to hold a 30-day feed supply (assuming a bulk woodchip density of 500 kg/m3). This
building (M-101), at a height of 30 feet, and at an overdesign of 25% to allow headspace and
equipment maneuvering, is sized at approximately 204,000 square feet.
Wood chips are delivered to the plant via tractor-trailer trucks. The trucks enter the plant
site and are weighed on a truck scale. The trucks are then moved to a truck dumper for unloading
of the chips. The truck dumpers tip each truck to transfer the solid material to a 6,900 cubic foot
receiving hopper. This operation can sustain seven truck deliveries per hour. The woodchips are
then conveyed to long-term storage and/or the process building and inside battery limits via belttype conveyors (see Block 100 process flow diagram on page 20).
From either the receiving hopper or long-term storage (depending on current process
demand and site conditions) woodchips are conveyed to three hammer mills (X-101, 102, 103),
each capable of processing 252,000 bone dry tons (bdt) per year. These mills crush the woodchip
feed to a particle size of 1/8 or less and are passed through a screen to ensure sufficient size
reduction. Oversize chips are deflected and recycled to the hammer mills to be reprocessed. The
crushed chips then are conveyed to one of six rotary drum dryers (H-101 through 106), each with
3,552 square feet of drying area. The woodchips are dried to a moisture content of 15%. After
each dryer, the material is conveyed to carbon steel storage bins (M-102 through 107), which
each have the capacity to hold approximately a half-day supply of dried feedstock material. From
these bins, the woodchip feed is conveyed to the lockhopper system (X-104 through 111) for
pressurization and introduction to the gasification units. Each lockhopper can handle up to 15
tons per hour, for a capacity of 30 tons per hour per gasifier.
49
Block 200 - Gasification

Gasification and Raw Synthesis Gas Production
The dried woodchips are split between four gasification units (R-201, 202, 203 and 204,
see page 22 for the Block 200 process flow diagram), which are operated at a pressure of 465
psia and 1700F. Each gasifier is comprised of a refractory-lined bed section, a cyclone
separation unit for recycle of ash and char particulates, and a char combustor to burn solid
carbon dropout. The four gasifiers combined are additionally fed with 56,667 lb/hr of 95%
oxygen at 465 psia and 180F, supplied by an air separation unit. The air inlet to the air
separation unit is compressed from atmospheric conditions to 85 psia via a multi-stage
compressor with intercooling, and similarly the oxygen product at the outlet of the air separation
unit is compressed from 85 psia to the required 465 psia for the gasifier feed. The waste nitrogen
effluent from the air separation unit is purged to the atmosphere (refer to page 55 for an
evaluation of alternative design considerations for the use of nitrogen gas). High-pressure steam
(1250 psi, 572F) is additionally fed to the gasification units at a rate of 46,840 lb/hr as reactant.
Some of the thermal energy requirement for the high operating temperature of 1700F is
provided directly by exothermic reactions in the gasification process (referred to as directlyheated gasification), but the residual heat duty of the primarily endothermic reactions must be
provided by burning fuel. A purge from the downstream DME reactor section is burned,
providing substantial heating value for this utility-intensive process and the remaining fuel
requirement must be made up by purchasing additional fuel. This excess heating requirement is
approximately 77 MMBtu/hr.
The primary characteristic of gasification is limiting the oxygen supply to render
incomplete combustion. Stoichiometric air, or the quantity of air required for complete
combustion, is approximately 4.58 pounds of air per pound of biomass (or similarly,
approximately 1.0 pound of oxygen per pound of biomass in this case of using pure oxygen
feed). This fraction of stoichiometric air required is referred to as an equivalence ratio, and
biomass gasification operations are optimally run in the range of 0.20 to 0.33 equivalence. At an
equivalence ratio of 0.25, one pound of dry biomass would be gasified with approximately 1.15
pounds of air (or 0.25 pounds of oxygen). The oxygen to biomass ratio of this operation is 0.271.
The quantity of oxygen introduced was a parameter manipulated to adjust the final synthesis gas
composition needed downstream for further reaction. The addition of an air separation unit for
50
generation of pure oxygen was chosen over a regular air feed to reduce the quantity of inert gases
flowing through the system downstream and eliminate the production of nitrogen oxides. At the
scale of this plant, the size increase of all equipment necessary to handle the extra 78% N 2
throughout the process would be a far greater expenditure than the air separation process.
Gasification occurs typically in the temperature range of 1112F to 2732F, where solid
fuel (woodchips in this instance) is heated to produce volatile compounds and solid residues like
ash and char. The generation of varying quantities of volatile matter and solid material depends
on reactor conditions, namely temperature. Pressure was not shown to have a significant impact
on the gasification process, and the operating pressure was chosen to eliminate the need for
greater compression of gases downstream. The higher temperature however, minimizes the
production of non-volatile solids like char. In this case, these char residues are separated via
cyclone and combusted to provide heat for the process. Gasification units of this type are often
fluidized bed units, with a solid particulate circulated such as alumina to aid heat transfer.
In the presence of limited oxygen, the primary reactions convert biomass to carbon
monoxide and carbon dioxide, with additional reactions producing small amounts of methane
and water vapor. The addition of high-pressure steam to the gasification reactors aids in the
conversion of char to volatile material and helps to adjust a favorable synthesis gas composition
as product. With the use of high temperature steam and oxygen in the gasification process, a
synthesis gas is generated as opposed to a producer gas (which is typically burned for fuel). The
important specification for this particular synthesis gas is the ratio of hydrogen to carbon
monoxide, which is significant for the further reaction to DME downstream. The approximate
H2/CO molar ratio of this synthesis gas product is 2:1. The primary reactions occurring within
the gasification units are shown below.
1.)C O2 CO2
2.)2 H 2 O2 2 H 2O
3.)C CO2 2CO
4.)C H 2O CO H 2
5.)CO H 2O CO H 2
6.)C 2 H 2 CH 4
7.)CO2 H 2 CO H 2O
Combustion:
1.) +393 MJ/kgmol
2.) -242 MJ/kgmol
Other reactions:
3.) -164.9 MJ/kgmol
4.) -122.6 MJ/kgmol
5.) +42 MJ/kgmol
6.) +75 MJ/kgmol
7.) -42.3 MJ/kgmol
51
The raw synthesis gas produced from the exit of the gasification units has an approximate
composition of 52% hydrogen, 22% CO2, 24% CO, and 2% methane and remaining inerts. The
flow rate of this gas product stream is 343,591 lb/hr and exits at gasifier pressure of 465 psia and
at a temperature of 1700F. To take advantage of the high temperature of this synthesis gas
stream, a series of shell and tube heat exchangers are used for a heat recovery steam generation
scheme. The synthesis gas passes through a superheater, an evaporator, and an economizer fed
with pressurized water to ultimately generate 120,000 lb/hr of high-pressure steam at 1800 psi
and 1400F. This superheated steam is subsequently sent to a steam turbine for electricity
generation. The electricity generated by this steam turbine is used to power the air compressor
feeding the air separation unit. The approximate power requirement is met by the 12,500 HP
output of the turbine. The steam effluent from the turbine exits at 854F and 299 psia and is
available to subsidize utilities elsewhere in the process.
After exchange with the high-pressure steam generation exchangers, the synthesis gas
exits at a reduced temperature of 747F and 429 psia. This gas is still at moderate temperature
and thus some remaining heat is exchanged in another evaporator and economizer to produce
65,000 lb/hr of low-pressure steam utility at a temperature of 393F and 229 psia. The synthesis
gas at this point is at a residual temperature of 342F and 429 psia. This stream is further heatintegrated to preheat the pressurized water feed to the low-pressure steam generation units in
another shell and tube exchanger, and exits the gasification section at a final temperature of
254F and 423 psia.
Process Design and Considerations
Detailed models for the gasification reactors and subsequent synthesis gas cleanup via
MEA absorption were generated using the Advanced Systems for Process Engineering (ASPEN)
chemical process simulator. While many prior studies have included ASPEN simulation of
combustion processes and even coal gasification, the wood biomass gasification process has
been little studied and infrequently modeled within ASPEN. The methodology used in this
design was based on equilibrium model design and experimental verification performed by
Paviet et al in 2009.
One design difficulty in generating a valid model for the wood gasification process
within ASPEN is the decision of how to treat solid components in a system that is largely
designed for handling liquid and gas phase processes. While the large majority of the process is
52
carried out in liquid and vapor phases (effectively all process units downstream of the four
gasifiers), accounting for an original solid feed is a significant factor. In this case, woodchips
were defined within ASPEN as a nonconventional component, using proximate, ultimate, and
sulfur analysis data coupled with ASPEN internal enthalpy model HCOALGEN and density
model DCOALIGT. This allowed for acceptable enthalpy and density calculations, but other
equilibrium and property calculations are not performed.
To model both the phase transition and all reactions taking place in the gasification units,
two separate blocks were used for the simulation. An RYIELD block was specified at the
operating temperature to convert the nonconventional solid feed stream to the elemental
composition of the woodchips in vapor phase. This effectively models the decomposition of
woodchips into volatile matter and char. This decomposition stream was then modeled as input
with the steam and oxygen inputs at the operating temperature and pressure of 1700F and 465
psia in an RGIBBS block. The results generated are assumed to be at chemical equilibrium and
constant temperature. Synthesis gas compositions from the gasification process can vary widely
by steam and oxygen inputs, temperature, pressure, and initial composition of the feedstock. Our
results were compared with several experimental results and deemed to be a reasonably valid
model of the gasification process in this particular application.
53
54
In further design of the gasification section, the waste nitrogen effluent from the air
separation unit was investigated for potential use. A design was developed for the integration of
a chilled water tower that cools water by mixing it with the dry nitrogen and taking advantage of
evaporative cooling. With a flow of ambient water at 90F introduced to the top of the tower and
passed through the dry nitrogen stream flowing upward through the column, chilled water could
be generated at 45F to subsidize process cooling needs downstream. The exit from the top of the
column would be humidified nitrogen that is purged to the atmosphere.
The performance of such a column was evaluated using ASPEN simulations, both at
atmospheric conditions and various vacuum pressures. While the atmospheric tower costs would
only include the vessel itself, operating at vacuum would require a multi-stage compressor of
substantial size to return the nitrogen effluent to atmospheric pressure and draw the vacuum.
Pressures in the range of 20 to 700 torr were explored for vacuum tower conditions and a
subsequent atmospheric analysis was performed. With decreasing pressure, the amount of chilled
water generation at 45F exit temperature increases exponentially (Figure 200.1).
Chilled Water Outlet Flow [lb/hr]
600000
500000
400000
300000
200000
100000
0
1
11
13
Column Pressure [psia]
Figure 9.1] Sensitivity Analysis of Column Pressure on Chilled Water Generation

Outlet Flow. At decreasing pressures, the amount of chilled water able to be generated
increases exponentially. It was found that the vacuum pressure operation was not
economically viable, and the atmospheric tower operation was impractical due to low flow
rates.
55
The question of economic validity was approached by comparing the utility costs of operating
the compressor versus the costs of purchasing the chilled water generated. In none of the vacuum
cases did the value of chilled water exceed the cost of electric utility for the necessary
compressor. Even without considering the capital expenditure of a sizable compressor (estimated
to be $11,200,000 at 50 torr and $7,600,000 at 100 torr), this was not economically viable. The
economic analysis results follow (Figure 200.2).
Pressure [torr] Pressure [psi]
HP req
kW req
Duty [btu/hr]
Intercooling [$/yr]
Electricity Cost [$/yr] Chilled Water Produced [lb/hr] Chilled Water Value [$/yr]
30
0.58
30301
22596
-6.6E+07
$155,714
$10,737,526
2,825,130
$4,195,318.50
50
0.97
19088
14234
-4.0E+07
$95,669
$6,763,789
1,323,187
$1,964,932.70
100
1.93
11740
8754
-2.3E+07
$55,022
$4,160,052
547,930
$813,676.05
200
3.87
6808
5077
-1.1E+07
$26,616
$2,412,598
231,564
$343,872.18
250
4.83
5388
4018
-7.7E+06
$18,230
$1,909,338
174,113
$258,557.50
500
9.67
1755
1309
0.0E+00
$0
$621,960
54,949
$81,600.00
Figure 9.2] Economic Analysis of Chilled Water Tower Vacuum Operation. It was
determined that no vacuum pressures provided economically viable results, thus eliminating
the design consideration of the use of nitrogen effluent for a chilled water tower. The utility
costs of operating the compressor necessary to draw vacuum superseded the purchase costs of
the original chilled water utility.
At atmospheric conditions, a range of flow rates was explored to determine the feasible
chilled water temperatures generated. It was found to be impractical to generate 45F chilled
water at atmospheric column conditions, so other temperature ranges were evaluated to
determine if any design would be valid for our process. It was shown that the cost of the tower,
even at atmospheric conditions, would not be economically justified over the life of the plant as
the flow rates of chilled water generated were too low. It was ultimately decided to simply purge
the waste nitrogen to the atmosphere and purchase the chilled water utility required.
56
54
Water Outlet Temp [deg F]
53
52
51
50
49
48
47
46
45
-5000
5000
15000
25000
35000
45000
55000
65000
75000
Water Inlet Flowrate at 90F [lb/hr], Atmospheric Conditions
Figure 9.3] Chilled Water Temperature at Varying Flow Rates for Atmospheric
Tower Operation. Atmospheric operation was also found to be impractical as the flow
rates of chilled water generated were too low for the plant requirements. Thus the nitrogen
effluent was chosen to be simply purged to the atmosphere.
57

The resulting synthesis gas has unfavorable levels of carbon dioxide, and thus enters a
stripping section before being sent onward to react in the DME section (see page 26 for the
Block 300 process flow diagram). The cooled gas stream enters the absorption tower where it is
passed against a flow of monoethanol amine (MEA) and water at a composition of
approximately 78% H2O and 22% MEA and a flow rate of 1,332,541 lb/hr in constant recycle.
Monoethanol amine is assumed available at $1,485/ton as per August 2010 price quotes. This
recycled MEA stream flows from a stripping tower downstream where the carbon dioxide is
removed in the column and the MEA solution is recovered. This recycle stream is cooled back
down to 100F before reintroduction to the column. The exchange is achieved with cooling water
at a rate of 7,669 gpm, entering at 90F and exiting at 120F. The operating conditions of the
tower are at 100F and 300 psi. The absorption column is a 4-stage tower with Koch-Glitsch BX
wire gauze packing, and results in an overhead stream of CO2-lean synthesis gas at a temperature
of 204F and 300 psi. This stream is cooled in a subsequent shell and tube heat exchanger to
125F and passed through a flash vessel to decant and recycle excess water from the passing
synthesis gas. The resultant stream is the final product from the gasification and gas-cleanup
segments of the process, at a flow of 199,575 lb/hr at 297 psi and a composition of
approximately 62% H2, 30% CO, 5% CO2, and 3 % CH4. This gas composition can be varied by
altering the flow rate of the MEA and water solution stream, with a higher flow rate removing
more CO2 and vice versa. The initial gas composition before introduction to the MEA absorption
section can be manipulated by flow rates of oxygen and high pressure steam. Due to water and
MEA inventory loss and side reactions, make-up streams must also be fed to the absorption
tower.
The bottoms product from the absorption tower is a CO2-rich carrier phase of MEA and
water that is sent to a stripping column to separate the CO2 and regenerate the absorbent. This
stream is throttled through a valve to decrease pressure because the stripping column is operated
at a lower pressure of 43 psi. Heat is then exchanged in a feed-product exchanger between this
stripper feed stream and the higher temperature stripper bottoms. CO2 is removed in the stripping
column, an 8-stage tower with similar Koch-Glitsch BX wire gauze packing. The exiting
overhead from this column is 200,000 lb/hr of 48% water vapor and 52% carbon dioxide. This
stream is further sent to a heat exchanger for cooling with cooling water to a temperature of
58
120F. This water vapor and carbon dioxide then enters a flash vessel to decant and recycle
excess water and purge CO2. This carbon dioxide stream is approximately 96% CO2 and 4% H2O
at a flow rate of 145,878 lb/hr. It is assumed to be sold at a price of $50/ton based on a figure
from Universal Industrial Gases for beverage-grade CO2. The decanted water is sent back to a
mixer with the stripper bottoms exiting the feed-product exchanger and this full stream is sent
back to a pump for re-pressurization and eventual recycle to the cooling exchanger upstream for
reintroduction to the absorption tower. This stream is brought from 39 psi back to 300 psi by a
centrifugal pump upstream of the exchanger unit.
The carbon dioxide MEA absorption section design was based upon previous design
work completed by Professor Leonard Fabiano for a client in 2007. The project was scaled and
adapted to fit our capacity and purity requirements. While it is possible to purchase package units
for MEA absorption, it was desired to have more accurate gas composition simulation results and
equipment sizing capabilities to integrate with the rest of our process design. The model was
evaluated using the ELECNTRL property set to properly describe the molecular interactions
occurring in the absorption process. The monoethanol amine recycle system was modeled with a
transfer block and subsequently iterated to convergence. The ASPEN flow diagram is shown
below.
59
60

The purified synthesis gas, S-401, and enters the process block (see page 30 for the Block
400 process flow diagram) along with the recycle of un-reacted syngas, FROM-REC. The unreacted syngas is pressurized by C-401 and then mixed with the fresh syngas. This mixture is
preheated in a heat exchanger, H-401, by the reactor effluent, and then flows into a microchannel
reactor, R-401, where the syngas is reacted to form mainly DME, but also methanol, water, and
carbon dioxide. Microchannel reactors, although not currently commercially available, allow for
a higher surface area to volume ratio, higher conversion, better product selectivity, and longer
catalyst life relative to standard fixed bed or slurry reactors. For this particular application, the
reactions are so highly exothermic that DME is usually formed in a slurry reactor using water as
the carrier phase to remove excess heat. However, the excess water hinders the mass transfer of
the syngas within the reactor and also allows for significant back-mixing, both of which
contribute to higher carbon dioxide selectivity and lower syngas conversion. A microchannel
reactor, due to the larger surface area to volume ratio, allows the reactions to take place in the
gas phase in reaction channels. This leads to faster mass transfer that increases conversion and
also allows for higher linear velocity within the microchannel reactor as compared to a slurry
61
reactor. This higher velocity aids in the clearing of catalyst sites, which leads to longer catalyst
life and even higher conversion. Furthermore, with the reactions taking place in the gas phase in
reaction channels, these channels are cooled by water flowing through adjacent coolant channels.
This water is vaporized and converted into high-pressure steam for use elsewhere in the plant.
The results from a study performed by Air Products using a slurry reactor were compared with
the results of a microchannel reactor. It was found that the syngas conversion in the
microchannel reactor was more than twice that of the slurry reactor, and the selectivity to carbon
dioxide, an undesirable byproduct, was less than half that of the slurry reactor. Therefore, the
microchannel reactor was selected to increase DME production, reduce the size of the recycle
stream, increase catalyst life, and to produce high-pressure steam.
The reactor effluent consists of DME, methanol, water, carbon dioxide, and un-reacted
syngas. Both DME and methanol are desired products that need to be sent into the next reactor
section, Block 600, to form propylene. The carbon dioxide needs to be separated and removed
from the system. The syngas and water need to be removed from the product stream and
recycled. The separation begins by cooling the reactor effluent, S-405, with a heat exchanger, H401, which transfers heat to the reactor inlet stream, S-404. The product stream then flows
through another heat exchanger, H-402, where it is further cooled by cooling water to a
temperature at which the majority of the water and methanol condense. This cooled stream is
sent out of this block section and into the next section as stream TO-SEP for separation of the
DME and methanol products.
62

The cooled reactor effluent enters this separation block (see page 32 for the Block 500
process flow diagram) as stream FROM-REAC. This stream is then fed into a flash vessel, V501, which separates the liquid water and methanol from the gas stream of DME and un-reacted
syngas. This is done because the most difficult part of the separation is separating carbon dioxide
from DME, and in the presence of methanol the separation is significantly more difficult. For
example, in one particular research system with water, methanol, DME, and carbon dioxide the
separation coefficient was 1.5, but when the methanol was removed the separation coefficient
increased to 35. Likewise, in the original setup of this simulation the entire reactor effluent was
sent directly to distillation chain and with methanol present it was nearly impossible to remove
enough carbon dioxide from the DME stream to obtain a sufficiently pure final product. When
methanol was removed prior to the carbon dioxide separation, DME with a purity of 99.9% was
easily achievable.
The vapor stream from the top of the flash vessel is sent into a packed absorption tower,
T-501, where water is used to absorb most of the DME and any remaining methanol in the vapor
stream. Unfortunately, some of the carbon dioxide and methane are also absorbed and need to be
removed by distillation. Nevertheless, the majority of the carbon dioxide, methane, and unreacted syngas come out of the top of the column as vapor in S-502. A small portion of the
overhead stream is purged from the system and the remaining vapor, TO-REC, is sent back to
Block 400 to be compressed, mixed with fresh syngas, and sent back into the microchannel
reactor. The purge stream, PURGE, comprised mainly of hydrogen, has a high heating value, and
is therefore sent back to Block 200 for use as a fuel to heat the gasifiers.
The bottoms stream from the absorption tower (mostly water), is pumped out by P-502
and needs to be distilled in order to separate and purify the DME. However, the methanol from
the bottom of the previous flash vessel also needs to be recovered. Since most of the carbon
dioxide has now been removed from the product stream, the methanol can be safely reintroduced
into it. Therefore, the bottoms of the flash vessel, S-503, is pumped out of the vessel by P-501
and mixed with the bottoms of the absorption tower, S-504. This goes through a pump, P-503, to
pressurize the stream prior to sending it into the distillation column, D-501.
Initially, instead of having only one distillation column, there was a series of three
distillation columns. The first removed methane and carbon dioxide as a vapor distillate and the
63
bottoms was comprised of DME, methanol, and water. The bottoms then entered a second
column that removed pure DME off the top and methanol and water came out the bottom.
Finally, the methanol and water were separated. This separation chain produced pure DME, pure
methanol, and pure water. However, there were several issues with this setup. First, the
separation between carbon dioxide and DME in the first column was difficult, so approximately
twenty percent of the total DME was lost in the overhead of that column. Furthermore, since the
methanol, DME, and part of the water stream need to be mixed back together prior to entering
the propylene reactor in the next block section, it was impractical to use two columns to split
these components into pure species. Yet, there was too much water in the bottoms stream to send
all of it into the propylene reactor, so some additional separation of the bottoms stream was
required.
Therefore, instead of using a separate column to separate DME from the methanol and
water, DME was taken off as a side-draw from the first distillation column. This left the carbon
dioxide and methane as the overhead, but DME and some methanol as a side draw-off, and water
and methanol came off the bottom. The water and methanol were, as before, sent into another
distillation column for purification. The side-draw led to a lower loss of DME in the overhead:
only ten percent versus twenty percent with the initial setup. This also eliminated one of the
unnecessary columns, but it was still a waste of capital and energy to completely separate the
methanol and water in the second distillation column. Thus, the side-draw flow rate, distillate
rate, reflux ratio, side-draw stage, and feed stage were all adjusted on the first column such that
all of the DME, all of the methanol, and some water came out in the side stream. By doing this,
the second distillation tower was eliminated and energy was saved by keeping the DME,
methanol, and water as a mixed stream rather than splitting them into pure components.
Furthermore, the amount of DME lost in the column overhead was reduced to only five percent.
In this final separation setup, only one distillation column with a side-draw is required.
The overhead of the distillation column comes off as a vapor stream of carbon dioxide, methane,
and DME. The overhead is cooled by H-501. The overhead is then flashed in the reflux drum, V502. The condensate, mostly DME, is refluxed to the column by the reflux pump, P-504, and the
remainder, S-507, exits the system as a vapor distillate. This stream contains significant amounts
of methane and DME, so it is sent back to Block 200 to be used as a fuel stream to heat the
gasifiers.
64
The main product stream, PRODUCT, comes off as a side-draw from the column. This
stream contains almost all of the DME and methanol, and as well as some water and is sent to a
pressurized storage vessel that can hold a one-day supply of the product stream. This tank feeds
DME into Block 600. The bottoms of the column, S-508, is a high-temperature, nearly pure
water stream that is drawn off by P-505. A portion of the water, S-509, is sent to the reactor in
Block 600 to achieve the required percentage of water for the propylene reactor. Another portion
of the water, S-510, goes to Block 700 for use as a hot water stream. In the original flow sheet,
both the extra water for the propylene reactor, S-509, and the hot water product stream, S-510,
were either recycled to the absorption column as needed, or disposed of as waste. However, to do
this, the streams first needed to be cooled to a lower temperature. The additional water needed in
Block 600 was instead a recycle of process water from Block 800. This water from Block 800 is
140F degrees colder than the distillation bottoms water, and the water needs to be heated prior
to entering the propylene reactor. Therefore, with this initial setup, the higher temperature water
from D-501 was being cooled for recycle, and the cooler water from Block 800 was being heated
to be sent into the reactor. This was an inefficient use of utilities which was remedied by sending
the hot water directly into Block 600, and then taking the cooler wastewater from Block 800, and
cooling that to be used as the absorption recycle.
The bottoms water from the distillation tower that is not required by Block 600 is passed
into a flash vessel, V-503, which flashes some of the hot water to low-pressure steam, STEAM,
which is sent off to be used elsewhere in the plant. The liquid water in the vessel is drawn off by
P-506. This water is mixed with the water stream from Block 800, FROM-800, and cooled with
cooling water in H-503. The hot water needs to be cooled for two reasons. First, some of this
cooled water, WASTE, is sent to an aerated lagoon as wastewater for treatment by microbes. If
the water is not cooled first, the extreme temperature would kill the bacteria in the lagoon. The
second reason is that the rest of the water is recycled to the absorption tower, and the lower
temperature is required to achieve the desired equilibrium within the tower. Prior to entering the
tower, this water recycle stream is pressurized by P-507.
65

Summary
The DME/methanol intermediaries (S-601) enter the block (see page 34 for the Block
600 process flow diagram) and are pressurized (P-602) in order to overcome the pressure drops
through the subsequent fixed bed reactors and heat exchangers. The intermediaries are heated
(H-608) to the reactor entrance temperature using the reactor effluent (S-625). The DME feed is
separated into four feed streams (S-610, S-614, S-618, and S-622) in order to minimize reactant
partial pressure in each reactor (which increases propylene selectivity) and reduce the exothermic
heat of reaction. More DME is sent to the later reactors as there is more product to absorb the
heat produced. The first DME feed stream is diluted with steam (S-606), which also serves to
absorb the heat of reaction. The steam is generated from the hot distillation bottoms stream (S509) from the DME recovery column. The water is sent through three sequential exchangers (H601, H-602, and H-603) in order to heat, vaporize, and superheat the steam to the reactor
temperature. The DME/steam mixture enters the first of four adiabatic, fixed-bed reactors (R601). In the reactor, the DME is converted to ethylene, propylene, and several other byproduct
66
species. The temperature increase of the stream across the reactor (S-612) is used to produce
high-pressure steam in a heat exchanger (H-604) before being mixed with another portion of the
DME feed (S-614) and fed to the second reactor (R-602). The outlet stream (S-616) is cooled
(H-605), mixed with another reactant stream (S-618), and fed to the third reactor (R-603). The
outlet (S-620) is also cooled (H-606), mixed with the final DME stream (S-622), and fed to the
final reactor (S-624). By the end of the reactor series, all of the DME and methanol has been
converted. The reactor effluent is cooled (H-607) and fed to the preheating exchanger (H-608).
Reactor Design
The reactors were designed in order to provide 100% DME/methanol conversion.
Operating at smaller conversions has the benefit of decreased reactor size and the presence of
additional recycled feed to absorb the heat produced, but requires an additional DME separation
column in order to separate and recycle the unreacted feed. As seen in the previous block, these
columns require significant volumes of water to recover the DME and subsequent distillation
sections to remove the DME from the water. Any DME that is not recovered also ends up in the
final ethylene/propylene separation, reducing the grades of one or both feeds. Since 100%
conversion was tested and found feasible at long run times, the high conversion was pursued.
Additionally, further optimization of the reactor conversion and propylene product selectivity
could be done by making slight variations in the catalyst across each sequential reactor. Finally,
if it were desired to increase the propylene production beyond the conversion ratio specified in
this problem, there has been some success recycling ethylene back through the reactor. This
could be done to produce a more favorable propylene/ethylene production ratio, but was avoided
in this application to decrease the required equipment sizes. An economic analysis of the
propylene to ethylene ratio is presented on page 257.
In order to determine the number and size of the reactors, the temperature increase across
each reactor was kept to 200F to stay in the range of optimal propylene selectivity, overall
conversion, and minimal catalyst degradation. The reactants were portioned between the reactors
such that the adiabatic increase across the reactor did not cross this threshold. Intercooling was
used to remove heat between the reactors and generate steam usable in other parts of the plant.
Ultimately, it was determined that four reactors would be needed. The size of the reactors was
then estimated using the WHSV and catalyst density.
67
Catalyst Regeneration
The modified H-ZSM-5 undergoes two types of catalyst degradation during operation.
First, carbonaceous material deposits onto the catalyst during operation, covering pore surfaces
and decreasing the number of active sites. This degradation can be avoided by operating at
higher temperatures or increasing the amount of steam diluent.
The catalyst can later be
regenerated by burning the deposits in air. However, the second type of degradation, resulting
from hydrothermal damage, cannot be regenerated. Therefore, it is important to balance the
amount of steam added, the temperatures of operation, and the propylene production with the
frequency and type of catalyst degeneration.
For the purposes of this reactor section,
regeneration times were based on the experiments that achieved 100% methanol conversion for
cumulative operation times of greater than 600 hours. The reactor is kept on line for greater than
24 hours, until the conversion dips below 99%. Then, the feed is switched to another reactor and
nitrogen is used to flush out remaining the hydrocarbon feed. Finally, air is introduced to the
reactor to remove carbonaceous deposits. The total regeneration time is approximately 6 hours.
The costs for duplicate reactors and catalyst were included in the overall economic analysis, but,
if the same catalyst was used in each reactor, the reactors are similarly designed such that a
smaller number of spares could be utilized. During operation, when both reactors were online,
the feed could also be routed through both sets of reactors for ease of transition and control.
Since other experimenters were successful after long periods of operation using higher
temperatures and larger amounts of steam, it is assumed that the costs of replacing damaged
catalyst will be minimal relative to other expenditures.
Process Modeling
The reactions taking place within the reactor are complicated and not well known. Some
kinetic models exist for the methanol-to-olefin process, but these are extremely complicated and
do not lend themselves for use in a preliminary design. Another difficulty is that the majority of
papers regarding the DME-to-olefin process only show the mole fractions of hydrocarbon or
olefin products. Oxygenate products are present in smaller quantities and are important for the
development of an overall design. Fortunately, one patent giving a distribution of all reaction
products and byproducts was found. This product distribution, along with the RGIBBS model in
ASPEN, could be used to make reasonable predictions about the reactor outlet composition.
68
Then, an RSTOIC block was used to adjust the compositions of the primary components to be in
line with those expected based on other experimenters research.
69

Summary
The undesired heavy byproducts (S-1005) enter the block (see page 38 for the Block 700
flow diagram) and are mixed with hot water from the DME separation column (S-510). The
resulting stream (S-703) is then vaporized in an exchanger (H-701). The vapor (S-704) is
exchanged (H-702) with the reactor effluent (S-713) but, due to the endothermic nature of the
reaction, a fired heater (V-701) is required to reach the reactor inlet temperature. The heated
feed (S-706) is then separated into thirds to reduce reactor size and sent to three identical reactors
(R-701, R-702, R-703).
The reactor effluents are recombined (S-713), passed through the
preheat exchanger, and exit the block (S-714).

Reactor Design
Several novel methods of steam cracking and its integration with the DME-to-olefin
process have been proposed, but were not considered for this design. The exothermic nature of
the main reaction lends itself to integration with this endothermic block. Reactors have been
designed where the two beds are held within the same reactor in order to directly transfer heat.
Additionally, some have proposed placement of the steam cracking reactor before the DME to
olefin reactor, or even with the catalyst intermixed within the DME to olefin reactor. For this
design, it was assumed that better catalyst selection for optimal propylene selectivity would be
enabled by the separation of the reactors. It was also assumed that combining the reactors would
result in larger bed size and the resulting pressure drops would require reactor pressures beyond
the preferable range for the desired reactions. Finally, descriptive product distributions were
known for the reactors in separate, but not for the combined configuration.
Catalyst Regeneration
Degeneration of the steam cracking catalyst did not seem to be as big of design
consideration as the degeneration of the olefin producing catalyst. However, it was assumed that
carbonaceous deposits would occur, and therefore duplicate reactors would be necessary for
continuous operation. A similar regeneration method would be used, where a nitrogen flush
followed by an air burn would remove the deposits.
70
Process Modeling
Because of the variety of byproducts fed to the steam cracking reactor, an experimental
trial was not available with the same distribution of reactants. Instead, another RGIBBS block
was used. The outlet from the RGIBBS block was compared to similar experimental trials, and
the relative proportions and conversions of the products appeared to correspond.
71

Summary
In order to minimize the number of pieces of equipment required, the block outlet from
the DME reactor section (S-626, see page 40 for the Block 800 flow diagram) is combined with
the reactor outlet from the steam cracking section (S-714). The combined stream (S-801) is
cooled by vaporizing low-pressure boiler feed water (H-801) and further cooled using cooling
water (H-802). The water that condensed out during this process is removed using a horizontal
flash vessel (V-801). The vapor leaving the flash vessel (S-804) is low-pressure and must be
pressurized in a compressor (C-801) to provide motive force. The liquid stream (S-806) is
simultaneously pressurized using a pump (P-801). The combined streams (S-808) are then fed to
a distillation column (D-801). Nearly-pure water is removed from the bottom of the column (S810) before being pumped (P-803) to the waste water section (S-811). The olefin products and
organic byproducts are taken as vapor distillation from the top of the column (S-809).
Other Considerations
The great difference in volatilities between the water and desired olefins would lend itself
towards the use of a flash vessel for separation. However, due to the large amount of steam used
as a diluent and generated during the reaction, even a small fraction of olefins in the condensed
phase results in significant product losses and decreased overall yield. The aqueous phase would
have to be treated for wastewater anyway, so the column reduces the amount of water treatment
required. The reflux ratio and boilup ratio of the column were adjusted to minimize the amount
of water passed on through the compression section, minimize the amount of hydrocarbons lost
in the bottoms, keep the condenser temperature in the cooling water range, and minimize the
reboiler duty.
72

Summary
The olefin stream (S-809, see page 42 for the Block 900 process flow diagram) is
compressed (C-901) with a compression ratio of approximately 3. The resulting stream (S-901)
is cooled using cooling water (H-901) and fed to a flash vessel (V-901). The vapor (S-903) is
fed to another compressor (C-902) and cooled again (H-902), while the liquid (S-904) is pumped
to the outlet pressure (P-901). The outlet from second exchanger (S-907) is fed to another flash
drum (V-902), where the liquid is removed (S-909) and pumped to the outlet pressure. The
vapor (S-908) is fed to the final compressor (C-903), cooled with cooling water (H-903), and
finally condensed using refrigerated propylene (H-904). The liquid is then pumped (P-903) to
the distillation pressure. All three pressurized liquid streams are mixed (S-915) and sent to the
distillation block.
Another design was tested where the intermediate streams were not condensed, but only
cooled to 10F of superheat and fed to the next compressor. The benefit of this design was that
the temperature required to condense the final vapor was achievable using cooling water.
However, the increased flow rates through the second and third compressor required
significantly more capacity and electricity than the corresponding increase in flow rates in the
propylene refrigeration cycle.
73

Summary
The pressurized olefins (S-915, see page 44 for the Block 1000 process flow diagram) are
heated (H-1001) using the distillation bottoms stream (S-1005). Propylene and ethylene are
removed from the top of the column (S-1002), while the heavier byproducts are separated off of
the bottom (S-1004).
The bottoms stream is depressurized in order to provide a more
economical temperature driving force across the exchanger.
The light olefin distillate is
pressurized further (P-1003) and sent to next distillation tower (D-1002).
Chemical-grade
ethylene is recovered from the top of the column (S-1007) before being pumped (P-1005) off to
the shift tank. Polymer-grade propylene (S-1009) is drawn from the bottom of the column and
pumped (P-1007) to its corresponding shift tank and storage.
In another design, the second column was eliminated and propylene was taken off as a
side stream. However, the purity of the propylene recovered was substantially decreased. The
increase in price for higher grade propylene was worth the cost of operation of a second
distillation column.
Both distillation columns were designed at as high of pressure as possible, without
approaching the critical pressure of the components and subsequently increasing column
diameter. The bottoms of the first product separation column reached pressures of 530 psia,
which nears butanes critical pressure of 550 psia and surpasses isobutanes critical pressure of
520 psia. The second columns reboiler operates at 650 psia, which is near propylenes critical
pressure of 667 psia. These pressures minimize the amount of refrigeration at the top of the
columns.
To estimate the capital and operating costs of refrigeration, a simple vapor-compression
propylene refrigeration cycle was modeled. The vaporizer pressure was set by the refrigeration
temperature, while the condenser temperature was set to use cooling water as its cooling source.
The flowrate of propylene was then set based on the amount of cooling duty required.
74
EQUIPMENT LIST &

UNIT DESCRIPTIONS
75
10.
Equipment List and Unit Descriptions

Note: Solids handling equipment layout is based upon available equipment pricing and
capacity data for constructed plants and is thus representative in nature. This layout is subject
to change in practice depending on availability of equipment, size limitations, batch versus
continuous processing, and other parameters beyond the scope of this preliminary design.
M-101: Long Term Storage
Covered storage for long-term holding of delivered feedstock. Steel building construction
cost estimated with figures from Green Diamond Building Systems of $5.92/sqft. With a feed
rate of 208,769 lb/hr at an assumed wood chip bulk density of 500kg/m3 (31.2 lb/ft3), a building
of about 4.9 million cubic feet is required to hold a 30-day feed supply. 25% extra volume added
for free air space and equipment maneuvering. Assuming a ceiling height of 30, this building is
estimated to cost approximately $1,208,373 at a size of 204,117 sqft.
X-101, 102, 103: Hammer Mills
Hammer mills and screens for feedstock processing in preparation for drying and
subsequent feed to gasification units. Wood chips processed to minimum size of 1/8. Cost
estimate based on 1992 TECOGEN plant capital expenditures data. Requiring three hammer
mills and screens at a capacity of 252,400 bdt/yr to meet feed rate specifications, the estimated
cost is $2,635,975. Cost estimate includes mechanical and electrical installation. Electricity
requirements are estimated assuming a 75 HP power requirement for each mill (based on a 300
tph unit operating at 400 HP, 730 rpm: approximately 3 times this operating capacity
specification). This assumed total power requirement of 225 HP for the entire milling operation
results in projected electricity usage of 1,330,560 kWh/yr at an estimated cost of $79,834/yr. See
page 274 of the Appendix for costing calculations.
H-101, 102, 103, 104, 105, 106: Feedstock Dryers
Feedstock dryers for reducing wood chip moisture from an estimated 50% upon delivery
to 15% for input to the gasifiers. Cost estimate based on drying area figures from 1992
76
TECOGEN plant capital expenditures data and assuming direct-heat, rotary carbon steel dryers.
The feed rate requires six drying units, with an inner diameter of 14.8 ft and a length of 120 feet.
Each unit has the capacity to process 252,000 bdt/yr with 3552 sqft of drying area. The total
F.O.B. cost is estimated to be $3,732,960. Each dryer will have an approximate power
requirement to turn the drum at typical speed (~4 rpm) of about 200 HP. For all 6 dryers, this
yields an estimated electricity requirement of 3,540,240 kWh/yr at a projected cost of
$212,414/yr. See page 275 of the Appendix for costing calculations.
M-102, 103, 104, 105, 106, 107: Dried Feedstock Short-term Storage
Storage bins for an approximate volume of day of feedstock material holding per dryer.
Each storage vessel is of carbon steel construction and at atmospheric pressure, fed by a
conveyor carrying dried material from each dryer. These storage bins are upstream of the
lockhoppers and material is fed to the lockhoppers from this short-term storage to keep feed to
the gasifiers constant. With a total inlet feed to the gasifiers of 208,769 lb/hr feedstock at 15%
moisture, the approximate volume of each storage bin is 92,340 cubic feet. The estimated cost of
each bin is $109,636; with a requirement of 6 bins the total purchase cost of this short-term
storage is $657,816. For all 6 storage bins, the bare module cost is estimated at $2,111,589. See
page 276 of the Appendix for costing calculations.
X-104, 105, 106, 107, 108, 109, 110, 111: Lockhopper Feed Systems
Double lockhopper systems with metering bin rated for a capacity of 15 tons per hour
feed rate. With a feed rate of 208,769 lb/hr dried feed at 15% moisture (an additional 31,315
lb/hr water), the total mass of material passing through the lockhopper setup is 240,084 lb/hr
(approximately 120 short tons per hour). At this capacity, each of the four gasifiers requires 2
double lockhopper systems at 15 short tons per hour each. Using a cost estimate from TR Miles
Technical Consultants, Inc., the total cost of the 8 lockhopper systems is $21,028,255. This
estimate includes all fabricated equipment, equipment supports and foundations, mechanical
installation, electrical controls, spare parts, freight, mechanical and electrical engineering costs,
and a 25% contingency and allowance for miscellaneous expenditures. Schematic attached. The
power requirement of each double lockhopper as estimated by TR Miles is approximately 320
77
HP. This results in a total electricity requirement of approximately 5,670,720 kWh/yr at a

projected cost of $340,243/yr. See page 275 of the Appendix for costing calculations.
Miscellaneous Material Transfer Logistics Equipment
Receiving biomass feedstock from delivery trucks and transferring material between units
requires extra equipment. An estimate for these costs was derived from the analysis of a
Weyerhauser biomass gasification system at their pulp mill in New Bern, North Carolina. The
capital cost estimate included a truck scale (fully electronic, with desktop indicator, ticket
printer, lightning protection, side rails, truck scale management system, and traffic light signals),
hydraulic truck dumpers rated for 35 ton maximum gross weight tractor-trailer trucks and for
seven dumping cycles per hour, above ground 6,900 cubic ft receiving hoppers, 160 tph capacity
belt-type unloading conveyor, transfer chute to a process building feed conveyor (covered,
trough-type belt conveyor rated for 160 tph, including 30 HP motor, with conveying distance of
250 horizontal feet and 45 vertical feet, furnished with steel stringers and support trestles from
foundations at grade, and transfer chute to a reversing conveyor), a reversing trough-type belt
conveyor with magnetic metal detector (rated for 160 tph, including 20 HP motor, furnished with
rejects chute and transfer chute to scalping screen), scalping screen rated for 160 tph designed to
pass all material smaller than 29mm, furnished with a 15HP motor and discharge chute for all
oversized material, two wet fuel storage pile feed conveyors (covered, trough-type belt
conveyors; one rated for 160 tph including 30 HP motor with conveying distance of 250
horizontal feet and 45 vertical feet, and the other rated for 50 tph and including a 25 HP motor,
conveying material a distance of 750 horizontal feet and 50 vertical feet both including transfer
chutes), and several other ancillary conveyor systems for fuel reclaim, stacking, and dryer
conveyance. Estimate also included hammer mills rated at 16 tph and a dryer feed surge hopper
(both of which were estimated separately from this analysis; refer to blocks X-101 to 103 and M101 to 107), and were not subtracted individually from this cost estimate to allow for
contingency. The Weyerhauser plant processed a capacity of 73.2 tons per hour of 50% moisture
feed, and consumed 604 kW of electricity. Adjusting for capacity differences, the estimated
capital cost for this application, including labor, is projected to be $8,492,549. Electricity
requirements are estimated to be 955 kW (7,563,600 kWh/yr) at a cost of $453,816/yr.
78
79
Block 200 - Gasification

C-201: Air Compressor for Air Separation Unit
3-stage air compressor with intercoolers for pressuring air inlet feed (S-201) to Air
Separation Unit from atmospheric conditions (14.7 psia) to 85 psia. The outlet temperature from
each intercooler is specified at 180F for safety reasons, requiring a total cooling duty of
24,172,500 Btu/hr. To achieve this cooling rate, a total flow of cooling water required for the air
compressor system is 96,960 gallons per hour. The cost of this cooling on a yearly basis is
estimated to be $57,434/yr. The air flow rate through the compressor is 283,335 lb/hr, assuming
a composition of 0.78084 Ns, 0.209476 O2, 0.00934 Ar, and 0.000314 CO2 by mole fraction. The
horsepower requirement of the compression system is 12,257 HP at an estimated total bare
module cost of $7,854,128. This power requirement will be supplied by a gas turbine
downstream. See page 125 for the specification sheet and page 283 for sample design and
costing calculations.
C-202: Oxygen Compressor, Post-ASU
3-stage compressor for bringing oxygen stream from air separation unit outlet (S-204)
from 85 psia to 450 psia for introduction to the gasification units. The outlet temperature from
each intercooler is specified at 180F for similar safety concerns, requiring a total cooling duty of
9,877,183 Btu/hr. To achieve this cooling rate, a total flow of cooling water required for the
oxygen compressor system is 39,540 gallons per hour. The cost of this cooling on a yearly basis
is estimated to be $23,487/yr. The oxygen flow rate through the compressor is 56,667 lb/hr,
assuming a stream from the ASU of approximately 92.0% oxygen, 6.5% argon, and 1.5%
nitrogen by mole percent. The horsepower requirement of the compression system is 4,374 HP.
The estimated purchase cost of the unit is $1,601,973, at a total bare module cost of $3,444,242.
The electricity requirements for this compressor are estimated to be 258,350,040 kWh/yr at a
projected cost of $1,550,102. See page 126 for the specification sheet and page 283 for sample
design and costing calculations.
80
C-203: Steam Turbine for Electricity Generation

Steam turbine for generating electricity from high pressure steam leaving the heat
recovery steam generation section. Inlet to the turbine (S-225) is high pressure steam at 1400F
and 1798 psia, at a flow rate of 120,000 lb/hr. The turbine is specified to produce 12,500 HP
(9321 kW) to supply sufficient power for the air compressor required upstream of the air
separation unit (X-201). Outlet from the turbine is steam at 854F and 299 psia. The turbine cost
estimate was developed using costing data obtained from NREL concerning a back-pressure
steam turbine installed in a paper mill with an inlet flow rate of 126,000 lb/hr. The equipment
cost for the paper mill unit was $225/kW, at a $385/kW total installed cost in 2003. For our
required power output, and adjusting for current dollars, the total equipment cost of this unit is
estimated to be $3,001,443. The total installed cost is estimated to be $5,136,009, yielding a bare
module factor of approximately 1.71. See page 127 for the specification sheet.
X-201: Air Products, Inc. Air Separation Unit
Air separation package system from Air Products, Inc. Cost estimation is based on a 95%
oxygen stream flow rate requirement to the gasifiers of 56,667 lb/hr. The purity of the outlet to
the gasifiers from the air separation unit is assumed to be 0.95 O2, 0.01 N2, and 0.04 Ar by mole
fraction. The air requirement for the air separation unit was calculated assuming oxygen recovery
of 20%. The total air flow rate to this unit (S-202) from the multi-stage compressor is 283,335
lb/hr. The cost of this package unit is estimated to be $18,120,000, using figures provided by Mr.
Adam Brostow of Air Products, Inc. See page 274 for the sizing and costing calculations.
R-201, 202, 203, 204: Gasifiers
High pressure, directly-heated, fluidized-bed gasification units. Cost estimate based on
NREL figures from a 1990 unit fed with Wisconsin Maple wood chips operating at 1525F, 465
psia, and a feed rate of 843 tons per day. The units are comprised of the reactor bed section,
solids cyclone separation, and char combustor. Our biomass feed requirements of 2881 tons per
day necessitate approximately 4 of these units. These four units are operating at 450 psig and
1700F. The woodchips are fed at 15% moisture at a mass flow rate of 240,768 lb/hr using
double lockhopper systems (S-207). Additional feed to the four units is made up of 56,667 lb/hr
of 95% oxygen from the air separation unit (S-205) and 46,840 lb/hr of 1250 psi steam at 572F
81
(S-206). The total estimated cost of these four units is $92,773,533. Some of the thermal energy
requirement is provided by exothermic reactions in the gasification process, but the four units
have a total additional required heat duty of 464,329,820 Btu/hr. A large majority of this heating
requirement is being met by burning a downstream purge from the DME reactor section, which
has an estimated heating value of 387,557,579 Btu/hr. This puts the net heating requirement to
the gasifiers at 76,772,241 Btu/hr, which will be supplied via direct fired natural gas. Assuming a
cost of $4.00/MMBtu, the yearly gas requirements for the gasifiers comes to $2,432,145/yr. The
size of these units was based on information from an IGT 9 tpd unit as well as a larger-scale 91
tpd unit operating at the Hawaiian Commercial and Sugar Company sugermill in Paia, Maui, by
the Pacific International Center for High Technology Research. Each gasifier is comprised of a
bed diameter of 9 feet, 5 inches, and a vessel outside diameter of 14 feet, the remainder lined
with refractory brick. See page 168 for the specification sheet and page 277 for sample design
and costing calculations.
H-201: Heat Recovery Steam Generator Superheater
Shell and tube heat exchanger superheating steam fed from the HRSG evaporator. Inlet
feed to this exchanger (S-224) on the shell side is 120,000 lb/hr of steam at 620.7F and 1799.0
psia. The outlet from the superheater, which is fed to a gas turbine for electricity generation,
leaves at 1400.0F and 1797.9 psia (S-225). Heat is exchanged with the passing synthesis gas
stream exiting the gasifiers and entering the tube side at 1700.0F and 464.7 psia (S-208) and
leaving the exchanger at 1370.5F and 461.2 psia (S-209). The flow rate of the synthesis gas is
343,591 lb/hr. The total exchange area is 1699 sqft. The shell and tube exchanger has a 34.9 inch
outer diameter carbon steel shell and 1040 carbon steel tubes in a single pass. Tube outer
diameter is 0.75 inches with a tube pitch of 0.9375 inches. Tube length is 6 feet. The exchangers
consist of 6 baffles with a center-center spacing of 6.75 inches. The total purchase cost of the
exchanger is estimated to be $50,140 using Aspen Plus EDR package (similarly used for
exchanger geometry design). The total bare module cost of the unit is estimated to be $158,944.
See page 188 for the specification sheet.
82
H-202: HRSG Evaporator

Shell and tube heat exchanger evaporating high pressure water inlet fed from the HRSG
economizer. Inlet feed to this exchanger on the shell side (S-223) is 120,000 lb/hr of liquid water
at 600.0F and 1799.7 psia. The outlet from the evaporator is steam at 620.7F and 1799.0 psia
(S-224). Heat is exchanged with the passing synthesis gas stream, entering the tube side (S-209)
at 1370.5F and 461.2 psia and leaving at 924.7F and 457.6 psia (S-210). Flow rate of the gas
stream is 343,591 lb/hr. The total exchange area is 878 sqft. The shell and tube exchanger has a
31.875 inch outer diameter carbon steel shell and 885 carbon steel tubes in a single pass. Tube
outer diameter is 0.75 inches with a tube pitch of 0.9375 inches. Tube length is 5 feet. The
exchanger consists of 6 baffles with a center-center spacing of 6.25 inches. The total purchase
cost of the exchanger is estimated to be $43,809 using Aspen Plus EDR package (similarly used
for exchanger geometry design). The total bare module cost of the unit is estimated to be
$138,875. See page 189 for the specification sheet.
H-203: HRSG Economizer
Shell and tube heat exchanger heating high-pressure water inlet fed from the highpressure water from pump 201. Inlet feed to this exchanger on the shell side (S-222) is 120,000
lb/hr of water at 400.0F and 1800.0 psia. This stream is assumed available at this temperature
from steam condensate. The outlet from the economizer (S-223) is at 600.0F and 1799.7 psia.
Heat is exchanged with the passing synthesis gas stream, entering the tube side (S-210) at
924.7F and 432.6 psia and exiting at 747.4F and 429.1 psia (S-211). Flow rate of the gas
stream is 343,591 lb/hr. The exchanger area is 812 sqft. The shell and tube exchanger has a
30.875 inch outer diameter carbon steel shell and 846 carbon steel tubes in a single pass. Tube
outer diameter is 0.75 inches with a tube pitch of 0.9375 inches. Tube length is 5 feet. The
exchanger consists of 6 baffles with a center-center spacing of 6.0 inches. The total purchase cost
of the exchanger is estimated to be $41,706 using Aspen Plus EDR package (similarly used for
exchanger geometry design). The total bare module cost of the unit is estimated to be $132,208.
83
H-204: Low Pressure Steam Generation Evaporator

Shell and tube heat exchanger evaporating moderate pressure water fed from the low
pressure steam generation economizer. Inlet feed to this exchanger on the shell side is 65,000
lb/hr of water at 350.0F and 229.1 psia. The outlet from the evaporator is steam at 393.0F and
228.6 psia. Heat is exchanged with the passing synthesis gas stream, entering the tube side at
747.4F and 429.1 psia and exiting at 372F and 429 psia. Flow rate of the gas stream is 343,591
lb/hr. The exchange area of this single shell and tube exchanger is 2734 sqft, with an overall heat
transfer coefficient of 178.3 BTU/hr-sqftR. The geometry of the exchanger was not ascertained
due to non-convergence of an EDR solution. The total purchase cost was estimated using the
figures from the HRSG evaporator unit (H-201), yielding a figure of $50,140 and a total bare
module cost of $158,944. See page 191 for the specification sheet.
H-205: Low Pressure Steam Generation Economizer
Shell and tube heat exchanger heating moderate pressure water feed to low pressure
steam generation exchangers. Inlet feed to this exchanger on the shell side(S-218) is 65,000 lb/hr
of water at 280F and 230 psia. The outlet from the economizer (S-219) is liquid water at 350F
and 229 psia. Heat is exchanged with the passing synthesis gas stream, entering the tube side (S211) at 372F and 429 psi and leaving at 342F and 429 psia (S-212). Flow rate of the gas stream
is 343,591 lb/hr. The exchange area of this single shell and tube heat exchanger is 743 sqft. The
exchanger has a 27.75 inch outer diameter carbon steel shell and 680 carbon steel tubes in a
single pass. Tube outer diameter is 0.75 inches with a tube pitch of 0.9375 inches. Tube length is
6 feet. The exchanger contains 6 baffles with a center-center spacing of 8.0 inches. The total
purchase cost is estimated to be $48,137 using Aspen Plus EDR package (similarly used for
exchanger geometry design). The total bare module cost of this unit is estimated to be $152,594.
H-206: Low Pressure Steam Generation Feed Pre-heater
Shell and tube heat exchanger heating moderate pressure water fed from pump 202 for
low pressure steam generation. Inlet feed to this exchanger on the shell side (S-213) is 65,000
lb/hr of water at 78F and 230 psia. The outlet from the pre-heater (S-214) is liquid water at
280F and 230 psia. Heat is exchanged with the passing synthesis gas stream, entering the tube
84
side (S-216) at 342F and 426 psia and leaving at 254F and 423 psia (S-217). Flow rate of the
gas stream is 343,591 lb/hr. The exchange area of this single shell and tube heat exchanger is 743
sqft. The exchanger has a 27.75 inch outer diameter carbon steel shell and 680 carbon steel tubes
in a single pass. Tube outer diameter is 0.75 inches with a tube pitch of 0.9375 inches. Tube
length is 6 feet. The exchanger contains 6 baffles with a center-center spacing of 8.0 inches. The
total purchase cost is estimated to be $47,982 using Aspen Plus EDR package (similarly used for
exchanger geometry design). The total bare module cost of this unit is estimated to be $152,013.
P-201: Pre-HRSG Reciprocating Plunger Pump
Reciprocating plunger pump of ductile iron construction providing pressure increase for
water inlet to the heat recovery steam generation exchanger section. Reciprocating plunger pump
necessary over centrifugal design due to a head developed of greater than 3200 ft. Flow to the
pump is 120,000 lb/hr of water (S-220) at 400F assumed available from steam condensate, with
a pressure increase of 1785 psi. Power consumption of the electric motor is calculated to be
422.6 HP. The total pump cost including V-belt drive and electric motor is estimated to be
$160,656. The electricity requirements to run this pump are estimated to be 2,309,789 kWh/yr at
a projected cost of $138,587/yr. See page 142 for the specification sheet and page 279 of the
appendix for a sample sizing and costing calculation.
P-202: Low Pressure Steam Generation Feed Pump
Centrifugal pump of carbon steel construction providing pressure increase for water inlet
to the low pressure steam generation heat exchanger section. Flow to the pump (S-215) is 65,000
lb/hr of water at ambient temperature of 25C, with a pressure increase of 215 psi. Power
consumption of the electric motor is calculated to be 32.4 HP operating at 1800 rpm with a dripproof enclosure. The total pump cost including the motor is estimated to be $9,232. The
electricity requirements to run this pump are estimated to be 169,754 kWh/yr at a projected cost
of $10,185/yr. See page 143 for the specification sheet and page 280 of the appendix for a
sample sizing and costing calculation.
85
X-202: Synthesis Gas Clean-up: Alkali Deposition Ceramic Candle Filters

Alkali species present in the synthesis gas exiting the gasifiers can cause downstream
equipment issues related to corrosion and deposition and thus must be removed prior. Alkali
species present in biomass syngas have high condensation temperatures: most species will
condense out below 1000F as fine particles that can be removed with ceramic candle filtration.
Thus, the process includes ceramic candle filtration of stream S-210 (between H-202 and 203);
the positioning of the filters being selected by proper gas temperature. The gas stream entering
the filters is at a temperature of 925F and a pressure of 458 psia and leaves at 433 psia, allowing
for a pressure drop of 25 psia across the filters. Temperature losses due to filtration are assumed
to be negligible. Costs adapted from a 1993 EBASCO estimate for a ceramic candle filter vessel
and scaled accordingly using volumetric flow rates (in standard cubic feet per minute) for each
process. The cost of this filtration vessel is estimated to be $1,700,000. It is of note that the gas
clean-up only includes this filtration there is no tar cracker present downstream of the
gasification units. Testing at the IGT process development unit in Chicago on tar cracking and
particulate and alkali removal strategy for synthesis gases suggest that a tar cracker may not be
necessary in commercial designs operating at scale. The particulate filters tested at IGT also
showed no plugging issues due to tars, and were successful in reducing alkali particulates in the
synthesis gas to acceptable levels. With these results, it was assumed that ceramic candle
filtration of the synthesis gas stream at the proper location in the process was sufficient to clean
the gas for processing downstream. Gasification units also contain solids cyclones and
subsequent recycle to char combustors, thus also reducing particulates in the effluent synthesis
gas stream. See page 282 of the appendix for the costing calculations.

H-301: MEA Recycle Cooler
A shell and tube heat exchanger that cools the recycled monoethanol amine and water solution
returning from the stripping tower for reintroduction to the absorption column. Inlet feed to this
exchanger on the shell side (CW-301) is 3,843,024 lb/hr of cooling water entering at 90.0F and
leaving at 120.0F (CW-302). Pressure drop on the shell side is 7.18 psi. Heat is exchanged with
the passing MEA and water recycle stream (S-301), entering the tube side at 216.0F and 300.0
86
psia and leaving at 100.0F and 297.6 psia (S-302). Flow rate of the recycle stream is 1,332,519
lb/hr. This cooler unit is comprised of 5 shell and tube exchangers in parallel, twice in series
(total of 10 exchangers). The exchange area per unit is 1674.8 sqft, yielding a total effective area
of 16748 sqft. Each shell and tube exchanger has a 26.75 inch outer diameter carbon steel shell
and 543 carbon steel tubes in two passes. Tube outer diameter is 0.75 inches with a tube pitch of
0.9375 inches. Tube length is 16 feet and pressure drop on the tube side is 2.41 psi. The
exchangers consist of 6 baffles with a center-center spacing of 23.5 inches. The total purchase
cost of all ten exchangers is estimated to be $389,800 using Aspen Plus EDR package (similarly
used for exchanger geometry design). The total bare module cost of these three units is estimated
to be $1,235,666. See page 194 for the specification sheet and page 278 of the appendix for the
costing and sizing calculations.
H-302: Absorber Overhead Cooler
A shell and tube heat exchanger that cools the absorber overhead before passing through
a flash vessel to recycle excess water and onward to the DME section. Inlet feed to this
exchanger on the shell side (CW-303) is 499,992 lb/hr of cooling water entering at 90.0F and
64.7 psia and leaving at 123.0F and 62.9 psia (CW-304). Pressure drop on the shell side is 1.77
psi. Heat is exchanged with the passing absorber overhead stream (S-305) containing the CO2
lean synthesis gas entering the tube side at 204.1F and 300.0 psia and leaving at 125.0F and
296.8 psia (S-306). The cooler unit is comprised of a single shell and tube exchanger with a total
area of 1209 sqft. The exchanger has a 27.75 inch outer diameter carbon steel shell and 635
carbon steel tubes in a single pass. Tube outer diameter is 0.75 inches with a tube pitch of 0.9375
inches. Tube length is 10 feet and pressure drop on the tube side is 3.24 psi. The exchanger
consists of 4 baffles with a center-center spacing of 23.5 inches. The total purchase cost of the
unit is estimated to be $38,278 using Aspen Plus EDR package (similarly used for exchanger
geometry design). The total bare module cost of the exchanger is estimated to be $121,341. See
page 195 for the specification sheet.
H-303: Stripper Feed-Product Heat Exchanger
A shell and tube heat exchanger that exchanges heat between the feed and the bottoms
product from the stripping tower. Inlet feed to this exchanger on the shell side (S-310) is
87
1,476,502 lb/hr of CO2 rich MEA and water solution from the bottoms of the absorption tower,
entering at 193.7F and 85.0 psia and leaving at 242.7F and 80.2 psia (S-311). Pressure drop on
the shell side is 4.78 psi. Heat is exchanged with the passing stripper bottoms (S-312) entering
the tube side at 290.4F and 43.0 psia and leaving at 218.7F and 39.7 psia (S-313) at a mass
flow rate of 1,276,506 lb/hr. The feed-product unit is comprised of 4 shell and tube exchangers, 2
in parallel, twice in series, with a per-unit area of 2318.5 sqft. The total effective area of all units
in this exchanger system is 9274 sqft. Each exchanger has a 33.875 inch outer diameter carbon
steel shell and 864 carbon steel tubes in two passes. Tube outer diameter is 0.75 inches with a
tube pitch of 0.9375 inches. Tube length is 14 feet and pressure drop on the tube side is 3.31 psi.
The exchangers consist of 5 baffles with a center-center spacing of 26 inches. The total purchase
cost of all four units is estimated to be $218,008 using Aspen Plus EDR package (similarly used
for exchanger geometry design). The total bare module cost of the exchangers is estimated to be
H-304: Stripper Overhead Cooler
A shell and tube heat exchanger that cools the stripper overhead with cooling water. Inlet
feed to this exchanger on the shell side (CW-305) is 2,050,000 lb/hr of cooling water, entering at
90.0F and 64.7 psia and exiting at 120.3F and 58.8 psia (CW-306). Pressure drop on the shell
side is 5.67 psi. Heat is exchanged with the passing stripper overhead (S-314) entering the tube
side at 249.4F and 43 psia and leaving at 120.0F and 39.3 psia (S-315). This unit is comprised
of 2 shell and tube exchangers in parallel, with a per-unit area of 1665.5 sqft. The total effective
area of both units in the exchanger system is 3331 sqft. Each exchanger has a 26.75 inch outer
diameter carbon steel shell and 540 carbon steel tubes in a single pass. Tube outer diameter is
0.75 inches with a tube pitch of 0.9375 inches. Tube length is 16 feet and pressure drop on the
tube side is 3.72 psi. The total purchase cost of both units is estimated to be $78,494 using Aspen
Plus EDR package (similarly used for exchanger geometry design). The total bare module cost of
the exchangers is estimated to be $248,826. See page 197 for the specification sheet.
T-301: Monoethanol Amine - CO2 Absorption Tower
Four-stage absorption column for removing excess carbon dioxide from the synthesis gas
stream as pretreatment prior to introduction to the DME reactor process section. Carbon dioxide
88
removal is achieved by passing a solution of monoethanol amine and water through the gas
stream in a packed column. The flow rate of MEA and water solution (S-302) to the column is
1,332,541 lb/hr in constant recycle returning from the stripping column and subsequent units
downstream, with an approximate composition of 78% water and 22% MEA present both in
solution and ionic compounds (MEACOO- and MEA+, about 6% combined). The synthesis gas
stream to undergo carbon dioxide removal (S-214) enters at a flow rate of 341,103 lb/hr with an
approximate composition of 52% hydrogen, 21% carbon dioxide, 24.5% carbon monoxide, and
2.5% methane by mole percent. The MEA and water inventory loss requires a make-up stream
(S-304) fed to the column of 170.0 lb/hr of MEA and 2467.4 lb/hr of water. The tower operates
at a pressure of 300.0 psia, with a top stage temperature of 204.1F and a bottom stage
temperature of 193.6F. Water reflux from flash vessel F-301 enters the column via stream S-307
at a flow rate of 7037 lb/hr, at 124.9F and 296.8 psia. To achieve sufficient mass transfer, KochGlitsch BX Wire Gauze structured packing in a packed height of 15 feet is used, equating to an
HETP value of approximately 3.75 ft. This packed height value is used for conservatism by
recommendation of Professor Leonard Fabiano of the University of Pennsylvania and is based on
previous MEA-CO2 absorption design work in 2007. Pressure drop for the section is estimated to
be 0.025 psi. The required vessel inside diameter is 15 feet, 11 inches. Using a design pressure of
375.1 psig, a maximum allowable stress of 13,750 psi (carbon steel, SA-285 up to 650F), and a
weld efficiency of 1.0, the required vessel thickness is calculated to be 2.65 inches. The height of
the tower, including the height of the packing and an additional 8 foot sump and 4 foot top
segment, is 27 feet. The required vertical tower thickness to compensate for wind load or
equivalent earthquake assuming a wind velocity of 140 mph acting uniformly over the height of
the tower is calculated to be 0.0095 inches. Accounting for the cost of the vessel, the cost of
platforms and ladders for maintenance, and the cost of the structured packing (estimated to be
approximately $250/cubic foot [Seider, 3rd Ed 2009]), the total cost of the tower is projected to
be $1,213,975. The cost of the MEA in constant recycle (approximately 293,159 lb/hr) is
estimated to be $217,150 (using an August 2010 pricing estimate of 1,150/tonne; note cost
estimate is converted to U.S. dollars and based upon short tons for appropriate conversion). An
operating cost of providing the MEA present in the make-up stream continuously at 170.0 lb/hr
is estimated to be $126/hr. For a year of operation, the make-up stream MEA requirements have
a projected cost of $997,920/yr. The process water present in the stream in constant recycle is
89
approximately 1,039,382 lb. The cost of this process water originally introduced to the system
loop upon start-up is estimated to be $93. The operating cost of the process water continuously
fed via the make-up stream at 2467.4 lb/hr is estimated to be $0.22/hr for a yearly cost of about
$1755/yr. See page 139 for the specification sheet and page 273 of the appendix for a sample
sizing and costing calculation.
T-302: Monoethanol Amine- CO2 Stripping Tower
Eight-stage stripping column for removing carbon dioxide from CO2-rich MEA and
water effluent from the absorption column to renew and recycle for reintroduction to the
absorption column. The flow rate of CO2-rich solution is first exchanged with the stripper
bottoms in a feed-product exchanger (H-303) and subsequently enters the column at 242.7F and
80.2 psia (S-311) with a mass flow rate of 1,476,527 lb/hr. The temperature at the top stage of
the column is 249.4F and the temperature at the reboiler is 290.4F, with a reboiler heat duty of
199,376,985 Btu/hr. The tower operates at a pressure 43.0 psia. The distillate (S-314) leaves the
top of the column at 200,000 lb/hr at 249.4F and 43.0 psia with an approximate composition of
52% CO2 and 48% water by mole percent, with trace amounts of MEA and various ionic
compounds. The bottoms product (S-312) leaves the column at 1,276,527 lb/hr at 290.4F and
43.0 psia. This stream has an approximate composition of 24% MEA and various ionic
compounds (3.6% MEACOO-, 3.8% MEA+), and 76% water by mole percent. Koch-Glitsch BX
Wire Gauze structured packing in a packed height of 15 feet is used, equating to an HETP value
of approximately 2 feet, 2 inches. This packed height value is used for conservatism by
recommendation of Professor Leonard Fabiano of the University of Pennsylvania and is based on
previous MEA-CO2 absorption design work in 2007. Pressure drop for the section is estimated to
be 0.05 psi. The required vessel inside diameter is 15.82 feet. Using a design pressure of 77.25
psig, a maximum allowable stress of 13,750 psi (carbon steel, SA-285 up to 650F), and a weld
efficiency of 0.85, the required vessel thickness is calculated to be 0.63 inches. The height of the
tower, including the height of the packing and an additional 8 foot sump and 4 foot top segment,
is 27 feet. The required vertical tower thickness to compensate for wind load or equivalent
earthquake assuming a wind velocity of 140 mph acting uniformly over the height of the tower is
calculated to be 0.0097 inches. Accounting for the cost of the vessel, the cost of platforms and
ladders for maintenance, and the cost of the structured packing (estimated to be approximately
90
$250/cubic foot [Seider, 3rd Ed 2009]), the total cost of the tower is projected to be $931,055.
See page 140 for the specification sheet and page 273 of the appendix for a sample sizing and
costing calculation.
V-301: Absorber Overhead Water Decant Flash Vessel
Horizontal flash vessel for decanting excess water leaving with the absorber overhead
stream to send dry gas to the DME reactor section. Inlet to the flash vessel (S-306) from the
absorber overhead heat exchanger unit (H-302) is the CO2-lean synthesis gas at 125.0F and
296.8 psia with an approximate composition of 60% H2, 5% CO2, 3% H2, 29% CO, and 3% CH4
at a mass flow rate of 206,792 lb/hr. The bottoms from the flash vessel (S-307) leaves at 124.9F
and 296.8 psia at a mass flow rate of 7,037 lb/hr with a composition of greater than 99% water.
This stream is reintroduced to the absorption tower. The overhead stream (S-308) is the final
treated synthesis gas sent to the DME reactor section. The synthesis gas stream exiting the vessel
is at 124.9F and 296.8 psia at a mass rate of 199,755 lb/hr. The approximate composition of this
synthesis gas is 62% H2, 5% CO2, 29% CO, 3% CH4, and 1% remainder H2O and N2. The
required vessel size is 2 feet in diameter with a length of 7 feet with a vessel wall thickness of
0.54 inches. The estimated purchase cost of this flash vessel including platforms and ladders is
projected to be $15,922. The bare module cost of this unit is estimated to be $48,564. See page
175 for the specification sheet and page 276 of the appendix for a sample sizing and costing
calculation.
V-302: Stripper Overhead Water Decant Flash Vessel
Horizontal flash vessel for decanting water leaving with the stripper overhead stream
from the CO2 effluent. Inlet to the vessel (S-315) from the stripper overhead heat exchanger unit
(H-304) is at 120.0F and 39.3 psia at a mass flow rate of 200,000 lb/hr. The composition of this
stream is approximately 52% CO2 and 48% water, with trace quantities of MEA and ionic
compounds. The stream exiting the top of the vessel (S-318) leaves at 118.4F at a pressure of
39.3 psia at a mass flow rate of 145,880 lb/hr. This stream is approximately 96% CO2 and 4%
water by mole percent. It is assumed that this stream may be sold at CO2 prices. The estimated
value of this effluent stream is $50/ton for beverage-grade CO2. The stream leaving the bottom
of the vessel (S-316) is comprised of about 99% water by mole percent at 118.4 F and 39.3 psia
91
at a mass flow rate of 54,120 lb/hr. The vessel size is 6 feet in diameter with a wall thickness of
0.44 inches. The vessel has a length of 18 feet. The estimated purchase cost of this flash vessel
including platforms and ladders is projected to be $33,813. The total bare module cost of this
unit is estimated to be $103,132. See page 176 for the specification sheet and page 276 of the
P-301: Centrifugal Pump for Re-pressurization of MEA Recycle
Centrifugal pump of cast iron construction providing pressure increase for MEA recycle
stream for reintroduction to the absorption column. Flow to the pump (S-316) is 1,332,541 lb/hr
at a temperature of 215.1F and 43 psia, with a pressure increase of 257 psi. Power consumption
of the electric motor is calculated to be 558 HP operating at 1800 rpm with a drip-proof
enclosure (brake horsepower of the pump calculated to be 520 HP). The total pump cost
excluding the motor is estimated to be $13,209 (at a bare module cost of $56,797). The purchase
cost of the electric motor is estimated to be $31,003 (at a bare module cost of $99,210). The
electricity requirements to run this pump are estimated to be 3,295,512 kWh/yr at a projected
cost of $197,731/yr. See page 144 for the specification sheet and page 279 of the appendix for a
Valve for Pressure Decrease from Absorption to Stripping Column
This valve is highlighted on the flow diagram to show a significant pressure drop. The
absorption column is operated at a pressure of 300 psia and the stripping tower is run at an
operating pressure of 43 psia. This stream must be throttled through a valve prior to entering the
stripping tower to regulate the appropriate pressures.
92

Compressor C-401
C-401 is a compressor that pressurizes the un-reacted syngas recycle stream before it is
mixed with the fresh syngas to enter the microchannel reactor. The compressor increases the
streams pressure from 200 psi to 295 psi and the temperature increases from 172F to 255F. It
is made from carbon steel and, with an efficiency of 0.7, requires 6613 hp. The compressor is
powered using an electric motor drive that consumes 4,931 kW. The bare module cost of the
compressor is $4,790,000. See page 128 for the specification sheet and page 283 of the appendix
for a sample sizing and costing calculation.
Heat Exchanger H-401
H-401 is a system of two identical fixed-head shell and tube heat exchangers in parallel
that preheat the feed into the microchannel reactor using the reactor effluent. The reactor feed is
on the shell side and is heated from 201F to 466F. On the tube side, the reactor effluent is
cooled from 536F to 251F. Both streams are vapor, so the overall heat transfer coefficient is
relatively low, 88 BTU/hr-sqft-R, which leads to a total heat transfer area of 14,600 sqft. The
total heat duty is 87.3 MMBTU/hr. There are 758 tubes that are 20 ft. long and have an OD of
0.75 in. The shell has an OD of 31 in. with a baffle spacing of 23.5 in. Both the tubes and shell
are constructed from carbon steel. All calculations were performed using Aspen Plus Exchanger
Design and Rating. The total bare module cost of the exchanger system is $937,000. See page
198 for the specification sheet.
Microchannel Reactor R-401
The microchannel reactor is the reactor that is used to convert the syngas into DME. The
unreacted syngas, S-403, enters the reactor at 466F.
Four exothermic reactions occur
simultaneously to form the DME and they are:

CO + 2 H2 CH3OH
H = -43.4 kcal/mol-DME
(1)
CO2 + 3 H2 CH3OH + H2O
(2)
2 CH3OH CH3OCH3 + H2O
(3)
CO + H2O CO2 + H2
(4)
93
The reactor achieves 95% conversion of the carbon monoxide, with a 60% DME selectivity.
Although in studies the carbon monoxide conversion was only as high as 90%, this was with a
H2:CO ratio of 3:1. With a 2:1 H2:CO ratio, the conversion was only 65%, and it increased to
90% with a 3:1 ratio. Based on this information and correlations provided by Hu et al. it was
assumed that by doubling the H2:CO ratio to 6:1 at these reactor conditions, the CO conversion
would increase to 95%.
Since this type of reactor is not currently in commercial use, it needs to be custom
fabricated in modules, each of which is 1.5 m high, 1 m wide, and 1 m long. To meet the flow
requirements, a total of 36 modules need to be run in parallel. Each module contains 3,400
reaction channels and 6,800 coolant channels. The reactor is operated at 536F, and is cooled by
water flowing counter-currently through the reactor coolant channels. The reactant channels are
operated at 200 psi because, since the reaction is a mole-reducing reaction, elevated pressure
favors a higher conversion of carbon monoxide, and therefore a higher DME yield. The coolant
channels are operated at 550 psi, so after exiting the reactor the water can be flashed to produce
high-pressure steam.
The reactor requires two different catalysts, one for the conversion of syngas to methanol
(reactions 1 and 2), and the second to dehydrate methanol into DME (reaction 3). The catalyst
used for methanol formation in this application is copper, but zinc oxide or a mixture of copper
and zinc oxide can be used as well with no significant change in the reaction. Aluminum oxide is
used as the methanol dehydration catalyst. For optimal DME production and carbon monoxide
conversion, the two catalysts are loaded in a 1:1 mass ratio. The catalyst is inserted into the
reactor by wash-coating a FeCrAlY metal wire felt with a thickness of 0.9 mm and 90% porosity
with the two catalysts, and then top and bottom of each reactor channel is lined with the catalystcoated felt. This reactor design information is based on information provided in U.S. patents
7,250,151 and 6,969,506 and information provided by Arkema Chemical. The total bare module
cost of the reactor, including catalyst, is $5,002,000. See page 169 for the specification sheet and
page 294 of the appendix for a sample sizing and costing calculation.
H-402 is a fixed-head shell and tube heat exchanger that cools the reactor effluent to a
temperature at which the majority of the methanol and water condense out of the product stream.
94
The reactor effluent on the tube side is cooled from 251F to 167F. Cooling water with a flow
rate of 5,000 gpm enters the exchanger at 90F and exits at 120F. The overall heat transfer
coefficient is 377 BTU/hr-sqft-R, which leads to a total heat transfer area of 2070 sqft. The total
heat duty is 70.8 MMBTU/hr. There are 1397 tubes that are 8 ft. long and have an OD of 0.75 in.
The shell has an OD of 42 in. with a baffle spacing of 15 in. Both the tubes and shell are
constructed from carbon steel. All calculations were performed using Aspen Plus Exchanger
Design and Rating. The total bare module cost of the exchanger system is $251,000 with an
annual utility cost of $184,000 for cooling water. See page 199 for the specification sheet.
95

Flash Vessel V-501
This V-L equilibrium horizontal pressure vessel separates the unreacted syngas, carbon
dioxide, and DME, which comes off the top of the vessel as a vapor, from liquid water and
methanol. The equilibrium occurs at 230 psi and 167F and has a vapor fraction of 0.9. The flow
rate into the vessel, S-406, is 483,000 lb/hr and a liquid residence time of thirty minutes leads to
a vessel length of 21 ft and a diameter of 7 ft. The bare module cost of the vessel $212,000. See
page 177 for the specification sheet and page 298 of the appendix for a sample sizing and costing
calculation.
Absorption Tower T-501
T-501 is a packed absorption tower that uses water to absorb DME out of the vapor
product stream. The column operates at 171F and 205 psi. Assuming a theoretical tray
efficiency of 0.7, 15 theoretical stages are required. The tower has a height of 44 ft and a
diameter of 9 ft 8 in. The packing within the tower is 30 ft tall, for a total packed volume of 1900
ft3. A metal wire gauze packing, CY700, purchased from Jincheng Chemical Packing Company
is used. The total bare module cost for the column, including internals, is $1,120,000. See page
calculation.
Centrifugal Pump P-501
P-501 is a centrifugal pump that is used to draw the liquid off the bottom of V-501 by
pressurizing the stream from 230 psi to 235 psi at 167F. Based on the recommendation of
industrial consultant Mr. Wismer, an in-line spare was not installed, but an allowance for
preventative maintenance, spare parts, and spare pumps is included in the capital cost of the
plant. The pump is constructed from stainless steel, operates at 3600 rpm, and uses an electric
motor drive. The flow rate through the pump is 161 gpm, and P-501 requires 2.56 kW to produce
the 14 ft of head. The bare module cost, including the drive, is $11,800. See page 145 for the
specification sheet and page 287 of the appendix for a sample sizing and costing calculation.
96

P-502 is a centrifugal pump that is used to draw the liquid off the bottom of T-501 by
pressurizing the stream from 202 psi to 207 psi at 171F. Based on the recommendation of
industrial consultant Mr. John Wismer, an in-line spare was not installed, but an allowance for
preventative maintenance, spare parts, and spare pumps is included in the capital cost of the
motor drive. The flow rate through the pump is 824 gpm, and P-502 needs 0.50 kW to produce
14 ft of head. The bare module cost, including the drive, is $15,100. See page 146 for the
P-503 is a centrifugal pump that is used to pressurize stream S-414 from 202 psi to 230
psi at 170F. The stream is pressurized prior to entering D-501 to obtain the desired equilibrium
and product compositions within the distillation tower. Although no spares pumps are installed,
an allowance for preventative maintenance, spare parts, and spare pumps is included in the
capital cost of the plant. The pump is constructed from stainless steel, operates at 3600 rpm, and
uses an electric motor drive. The flow rate through the pump is 985 gpm, and the pump requires
16.8 kW to produce 78 ft of head. The bare module cost, including the drive, is $33,400. See
calculation.
Distillation Column D-501
D-501 is a 25 stage carbon steel distillation column. It has 25 sieve trays with a tray
spacing of 2 ft, a sump of 10 ft, and an overhead space of 4 ft, leading to a total height of 60 ft.
The column has a diameter of 10 ft. The distillate comes off as a vapor stream at 59F. In order
to keep the distillate at a temperature at which chilled water can be used instead of a more
expensive refrigerant, the column is operated at an elevated pressure of 205 psi. The main
product stream is taken off as a liquid side-draw from stage 4, and comes off at a temperature of
151F. The bottoms of the column, almost pure water, comes off at a temperature of 385F. The
diameter of the top and bottom of the column were calculated separately in case the side-draw
had an effect on the required diameter, but the difference in diameter was found to be
97
insignificant, only 0.03 in. This small difference is most likely because the vapor flow rate
remains relatively unchanged through the column because the side-draw is entirely liquid. With
an insignificant difference between the required diameter at the top and bottom of the tower, the
entire column is constructed with a diameter of 10 ft. The bare module cost of this column,
including internals, is $1,240,000. See page 135 for the specification sheet and page 284 of the
DME Storage Tank:

This is an intermediate storage tank that can hold a 1 day supply of the DME product to
be fed into the propylene reactor. It is a spherical storage vessel with a capacity of 500,000 gal.
The bare module cost of this tank is $1,260,000.
Distillation Column Condenser H-501
H-501 is a system of three fixed-head shell and tube heat exchangers that cool and
partially condense the distillation column overhead. The first condenser uses cooling water on
the shell side to cool the overhead from 121F to 100F. The overhead stream is then split and
sent to the other two condensers that run in parallel. These condensers use chilled water to cool
the stream from 100F to 58.5F. The overall heat transfer coefficient in all three exchangers is
estimated to be 80 BTU/hr-sqft-R, which leads to a total heat transfer area of 22,500 sqft. The
total heat duty is 112 MMBTU/hr. Both the tubes and shell are constructed from carbon steel.
These calculations were performed using estimations for the overall heat transfer coefficient
provided by Seider 2009. The total bare module cot of the exchanger system is $520,000. See
calculation.
Reflux Drum V-502
This V-L equilibrium horizontal pressure vessel separates the distillate vapor from the
condensed liquid that is refluxed back to the distillation column. The equilibrium occurs at 205
psi and 59F and has a vapor fraction of 0.03. The flow rate into the vessel is 620,000 lb/hr. A
liquid residence time of 5 minutes assuming the drum is half filled with liquid leads to a vessel
length of 30 ft and a diameter of 10 ft. The bare module cost of the vessel $342,000. See page
98
calculation.
Reflux Pump P-504
P-504 is a centrifugal pump that is used to draw the liquid out of the reflux drum, V-502,
and send it back onto the top tray of the tower. The pump is constructed from stainless steel,
operates at 1800 rpm, and uses an electric motor drive. The flow rate through the pump is 1740
gpm, 11 ft 6 in of head is developed, and the pump requires 3.70 kW. The bare module cost,
including the drive, is $25,300. See page 148 for the specification sheet and page 290 of the
Kettle Reboiler H-502
H-502 is a system of two kettle reboilers in parallel that are used to boil-up a portion of
the liquid bottoms of D-501. The bottoms enter the reboiler as a liquid at 383F and leaves as a
vapor at 385F. The overall heat transfer coefficient is estimated to be 400 BTU/hr-sqft-R, as
suggested in Seider 2009. The total heat transfer area is 15,440 sqft and the total heat duty is
185.7 MMBTU/hr. This heat is provided by 500 psi steam generated from cooling the
microchannel reactor, R-401. The total bare module cost of the heat exchanger system is
$660,000. See page 201 for the specification sheet and page 286 of the appendix for a sample
P-505 is a centrifugal pump that is used to draw the bottoms off of D-501 by pressurizing
the stream from 207 psi to 212 psi at 385F. An in-line spare is not installed, but an allowance
for preventative maintenance, spare parts, and spare pumps is included in the capital cost of the
motor drive. The flow rate through the pump is 724 gpm, and P-505 requires 2.11 kW to produce
the 14 ft of head. The bare module cost, including the drive, is $14,700. See page 149 for the
Flash Vessel V-503
99
V-503 is a two phase horizontal flash drum which is used to separate the low-pressure
steam from the liquid water in stream S-511. The steam is sent out to the rest of the plant to be
used as a heat source, while the liquid is recycled back to the absorption tower. The flash vessel
operates at 50 psi and 281F with a vapor fraction of 13%. Assuming a liquid residence time of 5
minutes and the vessel being half filled with liquid, the drum has a volume of 450 ft3. The vessel
has a diameter of 6 ft and a length of 17 ft. The bare module cost of the flash drum is $99,700.
P-506 is a centrifugal pump that is used to draw the liquid water off the bottom of the
flash vessel V-503 by pressurizing the stream from 50 psi to 55 psi at 281F. An in-line spare is
not installed, but an allowance for preventative maintenance, spare parts, and spare pumps is
included in the capital cost of the plant. The pump is constructed from stainless steel, operates at
3600 rpm, and uses an electric motor drive. The flow rate through the pump is 340 gpm, and P506 requires 1.09 kW to produce the 13 ft of head. The bare module cost, including the drive, is
H-503 is a fixed-head shell and tube heat exchanger that cools the hot water from the
bottoms of D-501 and the recycle water from Block 500. The water stream enters the exchanger
at 267F and cooled to 110F on the tube side of the exchanger. Cooling water with a flow rate
of 3,400 gpm enters the exchanger on the shell side at 90F and exits at 120F. The overall heat
transfer coefficient is 475 BTU/hr-sqft-R, which leads to a total heat transfer area of 2300 sqft.
The total heat duty is 47.9 MMBTU/hr. There are 1006 tubes that are 12 ft. long and have an OD
of 0.75 in. The shell has an OD of 37 in. with a baffle spacing of 23.5 in. Both the tubes and shell
100

P-507 is a centrifugal pump that pressurizes the water recycle stream, S-515, prior to it
entering the absorption tower. The pump brings the stream with a flow rate of 516 gpm from 40
psi to 230 psi. An in-line spare is not installed, but an allowance for preventative maintenance,
spare parts, and spare pumps is included in the capital cost of the plant. The pump is constructed
from stainless steel, operates at 3600 rpm, and uses an electric motor drive. P-507 requires 60.9
kW and produces 450 ft of head. The bare module cost, including the drive, is $51,200. See page
calculation.
101

P-601 is a centrifugal pump that pressurizes the water diluent prior to entry of the reactor
train. The pressure is increased from 207.4 psi to 500 psi at 385F and 50.38 lb/ft3, requiring 55
Hp at 197 gpm. The pump requires 40.6 kW of electricity to generate 835 ft of head. The pump
operates at 3600 rpm, is a horizontal split case, and is constructed out of stainless steel. The
electric drive is a totally enclosed, fan-cooled drive. The total bare module cost for the pump
and drive is $47,900. See page 152 for the specification sheet and page 279 of the appendix for a
P-602 is a centrifugal pump that pressurizes the DME/methanol reactants prior to entry of
the reactor train. The pressure is increased from 206.2 psi to 485 psi at 138F and 39.02 lb/ft3,
requiring 79 Hp at 324 gpm. The pump requires 58.6 kW of electricity to generate 1025 ft of
head. The pump operates at 3600 rpm, is a horizontal split case, and is constructed out of
stainless steel. The electric drive is a totally enclosed, fan-cooled drive. The total bare module
cost for the pump and drive is $61,500. See page 153 for the specification sheet and page 279 of
the appendix for a sample sizing and costing calculation.
H-601 is a fixed-head shell and tube heat exchanger that heats the water feed to its
boiling point. The water on the tube side is heated from 385F to 447F. 400 psi steam with a
flow rate of 9,500 lb/hr condenses on the shell side. The overall heat transfer coefficient is
predicted to be 810 BTU/hr-sqft-R, which leads to a total heat transfer area of 514 sqft. The total
heat duty is 7.35 MMBTU/hr. There are 167 tubes that are 16 ft. long and have an OD of 0.75 in.
The shell has an OD of 16 in. with a baffle spacing of 26 in. Both the tubes and shell are
annual utility cost of $500,000 HP steam before integration. See page 203 for the specification
sheet.
102

H-602 is a fixed-head shell and tube heat exchanger that vaporizes the water diluent to
the reactor. The water on the tube side is heated from 447F to 461F. 800 psi steam with a flow
rate of 90,000 lb/hr condenses on the shell side. The overall heat transfer coefficient is predicted
to be 940 BTU/hr-sqft-R, which leads to a total heat transfer area of 1,125 sqft. The total heat
duty is 62.5 MMBTU/hr. There are 421 tubes that are 14 ft. long and have an OD of 0.75 in. The
shell has an OD of 24.625 in. with a baffle spacing of 15.5 in. Both the tubes and shell are
annual utility cost of $4,700,000 for steam before integration. See page 204 for the specification
sheet.
H-603 is a fixed-head shell and tube heat exchanger that superheats the steam diluent.
The water on the tube side is heated from 460F to 707F. 1800 psi steam with a flow rate of
36,000 lb/hr condenses on the shell side. The overall heat transfer coefficient is predicted to be
46.1 BTU/hr-sqft-R, which leads to a total heat transfer area of 3300 sqft. The total heat duty is
0.94 MMBTU/hr. There are 438 tubes that are 20 ft. long and have an OD of 0.75 in. The shell
has an OD of 34.5 in. with a baffle spacing of 4.5 in. Both the tubes and shell are constructed
from carbon steel. All calculations were performed using Aspen Plus Exchanger Design and
Rating. The total bare module cost of the exchanger system is $679,800 with an annual utility
cost of $2,300,000 for steam. See page 205 for the specification sheet.
Reactor R-601
R-601 is an adiabatic, fixed bed reactor with a diameter of 8 ft 6 in and a length of 17 ft 3
in. The horizontal vessel is made out of low-alloy steel. Reactants are fed to reactor at 707F
and 450 psi. The Ergun equation predicts a pressure drop of 30 psi across the reactor. The outlet
temperature is 933 F and the pressure is 420 psi. The total bare module cost of the reactor is
103

H-604 is a fixed-head shell and tube heat exchanger that generates high pressure steam
from the exothermic heat of reaction. The reactor effluent on the tube side is cooled from 924F
to 650F. 1800 psi steam with a flow rate of 20,700 lb/hr vaporizes on the shell side. The overall
heat transfer coefficient is predicted to be 80.1 BTU/hr-sqft-R, which leads to a total heat
transfer area of 1500 sqft. The total heat duty is 13.9 MMBTU/hr. There are 291 tubes that are
14 ft. long and have an OD of 0.75 in. The shell has an OD of 48.25 in. with a baffle spacing of
14 in. Both the tubes and shell are constructed from carbon steel. All calculations were
performed using Aspen Plus Exchanger Design and Rating. The total bare module cost of the
exchanger system is $1,117,200 with an annual utility cost of $300,000 for boiler feed water. See
Reactor R-602
and 410 psi. The Ergun equation predicts a pressure drop of 40 psi across the reactor. The outlet
temperature is 895 F and the pressure is 370 psi. The total bare module cost of the reactor is
from the exothermic heat of reaction of the second reactor effluent. The effluent on the tube side
is cooled from 896F to 650F. 1800 psi steam with a flow rate of 23,400 lb/hr vaporizes on the
shell side. The overall heat transfer coefficient is predicted to be 81.0 BTU/hr-sqft-R, which
leads to a total heat transfer area of 1852 sqft. The total heat duty is 15.8 MMBTU/hr. There are
359 tubes that are 14 ft. long and have an OD of 0.75 in. The shell has an OD of 40.5 in. with a
baffle spacing of 6.5 in. Both the tubes and shell are constructed from carbon steel. All
calculations were performed using Aspen Plus Exchanger Design and Rating. The total bare
module cost of the exchanger system is $789,000 with an annual utility cost of $330,000 for
boiler feed water. See page 207 for the specification sheet.
104
Reactor R-603
and 360 psi. The Ergun equation predicts a pressure drop of 100 psi across the reactor. The
outlet temperature is 911F and the pressure is 260 psi. The total bare module cost of the reactor
is $425,000. See page 172 for the specification sheet.
from the exothermic heat of reaction of the third reactor effluent. The effluent on the tube side is
cooled from 911F to 650F. 1800 psi steam with a flow rate of 36,000 lb/hr vaporizes on the
1097 tubes that are 12 ft. long and have an OD of 0.75 in. The shell has an OD of 80.875 in. with
a baffle spacing of 27 in. Both the tubes and shell are constructed from carbon steel. All
module cost of the exchanger system is $1,757,100 with an annual utility cost of $500,000 for
boiler feed water. See page 208 for the specification sheet.
Reactor R-604
and 235 psi. The Ergun equation predicts a pressure drop of 200 psi across the reactor. The
outlet temperature is 787F and the pressure is 35 psi. The total bare module cost of the reactor
is $425,000. See page 173 for the specification sheet.
from the exothermic heat of reaction of the final reactor effluent. The effluent on the tube side is
cooled from 787F to 730F. 1800 psi steam with a flow rate of 10,000 lb/hr vaporizes on the
105
854 tubes that are 5 ft. long and have an OD of 0.75 in. The shell has an OD of 39.125 in. with a
baffle spacing of 6 in. Both the tubes and shell are constructed from carbon steel. All calculations
were performed using Aspen Plus Exchanger Design and Rating. The total bare module cost of
the exchanger system is $520,800 with an annual utility cost of $140,000 for boiler feed water.
H-608 is a fixed-head shell and tube heat exchanger that transfer heat from the reactor
effluent to the DME/methanol feed. The effluent on the tube side is cooled from 730F to 240F.
The DME/methanol feed is vaporized on the shell side, with the temperature increasing from
138F to 707F. The overall heat transfer coefficient is predicted to be 25.4 BTU/hr-sqft-R,
which leads to a total heat transfer area of 18757 sqft. The total heat duty is 47.8 MMBTU/hr.
There are 4,976 tubes that are 20 ft. long and have an OD of 0.75 in. The shell has an OD of 74.5
in. with a baffle spacing of 23 in. Both the tubes and shell are constructed from carbon steel. All
module cost of the exchanger system is $520,800. See page 210 for the specification sheet.
106

H-701 is a fixed-head shell and tube heat exchanger that vaporizes the combined
water/byproduct feed to the steam cracking reactors. The feed on the tube side is heated from
234F to 300F. 90 psi steam condenses on the shell side at 60,000 lb/hr. The overall heat
transfer coefficient is predicted to be 415.8 BTU/hr-sqft-R, which leads to a total heat transfer
area of 3,347 sqft. The total heat duty is 50.7 MMBTU/hr. There are 965 tubes that are 18 ft.
long and have an OD of 0.75 in. The shell has an OD of 34.875 in. with a baffle spacing of 23.5
in. Both the tubes and shell are constructed from carbon steel. All calculations were performed
using Aspen Plus Exchanger Design and Rating. The total bare module cost of the exchanger
system is $187,800 with an annual utility cost of $2,300,000 for steam before integration. See
H-702 is a fixed-head shell and tube heat exchanger that transfers heat from the steam
cracking reactor effluent to the reactor feed. The feed on the tube side is heated from 297F to
665F. The reactor effluent cools from 705F to 344F on the shell side. The overall heat
transfer coefficient is predicted to be 24.6 BTU/hr-sqft-R, which leads to a total heat transfer
area of 31,830 sqft. The total heat duty is 30.8 MMBTU/hr. There are 1025 tubes that are 18 ft.
long and have an OD of 0.75 in. The shell has an OD of 34.875 in. with a baffle spacing of 23.25
in. Both the tubes and shell are constructed from carbon steel. All calculations were performed
using Aspen Plus Exchanger Design and Rating. The total bare module cost of the exchanger
system is $1,844,100. See page 212 for the specification sheet.
Fired Heater F-701
F-701 is a fired heater that brings the reactor feed to the reactor inlet temperature. The
heater is made of Cr-Mo Alloy Steel and operates at 80 psig. The feed is heated from 665F to
923F using 26.3 MMBTU/hr. The total bare module cost of the heat is $1,712,200, with an
annual utility cost of $800,000 for natural gas. See page 228 for the specification sheet.
107
Reactor R-701, R-702, R-703

Reactors R-701, R-702, R-703 are three identical, horizontal, adiabatic fixed bed reactors.
The feed enters the reactor at 921F and 65 psi. The Ergun equation predicts a pressure drop of
35 psig across the reactor. The temperature and pressure of the outlet is 705F and 30 psi. The
reactor is 19 ft long with a diameter of 9 ft 6 in, and is made of low-alloy steel. The total bare
module cost of each reactor is $197,000. See page 174 for the specification sheet.
108

H-801 is a fixed-head shell and tube heat exchanger that transfers heat from the combined
olefin product streams to boiler feed water. The feed on the tube side is cooled from 269F to
235F. 8,000 lb/hr boiler feed water is vaporized at 20 psi. The overall heat transfer coefficient
is predicted to be 38.1 BTU/hr-sqft-R, which leads to a total heat transfer area of 7,483 sqft. The
total heat duty is 5.18 MMBTU/hr. There are 3,302 tubes that are 12 ft. long and have an OD of
0.75 in. The shell has an OD of 59 in. with a baffle spacing of 23.25 in. Both the tubes and shell
annual utility cost of $110,000 for boiler feed water. See page 213 for the specification sheet.
H-802 is a fixed-head shell and tube heat exchanger that transfers heat from the combined
olefin product streams to cooling water. The olefins on the tube side are cooled from 235F to
138F. 5,000,000 lb/hr of cooling water passes through the shell side of the exchanger. The
overall heat transfer coefficient is predicted to be 312.1 BTU/hr-sqft-R, which leads to a total
heat transfer area of 6,846 sqft. The total heat duty is 184.7 MMBTU/hr. There are 997 tubes that
are 12 ft. long and have an OD of 0.75 in. The shell has an OD of 35.875 in. with a baffle
spacing of 23.25 in. Both the tubes and shell are constructed from carbon steel. All calculations
were performed using Aspen Plus Exchanger Design and Rating. The total bare module cost of
the exchanger system is $1,844,100 with an annual utility cost of $350,000 for cooling water.
Flash Vessel V-801
V-801 is a horizontal, adiabatic, pressure vessel that separates the gaseous olefin and
hydrocarbon products from the condensed aqueous phase. The equilibrium occurs at 18 psi and
138F, with a vapor fraction of 0.22. The flow rate into the vessel is 331,100 lb/hr. A liquid
residence time of five minutes at half height leads to a vessel length of 21 ft and a diameter of 7
109
ft. The bare module cost of the vessel $130,300. See page 180 for the specification sheet and
page 299 of the appendix for a sample sizing and costing calculation.
Compressor C-801
C-401 compresses the vapor from the flash drum to move the gas to the distillation
column. The compressor increases the streams pressure from 18 psi to 55 psi and the
temperature increases from 138F to 235F. It is made from carbon steel and, with an efficiency
of 0.7, requires 2117 hp. The compressor is powered using an electric motor drive that consumes
1,577 kW. The bare module cost of the compressor is $1,927,400. See page 129 for the
P-801 is a centrifugal pump that pressurizes the condensed liquid separated from the flash
vessel. The pressure is increased from 18 psi to 55 psi at 138F and 54.03 lb/ft3, requiring 10 Hp
at 470 gpm. The pump requires 10.7 kW of electricity to generate 100 ft of head. The pump
operates at 3600 rpm, is a vertical split case, and is constructed out of stainless steel. The
D-801 is a carbon steel distillation column with 7 theoretical trays. A tray efficiency of
27% leads to 24 sieve trays. Using tray spacing of 2 ft, a sump height of 10 ft, an overhead space
of 4 ft, and 3 ft at the inlet, a total height of 61 ft is required. The column has a diameter of 7 ft 6
in. The distillate comes off as a vapor stream at 133F at 29 psi. The bottoms of the column,
almost pure water, comes off at a temperature of 248F. The bare module cost of this column,
including internals, is $770,000. See page 136 for the specification sheet and page 284 of the
110

H-804 is a fixed-head shell and tube heat exchanger that condenses water from the olefin
vapor distillate. The olefins on the shell side are cooled from 215F to 130F. 1,400,000 lb/hr of
cooling water passes through the tube side of the exchanger. The overall heat transfer coefficient
is predicted to be 331.3 BTU/hr-sqft-R, which leads to a total heat transfer area of 1,488 sqft.
of 0.75 in. The shell has an OD of 32.875 in. with a baffle spacing of 26 in. Both the tubes and
shell are constructed from carbon steel. All calculations were performed using Aspen Plus
Exchanger Design and Rating. The total bare module cost of the exchanger system is $141,300
with an annual utility cost of $100,000 for cooling water. See page 216 for the specification
sheet.
Pressure Vessel V-802
V-802 is a horizontal pressure vessel used to store reflux for the distillation column. The
volumetric flow rate to the vessel is 1,033 cuft/hr at a pressure of 25 psi. Using a residence time
of five minutes at half full and an aspect ratio of three, a diameter of 4 ft 3 in and a length of 12
ft 9 in is found. The carbon steel vessel has a total bare module cost of $74,700. See page 181
for the specification sheet and page 298 of the appendix for a sample sizing and costing
calculation.
P-804 is a centrifugal pump that pressurizes reflux to the top stage pressure. The pressure is
increased from 25 psi to 27 psi at 133F and 49.73 lb/ft3, requiring 0.14 Hp at 124 gpm. The
pump requires 0.2 kW of electricity to generate 8.5 ft of head. The pump operates at 3600 rpm,
is a vertical split case, and is constructed out of stainless steel. The electric drive is a totally
enclosed, fan-cooled drive. The total bare module cost for the pump and drive is $13,700. See
calculation.
111

P-802 is a centrifugal pump that circulates the column bottoms through the reboiler. The
pressure is increased from 29 psi to 34 psi at 247 F and 56.02 lb/ft^3, requiring 1.5 Hp at 489
gpm. The pump requires 15 kW of electricity to generate 13 ft of head. The pump operates at
3600 rpm, is a vertical split case, and is constructed out of stainless steel. The electric drive is a
totally enclosed, fan-cooled drive. The total bare module cost for the pump and drive is $15,550.
H-803 is a kettle reboiler that returns vapor to the distillation column. The olefins on the
tube side are vaporized at 246F. 80,000 lb/hr of 40 psi steam condenses on the shell side of the
exchanger. The overall heat transfer coefficient is predicted to be 701.8 BTU/hr-sqft-R, which
leads to a total heat transfer area of 9,586 sqft. The total heat duty is 76.3 MMBTU/hr. The total
bare module cost of the exchanger system is $540,600 with an annual utility cost of $1,900,000
for steam before integration. See page 215 for the specification sheet and page 278 of the
P-803 is a centrifugal pump that sends the bottoms to the DME separation section to be used as
absorbent. The pressure is increased from 29 psi to 90 psi at 248F and 55.68 lb/ft3, requiring
19.1 Hp at 368 gpm. The pump requires 14 kW of electricity to generate 158 ft of head. The
pump operates at 3,600 rpm, is a vertical split case, and is constructed out of stainless steel. The
112

Compressor C-901
C-901 compresses the olefin distillate. The compressor increases the streams pressure
from 25 psi to 65 psi and the temperature increases from 133F to 211F. It is made from carbon
steel and, with an efficiency of 0.7, requires 2177 hp. The compressor is powered using an
electric motor drive that consumes 1,623 kW. The bare module cost of the compressor is
$1,971,000. See page 130 for the specification sheet and page 283 of the appendix for a sample
H-901 is a fixed-head shell and tube that cools and condenses the hot compressor outlet.
The olefins on the shell side are cooled from 210F to 110F. 550,000 lb/hr of cooling water
passes through the tube side of the exchanger. The overall heat transfer coefficient is predicted to
be 127.2 BTU/hr-sqft-R, which leads to a total heat transfer area of 4,670 sqft. The total heat
duty is 20.9 MMBTU/hr. There are 758 tubes that are 16 ft. long and have an OD of 0.75 in. The
shell has an OD of 30.875 in. with a baffle spacing of 23.5 in. Both the tubes and shell are
Flash Vessel V-901
V-901 is a horizontal, adiabatic, pressure vessel that separates the condensed liquid from
the cooled gas. The equilibrium occurs at 59 psi and 108F, with a vapor fraction of 0.64. The
flow rate into the vessel is 166,600 lb/hr. A liquid residence time of five minutes at half height
leads to a vessel length of 12 ft 6 in and a diameter of 4 ft 3 in. The bare module cost of the
vessel $74,900. See page 182 for the specification sheet and page 298 of the appendix for a
113
Compressor C-902
C-902 further compresses the olefin distillate. The compressor increases the streams
pressure from 59 psi to 150 psi and the temperature increases from 108F to 185.7F. It is made
from carbon steel and, with an efficiency of 0.7, requires 1,312 HP. The compressor is powered
using an electric motor drive that consumes 978 kW. The bare module cost of the compressor is
H-902 is a fixed-head shell and tube that cools and condenses the hot outlet from the
second compressor. The olefins on the shell side are cooled from 190F to 110F. 300,000 lb/hr
of cooling water passes through the tube side of the exchanger. The overall heat transfer
coefficient is predicted to be 120.2 BTU/hr-sqft-R, which leads to a total heat transfer area of
3700 sqft. The total heat duty is 11.3 MMBTU/hr. There are 959 tubes that are 20 ft. long and
have an OD of 0.75 in. The shell has an OD of 33.875 in. with a baffle spacing of 23.5 in. Both
the tubes and shell are constructed from carbon steel. All calculations were performed using
Aspen Plus Exchanger Design and Rating. The total bare module cost of the exchanger system is
$190,500 with an annual utility cost of $21,000 for cooling water. See page 218 for the
specification sheet.
Flash Vessel V-902
V-902 is a horizontal, adiabatic, pressure vessel that separates the condensed liquid from
the cooled second compressor outlet. The equilibrium occurs at 145 psi and 109F, with a vapor
fraction of 0.57. The flow rate into the vessel is 107,800 lb/hr. A liquid residence time of five
minutes at half height leads to a vessel length of 11 ft 6 in and a diameter of 4 ft. The bare
module cost of the vessel $74,100. See page 183 for the specification sheet and page 298 of the
Compressor C-903
C-903 is the final compressor in the sequence. The compressor increases the streams
pressure from 145 psi to 270 psi and the temperature increases from 109F to 167F. It is made
114
from carbon steel and, with an efficiency of 0.7, requires 517 HP. The compressor is powered
using an electric motor drive that consumes 386 kW. The bare module cost of the compressor is
H-903 is a fixed-head shell and tube that cools and condenses the hot outlet from the final
compressor. The olefins on the shell side are cooled from 170F to 100F. 225,000 lb/hr of
cooling water passes through the tube side of the exchanger. The overall heat transfer coefficient
is predicted to be 111.3 BTU/hr-sqft-R, which leads to a total heat transfer area of 2,982 sqft.
of 0.75 in. The shell has an OD of 29.875 in. with a baffle spacing of 9.25 in. Both the tubes and
shell are constructed from carbon steel. All calculations were performed using Aspen Plus
Exchanger Design and Rating. The total bare module cost of the exchanger system is $165,000
with an annual utility cost of $16,000 for cooling water. See page 219 for the specification sheet.
H-904 is a fixed-head shell and tube that condenses the olefin product. The olefins on the
tube side are cooled from 100F to 47.5F. 25,000 lb/hr of liquid propylene is evaporated on the
shell side of the exchanger. The overall heat transfer coefficient is predicted to be 248.1 BTU/hrsqft-R, which leads to a total heat transfer area of 264 sqft. The total heat duty is 3.91
MMBTU/hr. There are 68 tubes that are 20 ft. long and have an OD of 0.75 in. The shell has an
OD of 10.75 in. with a baffle spacing of 20.25 in. Both the tubes and shell are constructed from
carbon steel. All calculations were performed using Aspen Plus Exchanger Design and Rating.
The total bare module cost of the exchanger system is $165,000. See page 220 for the
P-901 is a centrifugal pump that compresses the first liquid condensate to the distillation
pressure. The pressure is increased from 60 psi to 558 psi at 110F and 39.92 lb/ft3, requiring 88
HP at 184 gpm. The pump requires 65 kW of electricity to generate 1,800 ft of head. The pump
115
operates at 3,600 rpm, is a horizontal split case, and is constructed out of stainless steel. The
and drive is $120,700. See page 158 for the specification sheet and page 279 of the appendix for
a sample sizing and costing calculation.
P-902 is a centrifugal pump that compresses the second liquid condensate to the
distillation pressure. The pressure is increased from 145 psi to 558 psi at 110F and 34.297
lb/ft3, requiring 71 HP at 180 gpm. The pump requires 53 kW of electricity to generate 1,733 ft
of head. The pump operates at 3,600 rpm, is a horizontal split case, and is constructed out of
stainless steel. The electric drive is a totally enclosed, fan-cooled drive. The total bare module
cost for the pump and drive is $116,400. See page 159 for the specification sheet and page 279
of the appendix for a sample sizing and costing calculation.
P-903 is a centrifugal pump that compresses the final liquid condensate to the distillation
pressure. The pressure is increased from 262 psi to 558 psi at 48F and 33.27 lb/ft3, requiring 60
HP at 219 gpm. The pump requires 45 kW of electricity to generate 1280 ft of head. The pump
operates at 3600 rpm, is a horizontal split case, and is constructed out of stainless steel. The
116

H-1001 is a fixed-head shell and tube that preheats the distillation column feed with the
bottoms. The feed on the shell side is heated from 91F to 180F. The bottoms is cooled from
224F to 180F. The overall heat transfer coefficient is predicted to be 214.3 BTU/hr-sqft-R,
which leads to a total heat transfer area of 949 sqft. The total heat duty is 12.1 MMBTU/hr.
There are 308 tubes that are 16 ft. long and have an OD of 0.75 in. The shell has an OD of 20 in.
with a baffle spacing of 22 in. Both the tubes and shell are constructed from carbon steel. All
module cost of the exchanger system is $92,400. See page 221 for the specification sheet.
of 4 ft, and 3 ft at the inlet, a total height of 63 ft is required. The column has a diameter of 13 ft.
The distillate comes off as a liquid stream at 193F and 525 psi. The bottoms of the column
comes off at a temperature of 321F. The bare module cost of this column, including internals, is
H-1002 is a fixed-head shell and tube that cools the distillate vapor with cooling water.
The distillate is cooled from 150F to 100F on the shell side. 400,000 lb/hr of cooling water is
passed through the tube side. The overall heat transfer coefficient is predicted to be 253.8
BTU/hr-sqft-R, which leads to a total heat transfer area of 4,010 sqft. The total heat duty is 14.8
The total bare module cost of the exchanger system is $283,200 with an annual utility cost of
$29,000 for cooling water. See page 222 for the specification sheet.
117

H-1003 is a fixed-head shell and tube that cools the distillate vapor with chilled water.
The distillate is cooled from 100F to 94F on the shell side. 30,000 lb/hr of chilled water is
passed through the tube side. The overall heat transfer coefficient is predicted to be 254.8
BTU/hr-sqft-R, which leads to a total heat transfer area of 268 sqft. The total heat duty is 9.1
The total bare module cost of the exchanger system is $47,100 with an annual utility cost of
$22,000 for chilled water. See page 223 for the specification sheet.
V-1001 is a horizontal pressure vessel used to store reflux for the distillation column.
The volumetric flow rate to the vessel is 4,275 cuft/hr at a pressure of 523 psi. Using a residence
time of five minutes at half full and an aspect ratio of three, a diameter of 6 ft 9 in and a length of
20 ft is found. The carbon steel vessel has a total bare module cost of $285,500. See page 184
calculation.
P-1002 is a centrifugal pump that returns the liquid to the distillation column. The
pressure is increased from 523 psi to 527 psi at 94 F and 28.31 lb/ft^3, requiring 2 Hp at 528
3600 rpm, is a vertical split case, and is constructed out of stainless steel. The electric drive is a
118

P-1003 is a centrifugal pump that pressurizes the propylene and ethylene distillate to the
pressure of the following column. The pressure is increased from 525 psi to 670 psi at 94F and
28.02 lb/ft3, requiring 19.6 HP at 232 gpm. The pump requires 23 kW of electricity to generate
745 ft of head. The pump operates at 3600 rpm, is a horizontal split case, and is constructed out
of stainless steel. The electric drive is a totally enclosed, fan-cooled drive. The total bare module
cost for the pump and drive is $43,000. See page 163 for the specification sheet and page 279 of
the appendix for a sample sizing and costing calculation.
P-1001 is a centrifugal pump that circulates liquid through the reboiler. The pressure is
increased from 531 psi to 535 psi at 304F and 28.96 lb/ft3, requiring 7 HP at 2850 gpm. The
pump requires 6 kW of electricity to generate 20 ft of head. The pump operates at 1800 rpm, is a
vertical split case, and is constructed out of stainless steel. The electric drive is a totally enclosed,
fan-cooled drive. The total bare module cost for the pump and drive is $33,400. See page 161
calculation.
H-1004 is kettle reboiler that returns vapor to the distillation column. The bottoms is
heated from 304F to 328F on the tube side. 15,000 lb/hr of 245 psi steam is condensed on the
leads to a total heat transfer area of 738 sqft. The total heat duty is 11.0 MMBTU/hr. The total
bare module cost of the exchanger system is $47,100 with an annual utility cost of $700,000 for
steam before integration. See page 224 for the specification sheet and page 278 of the appendix
of 4 ft, and 3 ft at the inlet, a total height of 61 ft is required. The column has a diameter of 6 ft 6
119
in. The distillate comes off as a liquid stream at 29F and 650 psi. The bottoms of the column
come off at a temperature of 193F. The bare module cost of this column, including internals, is
H-1006 is a kettle reboiler that returns vapor to the distillation column. The bottoms is
heated from 187F to 194F on the tube side. 6,000 lb/hr of 20 psi steam is condensed on the
leads to a total heat transfer area of 553 sqft. The total heat duty is 4.02 MMBTU/hr. The total
bare module cost of the exchanger system is $82,800 with an annual utility cost of $140,000 for
steam. See page 226 for the specification sheet and page 278 of the appendix for a sample sizing
and costing calculation.
P-1006 is a centrifugal pump that circulates liquid through the reboiler. The pressure is
increased from 654 psi to 658 psi at 187F and 21.05 lb/ft3, requiring 2 HP at 617 gpm. The
pump requires 1.5 kW of electricity to generate 27 ft of head. The pump operates at 3,600 rpm,
calculation.
H-1005 is a fixed-head shell and tube that returns condensate to the distillation column.
The distillate is cooled from 45F to 11F on the tube side.
35,000 lb/hr of refrigerated
propylene is evaporated on the shell side. The overall heat transfer coefficient is predicted to be
386.7 BTU/hr-sqft-R, which leads to a total heat transfer area of 359 sqft. The total heat duty is
has an OD of 16 in. with a baffle spacing of 13.25 in. Both the tubes and shell are constructed
from carbon steel. All calculations were performed using Aspen Plus Exchanger Design and
120
Rating. The total bare module cost of the exchanger system is $77,100. See page 225 for the
P-1004 is a centrifugal pump that circulates distillate back to the column. The pressure is
increased from 650 psi to 652 psi at 29F and 22.16 lb/ft3, requiring 0.25 HP at 116 gpm. The
pump requires 0.18kW of electricity to generate 13 ft of head. The pump operates at 3,600 rpm,
calculation.
V-1002 is a horizontal pressure vessel used to store reflux for the distillation column.
The volumetric flow rate to the vessel is 1,025 cuft/hr at a pressure of 650 psi. Using a residence
time of five minutes at half full and an aspect ratio of three, a diameter of 6 ft and a length of 18
ft 6 in is found. The carbon steel vessel has a total bare module cost of $265,000. See page 185
calculation.
P-1005 is a centrifugal pump that sends the ethylene product to shift storage. The
pressure is increased from 650 psi to 700 psi at 30F and 22.08 lb/ft3, requiring 4 HP at 58 gpm.
The pump requires 3 kW of electricity to generate 324 ft of head. The pump operates at 3,600
rpm, is a vertical split case, and is constructed out of stainless steel. The electric drive is a totally
calculation.
121

P-1006 is a centrifugal pump that sends the propylene product to shift storage. The
pressure is increased from 655 psi to 705 psi at 193F and 19.46 lb/ft3, requiring 12 HP at 268
3,600 rpm, is a vertical split case, and is constructed out of stainless steel. The electric drive is a
Pressure Vessel V-1003 - Not Shown
A pressure vessel is required for shift storage of the ethylene product. Approximately
468 cuft/hr of ethylene are produced and an eight hour shift is presumed. Assuming the vessel
would operate up to 75% full and using an aspect ratio of 3, a diameter of 12 ft 6 in and a length
of 38 ft 6 in is required. The vessel is horizontal and operates at a pressure of 700 psi. The total
bare module cost is $1,484,000. See page 186 for the specification sheet and page 298 of the
Pressure Vessel V-1004 Not Shown
A pressure vessel is required for shift storage of the propylene product. Approximately
2152 cuft/hr of propylene are produced and an eight hour shift is presumed. Assuming the vessel
would operate up to 75% full and using an aspect ratio of 3, a diameter of 21 ft 3 in and a length
of 64 ft is required. The vessel is horizontal and operates at a pressure of 70 psi. The total bare
module cost is $2,103,000. See page 187 for the specification sheet and page 298 of the appendix
Heat Exchanger H-1007 Not Shown
A heat exchanger is needed to condense compressed propylene in the vapor-compression
refrigeration cycle. The vapor is cooled from 192F to 100F on the shell side. 150,000 lb/hr of
cooling water passes through the tube side. The overall heat transfer coefficient is predicted to be
120.0 BTU/hr-sqft-R, which leads to a total heat transfer area of 2,028 sqft. The total heat duty is
122
has an OD of 24.875 in. with a baffle spacing of 10.25 in. Both the tubes and shell are
Design and Rating. The total bare module cost of the exchanger system is $123,000. See page
227 for the specification sheet.
Compressor C-1001 Not Shown
C-1001 is the first compressor in the propylene vapor-compression refrigeration cycle.
The compressor increases the streams pressure from 48 psi to 125 psi and the temperature
increases from -1F to 87F. It is made from carbon steel and, with an efficiency of 0.7, requires
423 HP. The compressor is powered using an electric motor drive that consumes 316 kW. The
bare module cost of the compressor is $535,500.
Compressor C-1002 Not Shown
C-1002 is the second compressor in the propylene vapor-compression refrigeration cycle.
The compressor increases the streams pressure from 125 psi to 375 psi and the temperature
increases from 87F to 193F. It is made from carbon steel and, with an efficiency of 0.7,
requires 580 HP. The compressor is powered using an electric motor drive that consumes 433
kW. The bare module cost of the compressor is $684,000. See page 134 for the specification
sheet and page 283 of the appendix for a sample sizing and costing calculation.
123
SPECIFICATION
SHEETS
124
11.
Specification Sheets
Compressor
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
Item
3-Stage Compressor for Air Separation Unit
Item No.
C-201
No. Required
1
To pressurize air inlet to air separation unit
Continuous
Performance of Unit
Inlet
Outlet
S-201
S-202
283,335
283,335
77
180
15
85
Type
Material
Power
Cooling Duty
Pressure change
Drive Type
Multi-Stage, Centrifugal
Carbon Steel
12,257 hp
24,172,500 Btu/hr
70
psi
Electric
Power supplied by gas turbine from HRSG process

Cooling Water, 1616 gpm, $57,434/yr
$3,653,083
Cost Information: Purchase Cost:
Bare Module Cost:
$7,854,128
Utilities:
Comments:
125
Compressor
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
Item
3-Stage Oxygen Compressor post-ASU
Item No.
C-202
No. Required
1
To pressurize oxygen outlet from air separation unit
Continuous
Performance of Unit
Inlet
Outlet
S-204
S-205
56,667
56,667
75
180
18
450
Type
Material
Power
Cooling Duty
Pressure change
Drive Type
Multi-Stage, Centrifugal
Carbon Steel
4,374
hp
9,877,183
Btu/hr
432
psi
Electric
Utilities:
Electricity at 3261.7 kW
Cooling Water, 659 gpm, $23,487/yr
$1,601,973
Bare Module Cost: $3,444,242
Comments:
126
Steam Turbine
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
Item
Steam Turbine
Item No.
C-203
No. Required
1
To generate electricity from high pressure steam exiting H-201
Continuous
Performance of Unit
Inlet
Outlet
S-225
S-226
120,000
120,000
1400
854
1798
299
Type
Material
Power Produced
Pressure change
Elec. Generation
Gas Turbine
NA
12,500
1499
9321.25
hp
psi
kW
Utilities:
Effluent of steam to be used elsewhere in process: 120,000 lb/hr at 854F

and 299 psia.
$1,601,973
Bare Module Cost: $3,444,242
Comments:
Power produced used to run air separation unit feed compressor (C-201)
127
Compressor
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
Item
Centrifugal Compressor with Electric Motor Drive
Item No.
C-401
No. Required
1
To pressurize the syngas recycle stream prior to entering the reactor
Continuous
Performance of Unit
Inlet
Outlet
FROM-REC
S-402
312,814
312,814
172
255
200
295
Type
Material
Flow Rate
Power
Cooling Duty
Pressure change
Drive Type
Utilities:
Electricity at 4931 kW
Cost Information:
Purchase Cost:
Bare Module Cost:
Single Stage, Centrifugal

Carbon Steel
150,000
scfm
6,613
hp
0
Btu/hr
70
psi
Electric
$2,230,000
$4,790,000
Comments:
128
Compressor
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
Item
Item No.
C-801
No. Required
1
To move the vapor reactor products to the distillation column
Continuous
Performance of Unit
Inlet
Outlet
S-804
S-805
128,000
128,000
138
235
18
55
Type
Material
Flow Rate
Power
Cooling Duty
Pressure change
Drive Type
Utilities:
Cost Information:
Purchase Cost:
Bare Module Cost:

Carbon Steel
17,464
scfm
2,177
hp
0
Btu/hr
37
psi
Electric
$916,700
$1,971,100
Comments:
129
Compressor
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
Item
Item No.
C-901
No. Required
1
First stage of olefin compression train
Continuous
Performance of Unit
Inlet
Outlet
S-809
S-901
166,700
166,700
133
210
25
65
Type
Material
Flow Rate
Power
Cooling Duty
Pressure change
Drive Type
Utilities:
Cost Information:
Purchase Cost:
Bare Module Cost:

Carbon Steel
21,405
scfm
2177
hp
0
Btu/hr
37
psi
Electric
$896,500
$1,927,400
Comments:
130
Compressor
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
Item
Item No.
C-902
No. Required
1
Second stage of olefin compression train
Continuous
Performance of Unit
Inlet
Outlet
S-903
S-906
107,800
107,800
108
186
59
150
Type
Material
Flow Rate
Power
Cooling Duty
Pressure change
Drive Type
Utilities:
Cost Information:
Purchase Cost:
Bare Module Cost:

Carbon Steel
14,326
scfm
1312
hp
0
Btu/hr
91
psi
Electric
$610,500
$1,312,400
Comments:
131
Compressor
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
Item
Item No.
C-903
No. Required
1
Final stage of olefin compression train
Continuous
Performance of Unit
Inlet
Outlet
S-908
S-911
58,400
58,400
109
167
145
270
Type
Material
Flow Rate
Power
Cooling Duty
Pressure change
Drive Type
Utilities:
Cost Information:
Purchase Cost:
Bare Module Cost:

Carbon Steel
8,540
scfm
517
hp
0
Btu/hr
125
psi
Electric
$290,200
$624,000
Comments:
132
Compressor
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
Item
Item No.
C-1001
No. Required
1
First compressor in vapor-compression refrigeration cycle
Continuous
Performance of Unit
Inlet
Outlet
Refrig. Propylene
Refrig. Propylene
58,400
58,400
1
87
48
125
Type
Material
Flow Rate
Power
Cooling Duty
Pressure change
Drive Type
Utilities:
Cost Information:
Purchase Cost:
Bare Module Cost:

Carbon Steel
5,260
scfm
423
hp
0
Btu/hr
91
psi
Electric
$249,100
$535,500
Comments:
133
Compressor
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
Item
Item No.
C-1002
No. Required
1
Second compressor in vapor-compression refrigeration cycle
Continuous
Performance of Unit
Inlet
Outlet
Refrig. Propylene
Refrig. Propylene
58,400
58,400
87
193
125
375
Type
Material
Flow Rate
Power
Cooling Duty
Pressure change
Drive Type
Utilities:
Cost Information:
Purchase Cost:
Bare Module Cost:

Carbon Steel
5,260
scfm
580
hp
0
Btu/hr
250
psi
Electric
$318,100
$684,000
Comments:
134
Distillation Column
Identification:
Function:
Operation:
Stream
Flow Rate [lb/hr]
Temperature [F]
Pressure [psi]
Phase
Composition
[mass frac]
H2
N2
CO
CO2
CH4
H2O
CH4O
C2H6O-01
Item
Item No.
No. Required
Distillation Column
D-501
1
To separate the DME and methanol products from water and CO2
Continuous
Performance of Unit
Feed
S-506
Overhead
S-507
Side-Draw
PRODUCT
Bottoms
S-508
414,074
20,000
102,000
292,074
170
59
151
385
230
205
206
212
Liquid
Vapor
Liquid
Liquid
0.000
0.000
0.000
0.000
0.000
0.010
0.000
0.000
0.000
0.001
0.000
0.000
0.015
0.277
0.005
0.000
0.013
0.269
0.002
0.000
0.706
0.000
0.022
0.993
0.026
0.000
0.104
0.000
0.240
0.444
0.867
0.007
Design Specifications
Column Type
Height [ft]
Inside Diameter [ft]
Wall Thickness [in]
Material
Design Pressure [psig]
Distillation
60
10
1.3
Carbon Steel
250
No. of Trays
Tray Efficiency
Tray Type
Tray Spacing [ft]
25
0.63
Sieve
2
Utilities/Materials
Cost Information
Purchase Cost per unit
Bare Module Cost
Total Bare Module Cost
$298,000
$1,240,000
$1,240,000
135
Distillation Column
Identification:
Function:
Operation:
Stream
Flow Rate [lb/hr]
Temperature [F]
Pressure [psi]
Phase
Composition
[mass frac main comp.]
Water
Propylene
Ethylene
Item
Item No.
No. Required
Distillation Column
D-801
1
To separate the hydrocarbon products from water

Continuous
Performance of Unit
Feed
S-808
Overhead
S-809
Bottoms
S-810
331,100
166,700
164,500
160
133
248
27
25
29
Liquid
Vapor
Liquid
0.5
0.03
0.98
0.12
0.25
0.03
0.06
*See PFD for other components
Column Type
Height [ft]
Wall Thickness [in]
Material
Distillation
61
7 6
0.375
Carbon Steel
38
No. of Trays
Tray Efficiency
Tray Type
Tray Spacing [ft]
24
0.27
Sieve
2
Utilities/Materials
Cost Information
Bare Module Cost
$185,100
$770,000
$770,000
136
Distillation Column
Identification:
Function:
Operation:
Stream
Flow Rate [lb/hr]
Temperature [F]
Pressure [psi]
Phase
Composition
Ethylene
Propylene
Butane
Item
Item No.
No. Required
Distillation Column
D-1001
1
Separate olefin products from hydrocarbon byproducts

Continuous
Performance of Unit
Feed
S-1001
Overhead
S-1002
Bottoms
S-1004
166,700
50,000
116,600
180
94
321
529
525
530
Liquid
Liquid
Liquid
0.06
0.20
0.25
0.80
0.02
0.20
0.00
0.30
Column Type
Height [ft]
Wall Thickness [in]
Material
Distillation
63
13
3.625
Carbon Steel
596
No. of Trays
Tray Efficiency
Tray Type
Tray Spacing [ft]
25
0.74
Sieve
2
Utilities/Materials
Cost Information
Bare Module Cost
$926,700
$926,700
$3,855,000
137
Distillation Column
Identification:
Function:
Operation:
Stream
Flow Rate [lb/hr]
Temperature [F]
Pressure [psi]
Phase
Composition
Ethylene
Propylene
Item
Item No.
No. Required
Distillation Column
D-1002
1
Separate ethylene from propylene

Continuous
Performance of Unit
Feed
S-1003
Overhead
S-1007
Bottoms
S-1006
50,000
9,800
40,200
96
29
186
653
650
654
Liquid
Liquid
Liquid
0.2
0.93
0.02
0.80
0.01
0.98
Column Type
Height [ft]
Wall Thickness [in]
Material
Distillation
61
6 6
2.375
Carbon Steel
729
No. of Trays
Tray Efficiency
Tray Type
Tray Spacing [ft]
24
0.67
Sieve
2
Utilities/Materials
Cost Information
Bare Module Cost
$367,800
$367,800
$1,530,100
138
Absorption Tower
Identification:
Function:
Operation:
Item
MEA-CO 2 Absorption Tower
Item No.
T-301
No. Required
1
To absorb carbon dioxide from synthesis gas stream
Continuous
Performance of Unit
Stream
Flow Rate [lb/hr]
Temperature [F]
Pressure [psi]
Phase
Composition
[mole frac]
MEA
H2O
H2
CO2
CO
CH4
N2
MEA+
MEACOOHCO3
Feed
Inlet 2
Inlet 3
Inlet 4
Overhead
Bottoms
Draw-off
S-214
S-302
S-304
S-307
S-305
S-309
NA
341,103
1,332,541
2,637
7,037
206,792
1,476,530
100
100
125
125
204
194
300
298
297
297
300
300
Vapor
Liquid
Liquid
Liquid
Vapor
Liquid
0.000
0.152
0.020
0.000
0.000
0.019
0.000
0.778
0.980
0.994
0.030
0.770
0.520
0.000
0.000
0.000
0.604
0.000
0.210
0.000
0.000
0.000
0.050
0.002
0.245
0.000
0.000
0.000
0.286
0.000
0.025
0.000
0.000
0.000
0.030
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.036
0.000
0.003
0.000
0.105
0.000
0.034
0.000
0.000
0.000
0.099
0.000
0.000
0.000
0.003
0.000
0.005
1.000
1.000
1.000
1.000
1.000
1.000
0.000
Column Type
Height [ft]
Inside Diameter
Thickness
Material
Absorption
27 ft
15 ft, 11 in
2.66 in
Carbon Steel
375.1
Number of Stages
Reflux Ratio
Tray Spacing [ft]
Packing
Packing Height [ft]
HETP
4
NA
NA
Koch-Glitsch BX
15
3 ft, 9 in
Utilities/Materials
Cost Information
Bare Module Cost
$1,213,975
$5,050,136
$5,050,136
139
Stripping Tower
Identification:
Function:
Operation:
Item
MEA-CO 2 Stripping Tower
Item No.
T-302
No. Required
1
To strip carbon dioxide from MEA stream to be recycled
Continuous
Performance of Unit
Stream
Flow Rate [lb/hr]
Temperature [F]
Pressure [psi]
Phase
Composition
[mole frac]
MEA
H2O
H2
CO2
CO
CH4
N2
MEA+
MEACOOHCO3
Feed
Inlet 2
Inlet 3
Inlet 4
Overhead
Bottoms
Draw-off
S-311
NA
NA
NA
S-314
S-312
NA
1,476,530
200,000
1,276,530
243
249
290
80
43
43
Liquid
Vapor
Liquid
0.040
0.002
0.164
0.764
0.482
0.761
0.000
0.000
0.000
0.014
0.516
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.092
0.000
0.038
0.088
0.000
0.036
0.002
0.000
0.001
1.000
1.000
1.000
0.000
0.000
0.000
0.000
Column Type
Height
Inside Diameter
Thickness
Material
Stripping
27 ft
15 ft, 10 in
0.64 in
Carbon Steel
77.25
Number of Stages
Reflux Ratio
Tray Spacing [ft]
Packing
Packing Height [ft]
HETP
8
NA
NA
Koch-Glitsch BX
15
2 ft, 2 in
Utilities/Materials
Steam (reboiler)
199,376,985 Btu/hr,
Cost Information
Bare Module Cost
$931,055
$3,873,189
$3,873,189
140
Absorption Tower
Identification:
Function:
Operation:
Item
Absorption Tower
Item No.
T-501
No. Required
1
To absorb DME out of the unreacted syngas stream
Continuous
Performance of Unit
Inlet 1
Stream
Flow Rate [lb/hr]
Temperature [F]
Pressure [psi]
Phase
Composition
[mass frac]
H2
N2
CO
CO2
CH4
H2O
CH4O
C2H6O-01
Inlet 2
Overhead
Bottoms
S-501
S-516
S-502
S-504
418,421
252,213
323,086
347,550
167
110
172
172
230
205
200
207
Vapor
Liquid
Vapor
Liquid
0.070
0.091
0.000
0.053
0.068
0.000
0.003
0.004
0.000
0.252
0.311
0.014
0.165
0.200
0.013
0.025
0.042
0.717
0.016
0.000
0.020
0.415
0.284
0.235
Column Type
Height [ft]
Inside Diameter
Wall Thickness [in]
Material
Absorption
44
9 ft 8 in
1.2
Carbon Steel
250
Theoretical Stages
Stage Efficiency
Packing Type
Packing Height [ft]
15
0.7
CY700 Wire Gauze
30 ft
Utilities/Materials
Cost Information
Bare Module Cost
$269,000
$1,120,000
$1,120,000
141
Reciprocating Plunger Pump

Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
Utilities:
Item
Reciprocating Plunger Pump and Electric Motor
Item No.
P-201
No. Required
1
To pressurize water inlet to high pressure steam generation section
Continuous
Performance of Unit
Inlet
Outlet
S-220
S-221
120,000
120,000
77
80
15
1800
Type
Reciprocating Plunger
Material
Ductile Iron
Flow Rate
240.3
gpm
Power
423
hp
Head
4130
ft
Pressure change
1785
psi
Drive Type
Electric
Drive Speed
1800
rpm

$160,656
Bare Module Cost: $530,165
Comments:
142
Centrifugal Pump
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
Utilities:
Item
Centrifugal Pump and Electric Motor
Item No.
P-202
No. Required
1
To pressurize water inlet to low pressure steam generation section
Continuous
Performance of Unit
Inlet
Outlet
S-215
S-216
1,332,541
1,332,541
77
78
15
230
Type
Centrifugal
Material
Carbon Steel
Flow Rate
130.2
Power
32
Head
498
Pressure change
215
Drive Type
Electric
Drive Speed
1800
gpm
hp
ft
psi
rpm

$9,232
Comments:
143
Centrifugal Pump
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
Utilities:
Item
Item No.
P-301
No. Required
1
To repressurize MEA recycle stream for reintroduction to absorption column
Continuous
Performance of Unit
Inlet
Outlet
S-316
S-319
1,332,541
1,332,541
215
216
43
300
Type
Centrifugal
Material
Carbon Steel
Flow Rate
2900
Power
558
Head
646
Pressure change
257
Drive Type
Electric
Drive Speed
1800
gpm
hp
ft
psi
rpm

$44,212
Comments:
144
Centrifugal Pump
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
Utilities:
Cost Information:
Item
Item No.
P-501
No. Required
1
To draw liquid off of V-501
Continuous
Performance of Unit
Inlet
Outlet
V-501 Liquid
S-503
66,524
66,524
167
167
230
235
Type
Material
Flow Rate
Power
Head
Pressure change
Drive Type
Drive Speed
Purchase Cost:
Bare Module Cost:
Centrifugal
Stainless Steel
161
0.67
14
5
Electric
3600
gpm
hp
ft
psi
rpm
$3,600
$11,800
Comments:
145
Centrifugal Pump
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
Utilities:
Cost Information:
Item
Item No.
P-502
No. Required
1
To draw the liquid bottoms off T-501
Continuous
Performance of Unit
Inlet
Outlet
D-501 Bottoms
S-504
347,500
347,501
171
171
202
207
Type
Material
Flow Rate
Power
Head
Pressure change
Drive Type
Drive Speed
Purchase Cost:
Bare Module Cost:
Centrifugal
Stainless Steel
824
3.43
14
5
Electric
3600
gpm
hp
ft
psi
rpm
$4,600
$15,100
Comments:
146
Centrifugal Pump
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
Utilities:
Cost Information:
Item
Item No.
P-503
No. Required
1
To pressurize the stream prior to enteirng D-501 for separation
Continuous
Performance of Unit
Inlet
Outlet
S-505
S-506
414,074
414,075
170
170
202
230
Type
Material
Flow Rate
Power
Head
Pressure change
Drive Type
Drive Speed
Purchase Cost:
Bare Module Cost:
Centrifugal
Stainless Steel
985
23.1
78
28.2
Electric
3600
gpm
hp
ft
psi
rpm
$10,100
$33,300
Comments:
147
Centrifugal Pump
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
Utilities:
Cost Information:
Item
Item No.
P-504
No. Required
1
Reflux pump for D-501
Continuous
Performance of Unit
Inlet
Outlet
Bottoms of V-502
Reflux to D-501
600,000
600,000
58.5
58.5
205
210
Type
Material
Flow Rate
Power
Head
Pressure change
Drive Type
Drive Speed
Purchase Cost:
Bare Module Cost:
Centrifugal
Stainless Steel
1740
4.98
12
5
Electric
3600
gpm
hp
ft
psi
rpm
$7,700
$25,200
Comments:
148
Centrifugal Pump
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
Utilities:
Cost Information:
Item
Item No.
P-505
No. Required
1
To draw the liquid bottoms off of D-501
Continuous
Performance of Unit
Inlet
Outlet
Bottoms of D-501
S-508
292,074
292,074
385
385
207
212
Type
Material
Flow Rate
Power
Head
Pressure change
Drive Type
Drive Speed
Purchase Cost:
Bare Module Cost:
Centrifugal
Stainless Steel
724
2.83
14
5
Electric
3600
gpm
hp
ft
psi
rpm
$4,500
$14,700
Comments:
149
Centrifugal Pump
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
Utilities:
Cost Information:
Item
Item No.
P-506
No. Required
1
To draw liquid off of V-503
Continuous
Performance of Unit
Inlet
Outlet
V-503 Liquid
S-512
148,555
148,555
281
281
50
55
Type
Material
Flow Rate
Power
Head
Pressure change
Drive Type
Drive Speed
Purchase Cost:
Bare Module Cost:
Centrifugal
Stainless Steel
339
1.41
13
5
Electric
3600
gpm
hp
ft
psi
rpm
$6,400
$21,100
Comments:
150
Centrifugal Pump
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
Utilities:
Cost Information:
Item
Item No.
P-507
No. Required
1
Pressurizes the water recycle prior to entering T-501
Continuous
Performance of Unit
Inlet
Outlet
S-515
S-516
252,214
252,214
110
110
40
205
Type
Material
Flow Rate
Power
Head
Pressure change
Drive Type
Drive Speed
Purchase Cost:
Bare Module Cost:
Centrifugal
Stainless Steel
516
81.7
449
190
Electric
3600
gpm
hp
ft
psi
rpm
$15,500
$51,200
Comments:
151
Centrifugal Pump
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
Utilities:
Cost Information:
Item
Item No.
P-601
No. Required
1
To pressurize water/steam diluent
Continuous
Performance of Unit
Inlet
Outlet
S-509
S-602
80,000
80,000
384.5
385.7
207.4
500
Type
Material
Flow Rate
Power
Head
Pressure change
Drive Type
Drive Speed
Purchase Cost:
Bare Module Cost:
Centrifugal
Stainless Steel
197
55
835
292.6
Electric
3600
gpm
hp
ft
psi
rpm
$14,515
$47,900
Comments:
152
Centrifugal Pump
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
Utilities:
Cost Information:
Item
Item No.
P-602
No. Required
1
To pressurize DME/methanol feed to reactor
Continuous
Performance of Unit
Inlet
Outlet
S-601
S-607
102,000
102,000
135.8
138.3
206.2
485
Type
Material
Flow Rate
Power
Head
Pressure change
Drive Type
Drive Speed
Purchase Cost:
Bare Module Cost:
Centrifugal
Stainless Steel
324
79
1025
278.8
Electric
3600
gpm
hp
ft
psi
rpm
$18,636
$61,500
Comments:
153
Centrifugal Pump
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
Utilities:
Cost Information:
Item
Item No.
P-801
No. Required
1
To pressurize liquid feed to distillation tower
Continuous
Performance of Unit
Inlet
Outlet
S-806
S-807
203,500
203,500
138
139
18
55
Type
Material
Flow Rate
Power
Head
Pressure change
Drive Type
Drive Speed
Purchase Cost:
Bare Module Cost:
Centrifugal
Stainless Steel
470
10
100
37
Electric
3600
gpm
hp
ft
psi
rpm
$6,700
$22,200
Comments:
154
Centrifugal Pump
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
Utilities:
Cost Information:
Item
Item No.
P-802
No. Required
1
To return water to the reboiler
Continuous
Performance of Unit
Inlet
Outlet
D-801
D-801
223,800
223,800
247
248
29
34
Type
Material
Flow Rate
Power
Head
Pressure change
Drive Type
Drive Speed
Purchase Cost:
Bare Module Cost:
Centrifugal
Stainless Steel
489
1.5
13
5
Electric
3600
gpm
hp
ft
psi
rpm
$4,700
$15,550
Comments:
155
Centrifugal Pump
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
Utilities:
Cost Information:
Item
Item No.
P-803
No. Required
1
To send the distillation bottoms to Block 500
Continuous
Performance of Unit
Inlet
Outlet
S-810
S-811
164,500
164,500
247
248
29
90
Type
Material
Flow Rate
Power
Head
Pressure change
Drive Type
Drive Speed
Purchase Cost:
Bare Module Cost:
Centrifugal
Stainless Steel
368
19.1
158
61
Electric
3600
gpm
hp
ft
psi
rpm
$7,000
$23,200
Comments:
156
Centrifugal Pump
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
Utilities:
Cost Information:
Item
Item No.
P-804
No. Required
1
To return reflux to the distillation column
Continuous
Performance of Unit
Inlet
Outlet
D-801
D-801
51,400
51,400
133
133
25
27
Type
Material
Flow Rate
Power
Head
Pressure change
Drive Type
Drive Speed
Purchase Cost:
Bare Module Cost:
Centrifugal
Stainless Steel
124
0.15
8.5
2
Electric
3600
gpm
hp
ft
psi
rpm
$4,200
$13,700
Comments:
157
Centrifugal Pump
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
Utilities:
Cost Information:
Item
Item No.
P-901
No. Required
1
Compress condensate from first flash vessel
Continuous
Performance of Unit
Inlet
Outlet
S-904
S-905
58,800
58,800
110
115
60
558
Type
Material
Flow Rate
Power
Head
Pressure change
Drive Type
Drive Speed
Purchase Cost:
Bare Module Cost:
Centrifugal
Stainless Steel
184
88
1800
498
Electric
3600
gpm
hp
ft
psi
rpm
$36,600
$120,700
Comments:
158
Centrifugal Pump
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
Utilities:
Cost Information:
Item
Item No.
P-902
No. Required
1
Compress condensate from second flash vessel
Continuous
Performance of Unit
Inlet
Outlet
S-909
S-910
49,500
49,500
110
115
145
558
Type
Material
Flow Rate
Power
Head
Pressure change
Drive Type
Drive Speed
Purchase Cost:
Bare Module Cost:
Centrifugal
Stainless Steel
180
71
1733
413
Electric
3600
gpm
hp
ft
psi
rpm
$35,300
$116,400
Comments:
159
Centrifugal Pump
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
Utilities:
Cost Information:
Item
Item No.
P-903
No. Required
1
Compress condensate from refrigerated exchanger
Continuous
Performance of Unit
Inlet
Outlet
S-913
S-914
49,500
49,500
47
48
260
558
Type
Material
Flow Rate
Power
Head
Pressure change
Drive Type
Drive Speed
Purchase Cost:
Bare Module Cost:
Centrifugal
Stainless Steel
219
60
1280
298
Electric
3600
gpm
hp
ft
psi
rpm
$26,500
$87,400
Comments:
160
Centrifugal Pump
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
Utilities:
Cost Information:
Item
Item No.
P-1001
No. Required
1
Move distillation bottoms through reboiler
Continuous
Performance of Unit
Inlet
Outlet
D-1001
D-1001
673,700
673,700
304
304
531
535
Type
Material
Flow Rate
Power
Head
Pressure change
Drive Type
Drive Speed
Electricity at 6 kW
Purchase Cost:
Bare Module Cost:
Centrifugal
Stainless Steel
2850
7
20
4
Electric
1800
gpm
hp
ft
psi
rpm
$10,100
$33,400
Comments:
161
Centrifugal Pump
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
Utilities:
Cost Information:
Item
Item No.
P-1002
No. Required
1
Return liquid distillate to column
Continuous
Performance of Unit
Inlet
Outlet
D-1001
D-1001
22,700
22,700
94
94
523
527
Type
Material
Flow Rate
Power
Head
Pressure change
Drive Type
Drive Speed
Electricity at 2 kW
Purchase Cost:
Bare Module Cost:
Centrifugal
Stainless Steel
528
2
23
4
Electric
3600
gpm
hp
ft
psi
rpm
$5,150
$17,000
Comments:
162
Centrifugal Pump
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
Utilities:
Cost Information:
Item
Item No.
P-1003
No. Required
1
Pressurize the propylene/ethylene distillate
Continuous
Performance of Unit
Inlet
Outlet
S-1002
S-1003
50,000
50,000
94
96
525
653
Type
Material
Flow Rate
Power
Head
Pressure change
Drive Type
Drive Speed
Purchase Cost:
Bare Module Cost:
Centrifugal
Stainless Steel
232
19.6
745
128
Electric
3600
gpm
hp
ft
psi
rpm
$13,000
$43,000
Comments:
163
Centrifugal Pump
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
Utilities:
Cost Information:
Item
Item No.
P-1004
No. Required
1
Return liquid distillate to the column
Continuous
Performance of Unit
Inlet
Outlet
D-1002
D-1002
15,100
15,100
29
29
650
652
Type
Material
Flow Rate
Power
Head
Pressure change
Drive Type
Drive Speed
Purchase Cost:
Bare Module Cost:
Centrifugal
Stainless Steel
116
0.25
13
2
Electric
3600
gpm
hp
ft
psi
rpm
$4,000
$13,000
Comments:
164
Centrifugal Pump
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
Utilities:
Cost Information:
Item
Item No.
P-1005
No. Required
1
Send ethylene product to shift storage
Continuous
Performance of Unit
Inlet
Outlet
S-1007
S-1008
9,800
9,800
29
29
650
700
Type
Material
Flow Rate
Power
Head
Pressure change
Drive Type
Drive Speed
Electricity at 3kW
Purchase Cost:
Bare Module Cost:
Centrifugal
Stainless Steel
58
4
324
50
Electric
3600
gpm
hp
ft
psi
rpm
$4,600
$15,300
Comments:
165
Centrifugal Pump
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
Utilities:
Cost Information:
Item
Item No.
P-1006
No. Required
1
Send column bottoms through reboiler
Continuous
Performance of Unit
Inlet
Outlet
D-1002
D-1002
146,400
146,400
187
187
654
658
Type
Material
Flow Rate
Power
Head
Pressure change
Drive Type
Drive Speed
Purchase Cost:
Bare Module Cost:
Centrifugal
Stainless Steel
617
2
27
4
Electric
3600
gpm
hp
ft
psi
rpm
$5,400
$17,800
Comments:
166
Centrifugal Pump
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
Utilities:
Cost Information:
Item
Item No.
P-1007
No. Required
1
Send propylene product to shift storage
Continuous
Performance of Unit
Inlet
Outlet
S-1009
S-1010
40,300
40,300
193
193
655
705
Type
Material
Flow Rate
Power
Head
Pressure change
Drive Type
Drive Speed
Electricity at 9 kW
Purchase Cost:
Bare Module Cost:
Centrifugal
Stainless Steel
268
12
370
50
Electric
3600
gpm
hp
ft
psi
rpm
$6,700
$22,100
Comments:
167
Reactor
Item
High Pressure Fluidized Bed Gasifier
Item No.
R-20X (X = 1, 2, 3, 4)
No. Required
4
To gasify feedstock woodchips for generation of raw synthesis gas
Continuous
Performance of Unit
Identification:
Function:
Operation:
Stre am
Flow Rate [lb/hr]
Te mpe rature [F]
Pre ssure [psig]
Phase
Composition
[mole frac]
Woodchips
H2O
H2
CO2
CO
CH4
N2
Ar
O2
Feed
Inlet 2
Inlet 3
S-207
S-206
S-205
Product
S-208
240,084
46,840
56,667
343,591
154
572
180
1700
465
1265
450
465
Solid
Vapor
Vapor
Vapor
0.914
0.000
0.000
0.000
0.086
1.000
0.000
0.000
0.000
0.000
0.000
0.518
0.000
0.000
0.000
0.215
0.000
0.000
0.000
0.240
0.000
0.000
0.000
0.023
0.000
0.000
0.010
0.001
0.000
0.000
0.040
0.004
0.000
0.000
0.950
0.000
1.000
1.000
1.000
1.000
Re actor Type
Inside Diame te r
Outside Diame te r
Re fractory Brick Line r
Ne t He at Duty
Ope rating Pre ssure [psig]
Gasifier
9 feet, 5 inches
14 feet
4 feet, 7 inches
76,772,241 BTU/hr
450
Ancillary Equipme nt
Double Lockhopper Feed System
Char Combustor
Solid Cyclone Separation and Recycle
Utilities/Materials
Natural Gas
Ste am
76,722,241 BTU/hr
46840 lb/hr, 1250 psi and 572F
Cost Information
$23,193,383
$43,139,693
$172,558,771
Purchase Cost pe r unit

Bare Module Cost pe r unit
Total Bare Module Cost (all units)
Unit and Reaction Details

Feedstock enters at 15% moisture by mass from dryer exit [208,769 lb/hr dry woodchips, 31,315 lb/hr water]
Woodchips Proximate analysis: 15% moisture, 17.7% fixed content, 81.5% volatile matter, 0.5% ash.
Woodchips Ultimate analysis: 5% ash, 49.54% carbon, 6.11% hydrogen, 0.1% nitrogen, 0.02% sulfur, 43.73% oxygen
Oxygen/Wood Ratio: 0.271, Steam/Wood Ratio: 0.224
(Note - Stoichiometric Air Required for Complete Combustion: 4.58 lb Air (~1.0 lb O 2 ) / lb Biomass
1.) +393 MJ/kgmol
1.)C O2 CO2
Combustion:
2.) -242 MJ/kgmol
2.)2 H 2 O2 2 H 2O
3.)C CO2 2CO

4.)C H 2O CO H 2
Other Reactions:
5.)CO H 2O CO H 2
6.)C 2 H 2 CH 4
7.)CO2 H 2 CO H 2O
3.)
4.)
5.)
6.)
7.)
-164.9 MJ/kgmol
-122.6 MJ/kgmol
+42 MJ/kgmol
+75 MJ/kgmol
-42.3 MJ/kgmol
168
Reactor
Item
Microchannel Reactor
R-401
Identification: Item No.
No. Required
1
React syngas to form DME
Function:
Continuous
Operation:
Performance of Unit
Inlet
Outlet
Stream
S-404
S-405
Flow Rate (lb/hr)
483,004
483,004
Temperature (F)
466
536
Pressure (psi)
265
240
Composition
(mass fraction)
0.1008
H2
0.0615
0.0462
N2
0.0462
0.2775
CO
0.0028
0.2179
CO2
0.2190
0.1448
CH4
0.1448
0.0289
H2O
0.1104
0.0000
CH4O
0.0219
0.1840
C2H6O-01
0.3935
Reactant Channels
Coolant Channels
Width
4.1 mm
Width
4.1 mm
Length
500 mm
Length
500 mm
Height
2 mm
Height
2 mm
No. per Module
3417
No. per Module
6834
Module Design
Reactor Design
Design Data
Width
Length
Height
No. Modules
1m
1m
1.5 m
36
Oper. Temperature
Oper. Pressure
Heat Duty
Heat Transfer Area
536 F
240 psi
199 MMBTU/hr
504 m3
Catalyst
Methanol formation:
85.3 lb of Cu cataylst
Methanol dehydration: 85.3 lb of aluminum oxide catalyst
Utilities:
Both catalysts are wash coated on to 0.9 thick 90% porosity FeCrAlY metal wire felt
in a 1:1 mass ratio.
Consumes: Boiler feed water at 350 gpm
Produces: 263,576 lb/hr 500 psi steam
Cost Information: Bare Module Cost:
$5,000,000
169
Reactor
Identification:
Function:
Operation:
Item
Item No.
No. Required
React DME to olefins
Continuous
Fixed Bed Reactor

R-601
2
Performance of Unit
Inlet
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Composition
(mass fraction)
Water
DME
MeOH
Propylene
Ethylene
Diameter
Length
Outlet
S-611
98,200
707
450
S-612
98,200
923
420
0.82
0.16
0.02
0.88
0
0
0.02
0.01
Reactant Design
8 6
17 6
Design Data
Catalyst
Catalyst:
H-ZSM-5 (Si/Al = 83.7)
Preparation: Prepared over ZrO2 and H3PO4
WHSV = 1kg/kg/hr
Utilities:
Cost Information:
Bare Module Cost:
$425,200
170
Reactor
Identification:
Function:
Operation:
Item
Item No.
No. Required
React DME to olfein
Continuous
Fixed Bed Reactor

R-602
2
Performance of Unit
Inlet
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Composition
(mass fraction)
Water
DME
MeOH
Propylene
Ethylene
Diameter
Length
Outlet
S-615
120,600
662
410
S-616
120,600
896
370
0.72
0.16
0.02
0.02
0.01
0.78
0
0
0.03
0.02
Reactant Design
8 6
17 6
Design Data
Catalyst
Catalyst:
H-ZSM-5 (Si/Al = 83.7)
WHSV = 1kg/kg/hr
Utilities:
Cost Information:
Bare Module Cost:
$425,200
171
Reactor
Identification:
Function:
Operation:
Item
Item No.
No. Required
React DME to olfein
Continuous
Fixed Bed Reactor

R-603
2
Performance of Unit
Inlet
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Composition
(mass fraction)
Water
DME
MeOH
Propylene
Ethylene
Diameter
Length
Outlet
S-619
156,300
664
360
S-620
156,300
896
260
0.61
0.20
0.02
0.02
0.01
0.70
0
0
0.04
0.01
Reactant Design
8 6
17 6
Design Data
Catalyst
Catalyst:
H-ZSM-5 (Si/Al = 83.7)
WHSV = 1kg/kg/hr
Utilities:
Cost Information:
Bare Module Cost:
$425,200
172
Reactor
Identification:
Function:
Operation:
Item
Item No.
No. Required
React DME to olfein
Continuous
Fixed Bed Reactor

R-604
2
Performance of Unit
Inlet
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Composition
(mass fraction)
Water
DME
MeOH
Propylene
Ethylene
Diameter
Length
Outlet
S-623
181,800
658
235
S-624
181,800
787
35
0.60
0.12
0.01
0.04
0.01
0.65
0
0
0.09
0.02
Reactant Design
8 6
17 6
Design Data
Catalyst
Catalyst:
H-ZSM-5 (Si/Al = 83.7)
WHSV = 1kg/kg/hr
Utilities:
Cost Information:
Bare Module Cost:
$425,200
173
Reactor
Identification:
Function:
Operation:
Item
Fixed Bed Reactor
Item No.
R-701, R-702, R-703
No. Required
6
React heavy products to light olefins
Continuous
Performance of Unit
Inlet
Outlet
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Composition
(mass fraction)
S-707
181,800
920
65
S-708
181,800
709
35
Water
isoButate
n-Butane
Cis-Butene
Iso-Butylene
Propylene
Ethylene
0.30
0.17
0.20
0.06
0.02
0
0
0.32
0.14
0.19
0.04
0
0.17
0.05
Diameter
Length
Reactant Design
9 6
19
Design Data
Catalyst:
Catalyst
H-ZSM-5 (Si/Al = 100)
WHSV = 1kg/kg/hr
Utilities:
Cost Information:
Bare Module Cost:
$197,000
174
Flash Vessel
Identification:
Function:
Operation:
Stream
Quantity (lb/hr)
Temperature (F)
Pressure (psi)
Phase
Composition
(mole frac)
H2
CO
CO 2
Item
Horizontal Pressure Vessel
Item No.
V-301
No. Required
1
To decant water from synthesis gas stream after carbon dioxide absorption
Continuous
Performance of Unit
Inlet
Outlets
S-306
S-308
S-307
206,792
199,575
7,037
125
125
125
297
297
297
Mixed
Vapor
Liquid
0.604
0.619
0.000
0.287
0.293
0.000
0.050
0.051
0.000
CH4
0.027
0.028
0.000
N2
0.002
0.002
0.000
H2 O
0.030
0.007
1.000
1.000
1.000
1.000
Design Data
Flash Type
Material
Diameter
Length
Capacity
Total Flow
Residence Time
V-L Equilibrium
Carbon Steel
2
ft
7
ft
96.3
gal
107
10
ft3 /min
min
Utilities:
$15,922
Comments:
175
Flash Vessel
Identification:
Function:
Operation:
Stream
Quantity (lb/hr)
Temperature (F)
Pressure (psi)
Phase
Composition
(mole frac)
H2
CO
CO2
Item
Item No.
V-302
No. Required
1
To decant water from stripper overhead stream for purification of carbon dioxide
Continuous
Performance of Unit
Inlet
Outlets
S-315
S-318
S-316
200,000
145,878
54,122
120
118
118
39
39
39
Mixed
Vapor
Liquid
0.000
0.000
0.000
0.000
0.000
0.000
0.517
0.957
0.000
CH4
0.000
0.000
0.000
N2
0.000
0.000
0.000
H2 O
0.483
0.043
1.000
1.000
1.000
1.000
Design Data
Flash Type
Material
Diameter
Length
Capacity
Total Flow
Residence Time
V-L Equilibrium
Carbon Steel
6
ft
18
ft
1871
gal
109
10
ft3 /min
min
Utilities:
$33,813
Comments:
176
Flash Vessel
Identification:
Function:
Operation:
Stream
Quantity (lb/hr)
Temperature (F)
Pressure (psi)
Phase
Composition
(mass frac)
H2
N2
CO
CO2
CH4
H2O
CH4O
C2H6O-01
Design Data
Item
Item No.
V-501
No. Required
1
To separate the vapor product from liquid methanol and water
Continuous
Performance of Unit
Inlet
Outlets
FROM-REAC
S-501
S-503
483,004
418,421 66,524
167
167
167
232
230
230
Mixed
Vapor
Liquid
0.062
0.046
0.003
0.219
0.145
0.110
0.022
0.393
Flash Type
Material
Diameter
Length
Capacity
Total Flow
Residence Time
0.070
0.053
0.003
0.252
0.165
0.025
0.016
0.415
V-L Equilibrium
Carbon Steel
7
21
6020
13000
30
0.000
0.001
0.000
0.018
0.015
0.647
0.057
0.262
ft
ft
gal
ft3/min
min
Utilities:
Cost Information:
Purchase Cost:
Bare Module Cost:
$66,600
$212,000
Comments:
177
Flash Vessel
Identification:
Function:
Operation:
Stream
Quantity (lb/hr)
Temperature (F)
Pressure (psi)
Phase
Composition
(mass frac)
H2
N2
CO
CO2
CH4
H2O
CH4O
C2H6O-01
Design Data
Item
Item No.
V-502
No. Required
1
Reflux drum for D-501. Separates vapor distillate from liquid reflux
Continuous
Performance of Unit
Inlet
Outlets
D-501 Overhead
S-507
D-501 Reflux
620,000
20,000
600,000
58.5
58.5
58.5
205
205
205
Mixed
Vapor
Liquid
0.000
0.006
0.000
0.082
0.016
0.000
0.000
0.866
Flash Type
Material
Diameter
Length
Capacity
Total Flow
Residence Time
0.000
0.010
0.001
0.277
0.269
0.000
0.000
0.444
V-L Equilibrium
Carbon Steel
10
30
17,000
509
5
0.000
0.006
0.000
0.076
0.008
0.000
0.000
0.880
ft
ft
gal
ft3/min
min
Utilities:
Cost Information:
Purchase Cost:
Bare Module Cost:
$112,200
$342,300
Comments:
178
Flash Vessel
Identification:
Function:
Operation:
Stream
Quantity (lb/hr)
Temperature (F)
Pressure (psi)
Phase
Composition
(mass frac)
H2
N2
CO
CO2
CH4
H2O
CH4O
C2H6O-01
Design Data
Utilities:
Cost Information:
Item
Item No.
V-503
No. Required
1
To flash hot water to low pressure steam
Continuous
Performance of Unit
Inlet
Outlets
S-511
STEAM
S-512
171,953
23,398
148,555
385
281
281
207
50
50
Liquid
Vapor
Liquid
0.000
0.000
0.000
0.000
0.000
0.993
0.000
0.007
Flash Type
Material
Diameter
Length
Capacity
0.000
0.000
0.000
0.000
0.000
0.971
0.000
0.029
V-L Equilibrium
Carbon Steel
6
17
3,394
Total Liquid Flow

3,360
Residence Time
5
Produces: 23,400 lb/hr 50 psi steam
Purchase Cost:
Bare Module Cost:
0.000
0.000
0.000
0.000
0.000
0.997
0.000
0.003
ft
ft
gal
ft3/min
min
$3,600
$11,800
Comments:
179
Flash Vessel
Identification:
Function:
Operation:
Stream
Quantity (lb/hr)
Temperature (F)
Pressure (psi)
Phase
Composition
(mass frac)
Water
Ethylene
Propylene
isoButane
n-Butane
Design Data
Item
Item No.
V-801
No. Required
1
To separate liquid phase from olefin reactor effluents
Continuous
Performance of Unit
Inlet
Outlets
S-803
S-804
S-806
331,100
127,700 203,500
140
138
138
19
18
18
Liquid
Vapor
Liquid
0.50
0.03
0.13
0.08
0.10
Flash Type
Material
Diameter
Length
Capacity
Total Liquid Flow
Residence Time
0.05
0.07
0.28
0.13
0.15
V-L Equilibrium
Carbon Steel
7
21
6045
62
5
0.78
0
0.03
0.04
0.07
ft
ft
gal
ft3/min
min
Utilities:
Cost Information:
Purchase Cost:
Bare Module Cost:
$42,700
$130,300
Comments:
180
Pressure Vessel
Identification:
Function:
Operation:
Stream
Quantity (lb/hr)
Temperature (F)
Pressure (psi)
Phase
Composition
(mass frac)
Water
Ethylene
Propylene
isoButane
n-Butane
Design Data
Item
Item No.
V-802
No. Required
1
To store reflux for column
Continuous
Performance of Unit
Inlet
Outlet
D-801
D-801
51,400
51,400
385
281
25
25
Liquid
Liquid
0.82
0.01
0.02
0.03
0.06
Flash Type
Material
Diameter
Length
Capacity
Total Liquid Flow
Residence Time
0.82
0.01
0.02
0.03
0.06
V-L Equilibrium
Carbon Steel
4 3
12 9
1253
17.2
5
ft
ft
gal
ft3/min
min
Utilities:
Cost Information:
Purchase Cost:
Bare Module Cost:
$24,500
$74,700
Comments:
181
Flash Vessel
Identification:
Function:
Operation:
Stream
Quantity (lb/hr)
Temperature (F)
Pressure (psi)
Phase
Composition
(mass frac)
Water
Ethylene
Propylene
isoButane
n-Butane
Design Data
Item
Item No.
V-901
No. Required
1
To remove condensed phase from separation train
Continuous
Performance of Unit
Inlet
Outlets
S-902
S-903
S-904
171,953
107,800
58,800
110
110
110
60
57
60
Liquid
Vapor
Liquid
0.03
0.06
0.25
0.16
0.20
Flash Type
Material
Diameter
Length
Capacity
0.00
0.09
0.34
0.17
0.20
V-L Equilibrium
Carbon Steel
4 3
12 6
1,326
Total Liquid Flow

Residence Time
25
5
0.08
0.00
0.09
0.14
0.21
ft
ft
gal
ft3/min
min
Utilities:
Cost Information:
Purchase Cost:
Bare Module Cost:
$24,600
$74,900
Comments:
182
Flash Vessel
Identification:
Function:
Operation:
Stream
Quantity (lb/hr)
Temperature (F)
Pressure (psi)
Phase
Composition
(mass frac)
Water
Ethylene
Propylene
isoButane
n-Butane
Design Data
Item
Item No.
V-902
No. Required
1
To separate condensate from compression train
Continuous
Performance of Unit
Inlet
Outlets
S-907
S-908
S-909
107,800
58,400
49,400
110
110
110
145
142
145
Liquid
Vapor
Liquid
0
0.09
0.34
0.17
0.20
Flash Type
Material
Diameter
Length
Capacity
0
0.14
0.46
0.15
0.14
V-L Equilibrium
Carbon Steel
4
11 6
1,081
Total Liquid Flow

Residence Time
24
5
0
0.02
0.21
0.20
0.26
ft
ft
gal
ft3/min
min
Utilities:
Cost Information:
Purchase Cost:
Bare Module Cost:
$24,300
$74,100
Comments:
183
Pressure Vessel
Identification:
Function:
Operation:
Stream
Quantity (lb/hr)
Temperature (F)
Pressure (psi)
Phase
Composition
(mass frac)
Item
Item No.
V-1001
No. Required
1
To hold reflux for column D-1001
Continuous
Performance of Unit
Inlet
Outlets
D-1001
D-1001
125,100
125,100
96
96
523
523
Liquid
Liquid
Ethylene
Propylene
Design Data
0.26
0.73
Material
Diameter
Length
Capacity
Total Liquid Flow
Residence Time
0.26
0.73
V-L Equilibrium
Carbon Steel
6 9
20
5,354
74
5
ft
ft
gal
ft3/min
min
Utilities:
Cost Information:
Purchase Cost:
Bare Module Cost:
$93,600
$285,500
Comments:
184
Pressure Vessel
Identification:
Function:
Operation:
Stream
Quantity (lb/hr)
Temperature (F)
Pressure (psi)
Phase
Composition
(mass frac)
Item
Item No.
V-1002
No. Required
1
To hold reflux for the column
Continuous
Performance of Unit
Inlet
Outlets
D-1002
D-1002
22,700
22,700
29
29
650
650
Liquid
Liquid
0.94
0.06
Ethylene
Propylene
Design Data
Flash Type
Material
Diameter
Length
Capacity
Total Liquid Flow
Residence Time
0.94
0.06
V-L Equilibrium
Carbon Steel
6
18 6
3,912
17
5
ft
ft
gal
ft3/min
min
Utilities:
Cost Information:
Purchase Cost:
Bare Module Cost:
$86,900
$265,500
Comments:
185
Pressure Vessel
Identification:
Function:
Operation:
Stream
Quantity (lb/hr)
Temperature (F)
Pressure (psi)
Phase
Composition
(mass frac)
Item
Item No.
V-1003
No. Required
2
Shift storage for ethylene product
Continuous
Performance of Unit
Inlet
S-1008
9,800
29
700
Liquid
0.93
0.01
Ethylene
Propylene
Design Data
Outlets
Flash Type
Material
Diameter
Length
Capacity
Total Liquid Flow
Fill Time
V-L Equilibrium
Carbon Steel
12 6
38 6
35,340
7.32
8
ft
ft
gal
ft3/min
hr
Utilities:
Cost Information:
Purchase Cost:
Bare Module Cost:
$486,600
$1,484,000
Comments:
186
Flash Vessel
Identification:
Function:
Operation:
Stream
Quantity (lb/hr)
Temperature (F)
Pressure (psi)
Phase
Composition
(mass frac)
Item
Item No.
V-1004
No. Required
2
Shift storage for propylene product
Continuous
Performance of Unit
Inlet
S-1010
40,300
186
705
Liquid
0.02
0.98
Ethylene
Propylene
Design Data
Outlets
Flash Type
Material
Diameter
Length
Capacity
V-L Equilibrium
Carbon Steel
21 3
64
169,800
Total Liquid Flow

Fill Time
32
8
Purchase Cost:
Bare Module Cost:
$689,500
$2,103,000
ft
ft
gal
ft3/min
hr
Utilities:
Cost Information:
Comments:
187
Heat Exchanger
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
(per Unit)
Item
Fixed-Head Shell and Tube Heat Exchanger
Item No.
H-201
No. Required
1
To superheat steam fed from the HRSG evaporator unit
Continuous
Performance of Unit
Shell Side
Tube Side
Inlet
Outlet
Inlet
Outlet
S-224
S-225
S-208
S-209
120,000
120,000
343,591
343,591
621
1400
1700
1371
1799
1798
465
461
Flow Type
Shell Type
LMTD
U
A
Heat Duty
Counter Current
One Pass
491.6 F
79.4 BTU/hr-sqft-R
1699 sqft
57,458,148 BTU/hr
Tube OD
Tube Length
No. Tubes
Shell OD
Baffle Spacing
Material
0.75 in
6 ft
1040
34.9 in
6.75 in
Carbon Steel
Utilities:
Cost Information: Purchase Cost per Unit:
Bare Module Cost per Unit:
Total Bare Module Cost:
$50,140
$158,944
$158,944
Comments:
188
Heat Exchanger
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
(per Unit)
Item
Item No.
H-202
No. Required
1
To evaporate steam fed to the HRSG process section
Continuous
Performance of Unit
Shell Side
Tube Side
Inlet
Outlet
Inlet
Outlet
S-223
S-224
S-209
S-210
120,000
120,000
343,591
343,591
600
621
1370
925
1800
1799
461
458
Flow Type
Shell Type
LMTD
U
A
Heat Duty
Counter Current
One Pass
497.0 F
178.8 BTU/hr-sqft-R
878 sqft
74,666,443 BTU/hr
Tube OD
Tube Length
No. Tubes
Shell OD
Baffle Spacing
Material
0.75 in
5 ft
885
31.875 in
6.25 in
Carbon Steel
Utilities:
$43,809
$138,875
$138,875
Comments:
189
Heat Exchanger
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
(per Unit)
Item
Item No.
H-203
No. Required
1
Economizer to heat water fed to the HRSG process section
Continuous
Performance of Unit
Shell Side
Tube Side
Inlet
Outlet
Inlet
Outlet
S-222
S-223
S-210
S-211
120,000
120,000
343,591
343,591
400
600
925
747
1800
1799
433
429
Flow Type
Shell Type
LMTD
U
A
Heat Duty
Counter Current
One Pass
331.2 F
144.3 BTU/hr-sqft-R
812 sqft
28,638,788 BTU/hr
Tube OD
Tube Length
No. Tubes
Shell OD
Baffle Spacing
Material
0.75 in
5 ft
846
30.875 in
6.0 in
Carbon Steel
Utilities:
$41,706
$132,208
$132,208
Comments:
190
Heat Exchanger
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
(per Unit)
Item
Item No.
H-204
No. Required
1
Low pressure steam evaporator via exchange with passing synthesis gas stream
Continuous
Performance of Unit
Shell Side
Tube Side
Inlet
Outlet
Inlet
Outlet
S-218
S-219
S-211
S-212
65,000
65,000
343,591
343,591
350
393
747
372
229
229
429
429
Flow Type
Shell Type
LMTD
U
A
Heat Duty
Counter Current
One Pass
120.2 F
178.3 BTU/hr-sqft-R
2734 sqft
58,595,594BTU/hr
Tube OD
Tube Length
No. Tubes
Shell OD
Baffle Spacing
Material
NA
NA
NA
NA
NA
Carbon Steel
Utilities:
Comments:
$50,140
$158,944
$158,944
Aspen EDR could not converge upon a solution for this heat exchanger design.
Overall heat transfer coefficient was estimated using the value from the HRSG
evaporator unit, and the cost estimate was also shared.
Shortcut method used for calculations.
191
Heat Exchanger
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
(per Unit)
Item
Item No.
H-205
No. Required
1
Economizer to heat water with passing synthesis gas for low pressure steam
Continuous
Performance of Unit
Shell Side
Tube Side
Inlet
Outlet
Inlet
Outlet
S-217
S-218
S-212
S-213
65,000
65,000
343,591
343,591
280
350
372
342
230
229
429
426
Flow Type
Shell Type
LMTD
U
A
Heat Duty
Counter Current
One Pass
38.7 F
178.3 BTU/hr-sqft-R
743 sqft
4,699,894 BTU/hr
Tube OD
Tube Length
No. Tubes
Shell OD
Baffle Spacing
Material
0.75 in
6 ft
680
27.75 in
8.0 in
Carbon Steel
Utilities:
$48,137
$152,594
$152,594
Comments:
192
Heat Exchanger
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
(per Unit)
Item
Item No.
H-206
No. Required
1
Economizer to preheat water with passing synthesis gas for low pressure steam
Continuous
Performance of Unit
Shell Side
Tube Side
Inlet
Outlet
Inlet
Outlet
S-213
S-214
S-216
S-217
65,000
65,000
343,591
343,591
280
350
372
342
230
229
429
426
Flow Type
Shell Type
LMTD
U
A
Heat Duty
Counter Current
One Pass
109.0 F
167.2 BTU/hr-sqft-R
743 sqft
13,195,202 BTU/hr
Tube OD
Tube Length
No. Tubes
Shell OD
Baffle Spacing
Material
0.75 in
6 ft
680
27.75 in
8.0 in
Carbon Steel
Utilities:
$47,982
$152,013
$152,013
Comments:
193
Heat Exchanger
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
(per Unit)
Utilities:
Item
Item No.
H-301
No. Required
10 (5 in parallel, 2 in series)
To cool recycled monoethanol amine and water solution from stripping column
Continuous
Performance of Unit
Shell Side
Tube Side
Inlet
Outlet
Inlet
Outlet
CW-301
CW-302
S-301
S-302
3,843,024
3,843,024
1,332,519
1,332,519
90
120
216
100
50
43
300
298
Flow Type
Shell Type
LMTD
U
A
Heat Duty
Counter Current
Two Pass
33.98 F
231.0 BTU/hr-sqft-R
1,675 sqft
115,032,041 BTU/hr
Tube OD
Tube Length
No. Tubes
Shell OD
Baffle Spacing
Material
0.75 in
16 ft
543
26.75 in
23.5 in
Carbon Steel
Cooling Water, 3,843,024 lb/hr (7669 gpm), $273,316/yr

$38,980
$123,567
$1,235,666
Comments:
194
Heat Exchanger
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
(per Unit)
Utilities:
Item
Item No.
H-302
No. Required
1
To cool absorber overhead stream before flash vessel F-301
Continuous
Performance of Unit
Shell Side
Tube Side
Inlet
Outlet
Inlet
Outlet
CW-303
CW-304
S-305
S-306
499,992
499,992
1,332,519
1,332,519
90
120
204
125
65
63
300
297
Flow Type
Shell Type
LMTD
U
A
Heat Duty
Counter Current
One Pass
54.39 F
264.7 BTU/hr-sqft-R
1,209 sqft
16,485,180 BTU/hr
Tube OD
Tube Length
No. Tubes
Shell OD
Baffle Spacing
Material
0.75 in
10 ft
635
27.75 in
23.5 in
Carbon Steel
Cooling Water, 499,992 lb/hr (1099gpm), $39,169/yr

$38,278
$121,341
$121,341
Comments:
195
Heat Exchanger
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
(per Unit)
Item
Item No.
H-303
No. Required
4 (2 parallel, 2 series)
Stripper Bottoms Feed-Product Exchanger
Continuous
Performance of Unit
Shell Side
Tube Side
Inlet
Outlet
Inlet
Outlet
S-310
S-311
S-312
S-313
1,476,502
1,476,502
1,276,506
1,276,506
194
243
290
219
85
80
43
40
Flow Type
Shell Type
LMTD
U
A
Heat Duty
Counter Current
Two Pass
28.41 F
311.1 BTU/hr-sqft-R
2,319 sqft
71,768,320 BTU/hr
Tube OD
Tube Length
No. Tubes
Shell OD
Baffle Spacing
Material
0.75 in
14 ft
864
33.875 in
26.0 in
Carbon Steel
Utilities:
$53,944
$171,002
$684,010
Comments:
196
Heat Exchanger
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
(per Unit)
Utilities:
Item
Item No.
H-304
No. Required
2 (2 parallel, 1 series)
Stripper Overhead Cooler
Continuous
Performance of Unit
Shell Side
Tube Side
Inlet
Outlet
Inlet
Outlet
CW-305
CW-306
S-314
S-315
2,049,966
2,049,966
199,997
199,997
90
120
249
119
65
59
43
39
Flow Type
Shell Type
LMTD
U
A
Heat Duty
Counter Current
Two Pass
84.66 F
247.2 BTU/hr-sqft-R
1,666 sqft
62,017,650 BTU/hr
Tube OD
Tube Length
No. Tubes
Shell OD
Baffle Spacing
Material
0.75 in
16 ft
540
26.75 in
23.5 in
Carbon Steel
Cooling Water, 2,050,000 lb/hr (4135 gpm), $147,354/yr

$39,247
$110,719
$221,437
Comments:
197
Heat Exchanger
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Item
Item No.
H-401
No. Required
5
To preheat the reactor feed and cool the reactor effluent
Continuous
Performance of Unit
Shell Side
Tube Side
Inlet
Outlet
Inlet
Outlet
S-403
S-404
S-405
S-406
408551
408551
410438
410438
193
457
536
251
270
265
240
235
Design Data
Flow Type
Shell Type
LMTD
(per Unit)
Counter
Current
One Pass
69.01 F
87.5 BTU/hr-sqftR
14,589 sqft
Shell OD
Baffle
Spacing
Heat Duty
87.2 MMBTU/hr
Material
Tube OD
Tube Length
No. Tubes
0.75 in
20 ft
758
30.875 in
23.5 in
Carbon
Steel
Utilities:
Cost
Information:
Purchase Cost per

Unit:
$59,100
$185,000
$924,900
Comments:
198
Heat Exchanger
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
(per Unit)
Item
Item No.
H-402
No. Required
1
Cools the reactor effluent to condense out the majority of the methanol and
water
Continuous
Performance of Unit
Shell Side
Tube Side
Inlet
Outlet
Inlet
Outlet
CW-IN
CW-OUT
S-406
TO-SEP
2,506,420
2,506,420
483004
483004
90
120
251
167
50
43
235
232
Flow Type
Shell Type
LMTD
U
A
Counter Current
One Pass
103 F
377 BTU/hr-sqft-R
2070 sqft
Tube OD
Tube Length
No. Tubes
Shell OD
Baffle Spacing
Heat Duty
70.8 MMBTU/hr
Material
Utilities:
Cooling water: 5,008 gpm
Cost Information:
Purchase Cost:
$80,200
0.75 in
8 ft
1397
42 in
15 in
Carbon
Steel
Comments:
199
Heat Exchanger
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
(per Unit)
Utilities:
Cost Information:
Item
Item No.
H-501
No. Required 3
Condenser for D-501. Partially condensess the column overhead.
Continuous
Performance of Unit
Shell Side
Tube Side
Inlet
Outlet
Inlet
Outlet
CW-IN
CW-OUT
D-501 Overhead Flow to V-502
2,506,420
2,506,420
620,000
620,000
45
111
121
58.5
50
45
205
205
Flow Type
Material
LMTD
U
A
Heat Duty
Counter Current
Carbon Steel
12 F
80 BTU/hr-sqft-R
7,500 sqft
37.5 MMBTU/hr

Chilled Water: 2,990 gpm
Purchase Cost per Unit:
$54,700
Total Purchase Cost:
$164,000
$520,000
Comments:
200
Heat Exchanger
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
(per Unit)
Item
Kettle Reboiler
Item No.
H-502
No. Required
2
Reboiler for D-501
Continuous
Performance of Unit
Shell Side
Inlet
Outlet
D-501 Bottoms
Boil Up
224,627
224,627
383
385
207
205
Flow Type
Material
LMTD
U
A
Heat Duty
Tube Side
Inlet
Outlet
Steam
Water
191,467 191,467
467
467
500
495
Counter Current
Carbon Steel
83 F
400 BTU/hr-sqft-R
7,720 sqft
80.8 MMBTU/hr
Utilities:
191,500 lb/hr 500 psi steam
Cost Information:

Total Purchase Cost:
$104,000
$208,000
$660,000
Comments:
201
Heat Exchanger
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
(per Unit)
Item
Item No.
H-503
No. Required 1
Cools the water recycle prior it entering the absorption tower, T-501
Continuous
Performance of Unit
Shell Side
Tube Side
Inlet
Outlet
Inlet
Outlet
CW-IN
CW-OUT
S-513
S-514
1,703,560
1,703,560
312,494
312,494
90
120
261
110
50
43
55
45
Flow Type
Shell Type
LMTD
U
A
Heat Duty
Counter Current
One Pass
61.8 F
475 BTU/hr-sqft-R
2300 sqft
47.9 MMBTU/hr
Utilities:
Cost Information:
Purchase Cost:
$64,400
Tube OD
Tube Length
No. Tubes
Shell OD
Baffle Spacing
Material
0.75 in
12 ft
1006
37 in
23.5 in
Carbon Steel
Comments:
202
Heat Exchanger
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
(per Unit)
Item
Item No.
H-601
No. Required 1
Heat water feed to DME reactor
Continuous
Performance of Unit
Shell Side
Tube Side
Inlet
Outlet
Inlet
HP Steam
HP Steam
S-603
9500
9500
79800
450
448.8
386
422
417
475
Flow Type
Shell Type
LMTD
U
A
Heat Duty
Counter Current
One Pass
19 F
810 BTU/hr-sqft-R
514 sqft
7352196BTU/hr
Utilities:
9,500 lb/hr of HP Steam
Cost Information:

$64,400
Bare Module Cost per Unit: $201,500
$201,500
Tube OD
Tube Length
No. Tubes
Shell OD
Baffle Spacing
Material
Outlet
S-604
79800
447
470
0.75 in
16 ft
167
37 in
26 in
Carbon Steel
Comments:
203
Heat Exchanger
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
(per Unit)
Item
Item No.
H-602
No. Required 1
Vaporize the water feed to the DME reactor
Continuous
Performance of Unit
Shell Side
Tube Side
Inlet
Outlet
Inlet
HP Steam
HP Steam
S-604
90000
90000
79800
520
515
447
811
806
465
Flow Type
Shell Type
LMTD
U
A
Heat Duty
Counter Current
One Pass
59.38 F
940 BTU/hr-sqft-R
1125 sqft
62504460 BTU/hr
Utilities:
Cost Information:

$42,200
$126,600
Tube OD
Tube Length
No. Tubes
Shell OD
Baffle Spacing
Material
Outlet
S-605
79800
461
460
0.75 in
14 ft
421
24.625 in
15.5 in
Carbon Steel
Comments:
204
Heat Exchanger
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
(per Unit)
Item
Item No.
H-603
No. Required 2
Superheat steam feed to DME reactor
Continuous
Performance of Unit
Shell Side
Tube Side
Inlet
Outlet
Inlet
HP Steam
HP Steam
S-605
36000
36000
79800
849
620
460
1795
1790
465
Flow Type
Shell Type
LMTD
U
A
Heat Duty
Counter Current
One Pass
63.11 F
46.1 BTU/hr-sqft-R
3300 sqft
944370 BTU/hr
Utilities:
Cost Information:

$113,300
$679,800
Tube OD
Tube Length
No. Tubes
Shell OD
Baffle Spacing
Material
Outlet
S-606
79800
707
460
0.75 in
20 ft
438
24.625 in
4.5 in
Carbon Steel
Comments:
205
Heat Exchanger
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
(per Unit)
Item
Item No.
H-604
No. Required 2
Recover exothermic heat of reaction
Continuous
Performance of Unit
Shell Side
Tube Side
Inlet
Outlet
Inlet
Boiler Water
HP Steam
S-612
20700
20700
98200
600
850
924
1800
1795
420
Flow Type
Shell Type
LMTD
U
A
Heat Duty
Counter Current
One Pass
117.35 F
80.09 BTU/hr-sqft-R
1500 sqft
13887750 BTU/hr
Utilities:
20,700 lb/hr of Boiler Feed Water
Cost Information:

$186,200
$1,117,200
Tube OD
Tube Length
No. Tubes
Shell OD
Baffle Spacing
Material
Outlet
S-613
98200
650
415
0.75 in
14 ft
291
24.625 in
14 in
Carbon Steel
Comments:
206
Heat Exchanger
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
(per Unit)
Item
Item No.
H-605
No. Required 2
Continuous
Performance of Unit
Shell Side
Tube Side
Inlet
Outlet
Inlet
Outlet
Boiler Water
HP Steam
S-616
S-617
23400
23400
120600
120600
600
855
896
650
1800
1795
370
365
Flow Type
Shell Type
LMTD
U
A
Heat Duty
Counter Current
One Pass
106 F
81.04 BTU/hr-sqft-R
1852 sqft
15758680BTU/hr
Utilities:
Cost Information:

$131,500
$789,000
Tube OD
Tube Length
No. Tubes
Shell OD
Baffle Spacing
Material
0.75 in
14 ft
359
24.625 in
6.5 in
Carbon Steel
Comments:
207
Heat Exchanger
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
(per Unit)
Item
Item No.
H-606
No. Required 1
Continuous
Performance of Unit
Shell Side
Tube Side
Inlet
Outlet
Inlet
Outlet
Boiler Water
HP Steam
S-620
S-621
36000
36000
156300
156300
600
751
910
650
1800
1795
260
255
Flow Type
Shell Type
LMTD
U
A
Heat Duty
Counter Current
One Pass
120 F
81.0 BTU/hr-sqft-R
2298 sqft
22375550 BTU/hr
Utilities:
Cost Information:

$585,700
Bare Module Cost per Unit: $1,757,100
$1,757,100
Tube OD
Tube Length
No. Tubes
Shell OD
Baffle Spacing
Material
0.75 in
12 ft
1097
24.625 in
27 in
Carbon Steel
Comments:
208
Heat Exchanger
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
(per Unit)
Item
Item No.
H-607
No. Required 2
Continuous
Performance of Unit
Shell Side
Tube Side
Inlet
Outlet
Inlet
Outlet
Boiler Water
HP Steam
S-624
S-625
10000
10000
181800
181800
600
661
787
730
1800
1795
35
30
Flow Type
Shell Type
LMTD
U
A
Heat Duty
Counter Current
One Pass
136 F
59.0 BTU/hr-sqft-R
1432 sqft
5716555 BTU/hr
Utilities:
Cost Information:

$86,800
$520,800
Tube OD
Tube Length
No. Tubes
Shell OD
Baffle Spacing
Material
0.75 in
5 ft
854
24.625 in
6 in
Carbon Steel
Comments:
209
Heat Exchanger
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
(per Unit)
Item
Item No.
H-608
No. Required 1
Transfer heat from reactor effluent to reactor feed
Continuous
Performance of Unit
Shell Side
Tube Side
Inlet
Outlet
Inlet
Outlet
S-608
S-609
S-625
S-626
102000
102000
181800
181800
138
707
730
240
460
455
30
25
Flow Type
Shell Type
LMTD
U
A
Heat Duty
Counter Current
One Pass
100 F
25.4 BTU/hr-sqft-R
18757 sqft
47745310 BTU/hr
Tube OD
Tube Length
No. Tubes
Shell OD
Baffle Spacing
Material
0.75 in
20 ft
4976
24.625 in
23 in
Carbon Steel
Utilities:
Cost Information:

$335,600
$1,006,800
Comments:
210
Heat Exchanger
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
(per Unit)
Item
Item No.
H-701
No. Required 1
To preheat the reactor feed
Continuous
Performance of Unit
Shell Side
Tube Side
Inlet
Outlet
Inlet
Outlet
IP Steam
IP Steam
S-703
S0795
60000
60000
149000
149000
320
316
234
297
90
85
105
100
Flow Type
Shell Type
LMTD
U
A
Heat Duty
Counter Current
One Pass
69.01 F
38.2 BTU/hr-sqft-R
3347 sqft
50698240 BTU/hr
Utilities:
60,000 lb/hr of IP Steam
Cost Information:

$62,600
$187,800
Tube OD
Tube Length
No. Tubes
Shell OD
Baffle Spacing
Material
0.75 in
18 ft
965
24.625 in
23.5 in
Carbon Steel
Comments:
211
Heat Exchanger
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
(per Unit)
Item
Item No.
H-702
No. Required 9
To preheat the reactor feed
Continuous
Performance of Unit
Shell Side
Tube Side
Inlet
Outlet
Inlet
Outlet
S-704
S-705
S-713
S-714
149000
149000
149000
149000
296
665
705
343
100
95
30
25
Flow Type
Shell Type
LMTD
U
A
Heat Duty
Counter Current
One Pass
42.7 F
24.6 BTU/hr-sqft-R
31830 sqft
30817550 BTU/hr
Tube OD
Tube Length
No. Tubes
Shell OD
Baffle Spacing
Material
0.75 in
18 ft
1025
24.625 in
23.25 in
Carbon Steel
Utilities:
Cost Information:

$68,300
$1,844,100
Comments:
212
Heat Exchanger
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
(per Unit)
Item
Item No.
H-801
No. Required 1
Cool combined olefin stream
Continuous
Performance of Unit
Shell Side
Tube Side
Inlet
Outlet
Inlet
Outlet
Boiler Water
LP Steam
S-801
S-802
8000
8000
331100
331100
220
220
269
235
20
17
25
22
Flow Type
Shell Type
LMTD
U
A
Heat Duty
Counter Current
One Pass
20.0 F
38.1 BTU/hr-sqft-R
7483 sqft
5178242 BTU/hr
Utilities:
Cost Information:

$157,500
$472,500
Tube OD
Tube Length
No. Tubes
Shell OD
Baffle Spacing
Material
0.75 in
12 ft
3302
24.625 in
23.25 in
Carbon Steel
Comments:
213
Heat Exchanger
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
(per Unit)
Item
Item No.
H-802
No. Required 3
Cool combined olefin feed
Continuous
Performance of Unit
Shell Side
Tube Side
Inlet
Outlet
Inlet
Outlet
Cooling Water
Cooling Water
S-802
S-803
5000000
5000000
331100
331100
90
130
235
140
40
35
22
19
Flow Type
Shell Type
LMTD
U
A
Heat Duty
Counter Current
One Pass
87.4 F
312.1 BTU/hr-sqft-R
6845 sqft
18460500 BTU/hr
Utilities:
110,000 gpm of Cooling Water
Cost Information:

$57,600
$518,400
Tube OD
Tube Length
No. Tubes
Shell OD
Baffle Spacing
Material
0.75 in
12 ft
997
24.625 in
23.5 in
Carbon Steel
Comments:
214
Heat Exchanger
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
(per Unit)
Item
Kettle Reboiler
Item No.
H-803
No. Required 1
Return vapor to the bottom of the column
Continuous
Performance of Unit
Shell Side
Inlet
Outlet
LP Steam
LP Steam
80000
80000
270
254
42
37
Flow Type
Shell Type
LMTD
U
A
Heat Duty
Counter Current
One Pass
12.4 F
701.8 BTU/hr-sqft-R
9587 sqft
76317280 BTU/hr
Utilities:
80,000 lb/hr of LP Steam
Cost Information:

$180,200
$540,600
Tube Side
Inlet
Outlet
D-801
D-801
219800
219800
247
246
34
29
Tube OD
Tube Length
No. Tubes
Shell OD
Baffle Spacing
Material
Carbon Steel
Comments:
215
Heat Exchanger
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
(per Unit)
Item
Item No.
H-804
No. Required 1
Condense distillate
Continuous
Performance of Unit
Shell Side
Tube Side
Inlet
Outlet
Inlet
Cooling Water
Cooling Water
D-801
1400000
1400000
94100
90
116
215
40
35
27
Flow Type
Shell Type
LMTD
U
A
Heat Duty
Counter Current
One Pass
72.1 F
331.3 BTU/hr-sqft-R
1488 sqft
34842840 BTU/hr
Utilities:
3300 gpm of Cooling Water
Cost Information:

$47,100
$141,300
Tube OD
Tube Length
No. Tubes
Shell OD
Baffle Spacing
Material
Outlet
D-801
94100
130
25
0.75 in
10 ft
783
24.625 in
26 in
Carbon Steel
Comments:
216
Heat Exchanger
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
(per Unit)
Item
Item No.
H-901
No. Required 2
Cool and condense compressor outlet
Continuous
Performance of Unit
Shell Side
Tube Side
Inlet
Outlet
Inlet
Outlet
S-809
S-901
Cooling Water
Cooling Water
166,600
166,600
550,000
550,000
210
110
90
130
65
60
40
35
Flow Type
Shell Type
LMTD
U
A
Heat Duty
Counter Current
One Pass
35.4 F
127.2 BTU/hr-sqft-R
4670 sqft
20947260 BTU/hr
Utilities:
Cost Information:

$49,200
$295,200
Tube OD
Tube Length
No. Tubes
Shell OD
Baffle Spacing
Material
0.75 in
16 ft
758
24.625 in
23.5 in
Carbon Steel
Comments:
217
Heat Exchanger
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
(per Unit)
Item
Item No.
H-902
No. Required 1
Continuous
Performance of Unit
Shell Side
Tube Side
Inlet
Outlet
Inlet
Outlet
S-906
S-907
Cooling Water
Cooling Water
107,800
107,800
300,000
300,000
190
110
90
130
150
145
40
35
Flow Type
Shell Type
LMTD
U
A
Heat Duty
Counter Current
One Pass
25.5 F
120.2 BTU/hr-sqft-R
3700 sqft
11292860 BTU/hr
Utilities:
Cost Information:

$63,500
$190,500
Tube OD
Tube Length
No. Tubes
Shell OD
Baffle Spacing
Material
0.75 in
20 ft
959
24.625 in
23.5 in
Carbon Steel
Comments:
218
Heat Exchanger
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
(per Unit)
Item
Item No.
H-903
No. Required 1
Continuous
Performance of Unit
Shell Side
Tube Side
Inlet
Outlet
Inlet
Outlet
S-911
S-912
Cooling Water
Cooling Water
58,400
58,400
225,000
225,000
170
100
90
122
270
265
40
35
Flow Type
Shell Type
LMTD
U
A
Heat Duty
Counter Current
One Pass
20.76 F
111.3 BTU/hr-sqft-R
2983 sqft
6844800 BTU/hr
Utilities:
Cost Information:

$55,000
$165,000
Tube OD
Tube Length
No. Tubes
Shell OD
Baffle Spacing
Material
0.75 in
20 ft
772
24.625 in
9.25 in
Carbon Steel
Comments:
219
Heat Exchanger
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
(per Unit)
Utilities:
Item
Item No.
H-904
No. Required
1
Condense olefin product
Continuous
Performance of Unit
Shell Side
Tube Side
Inlet
Outlet
Inlet
Outlet
Refrig. Proplyene
Refrig. Propylene
S-912
S-913
25,000
25,000
58,400
58,400
170
100
100
47.5
51
46
265
260
Flow Type
Shell Type
LMTD
U
A
Heat Duty
Counter Current
One Pass
71.4 F
248.1 BTU/hr-sqft-R
264 sqft
3912041 BTU/hr
Tube OD
Tube Length
No. Tubes
Shell OD
Baffle Spacing
Material
0.75 in
20 ft
68
24.625 in
20.25 in
Carbon Steel
25,000 lb/hr of Refrigerated Propylene
$15,500
$46,500
Comments:
220
Heat Exchanger
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
(per Unit)
Item
Item No.
H-1001
No. Required
1
Preheat distillation column feed with bottoms
Continuous
Performance of Unit
Shell Side
Tube Side
Inlet
Outlet
Inlet
Outlet
S-915
S-1001
S-1005
S-1006
166,700
166,700
11,375
11,375
91
180
224
182
558
553
105
100
Flow Type
Shell Type
LMTD
U
A
Heat Duty
Counter Current
One Pass
60.5 F
214.3 BTU/hr-sqft-R
949 sqft
12190680 BTU/hr
Tube OD
Tube Length
No. Tubes
Shell OD
Baffle Spacing
Material
0.75 in
16 ft
308
24.625 in
8 in
Carbon Steel
Utilities:
$30,800
$92,400
Comments:
221
Heat Exchanger
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
(per Unit)
Utilities:
Item
Item No.
H-1002
No. Required
2
Cool distillate vapor with cooling water
Continuous
Performance of Unit
Shell Side
Tube Side
Inlet
Outlet
Inlet
Outlet
D-1001
D-1001
Cooling Water
Cooling Water
115,300
115,300
400,000
400,000
150
100
90
130
527
525
40
35
Flow Type
Shell Type
LMTD
U
A
Heat Duty
Counter Current
One Pass
14.61 F
253.8 BTU/hr-sqft-R
4010 sqft
14808490 BTU/hr
Tube OD
Tube Length
No. Tubes
Shell OD
Baffle Spacing
Material
0.75 in
20 ft
520
24.625 in
12.5 in
Carbon Steel
$47,200
$283,200
Comments:
222
Heat Exchanger
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
(per Unit)
Utilities:
Item
Item No.
H-1003
No. Required
1
Cool distillate vapor with chilled water
Continuous
Performance of Unit
Shell Side
Tube Side
Inlet
Outlet
Inlet
Outlet
D-1001
D-1001
Chilled Water
Chilled Water
115,300
115,300
30,000
30,000
100
94
60
93
525
523
40
35
Flow Type
Shell Type
LMTD
U
A
Heat Duty
Counter Current
One Pass
13.9F
254.8 BTU/hr-sqft-R
268.2sqft
910822 BTU/hr
Tube OD
Tube Length
No. Tubes
Shell OD
Baffle Spacing
Material
0.75 in
20 ft
77
24.625 in
23.75 in
Carbon Steel
$15,700
$47,100
Comments:
223
Heat Exchanger
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
(per Unit)
Utilities:
Item
Kettle Reboiler
Item No.
H-1004
No. Required
1
Return vapor to distillation column
Continuous
Performance of Unit
Shell Side
Inlet
Outlet
HP Steam
HP Steam
15,000
15,000
400
400
246
241
Flow Type
Shell Type
LMTD
U
A
Heat Duty
Counter Current
One Pass
51.1 F
738 BTU/hr-sqft-R
738 sqft
11034339 BTU/hr
Tube Side
Inlet
D-1001
109,300
304
534
Outlet
D-1001
109,300
328
529
Tube OD
Tube Length
No. Tubes
Shell OD
Baffle Spacing
Material
Carbon Steel
$28,100
$84,300
Comments:
224
Heat Exchanger
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
(per Unit)
Utilities:
Item
Item No.
H-1005
No. Required
1
Return condensate to distillation column
Continuous
Performance of Unit
Shell Side
Tube Side
Inlet
Outlet
Inlet
Outlet
Refrig. Propylene
Refrig. Propylene
D-1001
D-1001
35,000
35,000
109,300
109,300
2.5
2.5
45
11
51
46
650
645
Flow Type
Shell Type
LMTD
U
A
Heat Duty
Counter Current
One Pass
27.81 F
386.7 BTU/hr-sqft-R
359 sqft
3471287 BTU/hr
Tube OD
Tube Length
No. Tubes
Shell OD
Baffle Spacing
Material
0.75 in
14 ft
134
24.625 in
13.25 in
Carbon Steel
35,000 lb/hr of Refrigerated Propylene
$25,700
$77,100
Comments:
225
Heat Exchanger
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
(per Unit)
Utilities:
Item
Kettle Reboiler
Item No.
H-1006
No. Required
1
Return vapor to distillation column
Continuous
Performance of Unit
Shell Side
Inlet
Outlet
LP Steam
LP Steam
6,000
6,000
230
227
20
19
Flow Type
Shell Type
LMTD
U
A
Heat Duty
Counter Current
One Pass
35.72 F
219.0 BTU/hr-sqft-R
553 sqft
4025542 BTU/hr
Tube Side
Inlet
Outlet
D-1001
D-1001
109,300
109,300
304
328
534
529
Tube OD
Tube Length
No. Tubes
Shell OD
Baffle Spacing
Material
Carbon Steel
6,000 lb/hr of LP Steam
$27,600
$82,600
Comments:
226
Heat Exchanger
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Design Data
(per Unit)
Utilities:
Cost
Information:
Item
Item No.
H-1007
No. Required
1
Condense propylene refrigerant
Continuous
Performance of Unit
Shell Side
Tube Side
Inlet
Outlet
Inlet
Outlet
Refrig.Propylene
Refrig. Propylene
Cooling Water
Cooling Water
35,000
193
375
35,000
100
372
150,000
90
40
150,000
130
35
Flow Type
Shell Type
LMTD
U
Counter Current
One Pass
25.09 F
120.0 BTU/hr-sqft-R
A
Heat Duty
2028 sqft
5988421 BTU/hr
Tube OD
Tube Length
No. Tubes
Shell OD
Baffle
Spacing
Material
0.75 in
20 ft
525
24.625 in
10.25in
Carbon Steel

$41,000
$123,000
Comments:
227
Fired Heater
Identification:
Function:
Operation:
Stream
Flow Rate (lb/hr)
Temperature (F)
Pressure (psi)
Item
Fired Heater
Item No.
F-701
No. Required
1
Preheat hydrocarbon byproducts to reactor temperature
Continuous
Performance of Unit
Inlet
Outlet
S-705
S-706
149,300
665
95
149,300
932
90
Heat Duty:
26.3 MMBTU/hr
Design Data
(per Unit)
Utilities:
Cost
Information:
$800,000 natural gas/year

$781,800
$1,712,200
Comments:
228
EQUIPMENT COST
SUMMARY
229
12. Equipment Cost Summary

Equipment Type
Compressors
C-201
C-202
C-203
C-401
C-801
C-901
C-902
C-903
C-1001
C-1002
Distillation Towers
D-501
D-801
D-1001
D-1002
Other Towers
T-301
T-302
T-501
Heat Exchanger
H-101 to 106
H-201
H-202
H-203
H-204
H-205
H-206
H-301
H-302
H-303
H-304
H-401
H-402
Purchase Cost ($) Bare Module Cost ($)

3,653,083
1,601,973
3,001,443
2,230,000
896,465
916,744
610,419
290,233
249,070
318,140
7,854,128
3,444,242
5,136,009
4,790,000
1,927,400
1,971,000
1,312,400
624,000
535,500
684,000
298,000
185,096
926,683
367,813
1,240,000
770,000
3,855,000
1,530,100
1,213,975
931,055
269,000
5,050,136
3,873,189
1,120,000
3,732,960
50,140
43,809
41,706
50,140
48,137
47,892
389,800
38,278
215,776
78,494
59,100
80,200
7,689,898
158,944
138,875
132,208
158,944
152,594
152,013
1,235,666
121,341
684,010
221,437
937,000
251,000
230
H-501
H-502
H-503
H-601
H-602
H-603
H-604
H-605
H-606
H-607
H-608
H-701
H-702
H-801
H-802
H-803
H-804
H-901
H-902
H-903
H-1001
H-1002
H-1003
H-1004
H-1005
H-1006
H-1007
54,700
312,000
64,400
23,853
42,200
226,600
372,368
263,000
585,700
173,600
335,600
62,600
614,700
157,500
172,800
180,200
47,100
98,400
63,500
15,500
30,800
94,400
15,700
28,100
25,700
27,600
41,000
520,000
660,000
202,000
71,559
126,600
679,800
1,117,104
789,000
1,757,100
520,800
1,006,800
187,800
1,844,100
472,500
518,400
540,600
141,300
295,200
190,500
46,500
92,400
283,200
47,100
84,300
77,100
82,800
123,000
P-201
P-202
P-301
P-501
P-502
P-503
P-504
P-505
P-506
P-507
160,656
9,232
44,212
3,600
4,600
10,100
7,700
4,500
6,400
15,500
530,165
30,466
156,007
11,800
15,100
33,400
25,300
14,700
21,100
51,200
Pumps
231
P-601
P-602
P-801
P-802
P-803
P-804
P-901
P-902
P-903
P-1001
P-1002
P-1003
P-1004
P-1005
P-1006
Reactors
R-201, 202, 203, 204
R-401
R-601
R-602
R-603
R-604
R-701
R-702
R-703
Storage Vessels
M-101
M-102 to 107
DME Storage
V-1003
V-1004
Flash Vessels
V-301
V-302
V-501
V-502
V-503
V-801
14,515
18,636
6,727
4,697
7,000
4,200
36,576
35,273
26,485
10,121
5,152
13,030
3,939
4,636
5,394
47,900
61,500
22,200
15,500
23,200
13,700
120,700
116,400
87,400
33,400
17,000
43,000
13,000
15,300
17,800
92,773,533
1,000,000
139,410
139,410
139,410
139,410
64,590
64,590
64,590
172,558,771
5,000,000
425,200
425,200
425,200
425,200
197,000
197,000
197,000
1,208,373
2,111,589
1,260,000
486,557
689,508
1,208,373
2,111,589
1,260,000
1,484,000
2,103,000
15,922
33,813
66,600
112,200
32,600
42,721
48,564
103,132
212,000
342,000
99,700
130,300
232
V-802
V-901
V-902
V-1001
V-1002
24,492
24,557
24,295
93,607
86,885
74,700
74,900
74,100
285,500
265,000
2,635,975
21,028,255
18,120,000
8,492,549
781,826
6,062,743
21,028,255
58,165,200
8,492,549
1,712,200
179,325,393
356,954,210
Other
X-101, 102, 103
X-104 to 111
X-201
Misc Solids Handling
F-701
Total
233
ENERGY BALANCE
AND UTILITY
REQUIREMENTS
234
13. Energy Balance and Utility Requirements

Overview:
This plant uses boiler feed water, cooling water, chilled water, electricity, 6 different
qualities of steam, and natural gas. The annual cost of each utility is shown in Table 13.1
Combining all utilities together, the annual expenditure on utilities comes to $19,600,000. All
utility cost estimates come from Seider 2009.
Table 13.1. Summary of Utility Costs.

Utility
Annual Cost
Electricity
$4,945,000
Boiler-Feed Water
$1,700,000
Chilled Water
$2,519,000
Cooling Water
$5,640,000
Steam
$2,405,265
Natural Gas
$2,395,000
$19,604,265
Total:
Electricity:
The majority of the plants electricity demand comes from compressors needed to
increase the pressure of vapor streams prior to reaction or separation steps. Other uses for
electricity include solids handling equipment, electric pump motors, and an aerator for the
aerated wastewater treatment lagoon, as shown on the next page in Table 13.2. A large portion of
the electricity needs to be purchased from the grid at an estimated cost of $0.060/kWh. However,
47% of the total electricity demand is met by the turbine C-203 that uses high-pressure, superheated steam produced using heat recovered from the gasifiers effluent. A net of 10,406 kW is
required from the grid, which totals to 82,420,000 kWh annually. The cost of purchasing this
electricity is $4,945,000.
235
Utility Type
Electricity (kWh)
Equipment Unit
Usage
Usage/lb propylene
X-101, 102, 103
168
0.0042
H-101 to 106
447
0.0111
X-104 to 111
716
0.0178
Misc Solid Hndlg
955
0.0237
Aerator
0.81
0.0000
C-201
9,140
0.2271
C-202
3,262
0.0810
C-203
-9,321
-0.2315
C-401
4,900
0.1217
C-801
1,577
0.0392
C-901
1,623
0.0403
C-902
978
0.0243
C-903
386
0.0096
P-201
292
0.0073
P-202
21
0.0005
P-301
416
0.0103
P-501
0.50
0.0000
P-502
2.56
0.0001
P-503
16.8
0.0004
P-504
3.70
0.0001
P-505
2.11
0.0001
P-506
1.09
0.0000
P-507
60.9
0.0015
P-601
40.6
0.0010
P-602
58.6
0.0015
P-801
10.7
0.0003
P-804
0.2
0.0000
P-802
15
0.0004
P-803
14
0.0003
P-901
65
0.0016
P-902
53
0.0013
P-903
45
0.0011
P-1003
23
0.0006
P-1001
0.0001
P-1006
1.5
0.0000
P-1004
0.18
0.0000
P-1005
0.0001
P-1006
0.0002
Total:
10,406
0.2585
Table 13.2. Electricity

Requirements by Unit
236
Boiler-Feed Water:
Boiler-feed water is used in this process in heat exchangers to vaporize to steam. This is
an effective method to recover and reuse heat from the high-temperature reactor effluent streams,
rather than merely disposing the heat to cooling water. A summary of the by-unit boiler-feed
water requirements is shown in Table 13.3.
Table 13.3. Boiler-Feed Water Requirements by Unit.
Utility Type
Boiler Feed Water (gal/hr)
Equipment Unit
R-401
H-604
H-605
H-606
H-607
Usage
21,000
20,700
23,400
36,000
10,000
Usage/lb propylene
0.5217
0.5142
0.5813
0.8943
0.2484
H-801
8,000
0.1987
Total:
119,100
2.9586
These values are calculated assuming that 5% make-up is required to maintain the necessary
quantity of boiler-feed water in the system. In total, 119,100 gal/hr is required, which translates
to 943,350,000 gal/yr. At a cost of $1.80/1000 gal, this comes to an annual cost of $1,700,000.
Chilled Water:
It is assumed that chilled water is available in the plant at a temperature of 45F, and is
taken to a maximum temperature of 90F. A summary of chilled water usage is shown below in
Table 13.4.
Table 13.4. Chilled Water Requirements by Unit
Utility Type
Chilled Water (ton/hr)
Equipment Unit
H-501
Usage
233
Usage/lb propylene
0.0058
H-1003
31.6
0.0008
Total:
265
0.0066
A ton of cooling is defined as 12,000 BTU/hr. Chilled water is available as a plant-wide utility at
a cost of $1.20/ton-day. This cost takes into account the cost of equipment for a refrigeration
cycle as well as the electricity requirement to operate that cycle. A total of 2,099,000 tons of
cooling is required annually from chilled water, which costs $2,519,000.
237
Cooling Water:
Cooling water is available within the plant at a temperature of 90F and is taken to a
maximum temperature of 130F. A summary of cooling water usage is shown below in Table
13.5.
Table 13.5. Cooling Water Requirements by Unit.

Utility Type
Cooling Water (gal/hr)
Equipment Unit
C-201
Usage
96,960
Usage/lb propylene
2.4086
C-202
39,540
0.9822
H-301
460,140
11.4306
H-302
H-304
H-402
65,940
248,100
300,000
1.6381
6.1632
7.4525
H-501
216,000
5.3658
H-503
H-802
H-804
H-901
H-902
H-903
204,000
5,000,000
1,400,000
550,000
300,000
225,000
5.0677
124.2082
34.7783
13.6629
7.4525
5.5894
H-1002
400,000
9.9367
Total:
9,505,680
236.1366
Cooling water is available as a plant-wide utility at a cost of $0.075/1000 gal. This cost takes
into account the re-cooling of the cooling water to a temperature of 90F after it is used. The
water is cooled by running it through a cooling tower where water is evaporated into the
surrounding air, and heat is removed through the latent heat of evaporation. A total of 9,505,000
gal/hr of cooling water is required. As an annual rate, this translates to 75,280,000,000 gal/yr,
which costs $5,640,000.
Steam:
Six different qualities of steam are produced or consumed by the plant, ranging from 50
to 1800 psi, as shown in Table 13.6.
238
Table 13.6. Steam Requirement by Quality and Unit.

Utility Type
Steam (50 psi, lb/hr)
Equipment Unit
V-503
H-803
H-1006
Total:
H-204
T-302
H-701
Total:
C-203
R-401
H-502
H-601
H-602
H-1004
Total:
R-201 to 204
H-603
H-604
H-605
H-606
Usage
-23,400
80,000
6,000
62,600
-65,000
168,105
60,000
163,105
-120,000
-264,000
191,500
7,762
73,532
12,255
21,049
46,840
36,000
-20,700
-23,400
-36,000
Usage/lb propylene
-0.5813
1.9873
0.1490
1.5551
-1.6147
4.1760
1.4905
4.0518
-2.9810
-6.5582
4.7572
0.1928
1.8267
0.3044
0.5229
1.1636
0.8943
-0.5142
-0.5813
-0.8943
H-607
-10,000
-0.2484
Total:
-54,100
-1.3439
Steam is required for preheating reactor feeds, heating distillation and stripping tower reboilers,
and as a reactant feed into the woodchip gasifiers. Some steam is produced internally by using
hot reactor effluents to boil boiler-feed water. This steam production is enough to meet 62% of
the plants steam requirements. The remaining steam needs to be purchased from off-site
sources. For the 300 psi and 1800 psi steam, the steam could not be efficiently used within the
plant, and therefore is sold to off-site buyers to subsidize the cost of steam that needs to be
purchased. In total, the plant requires 5,400,000,000 lb/yr of all the qualities of steam combined.
Purchasing all of this steam would require $31,600,000. However, by using the recovered heat
from reactor effluents to generate steam internally, enough steam is produced to cover 92% of
the steam utility costs. This comes to a net of $2,400,000 annual steam cost, as shown in Table
13.7.
239
Table 13.7. Annual Usage and Cost of Steam by Quality

Steam Pressure Annual lbs Required $ / 1000 lb Annual Cost
50
495,792,000.00
$3.00
$1,487,376
150
1,291,791,600.00
$4.80
$6,200,600
300
-950,400,000.00
$5.93
($5,635,872)
500
$6.77
$1,128,610
166,707,574.47
1250
370,972,800.00
$8.27
$3,067,945
1800
-428,472,000.00
$8.97
($3,843,394)
TOTAL:
$2,405,265
Natural Gas:
Natural gas is required to heat the gasifiers and furnace F-701. A summary of the natural
gas usage is shown below in Table 13.8.
Table 13.8. Natural Gas Usage by Unit
Utility Type
Equipment Unit
R-201 to 204
Usage
76,722,241
Usage/lb propylene
1905.9059
Natural gas, (BTU/hr)
F-701
26,300,000
653.3350
Total:
103,022,241
2559.2409
A total of 103 MMBTU/hr is required from natural gas. At a heating value of 1090 BTU/SCF,
this translates to 748,565,000 SCF per year. At a cost of $3.20/1000 SCF, natural gas costs
$2,395,000 annually.
Wastewater Treatment:
Stream WASTE in Block 400 is a wastewater stream that needs to be treated before being
disposed. Furthermore, the stream STEAM in Block 400 will eventually go to waste after its
energy has been used and the steam has been condensed back into water with some organics.
Typically, the wastewater would be disposed of through the municipal treatment system at a cost
of approximately $0.15/lb of organic removed. This would have amounted to an annual cost of
approximately $1.2 million.
Instead, an aerated lagoon was used. An aerated lagoon is a man-made pond with
artificial aeration to promote the growth of microbes that remove pollutants from the water. With
the wastewater flow rate of 10,200 gal/hr, a pond 3 m deep with a surface area of 23,000 sqft is
240
required to operate at 75 percent capacity with a standard residence time of 7 days. Operating at
75 percent capacity allows for the buildup of sludge without overflowing the banks of the
lagoon, and 7 days is sufficient time for degradation of the organic materials in the wastewater.
Building the lagoon will cost $775,000 with an annual operating cost of $400 to power
the electric, floating aerator (6400 kW-hr). Minimal maintenance is required for the operation of
the lagoon. Current operational lagoons with comparable flow rates and organics concentrations
have been used for over 25 years without any removal of sludge and have shown no decrease in
performance. Therefore, it is assumed that no de-sludging will be required over the lifespan of
the plant. Furthermore, the average lifespan of an aerator is 10 years, with a replacement cost of
$2,500 per aerator.
241
FIXED-CAPITAL
INVESTMENT
SUMMARY
242
14. Fixed-Capital Investment Summary

The fixed costs for the plant come mostly from the equipment costs, which were previously
shown by unit in the equipment cost summary beginning on page 221. The bare module cost for
each piece of equipment was obtained by multiplying the purchase cost by a bare module factor
which includes allowances for cost of installation materials, installation labor, freight, taxes,
insurance, construction overhead, and contractor engineering expenses. In addition to equipment
bare module costs, there are other factors, summarized in Table 14.1, that have significant
contributions to the fixed cost.
Table 14.1. Summary of Total Permanent Investment Factors.
Cost of Site Preparations:
Cost of Service Facilities:
Allocated Costs for utility plants and related
facilities:
5.00%
5.00%
of Total Bare Module Costs

of Total Bare Module Costs
Cost of Contingencies and Contractor Fees:
18.00%
of Direct Permanent Investment
Cost of Land:
2.00%
of Total Depreciable Capital
Cost of Royalties:
$0
Cost of Plant Start-Up:
10.00%
$775,000
of Total Depreciable Capital
The cost of site preparations is assumed to be 5% of the total bare module costs. This is
because, with the plant being located in the Southeast relatively close to the Gulf Coast, there
should already be a well-established infrastructure including roads, sewer lines, drainage, etc.
Therefore, 5% should be a reasonable estimate.
Service facility costs include utility lines, control rooms, maintenance shops, and other
buildings within the plant complex. Seider et al. recommends the factor of 5% of total bare
module costs, and this estimate in considered to be conservative for most plant setups and
locations. The allocated costs for utility plants and related facilities are for the aerated lagoon
that will be constructed for treating all of the plants wastewater streams.
The cost of contingencies and contractor fees is a combination of an allowance of 15% of
the direct permanent investment (DPI) for contingencies and an allowance of 3% for contractor
fees. Contingencies are given an estimate of 15% of the DPI because the majority of the
technologies in this process, with the exception of the microchannel reactor, are fairly well
known and commonly used. However, the process as a whole, producing propylene from a
feedstock of woodchips, has not previously been developed at a commercial scale. Thus, 15% of
243
the DPI should be reasonable for any unexpected events during plant construction and start-up.
Additionally, the cost of land is estimated at 2% of the total depreciable capital (TDC). As with
the contingency costs, since the majority of the technologies used in this process are well-known,
but the overall process has not yet been proven at a commercial scale, an estimate of 10% of the
TDC for plant start-up should be sufficient.
Taking these factors into account, the DPI, TDC, and total permanent investment were
calculated and are displayed on the next page in Table 14.2. The total permanent investment is
estimated to be $525,000,000.
244
Table 14.2. Summary of Fixed Capital Investment.

Investment Summary
Bare Module Costs
Fabricated Equipment
Process Machinery
Spares*
Storage
Other Equipment
Catalysts
Computers, Software, Etc.
$
$
$
$
$
$
$
225,802,185
29,815,917
8,166,962
95,460,947
909,378
-
Total Bare Module Costs:
360,155,388
396,945,927
468,396,194
Total Permanent Investment - Unadjusted

Site Factor
524,603,737
1.00
Total Permanent Investment
524,603,737
Direct Permanent Investment

Cost of Site Preparations:
$
Cost of Service Facilities:
$
Allocated Costs for utility plants and related facilities: $
18,007,769
18,007,769
775,000
Direct Permanent Investment
Total Depreciable Capital

Cost of Contingencies & Contractor Fees
71,450,267
Total Depreciable Capital

Total Permanent Investment
Cost of Land:
Cost of Royalties:
Cost of Plant Start-Up:
$
$
$
9,367,924
46,839,619
Rather than include costs for in-line spares, an allowance for preventative maintenance and shelf-spares is included
in the annual maintenance cost at the suggestion of Mr. Wismer
245
OPERATING COST AND

ECONOMIC ANALYSIS
246
15. Operating Cost and Economic Analysis

The economic analysis is based on results calculated using the Profitability Analysis
Spreadsheet 3.0 provided by Seider et al. Below in Table 15.1 is a summary of an operating
time-table and assumptions that are used to perform the analysis. An overall inflation rate of 3%
is assumed.
Table 15.1. Summary of Economic Analysis Inputs
General Information
Process Title:
Product:
Plant Site Location:
Site Factor:
Operating Hours per Year:
Operating Days Per Year:
Operating Factor:
Propylene from Biomass

Propylene
Georgia
1.00
7920
330
0.9041
Product Information
This Process will Yield
40,255
966,120
318,819,600
Price
$0.81
lb of Propylene per hour

lb of Propylene per day
lb of Propylene per year
/lb
Chronology
Year
2011
2012
2013
2014
2015
2016
2017
2018
2019
2020
2021
2022
2023
2024
2025
2026
2027
2028
2029
Action
Design
Construction
Construction
Construction
Production
Production
Production
Production
Production
Production
Production
Production
Production
Production
Production
Production
Production
Production
Production
Distribution of
Permanent Investment
100%
0%
0%
0%
Production
Capacity
0.0%
0.0%
0.0%
0.0%
50.0%
75.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
100.0%
Depreciation
5 year MACRS
20.00%
32.00%
19.20%
11.52%
11.52%
5.76%
Product Price
$0.81
$0.83
$0.85
$0.88
$0.91
$0.93
$0.96
$0.99
$1.02
$1.05
$1.08
$1.11
$1.15
$1.18
$1.22
247
Operating Cost Summary:

Variable Costs:
Variable costs for this plant include general expenses, raw materials, and utilities. Also
included in the variable costs is the revenue generated from the two by-products, chemical grade
ethylene, which has a current market value of $0.53 per lb, and carbon dioxide that can be sold to
beverage companies at a price of $50 per ton. In total these by-products generate an annual
revenue of $69,800,000.
General expenses include allowances for sales expenses, research costs, administrative
expenses, and management incentives. Since this process as a whole is a new technology, it is
assumed there will be significant research costs to continuously modify and improve the process
and process equipment. Because of this, direct research is estimated at 4.8% of sales and
allocated research is estimated at 0.5% of sales.
The two raw materials used in the plants are woodchips, which are purchased at $42.00
per dry ton. This price includes the transportation of the woodchips to the facility and assumes
the woodchips are all obtained within a 50 mile radius of the plant. A total of 750,000 metric
tons per year of woodchips is required, which amounts to 16% of Georgias unused woodchip
supply, and 6% of the states total woodchip supply. The other raw material required is MEA for
the removal of carbon dioxide from the syngas stream. MEA is available at $0.025 per lb and a
total of 1,350,000 lbs are required annually.
Utilities are a major expense in this process, and are discussed in detail in the utilities
section of this report, beginning on page 226. All utility costs were obtained from Seider 2009. A
summary of the annual variable costs incurred for this project are shown in Table 15.2 on the
following page.
248
Table 15.2 Summary of Annual Variable Costs.

Variable Cost Summary
Variable Costs at 100% Capacity:
General Expenses
Selling / Transfer Expenses:
Direct Research:
Allocated Research:
Administrative Expense:
Management Incentive Compensation:
Total General Expenses
$
$
$
$
$
7,699,493
12,319,189
1,283,249
5,132,996
3,208,122
29,643,049
Raw Materials
$0.106456 per lb of Propylene
$33,940,125
Byproducts
($69,810,653)
Utilities
$17,678,123
Total Variable Costs
11,450,644
Fixed Costs:
Fixed costs are costs that are incurred by the project regardless of the amount of
propylene that is produced. These include things such as salaries and benefits, maintenance costs,
operating overhead, taxes, and insurance. A summary of the fixed costs are shown in Table 15.3.
The fixed costs come to a total of $50,800,000.
249
Table 15.3. Summary of Annual Fixed Costs.

Fixed Cost Summary
Operations
Direct Wages and Benefits
Direct Salaries and Benefits
Operating Supplies and Services
Technical Assistance to Manufacturing
Control Laboratory
$
$
$
$
$
3,640,000
546,000
218,400
-
Total Operations
4,404,400
Wages and Benefits

Salaries and Benefits
Materials and Services
Maintenance Overhead
$
$
$
$
14,051,886
3,512,971
14,051,886
421,557
Total Maintenance
32,038,300
General Plant Overhead:

Mechanical Department Services:
Employee Relations Department:
Business Services:
$
$
$
$
1,544,311
522,021
1,283,301
1,609,563
Total Operating Overhead
4,959,195
9,367,924
Maintenance
Operating Overhead
Property Taxes and Insurance

Property Taxes and Insurance:
Other Annual Expenses
Total Fixed Costs
Rental Fees (Office and Laboratory Space):

Licensing Fees:
Miscellaneous:
$
$
$
Total Other Annual Expenses
50,769,819
250
Working Capital:
Working capital is defined as the sum of the cash reserves, inventory, and accounts
receivable less accounts payable. It is assumed that the accounts payable is equal to 30 days
worth of feedstock, accounts receivable is 30 days worth of sales, there are 30 days of cash
reserves, and an inventory of 1 day worth of propylene is stored on-site. A summary of the
working capital for the first three years of production is shown in Table 15.4. Based on these
values of working capital and the total permanent investment of $524,600,000 as discussed
earlier, the total capital investment is calculated to be $540,000,000.
Table 15.4. Summary of Working Capital.
Working Capital
Accounts Receivable
Cash Reserves
Accounts Payable
Propylene Inventory
Raw Materials
Total
$
$
$
$
$
$
Present Value at 15%
2014
10,547,251
2,812,929
(2,121,298)
351,575
1,394,800
12,985,257
Total Capital Investment
$
$
$
$
$
$
8,538,017 $
$
2015
5,273,626
1,406,465
(1,060,649)
175,788
697,400
6,492,629
$
$
$
$
$
$
3,712,181 $
2016
5,273,626
1,406,465
(1,060,649)
175,788
697,400
6,492,629
3,227,984
540,081,920
Cash Flow and Profitability Analysis:

The profitability and feasibility of this project are based on several measures, including
the return on investment (ROI), net present value (NPV), and investors return on investment
(IRR). As a base-case, it is assumed that the whole project will last for 19 years, 1 year for
planning, 3 years for construction, and 15 years for production. Based on this operating schedule
and the values and assumptions presented in the investment and operating expense summaries,
the ROI in the third year of production is 18.8%, the IRR is 17.53%, and the NPV, assuming a
discount rate of 15% as recommended by Seider 2009, is $87,800,000. A summary of the cash
flows and NPV calculation is shown in Table 15.5.
251
Table 15.5. Propylene from Biomass Cash Flow Summary.
Cash Flow Summary

Year
2011
2012
2013
2014
2015
2016
2017
2018
2019
2020
2021
2022
2023
2024
2025
2026
2027
2028
2029
Sales
128,324,900
198,262,000
272,279,700
280,448,100
288,861,600
297,527,400
306,453,300
315,646,900
325,116,300
334,869,700
344,915,800
355,263,300
365,921,200
376,898,900
388,205,800
Capital Costs Working Capital

(524,603,700)
(12,985,300)
(6,492,600)
(6,492,600)
25,970,500
Var Costs
(5,725,300)
(8,845,600)
(12,148,000)
(12,512,400)
(12,887,800)
(13,274,400)
(13,672,700)
(14,082,800)
(14,505,300)
(14,940,500)
(15,388,700)
(15,850,400)
(16,325,900)
(16,815,700)
(17,320,100)
Cumulative Net
Fixed Costs Depreciation Taxible Income
Taxes
Net Earnings Cash Flow Present Value at 15%
- (524,603,700)
(456,177,200)
(456,177,200)
(12,985,300)
(464,715,200)
(50,769,800) (93,679,200)
(21,849,491)
8,084,300 (13,765,200)
73,421,400
(422,736,200)
(52,292,900) (149,886,800)
(12,763,365)
4,722,400
(8,040,900) 135,353,200
(355,441,800)
(53,861,700) (89,932,100)
116,337,991 (43,045,100) 73,292,900 163,225,000
(284,875,100)
(55,477,600) (53,959,200)
158,498,920 (58,644,600) 99,854,300 153,813,600
(227,050,900)
(57,141,900) (53,959,200)
164,872,665 (61,002,900) 103,869,800 157,829,000
(175,456,300)
(58,856,100) (26,979,600)
198,417,243 (73,414,400) 125,002,900 151,982,500
(132,253,400)
(60,621,800)
232,158,770 (85,898,700) 146,260,000 146,260,000
(96,100,100)
(62,440,500)
239,123,533 (88,475,700) 150,647,800 150,647,800
(63,719,400)
(64,313,700)
246,297,239 (91,130,000) 155,167,300 155,167,300
(34,717,500)
(66,243,100)
253,686,156 (93,863,900) 159,822,300 159,822,300
(8,741,900)
(68,230,400)
261,296,741 (96,679,800) 164,616,900 164,616,900
14,523,100
(70,277,300)
269,135,643 (99,580,200) 169,555,500 169,555,500
35,360,600
(72,385,600)
277,209,712 (102,567,600) 174,642,100 174,642,100
54,023,700
(74,557,200)
285,526,004 (105,644,600) 179,881,400 179,881,400
70,739,300
(76,793,900)
294,091,784 (108,814,000) 185,277,800 211,248,300
87,809,200
252
Sensitivity Analysis:
Now that base-case profitability has been determined, more detailed analyses need to be
considered that take into account potential fluctuations in market conditions and plant operations.
Product Price and Variable Costs:

The first sensitivity analysis performed looks at the effect of both the propylene price and
annual variable costs incurred from plant operation. The propylene price has recently spiked to
record highs due to the decline in ethylene demand, and it is expected that the propylene price
will continue to rise. However, since plant production is currently projected to begin in 2015, it
is quite possible that by then either the ethylene demand will have recovered, thereby bringing
more propylene production plants back online, or sufficient on-purpose propylene plants will be
constructed to meet the demand, thereby reducing the propylene cost. On the other hand, it is
also possible that propylene demand will continue to outstrip supply, and by the time production
begins propylene will have an even higher price. To account for these potential variations, the
IRR was analyzed at an initial propylene price range from $0.40 to $1.21, which corresponds to
plus/minus 50% of the base-case value, $0.805 per lb or propylene. Note that these prices are for
the first year of production only, and then they increase by 3% each year to account for inflation.
Since this will be the first commercial-scale propylene-from-biomass plant, it is highly
likely that the variable cost estimations are significantly different from what the variable costs
will be in reality. Therefore, the change in the IRR was analyzed for variable costs ranging from
$5,700,000 to $17,200,000, which corresponds to plus/minus 50% of the estimated variable costs
of $11,450,000. Table 15.6 shows the results of the product price and variable cost sensitivity
analysis.
253
Product Price
Table 15.6. Sensitivity Analysis of IRR towards Propylene Price and Variable Costs.
$0.40
$0.48
$0.56
$0.64
$0.72
$0.81
$0.89
$0.97
$1.05
$1.13
$1.21
Variable Costs
$5,725,322 $6,870,387 $8,015,451 $9,160,515 $10,305,580 $11,450,644 $12,595,709 $13,740,773 $14,885,838 $16,030,902 $17,175,966
6.46%
6.31%
6.15%
6.00%
5.84%
5.68%
5.52%
5.36%
5.19%
5.02%
4.85%
9.49%
9.37%
9.24%
9.12%
8.99%
8.86%
8.73%
8.60%
8.47%
8.34%
8.21%
12.01%
11.91%
11.80%
11.69%
11.59%
11.48%
11.37%
11.26%
11.15%
11.04%
10.92%
14.20%
14.11%
14.01%
13.92%
13.82%
13.73%
13.63%
13.54%
13.44%
13.34%
13.24%
16.15%
16.06%
15.98%
15.89%
15.81%
15.72%
15.64%
15.55%
15.46%
15.38%
15.29%
17.91%
17.84%
17.76%
17.68%
17.60%
17.53%
17.45%
17.37%
17.29%
17.21%
17.13%
19.54%
19.47%
19.39%
19.32%
19.25%
19.18%
19.11%
19.03%
18.96%
18.89%
18.81%
21.04%
20.98%
20.91%
20.84%
20.78%
20.71%
20.64%
20.57%
20.50%
20.44%
20.37%
22.45%
22.39%
22.33%
22.27%
22.20%
22.14%
22.08%
22.01%
21.95%
21.88%
21.82%
23.78%
23.72%
23.66%
23.60%
23.54%
23.48%
23.42%
23.36%
23.30%
23.24%
23.18%
25.04%
24.98%
24.93%
24.87%
24.81%
24.76%
24.70%
24.64%
24.59%
24.53%
24.47%
254
For the extent of this sensitivity analysis, even in the worst case scenario of a 50%
overestimate of the propylene price and a 50% underestimate of the variable costs, the project
still comes out with a positive IRR of 4.85%, but has a NPV of $-247,000,000. If the propylene
price drops below $0.68 per lb, regardless of the variable costs, the NPV for the project will go
negative. Therefore, the propylene price should be monitored closely in the coming months to
determine whether or not it will stabilize above $0.68 per lb.
In the best case scenario, with a 50% underestimate of the propylene price and a 50%
overestimate of variable costs, the IRR comes out to 25.04% with an NPV of $423,000,000.
These values can be compared to the base-case that has an IRR of 17.53% and an NPV of
$87,800,000.
Based on these results, the feasibility of this project is highly sensitive to the propylene
price. However, it is relatively insensitive to the annual variable costs, which is promising since
the variable cost estimate for this new plant-type is likely subject to drastic changes.
Inflation Rate:
For the base-case, it was assumed that the overall inflation rate is 3%, which is based on
the historic average inflation rate in the United States of 3.48%. However, the inflation rate has
seen drastic changes throughout history, ranging from 23.7% to -15.8%. Although reaching these
extremes is unlikely during the life of the plant, some fluctuation in the inflation rate is to be
expected. For example, the most recent reported inflation rate value is 2.1% in February of 2011.
For this reason, an analysis of the sensitivity of the NPV to the inflation rate was performed and
is summarized in Table 15.7.
Table 15.7. Sensitivity Analysis of NPV towards Inflation Rate
Inflation Rate
NPV
-2%
$ (23,128,400)
-1%
$ (3,913,400)
0%
$ 16,671,000
1%
$ 38,738,100
2%
$ 62,407,000
3%
$ 87,809,200
4%
$ 115,086,700
255
If the inflation rate increases to anything above the base-case value of 3%, there will be a
positive effect on the NPV, meaning the profitability of the project increases. Conversely, if the
inflation rate decreases, the NPV decreases as well. The break-even inflation rate is -0.80%.
However, historically, deflation is a relatively rare and short-lived occurrence, and therefore it is
safe to assume that changes in the inflation rate will not change the overall feasibility of the
project.
Feedstock Price:
The feedstock price of $42.00 per dry ton of woodchips is a fairly conservative estimate
for plant operation in Georgia. This price was obtained assuming the entire supply of woodchips
can be obtained within a 50 mile radius of the plant. However, if the plant is located in close
proximity to large saw mills, it is possible that this radius could drop to 25 miles, which would
reduce the cost to $30.00 per dry ton. On the other hand, if in reality woodchips need to be
obtained from a distance of up to 75 miles away, the added cost of transportation will increase
the cost to $55.00 per dry ton. The effect of this potential change in feedstock price is displayed
below in Table 15.8.
Table 15.8. Sensitivity Analysis of NPV towards Feedstock Price
Feedstock Price
NPV
($/dry ton)
$
30.00 $ 111,623,000
$
42.00 $ 87,809,200
$
55.00 $ 62,011,000
$
86.00 $
As expected, any decrease in the woodchip price leads to an increase in the NPV, whereas an
increase in the price leads to a decrease in the NPV. However, even if the radius of woodchip of
obtainment needs to be increased by 50% to 75 miles, the NPV is still positive with a value of
$62,000,000. In fact, the feedstock price can more than double from the base case price of
$42.00 and the project can still have a positive NPV. The break-even woodchip price is $86.00
per dry ton.
256
Ethylene to Propylene Ratio:

In the base-case, for every lb of propylene that is produced, 0.242 lbs of ethylene is
produced. The amount of ethylene relative to propylene can be increased by recycling the
ethylene back to the propylene reactor, which will reform a portion of the ethylene to propylene.
This was not done for the base case because introducing a recycle stream vastly increases the
flow rates within process blocks 600-1000. However, it is possible that by recycling the ethylene,
a sufficient amount of profit would be generated that would cover the additional capital
investment cost of more, or larger, process units to handle the increased volume. For this reason
the sensitivity of the NPV to the ethylene to propylene production ratio, shown in Table 15.9.
Table 15.9. Sensitivity Analysis of NPV towards Ethylene to Propylene Ratio
lb Ethylene per
lb Propylene
0
0.05
0.1
0.15
0.2
0.2422
NPV
$ 106,721,800
$ 102,102,800
$ 97,903,700
$ 94,069,700
$ 90,555,200
$ 87,809,200
Based on this analysis, the more ethylene that can be converted to propylene, the better, which
makes sense because propylene has a higher per-carbon price than ethylene. However, without
specific costing information for the larger or additional process units, it is impossible to tell
whether or not the additional revenues from a higher selectivity to propylene is sufficient to
cover the increase in capital cost. This is something that would need to be investigated further.
Competitive Analysis:
With the economic analysis of the propylene-from-biomass (PFB) completed, it can now
be compared to other similar plants that have been researched. The most relevant comparison is
to compare the PFB process to Lurgis methanol-to-propylene (MTP) plant. The end of both
processes is nearly identical, converting methanol to propylene through a DME intermediate.
The two main differences between the processes are that the PFB process beings with a
woodchip feedstock whereas MTP begins with methanol as a feed, and the PFB uses a
257
microchannel reactor to increase the yield and selectivity of DME. A comparison between the
PFB and MTP plants are summarized below in Table 15.10.
Table 15.10. Comparison of PFB and MTP Processes.
The PFB process described in this report has a capital investment cost of $3,375 per
annual ton of propylene produced and a cost of production of $0.221 per lb of propylene. In
comparison, the MTP plant developed by Lurgi has a capital investment of $991 per annual ton
of propylene produced and a cost of production of $0.335 per lb of propylene. This provides an
interesting trade off. Purchasing all of the solids-handling equipment and gasifiers for the PFB
process creates a huge capital cost relative to the MTP process. However, the woodchip
feedstock is much cheaper than the methanol raw material required for the MTP process. As a
result, the cost of production for the PFB process is 34% lower per lb of propylene than the cost
of production for the MTP process. Unfortunately, Lurgi would not disclose any information
about the profitability or feasibility of their process, and therefore a direct comparison to the
profitability of the PFB process cannot be made. Nevertheless, with lower production costs, it is
possible that the PFB process may be able to compete on a commercial scale with existing
technologies. Additionally, since the PFB is a green process, it is possible that through future tax
credits or government subsidies, the process could become even more competitive with existing
industrial plants.
258
OTHER
CONSIDERATIONS
259
16. Other Considerations

Plant Startup
Because of the large amount of utilities required and the degree to which heat integration
is utilized, plant startup will require significant attention. Where outlets are used to preheat
feeds, such as in distillation columns or reactors, large startup heaters will be required.
Additionally, because much of our steam requirements are met using steam produced from one
of the several heat recovery steam regeneration systems, additional utilities will be required upon
startup.
Similarly, large recycle streams are incorporated into the DME Formation block and the
Steam Cracking block. Care will be needed to bring these cycles to continuous capacity.
These costs were assumed to be included in the startup cost factor incorporated into the
profitability analysis.
Plantwide Control
The lengthy process will require detailed system wide control in order to run optimally.
The DME intermediate is stored between blocks 500 and 600 to account for process fluctuations,
but it would be difficult to store the synthesis gas in any large quantity. The condensed olefin
feed to the product separation section could also be stored in the advent of process fluctuations,
as well as the combined ethylene/propylene stream.
Because of the heat integration and steam sharing of the process, boiler feed water and
steam flow rates and pressures will also need detailed control schemes.
Plant Layout
As alluded to earlier, solids handling and logistics will be a substantial portion of the
completed design and cost of the process. The optimal layout of the plant will require significant
attention that was beyond the scope of this design.
260
CONCLUSIONS
&
RECOMMENDATIONS
261
17. Conclusions and Recommendations

In summary, a base case process for the production of propylene from biomass has been
designed, costed, and analyzed under a variety of economic conditions. The process was shown
to have a positive NPV under a variety of situations. Without byproduct sales, variable costs
have a large impact on the profitability of the process, even with a large degree of heat
integration. The prices of the products have a large impact on the present value, and the relative
supply and demand of propylene and ethylene must be monitored throughout further design and
implementation. The proposed process has a higher capital cost per ton of propylene produced
than the conventional MTO process, but the cost of production is 34% lower.
Specific
profitability data for comparisons were not available to the public, so detailed comparisons with
conventional methods are still needed. Solids handling and gasification lead to most of the initial
capital expenditures, as well as drive the cost of the biomass feedstock.
We recommend that the base design be further pursued. Detailed siting and biomass supply
contracts will be vital to the success of the project, as well as the potential use of other biomass
sources. Detailed solids handling design will also be needed. Finally, further optimizing of
equipment items can be pursued to achieve better overall profitability and match current
propylene/ethylene demand.
262
ACKNOWLEDGEMENTS
263
18. Acknowledgements
The group wishes to thank Mr. John Wismer for his creation of the Propylene from
Biomass problem statement and his design assistance throughout.
We would also like to thank Dr. Wen K. Shieh for his valuable knowledge of biomass
feedstock and the logistics therein, as well as for his support and guidance along the way.
We also wish to thank Professor Leonard Fabiano for his invaluable help in developing
the process models with ASPEN, specifically with the detailed design of the monoethanol amine
absorption process section, and his vast industry experience.
Lastly, we thank the rest of the industry consultants for their time each Tuesday and for
their contribution of hugely helpful practical knowledge in equipment design and process
development.
Matthew Gay, Bryan Pope, and Jake Wharton
264
BIBLIOGRAPHY
265
19. Bibliography
Abbuehl, Christopher, Craig Hustwit, and Danette Delmastro. Biomass Energy - Focus on Wood
Waste. Federal Energy Management Program, 2004. Print.
Ariyapadi, Siva, Philip Shires, Manish Bhargava, and David Ebbern. KBR's Transport Gasifier
(TRIG) - An Advanced Gasification Technology for SNG Production From Low Rank
Coals. Pittsburgh, PA, 2008. Print.
Baratieri, M., P. Baggio, B. Bosio, M. Grigiante, and G.A. Longo. "The Use of Biomass Syngas
in IC Engines and CCGT Plants: A Comparative Analysis." Applied Thermal
Engineering 29 (2009): 3309-318. Print.
Bauman, R.F. et Al. High Throughput Propylene From Methanol Catalytic Process
Development Method. US Patent Application 0174129. Jul. 8, 2010.
Beech, J.H. et Al. Process for Converting Oxygenates to Olefins at Reduced Volumetric Flow
Rates. US Patent Application 0020155. Jan. 26, 2006.
Bozzano, A.G. et Al. Reactor System with Interstage Product Removal. US Patent 7,582,268.
Sep. 1, 2009.
Byers, Charles H. "An Aspen Simulation of Fuel Production by Hydrolysis of Woody Biomass."
Chemical Technology Division, Oak Ridge National Laboratory (1988): 143-57. Print.
Carpenter, Daniel L., Richard L. Bain, Ryan E. Davis, Abhijit Dutta, Calvin J. Feik, Katherine R.
Gaston, Whitney Jablonski, Steven D. Phillips, and Mark R. Nimlos. "Pilot-Scale
Gasification of Corn Stover, Switchgrass, Wheat Straw, and Wood: Parametric Study and
Comparison with Literature." Industrial Chemical Engineering 49 (2010): 1859-871.
Print.
266
Consonni, Stefano, Ryan E. Katofsky, and Eric D. Larson. "A Gasification-based Biorefinery
For The Pulp and Paper Industry." Chemical Engineering Research and Design 87
(2009): 1293-317. Print.
Craig, Kevin R., and Margaret K. Mann. Cost and Performance of Biomass-Based Integrated
Gasification Combined -Cycle Power Systems. Rep. Golden, CO: NREL, 1996. Print.
Doherty, Wayne, Anthony Reynolds, and David Kennedy. "Simulation of a Circulating Fluidised
Bed Biomass Gasifier Using ASPEN Plus." (2008). Print.
Dufour, A., P. Girods, E. Masson, Y. Rogaume, and A. Zoulalian. "Synthesis Gas Production by
Biomass Pyrolysis." International Journal of Hydrogen Energy 34 (2009): 1726-734.
Print.
Duplan,JL. et Al. Process for Multistage Conversion of a Charge Comprising Olefins with Four,
Five, or More Carbon Atoms, with the Aim of Producing Propylene. US Patent
7,262,332. Aug. 28, 2007.
Fehrs, Jeffrey E. Secondary Mill Residues and Urban Wood Waste Quantities in the U.S. Rep.
Washington D.C.: Northeast Regional Biomass Program, 1999. Print.
Goswami, Yogi. "Chapter 4." Alternative Energy in Agriculture. D ed. Vol. II. CRC. 83-102.
Print.
Haugaard, Jesper, and Bodil Voss. Process for the Synthesis of a Methanol/Dimethyl Ether
Mixture From Synthesis Gas. Haldor Topsoe A/S, assignee. Patent 6191175. 20 Feb.
2001. Print.
Hu, Jianli, Yong Wang, Chunshe Cao, Douglas C. Elliott, Don J. Stevens, and James F. White.
"Conversion of Biomass Syngas to DME Using a Microchannel Reactor." Industrial
Chemical Engineering 44 (2005): 1722-727. Print.
267
Inomata, Makoto, Akira Higashi, Yoshiteru Makino, and Yoshinori Mashiko. Process for the
Preparation of Lighter Olefins. JGC Corporation, assignee. Patent 6852987. 8 Feb. 2005.
Print.
Ito, H. et Al. Method and Apparatus for Producing Propylene. US Patent Application 0179365.
Jul. 15, 2010.
Ito, H. et Al. Method for Production of Lower Olefin. US Patent Application 0217054. Aug.
26, 2010.
Jin, Y. et Al. Synthesis of Liquefied Petroleum Gas via Methanol and/or Dimethyl Ether from
Natural Gas (Part 1) Catalysts and Reaction Behaviors Associated with Methanol and/or
Dimethyl Ether Conversion. Journal of the Japan Petroleum Institute (2004): 47, 394402.
Natural Gas (Part 2) Catalysts Improvements in Catlysts for Methanol and Dimethyl
Ether Conversion. Journal of the Japan Petroleum Institute (2004): 48, 45-52.
Natural Gas (Part 3) Investigation of Reaction Variables, Ethene Recycling and Catlyst
Regeneration at High Covnersion from Methanol and/or Dimethyl Ether to LPG. Journal
of the Japan Petroleum Institute (2005): 48, 97-1005.
Kuechler et Al. Process for Producing Olefins. US Patent Application 0283038. Dec. 22, 2005
Larson, Eric D., Haiming Jin, and Fuat E. Celik. "Large-Scale Gasification-Based Coproduction
of Fuels and Electricity From Switchgrass." Biofuels, Bioproducts, and Biorefining 3
(2009): 174-94. Print.
268
Leeper, Stephen A. "Wet Cooling Towers: 'Rule-of-Thumb' Design and Simulation." U.S.
Department of Energy Idaho Operations Office, Idaho National Engineering Laboratory
(1981): 1-24. Print.
Lincoln, James, Judith Kieffer, Dave Davidson, Robert Campbell, Bill Koos, Terry Adams, Ron
McKinsey, and Tom Vivenzio. Biomass Gasification Combined Cycle. Rep. no. DEFC36-96GO10173. Weyerhauser. Print.
Luke-Morgan, Audrey, George Shumaker, and John McKissick. The Impact on Georgia Biomass
for Feedstock from Rising Input and Transportation Costs in 2008. Rep. University of
Georgia, 2008. Print.
Lv, Pengmei, Zhenhong Yuan, Chuangzhi Wu, Longlong Ma, Yong Chen, and Noritatsu
Tsubaki. "Bio-syngas Production From Biomass Catalytic Gasification." Energy
Conversion and Management 48 (2007): 1132-139. Print.
Miller, L.W. et Al. Methanol-Water Mixtures in Olefin Producing Production via Oxygenate
Conversion. US Patent Application 0039670. Feb. 14, 2008.
Moelker, Friedrich-Wilhelm, Peter Koenig, Christopher Higman, and Hans-Dieter Holtmann.
Process of Generating C3 and C4 Olefins From a Feed Mixture Containing C4 to C7
Olefins. Metallgesellshaft Aktiengesellschaft, assignee. Patent 5981819. 9 Nov. 1999.
Print.
Mulvaney, R.C. et Al. Process for Producing Light Olefins. US Patent 5,744,680. Apr. 28,
1998.
Nabarlatz, Debora, Xavier Farriol, and Daniel Montane. "Kinetic Modeling of the
Autohydrolysis of Lignocellulosic Biomass for the Production of Hemicellulose-Derived
Oligosaccharides." Industrial Chemical Engineering 43 (2004): 4124-131. Print.
269
Nikoo, Mehrdokht B., and Nader Mahinpey. "Simulation of Biomass Gasification in Fluidized
Bed Reactor Using ASPEN PLUS." Biomass and Bioenergy 32 (2008): 1245-254. Print.
Perlack, R.D., and A.F. Turhollow. "Feedstock Cost Analysis of Corn Stover Residues for
Further Processing." Energy 28 (2003): 1395-403. Print.
Raju, Arun S.K., Chan S. Park, and Joseph M. Norbeck. "Synthesis Gas Production Using Steam
Hydrogasification." Fuel Processing Technology (2008). Print.
Reckchand, Premkumar. Aspen Simulation and Economic Analysis of Bio-ethanol Production
From Wood. Thesis. Lamar University, 2006. Ann Arbor, MI: ProQuest Information and
Learning, 2007. Print.
Sadaka, Samy. Gasification, Producer Gas, and Syngas. Rep. University of Arkansas Division of
Agriculture. Print.
Sardesai, A. & Lee, S. Alternative Source of Propylene. Energy Sources 27:6 (2005): 489500.
Spath, P., A. Aden, T. T. Eggeman, M. Ringer, B. Wallace, and J. Jechura. Biomass to Hydrogen
Production Detailed Design and Economics Utilizing the Battelle Columbus Laboratory
Indirectly-Heated Gasifier. Rep. Print.
Tisdale, Joan. Simulations and Modeling of Biomass Gasification Processes. Thesis.
Massachusetts Institute of Technology, 2002. Print.
TR Miles Design and Cost Estimate for RDG Lock Hopper System. Rep. Portland, OR: TR Miles
Technical Consultants. Print.
Van Der Drift, A., H. Boerrigter, B. Coda, M.K. Cieplik, and K. Hemmes. Entrained Flow
Gasification of Biomass. Rep. 2004. Print.
Vira, B.V. et Al. Enhanced Light Olefin Production. US Patent 6,049,017. Apr. 11, 2000.
270
Wang, Ligang, Deren Fang, Xingyun Huang, Shigang Zhang, Yue Qi, and Zhongmin Liu.
"Influence of Reaction Conditions on Methanol Synthesis and WGS Reaction in the
Syngas-to-DME Process." Journal of Natural Gas Chemistry 15 (2006): 38-44. Print.
Westrenen, J.V. et Al. Process for Converting an Oxygenate into an Olefin-Containing Product
and Reactor System. US Patent Application 0268007. Oct. 21, 2010.
Wooley, Robert J., and Victoria Putsche. Development of Aspen Plus Physical Property
Database for Biofuels Components. Rep. Golden, CO: NREL, 1996. Print.
Zhao, Tian-Sheng, Tomokazu Takemoto, and Noritatsu Tsubaki. "Direct Synthesis of Propylene
and Light Olefins From Dimethyl Ether Catalyzed by Modified H-ZSM-5." Catalyst
Communications 7 (2006): 647-50. Print.
271
APPENDICES
272
20.
Appendices
Sample Calculations
Absorption Tower Costing:
Vessel shell thickness requirement, excluding wind and earthquake considerations:

tp = Pd*Di/(2*S*E 1.2Pd)
Design Pressure, Pd = exp[.60608+0.91615*ln(Po)+0.0015655*(ln(Po))^2]
Operating Pressure, Po = 300 psia = 314.696 psig
Pd = 375.1 psig
Di = 15.91 ft = 190.92 in
S = 13,750 psi (Carbon Steel, SA-285 up to 650F)
E = 1.0 (Weld efficiency of 1.0 for thickness >1.25in)
tp = 2.65 in
Required vertical tower thickness to compensate for wind load or equivalent earthquake
(assuming wind velocity of 140mph acting uniformly over the height of the tower):
tw = [.22(Do + 18)*L^2]/S*(Do^2)
Do = 190.92 in + 2.65 in = 193.57 in
L = 15 ft + 8ft sump + 4ft top sec = 27 ft = 324 in
tw = .0095 in
Total required vessel shell thickness:
t = tp + tw
t = 2.66 in
Weight of the vertical vessel, assuming carbon steel construction and 2:1 elliptical heads:
W = *(Di + t)*(L + 0.8Di)*t*
= 0.284 lb/in^3
W = 219022.3 lbs
Cost of tower (for 9,000<W<2,500,000lbs):
Cv = exp[7.2756 + 0.18255*ln(W)+0.02297*(ln(W))^2]
Cv = $439679.1
Cost of platforms and ladders (for vertical vessels, 3 < Di 21 ft, 12 < L <40 ft):
Cpl = [361.8(Di)^(0.73960)]*[L^(.70684)]
273
Cpl = $28,771.93
Cost of structured packing (Using Koch-Glitsch BX Wire Gauze, assuming rough estimate of
$250/ft^3):
Volume of packing, Vp = (L 8 - 4)*(*(Di/2)^2)
Vp = 2982.1 ft^3
Cpk = $745523.79
Total absorption tower cost:

$1,213,975
Air Separation Unit, Syngas Section:
Oxygen requirement: 56667 lb/hr X 24h / 2205 lb/mt = 617 metric tons/day
From Mr. Adam Brostow, Air Products: A 450 MT/D plan cost about $15 million.
$15 million X (617/450)^0.6 = $18.12 million
Cost, Air Separation System (no utilities, no compression): $18.12 million
Air requirement: 56667 lb/hr O2 / 0.20 = 283335 lb/hr Air inlet (assuming oxygen recovery of
20% (A.Brostow))
.
Waste Nitrogen = (283335 56667)-(0.15)*(283335 56667) lb/hr = 192668 lb/hr
Hammer Mills:
(TECOGEN Data, NREL 1992, p.49)
Screen and Hammermill: $40,000
Electrical Installation: $92,180
Mechanical Installation: $414,500
$546,680 @ capacity of 252,400 bdt/yr
Scaled to capacity of 750,000 bdt/yr =
$1,640,040 (3 hammermills)
Using CE Plant Cost Index in 2008 of 575.4, and 2002 CEPCI of 358:
$2,635,975
274
(Seider, 3rd ed)
Feed rate = W (ton/hr) = (208,769*1.15/2000) = 120 t/hr

Cp = 3800W^(.78)
Cp = $159,097
(3x $40,000 = $120,000 for same capacity) excl. installation
Drying:
(TECOGEN Data, NREL, 1992, p.49)
2 dryers, ID = 14.8ft, L = 120 ft for capacity of 252,000 bdt/yr (3552 sqft of drying area)
For capacity of 750,000 bdt/yr, requires ~11,000 sqft of drying area
Rotary, Direct Gas Fired, 11,000 sqft, Carbon Steel:
$3,393,600 (6 dryers, F.O.B., Gulf Coast)
Using U.S. Northeast investment site factor of 1.10:
$3,732,960
rd
Seider, 3 ed:
Direct-heat rotary, stainless: Cost = exp(10.396+.1003*ln(A)+.04303*[ln(A)]^2)
Valid for A less than 3000 sqft
(11,000/3000 = 3.67)
Cost, 3000 sqft = $1,152,385
x 3.67 =
$4,229,253
Lockhoppers:
(TR Miles Technical Consultants, Cost estimate, 2x 15tph trains installed, 2002)
Feed System Equipment
Lock hoppers and Valves
$ 837,000
Precharge Hopper with Scales
Lock hoppers
Gate Valves
Transition to Meter Bin
Meter Bins and Injectors
$ 629,000
Inert and Purge Gas Compression
$ 689,000
Total Feed Equipment (installed)
275
$ 2,115,500
Civil/Structural- equipment supports, foundations
$ 98,000
Mechanical Installation, piping and hoppers
$ 86,000
Electrical and Controls Feed System
$ 69,000
Electrical and Controls, Purge Gas
$ 115,000
Miscellaneous, freight, spares
$ 155,000
Total Other
$ 523,000
Indirect Costs- mechanical and electrical engineering
$ 217,000
Total Feed System Construction Cost
$ 2,895,000
25% Contingency and allowance for unlisted items
$ 723,000
Total Estimated Capital Cost $ 3,618,000
*Note: Installation costs are estimated at 30% of equipment costs.
______________________________________________________________________________
208,769 lb/hr (dry wood chips) + 31315 lb/hr (15% moisture, post drying) = 240,084 lb/hr
Requires 4x 15tph trains
$3,618,000 x 4 =
$28,944,000
Present cost estimation using CEPCI in 2002 of 396:
$21,028,255
Storage Bin for day of material, post-dryer, pre-lockhoppers- 208769lb/h x 1.15 x 12h / 31.2
lb/cuft = 92,340 cuft
Seider, 3rd ed:
Cost = 570*(S)^(.46) , carbon steel at atmospheric
= 570*(92340)^.46
=$109,636
Assuming 6 bins, one for each dryer:
6x $109,636=
$657,816
Flash Vessel:
Assume residence time, = 10 min and aspect ratio, L/D = 2:
276
Holdup = volumetric flow ( liquid stream C7)* = 122.157359 ft^3/hr * 10 min *

1 hr/ 60 min
= 20.3596 ft^3
Required volume, V = 2 x holdup = 40.72 ft^3
V =( D^2/4)*L = (D^2/4)*2D D = (2V/)^(1/3)
D = 2.96 ft
L = 5.92 ft
Vessel shell thickness requirement, excluding wind and earthquake considerations:
tp = Pd*Di/(2*S*E 1.2Pd)
Design Pressure, Pd = exp[.60608+0.91615*ln(Po)+0.0015655*(ln(Po))^2]
Operating Pressure, Po = 300 psia = 314.696 psig
Pd = 375.1 psig
Di = 2.96 ft = 35.52 in
L = 70.97 ft = 71.04 in
S = 13,750 psi (Carbon Steel, SA-285 up to 650F)
E = 0.85 (Weld efficiency of 0.85 for thickness <1.25in)
tp =0.4861 in
Weight of the vessel, assuming carbon steel construction and 2:1 elliptical heads:
W = *(Di + t)*(L + 0.8Di)*t*
= 0.284 lb/in^3
W = 1,553.105 lbs
Cost for horizontal vessel (1,000 < W < 920,000 lb)
Cv = exp[8.9552 0.2330*ln(W)+0.04333*(ln(W))^2]
Cv = $14,510.70
Cost of platforms and ladders (for horizontal vessels 3 < Di < 12 ft):
Cpl = 2005*Di^(.20294)
Cpl = $2498.95
Total cost, flash vessel:
$17,010
Gasifiers:
(NREL, 1990, high pressure directly heated fluidized bed, 1525F, 465psia, 843tons/day)
$20,972,000 (including lock hopper feed system)
277
208769 lb/hr x 1.15 x 24h/d x 1t/2000lb = 2881 tpd

/843 tpd = 3.4 4 gasifiers required
4 gasifiers = $20,972,000 x4 = $83,888,000

Using 2008 CEPCI, cost =
$134,830,042
Subtracting the cost of lock hoppers (8) @$42,056,509 =
$92,773,533
MEA Recycle Cooler

DUTY AND AREA:
CALCULATED HEAT DUTY
BTU/HR
CALCULATED (REQUIRED) AREA

ACTUAL EXCHANGER AREA
67473270.5502
SQFT
7413.2200
SQFT
PER CENT OVER-DESIGN
7413.2200
0.0000
HEAT TRANSFER COEFFICIENT:

AVERAGE COEFFICIENT (DIRTY)
UA (DIRTY)
BTU/HR-R
BTU/HR-SQFT-R
149.6937
1109712.0009
Uses Chilled Water (45 to 90 F): 1,500,733.41 lb/hr

(1,500,733.41 lb/hr * 1 ton/ 2000lb * 24 h / 1 d)* $1.20 /td
$21,610/d *330 op days/yr = $7,131,485 /yr
Base cost, fixed head shell and tube, 20 ft or 1 in OD 16 BWG carbon steel tubes:
Cb = exp[11.2927 -0.9228*ln(A)+0.09861*(ln(A))^2]
Cb = $54,168.75
Pressure factor (300psia = 314.696 psig)
Fp = 0.9803 + 0.018(P/100) + 0.0017(P/100)^2
Fp = 1.053781
Cost = Fp*Cb
Cost = $57,082
278
Reciprocating Plunger Pump, Syngas Section:

(water flow to HRSG)
VOLUMETRIC FLOW RATE CUFT/HR
PRESSURE CHANGE PSI
NPSH AVAILABLE FT-LBF/LB
FLUID POWER HP
BRAKE POWER HP
ELECTRICITY KW
1,927.67
1,785.30
32.9279
250.290
391.096
291.640
PUMP EFFICIENCY USED
0.63997
NET WORK REQUIRED HP
391.096
HEAD DEVELOPED FT-LBF/LB
4,129.78
(240.333 gpm)
Reciprocating Plunger Pump required(head > 3200 ft):
Cb = exp[(7.8103+0.26986*ln(Pb)+0.06718*(ln(Pb))]
Pb = 391.096 HP
Cb = $135,212
(includes V-belt drive, ductile iron construction) [note, Fm for carbon steel = 1.5, stainless =
2.20]
Electric Motor:
Fractional efficiency of pump, Np = -0.316+0.24015*ln(Q)-0.01199*(ln(Q))^2

(for 50 < Q < 5000 gpm)
Np = 0.64 (same as above via Aspen)
Fractional efficiency of motor, Nm = 0.80 + 0.0319*ln(Pb)-0.00182*(ln(Pb))^2

(for 1 < Pb < 1500 HP)
Nm = 0.9256
279
Power consumption, Pc = Pb/Nm = 422.55HP
Cb = exp[5.8259+0.13141*ln(Pc)+0.053255*ln(Pc)^2+0.028628*ln(Pc)^3 0.0035549*ln(Pc)^4]
(for 1 < Pc < 700 HP, 3600 rpm, open, drip-proof enclosure)
Cb = $25,443.80
Total Pump Cost, B9:

$160,656
Electricity requirements:
291.640
KW * 24 h / 1 d * 330 op days/yr = 2309788.8 kWh/yr
Assuming $0.060/kWh $138,587/yr

Centrifugal Pump: (water flow to low pressure steam HXs):

PRESSURE CHANGE PSI
NPSH AVAILABLE FT-LBF/LB
FLUID POWER HP
BRAKE POWER HP
ELECTRICITY KW
1,044.16
215.304
32.9279
16.3499
28.7429
21.4336
0.56883
28.7429
498.043
(130.181gpm)
Centrifugal Pump, HSC, 1800 rpm, max flow 5000 gpm, max head 500 ft, max hp 250:
S = Q*(H)^0.5
280
Q = 130.181 gpm
H = 498.043 ft
S = 2905.23
Cb = exp[9.7171 0.6019*ln(S)+0.0519*ln(S)^2]
Cb = $3,705.80
Type factor, Ft = 2.00
Cost, pump only = $7411.60
Electric Motor:
Fractional efficiency of motor, Nm = 0.80 + 0.0319*ln(Pb)-0.00182*(ln(Pb))^2

(for 1 < Pb < 1500 HP)
Nm = 0.887
Power consumption, Pc = Pb/Nm = 32.42HP
Cb = exp[5.8259+0.13141*ln(Pc)+0.053255*ln(Pc)^2+0.028628*ln(Pc)^3 0.0035549*ln(Pc)^4]
(for 1 < Pc < 700 HP, 3600 rpm, open, drip-proof enclosure)
Cb = $2022.58
Type factor (to adjust for 1800rpm), Ft = 0.90
Cost, electric motor: $1820.32

Total Pump Cost:
$9,232
Electricity requirements:
21.4336
KW * 24 h / 1 d * 330 op days/yr = 169754.112 kWh/yr
Assuming $0.060/kWh $10,185/yr

281
Filters for Alkali Deposition:

NREL(1990) ceramic candle filters: $2,700,000
EBASCO (1993) ceramic candle filter vessel (34,948 scfm gas outlet): $2,200,000
Our outlet flow = 629233.532 ft^3/hr = 10487.225 ft^3/min
Using EBASCO estimate:
$2,200,000 * 575.4/359 = $3,526,128 in 2008 dollars
Our Cost = ~3,500,000/(34948/10487)^0.6
~ $1,700,000
282
C-401 Costing Calculations

Inlet
Outlet
Flow Rate (lb/hr)
312834 312834
Flow Rate (scf/min)
Temperature (F)
171.8
255
Pressure (psi)
200
295
Efficiency
Utility Used
Power Consumption
Material
Number of Stages
0.7
Electricity
6613 hp
Carbon Steel
1
Bare Module Factor

Bare Module Cost
2.15
4,794,126
4931 kw
283
D-501 Cost Calculations

Above Side Draw
f
G
L
pL
pG
Below Side Draw

0.75
703100
702800
60
1.661
f
G
L
pL
pG
0.75
503000
623900
47.44
1.661
Csb
Fst
Ff
F HA
0.33
1.141721938
1
1
Csb
Fst
Ff
F HA
0.27
1.14172194
1
1
F LG
C
Uf
Ad/At
Dt
0.166312099
1356.365662
8038.434192
0.107368011
10.00751401 ft
F LG
C
Uf
Ad/At
Dt
0.23209163
1109.75372
5826.0599
0.11467685
9.98355513
Liquid flow rate (gpm)
1460.262222 gpm Liquid flow rate (gpm)
Tray Efficiency
Number of Trays
Height
Diameter
Wall Thickness
Vessel Weight
Material
Vessel Cost
Platforms & Ladders Cost
Tray Cost
Total f.o.b. Purchase Cost
63%
25
60
10
1.3
109844
Carbon Steel
204127.2486
35037.24948
58601.21735
297765.7154
Bare-Module Factor
Total Bare-Module Cost
1639.53485
ft
ft
in
lb
4.16
1238705.376
284
T-501 Cost Calculations

f
G
L
pL
pG
0.85
413000
347000
52.6
0.389
Csb
Fst
Ff
F HA
0.38
1.18859
1
1
F LG
C
Uf
Ad/At
Dt
0.072254
1625.991
18837.55
0.096917
9.668739
Liquid flow rate (gpm)
822.4208
assuming 70% tray efficiency

Height
Diameter
Wall Thickness
Vessel Weight
Material
Vessel Cost - Eq. (22.54)
Platforms & Ladders Cost - Eq.
(22.56)
Tray Cost - Eq. (22.67)
Bare-Module Factor
Column Internals
Grand Total
15 trays
44
9.7
1.2
79604
Carbon
Steel
162495.9
ft
ft
in
lb
28180.13
55622.37
246298.4
4.16
1024602
100,000
1,124,602
285
H-501 Costing Calculations

Duty
-112516526
A
22503
U
80
No. Units
A per unit
Duty per unit
3
7501
-37505508.67
Cost per unit

Total purchase cost
Bare Module cost
A
Duty
54704
164112
520235.04
H-502 Costing Calculations

15440 sqft
185.8 MMBTU/hr
A per exchanger
No. Exchangers
Duty per exchanger
7720 sqft
2
80.8 MMBTU/hr

FBM
Bare Module Cost
104122.9
3.17
330069.7
Total:
660139.3
191467.4361
lb/hr 500 psia steam
286
Flow Rate
Fluid power
Brake power
efficiency
electricity
consumption
head developed
pressure change
density
Type
Shaft rpm
P-501 Costing Calculations

161 gpm
0.47 hp
0.67 hp
0.7
0.5
14
5
51.4
kW
ft
psi
lb/ft^3
centrifugal
3600
S
Cb
Ft
Fm
602.406839 B2*B7^0.5
2953.72476 EXP(9.7171-0.6019*LN(B14)+0.0519*(LN(B14))^2)
1
2 Stainless Steel
Cp
5907.44953 B15*B17*B16
Motor
np
nm
Pc
0.59470942 -0.316+0.24015*LN(B2)-0.01199*(LN(B2))^2
0.78693287 0.8+0.0319*LN(B4)-0.00182*(LN(B4))^2
1.00290313 B2*B7*B9/7.48/(33000*B23*B22)
Cb
Ft
EXP(5.8259+0.13141*LN(B24)+0.053255*(LN(B24))^2+0.028628*(L
339.09537 N(B24))^3-0.0035549*(LN(B24))^4)
1
Cp
339.09537 B26*B25
From
Spreadsheet
Bare module
cost =
$ 10,781.00 pump
1017.28611 motor
11798.2861 total
287
Flow Rate
Fluid power
Brake power
efficiency
electricity
consumption
head developed
pressure change
density

824 gpm
2.4 hp
3.43 hp
0.7
2.56
13.7
5
52.6
kW
ft
psi
lb/ft^3
Type
Shaft rpm
centrifugal
3600
S
Cb
Ft
Fm
3049.91331 B2*B7^0.5
3747.15656 EXP(9.7171-0.6019*LN(B14)+0.0519*(LN(B14))^2)
1
2 Stainless Steel
Cp
7494.31313 B15*B17*B16
Motor
np
nm
Pc
0.75589782 -0.316+0.24015*LN(B2)-0.01199*(LN(B2))^2
0.83655372 0.8+0.0319*LN(B4)-0.00182*(LN(B4))^2
3.80417998 B2*B7*B9/7.48/(33000*B23*B22)
Cb
Ft
EXP(5.8259+0.13141*LN(B24)+0.053255*(LN(B24))^2+0.028628*(L
470.360503 N(B24))^3-0.0035549*(LN(B24))^4)
1
Cp
470.360503 B26*B25
From Spreadsheet
Bare module cost
=
$
13,711.00 pump
1411.08151 motor
15122.0815 total
288

Flow Rate
985
gpm
Fluid power
16.2
hp
Brake power
23.1
hp
efficiency
electricity
consumption
0.7
16.8
kW
head developed
77.5
ft
pressure change
28.2
psi
density
52.4
lb/ft^3
Type
Shaft rpm
centrifugal
3600
8671.3573
B2*B7^0.5
Cb
5047.56858
Ft
Fm
Stainless Steel
Cp
10095.1372
B15*B17*B16
np
0.76964087
-0.316+0.24015*LN(B2)-0.01199*(LN(B2))^2
nm
0.8822181
Pc
23.8665473
B2*B7*B9/7.48/(33000*B23*B22)
Cb
1529.61744
EXP(5.8259+0.13141*LN(B24)+0.053255*(LN(B24))^2+0.028628*(LN(B24))^
3-0.0035549*(LN(B24))^4)
Ft
Cp
1529.61744
B26*B25
$ 28,771.14
pump
4588.85232
motor
33359.9932
total
EXP(9.7171-0.6019*LN(B14)+0.0519*(LN(B14))^2)
Motor
0.8+0.0319*LN(B4)-0.00182*(LN(B4))^2
From Spreadsheet
Bare module cost =
289
Flow Rate
Fluid power
Brake power
efficiency
electricity
consumption
head developed
pressure change
density
Type
Shaft rpm

1740 gpm
3.48 hp
4.98 hp
0.7
3.7
11.5
5
44
kW
ft
psi
lb/ft^3
centrifugal
3600
S
Cb
Ft
Fm
5900.62709 B2*B7^0.5
4463.64317 EXP(9.7171-0.6019*LN(B14)+0.0519*(LN(B14))^2)
1
2 Stainless Steel
Cp
8927.28634 B15*B17*B16
Motor
np
nm
Pc
0.80835677 -0.316+0.24015*LN(B2)-0.01199*(LN(B2))^2
0.84652234 0.8+0.0319*LN(B4)-0.00182*(LN(B4))^2
5.21245987 B2*B7*B9/7.48/(33000*B23*B22)
Cb
Ft
EXP(5.8259+0.13141*LN(B24)+0.053255*(LN(B24))^2+0.02862
539.405093 8*(LN(B24))^3-0.0035549*(LN(B24))^4)
1
Cp
539.405093 B26*B25
From Spreadsheet
Bare module cost =
$ 23,657.00
pump
1618.21528 motor
25275.2153 total
290
Flow Rate
Fluid power
Brake power
efficiency
electricity
consumption
head developed
pressure change
density
Type
Shaft rpm

724 gpm
2.11 hp
2.83 hp
0.7
2.11
14.3
5
50.3
kW
ft
psi
lb/ft^3
centrifugal
3600
S
Cb
Ft
Fm
2737.83067 B2*B7^0.5
3657.13436 EXP(9.7171-0.6019*LN(B14)+0.0519*(LN(B14))^2)
1
2 Stainless Steel
Cp
7314.26873 B15*B17*B16
Motor
np
nm
Pc
0.74545752 -0.316+0.24015*LN(B2)-0.01199*(LN(B2))^2
0.83121527 0.8+0.0319*LN(B4)-0.00182*(LN(B4))^2
3.40479244 B2*B7*B9/7.48/(33000*B23*B22)
Cb
Ft
EXP(5.8259+0.13141*LN(B24)+0.053255*(LN(B24))^2+0.028628*(L
451.00607 N(B24))^3-0.0035549*(LN(B24))^4)
1
Cp
451.00607 B26*B25
From
Spreadsheet
Bare module
cost =
$ 13,349.00 pump
1353.01821 motor
14702.0182 total
291
Flow Rate
Fluid power
Brake power
efficiency
electricity
consumption
head developed
pressure change
density
Type
Shaft rpm

339 gpm
0.99 hp
1.41 hp
0.7
1.09
13.2
5
54.7
kW
ft
psi
lb/ft^3
centrifugal
3600
S
Cb
Ft
Fm
1231.64816 B2*B7^0.5
3171.87574 EXP(9.7171-0.6019*LN(B14)+0.0519*(LN(B14))^2)
1
2 Stainless Steel
Cp
6343.75147 B15*B17*B16
Motor
np
nm
Pc
0.67614602 -0.316+0.24015*LN(B2)-0.01199*(LN(B2))^2
0.81074565 0.8+0.0319*LN(B4)-0.00182*(LN(B4))^2
1.80892388 B2*B7*B9/7.48/(33000*B23*B22)
Cb
Ft
EXP(5.8259+0.13141*LN(B24)+0.053255*(LN(B24))^2+0.028628*(L
375.411942 N(B24))^3-0.0035549*(LN(B24))^4)
1
Cp
375.411942 B26*B25
From
Spreadsheet
Bare module
cost =
$ 19,983.00 pump
1126.23583 motor
21109.2358 total
292

Utility Used
Power
Consumption
Electricity
60.9
kW
449
ft
Head
Material
Electric Motor
Number of
Stages
Stainless
Steel
3600 rpm
1
Efficiency
0.7
Flow Rate
516
gpm
Fluid power
57.2
hp
Brake power
81.7
hp
efficiency
pressure
change
0.7
190
psi
density
60.9
lb/ft3
Type
centrifugal
10933.84397
B2*B7^0.5
Cb
5475.956538
EXP(9.7171-0.6019*LN(B14)+0.0519*(LN(B14))^2)
Ft
Fm
Stainless Steel
Cp
10951.91308
B15*B17*B16
np
0.716226482
-0.316+0.24015*LN(B2)-0.01199*(LN(B2))^2
nm
0.905173293
0.8+0.0319*LN(B4)-0.00182*(LN(B4))^2
Pc
88.1689546
Cb
5567.995835
Ft
Motor
Cp
From
Spreadsheet
Bare module
cost =
5567.995835
B2*B7*B9/7.48/(33000*B23*B22)
EXP(5.8259+0.13141*LN(B24)+0.053255*(LN(B24))^2+0.028628*(LN(B24))^30.0035549*(LN(B24))^4)
B26*B25
$
34,498.00
pump
16703.9875
motor
51201.9875
total
293
R-401 Costing Calculations Microchannel Reactor:

This reactor design information is based on information provided in U.S. patents
7,250,151 and 6,969,506 and also in senior design report Alaskan Natural Gas to Liquids Using
Microchannel Reactors 2009, which contains equations as well as costing and sizing
recommendations provided by Arkema Chemical. Microchannel reactors are not currently
commercially available and the main manufacturer, Velocys, is protecting all design information
as proprietary. Therefore, all calculations had to be based on patent information and laboratory
scale data. This particular microchannel reactor design assumes that there are exothermic
reaction channels with a coolant channel both above and below each reaction channel.
Sizing Calculation for R-401: DME Microchannel Reactor
Volumetric flow rate of feed (at reaction conditions):
Stream S-305
Reaction Channel Dimensions:
Height
Width
1630440 ft3/hr
2 mm
4.1 mm
Reaction Zone Length
4100 mm
(6)
3
(7) = (4) * (5) * (6)
5 ms
(8)
3
Volume Flow per Channel
820 mm /ms
(9)=(7) / (8)
Volume Flow per Channel (STP)

Channels Required
1
(4)
(5)
500 mm
Reaction Zone Volume

Contact Time
(1)
105.1 mm /ms (10)=(9) / 7.8

121991 channels (11)=(1) / (10)
specified in the patent as the contact time at STP, so the volume

3
needs to be adjusted by 7.8 ft at STP/ft at reactor conditions
Capacity of One Module

End Plate Thickness
Effective Module Height
Thickness of Channel Set
# of Sets Vertically Stacked
Shim Width
# of Sets along Width
12.8 mm
987.2 mm
12 mm
82
36 mm
42
(1)
(2) =1 - (1)
(3)
(4) = (2) / (3)
(5)
(6) =1.5m / (5)
Total Sets per Module
3417
(7) = (4) * (6)
Reaction Channels
3417
(8)
Coolant Channels
6834
(9)
With no commercial-scale microchannel reactors available on the market, it was assumed

that the reactor would be custom fabricated in a module design. Each module is 1 m long, 1 m
294
wide, and 1.5 m tall. Based on these dimensions and the channel dimensions, and shown in the
table above, each module contains 3,417 reaction channels. From the sizing calculation table, it
was determined that for the volumetric flow rate through the reactor, a total of 121,991 reaction
channels are required. Therefore, 121,991/3,417 = 35.7 reactor modules would be required.
Assuming partial modules cannot be constructed, 36 modules need to be purchased.
However, another limitation to reactor design is the heat removal from the reactor.
Heat Flux Calculation
Reaction Channel Specifications:
Width
Length
# Coolant Channels per Module
# Modules
Total Heat Transfer Area
Heat Duty
Heat Flux
4.1
500
6834
36
mm
mm
channels
modules
5.04x106 cm2
1.99 x
108 BTU/hr
39.5 BTU/hr/cm2
Patent 6,969,506 states that microchannel reactors typically have heat flux values
between 3.41 and 68.3 BTU/hr-cc. Since the heat flux value required for this reactor of 39.5
BTU/hr-cc is well within the range of acceptable and observed values, this channel design should
be effective for use in the conversion of syngas to DME.
Because no commercially microchannel reactors are currently available on the market,
the cost of the reactor is estimated by determining the cost of the metal required to construct the
reactor.
295
Calculation of Reactor Mass

Reaction Channel:
Height
Width
Length
# per Set
# per Module
Volume per Module
2
4.1
500
1
mm
mm
mm
channels
3,417
channels
14,009,700
mm3
mm
Coolant Channel:
Height
Width
Length
# per Set
# per Module
4
500
2
6,834
mm
mm
channels
channels
Volume per Module
28,019,400
mm3
Total non-Metal Volume
42,029,100
mm3
Total Module Volume
795,000,000
mm3
Total Metal Volume

Material
Material Density
Material Mass
752,970,900 mm3
Stainless Steel
8,010
6,031
kg/m3
kg
Microchannel reactors are constructed out of 304-grade stainless steel. As shown in the
calculations above, 6,031 kg of stainless steel would be required to construct the 36 reactor
modules. With a cost of $4,572.43/ton according to MEPS International Ltd., the total material
cost of the reactor would be $999,405. Since the construction of microchannels is highly precise,
it is assumed the construction cost, in addition to the materials, will be relatively high. The
channels are formed using wire EDM and laser cutting, which not only requires expensive
equipments, but also skilled labor. Therefore, the materials cost is multiplied by a factor of 5 to
estimate the construction costs. This brings the cost of the reactor to approximately $4,997,000.
The catalyst for the reactor is inserted by wash-coating a FeCrAlY metal wire felt with a
thickness of 0.9 mm and 90% porosity with the two catalysts, and then top and bottom of each
reactor channel is lined with the catalyst-coated felt. The reactor requires two different catalysts,
one for the conversion of syngas to methanol and the second to dehydrate methanol into DME.
The catalyst used for methanol formation in this application is copper. Aluminum oxide is used
as the methanol dehydration catalyst. For optimal DME production and carbon monoxide
296
conversion, the two catalysts are loaded in a 1:1 mass ratio. Based on costs provided by
Technetics and provided in the 2009 GTL senior design report, the cost for both the catalyst and
catalyst inserts is estimated at $10,000. This brings the total reactor cost to $5,007,000.
297
V-501 Costing Calculations

Material
Carbon Steel
Presure
230
psi
Temperature
167
Wall Thickness
1.15
Vessel Weight
27736
Vessel Cost
66,604.91
Platform and Ladder Cost
2,975.90
Total f.o.b. cost
69580.808
Bare Module Cost
212221.46
LBS/HOUR=
483004
FLOW=
VAPOR FRACTION=INPUT THIS VALUE
0.9
VAPDENSITY=
0.2
LIQUID FRACTION=
0.1
LIQDENSITY=
60
VAPDENSITY=
0.2
LBS/FT3
LIQDENSITY=
60
LBS/FT3
L/D=
HOLD-UP TIME,MIN.=
30
FRACTION OF DRUM FULL FOR HORIZ
0.5
KFACTOR=
1 FOR
1=DEFAULT=0.27
0.27
LBS/FT3
2=USER INPUT
KFACTOR
VELOCITYALLOWED,FT.SEC=
17.29162
VFLOW RATE ,CUF/SEC
603.755
LFLOW RATE ,CUF/SEC
0.223613
FLOW, LBS/HOUR=
AREA REQ'D FOR VAPOR FT2
129.318
VOLUME OF LIQUID HELD,FT3
ACTUAL=
19.18862
FT2ACTUAL
402.50
11.39765
meter3
3.112
0.948687
meters
6.992
2.131164
meters
20.9754
6.393493
meters
19.188
5.848691
meter2
FT/SEC
0.27
4.668736
483004
LBS/HOUR
FOR GIVEN HOLD UP TIME

HEIGHT OF LIQUID IF VERTICAL,FT
FOR GIVEN HOLDUP TIME&C18 AREA
DIAMETER FOR DRUM AT GIVEN
HOLD UP, FEET FOR GIVEN %FULL
LENGTH OF LIQUID IF HORIZONTAL,FT
FOR GIVEN HOLD UP TIME, %FULL
AREA REQ'D FOR LIQUID FT2

AT C9 FULL DRUM, HORIZONTAL
298

Wall Thickness
Vessel Cost
Platform and Ladder Cost
Total f.o.b. cost
Bare Module Cost
1.16
109,039.00
3,199.00
112238
342325.9
LBS/HOUR=
FLOW=
VAPOR FRACTION=INPUT THIS VALUE
0.03333
LIQUID FRACTION=
0.96667
L/D=
HOLD-UP TIME,MIN.=
KFACTOR=
VFLOW RATE ,CUF/SEC
LFLOW RATE ,CUF/SEC
FLOW, LBS/HOUR=
620000
VAPDENSITY=
LIQDENSITY=
VAPDENSITY=
LIQDENSITY=
3
5
0.5
1
KFACTOR
17.29162
4.705055
3.783683
1.007779021
1135.10 ACTUAL=
1 lb/ft3
60
1.22 LBS/FT3
44 LBS/FT3
FT/SEC
METERS/SEC
0.27 4.668736 1.423031
620000

0.2
LBS/HOUR TOTAL
38.30197
32.14265 meter3
1126.343078
343.3094 meters
9.8784
3.010965 meters
29.635
9.032894 meters
38.301
11.67444 meter2
299

LBS/HOUR=
171952
KG/HOUR=
FLOW=
VAPOR FRACTION
0.134
VAPDENSITY=
0.118
LIQUID FRACTION=
0.866
LIQDENSITY=
54.7
VAPDENSITY=
0.118
LBS/FT3
LIQDENSITY=
54.7
LBS/FT3
L/D=
HOLD-UP TIME,MIN.=

KFACTOR=
1=DEFAULT=0.27
21.50
VFLOW RATE ,CUF/SEC
54.24
LFLOW RATE ,CUF/SEC
0.756
FLOW, LBS/HOUR=
lb/ft3
0.5
KFACTOR
0.27
171952.8
9.3
=ACTUAL
13.09292
FT/SEC
METERS/SEC
5.80694193
1.7699559
0.27
LBS/HOUR TOTAL
FT2ACTU
226.86

24.287

5.7756

17.326

13.092

Wall Thickness
0.4375
Vessel Weight
7186
Material Factor
Vessel Cost
1
29819
Platforms & Ladders Cost
2864
32683
Bare-Module Factor
3.05
99685
300
DME Reactor Sizing

Approximately 100,000 lb/hr of DME and methanol are fed to the propylene reactor train.
Assuming a series of adiabatic, fixed bed reactors, the temperature rise across the reactor was
kept to 200 F in order to stay within the optimal propylene production temperature range. The
exothermic heat of reaction was recovered between reactors using high-pressure steam. The
DME and methanol feed was split between the reactors, with less fed to the earlier reactors due
to the smaller amount of diluents to limit temperature increase. Under these constraints, it was
determined four reactors would be needed.
Using a WHSV of 1 lb/lb/hr and flow rate of 25,000 lb/hr of reactant, 25,000 kg of H-ZSM-5
catalyst is required per reactor. Assuming a catalyst density of 50 lb/ft^3 and a void fraction of
0.5, a total catalyst volume of 1000 ft^3 is required. Assuming an aspect ratio of 2 in order to
minimize the pressure drop, a diameter of 8 6 and length of 17 3 is found. To account for
catalyst support, the length is increased to 18 3.
To estimate a pressure drop across the reactor, the Ergun Equation is used:
The Ergun equation predicts a pressure drop of approximately 30 psig, 40 psig, 100 psig, and
200 psig across each sequential reactor.
Cracking Reactor Sizing

Approximately 100,000 lb/hr of byproduct hydrocarbons are fed to the steam cracking reactor.
Using 3 fixed bed reactors in parallel, 34,000 lb/hr of hydrocarbons are fed to each reactor.
Using a WHSV of 1 lb/lb/hr, this results in 34,000 lb of zeolite catalyst. Assuming a catalyst
density of 50 lb/ft^3 and a void fraction of 0.5, a total volume of 1360 ft^3. An aspect ratio of 2
gives a length and width of 9 6 and a length of 19. Increasing the length to 20 provides room
for catalyst support. Using the Ergun Equation provided above, a pressure drop of 35 psig is
determined.
301
Simulation Results
302
PSI
INPUT DATA
***
***
RESULTS
PSIA
***
432.586
2
30
0.000100000
25.0000
NO
FLASH SPECS FOR HOT SIDE:

TWO
PHASE
FLASH
MAXIMUM NO. ITERATIONS
CONVERGENCE TOLERANCE
***
INPUT DATA
***
0.00000
-0.640709E-09
RELATIVE DIFF.
0.00000
0.00000
0.00000
30
0.000100000
MASS AND ENERGY BALANCE ***

IN
OUT
CONV. COMP.(LBMOL/HR)
25987.0
25987.0
(LB/HR
)
463591.
463591.
NONCONV. COMP(LB/HR
)
0.00000
0.00000
TOTAL BALANCE
MASS(LB/HR
)
463591.
463591.
ENTHALPY(BTU/HR )
-0.158635E+10
-0.158635E+10
***
BLOCK: B1
MODEL: HEATX
----------------------------THIS BLOCK RUNS WITH ASPEN EDR 25.0 WITH ADVANCED METHOD FOR SHELL&TUBE
HOT SIDE:
--------INLET STREAM:
18
OUTLET STREAM:
2
PROPERTY OPTION SET:
ELECNRTL ELECTROLYTE NRTL / REDLICH-KWONG
COLD SIDE:
---------INLET STREAM:
23
OUTLET STREAM:
5
VALVE OUTLET PRESSURE
FLASH SPECIFICATIONS:
NPHASE
MAX NUMBER OF ITERATIONS
VALVE PRESSURE DROP

VALVE FLOW COEF CALC.
***
0.169410E-15
0.842843E-12
RELATIVE DIFF.
0.00000
0.169410E-15
0.00000
ELECTROLYTE NRTL / REDLICH-KWONG

IN
OUT
19326.0
19326.0
(LB/HR
)
343591.
343591.
NONCONV. COMP(LB/HR
)
0.00000
0.00000
TOTAL BALANCE
MASS(LB/HR
)
343591.
343591.
ENTHALPY(BTU/HR )
-0.807606E+09
-0.807606E+09
***
BLOCK: ALKFILTR MODEL: VALVE

----------------------------INLET STREAM:
14
OUTLET STREAM:
18
ELECNRTL
***
SHELLSIDE RESULTS:
AVERAGE WALL TEMPERATURE
CLEAN PRESSURE DROP
WINDOW PRESSURE DROP
PRESSURE DROP IN ENDS
CROSSFLOW PRESSURE DROP
BULK FILM COEFFICIENT
WALL FILM COEFFICIENT
THERMAL RESISTANCE
MAXIMUM FOULING RESISTANCE
FOULING RESISTANCE
CROSSFLOW VELOCITY
WINDOW VELOCITY
MIDPOINT VELOCITY
SHELL ENTRANCE RHOV^2
SHELL EXIT RHOV^2
BUNDLE ENTRANCE RHOV^2
BUNDLE EXIT RHOV^2
F
PSI
PSI
PSI
PSI
BTU/HR-SQFT-R
BTU/HR-SQFT-R
HR-SQFT-R/BTU
HR-SQFT-R/BTU
HR-SQFT-R/BTU
FT/SEC
FT/SEC
FT/SEC
LB/FT-SQSEC
LB/FT-SQSEC
LB/FT-SQSEC
LB/FT-SQSEC
BTU/HR-SQFT-R
BTU/HR-SQFT-R
BTU/HR-R
F
BTU/HR
SQFT
SQFT
4.0000D+02
1.8000D+03
0.0000D+00
7.4739D+02
4.2913D+02
1.0000D+00
505.3776
0.3050
0.0057
0.0057
0.0211
658.2193
658.2193
0.0015
0.001230
0.0000
2.0174
1.5904
1.8039
121.8296
257.8978
61.9032
78.6461
28638787.8439
599.4111
812.0397
35.4729
35.4729
144.2515
144.2515
86465.9331
331.2147
0.9860
1
1
23
T=
P=
V=
2
T=
P=
V=
ASPEN PLUS
ASPEN PLUS
B1.EDR
DESIGN
30
0.000100000
-------------------------------------|
|
----->|
HOT (TUBE)
|----->
9.2471D+02 |
|
4.3259D+02 |
|
1.0000D+00 |
|
|
|
<-----|
COLD (SHELL)
|<----6.0000D+02 |
|
1.7997D+03 |
|
0.0000D+00 |
|
--------------------------------------
OVERALL RESULTS
UNIT RESULTS:
% OVER (UNDER) DESIGN (DIRTY)
% OVER (UNDER) DESIGN (CLEAN)
AVERAGE COEFFICIENT (CLEAN)
UA (DIRTY)
LMTD (CORRECTED)
LMTD CORRECTION FACTOR
NUMBER OF SHELLS IN SERIES
NUMBER OF SHELLS IN PARALLEL
5
T=
P=
V=
18
T=
P=
V=
STREAMS:
***
HEAT CURVE GENERATION

HOT HEAT CURVE GENERATED BY
COLD HEAT CURVE GENERATED BY
SHELL&TUBE INPUT FILE NAME

SHELL&TUBE PROGRAM MODE
FLASH SPECS FOR COLD SIDE:

TWO
PHASE
FLASH
PSI
F
PSI
BTU/HR-SQFT-R
BTU/HR-SQFT-R
HR-SQFT-R/BTU
HR-SQFT-R/BTU
HR-SQFT-R/BTU
FT/SEC
FT/SEC
FT/SEC
PSI
596.6841
3.4562
215.9810
215.9810
0.0046
0.001230
0.0000
133.2640
117.1614
117.1614
0.0000
66.7890
3.7078
0.0000
21.9154
0.3036

TWO
PHASE
FLASH
***
INPUT DATA
***
0.00000
0.123419E-05
RELATIVE DIFF.
0.00000
0.00000
0.00000
30
0.000100000

IN
OUT
22934.1
22934.1
(LB/HR
)
408591.
408591.
NONCONV. COMP(LB/HR
)
0.00000
0.00000
TOTAL BALANCE
MASS(LB/HR
)
408591.
408591.
ENTHALPY(BTU/HR )
-0.126164E+10
-0.126164E+10
***
***********************************************************************
*
*
*
ERRORS IN BLOCK CALCULATIONS
*
*
*
*
CONVERGENCE FAILED - RESULTS REPORTED AT LAST ITERATION
*
*
*
***********************************************************************
BLOCK: B2
MODEL: HEATX
HOT SIDE:
2
OUTLET STREAM:
10
COLD SIDE:
20
OUTLET STREAM:
13
TUBESIDE RESULTS:
CLEAN PRESSURE DROP
THERMAL RESISTANCE
FOULING RESISTANCE
INPUT VELOCITY
OUTLET VELOCITY
MIDPOINT VELOCITY
FOULING % OF OVERALL RESISTANCE
FILM % OF OVERALL RESISTANCE
FRICTIONAL PRESSURE DROP

***
SHELLSIDE RESULTS:
CLEAN PRESSURE DROP
THERMAL RESISTANCE
FOULING RESISTANCE
CROSSFLOW VELOCITY
WINDOW VELOCITY
MIDPOINT VELOCITY
SHELL EXIT RHOV^2
BUNDLE EXIT RHOV^2
F
PSI
PSI
PSI
PSI
BTU/HR-SQFT-R
BTU/HR-SQFT-R
HR-SQFT-R/BTU
HR-SQFT-R/BTU
HR-SQFT-R/BTU
FT/SEC
FT/SEC
FT/SEC
LB/FT-SQSEC
LB/FT-SQSEC
LB/FT-SQSEC
LB/FT-SQSEC
BTU/HR-SQFT-R
BTU/HR-SQFT-R
BTU/HR-R
F
BTU/HR
SQFT
SQFT
3.5000D+02
2.2910D+02
0.0000D+00
3.7245D+02
4.2854D+02
1.0000D+00
389.8975
0.2113
0.0000
0.0000
0.0022
45.7900
45.7900
0.0218
0.001998
0.0000
3.9666
3.3665
3.6665
42.2892
478.3267
0.6989
49.5610
0.0000
58595593.7076
845792.6903
861618.7320
1.8711
1.8711
4.6816
4.6816
3959641.3261
14.7982
0.1231
1
1
20
T=
P=
V=
10
T=
P=
V=
ASPEN PLUS
ASPEN PLUS
B2.EDR
DESIGN
30
0.000100000
-------------------------------------|
|
----->|
HOT (TUBE)
|----->
7.4739D+02 |
|
4.2913D+02 |
|
1.0000D+00 |
|
|
|
<-----|
COLD (SHELL)
|<----3.9340D+02 |
|
2.2889D+02 |
|
1.0000D+00 |
|
--------------------------------------
OVERALL RESULTS
UNIT RESULTS:
UA (DIRTY)
LMTD (CORRECTED)
13
T=
P=
V=
2
T=
P=
V=
STREAMS:
***


TWO
PHASE
FLASH
PSI
F
PSI
BTU/HR-SQFT-R
BTU/HR-SQFT-R
HR-SQFT-R/BTU
HR-SQFT-R/BTU
HR-SQFT-R/BTU
FT/SEC
FT/SEC
FT/SEC
PSI
391.6244
0.5938
5.2229
5.2229
0.1915
0.001998
0.0000
1.1012
0.7594
0.7594
0.0000
89.6352
0.5939
10.2240
0.2113
ASPEN PLUS
ASPEN PLUS
B3.EDR
DESIGN


30
0.000100000

TWO
PHASE
FLASH
***
30
0.000100000
INPUT DATA
0.00000
0.181132E-08
RELATIVE DIFF.
0.00000
0.00000
0.00000

TWO
PHASE
FLASH
***

IN
OUT
22934.1
22934.1
(LB/HR
)
408591.
408591.
NONCONV. COMP(LB/HR
)
0.00000
0.00000
TOTAL BALANCE
MASS(LB/HR
)
408591.
408591.
ENTHALPY(BTU/HR )
-0.132493E+10
-0.132493E+10
***
BLOCK: B3
MODEL: HEATX
HOT SIDE:
10
OUTLET STREAM:
11
COLD SIDE:
16
OUTLET STREAM:
20
TUBESIDE RESULTS:
CLEAN PRESSURE DROP
THERMAL RESISTANCE
FOULING RESISTANCE
INPUT VELOCITY
OUTLET VELOCITY
MIDPOINT VELOCITY

***
PSI
F
PSI
BTU/HR-SQFT-R
BTU/HR-SQFT-R
HR-SQFT-R/BTU
HR-SQFT-R/BTU
HR-SQFT-R/BTU
TUBESIDE RESULTS:
CLEAN PRESSURE DROP
THERMAL RESISTANCE
FOULING RESISTANCE
F
PSI
PSI
PSI
PSI
BTU/HR-SQFT-R
BTU/HR-SQFT-R
HR-SQFT-R/BTU
HR-SQFT-R/BTU
HR-SQFT-R/BTU
FT/SEC
FT/SEC
FT/SEC
LB/FT-SQSEC
LB/FT-SQSEC
LB/FT-SQSEC
LB/FT-SQSEC
SHELLSIDE RESULTS:
CLEAN PRESSURE DROP
THERMAL RESISTANCE
FOULING RESISTANCE
CROSSFLOW VELOCITY
WINDOW VELOCITY
MIDPOINT VELOCITY
SHELL EXIT RHOV^2
BUNDLE EXIT RHOV^2
BTU/HR-SQFT-R
BTU/HR-SQFT-R
BTU/HR-R
F
BTU/HR
SQFT
SQFT
16
T=
P=
V=
11
T=
P=
V=
2.8000D+02
2.2956D+02
0.0000D+00
3.4161D+02
4.2533D+02
1.0000D+00
332.6893
3.2086
268.0660
268.0660
0.0037
0.000250
0.0000
320.6439
0.4595
0.0066
0.0066
0.0333
625.9575
625.9575
0.0016
0.000250
0.0000
1.1309
0.7728
0.9518
452.4210
638.7690
79.9936
83.3761
0.0000
28.4883
0.4593
4699893.7208
681.9337
742.6915
8.9096
8.9096
178.3246
178.3246
121605.5691
38.6487
0.9964
1
1
-------------------------------------|
|
----->|
HOT (TUBE)
|----->
3.7245D+02 |
|
4.2854D+02 |
|
1.0000D+00 |
|
|
|
<-----|
COLD (SHELL)
|<----3.5000D+02 |
|
2.2910D+02 |
|
0.0000D+00 |
|
--------------------------------------
OVERALL RESULTS
UNIT RESULTS:
UA (DIRTY)
LMTD (CORRECTED)
20
T=
P=
V=
10
T=
P=
V=
STREAMS:
***
PSI
FT/SEC
FT/SEC
FT/SEC
89.0501
86.3601
86.3601
0.0000
66.5227
3.2592
16
11
T=
P=
V=
***
OVERALL RESULTS
***
-------------------------------------|
|
----->|
HOT (TUBE)
|----->
3.4161D+02 |
|
4.2533D+02 |
|
1.0000D+00 |
|
|
|
<-----|
COLD (SHELL)
|<-----
STREAMS:
12
17
T=
P=
V=
2.5440D+02
4.2244D+02
1.0000D+00
ASPEN PLUS
ASPEN PLUS
B5.EDR
DESIGN


30
0.000100000

TWO
PHASE
FLASH
***
30
0.000100000
INPUT DATA
0.00000
0.102306E-10
RELATIVE DIFF.
0.00000
0.00000
0.00000

TWO
PHASE
FLASH
***

IN
OUT
22934.1
22934.1
(LB/HR
)
408591.
408591.
NONCONV. COMP(LB/HR
)
0.00000
0.00000
TOTAL BALANCE
MASS(LB/HR
)
408591.
408591.
ENTHALPY(BTU/HR )
-0.134283E+10
-0.134283E+10
***
BLOCK: B5
MODEL: HEATX
HOT SIDE:
11
OUTLET STREAM:
17
COLD SIDE:
12
OUTLET STREAM:
16
INPUT VELOCITY
OUTLET VELOCITY
MIDPOINT VELOCITY
2.8000D+02
2.2956D+02
0.0000D+00
BLOCK: B4
MODEL: HEATX
----------------------------THIS BLOCK RUNS WITH ASPEN EDR 25.0
HOT SIDE:
TUBESIDE RESULTS:
CLEAN PRESSURE DROP
THERMAL RESISTANCE
FOULING RESISTANCE
INPUT VELOCITY
OUTLET VELOCITY
MIDPOINT VELOCITY
SHELLSIDE RESULTS:
CLEAN PRESSURE DROP
THERMAL RESISTANCE
FOULING RESISTANCE
CROSSFLOW VELOCITY
WINDOW VELOCITY
MIDPOINT VELOCITY
SHELL EXIT RHOV^2
BUNDLE EXIT RHOV^2
7.7537D+01
2.3000D+02
0.0000D+00
232.3995
2.8848
263.2933
263.2933
0.0038
0.000078
0.0000
86.3601
77.3556
77.3556
0.0000
63.5184
3.0374
194.0630
0.4412
0.0058
0.0058
0.0349
524.5846
524.5846
0.0019
0.000078
0.0000
1.0850
0.7414
0.9132
421.0339
612.8527
74.4439
79.9934
0.0000
31.8804
0.4411
13195202.0917
723.7915
742.6915
2.6113
2.6113
167.2397
167.2397
121046.6825
109.0092
0.9974
1
1
T=
P=
V=
WITH ADVANCED METHOD FOR SHELL&TUBE
PSI
F
PSI
BTU/HR-SQFT-R
BTU/HR-SQFT-R
HR-SQFT-R/BTU
HR-SQFT-R/BTU
HR-SQFT-R/BTU
FT/SEC
FT/SEC
FT/SEC
PSI
F
PSI
PSI
PSI
PSI
BTU/HR-SQFT-R
BTU/HR-SQFT-R
HR-SQFT-R/BTU
HR-SQFT-R/BTU
HR-SQFT-R/BTU
FT/SEC
FT/SEC
FT/SEC
LB/FT-SQSEC
LB/FT-SQSEC
LB/FT-SQSEC
LB/FT-SQSEC
BTU/HR-SQFT-R
BTU/HR-SQFT-R
BTU/HR-R
F
BTU/HR
SQFT
SQFT
|
|
|
|
|
|
--------------------------------------
UNIT RESULTS:
UA (DIRTY)
LMTD (CORRECTED)
T=
P=
V=
RAWGAS
15
ELECNRTL
7
8
ELECNRTL
OVERALL RESULTS
***
-------------------------------------|
|
RAWGAS
----->|
HOT (TUBE)
|----->
T= 1.7000D+03 |
|
P= 4.6470D+02 |
|
V= 1.0000D+00 |
|
|
|
8
<-----|
COLD (SHELL)
|<----T= 1.4000D+03 |
|
P= 1.7979D+03 |
|
V= 1.0000D+00 |
|
STREAMS:
***
1.3705D+03
4.6121D+02
1.0000D+00
6.2069D+02
1.7990D+03
1.0000D+00
15
T=
P=
V=
7
T=
P=
V=
ASPEN PLUS
ASPEN PLUS
B4.EDR
DESIGN


30
0.000100000

TWO
PHASE
FLASH
***
30
0.000100000
INPUT DATA
0.00000
0.773010E-13
RELATIVE DIFF.
0.00000
0.00000
0.00000

TWO
PHASE
FLASH
***

IN
OUT
25987.0
25987.0
(LB/HR
)
463591.
463591.
NONCONV. COMP(LB/HR
)
0.00000
0.00000
TOTAL BALANCE
MASS(LB/HR
)
463591.
463591.
ENTHALPY(BTU/HR )
-0.135092E+10
-0.135092E+10
***
***********************************************************************
*
*
*
A POTENTIAL TUBE VIBRATIEON PROBLEM IS INDICATED
*
*
*
***********************************************************************
OUTLET STREAM:
COLD SIDE:
OUTLET STREAM:
***
1327.5106
3.4848
190.1462
190.1462
0.0053
0.000972
0.0000
140.5855
120.1210
120.1210
0.0000
41.7601
3.7107
1059.6629
1.1265
0.0691
0.0691
0.2945
161.9955
161.9955
0.0062
0.000972
0.0000
37.0096
26.2581
31.6339
380.8244
906.3478
306.5640
728.2066
0.0000
49.0170
1.0785
57458148.3230
1471.8175
1698.9621
15.4329
15.4329
79.4053
79.4053
116870.0803
491.6412
1.0012
1
1
***
PSI
F
PSI
BTU/HR-SQFT-R
BTU/HR-SQFT-R
HR-SQFT-R/BTU
HR-SQFT-R/BTU
HR-SQFT-R/BTU
FT/SEC
FT/SEC
FT/SEC
PSI
MASS AND ENERGY BALANCE
BLOCK: B6
MODEL: PUMP
---------------------------INLET STREAM:
6
OUTLET STREAM:
12
ELECNRTL
TUBESIDE RESULTS:
CLEAN PRESSURE DROP
THERMAL RESISTANCE
FOULING RESISTANCE
INPUT VELOCITY
OUTLET VELOCITY
MIDPOINT VELOCITY
F
PSI
PSI
PSI
PSI
BTU/HR-SQFT-R
BTU/HR-SQFT-R
HR-SQFT-R/BTU
HR-SQFT-R/BTU
HR-SQFT-R/BTU
FT/SEC
FT/SEC
FT/SEC
LB/FT-SQSEC
LB/FT-SQSEC
LB/FT-SQSEC
LB/FT-SQSEC
BTU/HR-SQFT-R
BTU/HR-SQFT-R
BTU/HR-R
F
BTU/HR
SQFT
SQFT
SHELLSIDE RESULTS:
CLEAN PRESSURE DROP
THERMAL RESISTANCE
FOULING RESISTANCE
CROSSFLOW VELOCITY
WINDOW VELOCITY
MIDPOINT VELOCITY
SHELL EXIT RHOV^2
BUNDLE EXIT RHOV^2
UNIT RESULTS:
UA (DIRTY)
LMTD (CORRECTED)
--------------------------------------
***
1,044.16
215.304
32.9279
16.3499
28.7429
21.4336
0.56883
28.7429
498.043
30
0.000100000
***
***
***
HP
HP
HP
HP
HP
RESULTS
INPUT DATA
-12,500.0
-12,500.0
-12,500.0
0.0
-13,888.9
298.796
854.394
12,500.0
0.90000
1.00000
0.00000
0.489477E-01
RELATIVE DIFF.
0.00000
0.00000
0.00000
INDICATED HORSEPOWER REQUIREMENT

BRAKE
HORSEPOWER REQUIREMENT
NET WORK REQUIRED
POWER LOSSES
ISENTROPIC HORSEPOWER REQUIREMENT
CALCULATED OUTLET PRES PSIA
CALCULATED OUTLET TEMP F
ISENTROPIC TURBINE
POWER SUPPLIED HP
ISENTROPIC EFFICIENCY
MECHANICAL EFFICIENCY
***
0.00000
-0.164954E-03
RELATIVE DIFF.
0.00000
0.00000
0.00000
230.000
1.00000
65000.0
-0.443290E+09
OUT
3608.05
65000.0
0.00000

IN
OUT
6661.01
6661.01
(LB/HR
)
120000.
120000.
NONCONV. COMP(LB/HR
)
0.00000
0.00000
TOTAL BALANCE
MASS(LB/HR
)
120000.
120000.
ENTHALPY(BTU/HR )
-0.617979E+09
-0.649784E+09
***
BLOCK: B8
MODEL: COMPR
----------------------------INLET STREAM:
8
OUTLET STREAM:
27
ELECNRTL
*** RESULTS
PRESSURE CHANGE PSI
NPSH AVAILABLE
FT-LBF/LB
FLUID POWER HP
BRAKE POWER HP
ELECTRICITY KW
***
***
INPUT DATA
LIQUID PHASE CALCULATION
NO FLASH PERFORMED
MAXIMUM NUMBER OF ITERATIONS
TOLERANCE
OUTLET PRESSURE PSIA

DRIVER EFFICIENCY
IN
3608.05
(LB/HR
)
65000.0
NONCONV. COMP(LB/HR
)
0.00000
TOTAL BALANCE
MASS(LB/HR
)
65000.0
ENTHALPY(BTU/HR )
-0.443363E+09
797.005
0.90000
1.00000
-229,167.
1.00000
1.30710
70,787.0
307,265.
0.95741
0.97740
1.26380
1.27940
1.22247
1.23992
STREAMS:
***
OVERALL RESULTS

***
ASPEN PLUS
ASPEN PLUS
B7.EDR
DESIGN
30
0.000100000

***
30
0.000100000
INPUT DATA
-0.251117E-15
-0.131380E-05
RELATIVE DIFF.
0.00000
-0.251117E-15
0.00000

TWO
PHASE
FLASH

TWO
PHASE
FLASH
***

IN
OUT
25987.0
25987.0
(LB/HR
)
463591.
463591.
NONCONV. COMP(LB/HR
)
0.00000
0.00000
TOTAL BALANCE
MASS(LB/HR
)
463591.
463591.
ENTHALPY(BTU/HR )
-0.148304E+10
-0.148304E+10
***
BLOCK: B7
MODEL: HEATX
HOT SIDE:
15
OUTLET STREAM:
14
COLD SIDE:
5
OUTLET STREAM:
7
ISENTROPIC TEMPERATURE F
EFFICIENCY (POLYTR/ISENTR) USED
OUTLET VAPOR FRACTION
HEAD DEVELOPED,
FT-LBF/LB
MECHANICAL EFFICIENCY USED
INLET HEAT CAPACITY RATIO
INLET VOLUMETRIC FLOW RATE , CUFT/HR
OUTLET VOLUMETRIC FLOW RATE, CUFT/HR
INLET COMPRESSIBILITY FACTOR
OUTLET COMPRESSIBILITY FACTOR
AV. ISENT. VOL. EXPONENT
AV. ISENT. TEMP EXPONENT
AV. ACTUAL VOL. EXPONENT
AV. ACTUAL TEMP EXPONENT
PSI
F
PSI
BTU/HR-SQFT-R
BTU/HR-SQFT-R
HR-SQFT-R/BTU
HR-SQFT-R/BTU
HR-SQFT-R/BTU
FT/SEC
FT/SEC
FT/SEC
TUBESIDE RESULTS:
CLEAN PRESSURE DROP
THERMAL RESISTANCE
FOULING RESISTANCE
INPUT VELOCITY
OUTLET VELOCITY
MIDPOINT VELOCITY
F
PSI
PSI
PSI
PSI
BTU/HR-SQFT-R
BTU/HR-SQFT-R
HR-SQFT-R/BTU
HR-SQFT-R/BTU
HR-SQFT-R/BTU
FT/SEC
FT/SEC
FT/SEC
LB/FT-SQSEC
LB/FT-SQSEC
LB/FT-SQSEC
LB/FT-SQSEC
BTU/HR-SQFT-R
BTU/HR-SQFT-R
BTU/HR-R
F
BTU/HR
SQFT
SQFT
SHELLSIDE RESULTS:
CLEAN PRESSURE DROP
THERMAL RESISTANCE
FOULING RESISTANCE
CROSSFLOW VELOCITY
WINDOW VELOCITY
MIDPOINT VELOCITY
SHELL EXIT RHOV^2
BUNDLE EXIT RHOV^2
UNIT RESULTS:
UA (DIRTY)
LMTD (CORRECTED)
7
T=
P=
V=
15
T=
P=
V=
5
T=
P=
V=
14
T=
P=
V=
6.0000D+02
1.7997D+03
0.0000D+00
9.2466D+02
4.5759D+02
1.0000D+00
695.6826
3.6249
228.6290
228.6290
0.0044
0.000126
0.0000
165.4779
126.2959
126.2959
619.7907
0.6517
0.0303
0.0303
0.1287
3352.2584
3352.2584
0.0003
0.000126
0.0000
18.9682
11.0052
14.9867
222.5189
1083.6923
180.1028
672.0643
0.0000
5.3325
0.6043
74666443.2122
840.4686
878.3812
4.5109
4.5109
178.7576
178.7576
150240.1539
496.9806
0.9785
1
1
-------------------------------------|
|
----->|
HOT (TUBE)
|----->
1.3705D+03 |
|
4.6121D+02 |
|
1.0000D+00 |
|
|
|
<-----|
COLD (SHELL)
|<----6.2069D+02 |
|
1.7990D+03 |
|
1.0000D+00 |
|
--------------------------------------
***
***
TWO
PHASE TP FLASH
SPECIFIED TEMPERATURE
SPECIFIED PRESSURE
0.00000
-0.121576E-02
RELATIVE DIFF.
0.00000
0.00000
0.00000
***
F
PSIA
INPUT DATA
400.000
1,800.00
30
0.00000
-0.474321E-01
RELATIVE DIFF.
0.00000
0.00000
0.00000
1,927.67
1,785.30
32.9279
250.290
391.096
291.640
0.63997
391.096
4,129.78
30
0.000100000
1,800.00
1.00000

IN
OUT
6661.01
6661.01
(LB/HR
)
120000.
120000.
NONCONV. COMP(LB/HR
)
0.00000
0.00000
TOTAL BALANCE
MASS(LB/HR
)
120000.
120000.
ENTHALPY(BTU/HR )
-0.817521E+09
-0.778744E+09
***
BLOCK: B12
MODEL: HEATER
-----------------------------INLET STREAM:
3
OUTLET STREAM:
23
ELECNRTL
*** RESULTS
PRESSURE CHANGE PSI
NPSH AVAILABLE
FT-LBF/LB
FLUID POWER HP
BRAKE POWER HP
ELECTRICITY KW
***
***
INPUT DATA
NO FLASH PERFORMED
TOLERANCE

DRIVER EFFICIENCY
0.0000
78.1868
4.2168
PSI

IN
OUT
6661.01
6661.01
(LB/HR
)
120000.
120000.
NONCONV. COMP(LB/HR
)
0.00000
0.00000
TOTAL BALANCE
MASS(LB/HR
)
120000.
120000.
ENTHALPY(BTU/HR )
-0.818516E+09
-0.817521E+09
***
BLOCK: B9
MODEL: PUMP
---------------------------INLET STREAM:
19
OUTLET STREAM:
3
ELECNRTL

F(I)
1.0000
Y(I)
1.0000
K(I)
0.18102
400.00
1800.0
0.38777E+08
0.0000
0.0000
MOISTR15
X(I)
1.0000
***
0.000100000
WATER
OUTLET TEMPERATURE
OUTLET PRESSURE
HEAT DUTY
VAPOR FRACTION
INERTS:
MASS-YIELD
SUBSTREAM MIXED
HYDROGEN
6.30
NITROGEN 0.100
***
***
53.1
INPUT DATA
*** RESULTS
F
PSIA
BTU/HR
***
TWO
PHASE TP FLASH
SPECIFIED TEMPERATURE F
SPECIFIED PRESSURE
PSIA
-0.121224E-15
-1.33416
RELATIVE DIFF.
0.00000
-0.869566
1.00000
OXYGEN
1700.0
464.70
0.33893E+10
0.54081
40.5
1,700.00
464.696
30
0.000100000
*** MASS AND ENERGY BALANCE ***

IN
OUT
GENERATION
1738.25
20142.0
18403.8
(LB/HR
)
31315.0
240084.
NONCONV COMP(LB/HR
)
208769.
0.00000
TOTAL BALANCE
MASS(LB/HR
)
240084.
240084.
ENTHALPY(BTU/HR )-0.848909E+09 0.254042E+10
***********************************************************************
*
*
*
SPECIFIED YIELDS HAVE BEEN NORMALIZED TO MAINTAIN MASS BALANCE *
*
*
***********************************************************************
BLOCK: DECOMP
MODEL: RYIELD
-----------------------------INLET STREAMS:
WOODCHIP
OUTLET STREAM:
ELMTCOMP
ELECNRTL
COMP
WATER
V-L PHASE EQUILIBRIUM :
*** RESULTS
OUTLET TEMPERATURE
F
OUTLET PRESSURE
PSIA
HEAT DUTY
BTU/HR
PRESSURE-DROP CORRELATION PARAMETER
F(I)
0.32392
0.45822
0.13119
0.37000E-03
0.86300E-01
O2

IN
OUT
24497.7
19326.0
343591.
343591.
0.00000
0.00000
K(I)
5768.2
0.14586E-12
726.06
749.44
95.670
INPUT DATA
***
***
GENERATION
-5171.65
0.271056E-14
1.30061
RELATIVE DIFF.
-0.148503E-15
0.271056E-14
0.00000
TEMPERATURE
PRESSURE
HEAT DUTY
ATOM MATRIX:
ELEMENT
HYDROGEN
C
OXYGEN
NITROGEN
CO
CO2
METHANE
WATER
SULFUR
MEA
ARGON
NITRO-01
NITRO-02
NITRO-02
H
2.00
0.00
0.00
0.00
0.00
0.00
4.00
2.00
0.00
7.00
0.00
0.00
0.00
N
0.00
0.00
0.00
2.00
0.00
0.00
0.00
0.00
0.00
1.00
0.00
1.00
2.00
O
0.00
0.00
2.00
0.00
1.00
2.00
0.00
1.00
0.00
1.00
0.00
2.00
1.00
S
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
1.00
0.00
0.00
0.00
0.00
*** RESULTS
F
PSIA
BTU/HR
C
0.00
1.00
0.00
0.00
1.00
1.00
1.00
0.00
0.00
2.00
0.00
0.00
0.00
***
AR
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
1.00
0.00
0.00
1700.0
464.70
-0.29225E+10
FLUID PHASE SPECIES IN PRODUCT LIST:

HYDROGEN C OXYGEN NITROGEN CO CO2 METHANE SULFUR ARGON NITRO-01
EQUILIBRIUM SPECIFICATIONS:
ONLY CHEMICAL EQUILIBRIUM IS CONSIDERED, THE FLUID PHASE IS VAPOR
SYSTEM TEMPERATURE
F
1700.0
TEMPERATURE FOR FREE ENERGY EVALUATION
F
1700.0
SYSTEM PRESSURE
PSIA
464.70
***
Y(I)
0.59886
0.14556E-12
0.24229
0.68337E-03
0.15817
STEAM
X(I)
0.10382E-03
0.99791
0.33370E-03
0.91184E-06
0.16533E-02
(LB/HR
)
NONCONV COMP(LB/HR
)
TOTAL BALANCE
MASS(LB/HR
)
343591.
343591.
ENTHALPY(BTU/HR ) 0.224701E+10 -0.675481E+09
***
BLOCK: GASIFR2 MODEL: RGIBBS

-----------------------------INLET STREAMS:
ELMTCOMP
OUTLET STREAM:
RAWGAS
ELECNRTL
COMP
HYDROGEN
C
OXYGEN
NITROGEN
WATER
LBMOL/HR
PHASE
OF TYPE
PHASE FRACTION
PLACED IN STREAM
HYDROGEN
OXYGEN
NITROGEN
CO
CO2
METHANE
ARGON
NITRO-01
NITRO-02
C
19326.02
VAPOR
VAPOR
1.000000
RAWGAS
0.5175001
0.7393533E-17
0.1294056E-02
0.2400411
0.2152437
0.2228731E-01
0.3633756E-02
0.1952746E-22
0.7185946E-18
0.5012321E-25
FLUID PHASE MOLE FRACTIONS:
VAPOR FRACTION
NUMBER OF FLUID PHASES
1.0000
1
10
B2
B3
MIXNC
MAX CONV. ERROR:

0.0
TOTAL STREAM:
LB/HR
3.4359+05
BTU/HR
-8.9484+08
SUBSTREAM: MIXED
PHASE:
VAPOR
COMPONENTS: LBMOL/HR
HYDROGEN
1.0001+04
C
9.6868-22
OXYGEN
1.4289-13
NITROGEN
25.0090
CO
4639.0385
CO2
4159.8043
METHANE
430.7250
WATER
0.0
SULFUR
0.0
MEA
0.0
ARGON
70.2260
NITRO-01
3.7739-19
NITRO-02
1.3888-14
COMPONENTS: MOLE FRAC
HYDROGEN
0.5175
C
5.0123-26
OXYGEN
7.3935-18
NITROGEN
1.2941-03
CO
0.2400
CO2
0.2152
METHANE
2.2287-02
WATER
0.0
SULFUR
0.0
MEA
0.0
ARGON
3.6338-03
NITRO-01
1.9527-23
NITRO-02
7.1859-19
TOTAL FLOW:
LBMOL/HR
1.9326+04
LB/HR
3.4359+05
CUFT/HR
4.0551+05
STATE VARIABLES:
TEMP
F
372.4459
PRES
PSIA
428.5362
VFRAC
1.0000
LFRAC
0.0
SFRAC
0.0
ENTHALPY:
BTU/LBMOL
-4.6302+04
BTU/LB
-2604.3786
BTU/HR
-8.9484+08
ENTROPY:
BTU/LBMOL-R
3.6786
BTU/LB-R
0.2069
STREAM ID
FROM :
TO
:
CLASS:
10 11 12 13 14
--------------
0.0
12
B6
B5
MIXNC
0.0
13
B2
---MIXNC
4.9302-07
14
B7
ALKFILTR
MIXNC
0.0
0.0
0.0
0.0
0.0
0.0
0.0
3608.0483
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
1.0000
0.0
0.0
0.0
0.0
0.0
3608.0483
6.5000+04
1043.5431
77.5371
230.0000
0.0
1.0000
0.0
0.5175
5.0123-26
7.3935-18
1.2941-03
0.2400
0.2152
2.2287-02
0.0
0.0
0.0
3.6338-03
1.9527-23
7.1859-19
1.9326+04
3.4359+05
3.9326+05
341.6102
425.3276
1.0000
0.0
0.0
393.4006
228.8880
1.0000
0.0
0.0
3608.0483
6.5000+04
1.3547+05
0.0
0.0
0.0
0.0
0.0
0.0
0.0
1.0000
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
3608.0483
0.0
0.0
0.0
0.0
0.0
VAPOR
VAPOR
924.6566
457.5862
1.0000
0.0
0.0
1.9326+04
3.4359+05
6.3254+05
0.5175
5.0123-26
7.3935-18
1.2941-03
0.2400
0.2152
2.2287-02
0.0
0.0
0.0
3.6338-03
1.9527-23
7.1859-19
1.0001+04
9.6868-22
1.4289-13
25.0090
4639.0385
4159.8043
430.7250
0.0
0.0
0.0
70.2260
3.7739-19
1.3888-14
3.3958
0.1910
-38.9505
-2.1621
-12.4825
-0.6929
7.6963
0.4329
-4.6546+04 -1.2286+05 -1.0166+05 -4.1789+04

-2618.0573 -6819.8435 -5643.0877 -2350.4882
-8.9954+08 -4.4329+08 -3.6680+08 -8.0761+08
LIQUID
VAPOR
1.0001+04
9.6868-22
1.4289-13
25.0090
4639.0385
4159.8043
430.7250
0.0
0.0
0.0
70.2260
3.7739-19
1.3888-14
3.4359+05 6.5000+04 6.5000+04 3.4359+05

-8.9954+08 -4.4329+08 -3.6680+08 -8.0761+08
0.0
11
B3
B5
MIXNC
15
B4
B7
MIXNC
4.7659-02
0.8473
17.7787
MAX CONV. ERROR:

0.0
TOTAL STREAM:
LB/HR
3.4359+05
BTU/HR
-7.3294+08
SUBSTREAM: MIXED
PHASE:
VAPOR
HYDROGEN
1.0001+04
C
9.6868-22
OXYGEN
1.4289-13
NITROGEN
25.0090
CO
4639.0385
CO2
4159.8043
METHANE
430.7250
WATER
0.0
SULFUR
0.0
MEA
0.0
ARGON
70.2260
NITRO-01
3.7739-19
NITRO-02
1.3888-14
HYDROGEN
0.5175
C
5.0123-26
OXYGEN
7.3935-18
NITROGEN
1.2941-03
CO
0.2400
CO2
0.2152
METHANE
2.2287-02
WATER
0.0
SULFUR
0.0
MEA
0.0
ARGON
3.6338-03
NITRO-01
1.9527-23
NITRO-02
7.1859-19
TOTAL FLOW:
LBMOL/HR
1.9326+04
LB/HR
3.4359+05
CUFT/HR
8.2877+05
STATE VARIABLES:
TEMP
F
1370.4723
PRES
PSIA
461.2111
VFRAC
1.0000
LFRAC
0.0
SFRAC
0.0
ENTHALPY:
BTU/LBMOL
-3.7925+04
BTU/LB
-2133.1749
STREAM ID
FROM :
TO
:
CLASS:
15 16 17 18 19
--------------
DENSITY:
LBMOL/CUFT
LB/CUFT
AVG MW
0.0
17
B5
---MIXNC
3.4575
62.2878
18.0153
0.0
18
ALKFILTR
B1
MIXNC
2.6633-02
0.4798
18.0153
0.0
19
---B9
MIXNC
3.0553-02
0.5432
17.7787
1.0001+04
9.6868-22
1.4289-13
25.0090
4639.0385
4159.8043
430.7250
0.0
0.0
0.0
70.2260
3.7739-19
1.3888-14
0.5175
5.0123-26
7.3935-18
1.2941-03
0.2400
0.2152
2.2287-02
0.0
0.0
0.0
3.6338-03
1.9527-23
7.1859-19
1.9326+04
3.4359+05
3.5225+05
254.4046
422.4428
1.0000
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
3608.0483
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
1.0000
0.0
0.0
0.0
0.0
0.0
3608.0483
6.5000+04
1121.3369
280.0000
229.5588
0.0
1.0000
0.0
924.7125
432.5862
1.0000
0.0
0.0
1.9326+04
3.4359+05
6.6882+05
0.5175
5.0123-26
7.3935-18
1.2941-03
0.2400
0.2152
2.2287-02
0.0
0.0
0.0
3.6338-03
1.9527-23
7.1859-19
1.0001+04
9.6868-22
1.4289-13
25.0090
4639.0385
4159.8043
430.7250
0.0
0.0
0.0
70.2260
3.7739-19
1.3888-14
VAPOR
77.0000
14.6959
0.0
1.0000
0.0
6661.0122
1.2000+05
1927.6749
0.0
0.0
0.0
0.0
0.0
0.0
0.0
1.0000
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
6661.0122
0.0
0.0
0.0
0.0
0.0
LIQUID
-1.1920+05 -4.7228+04 -4.1789+04 -1.2288+05

-6616.8404 -2656.4612 -2350.4882 -6820.9686
VAPOR
LIQUID
6.5000+04 3.4359+05 3.4359+05 1.2000+05

-4.3009+08 -9.1274+08 -8.0761+08 -8.1852+08
-2.4570-10
16
B5
B3
MIXNC
4.9143-02
0.8737
17.7787
2
B1
B2
MIXNC
2.3319-02
0.4146
17.7787
10.0971
0.5679
20
B3
B2
MIXNC
3.2176
57.9665
18.0153
-33.1769
-1.8416
23
B12
B1
MIXNC
5.4864-02
0.9754
17.7787
2.5074
0.1410
27
B8
---MIXNC
2.8896-02
0.5137
17.7787
7.8087
0.4392
3
B9
B12
MIXNC
3.4555
62.2512
18.0153
-38.9657
-2.1629
-7.3294+08 -4.3009+08 -9.1274+08 -8.0761+08 -8.1852+08
MAX CONV. ERROR:

0.0
-5.5247-11
0.0
0.0
0.0
TOTAL STREAM:
LB/HR
3.4359+05 6.5000+04 1.2000+05 1.2000+05 1.2000+05
BTU/HR
-8.3624+08 -4.2539+08 -7.7874+08 -6.4978+08 -8.1752+08
SUBSTREAM: MIXED
PHASE:
VAPOR
LIQUID
LIQUID
VAPOR
LIQUID
HYDROGEN
1.0001+04
0.0
0.0
0.0
0.0
C
9.6868-22
0.0
0.0
0.0
0.0
OXYGEN
1.4289-13
0.0
0.0
0.0
0.0
NITROGEN
25.0090
0.0
0.0
0.0
0.0
CO
4639.0385
0.0
0.0
0.0
0.0
CO2
4159.8043
0.0
0.0
0.0
0.0
METHANE
430.7250
0.0
0.0
0.0
0.0
WATER
0.0
3608.0483 6661.0122 6661.0122 6661.0122
SULFUR
0.0
0.0
0.0
0.0
0.0
MEA
0.0
0.0
0.0
0.0
0.0
ARGON
70.2260
0.0
0.0
0.0
0.0
NITRO-01
3.7739-19
0.0
0.0
0.0
0.0
NITRO-02
1.3888-14
0.0
0.0
0.0
0.0
HYDROGEN
0.5175
0.0
0.0
0.0
0.0
C
5.0123-26
0.0
0.0
0.0
0.0
OXYGEN
7.3935-18
0.0
0.0
0.0
0.0
NITROGEN
1.2941-03
0.0
0.0
0.0
0.0
CO
0.2400
0.0
0.0
0.0
0.0
CO2
0.2152
0.0
0.0
0.0
0.0
METHANE
2.2287-02
0.0
0.0
0.0
0.0
WATER
0.0
1.0000
1.0000
1.0000
1.0000
SULFUR
0.0
0.0
0.0
0.0
0.0
MEA
0.0
0.0
0.0
0.0
0.0
ARGON
3.6338-03
0.0
0.0
0.0
0.0
NITRO-01
1.9527-23
0.0
0.0
0.0
0.0
NITRO-02
7.1859-19
0.0
0.0
0.0
0.0
TOTAL FLOW:
LBMOL/HR
1.9326+04 3608.0483 6661.0122 6661.0122 6661.0122
LB/HR
3.4359+05 6.5000+04 1.2000+05 1.2000+05 1.2000+05
CUFT/HR
5.8801+05 1168.7560 2215.1476 3.0726+05 1918.2296
STATE VARIABLES:
TEMP
F
747.3931
350.0000
400.0000
854.3938
80.4577
PRES
PSIA
429.1300
229.0993 1800.0000
298.7956 1800.0000
VFRAC
1.0000
0.0
0.0
1.0000
0.0
LFRAC
0.0
1.0000
1.0000
0.0
1.0000
STREAM ID
FROM :
TO
:
CLASS:
2 20 23 27 3
------------
BTU/HR
ENTROPY:
BTU/LBMOL-R
BTU/LB-R
DENSITY:
LBMOL/CUFT
LB/CUFT
AVG MW
0.0
0.0
0.0
0.0
6
---B6
MIXNC
3.0871
55.6147
18.0153
3.2867-02
0.5843
17.7787
5
B1
B7
MIXNC
-31.4946
-1.7482
6.6796
0.3757
7
B7
B4
MIXNC
3.0070
54.1725
18.0153
-30.4223
-1.6887
8
B4
B8
MIXNC
2.1678-02
0.3905
18.0153
-9.1454
-0.5076
2.0142+04
2.4008+05
5.4677+05
0.3239
0.4582
0.1312
3.7000-04
0.0
0.0
0.0
8.6300-02
0.0
0.0
0.0
0.0
0.0
6524.4196
9229.5678
2642.3317
7.4524
0.0
0.0
0.0
1738.2466
0.0
0.0
0.0
0.0
0.0
MIXED
2.4008+05
2.5404+09
0.0
ELMTCOMP
DECOMP
GASIFR2
MIXNC
3.4725
62.5577
18.0153
-38.8673
-2.1575
-4.3270+04 -1.1790+05 -1.1691+05 -9.7550+04 -1.2273+05

-2433.8397 -6544.5344 -6489.5362 -5414.8669 -6812.6760
-8.3624+08 -4.2539+08 -7.7874+08 -6.4978+08 -8.1752+08
0.0
MAX CONV. ERROR:

0.0
0.0
-1.5009-10
0.0
TOTAL STREAM:
LB/HR
1.2000+05 6.5000+04 1.2000+05 1.2000+05
BTU/HR
-7.5011+08 -4.4336+08 -6.7544+08 -6.1798+08
SUBSTREAM: MIXED
PHASE:
LIQUID
LIQUID
VAPOR
VAPOR
HYDROGEN
0.0
0.0
0.0
0.0
C
0.0
0.0
0.0
0.0
OXYGEN
0.0
0.0
0.0
0.0
NITROGEN
0.0
0.0
0.0
0.0
CO
0.0
0.0
0.0
0.0
CO2
0.0
0.0
0.0
0.0
METHANE
0.0
0.0
0.0
0.0
WATER
6661.0122 3608.0483 6661.0122 6661.0122
SULFUR
0.0
0.0
0.0
0.0
MEA
0.0
0.0
0.0
0.0
ARGON
0.0
0.0
0.0
0.0
NITRO-01
0.0
0.0
0.0
0.0
NITRO-02
0.0
0.0
0.0
0.0
HYDROGEN
0.0
0.0
0.0
0.0
C
0.0
0.0
0.0
0.0
OXYGEN
0.0
0.0
0.0
0.0
NITROGEN
0.0
0.0
0.0
0.0
CO
0.0
0.0
0.0
0.0
CO2
0.0
0.0
0.0
0.0
METHANE
0.0
0.0
0.0
0.0
WATER
1.0000
1.0000
1.0000
1.0000
SULFUR
0.0
0.0
0.0
0.0
MEA
0.0
0.0
0.0
0.0
ARGON
0.0
0.0
0.0
0.0
NITRO-01
0.0
0.0
0.0
0.0
NITRO-02
0.0
0.0
0.0
0.0
TOTAL FLOW:
LBMOL/HR
6661.0122 3608.0483 6661.0122 6661.0122
LB/HR
1.2000+05 6.5000+04 1.2000+05 1.2000+05
CUFT/HR
2814.2974 1044.1572 2.9743+04 7.0787+04
STATE VARIABLES:
STREAM ID
FROM :
TO
:
CLASS:
5 6 7 8 ELMTCOMP
----------------
SFRAC
ENTHALPY:
BTU/LBMOL
BTU/LB
BTU/HR
ENTROPY:
BTU/LBMOL-R
BTU/LB-R
DENSITY:
LBMOL/CUFT
LB/CUFT
AVG MW
77.0000
14.6959
0.0
1.0000
0.0
620.6935
1799.0432
1.0000
0.0
0.0
1400.0000
1797.9167
1.0000
0.0
0.0
2.3668
42.6394
18.0153
-25.9491
-1.4404
STREAM ID
MOISTR15
FROM :
---TO
:
DECOMP
CLASS:
MIXNC
TOTAL STREAM:
LB/HR
3.1315+04
BTU/HR
-2.1115+08
SUBSTREAM: MIXED
PHASE:
LIQUID
HYDROGEN
0.0
C
0.0
OXYGEN
0.0
NITROGEN
0.0
CO
0.0
CO2
0.0
METHANE
0.0
WATER
1738.2466
SULFUR
0.0
MEA
0.0
ARGON
0.0
NITRO-01
0.0
NITRO-02
0.0
HYDROGEN
0.0
C
0.0
OXYGEN
0.0
NITROGEN
0.0
CO
0.0
CO2
0.0
METHANE
0.0
WATER
1.0000
SULFUR
0.0
MEA
0.0
ARGON
0.0
NITRO-01
0.0
NITRO-02
0.0
TOTAL FLOW:
LBMOL/HR
1738.2466
LB/HR
3.1315+04
RAWGAS
GASIFR2
B4
MIXNC
0.2240
4.0345
18.0153
-15.6401
-0.8682
STEAM
---GASIFR2
MIXNC
9.4099-02
1.6952
18.0153
-9.5582
-0.5306
WOODCHIP
---DECOMP
MIXNC
3.6838-02
0.4391
11.9196
38.0323
3.1907
1.2613+05
1.0581+04
2.5404+09
1700.0000
464.6959
0.5408
0.4592
0.0
VAPOR
1.0001+04
9.6868-22
1.4289-13
25.0090
4639.0385
4159.8043
430.7250
0.0
0.0
0.0
70.2260
3.7739-19
1.3888-14
0.5175
5.0123-26
7.3935-18
1.2941-03
0.2400
0.2152
2.2287-02
0.0
0.0
0.0
3.6338-03
1.9527-23
7.1859-19
1.9326+04
3.4359+05
VAPOR
0.0
0.0
1667.8685
17.5565
0.0
0.0
0.0
0.0
0.0
0.0
70.2260
0.0
0.0
0.0
0.0
0.9500
1.0000-02
0.0
0.0
0.0
0.0
0.0
0.0
4.0000-02
0.0
0.0
1755.6511
5.6667+04
2600.0000
4.6840+04
0.0
0.0
0.0
0.0
0.0
0.0
0.0
1.0000
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
2600.0000
0.0
0.0
0.0
0.0
0.0
LIQUID
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
MISSING
5.6667+04 3.4359+05 4.6840+04 2.0877+05

1.1317+06 -6.7548+08 -2.9454+08 -6.3776+08
O2
---GASIFR2
MIXNC
3.4555
62.2512
18.0153
-38.9657
-2.1629
-1.1261+05 -1.2288+05 -1.0140+05 -9.2775+04

-6250.8796 -6820.9686 -5628.6397 -5149.8218
-7.5011+08 -4.4336+08 -6.7544+08 -6.1798+08
600.0000
1799.6950
0.0
1.0000
0.0
MOISTR15 O2 RAWGAS STEAM WOODCHIP

---------------------------------
TEMP
F
PRES
PSIA
VFRAC
LFRAC
SFRAC
ENTHALPY:
BTU/LBMOL
BTU/LB
BTU/HR
ENTROPY:
BTU/LBMOL-R
BTU/LB-R
DENSITY:
LBMOL/CUFT
LB/CUFT
AVG MW
180.0000
450.0000
1.0000
0.0
0.0
154.4000
464.6959
0.0
1.0000
0.0
1700.0000
464.6959
1.0000
0.0
0.0
9.6997+05
572.0000
1250.0000
0.0
1.0000
0.0
1053.3732
6.6100-02
2.1335
32.2769
3.3968
61.1935
18.0153
1.9924-02
0.3542
17.7787
11.5752
0.6511
MISSING
MISSING
MISSING
1.0000
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
1.0000
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
1.0000
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
0.0
0.0
MISSING
450.0000
MISSING
MISSING
MISSING
0.0
MISSING
464.6959
MISSING
MISSING
MISSING
0.0
0.0
0.0
0.0
0.0
0.0
STRUCTURE: NON CONVENTIONAL
-5.2245
-0.1619
-36.5548
-2.0291
154.4000
464.6959
0.0
0.0
1.0000
2.0877+05
1.0000
2.0877+05
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
464.6959
MISSING
MISSING
MISSING
0.0
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
1.0000
0.0
0.0
2.0000-02
0.5000
49.5400
6.1100
0.1000
0.0
2.0000-02
43.7300
15.0000
17.7000
81.5000
0.8000
78.9298
1.0000
MISSING -3054.8643
MISSING -6.3776+08
MISSING
1250.0000
MISSING
MISSING
MISSING
0.0
0.0
0.0
2.4683
44.4664
18.0153
-26.5519
-1.4739
644.6150 -3.4952+04 -1.1328+05

19.9714 -1965.9464 -6288.2166
1.1317+06 -6.7548+08 -2.9454+08
2.6560+04
511.7375
-1.2147+05
-6742.6966
-2.1115+08
SUBSTREAM: NC
COMPONENTS: LB/HR
WOODCHIP
COMPONENTS: MASS FRAC
WOODCHIP
TOTAL FLOW:
LB/HR
STATE VARIABLES:
TEMP
F
PRES
PSIA
VFRAC
LFRAC
SFRAC
ENTHALPY:
BTU/LB
BTU/HR
DENSITY:
LB/CUFT
AVG MW
COMPONENT ATTRIBUTES:
WOODCHIP PROXANAL
MOISTURE
FC
VM
ASH
ULTANAL
ASH
CARBON
HYDROGEN
NITROGEN
CHLORINE
SULFUR
OXYGEN
SULFANAL
PYRITIC
SULFATE
ORGANIC
CUFT/HR
STATE VARIABLES:
TEMP
F
PRES
PSIA
VFRAC
LFRAC
SFRAC
ENTHALPY:
BTU/LBMOL
BTU/LB
BTU/HR
ENTROPY:
BTU/LBMOL-R
BTU/LB-R
DENSITY:
LBMOL/CUFT
LB/CUFT
AVG MW
***
PSIA
INPUT DATA
***
45844.4
0.147653E+07
-0.645130E+10
PSI
RESULTS
***
215.019
2
30
0.000100000
85.0000
NO
-0.983193E-04
0.00000
-0.270322E-06
RELATIVE DIFF.
TOTAL BALANCE
MOLE(LBMOL/HR)
***
45600.5
***
OUT
45597.7

IN
0.600846E-04
RELATIVE DIFF.
***********************************************************************
*
*
*
AT LEAST ONE OF THE INLET OR OUTLET STREAMS
*
*
IS NOT IN CHARGE BALANCE
*
*
*
***********************************************************************
BLOCK: D11
MODEL: MIXER
----------------------------INLET STREAMS:
V302BOTT
S313
OUTLET STREAM:
S316R
HENRY-COMPS ID:
GLOBAL
CHEMISTRY ID:
GLOBAL
- TRUE SPECIES
VALVE PRESSURE DROP
***
***
OUT
45849.0
0.147653E+07
-0.645130E+10

IN
NPHASE

TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
***
***********************************************************************
*
*
*
*
*
*
*
*
***********************************************************************
BLOCK: B1
MODEL: VALVE
----------------------------INLET STREAM:
S309
OUTLET STREAM:
S310
HENRY-COMPS ID:
GLOBAL
CHEMISTRY ID:
GLOBAL
- TRUE SPECIES
0.133065E+07
-0.574901E+10
0.00000
-0.347965E-07
)
***



TWO
PHASE
FLASH
INPUT DATA
***
259039.
0.517563E+07
-0.319403E+11
***
OUT
0.864426E-06
0.719775E-15
0.184486E-08
RELATIVE DIFF.
ASPEN PLUS
ASPEN PLUS
HX1.EDR
DESIGN
30
0.000100000
30
0.000100000
259039.
0.517563E+07
-0.319403E+11

IN

TWO
PHASE
FLASH
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
***
***********************************************************************
*
*
*
*
*
*
***********************************************************************
BLOCK: H301
MODEL: HEATX
HOT SIDE:
S319
OUTLET STREAM:
S302
HENRY-COMPS ID:
GLOBAL
CHEMISTRY ID:
GLOBAL
- TRUE SPECIES
COLD SIDE:
CW301
OUTLET STREAM:
CW302
HENRY-COMPS ID:
GLOBAL
CHEMISTRY ID:
GLOBAL
- TRUE SPECIES
30
0.000100000
0.133065E+07
-0.574901E+10
*** INPUT DATA ***

TWO
PHASE
FLASH
OUTLET PRESSURE: MINIMUM OF INLET STREAM PRESSURES
MASS(LB/HR
)
ENTHALPY(BTU/HR
OVERALL RESULTS
***
PSI
F
PSI
BTU/HR-SQFT-R
BTU/HR-SQFT-R
HR-SQFT-R/BTU
HR-SQFT-R/BTU
TUBESIDE RESULTS:
CLEAN PRESSURE DROP
THERMAL RESISTANCE
F
PSI
PSI
PSI
PSI
BTU/HR-SQFT-R
BTU/HR-SQFT-R
HR-SQFT-R/BTU
HR-SQFT-R/BTU
HR-SQFT-R/BTU
FT/SEC
FT/SEC
FT/SEC
LB/FT-SQSEC
LB/FT-SQSEC
LB/FT-SQSEC
LB/FT-SQSEC
BTU/HR-SQFT-R
BTU/HR-SQFT-R
BTU/HR-R
F
BTU/HR
SQFT
SQFT
SHELLSIDE RESULTS:
CLEAN PRESSURE DROP
THERMAL RESISTANCE
FOULING RESISTANCE
CROSSFLOW VELOCITY
WINDOW VELOCITY
MIDPOINT VELOCITY
SHELL EXIT RHOV^2
BUNDLE EXIT RHOV^2
UNIT RESULTS:
UA (DIRTY)
LMTD (CORRECTED)
CW301
T= 9.0000D+01
P= 6.4696D+01
V= 0.0000D+00
S302
T= 1.0000D+02
P= 2.9759D+02
V= 0.0000D+00
107.4238
2.4085
289.5264
289.5264
0.0035
0.000296
101.6708
7.2100
1.2927
1.2927
3.5226
1648.3326
1648.3326
0.0006
0.000296
0.0000
4.0927
4.3961
4.2444
669.9623
1061.9341
496.4650
817.6883
0.0000
14.0250
7.2084
115032034.8412
14643.1573
16647.9113
13.6907
13.6907
231.1787
231.1787
3385185.4462
33.9810
0.8934
1
2
-------------------------------------|
|
S319
----->|
HOT (TUBE)
|----->
T= 2.1604D+02 |
|
P= 3.0000D+02 |
|
V= 0.0000D+00 |
|
|
|
CW302
<-----|
COLD (SHELL)
|<----T= 1.2000D+02 |
|
P= 5.7486D+01 |
|
V= 0.0000D+00 |
|
--------------------------------------
STREAMS:
***
PSI
HR-SQFT-R/BTU
FT/SEC
FT/SEC
FT/SEC
0.0000
2.5589
2.4162
2.4162
0.0000
79.8472
2.4129

ASPEN PLUS
ASPEN PLUS
D5.EDR
DESIGN

***
-0.581095E-02
-0.169144E-15
0.719852E-10
100
0.000100000
INPUT DATA
89040.8
0.275305E+07
-0.117674E+11
RELATIVE DIFF.

TWO
PHASE
FLASH
***
88523.4
0.275305E+07
-0.117674E+11
***
OUT
100
0.000100000

IN

TWO
PHASE
FLASH
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
***
***********************************************************************
*
*
*
*
*
*
***********************************************************************
BLOCK: H303
MODEL: HEATX
HOT SIDE:
S312
OUTLET STREAM:
S313
HENRY-COMPS ID:
GLOBAL
CHEMISTRY ID:
GLOBAL
- TRUE SPECIES
COLD SIDE:
S310
OUTLET STREAM:
S311
HENRY-COMPS ID:
GLOBAL
CHEMISTRY ID:
GLOBAL
- TRUE SPECIES
FOULING RESISTANCE
INPUT VELOCITY
OUTLET VELOCITY
MIDPOINT VELOCITY
OVERALL RESULTS
***
PSI
F
PSI
BTU/HR-SQFT-R
BTU/HR-SQFT-R
HR-SQFT-R/BTU
HR-SQFT-R/BTU
HR-SQFT-R/BTU
TUBESIDE RESULTS:
CLEAN PRESSURE DROP
THERMAL RESISTANCE
FOULING RESISTANCE
F
PSI
PSI
PSI
PSI
BTU/HR-SQFT-R
BTU/HR-SQFT-R
HR-SQFT-R/BTU
HR-SQFT-R/BTU
HR-SQFT-R/BTU
FT/SEC
FT/SEC
FT/SEC
LB/FT-SQSEC
LB/FT-SQSEC
LB/FT-SQSEC
LB/FT-SQSEC
BTU/HR-SQFT-R
BTU/HR-SQFT-R
BTU/HR-R
F
BTU/HR
SQFT
SQFT
SHELLSIDE RESULTS:
CLEAN PRESSURE DROP
THERMAL RESISTANCE
FOULING RESISTANCE
CROSSFLOW VELOCITY
WINDOW VELOCITY
MIDPOINT VELOCITY
SHELL EXIT RHOV^2
BUNDLE EXIT RHOV^2
UNIT RESULTS:
UA (DIRTY)
LMTD (CORRECTED)
S310
T= 1.9375D+02
P= 8.5000D+01
V= 1.9774D-04
S313
T= 2.1875D+02
P= 3.9737D+01
V= 0.0000D+00
231.2350
3.3110
624.1956
624.1956
0.0016
0.000233
0.0000
218.4112
4.7800
0.6534
0.6534
1.9915
744.1126
744.1126
0.0013
0.000233
0.0000
4.8155
8.2684
6.5419
290.5490
1299.6994
321.4764
1819.3725
0.0000
41.7648
4.7558
71766598.5255
8101.8349
9273.9737
14.4676
14.4676
310.7768
310.7768
2517862.3678
28.5030
0.8063
1
2
-------------------------------------|
|
S312
----->|
HOT (TUBE)
|----->
T= 2.9036D+02 |
|
P= 4.3048D+01 |
|
V= 0.0000D+00 |
|
|
|
S311
<-----|
COLD (SHELL)
|<----T= 2.4266D+02 |
|
P= 8.0220D+01 |
|
V= 1.2309D-02 |
|
--------------------------------------
STREAMS:
***
PSI
FT/SEC
FT/SEC
FT/SEC
4.0526
3.8670
3.8670
0.0000
49.7884
3.3200
***
***
0.253012E-04
0.00000
-0.445723E-06
***
OVERALL RESULTS


ASPEN PLUS
ASPEN PLUS
HX2.EDR
DESIGN
100
0.000100000
INPUT DATA
44328.0
706792.
-0.382347E+10
RELATIVE DIFF.

TWO
PHASE
FLASH
***
44329.1
706792.
-0.382348E+10
***
OUT
100
0.000100000

IN

TWO
PHASE
FLASH
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
***
***********************************************************************
*
*
*
*
*
*
***********************************************************************
BLOCK: H302
MODEL: HEATX
HOT SIDE:
S305
OUTLET STREAM:
S306
HENRY-COMPS ID:
GLOBAL
CHEMISTRY ID:
GLOBAL
- TRUE SPECIES
COLD SIDE:
CW303
OUTLET STREAM:
CW304
HENRY-COMPS ID:
GLOBAL
CHEMISTRY ID:
GLOBAL
- TRUE SPECIES
INPUT VELOCITY
OUTLET VELOCITY
MIDPOINT VELOCITY
PSI
F
PSI
BTU/HR-SQFT-R
BTU/HR-SQFT-R
HR-SQFT-R/BTU
HR-SQFT-R/BTU
HR-SQFT-R/BTU
FT/SEC
TUBESIDE RESULTS:
CLEAN PRESSURE DROP
THERMAL RESISTANCE
FOULING RESISTANCE
INPUT VELOCITY
F
PSI
PSI
PSI
PSI
BTU/HR-SQFT-R
BTU/HR-SQFT-R
HR-SQFT-R/BTU
HR-SQFT-R/BTU
HR-SQFT-R/BTU
FT/SEC
FT/SEC
FT/SEC
LB/FT-SQSEC
LB/FT-SQSEC
LB/FT-SQSEC
LB/FT-SQSEC
BTU/HR-SQFT-R
BTU/HR-SQFT-R
BTU/HR-R
F
BTU/HR
SQFT
SQFT
SHELLSIDE RESULTS:
CLEAN PRESSURE DROP
THERMAL RESISTANCE
FOULING RESISTANCE
CROSSFLOW VELOCITY
WINDOW VELOCITY
MIDPOINT VELOCITY
SHELL EXIT RHOV^2
BUNDLE EXIT RHOV^2
UNIT RESULTS:
UA (DIRTY)
LMTD (CORRECTED)
CW303
T= 9.0000D+01
P= 6.4696D+01
V= 0.0000D+00
S306
T= 1.2500D+02
P= 2.9676D+02
V= 9.7678D-01
117.1942
3.2370
359.3488
359.3488
0.0028
0.000091
0.0000
93.0952
104.8401
1.7896
0.1501
0.1501
0.4615
1378.4096
1378.4096
0.0007
0.000091
0.0000
2.5680
2.7914
2.6797
455.6397
2072.9655
608.6563
682.6552
0.0000
19.2241
1.7897
16485178.8133
1143.5433
1198.7641
4.8289
4.8289
264.9873
264.9873
303024.4753
54.4021
0.9936
1
2
-------------------------------------|
|
S305
----->|
HOT (TUBE)
|----->
T= 2.0409D+02 |
|
P= 3.0000D+02 |
|
V= 1.0000D+00 |
|
|
|
CW304
<-----|
COLD (SHELL)
|<----T= 1.2305D+02 |
|
P= 6.2906D+01 |
|
V= 0.0000D+00 |
|
--------------------------------------
STREAMS:
PSI
FT/SEC
FT/SEC
81.0085
81.0085
0.0000
73.7410
3.3911
***
***
OVERALL RESULTS


***
ASPEN PLUS
ASPEN PLUS
1HX2.EDR
DESIGN
100
0.000100000
INPUT DATA
0.117829E-03
0.00000
0.396647E-08
RELATIVE DIFF.

TWO
PHASE
FLASH
***
120124.
0.225000E+07
-0.148291E+11
***
OUT
100
0.000100000
120138.
0.225000E+07
-0.148291E+11

IN

TWO
PHASE
FLASH
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
***
***********************************************************************
*
*
*
*
*
*
***********************************************************************
BLOCK: H304
MODEL: HEATX
HOT SIDE:
S314
OUTLET STREAM:
S315
HENRY-COMPS ID:
GLOBAL
CHEMISTRY ID:
GLOBAL
- TRUE SPECIES
COLD SIDE:
CW305
OUTLET STREAM:
CW306
HENRY-COMPS ID:
GLOBAL
CHEMISTRY ID:
GLOBAL
- TRUE SPECIES
OUTLET VELOCITY
MIDPOINT VELOCITY
PSI
F
PSI
BTU/HR-SQFT-R
BTU/HR-SQFT-R
HR-SQFT-R/BTU
HR-SQFT-R/BTU
HR-SQFT-R/BTU
FT/SEC
FT/SEC
TUBESIDE RESULTS:
CLEAN PRESSURE DROP
THERMAL RESISTANCE
FOULING RESISTANCE
INPUT VELOCITY
OUTLET VELOCITY
F
PSI
PSI
PSI
PSI
BTU/HR-SQFT-R
BTU/HR-SQFT-R
HR-SQFT-R/BTU
HR-SQFT-R/BTU
HR-SQFT-R/BTU
FT/SEC
FT/SEC
FT/SEC
LB/FT-SQSEC
LB/FT-SQSEC
LB/FT-SQSEC
LB/FT-SQSEC
BTU/HR-SQFT-R
BTU/HR-SQFT-R
BTU/HR-R
F
BTU/HR
SQFT
SQFT
SHELLSIDE RESULTS:
CLEAN PRESSURE DROP
THERMAL RESISTANCE
FOULING RESISTANCE
CROSSFLOW VELOCITY
WINDOW VELOCITY
MIDPOINT VELOCITY
SHELL EXIT RHOV^2
BUNDLE EXIT RHOV^2
UNIT RESULTS:
UA (DIRTY)
LMTD (CORRECTED)
CW305
T= 9.0000D+01
P= 6.4696D+01
V= 0.0000D+00
S315
T= 1.2000D+02
P= 3.9266D+01
V= 5.3717D-01
113.2402
3.7338
307.6877
307.6877
0.0033
0.000278
0.0000
153.4790
73.8826
100.1021
5.9337
1.1027
1.1027
2.9673
2032.5893
2032.5893
0.0005
0.000278
0.0000
5.4617
5.6553
5.5585
726.4897
1964.2834
665.7788
1528.4605
0.0000
12.2726
5.9308
62016808.1010
2925.0419
3331.0671
13.8810
13.8810
249.4518
249.4518
729656.8613
84.9945
1.2536
1
2
-------------------------------------|
|
S314
----->|
HOT (TUBE)
|----->
T= 2.4942D+02 |
|
P= 4.3000D+01 |
|
V= 1.0000D+00 |
|
|
|
CW306
<-----|
COLD (SHELL)
|<----T= 1.2034D+02 |
|
P= 5.8762D+01 |
|
V= 0.0000D+00 |
|
--------------------------------------
STREAMS:
PSI
FT/SEC
73.8826
0.0000
81.0730
4.3309
)
***
BLOCK: T301
MODEL: RADFRAC
------------------------------INLETS
- S304
STAGE
1
S307
STAGE
1
S302
STAGE
1
S214
STAGE
4
OUTLETS - S305
STAGE
1
S309
STAGE
4
ELECNRTL
HENRY-COMPS ID:
GLOBAL
-0.209338E-06
0.174727E-15
-0.229649E-03
RELATIVE DIFF.
23,259.3
257.000
79.1474
434.737
519.857
387.658
0.83626
519.857
645.968
30
0.000100000
300.000
1.00000
45715.6
0.133254E+07
-0.576026E+10
***
OUT
*** RESULTS
PRESSURE CHANGE PSI
NPSH AVAILABLE
FT-LBF/LB
FLUID POWER HP
BRAKE POWER HP
ELECTRICITY KW
***
***
INPUT DATA
45715.6
0.133254E+07
-0.576159E+10

IN
NO FLASH PERFORMED
TOLERANCE

DRIVER EFFICIENCY
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
***
***********************************************************************
*
*
*
*
*
*
*
*
***********************************************************************
BLOCK: P301
MODEL: PUMP
---------------------------INLET STREAM:
S316
OUTLET STREAM:
S319
HENRY-COMPS ID:
GLOBAL
CHEMISTRY ID:
GLOBAL
- TRUE SPECIES
MIDPOINT VELOCITY
GLOBAL
- TRUE SPECIES
****
**********************
**** INPUT DATA ****
**********************
INPUT PARAMETERS
65575.0
62419.3
0.168332E+07 0.168332E+07
-0.686866E+10 -0.686866E+10

IN
OUT
COL-SPECS
****
BTU/HR
BTU/HR
TO
1
2
3
4
EQUILIBRIUM
EQUILIBRIUM
EQUILIBRIUM
EQUILIBRIUM
LIQUID
LIQUID
LIQUID
LIQUID
PHASE
****
CONC.
TEMP APP TO EQUIL
BASIS
F
MOLE-GAMMA
0.0000
MOLE-GAMMA
0.0000
MOLE-GAMMA
0.0000
MOLE-GAMMA
0.0000
REACTION PARAMETERS
*****
-0.359118E-10
-0.983845E-12
0.475961E-07
RELATIVE DIFF.
CONVERSION
1.00000
0.0
0.0
4
NONIDEAL
STANDARD
NO
NEWTON
NESTED
50
10
30
0.000100000
0.000100000
-3155.66
***
GENERATION
REACTIONS/CHEMISTRY ID
GLOBAL
CHEMISTRY PARAGRAPH GLOBAL
STAGE
4
RXN NO. TYPE
****
*****
STAGE
1
**** REAC-STAGES SPECIFICATIONS ****
MOLAR VAPOR DIST / TOTAL DIST

CONDENSER DUTY (W/O SUBCOOL)
REBOILER DUTY
****
NUMBER OF STAGES
ALGORITHM OPTION
INITIALIZATION OPTION
HYDRAULIC PARAMETER CALCULATIONS
INSIDE LOOP CONVERGENCE METHOD
DESIGN SPECIFICATION METHOD
MAXIMUM NO. OF OUTSIDE LOOP ITERATIONS
MAXIMUM NO. OF INSIDE LOOP ITERATIONS
MAXIMUM NUMBER OF FLASH ITERATIONS
FLASH TOLERANCE
OUTSIDE LOOP CONVERGENCE TOLERANCE
****
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
***
***********************************************************************
*
*
*
FEED PRESSURE IS LOWER THAN STAGE PRESSURE.
*
*
*
***********************************************************************
CHEMISTRY ID:
***
STAGE
MEACOO0.000
0.000
0.000
-1.000
CO2
-1.000
0.000
0.000
0.000
PRES, PSIA
***
***
.17443E-03
.10774E-03
.10912
.99864
.98610
1.0000
1.0000
1.0000
1.0000
1.0000
.14384E-03
.17531E-03
OUTLET STREAMS
-------------S309
SUMMARY OF KEY RESULTS
.99983
.99989
.89088
.13586E-02
.13901E-01
0.0000
0.0000
0.0000
0.0000
0.0000
.99986
.99982
S305
C
-36.782
-35.482
0.0000
0.0000
*******************
**** RESULTS ****
*******************
****
B
-12092.
-12432.
-7008.4
-2545.5
COMPONENT SPLIT FRACTIONS
PROFILES
COMPONENT:
HYDROGEN
NITROGEN
CO2
MEA
WATER
MEA+
H3O+
MEACOOHCO3CO3-CO
METHANE
***
P-SPEC
****
METHANE
0.000
0.000
0.000
0.000
H3O+
1.000
1.000
1.000
0.000
NITROGEN
0.000
0.000
0.000
0.000
**
HCO31.000
-1.000
0.000
1.000
MEA
0.000
0.000
1.000
1.000
**
CO3-0.000
1.000
0.000
0.000
WATER
-2.000
-1.000
-1.000
-1.000
300.000
D
0.0000
0.0000
-0.31349E-02
0.0000
COEFFICIENTS OF EQUILIBRIUM CONSTANT EXPRESSION
CO
0.000
0.000
0.000
0.000
MEA+
0.000
0.000
-1.000
0.000
HYDROGEN
0.000
0.000
0.000
0.000
STOICHIOMETRIC COEFFICIENTS
RXN NO.
A
1
231.47
2
216.05
3
-3.0383
4
-0.52135
**
RXN NO.
1
2
3
4
RXN NO.
1
2
3
4
RXN NO.
1
2
3
4
**
PROFILES
****
STAGE=
STAGE=
STAGE=
4
1 COMP=CO3-1
204.093
193.628
46,471.7
45,844.4
16,574.9
19,663.4
0.0
0.0
HYDROGEN
0.48635E-04
0.40503E-04
0.39327E-04
0.38110E-04
MEA+
0.92311E-01
0.98499E-01
0.10019
STAGE
1
2
3
CO3-0.77091E-04
0.65722E-04
0.67927E-04
.14765+07
****
MOLE-X-PROFILE
****
H3O+
MEACOOHCO30.45143E-09
0.88634E-01
0.24671E-02
0.83031E-09
0.93518E-01
0.37953E-02
0.83365E-09
0.94926E-01
0.40679E-02
MIXED
PRODUCT RATE
LB/HR
LIQUID
VAPOR
.20679+06
.45844+05
WATER
0.77743
0.77450
0.77322
0.77044
.34110+06
FEED RATE
LB/HR
VAPOR
.19335+05
PRODUCT RATE
LBMOL/HR
LIQUID
VAPOR
.16575+05
HEAT DUTY
BTU/HR
****
MOLE-X-PROFILE
****
NITROGEN
CO2
MEA
0.10635E-06
0.59008E-03
0.38416E-01
0.87544E-07
0.24515E-02
0.27116E-01
0.85183E-07
0.25806E-02
0.24893E-01
0.83525E-07
0.22087E-02
0.18989E-01
LIQUID
.13422+07
****
MIXED
-25180.
-45568.
-47834.
-47812.
FEED RATE
LBMOL/HR
VAPOR
-0.13790E+06
-0.13906E+06
-0.13948E+06
-0.14072E+06
ENTHALPY
BTU/LBMOL
LIQUID
VAPOR
LIQUID
.46240+05
MASS FLOW PROFILES
STAGE
1
2
3
4
1
2
3
4
300.00
300.01
300.01
300.02
FLOW RATE
LB/HR
LIQUID
VAPOR
0.1463E+07 0.2068E+06
0.1479E+07 0.3280E+06
0.1479E+07 0.3440E+06
0.1477E+07 0.3434E+06
****
STAGE
1
2
3
4
204.09
213.12
209.57
193.63
PRESSURE
PSIA
FLOW RATE
LBMOL/HR
LIQUID
VAPOR
0.4647E+05 0.1657E+05
0.4652E+05 0.1945E+05
0.4633E+05 0.1979E+05
0.4584E+05 0.1966E+05
STAGE
1
2
3
4
STAGE TEMPERATURE
F
**NOTE** REPORTED VALUES FOR STAGE LIQUID AND VAPOR RATES ARE THE FLOWS
FROM THE STAGE INCLUDING ANY SIDE PRODUCT.
****
0.77471E-05
0.33721E-03
0.69591E-06
****
F
F
LBMOL/HR
LBMOL/HR
LBMOL/HR
LBMOL/HR
BTU/HR
BTU/HR
MAXIMUM FINAL RELATIVE ERRORS
BUBBLE POINT
COMPONENT MASS BALANCE
ENERGY BALANCE
****
TOP STAGE TEMPERATURE

BOTTOM STAGE TEMPERATURE
TOP STAGE LIQUID FLOW
BOTTOM STAGE LIQUID FLOW
TOP STAGE VAPOR FLOW
BOILUP VAPOR FLOW
REBOILER DUTY
STAGE
1
2
3
4
STAGE
1
2
3
4
STAGE
1
2
3
4
STAGE
1
2
3
4
STAGE
1
2
3
4
STAGE
1
2
3
4
STAGE
1
2
3
4
STAGE
1
2
3
4
HYDROGEN
0.000
0.000
0.000
0.000
CO
15162.
15764.
15899.
16209.
MEA+
0.0000
0.0000
0.0000
0.0000
HYDROGEN
12423.
12714.
12869.
13366.
CO
0.28623
0.24395
0.23975
0.24131
0.98617E-01
****
0.48805E-02
****
RATES OF GENERATION
****
WATER
-92.83
-61.38
-12.00
-35.82
****
****
****
HCO30.0000
0.0000
0.0000
0.0000
****
MEA
0.18600E-02
0.24873E-02
0.22676E-02
0.14423E-02
****
RATES OF GENERATION
LBMOL/HR
NITROGEN
CO2
MEA
0.000
-2644.
-5182.
0.000
-292.8
-523.7
0.000
-59.71
-107.5
0.000
-158.8
-282.2
****
K-VALUES
METHANE
12534.
13187.
13256.
13299.
****
K-VALUES
H3O+
MEACOO0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
****
K-VALUES
NITROGEN
CO2
20161.
84.523
20873.
73.367
21082.
75.924
21640.
90.788
****
MOLE-Y-PROFILE
METHANE
0.27429E-01
0.23378E-01
0.22975E-01
0.23124E-01
****
MOLE-Y-PROFILE
****
H3O+
MEACOOHCO30.12810-117
0.25151-109
0.70008-111
0.24358-117
0.27435-109
0.11134-110
0.24579-117
0.27988-109
0.11994-110
0.21787-117
0.29252-109
0.14477-110
****
MOLE-Y-PROFILE
****
NITROGEN
CO2
MEA
0.21441E-02
0.49876E-01
0.71455E-04
0.18273E-02
0.17986
0.67446E-04
0.17958E-02
0.19593
0.56447E-04
0.18075E-02
0.20053
0.27387E-04
****
MOLE-X-PROFILE
METHANE
0.21882E-05
0.17728E-05
0.17332E-05
0.17388E-05
0.73451E-09
****
MEA+
0.26195-109
0.28896-109
0.29539-109
0.31065-109
HYDROGEN
0.60420
0.51498
0.50610
0.50939
CO
0.18878E-04
0.15475E-04
0.15080E-04
0.14887E-04
0.10473
MEA+
2630.
292.3
59.80
159.3
CO3-0.0000
0.0000
0.0000
0.0000
WATER
0.38641E-01
0.46402E-01
0.43174E-01
0.30905E-01
CO3-0.21876-112
0.19280-112
0.20027-112
0.23885-112
WATER
0.30041E-01
0.35938E-01
0.33383E-01
0.23811E-01
0.80522E-04
MEA+
0.18201
0.19231
0.19490
0.20190
CO
0.16791E-04
0.13630E-04
0.13234E-04
0.12947E-04
HYDROGEN
0.97626E-01
0.61557E-01
0.58694E-01
0.58801E-01
MEA+
0.13037-108
0.10639-108
0.10552-108
0.11045-108
CO
0.64263
0.40518
0.38634
0.38705
STAGE
1
2
3
4
STAGE
1
2
3
4
STAGE
1
2
3
4
STAGE
1
2
3
4
STAGE
1
2
3
4
****
CO3-0.10522-111
0.68606-112
0.69141-112
0.82076-112
****
MASS-Y-PROFILE
****
H3O+
0.20983-108
0.34239-110
0.27475-117
0.16932-108
0.40284-110
0.26898-117
0.16759-108
0.42101-110
0.23733-117
0.17435-108
0.50582-110
****
MASS-Y-PROFILE
METHANE
0.35270E-01
0.22239E-01
0.21204E-01
0.21243E-01
WATER
0.43378E-01
0.38390E-01
0.34598E-01
0.24563E-01
****
MEA
0.34984E-03
0.24429E-03
0.19836E-03
0.95796E-04
****
****
MASS-X-PROFILE
METHANE
0.11148E-05
0.89428E-06
0.87116E-06
0.86609E-06
****
MASS-Y-PROFILE
NITROGEN
CO2
0.48142E-02
0.17594
0.30353E-02
0.46935
0.28941E-02
0.49607
0.28995E-02
0.50535
CO3-0.14691E-03
0.12401E-03
0.12771E-03
0.15003E-03
****
HCO30.47802E-02
0.72818E-02
0.77765E-02
0.92463E-02
METHANE
0.000
0.000
0.000
0.000
****
MASS-X-PROFILE
H3O+
MEACOO0.27269E-09
0.29296
0.49664E-09
0.30607
0.49684E-09
0.30956
0.43383E-09
0.31870
CO
0.000
0.000
0.000
0.000
WATER
0.44475
0.43873
0.43642
0.43095
CO3--13.92
-.5252
0.8984E-01
0.5443
****
MASS-X-PROFILE
****
NITROGEN
CO2
MEA
0.94604E-07
0.82464E-03
0.74516E-01
0.77113E-07
0.33924E-02
0.52081E-01
0.74762E-07
0.35583E-02
0.47639E-01
0.72649E-07
0.30181E-02
0.36014E-01
LBMOL/HR
MEACOOHCO32552.
106.8
231.4
61.91
47.71
11.91
122.9
35.27
MARANGONI INDEX = SIGMA - SIGMATO
*** DEFINITIONS ***
********************************
***** HYDRAULIC PARAMETERS *****
********************************
HYDROGEN
0.31133E-05
0.25674E-05
0.24838E-05
0.23853E-05
H3O+
0.2001E-04
0.1765E-04
-.1114E-08
-.4951E-05
STAGE
1
2
3
4
STAGE
1
2
3
4
-.48591
0.46577
1.9367
FLOW PARAM
0.50027
0.49291
0.50050
0.54534
STARTING STAGE NUMBER
VAPOR TO
16.865
17.383
17.463
17.642
WEIGHT
QR
CUFT/HR
52880.
54690.
53795.
49063.
REDUCED F-FACTOR
(LB-CUFT)**.5/HR
0.39207E+06
0.40381E+06
0.39733E+06
0.36302E+06
VISCOSITY
SURFACE TENSION
CP
DYNE/CM
LIQUID FROM VAPOR TO
LIQUID FROM
1.1967
0.18423E-01
63.682
1.2001
0.18382E-01
63.196
1.2792
0.18041E-01
63.662
1.6344
0.15943E-01
65.599
***************************************
***** PACKING SIZING CALCULATIONS *****
***************************************
MARANGONI INDEX
DYNE/CM
*******************
*** SECTION
1 ***
*******************
STAGE
1
2
3
4
DENSITY
LB/CUFT
STAGE LIQUID FROM VAPOR TO
1
55.672
0.70003
2
55.245
0.72579
3
55.299
0.74693
4
55.627
0.88291
MASS FLOW
VOLUME FLOW
MOLECULAR
LB/HR
CUFT/HR
LIQUID FROM
1 0.14635E+07 0.32803E+06 26287.
0.46860E+06 31.491
2 0.14794E+07 0.34402E+06 26780.
0.47400E+06 31.803
3 0.14788E+07 0.34339E+06 26742.
0.45973E+06 31.918
4 0.14765E+07 0.34110E+06 26543.
0.38634E+06 32.207
STAGE
1
2
3
4
TEMPERATURE
F
LIQUID FROM
VAPOR TO
204.09
213.12
213.12
209.57
209.57
193.63
193.63
100.00
FLOW PARAM = (ML/MV)*SQRT(RHOV/RHOL)

QR = QV*SQRT(RHOV/(RHOL-RHOV))
F FACTOR = QV*SQRT(RHOV)
WHERE:
SIGMA IS THE SURFACE TENSION OF LIQUID FROM THE STAGE
SIGMATO IS THE SURFACE TENSION OF LIQUID TO THE STAGE
ML IS THE MASS FLOW OF LIQUID FROM THE STAGE
MV IS THE MASS FLOW OF VAPOR TO THE STAGE
RHOL IS THE MASS DENSITY OF LIQUID FROM THE STAGE
RHOV IS THE MASS DENSITY OF VAPOR TO THE STAGE
QV IS THE VOLUMETRIC FLOW RATE OF VAPOR TO THE STAGE
HEIGHT
FROM TOP
OF SECTION
FT
0.000
3.750
7.500
11.25
LIQUID
SUPERFICIAL
STAGE VELOCITY
FT/SEC
1
0.3674E-01
1
2
3
4
FT/SEC
PSI
IN-WATER/FT
CUFT
FT/SEC
FT
0.6026
0.6200
0.6152
0.5871
FRACTIONAL
CAPACITY
PRESSURE
DROP
PSI
0.62279E-02
0.65616E-02
0.63912E-02
0.54680E-02
PRESSURE
DROP/HEIGHT
IN-WATER/FT
0.45970E-01
0.48433E-01
0.47175E-01
0.40361E-01
LIQUID
HOLDUP
CUFT
135.5
137.0
139.1
147.1
HETP
FT
3.750
3.750
3.750
3.750
15.9069
0.62000
0.076444
0.024649
0.045485
147.106
0.037432
BX
STANDARD
STANDARD
SULZER
22.1592
149.963
0.90000
1.00386
-0.11281
0.35400
3.75000
15.0000
MISSING
**** RATING PROFILES AT MAXIMUM COLUMN DIAMETER ****
COLUMN DIAMETER
MAXIMUM FRACTIONAL CAPACITY
MAXIMUM CAPACITY FACTOR
PRESSURE DROP FOR THE SECTION
AVERAGE PRESSURE DROP/HEIGHT
MAXIMUM LIQUID HOLDUP/STAGE
MAX LIQ SUPERFICIAL VELOCITY
STAGE
FT
FT
FT
1/FT
SQFT/CUF
***** SIZING RESULTS *****
PACKING SPECIFICATIONS
---------------------PACKING TYPE
PACKING MATERIAL
PACKING SIZE
VENDOR
PACKING FACTOR
PACKING SURFACE AREA
PACKING VOID FRACTION
FIRST STICHLMAIR CONSTANT
SECOND STICHLMAIR CONSTANT
THIRD STICHLMAIR CONSTANT
HETP
PACKING HEIGHT
PACKING SHEET THICKNESS
1.00000
0.70000
0.62000
MISSING
MISSING
MISSING
MISSING
DESIGN PARAMETERS
----------------OVERDESIGN FACTOR
SYSTEM FOAMING FACTOR
FRAC. APP. TO MAXIMUM CAPACITY
DESIGN CAPACITY FACTOR
PRESSURE DROP PER UNIT HEIGHT
FT/SEC
FT/SEC
PSI
IN-WATER/FT
4
SULZER
SULZER
STICHL
YES
ENDING STAGE NUMBER

CAPACITY CALCULATION METHOD
PRESSURE DROP CALCULATION METHOD
LIQUID HOLDUP CALCULATION METHOD
PRESSURE PROFILE UPDATED
T302
1
2
TOTAL AREA
SQFT
762.20
790.67
MODEL: RADFRAC
DIAMETER
FT
31.152
31.729
FT/SEC
FT
FT
FT
FT
FT
FT
FT
FT
FT
FT
ACTIVE AREA
SQFT
609.76
632.54
**** SIZING PROFILES ****
STAGE WITH MAXIMUM DIAMETER

COLUMN DIAMETER
DC AREA/COLUMN AREA
DOWNCOMER VELOCITY
FLOW PATH LENGTH
SIDE DOWNCOMER WIDTH
SIDE WEIR LENGTH
CENTER DOWNCOMER WIDTH
CENTER WEIR LENGTH
OFF-CENTER DOWNCOMER WIDTH
OFF-CENTER SHORT WEIR LENGTH
OFF-CENTER LONG WEIR LENGTH
TRAY CENTER TO OCDC CENTER
STAGE
FT
FLEXI
1
2.00000
SIDE DC AREA
SQFT
76.220
79.067
2
31.7287
0.10000
0.094083
21.7992
4.96477
23.0545
0.0
0.0
0.0
0.0
0.0
0.0
***** SIZING RESULTS @ STAGE WITH MAXIMUM DIAMETER *****
TRAY SPECIFICATIONS
------------------TRAY TYPE
NUMBER OF PASSES
TRAY SPACING
1.00000
0.70000
0.85000
1.00000
0.100000
DESIGN PARAMETERS
----------------PEAK CAPACITY FACTOR
FLOODING FACTOR
MINIMUM COLUMN DIAMETER
MINIMUM DC AREA/COLUMN AREA
FT
1
2
B960

ENDING STAGE NUMBER
FLOODING CALCULATION METHOD
*******************
*** SECTION
1 ***
*******************
************************************
***** TRAY SIZING CALCULATIONS *****
************************************
0.3743E-01
0.3738E-01
0.3710E-01
BLOCK:
2
3
4
****
**********************
**********************
46370.9
49020.3
0.147653E+07 0.147653E+07
-0.637953E+10 -0.618015E+10
INPUT PARAMETERS

IN
OUT
COL-SPECS
****
BTU/HR
LB/HR
TO
****
*****
STAGE
1
REACTION PARAMETERS
****
*****
0.182144E-06
-0.875974E-08
-0.312526E-01
RELATIVE DIFF.
1.00000
0.0
200,000.
8
NONIDEAL
STANDARD
NO
NEWTON
NESTED
25
10
30
0.000100000
0.000100000
2649.50
***
GENERATION
REACTIONS/CHEMISTRY ID
GLOBAL
CHEMISTRY PARAGRAPH GLOBAL
STAGE
8
**** REAC-STAGES SPECIFICATIONS ****

MASS DISTILLATE RATE
****
NUMBER OF STAGES
ALGORITHM OPTION
FLASH TOLERANCE
****
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
***
***********************************************************************
*
*
*
*
*
*
*
*
***********************************************************************
------------------------------INLETS
- S311
STAGE
1
OUTLETS - S314
STAGE
1
S312
STAGE
8
HENRY-COMPS ID:
GLOBAL
CHEMISTRY ID:
GLOBAL
- TRUE SPECIES
**
STAGE
MEACOO0.000
0.000
0.000
-1.000
CO2
-1.000
0.000
0.000
0.000
PRES, PSIA
1.0000
1.0000
.99856
.20906E-02
.86053E-01
0.0000
0.0000
0.0000
0.0000
S314
C
-36.782
-35.482
0.0000
0.0000
0.0000
0.0000
.14445E-02
.99791
.91395
1.0000
1.0000
1.0000
1.0000
OUTLET STREAMS
-------------S312
***
*******************
**** RESULTS ****
*******************
****
B
-12092.
-12432.
-7008.4
-2545.5
COMPONENT:
HYDROGEN
NITROGEN
CO2
MEA
WATER
MEA+
H3O+
MEACOOHCO3-
***
P-SPEC
PROFILES
RXN NO.
A
1
231.47
2
216.05
3
-3.0383
4
-0.52135
****
METHANE
0.000
0.000
0.000
0.000
H3O+
1.000
1.000
1.000
0.000
NITROGEN
0.000
0.000
0.000
0.000
**
HCO31.000
-1.000
0.000
1.000
MEA
0.000
0.000
1.000
1.000
CONC.
TEMP APP TO EQUIL
BASIS
F
MOLE-GAMMA
0.0000
MOLE-GAMMA
0.0000
MOLE-GAMMA
0.0000
MOLE-GAMMA
0.0000
**
CO3-0.000
1.000
0.000
0.000
WATER
-2.000
-1.000
-1.000
-1.000
CONVERSION
43.0000
D
0.0000
0.0000
-0.31349E-02
0.0000
COEFFICIENTS OF EQUILIBRIUM CONSTANT EXPRESSION
CO
0.000
0.000
0.000
0.000
RXN NO.
1
2
3
4
HYDROGEN
0.000
0.000
0.000
0.000
MEA+
0.000
0.000
-1.000
0.000
**
LIQUID
LIQUID
LIQUID
LIQUID
PHASE
STOICHIOMETRIC COEFFICIENTS
EQUILIBRIUM
EQUILIBRIUM
EQUILIBRIUM
EQUILIBRIUM
RXN NO.
1
2
3
4
RXN NO.
1
2
3
4
1
2
3
4
RXN NO. TYPE
PROFILES
****
0.62518E-05
0.63264E-04
0.16856E-05
****
STAGE=
STAGE=
STAGE=
2
1 COMP=CO3-3
249.423
290.360
47,031.2
42,674.4
6,345.93
10,789.7
0.25284
0.0
0.199376+09
1
2
6
7
8
43.000
43.005
43.032
43.040
43.048
-0.13456E+06
-0.13176E+06
-0.12616E+06
-0.12524E+06
-0.12457E+06
****
MOLE-X-PROFILE
FEED RATE
LB/HR
LIQUID
VAPOR
.14376+07 .38912+05
****
****
MIXED
MIXED
-0.13615E+06
-0.12469E+06
-0.10765E+06
-0.10614E+06
-0.10460E+06
ENTHALPY
BTU/LBMOL
LIQUID
VAPOR
FEED RATE
LBMOL/HR
LIQUID
VAPOR
.45425+05 1114.6929
MASS FLOW PROFILES
FLOW RATE
LB/HR
LIQUID
VAPOR
0.1453E+07 0.2000E+06
0.1469E+07 0.1765E+06
0.1486E+07 0.2077E+06
0.1489E+07 0.2094E+06
0.1277E+07 0.2123E+06
****
STAGE
1
2
6
7
8
249.42
265.53
282.97
284.30
290.36
PRESSURE
PSIA
FLOW RATE
LBMOL/HR
LIQUID
VAPOR
0.4703E+05 6346.
0.4895E+05 6521.
0.5254E+05 0.1012E+05
0.5305E+05 0.1048E+05
0.4267E+05 0.1079E+05
STAGE
1
2
6
7
8
STAGE TEMPERATURE
F
.12765+07
PRODUCT RATE
LB/HR
LIQUID
VAPOR
.20000+06
.42674+05
PRODUCT RATE
LBMOL/HR
LIQUID
VAPOR
6345.9336
.19938+09
HEAT DUTY
BTU/HR
****
BTU/HR
BTU/HR
BUBBLE POINT
ENERGY BALANCE
****
***
F
F
LBMOL/HR
LBMOL/HR
LBMOL/HR
LBMOL/HR
1.0000
0.0000
0.0000
0.0000
1.0000
1.0000

BOILUP VAPOR FLOW
MOLAR BOILUP RATIO
REBOILER DUTY
***
CO3-CO
METHANE
HYDROGEN
74727.
66060.
48370.
45502.
45427.
MEA+
0.0000
0.0000
0.0000
STAGE
1
2
6
CO
0.10755E-03
0.81362E-08
0.64315E-25
0.60603E-25
0.60948E-25
STAGE
1
2
6
7
8
STAGE
1
2
6
7
8
MEA+
0.22418-109
0.19036-109
0.11894-109
0.10681-109
0.10588-109
HYDROGEN
0.27531E-03
0.26573E-07
0.48369E-25
0.45502E-25
0.19778E-15
STAGE
1
2
6
7
8
STAGE
1
2
6
7
8
CO
0.11280E-08
0.94647E-13
0.10000E-29
0.10000E-29
0.10000E-29
MEA+
0.80535E-01
0.68389E-01
0.42701E-01
0.38341E-01
0.38024E-01
HYDROGEN
0.36842E-08
0.40225E-12
0.10000E-29
0.10000E-29
0.43538E-20
STAGE
1
2
6
7
8
STAGE
1
2
6
7
8
STAGE
1
2
6
7
8
CO2
0.14389E-02
0.10041E-02
0.20722E-03
0.14264E-03
0.11093E-03
MEA
0.59100E-01
0.74849E-01
0.11218
0.12017
0.16437
****
****
MEA
0.39181E-01
0.55551E-01
0.76172E-01
0.77524E-01
0.93747E-01
****
HCO30.0000
0.0000
0.0000
****
K-VALUES
H3O+
MEACOO0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
****
****
K-VALUES
NITROGEN
CO2
0.12445E+06
358.37
0.11143E+06
340.08
82747.
398.40
77926.
418.75
78166.
345.65
****
MOLE-Y-PROFILE
METHANE
0.12561E-04
0.11024E-08
0.57417E-25
0.16127E-19
0.53750E-20
****
MOLE-Y-PROFILE
****
H3O+
0.21532-109
0.56965-111
0.23547-117
0.18271-109
0.46428-111
0.17012-117
0.11338-109
0.27852-111
0.15239-117
0.10158-109
0.24815-111
0.13476-117
0.10056-109
0.19791-111
****
MOLE-Y-PROFILE
****
NITROGEN
CO2
MEA
0.60341E-06
0.51567
0.23156E-02
0.34970E-10
0.34150
0.41580E-02
0.82747E-25
0.82557E-01
0.85453E-02
0.77925E-25
0.59732E-01
0.93163E-02
0.78165E-25
0.38342E-01
0.15409E-01
****
MOLE-X-PROFILE
METHANE
0.15284E-09
0.14629E-13
0.10000E-29
0.29767E-24
0.98034E-25
****
MOLE-X-PROFILE
****
H3O+
MEACOOHCO30.82521E-09
0.77353E-01
0.20464E-02
0.84595E-09
0.65638E-01
0.16680E-02
0.61073E-09
0.40702E-01
0.99987E-03
0.54701E-09
0.36464E-01
0.89075E-03
0.48399E-09
0.36116E-01
0.71078E-03
NITROGEN
0.48485E-11
0.31382E-15
0.10000E-29
0.10000E-29
0.10000E-29
CO3-0.0000
0.0000
0.0000
WATER
0.61787
0.82996
1.1316
1.1580
1.2440
CO3-0.12795-112
0.11183-112
0.90069-113
0.85365-113
0.66177-113
WATER
0.48162
0.65435
0.90890
0.93095
0.94625
CO3-0.45964E-04
0.40174E-04
0.32335E-04
0.30643E-04
0.23767E-04
WATER
0.77948
0.78841
0.80317
0.80396
0.76065
0.0000
0.0000
****
K-VALUES
METHANE
82186.
75353.
57417.
54178.
54829.
0.0000
0.0000
MEA+
0.16185
0.14153
0.93746E-01
0.84833E-01
0.78927E-01
CO
0.10227E-08
0.88363E-13
0.99040E-30
0.99814E-30
0.93639E-30
HYDROGEN
0.17610E-04
0.19787E-08
0.47496E-26
0.45934E-26
0.20264E-16
STAGE
1
2
6
7
8
STAGE
1
2
6
7
8
STAGE
1
2
6
7
8
****
****
MASS-X-PROFILE
METHANE
0.79363E-10
0.78224E-14
0.56725E-30
0.17017E-24
0.52577E-25
WATER
0.27530
0.43545
0.79759
0.83986
0.86640
CO3-0.89280E-04
0.80356E-04
0.68610E-04
0.65528E-04
0.47680E-04
****
HCO30.40417E-02
0.33922E-02
0.21572E-02
0.19368E-02
0.14499E-02
****
MASS-X-PROFILE
H3O+
MEACOO0.50809E-09
0.26060
0.53637E-09
0.22772
0.41078E-09
0.14980
0.37079E-09
0.13525
0.30779E-09
0.12567
****
MASS-Y-PROFILE
****
NITROGEN
CO2
MEA
0.53634E-06
0.72009
0.44880E-02
0.36187E-10
0.55517
0.93820E-02
0.11291E-24
0.17698
0.25426E-01
0.10932E-24
0.13164
0.28498E-01
0.11129E-24
0.85762E-01
0.47837E-01
WATER
0.45452
0.47341
0.51161
0.51611
0.45810
METHANE
0.000
0.000
0.000
0.000
0.000
MEA+
-316.7
-439.9
-204.9
-209.3
-411.5
0.0000
0.0000
****
MASS-X-PROFILE
****
NITROGEN
CO2
MEA
0.43962E-11
0.20497E-02
0.11685
0.29302E-15
0.14729E-02
0.15239
0.99051E-30
0.32246E-03
0.24230
0.99825E-30
0.22370E-03
0.26158
0.93649E-30
0.16320E-03
0.33564
RATES OF GENERATION
****
LBMOL/HR
MEACOOHCO3CO3-CO
-302.4
-13.83
-.2259
0.000
-425.0
-14.60
-.1952
0.000
-199.8
-4.980
-.5002E-01
0.000
-203.8
-5.274
-.7308E-01
0.000
-393.3
-16.93
-.6115
0.000
****
****
WATER
14.06
14.79
5.030
5.347
17.54
0.0000
0.0000
****
RATES OF GENERATION
LBMOL/HR
NITROGEN
CO2
MEA
0.000
316.5
619.1
0.000
439.8
864.9
0.000
204.9
404.8
0.000
209.2
413.1
0.000
410.9
804.8
****
HYDROGEN
0.24039E-09
0.27027E-13
0.71278E-31
0.71835E-31
0.29341E-21
H3O+
0.4596E-05
0.2600E-05
-.2731E-05
-.3066E-05
-.8366E-05
HYDROGEN
0.000
0.000
0.000
0.000
0.000
CO
95341.
85962.
64316.
60603.
60948.
0.0000
0.0000
STAGE
1
2
6
7
8
STAGE
1
2
6
7
8
STAGE
1
2
6
7
8
STAGE
1
2
6
7
8
7
8
****
MASS-Y-PROFILE
METHANE
0.63941E-05
0.65327E-09
0.44869E-25
0.12956E-19
0.43826E-20
****
TEMPERATURE
F
LIQUID FROM
VAPOR TO
249.42
265.53
265.53
274.47
282.97
284.30
284.30
290.36
290.36
290.36

WHERE:
*** DEFINITIONS ***
MASS FLOW
VOLUME FLOW
MOLECULAR
LB/HR
CUFT/HR
LIQUID FROM
1 0.14531E+07 0.17652E+06 26603.
0.11647E+07 30.895
2 0.14686E+07 0.19211E+06 26963.
0.14449E+07 30.002
6 0.14859E+07 0.20935E+06 27145.
0.19144E+07 28.282
7 0.14888E+07 0.21229E+06 27146.
0.19857E+07 28.063
8 0.12765E+07 0.0000
23448.
0.0000
29.913
STAGE
1
2
6
7
8
CO
0.95587E-04
0.84184E-08
0.87752E-25
0.85006E-25
0.86766E-25
STAGE
1
2
6
7
8
****
MASS-Y-PROFILE
****
H3O+
0.71112-109
0.11029-110
0.16546-117
0.70248-109
0.10465-110
0.15763-117
0.57483-109
0.82781-111
0.14516-117
0.52948-109
0.75823-111
0.13029-117
0.53198-109
0.61376-111
********************************
********************************
MEA+
0.44166-109
0.43662-109
0.35974-109
0.33211-109
0.33412-109
STAGE
1
2
6
7
8
VAPOR TO
27.071
24.012
19.969
19.676
WEIGHT
CO3-0.24362-112
0.24789-112
0.26328-112
0.25654-112
0.20184-112
0.43360
0.37769
0.31724
0.30964
FLOW PARAM
QR
CUFT/HR
61438.
71476.
85652.
87757.
0.0000
REDUCED F-FACTOR
(LB-CUFT)**.5/HR
0.45343E+06
0.52687E+06
0.63307E+06
0.64927E+06
0.0000
VISCOSITY
SURFACE TENSION
CP
DYNE/CM
LIQUID FROM
0.61423
0.17060E-01
58.093
0.43733
0.16260E-01
55.599
0.26367
0.14777E-01
51.778
0.24772
0.14613E-01
51.242
0.23196
49.723
PACKING SPECIFICATIONS
---------------------PACKING TYPE
PACKING MATERIAL
PACKING SIZE
VENDOR
PACKING FACTOR
PACKING SURFACE AREA
PACKING VOID FRACTION
FIRST STICHLMAIR CONSTANT
SECOND STICHLMAIR CONSTANT
THIRD STICHLMAIR CONSTANT
1/FT
SQFT/CUF
BX
STANDARD
STANDARD
SULZER
22.1592
149.963
0.90000
1.00386
-0.11281
0.35400
1.00000
0.70000
0.85000
MISSING
MISSING
MISSING
MISSING
DESIGN PARAMETERS
----------------OVERDESIGN FACTOR
FRAC. APP. TO MAXIMUM CAPACITY
DESIGN CAPACITY FACTOR
PRESSURE DROP PER UNIT HEIGHT
FT/SEC
FT/SEC
PSI
IN-WATER/FT
1
7
SULZER
SULZER
STICHL
YES

ENDING STAGE NUMBER
CAPACITY CALCULATION METHOD
PRESSURE DROP CALCULATION METHOD
LIQUID HOLDUP CALCULATION METHOD
PRESSURE PROFILE UPDATED
*******************
*** SECTION
1 ***
*******************
***************************************
***** PACKING SIZING CALCULATIONS *****
***************************************
MARANGONI INDEX
STAGE
DYNE/CM
1
2
-2.4936
6
-.53438
7
-.53567
8
-1.5197
DENSITY
LB/CUFT
1
54.620
0.15156
2
54.469
0.13296
6
54.739
0.10936
7
54.845
0.10691
8
54.441
HEIGHT
FROM TOP
OF SECTION
FT
0.000
2.143
4.286
6.429
8.571
10.71
12.86
0.6683
0.7395
0.7834
0.8084
0.8242
0.8361
0.8500
FRACTIONAL
CAPACITY
PRESSURE
DROP
PSI
0.48249E-02
0.59957E-02
0.67762E-02
0.72466E-02
0.75554E-02
0.77998E-02
0.81273E-02
PRESSURE
DROP/HEIGHT
IN-WATER/FT
0.62325E-01
0.77448E-01
0.87530E-01
0.93607E-01
0.97595E-01
0.10075
0.10498
DESIGN PARAMETERS
-----------------

ENDING STAGE NUMBER
*******************
*** SECTION
1 ***
*******************
************************************
************************************
LIQUID
SUPERFICIAL
STAGE VELOCITY
FT/SEC
1
0.3760E-01
2
0.3811E-01
3
0.3834E-01
4
0.3840E-01
5
0.3840E-01
6
0.3837E-01
7
0.3837E-01
1
2
3
4
5
6
7
FT/SEC
PSI
IN-WATER/FT
CUFT
FT/SEC
FT
2
7
B960
LIQUID
HOLDUP
CUFT
65.87
60.97
57.92
56.09
54.86
53.90
53.06
HETP
FT
2.143
2.143
2.143
2.143
2.143
2.143
2.143
15.8184
0.85000
0.12404
0.048326
0.089177
65.8673
0.038399
2.14286
15.0000
MISSING
**** RATING PROFILES AT MAXIMUM COLUMN DIAMETER ****
COLUMN DIAMETER
MAXIMUM FRACTIONAL CAPACITY
AVERAGE PRESSURE DROP/HEIGHT
MAXIMUM LIQUID HOLDUP/STAGE
MAX LIQ SUPERFICIAL VELOCITY
STAGE
FT
FT
FT
***** SIZING RESULTS *****
HETP
PACKING HEIGHT
PACKING SHEET THICKNESS
FLEXI
1
2.00000
DIAMETER
FT
32.565
32.962
33.144
33.230
33.275
33.354
TOTAL AREA
SQFT
832.89
853.33
862.75
867.26
869.63
873.73
ACTIVE AREA
SQFT
666.31
682.66
690.20
693.81
695.70
698.98
SIDE DC AREA
SQFT
83.289
85.333
86.275
86.726
86.963
87.373
7
33.3536
0.10000
0.086304
22.9156
5.21903
24.2351
0.0
0.0
0.0
0.0
0.0
0.0
TWO
PHASE PQ
PRESSURE DROP
INPUT DATA
***
16573.8
206792.
-0.433843E+09
***
OUT
16573.8
206792.
-0.433843E+09

IN
***
FLASH
PSI
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
***
0.0
0.115667E-06
0.169914E-06
-0.492986E-06
RELATIVE DIFF.
BLOCK: V301
MODEL: FLASH2
-----------------------------INLET STREAM:
S306
OUTLET VAPOR STREAM:
S308
OUTLET LIQUID STREAM: S307
HENRY-COMPS ID:
GLOBAL
CHEMISTRY ID:
GLOBAL
- TRUE SPECIES
2
3
4
5
6
7
FT/SEC
FT
FT
FT
FT
FT
FT
FT
FT
FT
FT

COLUMN DIAMETER
DC AREA/COLUMN AREA
DOWNCOMER VELOCITY
FLOW PATH LENGTH
SIDE WEIR LENGTH
CENTER WEIR LENGTH
STAGE
FT
FT
1.00000
0.70000
0.85000
1.00000
0.100000
TRAY SPECIFICATIONS
------------------TRAY TYPE
NUMBER OF PASSES
TRAY SPACING
PEAK CAPACITY FACTOR

FLOODING FACTOR
***
F
PSIA
F(I)
0.60425
0.21442E-02
0.49811E-01
0.94156E-06
0.29978E-01
0.67810E-04
0.50570E-10
0.27077E-05
0.64826E-04
0.13831E-06
0.28625
0.27430E-01
***
X(I)
0.15561E-03
0.37614E-06
0.33306E-03
0.40454E-04
0.99356
0.29199E-02
0.21775E-08
0.11660E-03
0.27914E-02
0.59558E-05
0.71105E-04
0.90201E-05
RESULTS
Y(I)
0.61861
0.21952E-02
0.50988E-01
0.21520E-08
0.70679E-02
0.0000
0.0000
0.0000
0.0000
0.0000
0.29306
0.28082E-01
K(I)
3975.5
5836.1
153.09
0.53198E-04
0.71137E-02
0.0000
0.0000
0.0000
0.0000
0.0000
4121.5
3113.3
124.88
296.76
0.97678
0.0
30
0.000100000
***
F
PSIA
COMP
F(I)
OUTLET TEMPERATURE
OUTLET PRESSURE
VAPOR FRACTION
***
X(I)
RESULTS
***
6331.78
200000.
-0.926021E+09
***
OUT
Y(I)
-0.342917E-08
-0.145519E-15
0.432427E-08
RELATIVE DIFF.
118.41
39.266
0.53717
K(I)
0.0
0.0
30
0.000100000
6331.78
200000.
-0.926021E+09

IN
*** INPUT DATA

TWO
PHASE PQ FLASH
PRESSURE DROP
PSI
SPECIFIED HEAT DUTY
BTU/HR
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
***
BLOCK: V302
MODEL: FLASH2
-----------------------------INLET STREAM:
S315
S318
OUTLET LIQUID STREAM: V302BOTT
HENRY-COMPS ID:
GLOBAL
CHEMISTRY ID:
GLOBAL
- TRUE SPECIES
COMP
HYDROGEN
NITROGEN
CO2
MEA
WATER
MEA+
H3O+
MEACOOHCO3CO3-CO
METHANE
OUTLET TEMPERATURE
OUTLET PRESSURE
VAPOR FRACTION
SPECIFIED HEAT DUTY

BTU/HR
HYDROGEN
NITROGEN
CO2
MEA
WATER
MEA+
H3O+
MEACOOHCO3CO3-CO
METHANE
0.27593E-03
0.60475E-06
0.51459
0.13341E-04
0.48053
0.22387E-02
0.18861E-08
0.68728E-04
0.21639E-02
0.30273E-05
0.10779E-03
0.12589E-04
0.16968E-07
0.26093E-10
0.92036E-03
0.28817E-04
0.98938
0.48369E-02
0.40749E-08
0.14850E-03
0.46754E-02
0.65404E-05
0.66317E-08
0.10419E-08
0.51366E-03
0.11258E-05
0.95717
0.80130E-08
0.42089E-01
0.0000
0.0000
0.0000
0.0000
0.0000
0.20066E-03
0.23436E-04
30273.
43146.
1040.0
0.27807E-03
0.42541E-01
0.0000
0.0000
0.0000
0.0000
0.0000
30258.
22494.
CW301
---H301
CW302
H301
----
CW303
---H302
CW304
H302
----
CW305
---H304
SUBSTREAM: MIXED
PHASE:
LIQUID
LIQUID
LIQUID
LIQUID
LIQUID
HYDROGEN
0.0
0.0
0.0
0.0
0.0
OXYGEN
0.0
0.0
0.0
0.0
0.0
NITROGEN
0.0
0.0
0.0
0.0
0.0
CO2
0.0
0.0
0.0
0.0
0.0
MEA
0.0
0.0
0.0
0.0
0.0
WATER
2.1332+05 2.1332+05 2.7754+04 2.7754+04 1.1379+05
MEA+
0.0
0.0
0.0
0.0
0.0
H3O+
0.0
0.0
0.0
0.0
0.0
MEACOO0.0
0.0
0.0
0.0
0.0
HCO30.0
0.0
0.0
0.0
0.0
CO3-0.0
0.0
0.0
0.0
0.0
SULFU-01
0.0
0.0
0.0
0.0
0.0
CO
0.0
0.0
0.0
0.0
0.0
METHANE
0.0
0.0
0.0
0.0
0.0
H2
0.0
0.0
0.0
0.0
0.0
HYDROGEN
0.0
0.0
0.0
0.0
0.0
OXYGEN
0.0
0.0
0.0
0.0
0.0
NITROGEN
0.0
0.0
0.0
0.0
0.0
CO2
0.0
0.0
0.0
0.0
0.0
MEA
0.0
0.0
0.0
0.0
0.0
WATER
1.0000
1.0000
1.0000
1.0000
1.0000
MEA+
0.0
0.0
0.0
0.0
0.0
H3O+
0.0
0.0
0.0
0.0
0.0
MEACOO0.0
0.0
0.0
0.0
0.0
HCO30.0
0.0
0.0
0.0
0.0
CO3-0.0
0.0
0.0
0.0
0.0
SULFU-01
0.0
0.0
0.0
0.0
0.0
CO
0.0
0.0
0.0
0.0
0.0
METHANE
0.0
0.0
0.0
0.0
0.0
H2
0.0
0.0
0.0
0.0
0.0
TOTAL FLOW:
LBMOL/HR
2.1332+05 2.1332+05 2.7754+04 2.7754+04 1.1379+05
LB/HR
3.8431+06 3.8431+06 5.0000+05 5.0000+05 2.0500+06
CUFT/HR
6.1856+04 6.2264+04 8047.7387 8106.8727 3.2996+04
STATE VARIABLES:
TEMP
F
90.0000
120.0000
90.0000
123.0482
90.0000
PRES
PSIA
64.6959
57.4859
64.6959
62.9063
64.6959
VFRAC
0.0
0.0
0.0
0.0
0.0
LFRAC
1.0000
1.0000
1.0000
1.0000
1.0000
SFRAC
0.0
0.0
0.0
0.0
0.0
ENTHALPY:
BTU/LBMOL
-1.2272+05 -1.2218+05 -1.2272+05 -1.2213+05 -1.2272+05
BTU/LB
-6812.2302 -6782.2980 -6812.2302 -6779.2598 -6812.2302
BTU/HR
-2.6180+10 -2.6065+10 -3.4061+09 -3.3896+09 -1.3965+10
ENTROPY:
BTU/LBMOL-R
-38.5416
-37.5857
-38.5416
-37.4920
-38.5416
BTU/LB-R
-2.1394
-2.0863
-2.1394
-2.0811
-2.1394
DENSITY:
STREAM ID
FROM :
TO
:
CW301 CW302 CW303 CW304 CW305

-----------------------------
3.4487
62.1293
18.0153
CW306
H304
----
S214
---T301
3.4261
61.7229
18.0153
S302
H301
T301
3.4487
62.1293
18.0153
S304
---T301
3.4235
61.6761
18.0153
S305
T301
H302
3.4487
62.1293
18.0153
SUBSTREAM: MIXED
PHASE:
LIQUID
VAPOR
LIQUID
LIQUID
VAPOR
HYDROGEN
0.0
1.0016+04 5.3216-05
0.0
1.0015+04
OXYGEN
0.0
0.0
0.0
0.0
0.0
NITROGEN
0.0
35.5417 8.1323-08
0.0
35.5380
CO2
0.0
4083.4728 8.6535-04
0.0
826.6838
MEA
0.0
0.0
6964.4036
2.7831
1.1844
WATER
1.1379+05
0.0
3.5501+04
136.9601
497.9190
MEA+
0.0
0.0
1658.2480
0.0
0.0
H3O+
0.0
0.0
1.2884-07
0.0
0.0
MEACOO0.0
0.0
1567.3520
0.0
0.0
HCO30.0
0.0
6.8247
0.0
0.0
CO3-0.0
0.0
17.4985
0.0
0.0
SULFU-01
0.0
0.0
0.0
0.0
0.0
CO
0.0
4744.9668 2.0628-05
0.0
4744.3117
METHANE
0.0
454.7024 3.2276-06
0.0
454.6261
H2
0.0
0.0
0.0
0.0
0.0
HYDROGEN
0.0
0.5180 1.1641-09
0.0
0.6042
OXYGEN
0.0
0.0
0.0
0.0
0.0
NITROGEN
0.0
1.8382-03 1.7789-12
0.0
2.1441-03
CO2
0.0
0.2112 1.8929-08
0.0
4.9876-02
MEA
0.0
0.0
0.1523 1.9916-02 7.1455-05
WATER
1.0000
0.0
0.7766
0.9801 3.0041-02
MEA+
0.0
0.0
3.6273-02
0.0
0.0
H3O+
0.0
0.0
2.8183-12
0.0
0.0
MEACOO0.0
0.0
3.4285-02
0.0
0.0
HCO30.0
0.0
1.4929-04
0.0
0.0
CO3-0.0
0.0
3.8277-04
0.0
0.0
SULFU-01
0.0
0.0
0.0
0.0
0.0
CO
0.0
0.2454 4.5122-10
0.0
0.2862
METHANE
0.0
2.3517-02 7.0602-11
0.0
2.7429-02
H2
0.0
0.0
0.0
0.0
0.0
TOTAL FLOW:
LBMOL/HR
1.1379+05 1.9335+04 4.5715+04
139.7432 1.6575+04
LB/HR
2.0500+06 3.4110+05 1.3325+06 2637.3750 2.0679+05
CUFT/HR
3.3216+04 3.8636+05 2.1965+04
42.4605 3.9587+05
STATE VARIABLES:
TEMP
F
120.3357
100.0000
99.9999
100.0000
204.0932
PRES
PSIA
58.7622
300.0000
297.5915
300.0000
300.0000
VFRAC
0.0
1.0000
0.0
0.0
1.0000
LFRAC
1.0000
0.0
1.0000
1.0000
0.0
SFRAC
0.0
0.0
0.0
0.0
0.0
ENTHALPY:
BTU/LBMOL
-1.2218+05 -4.8050+04 -1.2852+05 -1.2245+05 -2.5180+04
BTU/LB
-6781.9781 -2723.6480 -4409.0895 -6487.8632 -2018.2592
BTU/HR
-1.3903+10 -9.2905+08 -5.8753+09 -1.7111+07 -4.1736+08
ENTROPY:
STREAM ID
FROM :
TO
:
CW306 S214 S302 S304 S305

-------------------------
LBMOL/CUFT
LB/CUFT
AVG MW
5.0044-02
0.8829
17.6418
3.4259
61.7181
18.0153
MAX CONV. ERROR:

SUBSTREAM: MIXED
PHASE:
HYDROGEN
OXYGEN
NITROGEN
CO2
MEA
WATER
MEA+
H3O+
CO
METHANE
H2
HYDROGEN
OXYGEN
NITROGEN
CO2
MEA
WATER
MEA+
H3O+
CO
METHANE
H2
TOTAL FLOW:
LBMOL/HR
LB/HR
CUFT/HR
STATE VARIABLES:
TEMP
F
PRES
PSIA
VFRAC
LFRAC
SFRAC
STREAM ID
FROM :
TO
:
1.4300-05
LIQUID
5.9892-02
0.0
1.4477-04
0.1282
1.5571-02
382.4193
1.1239
8.3813-07
4.4878-02
1.0744
2.2924-03
0.0
2.7368-02
3.4718-03
0.0
1.5560-04
0.0
3.7614-07
3.3306-04
4.0454-05
0.9936
2.9199-03
2.1775-09
1.1660-04
2.7914-03
5.9558-06
0.0
7.1104-05
9.0200-06
0.0
384.8994
7037.0794
114.2508
124.8824
296.7601
0.0
1.0000
0.0
0.0
MIXED
1.0015+04
0.0
35.5380
825.5622
1.5605-02
496.8423
1.1239
8.3814-07
4.4877-02
1.0744
2.2924-03
0.0
4744.3117
454.6261
0.0
0.6042
0.0
2.1442-03
4.9811-02
9.4156-07
2.9978-02
6.7810-05
5.0570-11
2.7077-06
6.4826-05
1.3831-07
0.0
0.2863
2.7430-02
0.0
1.6574+04
2.0679+05
3.4450+05
125.0000
296.7630
0.9768
2.3223-02
0.0
S306
H302
V301
S307
V301
T301
1.4230
8.0659-02
-37.5759
-2.0858
S306 S307 S308 S309 S310

------------------------
BTU/LBMOL-R
BTU/LB-R
DENSITY:
LBMOL/CUFT
LB/CUFT
AVG MW
124.8824
296.7630
1.0000
0.0
0.0
1.6189+04
1.9975+05
3.4439+05
0.6186
0.0
2.1952-03
5.0988-02
2.1520-09
7.0679-03
0.0
0.0
0.0
0.0
0.0
0.0
0.2931
2.8082-02
0.0
1.0015+04
0.0
35.5378
825.4340
3.4839-05
114.4210
0.0
0.0
0.0
0.0
0.0
0.0
4744.2843
454.6227
0.0
VAPOR
0.0
S308
V301
----
2.0813
60.6668
29.1487
-75.5634
-2.5923
193.6284
300.0192
0.0
1.0000
0.0
4.5844+04
1.4765+06
2.6543+04
3.8110-05
0.0
8.3525-08
2.2087-03
1.8989-02
0.7704
0.1047
7.3451-10
9.8617-02
4.8805-03
8.0522-05
0.0
1.4887-05
1.7388-06
0.0
1.7471
0.0
3.8292-03
101.2565
870.5400
3.5320+04
4801.2241
3.3673-05
4521.0225
223.7444
3.6915
0.0
0.6825
7.9713-02
0.0
LIQUID
7.9014-02
S309
T301
B1
3.2911
62.1136
18.8730
-39.6402
-2.1004
193.7484
85.0000
1.9774-04
0.9998
0.0
4.5849+04
1.4765+06
2.7283+04
3.8106-05
0.0
8.3517-08
2.3068-03
1.9145-02
0.7704
0.1046
7.3037-10
9.8547-02
4.8414-03
8.0738-05
0.0
1.4886-05
1.7386-06
0.0
1.7471
0.0
3.8292-03
105.7643
877.7856
3.5322+04
4796.7265
3.3487-05
4518.2745
221.9743
3.7017
0.0
0.6825
7.9713-02
0.0
MIXED
0.0
S310
B1
H303
4.1869-02
0.5224
12.4762
2.8516
0.2286
3.3689
61.5933
18.2829
4.8110-02
0.6003
12.4771
MAX CONV. ERROR:

SUBSTREAM: MIXED
PHASE:
HYDROGEN
OXYGEN
NITROGEN
CO2
MEA
WATER
MEA+
H3O+
CO
METHANE
H2
HYDROGEN
OXYGEN
NITROGEN
CO2
MEA
WATER
MEA+
H3O+
CO
METHANE
H2
TOTAL FLOW:
LBMOL/HR
LB/HR
CUFT/HR
STATE VARIABLES:
STREAM ID
FROM :
TO
:
9.8275-06
LIQUID
4.2674-26
0.0
4.2674-26
4.7336
7014.2101
3.2460+04
1622.6583
2.0654-05
1541.2237
30.3319
1.0142
0.0
2.4929-21
1.4240-20
0.0
1.0000-30
0.0
1.0000-30
1.1092-04
0.1644
0.7606
3.8024-02
4.8399-10
3.6116-02
7.1077-04
2.3767-05
0.0
5.8417-26
3.3370-25
0.0
4.2674+04
1.2765+06
2.3448+04
0.0
MIXED
1.7471
0.0
3.8292-03
627.6610
1839.8870
3.5405+04
4273.2549
5.1701-05
4079.6448
140.2823
2.1268
0.0
0.6825
7.9713-02
0.0
3.7677-05
0.0
8.2577-08
1.3536-02
3.9678-02
0.7635
9.2154-02
1.1149-09
8.7979-02
3.0252-03
4.5864-05
0.0
1.4718-05
1.7190-06
0.0
4.6371+04
1.4765+06
7.9483+04
S311
H303
T302
S312
T302
H303
-38.2515
-2.0922
1.2639
0.1013
4.2670+04
1.2765+06
2.2374+04
0.0
0.0
0.0
5.8278-06
0.1639
0.7610
3.8179-02
1.0017-10
3.6456-02
4.3412-04
6.9349-05
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.2487
6993.4323
3.2470+04
1629.0881
4.2741-06
1555.5716
18.5240
2.9591
0.0
0.0
0.0
0.0
LIQUID
0.0
S313
H303
D11
4.7008-02
0.5800
12.3390
2.2034
0.1786
6345.9337
2.0000+05
1.1100+06
2.7531-04
0.0
6.0341-07
0.5157
2.3156-03
0.4816
0.0
0.0
0.0
0.0
0.0
0.0
1.0755-04
1.2561-05
0.0
1.7471
0.0
3.8292-03
3272.4053
14.6946
3056.3206
0.0
0.0
0.0
0.0
0.0
0.0
0.6825
7.9713-02
0.0
VAPOR
0.0
S314
T302
H304
1.7272
55.6275
32.2073
-111.3980
-3.4588
6331.7778
2.0000+05
5.3213+05
2.7593-04
0.0
6.0475-07
0.5146
1.3341-05
0.4805
2.2387-03
1.8861-09
6.8728-05
2.1639-03
3.0273-06
0.0
1.0779-04
1.2589-05
0.0
1.7471
0.0
3.8292-03
3258.2494
8.4473-02
3042.5999
14.1750
1.1943-05
0.4352
13.7015
1.9168-02
0.0
0.6825
7.9713-02
0.0
MIXED
0.0
S315
H304
V302
1.6805
54.1195
32.2042
-111.3335
-3.4571
-2.6177+04 -1.2265+05 -2.3883+04 -1.4072+05 -1.4071+05

-2097.9696 -6708.6723 -1935.5405 -4369.2394 -4369.2382
-4.3384+08 -4.7209+07 -3.8663+08 -6.4513+09 -6.4513+09
S311 S312 S313 S314 S315

------------------------
ENTHALPY:
BTU/LBMOL
BTU/LB
BTU/HR
ENTROPY:
BTU/LBMOL-R
BTU/LB-R
DENSITY:
LBMOL/CUFT
LB/CUFT
AVG MW
SUBSTREAM: MIXED
PHASE:
HYDROGEN
OXYGEN
NITROGEN
CO2
MEA
WATER
MEA+
H3O+
CO
METHANE
H2
HYDROGEN
OXYGEN
NITROGEN
CO2
MEA
WATER
MEA+
H3O+
CO
METHANE
H2
TOTAL FLOW:
LBMOL/HR
STREAM ID
FROM :
TO
:
290.3597
43.0483
0.0
1.0000
0.0
218.7495
39.7373
0.0
1.0000
0.0
249.4234
43.0000
1.0000
0.0
0.0
120.0000
39.2662
0.5372
0.4628
0.0
0.5834
18.5768
31.8417
-102.3387
-3.2140
LIQUID
4.9725-05
0.0
7.6467-08
0.2060
6975.3266
3.5382+04
1646.5422
4.1107-06
1570.9177
19.5152
3.5175
0.0
1.9434-05
3.0532-06
0.0
1.0905-09
0.0
1.6770-12
4.5169-06
0.1530
0.7760
3.6110-02
9.0150-11
3.4452-02
4.2799-04
7.7143-05
0.0
4.2622-10
6.6960-11
0.0
4.5598+04
LIQUID
1.1641-09
0.0
1.7789-12
4.7077-06
0.1526
0.7766
3.5962-02
9.2517-11
3.4305-02
4.3134-04
7.5958-05
0.0
4.5122-10
7.0602-11
0.0
4.5716+04
S316R
D11
----
5.3216-05
0.0
8.1323-08
0.2152
6977.7265
3.5502+04
1644.0076
4.2295-06
1568.2695
19.7189
3.4725
0.0
2.0628-05
3.2276-06
0.0
S316
---P301
1.8200
54.4411
29.9132
-71.7179
-2.3975
3401.2206
5.1366-04
0.0
1.1258-06
0.9572
8.0130-09
4.2089-02
0.0
0.0
0.0
0.0
0.0
0.0
2.0066-04
2.3436-05
0.0
1.7471
0.0
3.8291-03
3255.5523
2.7254-05
143.1552
0.0
0.0
0.0
0.0
0.0
0.0
0.6825
7.9710-02
0.0
VAPOR
S318
V302
----
1.9071
57.0539
29.9163
-73.7992
-2.4669
4.5716+04
1.1641-09
0.0
1.7789-12
4.9170-06
0.1526
0.7766
3.5960-02
9.4747-11
3.4303-02
4.3445-04
7.4550-05
0.0
4.5122-10
7.0602-11
0.0
5.3216-05
0.0
8.1323-08
0.2248
6977.8881
3.5502+04
1643.9336
4.3314-06
1568.1819
19.8613
3.4081
0.0
2.0628-05
3.2276-06
0.0
LIQUID
S319
P301
H301
5.7170-03
0.1802
31.5162
-3.2553
-0.1033
2930.5572
1.6968-08
0.0
2.6093-11
9.2036-04
2.8817-05
0.9894
4.8369-03
4.0749-09
1.4850-04
4.6754-03
6.5404-06
0.0
6.6317-09
1.0419-09
0.0
4.9725-05
0.0
7.6467-08
2.6972
8.4450-02
2899.4448
14.1750
1.1942-05
0.4352
13.7014
1.9167-02
0.0
1.9434-05
3.0532-06
0.0
LIQUID
V302BOTT
V302
D11
1.1899-02
0.3758
31.5867
-18.4340
-0.5836
-1.3758+05 -1.2457+05 -1.2627+05 -1.3615+05 -1.4625+05

-4320.6332 -4164.5417 -4220.7619 -4320.0224 -4630.1067
-6.3795+09 -5.3162+09 -5.3879+09 -8.6400+08 -9.2602+08
242.6631
80.2200
1.2309-02
0.9877
0.0
S316 S316R S318 S319 V302BOTT

-----------------------------
TEMP
F
PRES
PSIA
VFRAC
LFRAC
SFRAC
ENTHALPY:
BTU/LBMOL
BTU/LB
BTU/HR
ENTROPY:
BTU/LBMOL-R
BTU/LB-R
DENSITY:
LBMOL/CUFT
LB/CUFT
AVG MW
LB/HR
CUFT/HR
STATE VARIABLES:
TEMP
F
PRES
PSIA
VFRAC
LFRAC
SFRAC
ENTHALPY:
BTU/LBMOL
BTU/LB
BTU/HR
ENTROPY:
BTU/LBMOL-R
BTU/LB-R
DENSITY:
LBMOL/CUFT
LB/CUFT
AVG MW
213.9836
39.2662
0.0
1.0000
0.0
215.0934
43.0000
0.0
1.0000
0.0
118.4109
39.2662
1.0000
0.0
0.0
1.4588+05
5.3125+05
216.0401
300.0000
0.0
1.0000
0.0
1.3325+06
2.3262+04
118.4109
39.2662
0.0
1.0000
0.0
5.4121+04
877.1478
1.9655
57.2908
29.1485
-71.4761
-2.4521
1.9642
57.3203
29.1823
6.4022-03
0.2746
42.8903
-71.6475
-0.7374
-2.4552 -1.7193-02
1.9652
57.2834
29.1485
-71.4493
-2.4512
3.3410
61.7009
18.4677
-38.9727
-2.1103
-1.2603+05 -1.2608+05 -1.6610+05 -1.2600+05 -1.2322+05

-4323.7571 -4320.4590 -3872.5770 -4322.7642 -6671.9810
-5.7616+09 -5.7490+09 -5.6493+08 -5.7603+09 -3.6109+08
1.3306+06
2.3214+04
1.3325+06
2.3259+04
P-SPEC
STAGE
PRES, PSIA
200.000
BLOCK 400 and 500

*******************
**** RESULTS ****
*******************
BLOCK Results:
BLOCK: ABS-401 MODEL: RADFRAC
------------------------------INLETS
- Q
STAGE 10
S-430
STAGE
1
OUTLETS - S-408
STAGE
1
W
STAGE 10
NRTL-RK
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
***
S-408
RENON (NRTL) / REDLICH-KWONG

IN
40726.2
670635.
-0.261418E+10
***
OUT
RELATIVE DIFF.
40726.2
670635.
-0.261419E+10
0.178656E-15
0.107048E-06
0.684689E-05
**********************
**********************
****
INPUT PARAMETERS
****
COL-SPECS
10
3-PHASE
NO
STANDARD
NO
BROYDEN
NESTED
100
10
40
0.000100000
0.000100000
****

REBOILER DUTY
BTU/HR
BTU/HR
TWO LIQUID PHASE CALCULATIONS ARE PERFORMED FOR
STAGE
2
TO
**** L2-COMPS SPECIFICATIONS ****

KEY COMPONENTS IN THE SECOND LIQUID PHASE
PROFILES
****
COMPONENT
C2H6O-01
CH4O
STAGE
10
1.0000
.99271
.99088
.95408
.93418
.51237E-01
.39322E-03
.52851
.10491E-06
.72916E-02
.91200E-02
.45915E-01
.65815E-01
.94876
.99961
.47149

BOILUP VAPOR FLOW
REBOILER DUTY
****
***
OUTLET STREAMS
-------------W
***
F
F
LBMOL/HR
LBMOL/HR
LBMOL/HR
LBMOL/HR
BTU/HR
BTU/HR
DEW POINT
BUBBLE POINT
ENERGY BALANCE
****
1.00000
0.0
0.0
**** L2-STAGES SPECIFICATIONS ****
****
COMPONENT:
H2
N2
CO
CO2
CH4
WATER
CH4O
C2H6O-01
***
****
NUMBER OF STAGES
ALGORITHM OPTION
ABSORBER OPTION
FLASH TOLERANCE
PROFILES
171.977
170.659
15,549.2
16,228.0
24,498.2
26,667.3
0.0
0.0
****
0.68004E-04
0.91932E-03
0.22115E-05
0.34136E-04
STAGE=
STAGE=
STAGE=
STAGE=
6 PHASE=L1
6 PHASE=L1
1 COMP=WATER
5
****
STAGE TEMPERATURE
F
1
2
9
10
171.98
180.15
173.57
170.66
PRESSURE
PSIA
200.00
201.00
201.70
201.80
FLOW RATE
LBMOL/HR
LIQUID
VAPOR
1 0.1555E+05 0.2450E+05
ENTHALPY
BTU/LBMOL
LIQUID
VAPOR
-0.11773E+06
-0.11689E+06
-0.11609E+06
-0.11584E+06
STAGE
LIQUID
.14000+05
HEAT DUTY
BTU/HR
-29977.
-32769.
-33673.
-33743.
FEED RATE
LBMOL/HR
VAPOR
MIXED
PRODUCT RATE
LBMOL/HR
LIQUID
VAPOR
.24498+05
2 0.1588E+05 0.2605E+05
9 0.1617E+05 0.2662E+05
10 0.1623E+05 0.2667E+05
STAGE
1
2
9
10
FLOW RATE
LBMOL/HR
LIQUID1
LIQUID2
0.1555E+05 0.000
0.1588E+05 0.000
0.1617E+05 0.000
0.1623E+05 0.000
****
.26726+05
LIQUID
.25221+06
FEED RATE
LB/HR
VAPOR
MIXED
.41842+06
PRODUCT RATE
LB/HR
LIQUID
VAPOR
.32309+06
.34755+06
STAGE
1
2
9
10
FLOW RATE
LB/HR
LIQUID1
LIQUID2
0.3099E+06 0.000
0.3248E+06 0.000
0.3426E+06 0.000
0.3475E+06 0.000
STAGE
1
2
9
10
H2
0.10203E-06
0.10777E-06
0.97570E-07
0.94479E-07
****
MOLE-X-PROFILE
****
N2
CO
CO2
0.37125E-03
0.28021E-04
0.61363E-02
0.33093E-03
0.24900E-04
0.50170E-02
0.34442E-03
0.26010E-04
0.61188E-02
0.35515E-03
0.26867E-04
0.67705E-02
STAGE
1
2
9
10
WATER
0.91246
0.89517
0.86533
0.85267
****
MOLE-X-PROFILE
****
CH4O
C2H6O-01
0.12906E-04
0.63749E-01
0.34305E-04
0.83460E-01
0.55905E-02
0.10575
0.13225E-01
0.10945
STAGE
1
2
9
10
H2
0.10203E-06
0.10777E-06
0.97570E-07
0.94479E-07
****
MOLE-X1-PROFILE
****
N2
CO
CO2
0.37125E-03
0.28021E-04
0.61363E-02
0.33093E-03
0.24900E-04
0.50170E-02
0.34442E-03
0.26010E-04
0.61188E-02
0.35515E-03
0.26867E-04
0.67705E-02
STAGE
1
2
9
10
WATER
0.91246
0.89517
0.86533
0.85267
****
MOLE-X1-PROFILE
****
CH4O
C2H6O-01
0.12906E-04
0.63749E-01
0.34305E-04
0.83460E-01
0.55905E-02
0.10575
0.13225E-01
0.10945
STAGE
H2
****
N2
0.10203E-06
0.10777E-06
0.97570E-07
0.94479E-07
0.37125E-03
0.33093E-03
0.34442E-03
0.35515E-03
STAGE
1
2
9
10
WATER
0.91246
0.89517
0.86533
0.85267
****
MOLE-X2-PROFILE
****
CH4O
C2H6O-01
0.12906E-04
0.63749E-01
0.34305E-04
0.83460E-01
0.55905E-02
0.10575
0.13225E-01
0.10945
STAGE
1
2
9
10
H2
0.59657
0.56109
0.54901
0.54804
****
MOLE-Y-PROFILE
****
N2
CO
CO2
0.32029E-01
0.19336E-02
0.93193E-01
0.30346E-01
0.18353E-02
0.91313E-01
0.29681E-01
0.17950E-02
0.89259E-01
0.29633E-01
0.17921E-02
0.89322E-01
STAGE
1
2
9
10
WATER
0.30502E-01
0.35908E-01
0.30017E-01
0.27711E-01
****
MOLE-Y-PROFILE
****
CH4O
C2H6O-01
0.34462E-05
0.81272E-01
0.10945E-04
0.11449
0.15483E-02
0.13732
0.33928E-02
0.13878
STAGE
1
2
9
10
H2
5.8479+06
5.2066+06
5.6228+06
5.7987+06
****
K-VALUES: V-L1
N2
CO
86.2776
69.0100
91.6988
73.7088
86.1550
68.9944
83.4271
66.6968
****
CO2
15.1861
18.2000
14.5913
13.1943
CH4O
0.2670
0.3191
0.2770
0.2565
****
K-VALUES: V-L1
C2H6O-01
1.2749
1.3719
1.2983
1.2678
****
STAGE
1
2
9
10
STAGE
1
2
9
10
H2
MISSING
MISSING
MISSING
MISSING
****
K-VALUES: V-L2
N2
CO
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
****
CO2
MISSING
MISSING
MISSING
MISSING
CH4O
MISSING
MISSING
MISSING
MISSING
****
K-VALUES: V-L2
C2H6O-01
MISSING
MISSING
MISSING
MISSING
****
STAGE
1
2
9
10
STAGE
1
2
9
10
H2
MISSING
MISSING
MISSING
MISSING
****
K-VALUES: L2-L1
N2
CO
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
****
CO2
MISSING
MISSING
MISSING
MISSING
****
STAGE
1
2
9
10
.16228+05
ENTHALPY
BTU/LBMO
LIQUID1
LIQUID2
-0.11773E+06 -0.11773E+06
-0.11689E+06 -0.11689E+06
-0.11609E+06 -0.11609E+06
-0.11584E+06 -0.11584E+06
MASS FLOW PROFILES
FLOW RATE
LB/HR
LIQUID
VAPOR
0.3099E+06 0.3231E+06
0.3248E+06 0.3808E+06
0.3426E+06 0.4105E+06
0.3475E+06 0.4135E+06
1
2
9
10
MOLE-X2-PROFILE
CO
****
CO2
CH4
0.17240E-01
0.15962E-01
0.16838E-01
0.17495E-01
CH4
0.17240E-01
0.15962E-01
0.16838E-01
0.17495E-01
CH4
0.28021E-04
0.24900E-04
0.26010E-04
0.26867E-04
0.61363E-02
0.50170E-02
0.61188E-02
0.67705E-02
0.17240E-01
0.15962E-01
0.16838E-01
0.17495E-01
CH4
0.16450
0.16501
0.16136
0.16133
CH4
9.5418
10.3377
9.5814
9.2203
WATER
3.3428-02
4.0113-02
3.4691-02
3.2500-02
CH4
MISSING
MISSING
MISSING
MISSING
WATER
MISSING
MISSING
MISSING
MISSING
CH4
MISSING
MISSING
MISSING
MISSING
WATER
MISSING
MISSING
MISSING
MISSING
STAGE
1
2
9
10
CH4O
MISSING
MISSING
MISSING
MISSING
****
K-VALUES: L2-L1
C2H6O-01
MISSING
MISSING
MISSING
MISSING
STAGE
1
2
9
10
H2
0.10318E-07
0.10618E-07
0.92822E-08
0.88930E-08
****
MASS-X-PROFILE
****
N2
CO
CO2
0.52174E-03
0.39375E-04
0.13548E-01
0.45312E-03
0.34090E-04
0.10792E-01
0.45534E-03
0.34382E-04
0.12708E-01
0.46455E-03
0.35138E-04
0.13913E-01
STAGE
1
2
9
10
WATER
0.82466
0.78822
0.73569
0.71725
****
MASS-X-PROFILE
CH4O
C2H6O-01
0.20746E-04
0.14733
0.53725E-04
0.18793
0.84536E-02
0.22991
0.19787E-01
0.23544
STAGE
1
2
9
10
H2
0.10318E-07
0.10618E-07
0.92822E-08
0.88930E-08
****
MASS-X1-PROFILE
****
N2
CO
CO2
0.52174E-03
0.39375E-04
0.13548E-01
0.45312E-03
0.34090E-04
0.10792E-01
0.45534E-03
0.34382E-04
0.12708E-01
0.46455E-03
0.35138E-04
0.13913E-01
STAGE
1
2
9
10
WATER
0.82466
0.78822
0.73569
0.71725
****
MASS-X1-PROFILE
CH4O
C2H6O-01
0.20746E-04
0.14733
0.53725E-04
0.18793
0.84536E-02
0.22991
0.19787E-01
0.23544
STAGE
1
2
9
10
H2
0.10318E-07
0.10618E-07
0.92822E-08
0.88930E-08
****
MASS-X2-PROFILE
****
N2
CO
CO2
0.52174E-03
0.39375E-04
0.13548E-01
0.45312E-03
0.34090E-04
0.10792E-01
0.45534E-03
0.34382E-04
0.12708E-01
0.46455E-03
0.35138E-04
0.13913E-01
STAGE
1
2
9
10
WATER
0.82466
0.78822
0.73569
0.71725
****
MASS-X2-PROFILE
CH4O
C2H6O-01
0.20746E-04
0.14733
0.53725E-04
0.18793
0.84536E-02
0.22991
0.19787E-01
0.23544
H2
0.91189E-01
0.77364E-01
0.71763E-01
0.71251E-01
****
MASS-Y-PROFILE
****
N2
CO
CO2
0.68035E-01
0.41068E-02
0.31099
0.58145E-01
0.35163E-02
0.27487
0.53914E-01
0.32601E-02
0.25472
0.53536E-01
0.32374E-02
0.25352
WATER
0.41667E-01
****
MASS-Y-PROFILE
CH4O
C2H6O-01
0.83731E-05
0.28390
STAGE
1
2
9
10
STAGE
1
2
9
10
****
0.44246E-01
0.35064E-01
0.32196E-01
0.23988E-04
0.32169E-02
0.70112E-02
BLOCK: B2
MODEL: MIXER
----------------------------INLET STREAMS:
S-417
OUTLET STREAM:
S-420
NRTL-RK
CH4
0.13875E-01
0.12516E-01
0.12748E-01
0.13105E-01
****
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
6828.21
182121.
-0.731920E+09
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
CH4
0.13875E-01
0.12516E-01
0.12748E-01
0.13105E-01
RELATIVE DIFF.
6828.21
182121.
-0.731920E+09
0.00000
0.159805E-15
0.00000
***
S-424

IN
17329.7
312494.
-0.207053E+10
***
OUT
RELATIVE DIFF.
17329.7
312494.
-0.207053E+10
0.00000
0.372536E-15
-0.230297E-15
*** INPUT DATA ***

TWO
PHASE
FLASH
***
CH4
0.20010
0.18106
0.16785
0.16691
***
OUT
40
0.000100000
206.200
BLOCK: B5
MODEL: FSPLIT
-----------------------------INLET STREAM:
S-427
OUTLET STREAMS:
S-429B
NRTL-RK
****
****
INPUT DATA
BLOCK: B3
MODEL: MIXER
----------------------------INLET STREAMS:
S-425
OUTLET STREAM:
S-426
NRTL-RK
****
S-419

IN
***
TWO
PHASE
FLASH
OUTLET PRESSURE
PSIA
CH4
0.13875E-01
0.12516E-01
0.12748E-01
0.13105E-01
0.36077
0.41021
0.41233
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
17329.7
312494.
-0.211844E+10
***
MOLE-FLOW
S-428

IN
(LBMOL/HR)
INPUT DATA
RESULTS
***
OUT
RELATIVE DIFF.
17329.7
312494.
-0.211844E+10
0.00000
0.00000
0.00000
***
STRM=S-429B
***
40
0.000100000
***
FLOW=
14,000.0
KEY= 0
ENTHALPY(BTU/HR
STREAM= S-429B
S-428
SPLIT=
0.80786
0.19214
BLOCK: COMP-401 MODEL: COMPR

----------------------------INLET STREAM:
S-410
OUTLET STREAM:
S-309
NRTL-RK
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
KEY=
23763.2
313393.
-0.712343E+09
***
STREAM-ORDER=
INPUT DATA
***
OUT
RELATIVE DIFF.
23763.2
313393.
-0.695507E+09
0.00000
-0.185734E-15
-0.236344E-01
***
ISENTROPIC CENTRIFUGAL COMPRESSOR

295.000
0.72000
1.00000
****
RESULTS
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
-0.329610E-01
****
NUMBER OF STAGES
ALGORITHM OPTION
ABSORBER OPTION
FLASH TOLERANCE
6,616.72
6,616.72
6,616.72
0.0
4,764.04
255.082
232.465
0.72000
1.00000
30,098.9
1.00000
1.32116
803,937.
618,320.
0.99820
1.00073
1.31582
1.30770
1.48052
1.46634
COL-SPECS
16
STANDARD
NO
STANDARD
NO
BROYDEN
NESTED
150
10
40
0.000100000
0.000100000
****

MASS REFLUX RATIO
MASS DISTILLATE RATE
****
PROFILES
P-SPEC
1.00000
30.0000
20,000.0
LB/HR
****
STAGE
PRES, PSIA
205.000
*******************
**** RESULTS ****
*******************
***
S-416
COMPONENT:
H2
N2
CO
CO2
CH4
WATER
CH4O
C2H6O-01
1.0000
.99722
.99648
.91758
.96713
.80898E-11
.20502E-04
.89462E-01
***
OUTLET STREAMS
-------------V
S-417
0.0000
0.0000
0.0000
0.0000
.83142E-12
.99231
.11094E-02
.19717E-01
.26891E-07
.27807E-02
.35196E-02
.82418E-01
.32868E-01
.76890E-02
.99887
.89082

***
***
-0.214776E+10
***
INDICATED HORSEPOWER REQUIREMENT HP

BRAKE
HORSEPOWER REQUIREMENT HP
NET WORK REQUIRED
HP
POWER LOSSES
HP
ISENTROPIC HORSEPOWER REQUIREMENT HP
HEAD DEVELOPED,
FT-LBF/LB
BLOCK: DIST-401 MODEL: RADFRAC
------------------------------INLETS
- S
STAGE
8
OUTLETS - S-416
STAGE
1
V
STAGE 16
S-417
STAGE
4
NRTL-RK
-0.222097E+10
INPUT PARAMETERS
****
***
1
2
**********************
**********************

IN
0
0

IN
19206.2
414074.
***
OUT
19206.2
414074.
RELATIVE DIFF.
0.00000
0.252235E-06

***
F
F
LBMOL/HR
LBMOL/HR
58.4913
384.477
14,137.8
16,146.1

BOILUP VAPOR FLOW
MOLAR REFLUX RATIO
MOLAR BOILUP RATIO
REBOILER DUTY
****
LBMOL/HR
LBMOL/HR
BTU/HR
BTU/HR
DEW POINT
BUBBLE POINT
ENERGY BALANCE
****
PROFILES
661.004
12,297.9
21.3884
0.76166
-0.112521+09
0.185734+09
0.43790E-03
0.57586E-03
0.23815E-05
0.41860E-03
STAGE=
STAGE=
STAGE=
STAGE=
4
4
1 COMP=N2
6
****
1
2
3
4
5
6
7
8
9
15
16
58.491
120.93
134.34
151.07
230.44
311.36
339.63
347.46
364.66
383.86
384.48
ENTHALPY
BTU/LBMOL
LIQUID
VAPOR
PRESSURE
PSIA
205.00
206.00
206.10
206.20
206.30
206.40
206.50
206.60
206.70
207.30
207.40
1
2
3
4
5
6
7
8
9
15
16
FLOW RATE
LBMOL/HR
LIQUID
VAPOR
0.1414E+05 661.0
0.1555E+05 0.1480E+05
0.1503E+05 0.1622E+05
0.1132E+05 0.1569E+05
6324.
0.1199E+05
5852.
9384.
5679.
8912.
0.2940E+05 8739.
0.2924E+05 0.1326E+05
0.2844E+05 0.1234E+05
0.1615E+05 0.1230E+05
-88006.
-71989.
-86877.
-79688.
-86568.
-79331.
-89495.
-78784.
-0.10201E+06 -79139.
-0.10969E+06 -84700.
-0.11248E+06 -88840.
-0.11312E+06 -90226.
-0.11427E+06 -94653.
-0.11669E+06 -0.10123E+06
-0.11678E+06 -0.10147E+06
STAGE
****
MASS FLOW PROFILES
0.5015E+06
0.3172E+06
0.2624E+06
0.2455E+06
0.3316E+06
0.2284E+06
0.2246E+06
.41407+06
.29207+06
FEED RATE
LBMOL/HR
VAPOR
MIXED
STAGE
1
2
3
4
5
6
7
8
9
15
16
H2
0.79998E-13
0.11927E-13
0.14121E-13
0.20707E-13
0.76306E-13
0.20217E-12
0.24900E-12
0.26326E-12
0.82306E-18
0.16150E-50
0.60082E-56
****
MOLE-X-PROFILE
****
N2
CO
CO2
0.38592E-03
0.38959E-04
0.72813E-01
0.17094E-04
0.19011E-05
0.23097E-01
0.84143E-05
0.82270E-06
0.86623E-02
0.81508E-05
0.77976E-06
0.47079E-02
0.59755E-05
0.54609E-06
0.13528E-02
0.42710E-05
0.37414E-06
0.22722E-03
0.35496E-05
0.30673E-06
0.92749E-04
0.33815E-05
0.29114E-06
0.72877E-04
0.28509E-07
0.27734E-08
0.49149E-06
0.71755E-20
0.13976E-20
0.12740E-20
0.56236E-22
0.12265E-22
0.37340E-23
STAGE
1
2
3
4
5
6
7
8
9
15
16
WATER
0.17516E-06
0.16867E-04
0.11482E-02
0.52011E-01
0.42548
0.73770
0.84981
0.87672
0.91816
0.99467
0.99735
****
MOLE-X-PROFILE
****
CH4O
C2H6O-01
0.55989E-03
0.81083
0.44583E-02
0.94624
0.26352E-01
0.95575
0.13835
0.80018
0.22714
0.34348
0.95043E-01
0.16559
0.31699E-01
0.11730
0.16432E-01
0.10574
0.84679E-02
0.73318E-01
0.64622E-04
0.52645E-02
0.22832E-04
0.26315E-02
STAGE
1
2
3
4
5
6
7
8
9
15
16
H2
0.27948E-05
0.12483E-06
0.11393E-06
0.11774E-06
0.15414E-06
0.19686E-06
0.20728E-06
0.21140E-06
0.58391E-12
0.10090E-44
0.37354E-50
****
MOLE-Y-PROFILE
****
N2
CO
CO2
0.10609E-01
0.80125E-03
0.19023
0.84254E-03
0.73007E-04
0.78058E-01
0.44886E-03
0.34487E-04
0.29910E-01
0.45498E-03
0.34543E-04
0.16311E-01
0.59280E-03
0.44927E-04
0.14940E-01
0.75337E-03
0.57005E-04
0.15515E-01
0.79183E-03
0.59882E-04
0.15525E-01
0.80701E-03
0.61021E-04
0.15742E-01
0.75003E-05
0.64575E-06
0.16164E-03
0.21030E-17
0.36552E-18
0.97260E-18
0.16522E-19
0.32164E-20
0.29418E-20
STAGE
1
2
3
4
5
6
7
8
WATER
0.19861E-09
0.16734E-06
0.16179E-04
0.10999E-02
0.49143E-01
0.30004
0.49841
0.56651
****
MOLE-Y-PROFILE
CH4O
C2H6O-01
0.10306E-04
0.29165
0.53534E-03
0.78764
0.42770E-02
0.91956
0.25243E-01
0.92778
0.13072
0.77213
0.18844
0.45659
0.99651E-01
0.34576
0.58580E-01
0.31796
HEAT DUTY
BTU/HR
-.11252+09
.18573+09
PRODUCT RATE
LBMOL/HR
LIQUID
VAPOR
661.0042
2399.0376
.19206+05
.16146+05
****
STAGE
1
2
3
4
FLOW RATE
LB/HR
LIQUID
VAPOR
0.6000E+06 0.2000E+05
0.7026E+06 0.6200E+06
0.6824E+06 0.7226E+06
0.4815E+06 0.7024E+06
LIQUID
0.1952E+06
0.1404E+06
0.1235E+06
0.6237E+06
0.5904E+06
0.5167E+06
0.2921E+06
****
STAGE TEMPERATURE
F
5
6
7
8
9
15
16
LIQUID
FEED RATE
LB/HR
VAPOR
MIXED
PRODUCT RATE
LB/HR
LIQUID
VAPOR
.20000+05
.10200+06
****
CH4
0.11537
0.26168E-01
0.80758E-02
0.47447E-02
0.25313E-02
0.14275E-02
0.10967E-02
0.10225E-02
0.50283E-04
0.41457E-12
0.17833E-13
CH4
0.50669
0.13285
0.45756E-01
0.29081E-01
0.32428E-01
0.38609E-01
0.39794E-01
0.40342E-01
0.22679E-02
0.21666E-10
0.93545E-12
9
15
16
0.72981
0.98224
0.99116
0.36419E-01
0.33662E-03
0.11949E-03
STAGE
1
2
3
4
5
6
7
8
9
15
16
H2
0.34939E+08
0.10465E+08
0.80698E+07
0.56981E+07
0.20202E+07
0.97432E+06
0.83260E+06
0.80330E+06
0.70942E+06
0.62475E+06
0.62172E+06
****
K-VALUES
N2
CO
27.490
20.567
49.288
38.401
53.349
41.921
55.855
44.325
99.195
82.262
176.38
152.35
223.06
195.21
238.67
209.61
263.07
232.83
293.08
261.53
293.80
262.25
****
CO2
2.6126
3.3794
3.4532
3.4677
11.033
68.114
167.37
216.05
328.98
763.41
787.84
WATER
0.11339E-02
0.99223E-02
0.14090E-01
0.21138E-01
0.11551
0.40674
0.58650
0.64616
0.79485
0.98750
0.99380
****
K-VALUES
CH4O
C2H6O-01
0.18409E-01
0.35970
0.12009
0.83238
0.16231
0.96215
0.18243
1.1601
0.57511
2.2488
1.9808
2.7592
3.1425
2.9484
3.5647
3.0075
4.3005
3.1553
5.2091
3.3105
5.2335
3.3143
****
STAGE
1
2
3
4
5
6
7
8
9
15
16
STAGE
1
2
3
4
5
6
7
8
9
15
16
H2
0.37999E-14
0.53224E-15
0.62690E-15
0.98181E-15
0.49833E-14
0.16984E-13
0.23078E-13
0.25019E-13
0.82176E-19
0.17924E-51
0.66956E-57
****
MASS-X-PROFILE
****
N2
CO
CO2
0.25474E-03
0.25713E-04
0.75508E-01
0.10601E-04
0.11788E-05
0.22502E-01
0.51912E-05
0.50750E-06
0.83958E-02
0.53704E-05
0.51371E-06
0.48732E-02
0.54230E-05
0.49554E-06
0.19287E-02
0.49858E-05
0.43671E-06
0.41671E-03
0.45716E-05
0.39501E-06
0.18767E-03
0.44658E-05
0.38444E-06
0.15120E-03
0.39555E-07
0.38475E-08
0.10713E-05
0.11066E-19
0.21552E-20
0.30869E-20
0.87088E-22
0.18991E-22
0.90845E-23
WATER
0.74353E-07
0.67267E-05
0.45557E-03
0.22038E-01
0.24832
0.55381
0.70386
0.74459
0.81923
0.98653
0.99326
****
MASS-X-PROFILE
****
CH4O
C2H6O-01
0.42273E-03
0.88018
0.31624E-02
0.96502
0.18596E-01
0.96969
0.10426
0.86703
0.23578
0.51264
0.12691
0.31790
0.46697E-01
0.24844
0.24822E-01
0.22966
0.13438E-01
0.16729
0.11400E-03
0.13352E-01
0.40442E-04
0.67017E-02
STAGE
1
2
3
4
5
6
7
8
9
15
16
0.23134
0.17428E-01
0.87214E-02
CH4
4.3919
5.0769
5.6661
6.1322
12.809
27.041
36.281
39.456
45.101
52.261
52.457
CH4
0.43614E-01
0.92933E-02
0.28533E-02
0.17903E-02
0.13156E-02
0.95431E-03
0.80888E-03
0.77331E-03
0.39953E-04
0.36616E-12
0.15815E-13
STAGE
1
2
3
4
5
6
7
8
9
15
16
H2
0.18620E-06
0.60065E-08
0.51536E-08
0.53015E-08
0.74263E-08
0.11740E-07
0.14190E-07
0.15168E-07
0.47054E-13
0.10989E-45
0.41235E-51
****
MASS-Y-PROFILE
****
N2
CO
CO2
0.98223E-02
0.74176E-03
0.27670
0.56337E-03
0.48811E-04
0.81998E-01
0.28216E-03
0.21676E-04
0.29538E-01
0.28470E-03
0.21612E-04
0.16035E-01
0.39689E-03
0.30077E-04
0.15714E-01
0.62434E-03
0.47237E-04
0.20199E-01
0.75329E-03
0.56962E-04
0.23204E-01
0.80466E-03
0.60837E-04
0.24659E-01
0.83991E-05
0.72305E-06
0.28437E-03
0.31829E-17
0.55316E-18
0.23126E-17
0.25346E-19
0.49335E-20
0.70897E-20
STAGE
1
2
3
4
5
6
7
8
9
15
16
WATER
0.11825E-09
0.71958E-07
0.65405E-05
0.44260E-03
0.21159E-01
0.15991
0.30493
0.36326
0.52557
0.95604
0.97779
****
MASS-Y-PROFILE
****
CH4O
C2H6O-01
0.10914E-04
0.44407
0.40944E-03
0.86611
0.30752E-02
0.95060
0.18067E-01
0.95473
0.10011
0.85016
0.17863
0.62227
0.10844
0.54094
0.66810E-01
0.52137
0.46648E-01
0.42603
0.58275E-03
0.43378E-01
0.20966E-03
0.22002E-01
BLOCK: FV-401
MODEL: FLASH2
-----------------------------INLET STREAM:
S-405
S-407
OUTLET LIQUID STREAM: K
NRTL-RK
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
***
TWO
PHASE PV FLASH
SPECIFIED PRESSURE
PSIA
VAPOR FRACTION
OUTLET TEMPERATURE
OUTLET PRESSURE
HEAT DUTY
VAPOR FRACTION

IN
29781.7
483548.
-0.116781E+10
INPUT DATA
*** RESULTS
F
PSIA
BTU/HR
CH4
0.26866
0.50873E-01
0.16472E-01
0.10421E-01
0.12434E-01
0.18324E-01
0.21680E-01
0.23036E-01
0.14544E-02
0.18779E-10
0.82179E-12
***
OUT
RELATIVE DIFF.
29704.3
484946.
-0.124388E+10
0.259760E-02
-0.288181E-02
0.611537E-01
***
230.000
0.90000
40
0.000100000
***
167.08
230.00
-0.70911E+08
0.90000
COMP
H2
N2
CO
CO2
CH4
WATER
CH4O
C2H6O-01
F(I)
0.49502
0.26752E-01
0.16084E-02
0.80791E-01
0.14651
0.99527E-01
0.11088E-01
0.13870
BLOCK: FV-402
MODEL: FLASH2
-----------------------------INLET STREAM:
S-422
S-423
OUTLET LIQUID STREAM: 9
NRTL-RK
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
X(I)
0.10549E-06
0.42597E-03
0.32071E-04
0.91214E-02
0.20950E-01
0.80280
0.39506E-01
0.12717
9505.71
171953.
-0.111003E+10
*** INPUT DATA

TWO
PHASE PQ FLASH
SPECIFIED PRESSURE
PSIA
SPECIFIED HEAT DUTY
BTU/HR
OUTLET TEMPERATURE
OUTLET PRESSURE
VAPOR FRACTION
***
F
PSIA
K(I)
0.52143E+07
69.669
55.613
9.7304
7.6593
0.26640E-01
0.20074
1.1008

IN
Y(I)
0.55003
0.29677E-01
0.17835E-02
0.88754E-01
0.16046
0.21387E-01
0.79306E-02
0.13998
RESULTS
***
OUT
RELATIVE DIFF.
9505.71
171953.
-0.111003E+10
0.00000
0.169255E-15
-0.949627E-07
F(I)
0.17833E-13
0.99735
0.22832E-04
0.26315E-02
BLOCK: HX-401
MODEL: HEATX
----------------------------HOT SIDE:
S-404
OUTLET STREAM:
S-405
NRTL-RK
COLD SIDE:
S-402
OUTLET STREAM:
S-403
NRTL-RK
***
)
***
IN
OUT
RELATIVE DIFF.
69023.3
967131.
-0.205049E+10
69023.3
967131.
-0.205049E+10
0.00000
-0.120372E-15
0.00000
INPUT DATA
***

TWO
PHASE
FLASH
40
0.000100000

TWO
PHASE
FLASH
40
0.000100000
FLOW DIRECTION AND SPECIFICATION:

COUNTERCURRENT
HEAT EXCHANGER
SPECIFIED HOT APPROACH TEMP
SPECIFIED VALUE
F
TEMPERATURE TOLERANCE
F
50.0000
0.01800
1.00000
***
50.0000
0.0
40
0.000100000
***
280.46
50.000
0.13424

COMP
CH4
WATER
CH4O
C2H6O-01
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
X(I)
0.12509E-14
0.99871
0.13046E-04
0.12724E-02
Y(I)
0.12477E-12
0.98852
0.85944E-04
0.11397E-01
***
K(I)
99.751
0.98979
6.5879
8.9579
PRESSURE SPECIFICATION:
HOT SIDE PRESSURE DROP
COLD SIDE PRESSURE DROP
PSI
PSI
5.0000
5.0000
HEAT TRANSFER COEFFICIENT SPECIFICATION:

HOT LIQUID
COLD LIQUID
BTU/HR-SQFT-R
HOT 2-PHASE
COLD LIQUID
BTU/HR-SQFT-R
HOT VAPOR
COLD LIQUID
BTU/HR-SQFT-R
HOT LIQUID
COLD 2-PHASE
BTU/HR-SQFT-R
HOT 2-PHASE
COLD 2-PHASE
BTU/HR-SQFT-R
HOT VAPOR
COLD 2-PHASE
BTU/HR-SQFT-R
HOT LIQUID
COLD VAPOR
BTU/HR-SQFT-R
HOT 2-PHASE
COLD VAPOR
BTU/HR-SQFT-R
HOT VAPOR
COLD VAPOR
BTU/HR-SQFT-R
***
OVERALL RESULTS
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
***
STREAMS:
-------------------------------------|
|
S-404
----->|
HOT
|----->
T= 5.3600D+02 |
|
P= 2.4000D+02 |
|
V= 1.0000D+00 |
|
|
|
S-403
<-----|
COLD
|<----T= 4.6545D+02 |
|
P= 2.6500D+02 |
|
V= 1.0000D+00 |
|
-------------------------------------DUTY AND AREA:
BTU/HR
SQFT
SQFT
S-405
T= 2.5049D+02
P= 2.3500D+02
V= 1.0000D+00
S-402
T= 2.0049D+02
P= 2.7000D+02
V= 1.0000D+00
86283469.4025
9657.3747
9657.3747
0.0000

UA (DIRTY)
BTU/HR-SQFT-R
BTU/HR-R
1.0000
59.6850
1
PSI
PSI
5.0000
5.0000
PRESSURE DROP PARAMETER:

HOT SIDE:
COLD SIDE:
***
63.000
57.305
ZONE RESULTS
***
TEMPERATURE LEAVING EACH ZONE:

HOT
------------------------------------------------------------|
|
S-404
|
VAP
| S-405
------> |
|------>
536.0 |
| 250.5
|
|
S-403
|
VAP
| S-402
<------ |
|<-----465.5 |
| 200.5
|
|
------------------------------------------------------------COLD
0.201606E+07
-0.136640E+11
)
***
149.6937
1445647.7309
LOG-MEAN TEMPERATURE DIFFERENCE:

LMTD (CORRECTED)
F
PRESSURE DROP:
HOTSIDE, TOTAL
COLDSIDE, TOTAL
MASS(LB/HR
)
ENTHALPY(BTU/HR
INPUT DATA
0.201606E+07
-0.136640E+11
0.00000
0.139589E-15
***

TWO
PHASE
FLASH
40
0.000100000

TWO
PHASE
FLASH
40
0.000100000

COUNTERCURRENT
HEAT EXCHANGER
SPECIFIED COLD OUTLET TEMP
SPECIFIED VALUE
F
120.0000
1.00000
PSI
PSI
0.0000
0.0000

HOT LIQUID
COLD LIQUID
BTU/HR-SQFT-R
HOT 2-PHASE
COLD LIQUID
BTU/HR-SQFT-R
HOT VAPOR
COLD LIQUID
BTU/HR-SQFT-R
HOT LIQUID
COLD 2-PHASE
BTU/HR-SQFT-R
HOT 2-PHASE
COLD 2-PHASE
BTU/HR-SQFT-R
HOT VAPOR
COLD 2-PHASE
BTU/HR-SQFT-R
HOT LIQUID
COLD VAPOR
BTU/HR-SQFT-R
HOT 2-PHASE
COLD VAPOR
BTU/HR-SQFT-R
HOT VAPOR
COLD VAPOR
BTU/HR-SQFT-R
***
OVERALL RESULTS
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
***
ZONE HEAT TRANSFER AND AREA:

STREAMS:
ZONE
1
HEAT DUTY
BTU/HR
86283469.402
AREA
SQFT
9657.3747
BLOCK: HX-403
MODEL: HEATX
----------------------------HOT SIDE:
S-426
OUTLET STREAM:
S-427
NRTL-RK
COLD SIDE:
CW-403
OUTLET STREAM:
CW-404
NRTL-RK
***
TOTAL BALANCE
MOLE(LBMOL/HR)
LMTD
F
59.6850
AVERAGE U
UA
BTU/HR-SQFT-R
BTU/HR-R
149.6937
1445647.7309
DUTY AND AREA:


IN
111892.
***
OUT
111892.
-------------------------------------|
|
S-426
----->|
HOT
|----->
T= 2.6048D+02 |
|
P= 5.5000D+01 |
|
V= 0.0000D+00 |
|
|
|
CW-404
<-----|
COLD
|<----T= 1.2000D+02 |
|
P= 5.0000D+01 |
|
V= 0.0000D+00 |
|
--------------------------------------
BTU/HR
SQFT
SQFT
S-427
T= 1.1000D+02
P= 5.5000D+01
V= 0.0000D+00
CW-403
T= 9.0000D+01
P= 5.0000D+01
V= 0.0000D+00
47911898.5352
5179.0246
5179.0246
0.0000
RELATIVE DIFF.
0.00000

BTU/HR-SQFT-R
149.6937
UA (DIRTY)
BTU/HR-R
775267.1282

LMTD (CORRECTED)
F
PRESSURE DROP:
HOTSIDE, TOTAL
COLDSIDE, TOTAL
1.0000
61.8005
1
PSI
PSI
0.0000
0.0000

HOT SIDE:
COLD SIDE:
***
0.0000
0.0000
ZONE RESULTS
***

HOT
------------------------------------------------------------|
|
S-426
|
LIQ
| S-427
------> |
|------>
260.5 |
| 110.0
|
|
CW-404 |
LIQ
| CW-403
<------ |
|<-----120.0 |
|
90.0
|
|
------------------------------------------------------------COLD
ZONE
1
HEAT DUTY
BTU/HR
47911898.535
AREA
SQFT
5179.0246
BLOCK: MCR-401 MODEL: RSTOIC

-----------------------------INLET STREAM:
S-305
OUTLET STREAM:
S-404
OUTLET HEAT STREAM:
Q-301
NRTL-RK
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
LMTD
F
61.8005

IN
OUT
39241.6
29781.7
483583.
483548.
-0.882682E+09 -0.882627E+09
***
AVERAGE U
UA
BTU/HR-SQFT-R
BTU/HR-R
149.6937
775267.1282
INPUT DATA
***
GENERATION
-9460.29
:
CO
:
CO2
-1.00
WATER
1.00
REACTION #
3:
SUBSTREAM MIXED
WATER
1.00
:
CH4O
-2.00
C2H6O-01
1.00
REACTION #
4:
SUBSTREAM MIXED
H2
1.00
:
CO
-1.00
CO2
1.00
REACTION CONVERSION SPECS: NUMBER=

REACTION #
1:
SUBSTREAM:MIXED
KEY COMP:CO
REACTION #
2:
SUBSTREAM:MIXED
KEY COMP:CO2
REACTION #
4:
SUBSTREAM:MIXED
KEY COMP:CO
1.00
WATER
-1.00
3
CONV FRAC: 0.9550
CONV FRAC: 0.6500E-01
CONV FRAC: 0.3500E-01
REACTION EXTENT SPECS: NUMBER=

1
REACTION #
3: EXTENT=
2200.
LBMOL/HR
TWO
PHASE TP FLASH
SPECIFIED TEMPERATURE F
SPECIFIED PRESSURE
PSIA
SIMULTANEOUS REACTIONS
GENERATE COMBUSTION REACTIONS FOR FEED SPECIES
OUTLET TEMPERATURE
OUTLET PRESSURE
HEAT DUTY
VAPOR FRACTION
CH4O
*** RESULTS
F
PSIA
BTU/HR
536.000
240.000
40
0.000100000
NO
***
536.00
240.00
-0.19890E+09
1.0000
REACTION EXTENTS:
RELATIVE DIFF.
-0.867647E-05
0.722147E-04
-0.621258E-04
REACTION
NUMBER
1
2
3
4
REACTION
EXTENT
LBMOL/HR
4574.5
155.62
2200.0
167.65
***
STOICHIOMETRY MATRIX:
REACTION #
1:
SUBSTREAM MIXED
H2
-2.00
REACTION #
2:
SUBSTREAM MIXED
H2
-3.00
-1.00
CH4O
1.00
COMP
H2
N2
CO
F(I)
0.49498
0.26752E-01
0.16084E-02
X(I)
0.35013E-04
0.88082E-03
0.56055E-04
Y(I)
0.49498
0.26752E-01
0.16084E-02
K(I)
0.19992E+06
429.51
405.78
CO2
CH4
WATER
CH4O
C2H6O-01
0.80794E-01
0.14654
0.99521E-01
0.11088E-01
0.13872
BLOCK: MIX-301 MODEL: MIXER

----------------------------INLET STREAMS:
S-411
OUTLET STREAM:
S-402
NRTL-RK
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
0.89265E-02
0.20220E-01
0.41785
0.21289E-01
0.53074
39241.6
483583.
-0.968966E+09
***
TWO
PHASE
FLASH
OUTLET PRESSURE
PSIA
128.09
102.49
3.3681
7.3659
3.6961
S-401

IN
0.80794E-01
0.14654
0.99521E-01
0.11088E-01
0.13872
INPUT DATA
***
OUT
RELATIVE DIFF.
39241.6
483583.
-0.968966E+09
0.00000
0.120367E-15
-0.246055E-15
***
40
0.000100000
270.000
NO FLASH PERFORMED
TOLERANCE
*** RESULTS
PRESSURE CHANGE PSI
NPSH AVAILABLE
FT-LBF/LB
FLUID POWER HP
BRAKE POWER HP
ELECTRICITY KW
BLOCK: PUMP-402 MODEL: PUMP
---------------------------INLET STREAM:
W
OUTLET STREAM:
S-413
NRTL-RK
***
BLOCK: MIX-401 MODEL: MIXER

----------------------------INLET STREAMS:
S-413
OUTLET STREAM:
S-414
NRTL-RK
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
19206.2
414074.
-0.222103E+10
***
TWO
PHASE
FLASH
OUTLET PRESSURE
PSIA
INPUT DATA
19206.2
414074.
-0.222103E+10
0.00000
-0.140573E-15
0.214692E-15
***
2978.17
66524.4
-0.341218E+09
)
***
PRESSURE CHANGE PSI

DRIVER EFFICIENCY
RELATIVE DIFF.

IN
INPUT DATA
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
***
OUT
RELATIVE DIFF.
2978.17
66524.4
-0.341216E+09
0.00000
-0.218746E-15
-0.590303E-05
***
1,294.92
5.00000
0.0
0.47088
0.79162
0.59031
0.59483
0.79162
14.0151

IN
16228.0
347550.
-0.187982E+10
)
***
***
OUT
40
0.000100000
201.800

---------------------------INLET STREAM:
K
OUTLET STREAM:
S-412
NRTL-RK
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR

IN
***
S-412
40
0.000100000
INPUT DATA
***
OUT
RELATIVE DIFF.
16228.0
347550.
-0.187981E+10
0.00000
0.00000
-0.430313E-05
***
PRESSURE CHANGE PSI

DRIVER EFFICIENCY
5.00000
1.00000
NO FLASH PERFORMED
TOLERANCE
40
0.000100000
*** RESULTS
PRESSURE CHANGE PSI
NPSH AVAILABLE
FT-LBF/LB
FLUID POWER HP
BRAKE POWER HP
ELECTRICITY KW
---------------------------INLET STREAM:
S-414
OUTLET STREAM:
S-415
NRTL-RK
***
6,606.27
5.00000
0.11970
2.40228
3.17914
2.37068
0.75564
3.17914
13.6859
***
5.00000
1.00000
***

IN
***
OUT
RELATIVE DIFF.
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR

19206.2
414074.
-0.222103E+10
)
***
INPUT DATA
19206.2
414074.
-0.222097E+10
0.00000
0.00000
-0.265203E-04
***

PUMP EFFICIENCY
DRIVER EFFICIENCY
230.000
0.70000
1.00000
NO FLASH PERFORMED
TOLERANCE
40
0.000100000

---------------------------INLET STREAM:
9
OUTLET STREAM:
S-424
NRTL-RK
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
***
VOLUMETRIC FLOW RATE

7,901.19
PRESSURE CHANGE PSI
28.2000
NPSH AVAILABLE
FT-LBF/LB
-11.9881
FLUID POWER HP
16.2046
BRAKE POWER HP
23.1495
ELECTRICITY KW
17.2626
0.70000
23.1495
77.4866
NEGATIVE NPSH MAY BE DUE TO VAPOR IN THE FEED OR UNACCOUNTED SUCTION HEAD.
---------------------------INLET STREAM:
V
OUTLET STREAM:
S-418
NRTL-RK
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR

IN
16146.1
292074.
-0.188548E+10
)
***
INPUT DATA
***
OUT
RELATIVE DIFF.
16146.1
292074.
-0.188547E+10
0.00000
-0.199291E-15
-0.382608E-05
8229.65
148555.
-0.979773E+09
5.00000
1.00000
RELATIVE DIFF.
8229.65
148555.
-0.979769E+09
0.00000
-0.195913E-15
-0.379698E-05
***
PRESSURE CHANGE PSI

DRIVER EFFICIENCY
5.00000
1.00000
NO FLASH PERFORMED
TOLERANCE
40
0.000100000
*** RESULTS
PRESSURE CHANGE PSI
NPSH AVAILABLE
FT-LBF/LB
FLUID POWER HP
BRAKE POWER HP
ELECTRICITY KW
---------------------------INLET STREAM:
S-429
OUTLET STREAM:
R
NRTL-RK
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
NO FLASH PERFORMED
TOLERANCE

PRESSURE CHANGE PSI
NPSH AVAILABLE
FT-LBF/LB
FLUID POWER HP
BRAKE POWER HP
ELECTRICITY KW
INPUT DATA
***
OUT
***
2,717.52
5.00000
0.0
0.98819
1.46208
1.09028
0.67588
1.46208
13.1710
***
PRESSURE CHANGE PSI

DRIVER EFFICIENCY
*** RESULTS
CUFT/HR

IN
***
*** RESULTS
CUFT/HR
14.3246
5,810.88
5.00000
0.0
2.11305
2.83521
2.11421
0.74529
2.83521
14000.0
252214.
-0.171172E+10
40
0.000100000
***

IN
***
INPUT DATA

PUMP EFFICIENCY
DRIVER EFFICIENCY
NO FLASH PERFORMED
TOLERANCE
***
OUT
RELATIVE DIFF.
14000.0
252214.
-0.171152E+10
0.00000
0.00000
-0.121453E-03
***
230.000
0.70000
1.00000
40
0.000100000
*** RESULTS
PRESSURE CHANGE PSI
NPSH AVAILABLE
FT-LBF/LB
FLUID POWER HP
BRAKE POWER HP
ELECTRICITY KW
BLOCK: SPLT-401 MODEL: FSPLIT
-----------------------------INLET STREAM:
S-418
OUTLET STREAMS:
S-422
NRTL-RK
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
***
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
16146.1
292074.
-0.188547E+10
***
OUT
39241.6
483583.
-0.882682E+09
VALVE PRESSURE DROP

RELATIVE DIFF.
16146.1
292074.
-0.188547E+10
INPUT DATA
(LB/HR
***
STRM=S-419
FRAC=
STRM=S-421
FLOW=
RESULTS
0.27432
SPLIT=
2
40
0.000100000
***
PSIA
240.000
40,000.0
KEY= 0
***
KEY=
0
0
0
STREAM-ORDER=
3
1
2
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR

IN
23763.2
313393.
-0.695507E+09
)
***
S-410

IN
24498.2
323085.
-0.734374E+09
***
OUT
RELATIVE DIFF.
24498.2
323085.
-0.734374E+09
0.00000
0.00000
-0.162328E-15
VALVE PRESSURE DROP

INPUT DATA
SPLIT=
RESULTS
0.00000
0.00000
0.00000
25.0000
NO
RESULTS
2
40
0.000100000
***
***
STRM=S-409
***
RELATIVE DIFF.
***
NPHASE

FRACTION OF FLOW
INPUT DATA
***
OUT
23763.2
313393.
-0.695507E+09
PSI
***
***
***
0.58873
0.27432
0.13695
BLOCK: SPLT-402 MODEL: FSPLIT

-----------------------------INLET STREAM:
S-408
OUTLET STREAMS:
S-409
NRTL-RK
STREAM= S-409
S-410
25.0000
NO
RESULTS
BLOCK: VALV-302 MODEL: VALVE

----------------------------INLET STREAM:
S-309
OUTLET STREAM:
S-411
NRTL-RK
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
***
207.400
STREAM= S-422
S-419
S-421
0.00000
0.00000
0.405160E-15
***
PSIA
FRACTION OF FLOW
MASS-FLOW
RELATIVE DIFF.
39241.6
483583.
-0.882682E+09
NPHASE
0.00000
0.00000
0.00000

OUTLET PRESSURE
INPUT DATA
***
OUT
PSI
***
***

IN
***
S-419
S-421

IN

----------------------------INLET STREAM:
S-403
OUTLET STREAM:
S-305
NRTL-RK
4,139.03
190.000
91.5088
57.1939
81.7056
60.9278
0.70000
81.7056
449.000
FRAC=
***
0.030000
0.97000
KEY=
PSIA
270.000
0.030000
0
0
STREAM-ORDER=
1
2

----------------------------INLET STREAM:
S-407
OUTLET STREAM:
Q
NRTL-RK
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR

IN
26726.2
418421.
-0.902661E+09
)
***
VALVE PRESSURE DROP

INPUT DATA
***
OUT
RELATIVE DIFF.
26726.2
418421.
-0.902661E+09
0.00000
0.00000
-0.132064E-15
***
PSI
25.0000
NO
***
VALVE PRESSURE DROP
INPUT DATA
***
PSI
25.0000
NO
NPHASE
***
RESULTS
2
40
0.000100000
***
NPHASE
2
40
0.000100000
PSIA
205.000
STREAM Results:
***
RESULTS
PSIA

----------------------------INLET STREAM:
S-415
OUTLET STREAM:
S
NRTL-RK
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
***
205.000
STREAM ID
FROM :
TO
:

IN
19206.2
414074.
-0.222097E+10
)
***
VALVE PRESSURE DROP

INPUT DATA
***
OUT
25.0000
NO
RESULTS
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
2
40
0.000100000
***
PSIA

----------------------------INLET STREAM:
R
OUTLET STREAM:
S-430
NRTL-RK
0.00000
0.00000
0.00000
***
NPHASE
RELATIVE DIFF.
19206.2
414074.
-0.222097E+10
PSI
***
9 CW-403 CW-404 K Q
-------------------
205.000

IN
14000.0
252214.
-0.171152E+10
***
OUT
14000.0
252214.
-0.171152E+10
RELATIVE DIFF.
0.00000
0.00000
0.00000
9
FV-402
PUMP-405
CW-403
---HX-403
CW-404
HX-403
----
K
FV-401
PUMP-401
Q
VALV-401
ABS-401
SUBSTREAM: MIXED
PHASE:
LIQUID
LIQUID
LIQUID
LIQUID
VAPOR
H2
0.0
0.0
0.0
3.1415-04 1.4615+04
N2
0.0
0.0
0.0
1.2686
790.4210
CO
0.0
0.0
0.0
9.5512-02
47.8061
CO2
0.0
0.0
0.0
27.1649 2392.9258
CH4
1.0294-11
0.0
0.0
62.3934 4313.8183
WATER
8219.0753 9.4562+04 9.4562+04 2390.8590
584.4347
CH4O
0.1074
0.0
0.0
117.6567
214.7047
C2H6O-01
10.4711
0.0
0.0
378.7296 3767.2108
C10H2-01
0.0
0.0
0.0
0.0
0.0
HEXANE
0.0
0.0
0.0
0.0
0.0
C4H8O-01
0.0
0.0
0.0
0.0
0.0
NBUTANOL
0.0
0.0
0.0
0.0
0.0
C12H2-01
0.0
0.0
0.0
0.0
0.0
ARGON
0.0
0.0
0.0
0.0
0.0
TOTAL FLOW:
LBMOL/HR
8229.6538 9.4562+04 9.4562+04 2978.1680 2.6726+04
LB/HR
1.4855+05 1.7036+06 1.7036+06 6.6524+04 4.1842+05
CUFT/HR
2717.5181 2.7649+04 2.8115+04 1294.9243 8.7188+05
STATE VARIABLES:
TEMP
F
280.4639
90.0000
120.0000
167.0815
167.4211
PRES
PSIA
50.0000
50.0000
50.0000
230.0000
205.0000
VFRAC
0.0
0.0
0.0
0.0
1.0000
LFRAC
1.0000
1.0000
1.0000
1.0000
0.0
SFRAC
0.0
0.0
0.0
0.0
0.0
ENTHALPY:
BTU/LBMOL
-1.1905+05 -1.2260+05 -1.2209+05 -1.1457+05 -3.3774+04
BTU/LB
-6595.3620 -6805.4255 -6777.3009 -5129.2153 -2157.3026
BTU/HR
-9.7977+08 -1.1593+10 -1.1546+10 -3.4122+08 -9.0266+08
ENTROPY:
BTU/LBMOL-R
-33.0716
-38.4593
-37.5661
-40.0640
-12.7681
BTU/LB-R
-1.8321
-2.1348
-2.0852
-1.7936
-0.8155
DENSITY:
LBMOL/CUFT
LB/CUFT
AVG MW
3.0284
54.6656
18.0512
MIXED
SUBSTREAM PROPERTIES:
*** ALL
MASSVFRA
MASSFLMX
HMX
RHOMX
CPMX
PCMX
MWMX
PHASES
3.4201
61.6141
18.0153
3.3634
60.5929
18.0153
2.2999
51.3732
22.3373
3.0654-02
0.4799
15.6559
***
KG/SEC
J/KG
KG/CUM
J/KG-K
N/SQM
0.0
0.0
0.0
0.0
1.0000
18.7176
214.6451
214.6451
8.3819
52.7202
-1.5341+07 -1.5829+07 -1.5764+07 -1.1931+07 -5.0179+06
875.6590
986.9629
970.6055
822.9194
7.6874
4659.4344 3867.8055 3983.5355 3834.9701 2451.2826
2.2043+07 2.2064+07 2.2064+07 1.8880+07 3.5325+06
18.0512
18.0153
18.0153
22.3373
15.6559
*** VAPOR PHASE

***
RHOMX
LB/CUFT
KG/CUM
MUMX
CP
N-SEC/SQM
MASSFLMX KG/SEC
HMX
J/KG
CPMX
J/KG-K
PCMX
N/SQM
KMX
WATT/M-K
MWMX
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
0.4799
MISSING
7.6874
MISSING 1.4236-02
MISSING 1.4236-05
MISSING
52.7202
MISSING -5.0179+06
MISSING 2451.2826
MISSING 3.5325+06
MISSING 8.6653-02
MISSING
15.6559
*** LIQUID PHASE ***

RHOMX
LB/CUFT
54.6656
61.6141
60.5929
51.3732
KG/CUM
875.6590
986.9629
970.6055
822.9194
MUMX
CP
0.1960
0.7827
0.5705
0.2685
N-SEC/SQM
1.9597-04 7.8270-04 5.7050-04 2.6849-04
SIGMAMX DYNE/CM
50.6961
71.2679
68.0492
51.9493
N/M
5.0696-02 7.1268-02 6.8049-02 5.1949-02
MASSFLMX KG/SEC
18.7176
214.6451
214.6451
8.3819
HMX
J/KG
-1.5341+07 -1.5829+07 -1.5764+07 -1.1931+07
CPMX
J/KG-K
4659.4344 3867.8055 3983.5355 3834.9701
PCMX
N/SQM
2.2043+07 2.2064+07 2.2064+07 1.8880+07
KMX
WATT/M-K
0.6253
0.6161
0.6362
0.1855
MWMX
18.0512
18.0153
18.0153
22.3373
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
R S S-305 S-309 S-401

--------------------STREAM ID
FROM :
TO
:
SUBSTREAM: MIXED
PHASE:
H2
N2
CO
CO2
CH4
WATER
CH4O
C2H6O-01
C10H2-01
R
PUMP-406
VALV-404
S
VALV-402
DIST-401
S-305
VALV-301
MCR-401
S-309
COMP-401
VALV-302
S-401
---MIX-301
LIQUID
MIXED
VAPOR
VAPOR
MIXED
0.0
0.0
0.0
0.0
0.0
1.4000+04
0.0
0.0
0.0
1.8474-03
7.0320
0.5315
137.0373
346.3077
1.6228+04
332.2768
2154.9372
0.0
2.4189+04
796.7185
4790.0829
2394.1122
4364.0735
775.9163
8.1894-02
1931.2728
0.0
1.4176+04
761.1182
45.9490
2214.5626
3909.0081
724.8376
8.1894-02
1931.2728
0.0
1.0013+04
35.6004
4744.1339
179.5496
455.0654
51.0788
0.0
0.0
0.0
HEXANE
C4H8O-01
NBUTANOL
C12H2-01
ARGON
TOTAL FLOW:
LBMOL/HR
LB/HR
CUFT/HR
STATE VARIABLES:
TEMP
F
PRES
PSIA
VFRAC
LFRAC
SFRAC
ENTHALPY:
BTU/LBMOL
BTU/LB
BTU/HR
ENTROPY:
BTU/LBMOL-R
BTU/LB-R
DENSITY:
LBMOL/CUFT
LB/CUFT
AVG MW
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
1.4000+04
2.5221+05
4139.8524
1.9206+04
4.1407+05
7902.1970
3.9242+04
4.8358+05
1.6308+06
2.3763+04
3.1339+05
6.1832+05
1.5478+04
1.7019+05
3.1175+05
110.3534
230.0000
0.0
1.0000
0.0
170.3112
205.0000
1.6700-09
1.0000
0.0
465.4144
240.0000
1.0000
0.0
0.0
255.0823
295.0000
1.0000
0.0
0.0
99.0000
300.0000
0.9999
7.5946-05
0.0
-1.2225+05 -1.1564+05 -2.2494+04 -2.9268+04 -1.7667+04

-6785.9698 -5363.7039 -1825.2966 -2219.2814 -1606.7846
-1.7115+09 -2.2210+09 -8.8268+08 -6.9551+08 -2.7346+08
-37.8538
-2.1012
3.3818
60.9234
18.0153
MIXED
*** ALL
MASSVFRA
MASSFLMX
HMX
RHOMX
CPMX
PCMX
MWMX
PHASES
KG/SEC
J/KG
KG/CUM
J/KG-K
N/SQM
-39.2497
-1.1559
-1.8205 -9.3802-02
2.4305
52.3998
21.5594
2.4063-02
0.2965
12.3232
-9.1258
-0.6920
1.8565
0.1688
3.8432-02
0.5068
13.1882
4.9651-02
0.5459
10.9953
***
0.0
1.2123-09
1.0000
1.0000
0.9999
31.7784
52.1724
60.9304
39.4868
21.4436
-1.5784+07 -1.2476+07 -4.2456+06 -5.1620+06 -3.7374+06
975.8994
839.3650
4.7500
8.1189
8.7449
3943.8755 3871.3473 2910.1420 2795.4243 2689.6860
2.2064+07 1.9522+07 2.9680+06 3.4530+06 2.2233+06
18.0153
21.5594
12.3232
13.1882
10.9953
*** VAPOR PHASE

***
RHOMX
LB/CUFT
KG/CUM
MUMX
CP
N-SEC/SQM
MASSFLMX KG/SEC
HMX
J/KG
CPMX
J/KG-K
PCMX
N/SQM
KMX
WATT/M-K
MWMX
MISSING
0.4775
0.2965
0.5068
0.5459
MISSING
7.6486
4.7500
8.1189
8.7438
MISSING 1.4324-02 2.0643-02 1.6125-02 1.5514-02
MISSING 1.4324-05 2.0643-05 1.6125-05 1.5514-05
MISSING 6.3247-08
60.9304
39.4868
21.4408
MISSING -5.0659+06 -4.2456+06 -5.1620+06 -3.7359+06
MISSING 2451.2017 2910.1420 2795.4243 2689.5618
MISSING 3.6179+06 2.9680+06 3.4530+06 2.2218+06
MISSING 8.6789-02
0.1492
0.1114
0.1065
MISSING
15.6498
12.3232
13.1882
10.9947

RHOMX
LB/CUFT
60.9234
52.3999
KG/CUM
975.8994
839.3651
MUMX
CP
0.6282
0.2759
N-SEC/SQM
6.2816-04 2.7595-04
SIGMAMX DYNE/CM
69.0802
53.8172
N/M
6.9080-02 5.3817-02
MASSFLMX KG/SEC
31.7784
52.1724
HMX
J/KG
-1.5784+07 -1.2476+07
CPMX
J/KG-K
3943.8755 3871.3473
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
60.4115
MISSING
967.6998
MISSING
0.6182
MISSING 6.1821-04
MISSING
67.8143
MISSING 6.7814-02
MISSING 2.7374-03
MISSING -1.5323+07
MISSING 3662.4414
PCMX
KMX
MWMX
N/SQM
WATT/M-K
2.2064+07
0.6301
18.0153
1.9522+07
0.1963
21.5594
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
2.1471+07
0.2318
18.4816
S-402 S-403 S-404 S-405 S-407

----------------------------STREAM ID
FROM :
TO
:
S-402
MIX-301
HX-401
S-403
HX-401
VALV-301
S-404
MCR-401
HX-401
S-405
HX-401
FV-401
S-407
FV-401
VALV-401
MAX CONV. ERROR:

0.0
0.0
1.6486-04
0.0
-1.9166-02
SUBSTREAM: MIXED
PHASE:
VAPOR
VAPOR
VAPOR
VAPOR
VAPOR
H2
2.4189+04 2.4189+04 1.4743+04 1.4743+04 1.4615+04
N2
796.7185
796.7185
796.7047
796.7047
790.4210
CO
4790.0829 4790.0829
47.9008
47.9008
47.8061
CO2
2394.1122 2394.1122 2406.0879 2406.0879 2392.9258
CH4
4364.0735 4364.0735 4363.3541 4363.3541 4313.8183
WATER
775.9163
775.9163 2964.0927 2964.0927
584.4347
CH4O
8.1894-02 8.1894-02
330.2234
330.2234
214.7047
C2H6O-01
1931.2728 1931.2728 4130.6853 4130.6853 3767.2108
C10H2-01
0.0
0.0
0.0
0.0
0.0
HEXANE
0.0
0.0
0.0
0.0
0.0
C4H8O-01
0.0
0.0
0.0
0.0
0.0
NBUTANOL
0.0
0.0
0.0
0.0
0.0
C12H2-01
0.0
0.0
0.0
0.0
0.0
ARGON
0.0
0.0
0.0
0.0
0.0
TOTAL FLOW:
LBMOL/HR
3.9242+04 3.9242+04 2.9782+04 2.9782+04 2.6726+04
LB/HR
4.8358+05 4.8358+05 4.8355+05 4.8355+05 4.1842+05
CUFT/HR
1.0327+06 1.4777+06 1.3260+06 9.5771+05 7.8115+05
STATE VARIABLES:
TEMP
F
200.4927
465.4535
536.0000
250.4927
167.0815
PRES
PSIA
270.0000
265.0000
240.0000
235.0000
230.0000
VFRAC
1.0000
1.0000
1.0000
1.0000
1.0000
LFRAC
0.0
0.0
0.0
0.0
0.0
SFRAC
0.0
0.0
0.0
0.0
0.0
ENTHALPY:
BTU/LBMOL
-2.4692+04 -2.2494+04 -3.6315+04 -3.9212+04 -3.3774+04
BTU/LB
-2003.7220 -1825.2966 -2236.6500 -2415.0883 -2157.3026
BTU/HR
-9.6897+08 -8.8268+08 -1.0815+09 -1.1678+09 -9.0266+08
ENTROPY:
BTU/LBMOL-R
-4.1861
-1.3537
-8.7528
-12.1288
-13.0205
BTU/LB-R
-0.3397
-0.1098
-0.5391
-0.7470
-0.8317
DENSITY:
LBMOL/CUFT
3.7999-02 2.6555-02 2.2460-02 3.1097-02 3.4214-02
LB/CUFT
0.4683
0.3272
0.3647
0.5049
0.5356
AVG MW
12.3232
12.3232
16.2364
16.2364
15.6559
MIXED
*** ALL
MASSVFRA
MASSFLMX
HMX
RHOMX
CPMX
PHASES
KG/SEC
J/KG
KG/CUM
J/KG-K
***
1.0000
1.0000
1.0000
1.0000
1.0000
60.9304
60.9304
60.9260
60.9260
52.7202
-4.6607+06 -4.2456+06 -5.2024+06 -5.6175+06 -4.9748+06
7.5010
5.2419
5.8411
8.0877
8.6339
2726.2002 2911.2912 2761.7095 2470.9315 2451.1829
PCMX
MWMX
N/SQM
2.9680+06
12.3232
2.9680+06
12.3232
5.0473+06
16.2364
5.0473+06
16.2364
3.5325+06
15.6559
*** VAPOR PHASE

***
RHOMX
LB/CUFT
0.4683
0.3272
0.3646
0.5049
0.5356
KG/CUM
7.5010
5.2419
5.8411
8.0877
8.5803
MUMX
CP
1.6034-02 2.0653-02 2.1073-02 1.6005-02 1.4246-02
N-SEC/SQM
1.6034-05 2.0653-05 2.1073-05 1.6005-05 1.4246-05
MASSFLMX KG/SEC
60.9304
60.9304
60.9260
60.9260
52.3924
HMX
J/KG
-4.6607+06 -4.2456+06 -5.2024+06 -5.6175+06 -5.0059+06
CPMX
J/KG-K
2726.2002 2911.2912 2761.7095 2470.9315 2466.5162
PCMX
N/SQM
2.9680+06 2.9680+06 5.0473+06 5.0473+06 3.5102+06
KMX
WATT/M-K
0.1098
0.1492
0.1275 8.9378-02 8.7128-02
MWMX
12.3232
12.3232
16.2364
16.2364
15.5585
RHOMX
LB/CUFT
KG/CUM
MUMX
CP
N-SEC/SQM
SIGMAMX DYNE/CM
N/M
MASSFLMX KG/SEC
HMX
J/KG
CPMX
J/KG-K
PCMX
N/SQM
KMX
WATT/M-K
MWMX
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
S-408
ABS-401
SPLT-402
S-409
SPLT-402
----
S-410
SPLT-402
COMP-401
S-411
VALV-302
MIX-301
S-412
PUMP-401
MIX-401
VAPOR
VAPOR
VAPOR
VAPOR
LIQUID
1.4615+04
784.6579
47.3701
2283.0542
4029.9052
747.2552
8.4427-02
1991.0029
0.0
0.0
0.0
0.0
0.0
0.0
438.4450
23.5397
1.4211
68.4916
120.8972
22.4177
2.5328-03
59.7301
0.0
0.0
0.0
0.0
0.0
0.0
1.4176+04
761.1182
45.9490
2214.5626
3909.0081
724.8376
8.1894-02
1931.2728
0.0
0.0
0.0
0.0
0.0
0.0
1.4176+04
761.1182
45.9490
2214.5626
3909.0081
724.8376
8.1894-02
1931.2728
0.0
0.0
0.0
0.0
0.0
0.0
3.1415-04
1.2686
9.5512-02
27.1649
62.3934
2390.8590
117.6567
378.7296
0.0
0.0
0.0
0.0
0.0
0.0
2.4498+04
3.2309+05
8.2880+05
734.9449
9692.5644
2.4864+04
2.3763+04
3.1339+05
8.0394+05
2.3763+04
3.1339+05
6.7523+05
2978.1680
6.6524+04
1294.9530
171.9775
200.0000
171.9775
200.0000
171.9775
200.0000
254.7994
270.0000
167.1063
235.0000
S-408 S-409 S-410 S-411 S-412

----------------------------STREAM ID
FROM :
TO
:
SUBSTREAM: MIXED
PHASE:
H2
N2
CO
CO2
CH4
WATER
CH4O
C2H6O-01
C10H2-01
HEXANE
C4H8O-01
NBUTANOL
C12H2-01
ARGON
TOTAL FLOW:
LBMOL/HR
LB/HR
CUFT/HR
STATE VARIABLES:
TEMP
F
PRES
PSIA
VFRAC
LFRAC
SFRAC
ENTHALPY:
BTU/LBMOL
BTU/LB
BTU/HR
ENTROPY:
BTU/LBMOL-R
BTU/LB-R
DENSITY:
LBMOL/CUFT
LB/CUFT
AVG MW
1.0000
0.0
0.0
1.0000
0.0
0.0
1.0000
0.0
0.0
0.0
1.0000
0.0
-2.9977+04 -2.9977+04 -2.9977+04 -2.9268+04 -1.1457+05

-2273.0025 -2273.0025 -2273.0025 -2219.2814 -5129.1850
-7.3437+08 -2.2031+07 -7.1234+08 -6.9551+08 -3.4122+08
-9.4078
-0.7134
-9.4078
-0.7134
-9.4078
-0.7134
-8.9498
-0.6786
-40.0637
-1.7936
2.9559-02
0.3898
13.1882
2.9559-02
0.3898
13.1882
2.9559-02
0.3898
13.1882
3.5193-02
0.4641
13.1882
2.2998
51.3720
22.3373
MIXED
*** ALL
MASSVFRA
MASSFLMX
HMX
RHOMX
CPMX
PCMX
MWMX
PHASES
KG/SEC
J/KG
KG/CUM
J/KG-K
N/SQM
1.0000
0.0
0.0
***
1.0000
1.0000
1.0000
1.0000
0.0
40.7081
1.2212
39.4868
39.4868
8.3819
-5.2870+06 -5.2870+06 -5.2870+06 -5.1620+06 -1.1930+07
6.2444
6.2444
6.2444
7.4346
822.9011
2701.8187 2701.8187 2701.8187 2792.2701 3834.6453
3.4530+06 3.4530+06 3.4530+06 3.4530+06 1.8880+07
13.1882
13.1882
13.1882
13.1882
22.3373
*** VAPOR PHASE

***
RHOMX
LB/CUFT
0.3898
0.3898
0.3898
0.4641
KG/CUM
6.2444
6.2444
6.2444
7.4346
MUMX
CP
1.4554-02 1.4554-02 1.4554-02 1.6105-02
N-SEC/SQM
1.4554-05 1.4554-05 1.4554-05 1.6105-05
MASSFLMX KG/SEC
40.7081
1.2212
39.4868
39.4868
HMX
J/KG
-5.2870+06 -5.2870+06 -5.2870+06 -5.1620+06
CPMX
J/KG-K
2701.8187 2701.8187 2701.8187 2792.2701
PCMX
N/SQM
3.4530+06 3.4530+06 3.4530+06 3.4530+06
KMX
WATT/M-K
9.8755-02 9.8755-02 9.8755-02
0.1114
MWMX
13.1882
13.1882
13.1882
13.1882
RHOMX
LB/CUFT
KG/CUM
MUMX
CP
N-SEC/SQM
SIGMAMX DYNE/CM
N/M
MASSFLMX KG/SEC
HMX
J/KG
CPMX
J/KG-K
PCMX
N/SQM
KMX
WATT/M-K
MWMX
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
51.3720
MISSING
822.9011
MISSING
0.2684
MISSING 2.6844-04
MISSING
51.9469
MISSING 5.1947-02
MISSING
8.3819
MISSING -1.1930+07
MISSING 3834.6453
MISSING 1.8880+07
MISSING
0.1855
MISSING
22.3373
S-414
MIX-401
PUMP-403
S-415
PUMP-403
VALV-402
S-416
DIST-401
----
S-413 S-414 S-415 S-416 S-417

----------------------------STREAM ID
FROM :
TO
:
SUBSTREAM: MIXED
S-413
PUMP-402
MIX-401
S-417
DIST-401
B2
PHASE:
LIQUID
MIXED
LIQUID
VAPOR
LIQUID
H2
1.5332-03 1.8474-03 1.8474-03 1.8474-03 4.9678-11
N2
5.7634
7.0320
7.0320
7.0125 1.9554-02
CO
0.4360
0.5315
0.5315
0.5296 1.8707-03
CO2
109.8724
137.0373
137.0373
125.7434
11.2943
CH4
283.9143
346.3077
346.3077
334.9263
11.3826
WATER
1.3837+04 1.6228+04 1.6228+04 1.3128-07
124.7770
CH4O
214.6201
332.2768
332.2768 6.8124-03
331.9006
C2H6O-01
1776.2076 2154.9372 2154.9372
192.7838 1919.6617
C10H2-01
0.0
0.0
0.0
0.0
0.0
HEXANE
0.0
0.0
0.0
0.0
0.0
C4H8O-01
0.0
0.0
0.0
0.0
0.0
NBUTANOL
0.0
0.0
0.0
0.0
0.0
C12H2-01
0.0
0.0
0.0
0.0
0.0
ARGON
0.0
0.0
0.0
0.0
0.0
TOTAL FLOW:
LBMOL/HR
1.6228+04 1.9206+04 1.9206+04
661.0043 2399.0376
LB/HR
3.4755+05 4.1407+05 4.1407+05 2.0000+04 1.0200+05
CUFT/HR
6606.3669 7901.1984 7901.9171 1.6440+04 2672.1631
STATE VARIABLES:
TEMP
F
170.6760
170.1627
170.2698
58.4913
151.0655
PRES
PSIA
206.8000
201.8000
230.0000
205.0000
206.2000
VFRAC
0.0
6.5988-09
0.0
1.0000
0.0
LFRAC
1.0000
1.0000
1.0000
0.0
1.0000
SFRAC
0.0
0.0
0.0
0.0
0.0
ENTHALPY:
BTU/LBMOL
-1.1584+05 -1.1564+05 -1.1564+05 -7.1989+04 -8.9495+04
BTU/LB
-5408.7626 -5363.8462 -5363.7039 -2379.2431 -2104.9151
BTU/HR
-1.8798+09 -2.2210+09 -2.2210+09 -4.7585+07 -2.1470+08
ENTROPY:
BTU/LBMOL-R
-39.1126
-39.2541
-39.2530
-30.0659
-66.3932
BTU/LB-R
-1.8263
-1.8207
-1.8207
-0.9937
-1.5616
DENSITY:
LBMOL/CUFT
2.4564
2.4308
2.4306 4.0206-02
0.8978
LB/CUFT
52.6083
52.4065
52.4017
1.2165
38.1713
AVG MW
21.4167
21.5594
21.5594
30.2569
42.5170
MIXED
*** ALL
MASSVFRA
MASSFLMX
HMX
RHOMX
CPMX
PCMX
MWMX
PHASES
KG/SEC
J/KG
KG/CUM
J/KG-K
N/SQM
***
0.0
4.8436-09
0.0
1.0000
0.0
43.7905
52.1724
52.1724
2.5200
12.8518
-1.2581+07 -1.2476+07 -1.2476+07 -5.5341+06 -4.8960+06
842.7036
839.4711
839.3947
19.4866
611.4456
3876.4275 3870.8207 3868.9063 1586.0092 2908.5994
1.9640+07 1.9522+07 1.9522+07 5.3399+06 6.6196+06
21.4167
21.5594
21.5594
30.2569
42.5170
*** VAPOR PHASE

***
RHOMX
LB/CUFT
KG/CUM
MUMX
CP
N-SEC/SQM
MASSFLMX KG/SEC
HMX
J/KG
CPMX
J/KG-K
PCMX
N/SQM
KMX
WATT/M-K
MWMX
MISSING
0.4755
MISSING
7.6170
MISSING 1.4323-02
MISSING 1.4323-05
MISSING 2.5270-07
MISSING -5.0731+06
MISSING 2431.3779
MISSING 3.6468+06
MISSING 8.5836-02
MISSING
15.8249
MISSING
1.2165
MISSING
19.4866
MISSING 1.1581-02
MISSING 1.1581-05
MISSING
2.5200
MISSING -5.5341+06
MISSING 1586.0092
MISSING 5.3399+06
MISSING 2.2480-02
MISSING
30.2569
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING

RHOMX
LB/CUFT
52.6083
52.4065
52.4017
KG/CUM
842.7036
839.4715
839.3947
MUMX
CP
0.2778
0.2762
0.2760
N-SEC/SQM
2.7776-04 2.7623-04 2.7603-04
SIGMAMX DYNE/CM
54.1808
53.8318
53.8213
N/M
5.4181-02 5.3832-02 5.3821-02
MASSFLMX KG/SEC
43.7905
52.1724
52.1724
HMX
J/KG
-1.2581+07 -1.2476+07 -1.2476+07
CPMX
J/KG-K
3876.4275 3870.8207 3868.9063
PCMX
N/SQM
1.9640+07 1.9522+07 1.9522+07
KMX
WATT/M-K
0.1987
0.1964
0.1963
MWMX
21.4167
21.5594
21.5594
MISSING
38.1713
MISSING
611.4456
MISSING
0.1160
MISSING 1.1597-04
MISSING
10.7791
MISSING 1.0779-02
MISSING
12.8518
MISSING -4.8960+06
MISSING 2908.5994
MISSING 6.6196+06
MISSING
0.1250
MISSING
42.5170
S-418 S-419 S-420 S-421 S-422

----------------------------STREAM ID
FROM :
TO
:
S-418
PUMP-404
SPLT-401
S-419
SPLT-401
B2
S-420
B2
----
S-421
SPLT-401
----
S-422
SPLT-401
FV-402
SUBSTREAM: MIXED
PHASE:
LIQUID
MIXED
LIQUID
MIXED
MIXED
H2
0.0
0.0
4.9678-11
0.0
0.0
N2
9.0800-19 2.4908-19 1.9554-02 1.2435-19 5.3457-19
CO
1.9803-19 5.4322-20 1.8707-03 2.7120-20 1.1658-19
CO2
6.0290-20 1.6539-20
11.2943 8.2568-21 3.5495-20
CH4
2.8793-10 7.8984-11
11.3826 3.9432-11 1.6951-10
WATER
1.6103+04 4417.4133 4542.1903 2205.3676 9480.4762
CH4O
0.3686
0.1011
332.0017 5.0486-02
0.2170
C2H6O-01
42.4880
11.6552 1931.3169
5.8188
25.0140
C10H2-01
0.0
0.0
0.0
0.0
0.0
HEXANE
0.0
0.0
0.0
0.0
0.0
C4H8O-01
0.0
0.0
0.0
0.0
0.0
NBUTANOL
0.0
0.0
0.0
0.0
0.0
C12H2-01
0.0
0.0
0.0
0.0
0.0
ARGON
0.0
0.0
0.0
0.0
0.0
TOTAL FLOW:
LBMOL/HR
1.6146+04 4429.1697 6828.2073 2211.2369 9505.7073
LB/HR
2.9207+05 8.0121+04 1.8212+05 4.0000+04 1.7195+05
CUFT/HR
5810.9568 1599.3753 4246.4906
798.4787 3432.5156
STATE VARIABLES:
TEMP
F
384.4917
384.4774
253.0247
384.4774
384.4774
PRES
PSIA
212.4000
207.4000
206.2000
207.4000
207.4000
VFRAC
0.0
2.9559-05
0.0
2.9559-05 2.9559-05
LFRAC
1.0000
1.0000
1.0000
1.0000
1.0000
SFRAC
0.0
0.0
0.0
0.0
0.0
ENTHALPY:
BTU/LBMOL
-1.1678+05 -1.1678+05 -1.0719+05 -1.1678+05 -1.1678+05
BTU/LB
-6455.4595 -6455.4595 -4018.8645 -6455.4595 -6455.4595
BTU/HR
-1.8855+09 -5.1722+08 -7.3192+08 -2.5822+08 -1.1100+09
ENTROPY:
BTU/LBMOL-R
-30.3582
-30.3578
-41.5490
-30.3578
-30.3578
BTU/LB-R
-1.6782
-1.6782
-1.5578
-1.6782
-1.6782
DENSITY:
LBMOL/CUFT
2.7786
2.7693
1.6080
2.7693
2.7693
LB/CUFT
50.2626
50.0953
42.8874
50.0953
50.0953
AVG MW
18.0894
18.0894
26.6719
18.0894
18.0894
MIXED
*** ALL
MASSVFRA
MASSFLMX
HMX
RHOMX
CPMX
PCMX
MWMX
PHASES
***
KG/SEC
J/KG
KG/CUM
J/KG-K
N/SQM
0.0
2.9841-05
0.0
2.9841-05 2.9841-05
36.8007
10.0951
22.9469
5.0399
21.6657
-1.5015+07 -1.5015+07 -9.3479+06 -1.5015+07 -1.5015+07
805.1298
802.4491
686.9907
802.4491
802.4491
5227.7330 5227.7465 1.6371+04 5227.7465 5227.7465
2.2020+07 2.2020+07 1.6609+07 2.2020+07 2.2020+07
18.0894
18.0894
26.6719
18.0894
18.0894
*** VAPOR PHASE

***
RHOMX
LB/CUFT
KG/CUM
MUMX
CP
N-SEC/SQM
MASSFLMX KG/SEC
HMX
J/KG
CPMX
J/KG-K
PCMX
N/SQM
KMX
WATT/M-K
MWMX
MISSING
0.4433
MISSING
7.1012
MISSING 1.6434-02
MISSING 1.6434-05
MISSING 3.0125-04
MISSING -1.2924+07
MISSING 2060.8545
MISSING 2.1917+07
MISSING 3.3599-02
MISSING
18.2616
MISSING
0.4433
0.4433
MISSING
7.1012
7.1012
MISSING 1.6434-02 1.6434-02
MISSING 1.6434-05 1.6434-05
MISSING 1.5039-04 6.4652-04
MISSING -1.2924+07 -1.2924+07
MISSING 2060.8545 2060.8545
MISSING 2.1917+07 2.1917+07
MISSING 3.3599-02 3.3599-02
MISSING
18.2616
18.2616

RHOMX
LB/CUFT
50.2626
50.2633
42.8874
50.2633
50.2633
KG/CUM
805.1298
805.1401
686.9907
805.1401
805.1401
MUMX
CP
0.1365
0.1365
0.1616
0.1365
0.1365
N-SEC/SQM
1.3653-04 1.3654-04 1.6162-04 1.3654-04 1.3654-04
SIGMAMX DYNE/CM
38.5304
38.5321
36.4958
38.5321
38.5321
N/M
3.8530-02 3.8532-02 3.6496-02 3.8532-02 3.8532-02
MASSFLMX KG/SEC
36.8007
10.0948
22.9469
5.0398
21.6650
HMX
J/KG
-1.5015+07 -1.5015+07 -9.3479+06 -1.5015+07 -1.5015+07
CPMX
J/KG-K
5227.7330 5227.8410 1.6371+04 5227.8410 5227.8410
PCMX
N/SQM
2.2020+07 2.2020+07 1.6609+07 2.2020+07 2.2020+07
KMX
WATT/M-K
0.5654
0.5655
0.1231
0.5655
0.5655
MWMX
18.0894
18.0894
26.6719
18.0894
18.0894
S-423 S-424 S-425 S-426 S-427
----------------------------STREAM ID
FROM :
TO
:
SUBSTREAM: MIXED
PHASE:
H2
N2
CO
CO2
CH4
WATER
CH4O
C2H6O-01
C10H2-01
HEXANE
C4H8O-01
NBUTANOL
S-423
FV-402
----
S-424
PUMP-405
B3
S-425
---B3
S-426
B3
HX-403
S-427
HX-403
B5
VAPOR
LIQUID
LIQUID
LIQUID
LIQUID
0.0
0.0
0.0
0.0
1.5922-10
1261.4009
0.1097
14.5429
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
1.0294-11
8219.0753
0.1074
10.4711
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
9100.0000
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
1.0294-11
1.7319+04
0.1074
10.4711
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
1.0294-11
1.7319+04
0.1074
10.4711
0.0
0.0
0.0
0.0
C12H2-01
ARGON
TOTAL FLOW:
LBMOL/HR
LB/HR
CUFT/HR
STATE VARIABLES:
TEMP
F
PRES
PSIA
VFRAC
LFRAC
SFRAC
ENTHALPY:
BTU/LBMOL
BTU/LB
BTU/HR
ENTROPY:
BTU/LBMOL-R
BTU/LB-R
DENSITY:
LBMOL/CUFT
LB/CUFT
AVG MW
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
1276.0535
2.3398+04
1.9887+05
8229.6538
1.4855+05
2717.5447
9100.0000
1.6394+05
2916.8820
1.7330+04
3.1249+05
5632.8875
1.7330+04
3.1249+05
5130.4482
280.4639
50.0000
1.0000
0.0
0.0
280.4776
55.0000
0.0
1.0000
0.0
242.2000
65.0000
0.0
1.0000
0.0
260.4756
55.0000
0.0
1.0000
0.0
109.9963
55.0000
0.0
1.0000
0.0
-1.0208+05 -1.1905+05 -1.1986+05 -1.1948+05 -1.2224+05

-5567.2088 -6595.3369 -6653.4421 -6625.8198 -6779.1409
-1.3026+08 -9.7977+08 -1.0908+09 -2.0705+09 -2.1184+09
-10.8585
-0.5922
-33.0714
-1.8321
-34.0946
-1.8925
-33.5998
-1.8633
-37.8739
-2.1003
6.4167-03
0.1177
18.3362
3.0283
54.6651
18.0512
3.1198
56.2035
18.0153
3.0765
55.4767
18.0323
3.3778
60.9097
18.0323
MIXED
*** ALL
MASSVFRA
MASSFLMX
HMX
RHOMX
CPMX
PCMX
MWMX
PHASES
KG/SEC
J/KG
KG/CUM
J/KG-K
N/SQM
***
1.0000
0.0
0.0
0.0
0.0
2.9481
18.7176
20.6560
39.3736
39.3736
-1.2949+07 -1.5341+07 -1.5476+07 -1.5412+07 -1.5768+07
1.8847
875.6504
900.2941
888.6510
975.6791
1939.4161 4659.5779 4515.1983 5129.7010 3941.9850
2.1873+07 2.2043+07 2.2064+07 2.2054+07 2.2054+07
18.3362
18.0512
18.0153
18.0323
18.0323
*** VAPOR PHASE

***
RHOMX
LB/CUFT
0.1177
KG/CUM
1.8847
MUMX
CP
1.4092-02
N-SEC/SQM
1.4092-05
MASSFLMX KG/SEC
2.9481
HMX
J/KG
-1.2949+07
CPMX
J/KG-K
1939.4161
PCMX
N/SQM
2.1873+07
KMX
WATT/M-K
2.7954-02
MWMX
18.3362
RHOMX
LB/CUFT
KG/CUM
MUMX
CP
N-SEC/SQM
SIGMAMX DYNE/CM
N/M
MASSFLMX KG/SEC
HMX
J/KG
CPMX
J/KG-K
PCMX
N/SQM
KMX
WATT/M-K
MWMX
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
54.6651
56.2035
55.4767
60.9097
MISSING
875.6504
900.2941
888.6510
975.6791
MISSING
0.1960
0.2356
0.2149
0.6298
MISSING 1.9596-04 2.3562-04 2.1485-04 6.2977-04
MISSING
50.6946
54.9816
52.9466
69.0817
MISSING 5.0695-02 5.4982-02 5.2947-02 6.9082-02
MISSING
18.7176
20.6560
39.3736
39.3736
MISSING -1.5341+07 -1.5476+07 -1.5412+07 -1.5768+07
MISSING 4659.5779 4515.1983 5129.7010 3941.9850
MISSING 2.2043+07 2.2064+07 2.2054+07 2.2054+07
MISSING
0.6253
0.6827
0.6541
0.6198
MISSING
18.0512
18.0153
18.0323
18.0323
S-428 S-429 S-429B S-430 V

-------------------------STREAM ID
FROM :
TO
:
S-428
B5
----
S-429
---PUMP-406
S-429B
B5
----
S-430
VALV-404
ABS-401
V
DIST-401
PUMP-404
SUBSTREAM: MIXED
PHASE:
LIQUID
LIQUID
LIQUID
LIQUID
LIQUID
H2
0.0
0.0
0.0
0.0
0.0
N2
0.0
0.0
0.0
0.0
9.0800-19
CO
0.0
0.0
0.0
0.0
1.9803-19
CO2
0.0
0.0
0.0
0.0
6.0290-20
CH4
1.9779-12
0.0
8.3165-12
0.0
2.8793-10
WATER
3327.6213 1.4000+04 1.3991+04 1.4000+04 1.6103+04
CH4O
2.0628-02
0.0
8.6735-02
0.0
0.3686
C2H6O-01
2.0119
0.0
8.4592
0.0
42.4880
C10H2-01
0.0
0.0
0.0
0.0
0.0
HEXANE
0.0
0.0
0.0
0.0
0.0
C4H8O-01
0.0
0.0
0.0
0.0
0.0
NBUTANOL
0.0
0.0
0.0
0.0
0.0
C12H2-01
0.0
0.0
0.0
0.0
0.0
ARGON
0.0
0.0
0.0
0.0
0.0
TOTAL FLOW:
LBMOL/HR
3329.6538 1.4000+04 1.4000+04 1.4000+04 1.6146+04
LB/HR
6.0041+04 2.5221+05 2.5245+05 2.5221+05 2.9207+05
CUFT/HR
985.7448 4139.0326 4144.7034 4140.0117 5810.8838
STATE VARIABLES:
TEMP
F
109.9963
110.0000
109.9963
110.4220
384.4774
PRES
PSIA
55.0000
40.0000
55.0000
205.0000
207.4000
VFRAC
0.0
0.0
0.0
0.0
0.0
LFRAC
1.0000
1.0000
1.0000
1.0000
1.0000
SFRAC
0.0
0.0
0.0
0.0
0.0
ENTHALPY:
BTU/LBMOL
-1.2224+05 -1.2227+05 -1.2224+05 -1.2225+05 -1.1678+05
BTU/LB
-6779.1409 -6786.7941 -6779.1409 -6785.9698 -6455.4842
BTU/HR
-4.0703+08 -1.7117+09 -1.7114+09 -1.7115+09 -1.8855+09
ENTROPY:
BTU/LBMOL-R
-37.8739
-37.8618
-37.8739
-37.8514
-30.3584
BTU/LB-R
-2.1003
-2.1016
-2.1003
-2.1011
-1.6782
DENSITY:
LBMOL/CUFT
3.3778
3.3824
3.3778
3.3816
2.7786
LB/CUFT
60.9097
60.9355
60.9097
60.9211
50.2632
AVG MW
18.0323
18.0153
18.0323
18.0153
18.0894
MIXED
*** ALL
MASSVFRA
MASSFLMX
HMX
RHOMX
CPMX
PCMX
MWMX
PHASES
KG/SEC
J/KG
KG/CUM
J/KG-K
N/SQM
*** VAPOR PHASE

RHOMX
LB/CUFT
***
0.0
0.0
0.0
0.0
0.0
7.5651
31.7784
31.8085
31.7784
36.8007
-1.5768+07 -1.5786+07 -1.5768+07 -1.5784+07 -1.5015+07
975.6791
976.0927
975.6791
975.8618
805.1400
3941.9850 3944.2465 3941.9850 3944.3730 5227.8389
2.2054+07 2.2064+07 2.2054+07 2.2064+07 2.2020+07
18.0323
18.0153
18.0323
18.0153
18.0894
***
MISSING
MISSING
MISSING
MISSING
MISSING
KG/CUM
CP
N-SEC/SQM
MASSFLMX KG/SEC
HMX
J/KG
CPMX
J/KG-K
PCMX
N/SQM
KMX
WATT/M-K
MWMX
MUMX
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING

RHOMX
LB/CUFT
60.9097
60.9355
60.9097
60.9211
50.2632
KG/CUM
975.6791
976.0927
975.6791
975.8618
805.1400
MUMX
CP
0.6298
0.6304
0.6298
0.6277
0.1365
N-SEC/SQM
6.2977-04 6.3044-04 6.2977-04 6.2772-04 1.3654-04
SIGMAMX DYNE/CM
69.0817
69.1180
69.0817
69.0728
38.5321
N/M
6.9082-02 6.9118-02 6.9082-02 6.9073-02 3.8532-02
MASSFLMX KG/SEC
7.5651
31.7784
31.8085
31.7784
36.8007
HMX
J/KG
-1.5768+07 -1.5786+07 -1.5768+07 -1.5784+07 -1.5015+07
CPMX
J/KG-K
3941.9850 3944.2465 3941.9850 3944.3730 5227.8389
PCMX
N/SQM
2.2054+07 2.2064+07 2.2054+07 2.2064+07 2.2020+07
KMX
WATT/M-K
0.6198
0.6299
0.6198
0.6302
0.5655
MWMX
18.0323
18.0153
18.0323
18.0153
18.0894
W
STREAM ID
FROM :
TO
:
W
ABS-401
PUMP-402
SUBSTREAM: MIXED
PHASE:
LIQUID
H2
1.5332-03
N2
5.7634
CO
0.4360
CO2
109.8724
CH4
283.9143
WATER
1.3837+04
CH4O
214.6201
C2H6O-01
1776.2076
C10H2-01
0.0
HEXANE
0.0
C4H8O-01
0.0
NBUTANOL
0.0
C12H2-01
0.0
ARGON
0.0
TOTAL FLOW:
LBMOL/HR
1.6228+04
LB/HR
3.4755+05
CUFT/HR
6606.2730
STATE VARIABLES:
TEMP
F
170.6592
PRES
PSIA
201.8000
VFRAC
0.0
LFRAC
1.0000
SFRAC
0.0
ENTHALPY:
BTU/LBMOL
-1.1584+05
BTU/LB
BTU/HR
ENTROPY:
BTU/LBMOL-R
BTU/LB-R
DENSITY:
LBMOL/CUFT
LB/CUFT
AVG MW
-5408.7859
-1.8798+09
-39.1128
-1.8263
2.4565
52.6090
21.4167
MIXED
*** ALL
MASSVFRA
MASSFLMX
HMX
RHOMX
CPMX
PCMX
MWMX
PHASES
***
KG/SEC
J/KG
KG/CUM
J/KG-K
N/SQM
0.0
43.7905
-1.2581+07
842.7156
3876.7745
1.9640+07
21.4167
*** VAPOR PHASE

***
RHOMX
LB/CUFT
KG/CUM
MUMX
CP
N-SEC/SQM
MASSFLMX KG/SEC
HMX
J/KG
CPMX
J/KG-K
PCMX
N/SQM
KMX
WATT/M-K
MWMX
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING

RHOMX
LB/CUFT
52.6090
KG/CUM
842.7156
MUMX
CP
0.2778
N-SEC/SQM
2.7779-04
SIGMAMX DYNE/CM
54.1825
N/M
5.4182-02
MASSFLMX KG/SEC
43.7905
HMX
J/KG
-1.2581+07
CPMX
J/KG-K
3876.7745
PCMX
N/SQM
1.9640+07
KMX
WATT/M-K
0.1987
MWMX
21.4167
Q-301
----STREAM ID
FROM :
TO
:
CLASS:
STREAM ATTRIBUTES:
HEAT
Q
BTU/HR
TBEG
F
TEND
F
Q-301
MCR-401
---HEAT
1.9890+08
465.4144
536.0000
Page 1
B80
B34
101
137
134
127
Q=138877
95
B32
B23
21
33
W=54
B74
B73
135
Q=7370181
Q=62463933
B3
69
Q=9443788
92
136
126
Q=0
B71
113
56
Q=0
73
B48
68
102
B69
105
B60
67
96
Q=-0
93
66
B51
B52
40
B10
B64
104
54
140
B88
55
141
B90
B13
S-501
W=79
20
Q=47745324
Page 2
22
B86
Q=0
Page 2
B80
114
Q=13887751
B81
128
129
131
Q=22375551
B68
97
112
B70
108
B67
98
Q=0
S-505C
B6299
B50
109 B72
B66
107
B-505
S-505A
110
103
86
B49
B89
B-504
Q=15758683
Q=0
85
70
B84
130
B40
Q=0
Q=0
87
Q=-0
Q=-0
Q=-0
111
100
106
B64
B53
94
Page 3
Page 1
132
S-506
29
B4
B-601
B38
34
47
Q=5178242
35
59
32
38
B41
41
B27
B11
44
B31
57
Q=50453509
Q=30817554
120
31 58
B12
B-806
3
B63
88
Q=-5903359
B79
30
B75
B29
23
Q=5903359
B77 B78
117
118
119
Q=26319913
61
89
B65
Q=-5903359
65
Q=5903359
B56 B59
63
64
B61
Q=-5903359
Q=6082249
Page 3
B-505
S-505C
B-507
91
26
B-606
B6
W=2177
B58
72
133
7
B9
S-604
52
Page 2
W=2117
121
43
B5
49
B18
S-601 B15
14
Q=0
15
Q=182083007
B16
12
W=14
45
17
Duty (Btu/hr)
Power(hp)
Errors
124
Q=10866397
11
Q=6753325
B83
25
Q=0
B82
B-603
S-603
Q=0
123
S-605
QC=-38436749
QR=54803196
B55
125
B36
W=71
W=87
B-612
S-606
W=19
19
B2690
122
B8
B25
B45
46
Page 4
Q=20029158
S-611
B57 71
B14
Q=5716555
=5178242
53
24
S-613
W=556
W=1423
B85
B-608
Page 4
83
B2
10
13
Q=5988421
84
B46
78
B43
W=580
36
B7
82B44
80
138
B87 S-614
Q=3434866
81
B-610
16
19
139
Q=4168101
W=60
B-702
S-703
B21
53325
Page 3
S-701
W=31
18
QC=-16265185
S-702
QR=31289613
B20
S-615
B19
B35
51
Q=12189673
27
50
S-801
B-705
B-704
B-703
S-704
S-705
S-706
S-707
QC=-2068827
QR=6503032
W=424
103 104 105 106 107

-------------------
1 10 100 101 102

---------------STREAM ID
FROM :
TO
:
1
B-806
B63
10
---B2
100
B62
B-507
101
B71
----
102
B69
B80
SUBSTREAM: MIXED
PHASE:
VAPOR
LIQUID
VAPOR
MIXED
VAPOR
CO2
0.0
0.0
11.3070
0.0
2.0353
WATER
865.9075 6661.0122
0.0
2000.0000 4813.5183
METHANOL
1.7572-02
0.0
0.0
0.0
0.1091
DME
1.3182-06
0.0
0.0
0.0
8.3922-06
METHY-01
2.1086-06
0.0
0.0
0.0
1.1252-05
METHY-02
1.3584-06
0.0
0.0
0.0
5.9089-06
N-PRO-01
1.5562
0.0
0.0
0.0
6.6259
METHA-01
0.0
0.0
0.0
0.0
7.9911
N-BUT-01
0.2248
0.0
0.0
0.0
0.8371
METHY-03
1.2326-02
0.0
0.0
0.0
0.9215
3-MET-01
4.4546-02
0.0
0.0
0.0
0.1384
VALER-01
2.2016-02
0.0
0.0
0.0
7.1684-02
ETHANOL
2.7107-02
0.0
0.0
0.0
0.1394
CIS-C-01
6.4820-02
0.0
0.0
0.0
0.2675
METHY-05
1.4729
0.0
0.0
0.0
4.0637
DIETH-01
0.9440
0.0
0.0
0.0
2.6929
2-MET-01
4.2717-04
0.0
0.0
0.0
1.3032-03
METHY-06
2.7684
0.0
0.0
0.0
7.8081
DIETH-02
0.9440
0.0
0.0
0.0
2.6929
METHY-07
2.7684
0.0
0.0
0.0
7.8081
3-MET-02
0.1619
0.0
0.0
0.0
0.3942
TERT--01
4.1450-03
0.0
0.0
0.0
1.4048-02
ETHYLENE
83.3248
0.0
0.0
0.0
22.0190
CYCLO-01
2.5315-02
0.0
0.0
0.0
6.3685-03
PROPYLEN
198.4062
0.0
0.0
0.0
43.4288
ISOBUTAN
119.4926
0.0
0.0
0.0
18.4039
N-BUTANE
166.4802
0.0
0.0
0.0
26.6494
TRANS-BU
0.0
0.0
0.0
0.0
8.8932
1-BUTENE
0.0
0.0
0.0
0.0
6.5928
ISOBUTEN
0.0
0.0
0.0
0.0
16.3667
CIS-2-01
39.3610
0.0
0.0
0.0
7.2359
2-MET-02
40.8643
0.0
0.0
0.0
5.5533
1:2-B-01
4.7772-03
0.0
0.0
0.0
1.2927-03
1:3-B-01
5.5603
0.0
0.0
0.0
1.2162
N-PENTAN
0.0
0.0
0.0
0.0
3.6584
N-HEXANE
0.0
0.0
0.0
0.0
0.4373
N-HEPTAN
0.0
0.0
0.0
0.0
5.6716-02
NITRO-01
0.0
0.0
1.9562-02
0.0
3.5212-03
TOTAL FLOW:
LBMOL/HR
1530.4604 6661.0122
11.3266 2000.0000 5018.6534
LB/HR
4.9269+04 1.2000+05
498.1680 3.6031+04 9.8158+04
CUFT/HR
7.3726+05 1947.6067
578.3093 9389.6146 1.7740+05
STATE VARIABLES:
TEMP
F
887.0000
90.0000
658.4085
620.0854
923.7492
PRES
PSIA
30.0000
40.0000
235.0000 1790.0000
420.0000
VFRAC
1.0000
0.0
1.0000
0.7029
1.0000
LFRAC
0.0
1.0000
0.0
0.2971
0.0
SFRAC
0.0
0.0
0.0
0.0
0.0
ENTHALPY:
BTU/LBMOL
-5.4948+04 -1.2260+05 -1.6289+05 -1.0214+05 -9.3067+04
BTU/LB
-1706.8445 -6805.4650 -3703.5348 -5669.8657 -4758.3774
BTU/HR
-8.4095+07 -8.1666+08 -1.8450+06 -2.0429+08 -4.6707+08
ENTROPY:
BTU/LBMOL-R
-15.8063
-38.4569
2.6700
-16.8450
-9.9618
BTU/LB-R
-0.4910
-2.1347 6.0705-02
-0.9350
-0.5093
DENSITY:
LBMOL/CUFT
2.0759-03
3.4201 1.9586-02
0.2130 2.8290-02
LB/CUFT
6.6828-02
61.6141
0.8614
3.8373
0.5533
AVG MW
32.1925
18.0153
43.9822
18.0153
19.5586
STREAM ID
FROM :
TO
:
103
B70
B81
104
B10
B64
105
B80
B49
106
B64
B67
107
B67
B66
SUBSTREAM: MIXED
PHASE:
VAPOR
VAPOR
VAPOR
VAPOR
VAPOR
CO2
4.5228
3.9575
2.0353
3.9575
8.4803
CO
0.0
6.4976-04
0.0
6.4976-04 6.4976-04
WATER
5272.0327
43.6720 4813.5183
43.6720 5315.7047
METHANOL
0.1191
116.1652
0.1091
116.1652
116.2843
DME
9.7438-06
672.0867 8.3922-06
672.0867
672.0867
METHY-01
1.6184-05
0.0
1.1252-05
0.0
1.6184-05
METHY-02
1.0752-05
0.0
5.9089-06
0.0
1.0752-05
N-PRO-01
11.7045
0.0
6.6259
0.0
11.7045
METHA-01
16.9359
0.0
7.9911
0.0
16.9359
N-BUT-01
1.7738
0.0
0.8371
0.0
1.7738
METHY-03
1.7977
0.0
0.9215
0.0
1.7977
3-MET-01
0.3646
0.0
0.1384
0.0
0.3646
1:1-D-01
1.0268-11
0.0
6.8477-12
0.0
1.0268-11
VALER-01
0.1822
0.0
7.1684-02
0.0
0.1822
ETHANOL
0.1902
0.0
0.1394
0.0
0.1902
CIS-C-01
0.5429
0.0
0.2675
0.0
0.5429
METHY-05
11.7121
0.0
4.0637
0.0
11.7121
DIETH-01
7.5677
0.0
2.6929
0.0
7.5677
2-MET-01
3.3618-03
0.0
1.3032-03
0.0
3.3618-03
METHY-06
22.1320
0.0
7.8081
0.0
22.1320
DIETH-02
7.5677
0.0
2.6929
0.0
7.5677
METHY-07
22.1320
0.0
7.8081
0.0
22.1320
3-MET-02
1.3539
0.0
0.3942
0.0
1.3539
TERT--01
3.0880-02
0.0
1.4048-02
0.0
3.0880-02
METHANE
0.0
3.9839
0.0
3.9839
3.9839
ETHYLENE
30.4524
0.0
22.0190
0.0
30.4524
CYCLO-01
9.9081-03
0.0
6.3685-03
0.0
9.9081-03
PROPYLEN
75.0756
0.0
43.4288
0.0
75.0756
ISOBUTAN
43.4622
0.0
18.4039
0.0
43.4622
N-BUTANE
61.1235
0.0
26.6494
0.0
61.1235
TRANS-BU
19.1115
0.0
8.8932
0.0
19.1115
1-BUTENE
13.6763
0.0
6.5928
0.0
13.6763
ISOBUTEN
35.7991
0.0
16.3667
0.0
35.7991
CIS-2-01
15.4729
0.0
7.2359
0.0
15.4729
2-MET-02
15.6265
0.0
5.5533
0.0
15.6265
1:2-B-01
2.1354-03
0.0
1.2927-03
0.0
2.1354-03
1:3-B-01
2.3601
0.0
1.2162
0.0
2.3601
N-PENTAN
10.0776
0.0
3.6584
0.0
10.0776
N-HEXANE
1.4428
0.0
0.4373
0.0
1.4428
N-HEPTAN
0.2245
0.0
5.6716-02
0.0
0.2245
NITRO-01
7.8248-03 6.8467-03 3.5212-03 6.8467-03 1.4672-02
TOTAL FLOW:
LBMOL/HR
5706.5909
839.8728 5018.6534
839.8728 6546.4637
LB/HR
1.2060+05 3.5710+04 9.8158+04 3.5710+04 1.5631+05
CUFT/HR
2.2431+05 2.3110+04 1.4401+05 2.9209+04 2.1926+05
STATE VARIABLES:
TEMP
F
895.5823
707.0000
650.0000
707.0000
663.8957
PRES
PSIA
370.0000
455.0000
415.0000
360.0000
360.0000
VFRAC
1.0000
1.0000
1.0000
1.0000
1.0000
LFRAC
0.0
0.0
0.0
0.0
0.0
SFRAC
0.0
0.0
0.0
0.0
0.0
ENTHALPY:
BTU/LBMOL
-9.0698+04 -6.9361+04 -9.5834+04 -6.9361+04 -9.0368+04
BTU/LB
-4291.5430 -1631.3358 -4899.8615 -1631.3358 -3784.6361
BTU/HR
-5.1758+08 -5.8254+07 -4.8096+08 -5.8254+07 -5.9159+08
ENTROPY:
BTU/LBMOL-R
-10.9631
-41.4961
-12.1644
-41.0310
-16.0458
BTU/LB-R
-0.5187
-0.9760
-0.6219
-0.9650
-0.6720
DENSITY:
LBMOL/CUFT
2.5440-02 3.6342-02 3.4850-02 2.8754-02 2.9857-02
LB/CUFT
0.5377
1.5452
0.6816
1.2226
0.7129
AVG MW
21.1341
42.5179
19.5586
42.5179
23.8775
108 109 11 110 111

-----------------STREAM ID
FROM :
TO
:
108
B66
B68
109
B68
B72
11
B26
B83
110
B84
B50
111
B66
B72
SUBSTREAM: MIXED
PHASE:
VAPOR
VAPOR
MIXED
VAPOR
VAPOR
CO2
0.0
0.0
11.0246
8.4803
8.4803
CO
6.4976-04
0.0
0.0
0.0
0.0
WATER
5315.7047 6034.0137
19.8082 6034.0137
0.0
METHANOL
116.2843
0.1555 3.1714-02
0.1555
0.0
DME
672.0867 1.4000-05 5.3065-06 1.4000-05
0.0
METHY-01
1.6184-05 2.3579-05 6.3544-06 2.3579-05
0.0
METHY-02
1.0752-05 1.5707-05 4.3790-06 1.5707-05
0.0
N-PRO-01
11.7045
18.6330
7.6586
18.6330
0.0
METHA-01
16.9359
33.9543
1.6513
33.9543
0.0
N-BUT-01
1.7738
2.9137
0.5139
2.9137
0.0
METHY-03
1.7977
2.0283
0.4156
2.0283
0.0
3-MET-01
0.3646
0.6060 1.9404-03
0.6060
0.0
1:1-D-01
1.0268-11 1.2449-11
0.0
1.2449-11
0.0
VALER-01
0.1822
0.3088 2.8364-02
0.3088
0.0
ETHANOL
0.1902
0.2505 2.4332-02
0.2505
0.0
CIS-C-01
0.5429
1.1143 6.9529-03
1.1143
0.0
METHY-05
11.7121
18.5506
2.8900
18.5506
0.0
DIETH-01
7.5677
12.1505
1.3403
12.1505
0.0
2-MET-01
3.3618-03 4.6302-03 1.2971-04 4.6302-03
0.0
METHY-06
22.1320
35.3708
3.6147
35.3708
0.0
DIETH-02
7.5677
12.1505
1.3403
12.1505
0.0
METHY-07
22.1320
35.3708
3.6147
35.3708
0.0
3-MET-02
1.3539
2.2204
0.1222
2.2204
0.0
TERT--01
3.0880-02 4.0737-02 2.9012-03 4.0737-02
0.0
METHANE
3.9839
0.0
9.0965
0.0
0.0
ETHYLENE
30.4524
65.0054
340.9935
65.0054
0.0
CYCLO-01
9.9081-03 2.2592-02 8.1087-02 2.2592-02
0.0
PROPYLEN
75.0756
161.7297
874.8024
161.7297
0.0
ISOBUTAN
43.4622
73.7779
322.6666
73.7779
0.0
N-BUTANE
61.1235
105.4057
365.8497
105.4057
0.0
TRANS-BU
19.1115
41.6706
8.1021
41.6706
0.0
1-BUTENE
13.6763
30.3929
10.9290
30.3929
0.0
ISOBUTEN
35.7991
77.3155
38.1861
77.3155
0.0
CIS-2-01
15.4729
33.8283
102.9130
33.8283
0.0
2-MET-02
15.6265
27.4686
96.9650
27.4686
0.0
1:2-B-01
2.1354-03 6.5499-03 1.0938-02 6.5499-03
0.0
1:3-B-01
2.3601
6.6366
19.1220
6.6366
0.0
N-PENTAN
10.0776
17.9194
15.3467
17.9194
0.0
N-HEXANE
1.4428
2.6493
1.3048
2.6493
0.0
N-HEPTAN
0.2245
0.4253
4.5664
0.4253
0.0
BENZENE
0.0
0.0
6.0714-02
0.0
0.0
NITRO-01
0.0
0.0
1.9520-02 1.4672-02 1.4672-02
TOTAL FLOW:
LBMOL/HR
6537.9687 6854.0915 2265.1069 6862.5864
8.4949
LB/HR
1.5594+05 1.5594+05 1.0784+05 1.5631+05
373.6260
CUFT/HR
2.1898+05 3.8770+05 5.8370+04 3.2048+05
284.5201
STATE VARIABLES:
TEMP
F
663.8957
910.7688
110.0000
650.0000
663.8957
PRES
PSIA
360.0000
260.0000
145.0000
255.0000
360.0000
VFRAC
1.0000
1.0000
0.5961
1.0000
1.0000
LFRAC
0.0
0.0
0.4039
0.0
0.0
SFRAC
0.0
0.0
0.0
0.0
0.0
ENTHALPY:
BTU/LBMOL
-9.0274+04 -8.6110+04 -1.9043+04 -8.9466+04 -1.6283+05
BTU/LB
-3784.8338 -3784.8338 -399.9987 -3927.7816 -3702.1151
BTU/HR
-5.9021+08 -5.9021+08 -4.3134+07 -6.1396+08 -1.3832+06
ENTROPY:
BTU/LBMOL-R
-16.0889
-11.0327
-58.5515
-13.5940
1.8787
BTU/LB-R
-0.6745
-0.4849
-1.2299
-0.5968 4.2714-02
DENSITY:
LBMOL/CUFT
2.9857-02 1.7679-02 3.8806-02 2.1414-02 2.9857-02
LB/CUFT
0.7121
0.4022
1.8474
0.4878
1.3132
AVG MW
23.8514
22.7513
47.6072
22.7776
43.9822
112 113 114 117 118

------------------STREAM ID
FROM :
TO
:
112
B72
B84
113
B73
B74
114
---B80
117
B75
B77
118
B77
B78
SUBSTREAM: MIXED
PHASE:
VAPOR
LIQUID
LIQUID
MIXED
MIXED
CO2
8.4803
0.0
0.0
7.3550-08 7.3550-08
WATER
6034.0137 4429.1700 1150.0000
811.9113
811.9113
METHANOL
0.1555
0.0
0.0
3.7877-02 3.7877-02
DME
1.4000-05
0.0
0.0
1.4884-06 1.4884-06
METHY-01
2.3579-05
0.0
0.0
3.8059-06 3.8059-06
METHY-02
1.5707-05
0.0
0.0
2.6368-06 2.6368-06
N-PRO-01
18.6330
0.0
0.0
7.2931
7.2931
METHA-01
33.9543
0.0
0.0
3.1550
3.1550
N-BUT-01
2.9137
0.0
0.0
0.9999
0.9999
METHY-03
2.0283
0.0
0.0
0.5104
0.5104
3-MET-01
0.6060
0.0
0.0
7.9632-03 7.9632-03
1:1-D-01
1.2449-11
0.0
0.0
0.0
0.0
VALER-01
0.3088
0.0
0.0
9.3340-02 9.3340-02
ETHANOL
0.2505
0.0
0.0
6.2206-02 6.2206-02
CIS-C-01
1.1143
0.0
0.0
2.4693-02 2.4693-02
METHY-05
18.5506
0.0
0.0
8.9203
8.9203
DIETH-01
12.1505
0.0
0.0
5.3038
5.3038
2-MET-01
4.6302-03
0.0
0.0
1.0986-03 1.0986-03
METHY-06
35.3708
0.0
0.0
15.9490
15.9490
DIETH-02
12.1505
0.0
0.0
5.3038
5.3038
METHY-07
35.3708
0.0
0.0
15.9490
15.9490
3-MET-02
2.2204
0.0
0.0
0.9086
0.9086
TERT--01
4.0737-02
0.0
0.0
1.1435-02 1.1435-02
METHANE
0.0
0.0
0.0
4.2550-11 4.2550-11
ETHYLENE
65.0054
0.0
0.0
1.1185-05 1.1185-05
CYCLO-01
2.2592-02
0.0
0.0
9.6664-03 9.6664-03
PROPYLEN
161.7297
0.0
0.0
2.1401
2.1401
ISOBUTAN
73.7779
0.0
0.0
141.9000
141.9000
N-BUTANE
105.4057
0.0
0.0
171.6000
171.6000
TRANS-BU
41.6706
0.0
0.0
4.3129
4.3129
1-BUTENE
30.3929
0.0
0.0
5.3402
5.3402
ISOBUTEN
77.3155
0.0
0.0
18.6919
18.6919
CIS-2-01
33.8283
0.0
0.0
56.3938
56.3938
2-MET-02
27.4686
0.0
0.0
52.0112
52.0112
1:2-B-01
6.5499-03
0.0
0.0
6.6676-03 6.6676-03
1:3-B-01
6.6366
0.0
0.0
9.5827
9.5827
N-PENTAN
17.9194
0.0
0.0
9.5776
9.5776
N-HEXANE
2.6493
0.0
0.0
1.4218
1.4218
N-HEPTAN
0.4253
0.0
0.0
11.8599
11.8599
BENZENE
0.0
0.0
0.0
0.1538
0.1538
NITRO-01
1.4672-02
0.0
0.0
4.3293-16 4.3293-16
TOTAL FLOW:
LBMOL/HR
6862.5864 4429.1700 1150.0000 1361.4450 1361.4450
LB/HR
1.5631+05 7.9793+04 2.0718+04 4.9269+04 4.9269+04
CUFT/HR
3.8810+05 1678.2136
536.3915 2.2291+05 3.0901+05
STATE VARIABLES:
TEMP
F
910.4928
447.2897
600.0000
920.1381
921.2617
PRES
PSIA
260.0000
470.0000 1800.0000
90.0000
65.0000
VFRAC
1.0000
0.0
0.0
0.9950
0.9954
LFRAC
0.0
1.0000
1.0000 5.0245-03 4.5801-03
SFRAC
0.0
0.0
0.0
0.0
0.0
ENTHALPY:
BTU/LBMOL
-8.6205+04 -1.1492+05 -1.0949+05 -6.6105+04 -6.6105+04
BTU/LB
-3784.6361 -6379.2714 -6077.5465 -1826.6625 -1826.6625
BTU/HR
-5.9159+08 -5.0902+08 -1.2591+08 -8.9999+07 -8.9999+07
ENTROPY:
BTU/LBMOL-R
-10.9968
-28.3483
-23.5289
-23.5173
-22.8742
BTU/LB-R
-0.4828
-1.5736
-1.3061
-0.6498
-0.6321
DENSITY:
LBMOL/CUFT
1.7683-02
2.6392
2.1440 6.1076-03 4.4058-03
LB/CUFT
0.4028
47.5462
38.6240
0.2210
0.1594
AVG MW
22.7776
18.0153
18.0153
36.1890
36.1890
119 12 120 121 122

-----------------STREAM ID
FROM :
TO
:
AVG MW
32.1925
21.1429
32.1925
49.2362
47.6072
123
B82
B36
124
B83
B58
125
B83
B55
126
---B73
127
B80
----
123 124 125 126 127

------------------119
B78
B65
12
B15
B16
120
B79
B31
121
B9
B82
122
B82
B57
MAX CONV. ERROR:

0.0
0.0
1.9693-12
0.0
0.0
SUBSTREAM: MIXED
PHASE:
VAPOR
LIQUID
VAPOR
MIXED
VAPOR
CO2
0.0
0.3778
0.0
11.3070
11.0246
WATER
865.9075 8840.8521 2623.9620
277.6224
19.8082
METHANOL
1.7572-02 8.2855-02 5.3248-02
0.1115 3.1714-02
DME
1.3182-06 1.6002-06 3.9944-06 6.6465-06 5.3065-06
METHY-01
2.1086-06 4.8710-06 6.3897-06 1.0788-05 6.3544-06
METHY-02
1.3584-06 1.6557-07 4.1162-06 7.3112-06 4.3790-06
N-PRO-01
1.5562
2.8872
4.7157
21.4941
7.6586
METHA-01
0.0
41.1618
0.0
11.1575
1.6513
N-BUT-01
0.2248
0.8673
0.6812
2.9074
0.5139
METHY-03
1.2326-02
0.3321 3.7351-02
1.5345
0.4156
3-MET-01
4.4546-02
0.5598
0.1350 3.1622-02 1.9404-03
VALER-01
2.2016-02 5.2147-02 6.6714-02
0.2673 2.8364-02
ETHANOL
2.7107-02
0.1292 8.2142-02
0.1827 2.4332-02
CIS-C-01
6.4820-02
1.3701
0.1964 9.8800-02 6.9529-03
METHY-05
1.4729
5.7600
4.4632
25.9896
2.8900
DIETH-01
0.9440
3.7878
2.8607
15.4042
1.3403
2-MET-01
4.2717-04 1.9613-03 1.2944-03 3.0442-03 1.2971-04
METHY-06
2.7684
13.5289
8.3891
46.3720
3.6147
DIETH-02
0.9440
3.7878
2.8607
15.4042
1.3403
METHY-07
2.7684
13.5289
8.3891
46.3720
3.6147
3-MET-02
0.1619
0.5945
0.4907
2.6112
0.1222
TERT--01
4.1450-03 1.7393-02 1.2561-02 3.2580-02 2.9012-03
METHANE
0.0
7.6249-02
0.0
9.1456
9.0965
ETHYLENE
83.3248
12.0530
252.4993
349.5930
340.9935
CYCLO-01
2.5315-02 2.1179-02 7.6711-02 9.8375-02 8.1087-02
PROPYLEN
198.4062
152.4748
601.2308
994.9092
874.8024
ISOBUTAN
119.4926
159.3838
362.0987
459.6410
322.6666
N-BUTANE
166.4802
244.6690
504.4854
582.9881
365.8497
TRANS-BU
0.0
5.5569
0.0
13.0567
8.1021
1-BUTENE
0.0
6.0148
0.0
16.1773
10.9290
ISOBUTEN
0.0
21.1593
0.0
56.6256
38.1861
CIS-2-01
39.3610
75.7870
119.2758
170.7826
102.9130
2-MET-02
40.8643
0.1156
123.8313
153.7638
96.9650
1:2-B-01
4.7772-03 9.8934-03 1.4476-02 1.9951-02 1.0938-02
1:3-B-01
5.5603
11.1640
16.8493
28.8289
19.1220
N-PENTAN
0.0
3.6815-02
0.0
29.0234
15.3467
N-HEXANE
0.0
1.2699-02
0.0
4.3085
1.3048
N-HEPTAN
0.0
0.2351
0.0
35.9388
4.5664
BENZENE
0.0
4.6975
0.0
0.5973 6.0714-02
NITRO-01
0.0
6.9148-05
0.0
1.9562-02 1.9520-02
TOTAL FLOW:
LBMOL/HR
1530.4604 9623.1474 4637.7588 3384.4210 2265.1069
LB/HR
4.9269+04 2.0346+05 1.4930+05 1.6664+05 1.0784+05
CUFT/HR
7.3726+05 3765.4328 1.9329+06 2.3226+05 2.3079+05
STATE VARIABLES:
TEMP
F
887.0000
138.3754
705.4238
110.0000
109.9994
PRES
PSIA
30.0000
18.0000
30.0000
60.0000
60.0000
VFRAC
1.0000
0.0
1.0000
0.6693
1.0000
LFRAC
0.0
1.0000
0.0
0.3307
0.0
SFRAC
0.0
0.0
0.0
0.0
0.0
ENTHALPY:
BTU/LBMOL
-5.4948+04 -1.1529+05 -5.8766+04 -3.4934+04 -1.5844+04
BTU/LB
-1706.8445 -5452.7333 -1825.4644 -709.5121 -332.7990
BTU/HR
-8.4095+07 -1.1094+09 -2.7254+08 -1.1823+08 -3.5888+07
ENTROPY:
BTU/LBMOL-R
-15.8063
-39.9840
-18.8495
-60.7474
-51.4207
BTU/LB-R
-0.4910
-1.8911
-0.5855
-1.2338
-1.0801
DENSITY:
LBMOL/CUFT
2.0759-03
2.5557 2.3994-03 1.4571-02 9.8146-03
LB/CUFT
6.6828-02
54.0341 7.7243-02
0.7174
0.4672
STREAM ID
FROM :
TO
:
SUBSTREAM: MIXED
PHASE:
LIQUID
VAPOR
LIQUID
VAPOR
VAPOR
CO2
0.2824
10.2909
0.7337
0.0
0.0
WATER
257.8141
0.3712
19.4370
527.3301 1150.0000
METHANOL
7.9743-02 6.4705-03 2.5243-02
0.0
0.0
DME
1.3400-06 3.1160-06 2.1905-06
0.0
0.0
METHY-01
4.4335-06 2.1598-06 4.1947-06
0.0
0.0
METHY-02
2.9322-06 8.6071-07 3.5183-06
0.0
0.0
N-PRO-01
13.8355
0.8952
6.7634
0.0
0.0
METHA-01
9.5062 9.6997-02
1.5543
0.0
0.0
N-BUT-01
2.3935 2.4538-02
0.4894
0.0
0.0
METHY-03
1.1189 3.5688-02
0.3799
0.0
0.0
3-MET-01
2.9682-02 4.4522-05 1.8958-03
0.0
0.0
VALER-01
0.2389 4.9769-04 2.7867-02
0.0
0.0
ETHANOL
0.1584 8.6385-04 2.3468-02
0.0
0.0
CIS-C-01
9.1847-02 1.8407-04 6.7688-03
0.0
0.0
METHY-05
23.0997 7.3879-02
2.8161
0.0
0.0
DIETH-01
14.0639 2.4178-02
1.3161
0.0
0.0
2-MET-01
2.9145-03 1.3755-06 1.2834-04
0.0
0.0
METHY-06
42.7573 6.2978-02
3.5517
0.0
0.0
DIETH-02
14.0639 2.4178-02
1.3161
0.0
0.0
METHY-07
42.7573 6.2978-02
3.5517
0.0
0.0
3-MET-02
2.4890 1.1970-03
0.1210
0.0
0.0
TERT--01
2.9679-02 7.1061-05 2.8301-03
0.0
0.0
METHANE
4.9130-02
8.9617
0.1347
0.0
0.0
ETHYLENE
8.5995
318.6260
22.3675
0.0
0.0
CYCLO-01
1.7288-02 5.0887-02 3.0200-02
0.0
0.0
PROPYLEN
120.1068
632.8994
241.9030
0.0
0.0
ISOBUTAN
136.9744
147.8985
174.7682
0.0
0.0
N-BUTANE
217.1384
138.4806
227.3691
0.0
0.0
TRANS-BU
4.9546
3.0025
5.0995
0.0
0.0
1-BUTENE
5.2482
4.6824
6.2466
0.0
0.0
ISOBUTEN
18.4395
16.2890
21.8971
0.0
0.0
CIS-2-01
67.8696
36.3739
66.5392
0.0
0.0
2-MET-02
56.7988
20.3235
76.6415
0.0
0.0
1:2-B-01
9.0135-03 3.3205-03 7.6172-03
0.0
0.0
1:3-B-01
9.7069
7.9544
11.1677
0.0
0.0
N-PENTAN
13.6767
2.5434
12.8032
0.0
0.0
N-HEXANE
3.0037 8.0991-02
1.2239
0.0
0.0
N-HEPTAN
31.3724 9.8243-02
4.4681
0.0
0.0
BENZENE
0.5366 2.3715-03 5.8342-02
0.0
0.0
NITRO-01
4.2140-05 1.9403-02 1.1660-04
0.0
0.0
TOTAL FLOW:
LBMOL/HR
1119.3141 1350.2628
914.8441
527.3301 1150.0000
LB/HR
5.8801+04 5.8391+04 4.9444+04 9500.0000 2.0718+04
CUFT/HR
1472.8348 5.6929+04 1441.6441 1.2205+04 9005.0198
STATE VARIABLES:
TEMP
F
109.9994
110.0000
110.0000
450.0000
850.0989
PRES
PSIA
60.0000
145.0000
145.0000
421.7880 1795.0000
VFRAC
0.0
1.0000
0.0
1.0000
1.0000
LFRAC
1.0000
0.0
1.0000
0.0
0.0
SFRAC
0.0
0.0
0.0
0.0
0.0
ENTHALPY:
BTU/LBMOL
-7.3565+04 -4597.1303 -4.0364+04 -1.0090+05 -9.7412+04
BTU/LB
-1400.3731 -106.3061 -746.8346 -5601.0157 -5407.2096
BTU/HR
-8.2343+07 -6.2073+06 -3.6927+07 -5.3210+07 -1.1202+08
ENTROPY:
BTU/LBMOL-R
-79.6214
-43.2647
-81.1141
-12.9440
-12.6457
BTU/LB-R
-1.5157
-1.0005
-1.5008
-0.7185
-0.7019
DENSITY:
LBMOL/CUFT
0.7600 2.3719-02
0.6346 4.3207-02
0.1277
LB/CUFT
39.9234
1.0257
34.2971
0.7784
2.3007
AVG MW
52.5327
43.2443
54.0466
18.0153
18.0153
137 138 139 14 140

-----------------STREAM ID
FROM :
TO
:
128 129 13 130 131

-----------------STREAM ID
FROM :
TO
:
128
---B81
129
B81
----
13
B2
----
130
---B84
131
B84
----
SUBSTREAM: MIXED
PHASE:
LIQUID
VAPOR
LIQUID
LIQUID
VAPOR
WATER
1300.0000 1300.0000 6661.0122 2000.0000 2000.0000
TOTAL FLOW:
LBMOL/HR
1300.0000 1300.0000 6661.0122 2000.0000 2000.0000
LB/HR
2.3420+04 2.3420+04 1.2000+05 3.6031+04 3.6031+04
CUFT/HR
606.3556 1.0219+04 2006.0572
932.8547 1.4475+04
STATE VARIABLES:
TEMP
F
600.0000
855.1602
142.3577
600.0000
750.9097
PRES
PSIA
1800.0000 1795.0000
37.0000 1800.0000 1795.0000
VFRAC
0.0
1.0000
0.0
0.0
1.0000
LFRAC
1.0000
0.0
1.0000
1.0000
0.0
SFRAC
0.0
0.0
0.0
0.0
0.0
ENTHALPY:
BTU/LBMOL
-1.0949+05 -9.7367+04 -1.2170+05 -1.0949+05 -9.8301+04
BTU/LB
-6077.5465 -5404.6697 -6755.5615 -6077.5465 -5456.5305
BTU/HR
-1.4234+08 -1.2658+08 -8.1067+08 -2.1898+08 -1.9660+08
ENTROPY:
BTU/LBMOL-R
-23.5289
-12.6108
-36.9046
-23.5289
-13.3511
BTU/LB-R
-1.3061
-0.7000
-2.0485
-1.3061
-0.7411
DENSITY:
LBMOL/CUFT
2.1440
0.1272
3.3204
2.1440
0.1382
LB/CUFT
38.6240
2.2918
59.8188
38.6240
2.4892
AVG MW
18.0153
18.0153
18.0153
18.0153
18.0153
132 133 134 135 136
------------------STREAM ID
FROM :
TO
:
132
---B85
133
B85
----
134
B73
----
135
B74
B71
136
---B74
SUBSTREAM: MIXED
PHASE:
LIQUID
VAPOR
LIQUID
VAPOR
VAPOR
WATER
550.0000
550.0000
527.3301 4429.1700 5000.0000
TOTAL FLOW:
LBMOL/HR
550.0000
550.0000
527.3301 4429.1700 5000.0000
LB/HR
9908.4040 9908.4040 9500.0000 7.9793+04 9.0076+04
CUFT/HR
256.5350 3684.2282
200.1174 9.3982+04 6.4752+04
STATE VARIABLES:
TEMP
F
600.0000
660.7779
448.8181
459.7646
520.0000
PRES
PSIA
1800.0000 1795.0000
416.7880
465.0000
811.8109
VFRAC
0.0
1.0000
0.0
1.0000
1.0000
LFRAC
1.0000
0.0
1.0000
0.0
0.0
SFRAC
0.0
0.0
0.0
0.0
0.0
ENTHALPY:
BTU/LBMOL
-1.0949+05 -9.9095+04 -1.1488+05 -1.0082+05 -1.0031+05
BTU/LB
-6077.5465 -5500.6064 -6376.8242 -5596.4440 -5568.0740
BTU/HR
-6.0219+07 -5.4502+07 -6.0580+07 -4.4656+08 -5.0155+08
ENTROPY:
BTU/LBMOL-R
-23.5289
-14.0326
-28.3045
-13.0476
-13.6158
BTU/LB-R
-1.3061
-0.7789
-1.5711
-0.7243
-0.7558
DENSITY:
LBMOL/CUFT
2.1440
0.1493
2.6351 4.7128-02 7.7218-02
LB/CUFT
38.6240
2.6894
47.4721
0.8490
1.3911
AVG MW
18.0153
18.0153
18.0153
18.0153
18.0153
137
B74
----
SUBSTREAM: MIXED
PHASE:
LIQUID
CO2
0.0
CO
0.0
WATER
5000.0000
METHANOL
0.0
DME
0.0
METHY-01
0.0
METHY-02
0.0
N-PRO-01
0.0
METHA-01
0.0
N-BUT-01
0.0
METHY-03
0.0
3-MET-01
0.0
VALER-01
0.0
ETHANOL
0.0
CIS-C-01
0.0
METHY-05
0.0
DIETH-01
0.0
2-MET-01
0.0
METHY-06
0.0
DIETH-02
0.0
METHY-07
0.0
3-MET-02
0.0
TERT--01
0.0
METHANE
0.0
ETHYLENE
0.0
CYCLO-01
0.0
PROPYLEN
0.0
ISOBUTAN
0.0
N-BUTANE
0.0
TRANS-BU
0.0
1-BUTENE
0.0
ISOBUTEN
0.0
CIS-2-01
0.0
2-MET-02
0.0
1:2-B-01
0.0
1:3-B-01
0.0
N-PENTAN
0.0
N-HEXANE
0.0
N-HEPTAN
0.0
BENZENE
0.0
NITRO-01
0.0
TOTAL FLOW:
LBMOL/HR
5000.0000
LB/HR
9.0076+04
CUFT/HR
2045.9258
STATE VARIABLES:
TEMP
F
515.2205
PRES
PSIA
806.8109
VFRAC
0.0
LFRAC
1.0000
SFRAC
0.0
ENTHALPY:
BTU/LBMOL
-1.1280+05
BTU/LB
-6261.5291
BTU/HR
-5.6402+08
ENTROPY:
BTU/LBMOL-R
-26.3476
BTU/LB-R
-1.4625
DENSITY:
LBMOL/CUFT
2.4439
LB/CUFT
44.0272
AVG MW
18.0153
138
---B87
139
B87
----
14
B16
B18
140
B88
B10
LIQUID
MIXED
LIQUID
VAPOR
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
594.0974
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
594.0974
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.3778
0.0
8840.8521
8.2855-02
1.6002-06
4.8710-06
1.6557-07
2.8872
41.1618
0.8673
0.3321
0.5598
5.2147-02
0.1292
1.3701
5.7600
3.7878
1.9613-03
13.5289
3.7878
13.5289
0.5945
1.7393-02
7.6249-02
12.0530
2.1179-02
152.4748
159.3838
244.6690
5.5569
6.0148
21.1593
75.7870
0.1156
9.8934-03
11.1640
3.6815-02
1.2699-02
0.2351
4.6975
6.9148-05
11.3070
1.8565-03
124.7770
331.9006
1920.2477
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
11.3826
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
1.9562-02
594.0974
2.5000+04
698.7747
594.0974
2.5000+04
6.0473+04
9623.1474
2.0346+05
3765.9695
2399.6364
1.0203+05
6.6030+04
0.0
51.0000
0.0
1.0000
0.0
-2.7958
46.0000
0.9545
4.5495-02
0.0
138.5663
55.0000
0.0
1.0000
0.0
707.0000
455.0000
1.0000
0.0
0.0
176.9231
4.2044
1.0511+05
7192.7812 -1.1528+05 -6.9361+04

170.9285 -5452.5541 -1631.3358
4.2732+06 -1.1094+09 -1.6644+08
-54.6956
-1.2998
-39.3298
-0.9346
-39.9778
-1.8908
-41.4961
-0.9760
0.8502
35.7769
42.0806
9.8242-03
0.4134
42.0806
2.5553
54.0264
21.1429
3.6342-02
1.5452
42.5179
19 2 20 21 22
-------------
141 15 16 17 18
--------------STREAM ID
FROM :
TO
:
141
B90
B86
SUBSTREAM: MIXED
PHASE:
LIQUID
CO2
11.3070
CO
1.8565-03
WATER
124.7770
METHANOL
331.9006
DME
1920.2477
METHY-01
0.0
METHY-02
0.0
N-PRO-01
0.0
METHA-01
0.0
N-BUT-01
0.0
METHY-03
0.0
3-MET-01
0.0
VALER-01
0.0
ETHANOL
0.0
CIS-C-01
0.0
METHY-05
0.0
DIETH-01
0.0
2-MET-01
0.0
METHY-06
0.0
DIETH-02
0.0
METHY-07
0.0
3-MET-02
0.0
TERT--01
0.0
METHANE
11.3826
ETHYLENE
0.0
CYCLO-01
0.0
PROPYLEN
0.0
ISOBUTAN
0.0
N-BUTANE
0.0
TRANS-BU
0.0
1-BUTENE
0.0
ISOBUTEN
0.0
CIS-2-01
0.0
2-MET-02
0.0
1:2-B-01
0.0
1:3-B-01
0.0
N-PENTAN
0.0
N-HEXANE
0.0
N-HEPTAN
0.0
BENZENE
0.0
NITRO-01
1.9562-02
TOTAL FLOW:
LBMOL/HR
2399.6364
LB/HR
1.0203+05
CUFT/HR
2615.9648
STATE VARIABLES:
TEMP
F
138.2963
PRES
PSIA
460.0000
VFRAC
0.0
LFRAC
1.0000
SFRAC
0.0
ENTHALPY:
BTU/LBMOL
-8.9258+04
BTU/LB
-2099.3011
BTU/HR
-2.1419+08
ENTROPY:
BTU/LBMOL-R
-66.2979
BTU/LB-R
-1.5593
DENSITY:
LBMOL/CUFT
0.9173
LB/CUFT
39.0019
AVG MW
42.5179
15
B15
----
16
---B7
17
B18
B-603
18
B20
B21
MISSING
VAPOR
MIXED
LIQUID
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
1000.0000
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
11.3070
0.0
9233.1865
0.1140
6.6466-06
1.0804-05
7.3112-06
21.4941
48.0445
2.9074
1.5345
0.5986
0.2673
0.1831
1.4784
25.9896
15.4042
3.0470-03
46.3720
15.4042
46.3720
2.6112
3.2580-02
9.1456
349.5930
9.8375-02
994.9095
459.7299
583.5666
13.0695
16.1828
56.6444
171.0384
153.7638
2.0041-02
28.8417
29.0234
4.3085
35.9388
5.2229
1.9562-02
11.3070
0.0
277.6224
0.1115
6.6465-06
1.0788-05
7.3112-06
21.4941
11.1575
2.9074
1.5345
3.1622-02
0.2673
0.1827
9.8800-02
25.9896
15.4042
3.0442-03
46.3720
15.4042
46.3720
2.6112
3.2580-02
9.1456
349.5930
9.8375-02
994.9092
459.6410
582.9881
13.0567
16.1773
56.6256
170.7826
153.7638
1.9951-02
28.8289
29.0234
4.3085
35.9388
0.5973
1.9562-02
0.0
0.0
0.0
1000.0000
2.8054+04
8332.0286
1.2384+04
3.3112+05
2.6036+05
3384.4210
1.6664+05
5428.5841
45.0000
650.0000
1.0000
0.0
0.0
182.4082
55.0000
0.1647
0.8353
0.0
180.0000
557.9000
0.0
1.0000
0.0
MISSING
18.0000
MISSING
MISSING
MISSING
MISSING
MISSING
MISSING
2.2254+04 -9.6431+04 -3.6117+04

793.2466 -3606.6506 -733.5541
2.2254+07 -1.1942+09 -1.2224+08
MISSING
MISSING
-20.9045
-0.7452
-41.0055
-1.5337
-64.5626
-1.3113
MISSING
MISSING
MISSING
0.1200
3.3670
28.0538
4.7566-02
1.2718
26.7369
0.6234
30.6960
49.2362
STREAM ID
FROM :
TO
:
19
B25
B87
2
---B38
20
B13
B90
21
B23
B32
22
B86
B88
SUBSTREAM: MIXED
PHASE:
MIXED
MIXED
LIQUID
LIQUID
VAPOR
CO2
10.2909 2.2288-07
11.3070
0.0
11.3070
CO
0.0
0.0
1.8565-03
0.0
1.8565-03
WATER
0.3712
240.0000
124.7770 4429.1700
124.7770
METHANOL
6.4705-03
0.1148
331.9006
0.0
331.9006
DME
3.1160-06 4.5103-06 1920.2477
0.0
1920.2477
METHY-01
2.1598-06 1.1533-05
0.0
0.0
0.0
METHY-02
8.6071-07 7.9904-06
0.0
0.0
0.0
N-PRO-01
0.8952
22.1003
0.0
0.0
0.0
METHA-01
9.6997-02
9.5607
0.0
0.0
0.0
N-BUT-01
2.4538-02
3.0300
0.0
0.0
0.0
METHY-03
3.5688-02
1.5468
0.0
0.0
0.0
3-MET-01
4.4522-05 2.4131-02
0.0
0.0
0.0
VALER-01
4.9769-04
0.2828
0.0
0.0
0.0
ETHANOL
8.6385-04
0.1885
0.0
0.0
0.0
CIS-C-01
1.8407-04 7.4827-02
0.0
0.0
0.0
METHY-05
7.3879-02
27.0313
0.0
0.0
0.0
DIETH-01
2.4178-02
16.0720
0.0
0.0
0.0
2-MET-01
1.3755-06 3.3292-03
0.0
0.0
0.0
METHY-06
6.2978-02
48.3304
0.0
0.0
0.0
DIETH-02
2.4178-02
16.0720
0.0
0.0
0.0
METHY-07
6.2978-02
48.3304
0.0
0.0
0.0
3-MET-02
1.1970-03
2.7533
0.0
0.0
0.0
TERT--01
7.1061-05 3.4652-02
0.0
0.0
0.0
METHANE
8.9617 1.2894-10
11.3826
0.0
11.3826
ETHYLENE
318.6260 3.3893-05
0.0
0.0
0.0
CYCLO-01
5.0887-02 2.9292-02
0.0
0.0
0.0
PROPYLEN
632.8994
6.4851
0.0
0.0
0.0
ISOBUTAN
147.8985
430.0000
0.0
0.0
0.0
N-BUTANE
138.4806
520.0000
0.0
0.0
0.0
TRANS-BU
3.0025
13.0693
0.0
0.0
0.0
1-BUTENE
4.6824
16.1824
0.0
0.0
0.0
ISOBUTEN
16.2890
56.6421
0.0
0.0
0.0
CIS-2-01
36.3739
170.8902
0.0
0.0
0.0
2-MET-02
20.3235
157.6096
0.0
0.0
0.0
1:2-B-01
3.3205-03 2.0205-02
0.0
0.0
0.0
1:3-B-01
7.9544
29.0384
0.0
0.0
0.0
N-PENTAN
2.5434
29.0231
0.0
0.0
0.0
N-HEXANE
8.0991-02
4.3084
0.0
0.0
0.0
N-HEPTAN
9.8243-02
35.9390
0.0
0.0
0.0
BENZENE
2.3715-03
0.4661
0.0
0.0
0.0
NITRO-01
1.9403-02 1.3119-15 1.9562-02
0.0
1.9562-02
TOTAL FLOW:
LBMOL/HR
1350.2628 1905.2535 2399.6364 4429.1700 2399.6364
LB/HR
5.8391+04 1.0930+05 1.0203+05 7.9793+04 1.0203+05
CUFT/HR
1.3334+04 4.4809+04 2615.9648 1583.6826 6.6030+04
STATE VARIABLES:
TEMP
F
100.0000
185.0000
138.2963
385.7323
707.0000
PRES
PSIA
265.0000
105.0000
485.0000
500.0000
455.0000
VFRAC
0.3963
0.3412
0.0
0.0
1.0000
LFRAC
0.6037
0.6588
1.0000
1.0000
0.0
SFRAC
0.0
0.0
0.0
0.0
0.0
ENTHALPY:
BTU/LBMOL
-8550.9282 -6.3707+04 -8.9258+04 -1.1659+05 -6.9361+04
BTU/LB
-197.7355 -1110.4986 -2099.3011 -6471.6379 -1631.3358
BTU/HR
-1.1546+07 -1.2138+08 -2.1419+08 -5.1639+08 -1.6644+08
ENTROPY:
BTU/LBMOL-R
-51.0984
-82.5615
-66.2979
-30.0802
-41.4961
BTU/LB-R
-1.1816
-1.4391
-1.5593
-1.6697
-0.9760
DENSITY:
LBMOL/CUFT
0.1013 4.2519-02
0.9173
2.7968 3.6342-02
LB/CUFT
4.3791
2.4393
39.0019
50.3843
1.5452
AVG MW
43.2443
57.3683
42.5179
18.0153
42.5179
23 24 25 26 27
-------------STREAM ID
FROM :
TO
:
29 3 30 31 32
------------23
B29
B75
24
---B25
25
B25
----
26
B58
B-608
27
B35
B20
SUBSTREAM: MIXED
PHASE:
VAPOR
LIQUID
LIQUID
VAPOR
LIQUID
CO2
2.2288-07
0.0
0.0
10.2909
11.3070
WATER
2460.3374 1.2489+04 1.2489+04
0.3712
277.6224
METHANOL
0.1148
0.0
0.0
6.4705-03
0.1115
DME
4.5103-06
0.0
0.0
3.1160-06 6.6465-06
METHY-01
1.1533-05
0.0
0.0
2.1598-06 1.0788-05
METHY-02
7.9904-06
0.0
0.0
8.6071-07 7.3112-06
N-PRO-01
22.1003
0.0
0.0
0.8952
21.4941
METHA-01
9.5607
0.0
0.0
9.6997-02
11.1575
N-BUT-01
3.0300
0.0
0.0
2.4538-02
2.9074
METHY-03
1.5468
0.0
0.0
3.5688-02
1.5345
3-MET-01
2.4131-02
0.0
0.0
4.4522-05 3.1622-02
VALER-01
0.2828
0.0
0.0
4.9769-04
0.2673
ETHANOL
0.1885
0.0
0.0
8.6385-04
0.1827
CIS-C-01
7.4827-02
0.0
0.0
1.8407-04 9.8800-02
METHY-05
27.0313
0.0
0.0
7.3879-02
25.9896
DIETH-01
16.0720
0.0
0.0
2.4178-02
15.4042
2-MET-01
3.3292-03
0.0
0.0
1.3755-06 3.0442-03
METHY-06
48.3304
0.0
0.0
6.2978-02
46.3720
DIETH-02
16.0720
0.0
0.0
2.4178-02
15.4042
METHY-07
48.3304
0.0
0.0
6.2978-02
46.3720
3-MET-02
2.7533
0.0
0.0
1.1970-03
2.6112
TERT--01
3.4652-02
0.0
0.0
7.1061-05 3.2580-02
METHANE
1.2894-10
0.0
0.0
8.9617
9.1456
ETHYLENE
3.3893-05
0.0
0.0
318.6260
349.5930
CYCLO-01
2.9292-02
0.0
0.0
5.0887-02 9.8375-02
PROPYLEN
6.4851
0.0
0.0
632.8994
994.9092
ISOBUTAN
430.0000
0.0
0.0
147.8985
459.6410
N-BUTANE
520.0000
0.0
0.0
138.4806
582.9881
TRANS-BU
13.0693
0.0
0.0
3.0025
13.0567
1-BUTENE
16.1824
0.0
0.0
4.6824
16.1773
ISOBUTEN
56.6421
0.0
0.0
16.2890
56.6256
CIS-2-01
170.8902
0.0
0.0
36.3739
170.7826
2-MET-02
157.6096
0.0
0.0
20.3235
153.7638
1:2-B-01
2.0205-02
0.0
0.0
3.3205-03 1.9951-02
1:3-B-01
29.0384
0.0
0.0
7.9544
28.8289
N-PENTAN
29.0231
0.0
0.0
2.5434
29.0234
N-HEXANE
4.3084
0.0
0.0
8.0991-02
4.3085
N-HEPTAN
35.9390
0.0
0.0
9.8243-02
35.9388
BENZENE
0.4661
0.0
0.0
2.3715-03
0.5973
NITRO-01
1.3119-15
0.0
0.0
1.9403-02 1.9562-02
TOTAL FLOW:
LBMOL/HR
4125.5909 1.2489+04 1.2489+04 1350.2628 3384.4210
LB/HR
1.4930+05 2.2500+05 2.2500+05 5.8391+04 1.6664+05
CUFT/HR
6.8460+05 3651.7625 3717.2109 5.8131+04 4688.8529
STATE VARIABLES:
TEMP
F
932.0000
90.0000
121.8515
110.0000
91.0518
PRES
PSIA
90.0000
40.0000
35.0000
142.0000
557.9000
VFRAC
1.0000
0.0
0.0
1.0000
0.0
LFRAC
0.0
1.0000
1.0000
0.0
1.0000
SFRAC
0.0
0.0
0.0
0.0
0.0
ENTHALPY:
BTU/LBMOL
-6.6105+04 -1.2260+05 -1.2206+05 -4597.1303 -3.9719+04
BTU/LB
-1826.6625 -6805.4650 -6775.4502 -106.3061 -806.7056
BTU/HR
-2.7272+08 -1.5312+09 -1.5245+09 -6.2073+06 -1.3443+08
ENTROPY:
BTU/LBMOL-R
-23.5413
-38.4569
-37.5069
-43.2232
-69.9886
BTU/LB-R
-0.6505
-2.1347
-2.0819
-0.9995
-1.4215
DENSITY:
LBMOL/CUFT
6.0263-03
3.4201
3.3599 2.3228-02
0.7218
LB/CUFT
0.2181
61.6141
60.5293
1.0045
35.5388
AVG MW
36.1890
18.0153
18.0153
43.2443
49.2362
STREAM ID
FROM :
TO
:
29
---B4
3
B12
B-806
30
B75
B12
31
B31
B29
32
B31
B-601
SUBSTREAM: MIXED
PHASE:
LIQUID
MIXED
MIXED
VAPOR
VAPOR
CO2
0.0
7.3550-08 7.3550-08 2.2288-07
0.0
WATER
444.0675
811.9113
811.9113 2460.3374 2623.9620
METHANOL
0.0
3.7877-02 3.7877-02
0.1148 5.3248-02
DME
0.0
1.4884-06 1.4884-06 4.5103-06 3.9944-06
METHY-01
0.0
3.8059-06 3.8059-06 1.1533-05 6.3897-06
METHY-02
0.0
2.6368-06 2.6368-06 7.9904-06 4.1162-06
N-PRO-01
0.0
7.2931
7.2931
22.1003
4.7157
METHA-01
0.0
3.1550
3.1550
9.5607
0.0
N-BUT-01
0.0
0.9999
0.9999
3.0300
0.6812
METHY-03
0.0
0.5104
0.5104
1.5468 3.7351-02
3-MET-01
0.0
7.9632-03 7.9632-03 2.4131-02
0.1350
VALER-01
0.0
9.3340-02 9.3340-02
0.2828 6.6714-02
ETHANOL
0.0
6.2206-02 6.2206-02
0.1885 8.2142-02
CIS-C-01
0.0
2.4693-02 2.4693-02 7.4827-02
0.1964
METHY-05
0.0
8.9203
8.9203
27.0313
4.4632
DIETH-01
0.0
5.3038
5.3038
16.0720
2.8607
2-MET-01
0.0
1.0986-03 1.0986-03 3.3292-03 1.2944-03
METHY-06
0.0
15.9490
15.9490
48.3304
8.3891
DIETH-02
0.0
5.3038
5.3038
16.0720
2.8607
METHY-07
0.0
15.9490
15.9490
48.3304
8.3891
3-MET-02
0.0
0.9086
0.9086
2.7533
0.4907
TERT--01
0.0
1.1435-02 1.1435-02 3.4652-02 1.2561-02
METHANE
0.0
4.2550-11 4.2550-11 1.2894-10
0.0
ETHYLENE
0.0
1.1185-05 1.1185-05 3.3893-05
252.4993
CYCLO-01
0.0
9.6664-03 9.6664-03 2.9292-02 7.6711-02
PROPYLEN
0.0
2.1401
2.1401
6.4851
601.2308
ISOBUTAN
0.0
141.9000
141.9000
430.0000
362.0987
N-BUTANE
0.0
171.6000
171.6000
520.0000
504.4854
TRANS-BU
0.0
4.3129
4.3129
13.0693
0.0
1-BUTENE
0.0
5.3402
5.3402
16.1824
0.0
ISOBUTEN
0.0
18.6919
18.6919
56.6421
0.0
CIS-2-01
0.0
56.3938
56.3938
170.8902
119.2758
2-MET-02
0.0
52.0112
52.0112
157.6096
123.8313
1:2-B-01
0.0
6.6676-03 6.6676-03 2.0205-02 1.4476-02
1:3-B-01
0.0
9.5827
9.5827
29.0384
16.8493
N-PENTAN
0.0
9.5776
9.5776
29.0231
0.0
N-HEXANE
0.0
1.4218
1.4218
4.3084
0.0
N-HEPTAN
0.0
11.8599
11.8599
35.9390
0.0
BENZENE
0.0
0.1538
0.1538
0.4661
0.0
TOTAL FLOW:
LBMOL/HR
444.0675 1361.4450 1361.4450 4125.5909 4637.7588
LB/HR
8000.0000 4.9269+04 4.9269+04 1.4930+05 1.4930+05
CUFT/HR
140.2716 3.0901+05 2.2291+05 5.2414+05 1.5990+06
STATE VARIABLES:
TEMP
F
220.0000
921.2617
920.1381
665.0000
343.5152
PRES
PSIA
20.0000
65.0000
90.0000
95.0000
25.0000
VFRAC
0.0
0.9954
0.9950
1.0000
1.0000
LFRAC
1.0000 4.5801-03 5.0245-03
0.0
0.0
SFRAC
0.0
0.0
0.0
0.0
0.0
ENTHALPY:
BTU/LBMOL
-1.2026+05 -6.6105+04 -6.6105+04 -7.2485+04 -6.5411+04
BTU/LB
-6675.6149 -1826.6625 -1826.6625 -2002.9500 -2031.8765
BTU/HR
-5.3405+07 -8.9999+07 -8.9999+07 -2.9904+08 -3.0336+08
ENTROPY:
BTU/LBMOL-R
-34.6798
-22.8742
-23.5173
-28.7284
-25.2724
BTU/LB-R
-1.9250
-0.6321
-0.6498
-0.7938
-0.7850
DENSITY:
LBMOL/CUFT
3.1658 4.4058-03 6.1076-03 7.8712-03 2.9005-03
LB/CUFT
57.0322
0.1594
0.2210
0.2849 9.3373-02
AVG MW
18.0153
36.1890
36.1890
36.1890
32.1925
40 41 43 44 45
-------------33 34 35 36 38
-------------STREAM ID
FROM :
TO
:
33
---B23
34
B86
B-601
35
B4
----
SUBSTREAM: MIXED
PHASE:
LIQUID
MIXED
MIXED
CO2
0.0
11.3070
0.0
WATER
4429.1700 6609.2246
444.0675
METHANOL
0.0
6.0781-02
0.0
DME
0.0
2.6521-06
0.0
METHY-01
0.0
4.4138-06
0.0
METHY-02
0.0
3.1950-06
0.0
N-PRO-01
0.0
16.7783
0.0
METHA-01
0.0
48.0445
0.0
N-BUT-01
0.0
2.2263
0.0
METHY-03
0.0
1.4971
0.0
3-MET-01
0.0
0.4636
0.0
VALER-01
0.0
0.2005
0.0
ETHANOL
0.0
0.1010
0.0
CIS-C-01
0.0
1.2820
0.0
METHY-05
0.0
21.5264
0.0
DIETH-01
0.0
12.5435
0.0
2-MET-01
0.0
1.7526-03
0.0
METHY-06
0.0
37.9829
0.0
DIETH-02
0.0
12.5435
0.0
METHY-07
0.0
37.9829
0.0
3-MET-02
0.0
2.1204
0.0
TERT--01
0.0
2.0020-02
0.0
METHANE
0.0
9.1456
0.0
ETHYLENE
0.0
97.0937
0.0
CYCLO-01
0.0
2.1665-02
0.0
PROPYLEN
0.0
393.6787
0.0
ISOBUTAN
0.0
97.6312
0.0
N-BUTANE
0.0
79.0812
0.0
TRANS-BU
0.0
13.0695
0.0
1-BUTENE
0.0
16.1828
0.0
ISOBUTEN
0.0
56.6444
0.0
CIS-2-01
0.0
51.7626
0.0
2-MET-02
0.0
29.9325
0.0
1:2-B-01
0.0
5.5645-03
0.0
1:3-B-01
0.0
11.9924
0.0
N-PENTAN
0.0
29.0234
0.0
N-HEXANE
0.0
4.3085
0.0
N-HEPTAN
0.0
35.9388
0.0
BENZENE
0.0
5.2229
0.0
NITRO-01
0.0
1.9562-02
0.0
TOTAL FLOW:
LBMOL/HR
4429.1700 7746.6622
444.0675
LB/HR
7.9793+04 1.8182+05 8000.0000
CUFT/HR
1581.9801 2.2573+06 1.2729+05
STATE VARIABLES:
TEMP
F
384.5000
231.7924
219.4771
PRES
PSIA
207.4000
25.0000
17.0000
VFRAC
0.0
0.9817
0.6684
LFRAC
1.0000 1.8298-02
0.3316
SFRAC
0.0
0.0
0.0
ENTHALPY:
BTU/LBMOL
-1.1662+05 -9.1528+04 -1.0860+05
BTU/LB
-6473.3749 -3899.6624 -6028.3346
BTU/HR
-5.1653+08 -7.0904+08 -4.8227+07
ENTROPY:
BTU/LBMOL-R
-30.1145
-15.1555
-17.5096
BTU/LB-R
-1.6716
-0.6457
-0.9719
DENSITY:
LBMOL/CUFT
2.7998 3.4318-03 3.4886-03
LB/CUFT
50.4385 8.0548-02 6.2848-02
AVG MW
18.0153
23.4708
18.0153
36
B7
----
38
B38
B27
LIQUID
MIXED
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
1000.0000
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
2.2288-07
240.0000
0.1148
4.5103-06
1.1533-05
7.9904-06
22.1003
9.5607
3.0300
1.5468
2.4131-02
0.2828
0.1885
7.4827-02
27.0313
16.0720
3.3292-03
48.3304
16.0720
48.3304
2.7533
3.4652-02
1.2894-10
3.3893-05
2.9292-02
6.4851
430.0000
520.0000
13.0693
16.1824
56.6421
170.8902
157.6096
2.0205-02
29.0384
29.0231
4.3084
35.9390
0.4661
1.3119-15
1000.0000
2.8054+04
1151.8425
1905.2535
1.0930+05
4.4810+04
11.6077
647.0000
0.0
1.0000
0.0
185.0004
105.0000
0.3412
0.6588
0.0
1.8819+04 -6.3707+04
670.8079 -1110.4986
1.8819+07 -1.2138+08
-27.4635
-0.9790
-82.5614
-1.4391
0.8682
24.3556
28.0538
4.2518-02
2.4392
57.3683
STREAM ID
FROM :
TO
:
40
B10
B51
41
B41
B27
43
---B5
44
B27
B11
45
B5
----
SUBSTREAM: MIXED
PHASE:
VAPOR
MIXED
LIQUID
MIXED
LIQUID
CO2
2.0353
0.0
0.0
2.2288-07
0.0
CO
3.3416-04
0.0
0.0
0.0
0.0
WATER
22.4599 2220.3374 2.7754+05 2460.3374 2.7754+05
METHANOL
59.7421
0.0
0.0
0.1148
0.0
DME
345.6446
0.0
0.0
4.5103-06
0.0
METHY-01
0.0
0.0
0.0
1.1533-05
0.0
METHY-02
0.0
0.0
0.0
7.9904-06
0.0
N-PRO-01
0.0
0.0
0.0
22.1003
0.0
METHA-01
0.0
0.0
0.0
9.5607
0.0
N-BUT-01
0.0
0.0
0.0
3.0300
0.0
METHY-03
0.0
0.0
0.0
1.5468
0.0
3-MET-01
0.0
0.0
0.0
2.4131-02
0.0
VALER-01
0.0
0.0
0.0
0.2828
0.0
ETHANOL
0.0
0.0
0.0
0.1885
0.0
CIS-C-01
0.0
0.0
0.0
7.4827-02
0.0
METHY-05
0.0
0.0
0.0
27.0313
0.0
DIETH-01
0.0
0.0
0.0
16.0720
0.0
2-MET-01
0.0
0.0
0.0
3.3292-03
0.0
METHY-06
0.0
0.0
0.0
48.3304
0.0
DIETH-02
0.0
0.0
0.0
16.0720
0.0
METHY-07
0.0
0.0
0.0
48.3304
0.0
3-MET-02
0.0
0.0
0.0
2.7533
0.0
TERT--01
0.0
0.0
0.0
3.4652-02
0.0
METHANE
2.0489
0.0
0.0
1.2894-10
0.0
ETHYLENE
0.0
0.0
0.0
3.3893-05
0.0
CYCLO-01
0.0
0.0
0.0
2.9292-02
0.0
PROPYLEN
0.0
0.0
0.0
6.4851
0.0
ISOBUTAN
0.0
0.0
0.0
430.0000
0.0
N-BUTANE
0.0
0.0
0.0
520.0000
0.0
TRANS-BU
0.0
0.0
0.0
13.0693
0.0
1-BUTENE
0.0
0.0
0.0
16.1824
0.0
ISOBUTEN
0.0
0.0
0.0
56.6421
0.0
CIS-2-01
0.0
0.0
0.0
170.8902
0.0
2-MET-02
0.0
0.0
0.0
157.6096
0.0
1:2-B-01
0.0
0.0
0.0
2.0205-02
0.0
1:3-B-01
0.0
0.0
0.0
29.0384
0.0
N-PENTAN
0.0
0.0
0.0
29.0231
0.0
N-HEXANE
0.0
0.0
0.0
4.3084
0.0
N-HEPTAN
0.0
0.0
0.0
35.9390
0.0
BENZENE
0.0
0.0
0.0
0.4661
0.0
NITRO-01
3.5212-03
0.0
0.0
1.3119-15
0.0
TOTAL FLOW:
LBMOL/HR
431.9346 2220.3374 2.7754+05 4125.5909 2.7754+05
LB/HR
1.8365+04 4.0000+04 5.0000+06 1.4930+05 5.0000+06
CUFT/HR
1.1885+04 1.5070+04 8.1150+04 6.1630+04 8.2919+04
STATE VARIABLES:
TEMP
F
707.0000
331.5216
90.0000
234.4126
128.5043
PRES
PSIA
455.0000
105.0000
40.0000
105.0000
37.0000
VFRAC
1.0000 8.0047-02
0.0
0.2020
0.0
LFRAC
0.0
0.9200
1.0000
0.7980
1.0000
SFRAC
0.0
0.0
0.0
0.0
0.0
ENTHALPY:
BTU/LBMOL
-6.9361+04 -1.1662+05 -1.2260+05 -9.2184+04 -1.2195+05
BTU/LB
-1631.3358 -6473.3749 -6805.4650 -2547.2934 -6769.0484
BTU/HR
-2.9959+07 -2.5893+08 -3.4027+10 -3.8031+08 -3.3845+10
ENTROPY:
BTU/LBMOL-R
-41.4961
-29.9606
-38.4569
-53.4828
-37.3107
BTU/LB-R
-0.9760
-1.6631
-2.1347
-1.4779
-2.0711
DENSITY:
LBMOL/CUFT
3.6342-02
0.1473
3.4201 6.6941-02
3.3471
LB/CUFT
1.5452
2.6542
61.6141
2.4225
60.2998
AVG MW
42.5179
18.0153
18.0153
36.1890
18.0153
46 47 49 5 50
------------STREAM ID
FROM :
TO
:
51 52 53 54 55
-------------46
B45
----
47
B-601
B4
49
B4
B5
5
---B41
50
B55
B35
SUBSTREAM: MIXED
PHASE:
LIQUID
VAPOR
VAPOR
LIQUID
LIQUID
CO2
8.0145-11
11.3070
11.3070
0.0
0.7337
WATER
8955.5642 9233.1865 9233.1865 2220.3374
19.4370
METHANOL
2.5719-03
0.1140
0.1140
0.0
2.5243-02
DME
4.8065-11 6.6466-06 6.6466-06
0.0
2.1905-06
METHY-01
1.5587-08 1.0804-05 1.0804-05
0.0
4.1947-06
METHY-02
9.1987-23 7.3112-06 7.3112-06
0.0
3.5183-06
N-PRO-01
1.2776-07
21.4941
21.4941
0.0
6.7634
METHA-01
36.8870
48.0445
48.0445
0.0
1.5543
N-BUT-01
1.8333-06
2.9074
2.9074
0.0
0.4894
METHY-03
3.3346-07
1.5345
1.5345
0.0
0.3799
3-MET-01
0.5670
0.5986
0.5986
0.0
1.8958-03
VALER-01
5.7960-09
0.2673
0.2673
0.0
2.7867-02
ETHANOL
4.1307-04
0.1831
0.1831
0.0
2.3468-02
CIS-C-01
1.3796
1.4784
1.4784
0.0
6.7688-03
METHY-05
8.3389-09
25.9896
25.9896
0.0
2.8161
DIETH-01
2.1676-07
15.4042
15.4042
0.0
1.3161
2-MET-01
2.8277-06 3.0470-03 3.0470-03
0.0
1.2834-04
METHY-06
4.7059-07
46.3720
46.3720
0.0
3.5517
DIETH-02
2.1676-07
15.4042
15.4042
0.0
1.3161
METHY-07
4.7059-07
46.3720
46.3720
0.0
3.5517
3-MET-02
2.4858-11
2.6112
2.6112
0.0
0.1210
TERT--01
1.8541-08 3.2580-02 3.2580-02
0.0
2.8301-03
METHANE
4.3694-14
9.1456
9.1456
0.0
0.1347
ETHYLENE
7.3073-09
349.5930
349.5930
0.0
22.3675
CYCLO-01
3.9100-07 9.8375-02 9.8375-02
0.0
3.0200-02
PROPYLEN
3.1711-04
994.9095
994.9095
0.0
241.9030
ISOBUTAN
8.8870-02
459.7299
459.7299
0.0
174.7682
N-BUTANE
0.5786
583.5666
583.5666
0.0
227.3691
TRANS-BU
1.2811-02
13.0695
13.0695
0.0
5.0995
1-BUTENE
5.5786-03
16.1828
16.1828
0.0
6.2466
ISOBUTEN
1.8830-02
56.6444
56.6444
0.0
21.8971
CIS-2-01
0.2558
171.0384
171.0384
0.0
66.5392
2-MET-02
4.6287-30
153.7638
153.7638
0.0
76.6415
1:2-B-01
8.9541-05 2.0041-02 2.0041-02
0.0
7.6172-03
1:3-B-01
1.2775-02
28.8417
28.8417
0.0
11.1677
N-PENTAN
1.6981-29
29.0234
29.0234
0.0
12.8032
N-HEXANE
1.0095-23
4.3085
4.3085
0.0
1.2239
N-HEPTAN
4.9413-27
35.9388
35.9388
0.0
4.4681
BENZENE
4.6256
5.2229
5.2229
0.0
5.8342-02
NITRO-01
5.9292-19 1.9562-02 1.9562-02
0.0
1.1660-04
TOTAL FLOW:
LBMOL/HR
9000.0000 1.2384+04 1.2384+04 2220.3374
914.8441
LB/HR
1.6449+05 3.3112+05 3.3112+05 4.0000+04 4.9444+04
CUFT/HR
2954.5067 3.8730+06 4.1965+06
793.0447 1451.6518
STATE VARIABLES:
TEMP
F
248.4029
268.8775
235.0000
384.5000
114.9356
PRES
PSIA
65.0000
25.0000
22.0000
207.4000
557.9000
VFRAC
0.0
1.0000
1.0000
0.0
0.0
LFRAC
1.0000
0.0
0.0
1.0000
1.0000
SFRAC
0.0
0.0
0.0
0.0
0.0
ENTHALPY:
BTU/LBMOL
-1.1934+05 -8.1748+04 -8.2166+04 -1.1662+05 -4.0166+04
BTU/LB
-6529.9615 -3057.4862 -3073.1247 -6473.3749 -743.1667
BTU/HR
-1.0741+09 -1.0124+09 -1.0176+09 -2.5893+08 -3.6745+07
ENTROPY:
BTU/LBMOL-R
-33.9327
-18.7231
-19.0568
-30.1145
-80.7928
BTU/LB-R
-1.8567
-0.7003
-0.7128
-1.6716
-1.4949
DENSITY:
LBMOL/CUFT
3.0462 3.1976-03 2.9511-03
2.7998
0.6302
LB/CUFT
55.6727 8.5494-02 7.8904-02
50.4385
34.0607
AVG MW
18.2761
26.7369
26.7369
18.0153
54.0466
STREAM ID
FROM :
TO
:
51
B36
B35
52
---B9
53
B9
----
54
B10
B52
55
B10
B53
SUBSTREAM: MIXED
PHASE:
LIQUID
LIQUID
LIQUID
VAPOR
VAPOR
CO2
0.2824
0.0
0.0
2.4875
2.8268
CO
0.0
0.0
0.0
4.0842-04 4.6411-04
WATER
257.8141 3.0530+04 3.0530+04
27.4509
31.1943
METHANOL
7.9743-02
0.0
0.0
73.0181
82.9751
DME
1.3400-06
0.0
0.0
422.4545
480.0619
METHY-01
4.4335-06
0.0
0.0
0.0
0.0
METHY-02
2.9322-06
0.0
0.0
0.0
0.0
N-PRO-01
13.8355
0.0
0.0
0.0
0.0
METHA-01
9.5062
0.0
0.0
0.0
0.0
N-BUT-01
2.3935
0.0
0.0
0.0
0.0
METHY-03
1.1189
0.0
0.0
0.0
0.0
3-MET-01
2.9682-02
0.0
0.0
0.0
0.0
VALER-01
0.2389
0.0
0.0
0.0
0.0
ETHANOL
0.1584
0.0
0.0
0.0
0.0
CIS-C-01
9.1847-02
0.0
0.0
0.0
0.0
METHY-05
23.0997
0.0
0.0
0.0
0.0
DIETH-01
14.0639
0.0
0.0
0.0
0.0
2-MET-01
2.9145-03
0.0
0.0
0.0
0.0
METHY-06
42.7573
0.0
0.0
0.0
0.0
DIETH-02
14.0639
0.0
0.0
0.0
0.0
METHY-07
42.7573
0.0
0.0
0.0
0.0
3-MET-02
2.4890
0.0
0.0
0.0
0.0
TERT--01
2.9679-02
0.0
0.0
0.0
0.0
METHANE
4.9130-02
0.0
0.0
2.5042
2.8457
ETHYLENE
8.5995
0.0
0.0
0.0
0.0
CYCLO-01
1.7288-02
0.0
0.0
0.0
0.0
PROPYLEN
120.1068
0.0
0.0
0.0
0.0
ISOBUTAN
136.9744
0.0
0.0
0.0
0.0
N-BUTANE
217.1384
0.0
0.0
0.0
0.0
TRANS-BU
4.9546
0.0
0.0
0.0
0.0
1-BUTENE
5.2482
0.0
0.0
0.0
0.0
ISOBUTEN
18.4395
0.0
0.0
0.0
0.0
CIS-2-01
67.8696
0.0
0.0
0.0
0.0
2-MET-02
56.7988
0.0
0.0
0.0
0.0
1:2-B-01
9.0135-03
0.0
0.0
0.0
0.0
1:3-B-01
9.7069
0.0
0.0
0.0
0.0
N-PENTAN
13.6767
0.0
0.0
0.0
0.0
N-HEXANE
3.0037
0.0
0.0
0.0
0.0
N-HEPTAN
31.3724
0.0
0.0
0.0
0.0
BENZENE
0.5366
0.0
0.0
0.0
0.0
NITRO-01
4.2140-05
0.0
0.0
4.3036-03 4.8905-03
TOTAL FLOW:
LBMOL/HR
1119.3141 3.0530+04 3.0530+04
527.9200
599.9091
LB/HR
5.8801+04 5.5000+05 5.5000+05 2.2446+04 2.5507+04
CUFT/HR
1481.2503 8926.5306 9121.0577 1.4527+04 1.6507+04
STATE VARIABLES:
TEMP
F
115.2521
90.0000
128.4990
707.0000
707.0000
PRES
PSIA
557.9000
40.0000
35.0000
455.0000
455.0000
VFRAC
0.0
0.0
0.0
1.0000
1.0000
LFRAC
1.0000
1.0000
1.0000
0.0
0.0
SFRAC
0.0
0.0
0.0
0.0
0.0
ENTHALPY:
BTU/LBMOL
-7.3367+04 -1.2260+05 -1.2195+05 -6.9361+04 -6.9361+04
BTU/LB
-1396.5889 -6805.4650 -6769.0535 -1631.3358 -1631.3358
BTU/HR
-8.2120+07 -3.7430+09 -3.7230+09 -3.6617+07 -4.1610+07
ENTROPY:
BTU/LBMOL-R
-79.2895
-38.4569
-37.3109
-41.4961
-41.4961
BTU/LB-R
-1.5093
-2.1347
-2.0711
-0.9760
-0.9760
DENSITY:
LBMOL/CUFT
0.7557
3.4201
3.3472 3.6342-02 3.6342-02
LB/CUFT
39.6966
61.6141
60.3000
1.5452
1.5452
AVG MW
52.5327
18.0153
18.0153
42.5179
42.5179
56 57 58 59 6
------------STREAM ID
FROM :
TO
:
61 63 64 65 66
-------------56
B32
B73
57
B11
B31
58
---B11
59
B11
----
6
B19
B20
MAX CONV. ERROR:

0.0
0.0
0.0
0.0
-8.5053-05
SUBSTREAM: MIXED
PHASE:
LIQUID
VAPOR
VAPOR
MIXED
MIXED
CO2
0.0
2.2288-07
0.0
0.0
1.7947-07
WATER
4429.1700 2460.3374 3330.5061 3330.5061
277.6224
METHANOL
0.0
0.1148
0.0
0.0
0.1114
DME
0.0
4.5103-06
0.0
0.0
3.8616-06
METHY-01
0.0
1.1533-05
0.0
0.0
1.0788-05
METHY-02
0.0
7.9904-06
0.0
0.0
7.3112-06
N-PRO-01
0.0
22.1003
0.0
0.0
21.4941
METHA-01
0.0
9.5607
0.0
0.0
11.1575
N-BUT-01
0.0
3.0300
0.0
0.0
2.9074
METHY-03
0.0
1.5468
0.0
0.0
1.5345
3-MET-01
0.0
2.4131-02
0.0
0.0
3.1622-02
VALER-01
0.0
0.2828
0.0
0.0
0.2673
ETHANOL
0.0
0.1885
0.0
0.0
0.1827
CIS-C-01
0.0
7.4827-02
0.0
0.0
9.8800-02
METHY-05
0.0
27.0313
0.0
0.0
25.9896
DIETH-01
0.0
16.0720
0.0
0.0
15.4042
2-MET-01
0.0
3.3292-03
0.0
0.0
3.0442-03
METHY-06
0.0
48.3304
0.0
0.0
46.3720
DIETH-02
0.0
16.0720
0.0
0.0
15.4042
METHY-07
0.0
48.3304
0.0
0.0
46.3720
3-MET-02
0.0
2.7533
0.0
0.0
2.6112
TERT--01
0.0
3.4652-02
0.0
0.0
3.2580-02
METHANE
0.0
1.2894-10
0.0
0.0
1.1396-10
ETHYLENE
0.0
3.3893-05
0.0
0.0
3.0046-05
CYCLO-01
0.0
2.9292-02
0.0
0.0
2.4660-02
PROPYLEN
0.0
6.4851
0.0
0.0
5.1660
ISOBUTAN
0.0
430.0000
0.0
0.0
459.5317
N-BUTANE
0.0
520.0000
0.0
0.0
582.9851
TRANS-BU
0.0
13.0693
0.0
0.0
13.0566
1-BUTENE
0.0
16.1824
0.0
0.0
16.1763
ISOBUTEN
0.0
56.6421
0.0
0.0
56.6222
CIS-2-01
0.0
170.8902
0.0
0.0
170.7823
2-MET-02
0.0
157.6096
0.0
0.0
153.7638
1:2-B-01
0.0
2.0205-02
0.0
0.0
1.9951-02
1:3-B-01
0.0
29.0384
0.0
0.0
28.8280
N-PENTAN
0.0
29.0231
0.0
0.0
29.0234
N-HEXANE
0.0
4.3084
0.0
0.0
4.3085
N-HEPTAN
0.0
35.9390
0.0
0.0
35.9388
BENZENE
0.0
0.4661
0.0
0.0
0.5973
TOTAL FLOW:
LBMOL/HR
4429.1700 4125.5909 3330.5061 3330.5061 2024.4210
LB/HR
7.9793+04 1.4930+05 6.0000+04 6.0000+04 1.1452+05
CUFT/HR
1583.6826 3.3476+05 3.1150+05 2.3677+04 1.3764+05
STATE VARIABLES:
TEMP
F
385.7323
296.4520
320.0000
315.9497
227.8743
PRES
PSIA
475.0000
100.0000
89.4579
84.4579
100.0000
VFRAC
0.0
1.0000
1.0000 6.8944-02
0.9200
LFRAC
1.0000
0.0
0.0
0.9311 7.9986-02
SFRAC
0.0
0.0
0.0
0.0
0.0
ENTHALPY:
BTU/LBMOL
-1.1659+05 -7.9955+04 -1.0199+05 -1.1714+05 -5.7399+04
BTU/LB
-6471.6379 -2209.3621 -5661.1831 -6502.0750 -1014.6234
BTU/HR
-5.1639+08 -3.2986+08 -3.3967+08 -3.9012+08 -1.1620+08
ENTROPY:
BTU/LBMOL-R
-30.0802
-36.8153
-11.1499
-30.5669
-71.5927
BTU/LB-R
-1.6697
-1.0173
-0.6189
-1.6967
-1.2655
DENSITY:
LBMOL/CUFT
2.7968 1.2324-02 1.0692-02
0.1407 1.4708-02
LB/CUFT
50.3843
0.4460
0.1926
2.5341
0.8320
AVG MW
18.0153
36.1890
18.0153
18.0153
56.5716
STREAM ID
FROM :
TO
:
61
B75
B56
63
B56
B59
64
B59
B61
65
B61
B79
66
B51
B48
SUBSTREAM: MIXED
PHASE:
MIXED
MIXED
VAPOR
VAPOR
VAPOR
CO2
7.5779-08 7.5779-08
0.0
0.0
2.0353
CO
0.0
0.0
0.0
0.0
3.3416-04
WATER
836.5147
836.5147
892.1471
892.1471
22.4599
METHANOL
3.9025-02 3.9025-02 1.8104-02 1.8104-02
59.7421
DME
1.5335-06 1.5335-06 1.3581-06 1.3581-06
345.6446
METHY-01
3.9212-06 3.9212-06 2.1725-06 2.1725-06
0.0
METHY-02
2.7167-06 2.7167-06 1.3995-06 1.3995-06
0.0
N-PRO-01
7.5141
7.5141
1.6033
1.6033
0.0
METHA-01
3.2506
3.2506
0.0
0.0
0.0
N-BUT-01
1.0302
1.0302
0.2316
0.2316
0.0
METHY-03
0.5259
0.5259 1.2699-02 1.2699-02
0.0
3-MET-01
8.2045-03 8.2045-03 4.5896-02 4.5896-02
0.0
VALER-01
9.6168-02 9.6168-02 2.2683-02 2.2683-02
0.0
ETHANOL
6.4091-02 6.4091-02 2.7928-02 2.7928-02
0.0
CIS-C-01
2.5441-02 2.5441-02 6.6785-02 6.6785-02
0.0
METHY-05
9.1906
9.1906
1.5175
1.5175
0.0
DIETH-01
5.4645
5.4645
0.9726
0.9726
0.0
2-MET-01
1.1319-03 1.1319-03 4.4011-04 4.4011-04
0.0
METHY-06
16.4323
16.4323
2.8523
2.8523
0.0
DIETH-02
5.4645
5.4645
0.9726
0.9726
0.0
METHY-07
16.4323
16.4323
2.8523
2.8523
0.0
3-MET-02
0.9361
0.9361
0.1669
0.1669
0.0
TERT--01
1.1782-02 1.1782-02 4.2706-03 4.2706-03
0.0
METHANE
4.3840-11 4.3840-11
0.0
0.0
2.0489
ETHYLENE
1.1524-05 1.1524-05
85.8498
85.8498
0.0
CYCLO-01
9.9593-03 9.9593-03 2.6082-02 2.6082-02
0.0
PROPYLEN
2.2049
2.2049
204.4185
204.4185
0.0
ISOBUTAN
146.2000
146.2000
123.1135
123.1135
0.0
N-BUTANE
176.8000
176.8000
171.5250
171.5250
0.0
TRANS-BU
4.4436
4.4436
0.0
0.0
0.0
1-BUTENE
5.5020
5.5020
0.0
0.0
0.0
ISOBUTEN
19.2583
19.2583
0.0
0.0
0.0
CIS-2-01
58.1027
58.1027
40.5538
40.5538
0.0
2-MET-02
53.5873
53.5873
42.1026
42.1026
0.0
1:2-B-01
6.8697-03 6.8697-03 4.9220-03 4.9220-03
0.0
1:3-B-01
9.8731
9.8731
5.7288
5.7288
0.0
N-PENTAN
9.8678
9.8678
0.0
0.0
0.0
N-HEXANE
1.4649
1.4649
0.0
0.0
0.0
N-HEPTAN
12.2193
12.2193
0.0
0.0
0.0
BENZENE
0.1585
0.1585
0.0
0.0
0.0
NITRO-01
4.4605-16 4.4605-16
0.0
0.0
3.5212-03
TOTAL FLOW:
LBMOL/HR
1402.7009 1402.7009 1576.8380 1576.8380
431.9346
LB/HR
5.0762+04 5.0762+04 5.0762+04 5.0762+04 1.8365+04
CUFT/HR
2.2966+05 3.1838+05 7.5960+05 6.5927+05 1.2017+04
STATE VARIABLES:
TEMP
F
920.1381
921.2617
887.0000
709.1246
707.0000
PRES
PSIA
90.0000
65.0000
30.0000
30.0000
450.0000
VFRAC
0.9950
0.9954
1.0000
1.0000
1.0000
LFRAC
5.0245-03 4.5801-03
0.0
0.0
0.0
SFRAC
0.0
0.0
0.0
0.0
0.0
ENTHALPY:
BTU/LBMOL
-6.6105+04 -6.6105+04 -5.4948+04 -5.8691+04 -6.9361+04
BTU/LB
-1826.6625 -1826.6625 -1706.8445 -1823.1385 -1631.3358
BTU/HR
-9.2726+07 -9.2726+07 -8.6643+07 -9.2547+07 -2.9959+07
ENTROPY:
BTU/LBMOL-R
-23.5173
-22.8742
-15.8063
-18.7853
-41.4741
BTU/LB-R
-0.6498
-0.6321
-0.4910
-0.5835
-0.9755
DENSITY:
LBMOL/CUFT
6.1076-03 4.4058-03 2.0759-03 2.3918-03 3.5942-02
LB/CUFT
0.2210
0.1594 6.6828-02 7.6998-02
1.5282
AVG MW
36.1890
36.1890
32.1925
32.1925
42.5179
67 68 69 7 70
------------STREAM ID
FROM :
TO
:
71 72 73 78 8
------------67
B48
B60
68
B34
B69
69
B71
B3
7
B6
B9
70
B49
B89
SUBSTREAM: MIXED
PHASE:
VAPOR
VAPOR
VAPOR
VAPOR
VAPOR
CO2
2.0353
0.0
0.0
11.3070
4.5228
CO
3.3416-04
0.0
0.0
0.0
4.0842-04
WATER
4451.6299 4813.5183 4429.1700
277.6224 4840.9692
METHANOL
59.7421
0.1091
0.0
0.1115
73.1273
DME
345.6446 8.3922-06
0.0
6.6465-06
422.4545
METHY-01
0.0
1.1252-05
0.0
1.0788-05 1.1252-05
METHY-02
0.0
5.9089-06
0.0
7.3112-06 5.9089-06
N-PRO-01
0.0
6.6259
0.0
21.4941
6.6259
METHA-01
0.0
7.9911
0.0
11.1575
7.9911
N-BUT-01
0.0
0.8371
0.0
2.9074
0.8371
METHY-03
0.0
0.9215
0.0
1.5345
0.9215
3-MET-01
0.0
0.1384
0.0
3.1622-02
0.1384
VALER-01
0.0
7.1684-02
0.0
0.2673 7.1684-02
ETHANOL
0.0
0.1394
0.0
0.1827
0.1394
CIS-C-01
0.0
0.2675
0.0
9.8800-02
0.2675
METHY-05
0.0
4.0637
0.0
25.9896
4.0637
DIETH-01
0.0
2.6929
0.0
15.4042
2.6929
2-MET-01
0.0
1.3032-03
0.0
3.0442-03 1.3032-03
METHY-06
0.0
7.8081
0.0
46.3720
7.8081
DIETH-02
0.0
2.6929
0.0
15.4042
2.6929
METHY-07
0.0
7.8081
0.0
46.3720
7.8081
3-MET-02
0.0
0.3942
0.0
2.6112
0.3942
TERT--01
0.0
1.4048-02
0.0
3.2580-02 1.4048-02
METHANE
2.0489
0.0
0.0
9.1456
2.5042
ETHYLENE
0.0
22.0190
0.0
349.5930
22.0190
CYCLO-01
0.0
6.3685-03
0.0
9.8375-02 6.3685-03
PROPYLEN
0.0
43.4288
0.0
994.9092
43.4288
ISOBUTAN
0.0
18.4039
0.0
459.6410
18.4039
N-BUTANE
0.0
26.6494
0.0
582.9881
26.6494
TRANS-BU
0.0
8.8932
0.0
13.0567
8.8932
1-BUTENE
0.0
6.5928
0.0
16.1773
6.5928
ISOBUTEN
0.0
16.3667
0.0
56.6256
16.3667
CIS-2-01
0.0
7.2359
0.0
170.7826
7.2359
2-MET-02
0.0
5.5533
0.0
153.7638
5.5533
1:2-B-01
0.0
1.2927-03
0.0
1.9951-02 1.2927-03
1:3-B-01
0.0
1.2162
0.0
28.8289
1.2162
N-PENTAN
0.0
3.6584
0.0
29.0234
3.6584
N-HEXANE
0.0
0.4373
0.0
4.3085
0.4373
N-HEPTAN
0.0
5.6716-02
0.0
35.9388 5.6716-02
BENZENE
0.0
0.0
0.0
0.5973
0.0
NITRO-01
3.5212-03
0.0
0.0
1.9562-02 7.8248-03
TOTAL FLOW:
LBMOL/HR
4861.1046 5016.6147 4429.1700 3384.4210 5546.5735
LB/HR
9.8158+04 9.8068+04 7.9793+04 1.6664+05 1.2060+05
CUFT/HR
1.3525+05 1.7734+05 1.2055+05 3.7453+05 1.6278+05
STATE VARIABLES:
TEMP
F
707.0000
923.8490
707.0000
210.6084
661.6112
PRES
PSIA
450.0000
420.0000
460.0000
65.0000
410.0000
VFRAC
1.0000
1.0000
1.0000
1.0000
1.0000
LFRAC
0.0
0.0
0.0
0.0
0.0
SFRAC
0.0
0.0
0.0
0.0
0.0
ENTHALPY:
BTU/LBMOL
-9.6083+04 -9.3039+04 -9.8689+04 -2.9016+04 -9.3315+04
BTU/LB
-4758.3763 -4759.3535 -5478.0903 -589.3321 -4291.5430
BTU/HR
-4.6707+08 -4.6674+08 -4.3711+08 -9.8204+07 -5.1758+08
ENTROPY:
BTU/LBMOL-R
-13.1066
-9.9738
-10.9741
-51.2137
-14.3502
BTU/LB-R
-0.6491
-0.5102
-0.6092
-1.0402
-0.6600
DENSITY:
LBMOL/CUFT
3.5942-02 2.8288-02 3.6741-02 9.0365-03 3.4073-02
LB/CUFT
0.7258
0.5530
0.6619
0.4449
0.7409
AVG MW
20.1925
19.5486
18.0153
49.2362
21.7438
STREAM ID
FROM :
TO
:
71
---B26
72
B57
B-606
73
B3
B48
SUBSTREAM: MIXED
PHASE:
LIQUID
VAPOR
VAPOR
CO2
0.0
11.0246
0.0
WATER
1.6653+04
19.8082 4429.1700
METHANOL
0.0
3.1714-02
0.0
DME
0.0
5.3065-06
0.0
METHY-01
0.0
6.3544-06
0.0
METHY-02
0.0
4.3790-06
0.0
N-PRO-01
0.0
7.6586
0.0
METHA-01
0.0
1.6513
0.0
N-BUT-01
0.0
0.5139
0.0
METHY-03
0.0
0.4156
0.0
3-MET-01
0.0
1.9404-03
0.0
VALER-01
0.0
2.8364-02
0.0
ETHANOL
0.0
2.4332-02
0.0
CIS-C-01
0.0
6.9529-03
0.0
METHY-05
0.0
2.8900
0.0
DIETH-01
0.0
1.3403
0.0
2-MET-01
0.0
1.2971-04
0.0
METHY-06
0.0
3.6147
0.0
DIETH-02
0.0
1.3403
0.0
METHY-07
0.0
3.6147
0.0
3-MET-02
0.0
0.1222
0.0
TERT--01
0.0
2.9012-03
0.0
METHANE
0.0
9.0965
0.0
ETHYLENE
0.0
340.9935
0.0
CYCLO-01
0.0
8.1087-02
0.0
PROPYLEN
0.0
874.8024
0.0
ISOBUTAN
0.0
322.6666
0.0
N-BUTANE
0.0
365.8497
0.0
TRANS-BU
0.0
8.1021
0.0
1-BUTENE
0.0
10.9290
0.0
ISOBUTEN
0.0
38.1861
0.0
CIS-2-01
0.0
102.9130
0.0
2-MET-02
0.0
96.9650
0.0
1:2-B-01
0.0
1.0938-02
0.0
1:3-B-01
0.0
19.1220
0.0
N-PENTAN
0.0
15.3467
0.0
N-HEXANE
0.0
1.3048
0.0
N-HEPTAN
0.0
4.5664
0.0
BENZENE
0.0
6.0714-02
0.0
NITRO-01
0.0
1.9520-02
0.0
TOTAL FLOW:
LBMOL/HR
1.6653+04 2265.1069 4429.1700
LB/HR
3.0000+05 1.0784+05 7.9793+04
CUFT/HR
4869.0167 2.4294+05 1.2188+05
STATE VARIABLES:
TEMP
F
90.0000
109.9994
707.0000
PRES
PSIA
40.0000
57.0000
455.0000
VFRAC
0.0
1.0000
1.0000
LFRAC
1.0000
0.0
0.0
SFRAC
0.0
0.0
0.0
ENTHALPY:
BTU/LBMOL
-1.2260+05 -1.5844+04 -9.8689+04
BTU/LB
-6805.4650 -332.7990 -5478.0903
BTU/HR
-2.0416+09 -3.5888+07 -4.3711+08
ENTROPY:
BTU/LBMOL-R
-38.4569
-51.3188
-10.9524
BTU/LB-R
-2.1347
-1.0780
-0.6079
DENSITY:
LBMOL/CUFT
3.4201 9.3239-03 3.6342-02
LB/CUFT
61.6141
0.4439
0.6547
AVG MW
18.0153
47.6072
18.0153
78
---B43
8
B15
B14
LIQUID
VAPOR
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
831.7364
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
10.9292
392.3345
3.1174-02
5.0464-06
5.9325-06
7.1457-06
18.6069
6.8828
2.0401
1.2024
3.8730-02
0.2151
5.3939-02
0.1084
20.2296
11.6164
1.0858-03
32.8431
11.6164
32.8431
2.0166
1.5187-02
9.0694
337.5400
7.7196-02
842.4347
300.3461
338.8976
7.5126
10.1680
35.4851
95.2514
153.6481
1.0147-02
17.6777
28.9866
4.2958
35.7037
0.5254
1.9493-02
831.7364
3.5000+04
1155.8764
2761.2736
1.2766+05
9.8453+05
100.0000
369.0000
0.0
1.0000
0.0
138.3754
18.0000
1.0000
0.0
0.0
3431.2963 -3.2681+04
81.5410 -706.8803
2.8539+06 -9.0240+07
-48.8265
-1.1603
-45.6354
-0.9871
0.7196
30.2801
42.0806
2.8047-03
0.1297
46.2322
85 86 87 88 89
--------------
80 81 82 83 84
-------------STREAM ID
FROM :
TO
:
SUBSTREAM: MIXED
PHASE:
PROPYLEN
TOTAL FLOW:
LBMOL/HR
LB/HR
CUFT/HR
STATE VARIABLES:
TEMP
F
PRES
PSIA
VFRAC
LFRAC
SFRAC
ENTHALPY:
BTU/LBMOL
BTU/LB
BTU/HR
ENTROPY:
BTU/LBMOL-R
BTU/LB-R
DENSITY:
LBMOL/CUFT
LB/CUFT
AVG MW
80
B43
B7
81
B7
B44
82
B44
B46
83
B2
----
84
B46
B2
MIXED
VAPOR
VAPOR
LIQUID
VAPOR
831.7364
831.7364
831.7364
831.7364
831.7364
831.7364
3.5000+04
3.5567+04
831.7364
3.5000+04
8.5364+04
831.7364
3.5000+04
3.9055+04
831.7364
3.5000+04
1155.8764
831.7364
3.5000+04
1.5532+04
2.5530
51.0000
0.4328
0.5672
0.0
-0.6047
48.0000
1.0000
0.0
0.0
87.2693
125.0000
1.0000
0.0
0.0
100.0000
372.0000
0.0
1.0000
0.0
192.8858
375.0000
1.0000
0.0
0.0
3431.2963
81.5410
2.8539+06
7561.0494
179.6800
6.2888+06
8857.3491
210.4851
7.3670+06
3431.2963
81.5410
2.8539+06
1.0631+04
252.6387
8.8424+06
-47.6624
-1.1326
-38.6084
-0.9175
-37.9302
-0.9014
-48.8265
-1.1603
-37.1522
-0.8829
2.3385-02
0.9841
42.0806
9.7434-03
0.4100
42.0806
2.1297-02
0.8962
42.0806
0.7196
30.2801
42.0806
5.3550-02
2.2534
42.0806
STREAM ID
FROM :
TO
:
85
B40
B70
86
B81
B67
87
B50
B62
88
B63
B79
89
B65
B79
MAX CONV. ERROR:

0.0
0.0
1.6066-09
0.0
0.0
SUBSTREAM: MIXED
PHASE:
VAPOR
VAPOR
VAPOR
VAPOR
VAPOR
CO2
0.0
4.5228
11.3070
0.0
0.0
CO
0.0
0.0
4.6411-04
0.0
0.0
WATER
5272.0327 5272.0327 6065.2080
865.9075
865.9075
METHANOL
0.1191
0.1191
83.1306 1.7572-02 1.7572-02
DME
9.7438-06 9.7438-06
480.0619 1.3182-06 1.3182-06
METHY-01
1.6184-05 1.6184-05 2.3579-05 2.1086-06 2.1086-06
METHY-02
1.0752-05 1.0752-05 1.5707-05 1.3584-06 1.3584-06
N-PRO-01
11.7045
11.7045
18.6330
1.5562
1.5562
METHA-01
16.9359
16.9359
33.9543
0.0
0.0
N-BUT-01
1.7738
1.7738
2.9137
0.2248
0.2248
METHY-03
1.7977
1.7977
2.0283 1.2326-02 1.2326-02
3-MET-01
0.3646
0.3646
0.6060 4.4546-02 4.4546-02
1:1-D-01
1.0268-11 1.0268-11 1.2449-11 6.0902-14 6.0902-14
VALER-01
0.1822
0.1822
0.3088 2.2016-02 2.2016-02
ETHANOL
0.1902
0.1902
0.2505 2.7107-02 2.7107-02
CIS-C-01
0.5429
0.5429
1.1143 6.4820-02 6.4820-02
METHY-05
11.7121
11.7121
18.5506
1.4729
1.4729
DIETH-01
7.5677
7.5677
12.1505
0.9440
0.9440
2-MET-01
3.3618-03 3.3618-03 4.6302-03 4.2717-04 4.2717-04
METHY-06
22.1320
22.1320
35.3708
2.7684
2.7684
DIETH-02
7.5677
7.5677
12.1505
0.9440
0.9440
METHY-07
22.1320
22.1320
35.3708
2.7684
2.7684
3-MET-02
1.3539
1.3539
2.2204
0.1619
0.1619
TERT--01
3.0880-02 3.0880-02 4.0737-02 4.1450-03 4.1450-03
METHANE
0.0
0.0
2.8457
0.0
0.0
ETHYLENE
30.4524
30.4524
65.0054
83.3248
83.3248
CYCLO-01
9.9081-03 9.9081-03 2.2592-02 2.5315-02 2.5315-02
PROPYLEN
75.0756
75.0756
161.7297
198.4062
198.4062
ISOBUTAN
43.4622
43.4622
73.7779
119.4926
119.4926
N-BUTANE
61.1235
61.1235
105.4057
166.4802
166.4802
TRANS-BU
19.1115
19.1115
41.6706
0.0
0.0
1-BUTENE
13.6763
13.6763
30.3929
0.0
0.0
ISOBUTEN
35.7991
35.7991
77.3155
0.0
0.0
CIS-2-01
15.4729
15.4729
33.8283
39.3610
39.3610
2-MET-02
15.6265
15.6265
27.4686
40.8643
40.8643
1:2-B-01
2.1354-03 2.1354-03 6.5499-03 4.7772-03 4.7772-03
1:3-B-01
2.3601
2.3601
6.6366
5.5603
5.5603
N-PENTAN
10.0776
10.0776
17.9194
0.0
0.0
N-HEXANE
1.4428
1.4428
2.6493
0.0
0.0
N-HEPTAN
0.2245
0.2245
0.4253
0.0
0.0
NITRO-01
0.0
7.8248-03 1.9562-02
0.0
0.0
TOTAL FLOW:
LBMOL/HR
5702.0603 5706.5909 7462.4956 1530.4604 1530.4604
LB/HR
1.2040+05 1.2060+05 1.8182+05 4.9269+04 4.9269+04
CUFT/HR
2.2416+05 1.8618+05 3.8102+05 6.3680+05 6.3680+05
STATE VARIABLES:
TEMP
F
895.7698
650.0000
658.4085
703.5149
703.5149
PRES
PSIA
370.0000
365.0000
235.0000
30.0000
30.0000
VFRAC
1.0000
1.0000
1.0000
1.0000
1.0000
LFRAC
0.0
0.0
0.0
0.0
0.0
SFRAC
0.0
0.0
0.0
0.0
0.0
ENTHALPY:
BTU/LBMOL
-9.0641+04 -9.3459+04 -8.7849+04 -5.8805+04 -5.8805+04
BTU/LB
-4292.5175 -4422.2079 -3605.6219 -1826.6625 -1826.6625
BTU/HR
-5.1684+08 -5.3333+08 -6.5558+08 -8.9999+07 -8.9999+07
ENTROPY:
BTU/LBMOL-R
-10.9862
-13.1817
-15.0788
-18.8826
-18.8826
BTU/LB-R
-0.5203
-0.6237
-0.6189
-0.5866
-0.5866
DENSITY:
LBMOL/CUFT
2.5437-02 3.0651-02 1.9586-02 2.4033-03 2.4033-03
LB/CUFT
0.5371
0.6478
0.4772 7.7370-02 7.7370-02
AVG MW
21.1160
21.1341
24.3645
32.1925
32.1925
9 90 91 92 93
------------STREAM ID
FROM :
TO
:
94 95 96 97 98
-------------9
B14
B18
90
B26
----
91
B-507
B85
92
---B71
93
B52
B49
SUBSTREAM: MIXED
PHASE:
VAPOR
LIQUID
VAPOR
VAPOR
VAPOR
CO2
10.9292
0.0
11.3070
0.0
2.4875
CO
0.0
0.0
0.0
0.0
4.0842-04
WATER
392.3345 1.6653+04 6609.2246 2000.0000
27.4509
METHANOL
3.1174-02
0.0
6.0781-02
0.0
73.0181
DME
5.0464-06
0.0
2.6521-06
0.0
422.4545
METHY-01
5.9325-06
0.0
4.4138-06
0.0
0.0
METHY-02
7.1457-06
0.0
3.1950-06
0.0
0.0
N-PRO-01
18.6069
0.0
16.7783
0.0
0.0
METHA-01
6.8828
0.0
48.0445
0.0
0.0
N-BUT-01
2.0401
0.0
2.2263
0.0
0.0
METHY-03
1.2024
0.0
1.4971
0.0
0.0
3-MET-01
3.8730-02
0.0
0.4636
0.0
0.0
VALER-01
0.2151
0.0
0.2005
0.0
0.0
ETHANOL
5.3939-02
0.0
0.1010
0.0
0.0
CIS-C-01
0.1084
0.0
1.2820
0.0
0.0
METHY-05
20.2296
0.0
21.5264
0.0
0.0
DIETH-01
11.6164
0.0
12.5435
0.0
0.0
2-MET-01
1.0858-03
0.0
1.7526-03
0.0
0.0
METHY-06
32.8431
0.0
37.9829
0.0
0.0
DIETH-02
11.6164
0.0
12.5435
0.0
0.0
METHY-07
32.8431
0.0
37.9829
0.0
0.0
3-MET-02
2.0166
0.0
2.1204
0.0
0.0
TERT--01
1.5187-02
0.0
2.0020-02
0.0
0.0
METHANE
9.0694
0.0
9.1456
0.0
2.5042
ETHYLENE
337.5400
0.0
97.0937
0.0
0.0
CYCLO-01
7.7196-02
0.0
2.1665-02
0.0
0.0
PROPYLEN
842.4347
0.0
393.6787
0.0
0.0
ISOBUTAN
300.3461
0.0
97.6312
0.0
0.0
N-BUTANE
338.8976
0.0
79.0812
0.0
0.0
TRANS-BU
7.5126
0.0
13.0695
0.0
0.0
1-BUTENE
10.1680
0.0
16.1828
0.0
0.0
ISOBUTEN
35.4851
0.0
56.6444
0.0
0.0
CIS-2-01
95.2514
0.0
51.7626
0.0
0.0
2-MET-02
153.6481
0.0
29.9325
0.0
0.0
1:2-B-01
1.0147-02
0.0
5.5645-03
0.0
0.0
1:3-B-01
17.6777
0.0
11.9924
0.0
0.0
N-PENTAN
28.9866
0.0
29.0234
0.0
0.0
N-HEXANE
4.2958
0.0
4.3085
0.0
0.0
N-HEPTAN
35.7037
0.0
35.9388
0.0
0.0
BENZENE
0.5254
0.0
5.2229
0.0
0.0
NITRO-01
1.9493-02
0.0
1.9562-02
0.0
4.3036-03
TOTAL FLOW:
LBMOL/HR
2761.2736 1.6653+04 7746.6622 2000.0000
527.9200
LB/HR
1.2766+05 3.0000+05 1.8182+05 3.6031+04 2.2446+04
CUFT/HR
3.7431+05 4974.5607 2.9607+06 1.5648+04 1.6121+04
STATE VARIABLES:
TEMP
F
235.0763
128.3020
786.8357
849.0000
707.0000
PRES
PSIA
55.0000
35.0000
35.0000 1795.0000
410.0000
VFRAC
1.0000
0.0
1.0000
1.0000
1.0000
LFRAC
0.0
1.0000
0.0
0.0
0.0
SFRAC
0.0
0.0
0.0
0.0
0.0
ENTHALPY:
BTU/LBMOL
-3.0730+04 -1.2195+05 -8.4627+04 -9.7422+04 -6.9361+04
BTU/LB
-664.6842 -6769.2438 -3605.6253 -5407.7608 -1631.3358
BTU/HR
-8.4853+07 -2.0308+09 -6.5558+08 -1.9484+08 -3.6617+07
ENTROPY:
BTU/LBMOL-R
-44.8342
-37.3167
-8.4498
-12.6533
-41.2893
BTU/LB-R
-0.9698
-2.0714
-0.3600
-0.7024
-0.9711
DENSITY:
LBMOL/CUFT
7.3770-03
3.3475 2.6165-03
0.1278 3.2748-02
LB/CUFT
0.3411
60.3068 6.1411-02
2.3026
1.3924
AVG MW
46.2322
18.0153
23.4708
18.0153
42.5179
STREAM ID
FROM :
TO
:
94
B53
B50
95
B60
B34
96
B60
B69
97
B89
B40
98
B89
B70
SUBSTREAM: MIXED
PHASE:
VAPOR
VAPOR
VAPOR
VAPOR
VAPOR
CO2
2.8268
0.0
2.0353
0.0
4.5228
CO
4.6411-04 3.3416-04
0.0
4.0842-04
0.0
WATER
31.1943 4451.6299
0.0
4840.9692
0.0
METHANOL
82.9751
59.7421
0.0
73.1273
0.0
DME
480.0619
345.6446
0.0
422.4545
0.0
METHY-01
0.0
0.0
0.0
1.1252-05
0.0
METHY-02
0.0
0.0
0.0
5.9089-06
0.0
N-PRO-01
0.0
0.0
0.0
6.6259
0.0
METHA-01
0.0
0.0
0.0
7.9911
0.0
N-BUT-01
0.0
0.0
0.0
0.8371
0.0
METHY-03
0.0
0.0
0.0
0.9215
0.0
3-MET-01
0.0
0.0
0.0
0.1384
0.0
VALER-01
0.0
0.0
0.0
7.1684-02
0.0
ETHANOL
0.0
0.0
0.0
0.1394
0.0
CIS-C-01
0.0
0.0
0.0
0.2675
0.0
METHY-05
0.0
0.0
0.0
4.0637
0.0
DIETH-01
0.0
0.0
0.0
2.6929
0.0
2-MET-01
0.0
0.0
0.0
1.3032-03
0.0
METHY-06
0.0
0.0
0.0
7.8081
0.0
DIETH-02
0.0
0.0
0.0
2.6929
0.0
METHY-07
0.0
0.0
0.0
7.8081
0.0
3-MET-02
0.0
0.0
0.0
0.3942
0.0
TERT--01
0.0
0.0
0.0
1.4048-02
0.0
METHANE
2.8457
2.0489
0.0
2.5042
0.0
ETHYLENE
0.0
0.0
0.0
22.0190
0.0
CYCLO-01
0.0
0.0
0.0
6.3685-03
0.0
PROPYLEN
0.0
0.0
0.0
43.4288
0.0
ISOBUTAN
0.0
0.0
0.0
18.4039
0.0
N-BUTANE
0.0
0.0
0.0
26.6494
0.0
TRANS-BU
0.0
0.0
0.0
8.8932
0.0
1-BUTENE
0.0
0.0
0.0
6.5928
0.0
ISOBUTEN
0.0
0.0
0.0
16.3667
0.0
CIS-2-01
0.0
0.0
0.0
7.2359
0.0
2-MET-02
0.0
0.0
0.0
5.5533
0.0
1:2-B-01
0.0
0.0
0.0
1.2927-03
0.0
1:3-B-01
0.0
0.0
0.0
1.2162
0.0
N-PENTAN
0.0
0.0
0.0
3.6584
0.0
N-HEXANE
0.0
0.0
0.0
0.4373
0.0
N-HEPTAN
0.0
0.0
0.0
5.6716-02
0.0
NITRO-01
4.8905-03
0.0
3.5212-03
0.0
7.8248-03
TOTAL FLOW:
LBMOL/HR
599.9091 4859.0658
2.0388 5542.0428
4.5306
LB/HR
2.5507+04 9.8068+04
89.6702 1.2040+05
199.2672
CUFT/HR
3.1961+04 1.3519+05
56.7236 1.6265+05
132.9678
STATE VARIABLES:
TEMP
F
707.0000
707.0000
707.0000
661.6112
661.6112
PRES
PSIA
235.0000
450.0000
450.0000
410.0000
410.0000
VFRAC
1.0000
1.0000
1.0000
1.0000
1.0000
LFRAC
0.0
0.0
0.0
0.0
0.0
SFRAC
0.0
0.0
0.0
0.0
0.0
ENTHALPY:
BTU/LBMOL
-6.9361+04 -9.6056+04 -1.6233+05 -9.3258+04 -1.6285+05
BTU/LB
-1631.3358 -4759.3524 -3690.8941 -4292.5175 -3702.7064
BTU/HR
-4.1610+07 -4.6674+08 -3.3096+05 -5.1684+08 -7.3783+05
ENTROPY:
BTU/LBMOL-R
-40.1840
-13.1201
1.8666
-14.3764
1.5972
BTU/LB-R
-0.9451
-0.6501 4.2439-02
-0.6617 3.6315-02
DENSITY:
LBMOL/CUFT
1.8770-02 3.5942-02 3.5942-02 3.4073-02 3.4073-02
LB/CUFT
0.7981
0.7254
1.5808
0.7403
1.4986
AVG MW
42.5179
20.1825
43.9822
21.7256
43.9822
99 S-501 S-505A S-505C S-506

---------------------------STREAM ID
FROM :
TO
:
99
B62
B-504
S-601 S-603 S-604 S-605 S-606

----------------------------S-501
---B13
S-505A
B-504
B-505
S-505C
B-505
B-507
S-506
B85
B86
SUBSTREAM: MIXED
PHASE:
VAPOR
LIQUID
VAPOR
VAPOR
VAPOR
CO2
0.0
11.3070
0.0
0.0
11.3070
CO
4.6411-04 1.8565-03
0.0
0.0
0.0
WATER
6065.2080
124.7770 6609.2246 6609.2246 6609.2246
METHANOL
83.1306
331.9006 6.0781-02 6.0781-02 6.0781-02
DME
480.0619 1920.2477 2.6521-06 2.6521-06 2.6521-06
METHY-01
2.3579-05
0.0
4.4138-06 4.4138-06 4.4138-06
METHY-02
1.5707-05
0.0
3.1950-06 3.1950-06 3.1950-06
N-PRO-01
18.6330
0.0
16.7783
16.7783
16.7783
METHA-01
33.9543
0.0
48.0445
48.0445
48.0445
N-BUT-01
2.9137
0.0
2.2263
2.2263
2.2263
METHY-03
2.0283
0.0
1.4971
1.4971
1.4971
3-MET-01
0.6060
0.0
0.4636
0.4636
0.4636
1:1-D-01
1.2449-11
0.0
5.3195-13
0.0
0.0
VALER-01
0.3088
0.0
0.2005
0.2005
0.2005
ETHANOL
0.2505
0.0
0.1010
0.1010
0.1010
CIS-C-01
1.1143
0.0
1.2820
1.2820
1.2820
METHY-05
18.5506
0.0
21.5264
21.5264
21.5264
DIETH-01
12.1505
0.0
12.5435
12.5435
12.5435
2-MET-01
4.6302-03
0.0
1.7526-03 1.7526-03 1.7526-03
METHY-06
35.3708
0.0
37.9829
37.9829
37.9829
DIETH-02
12.1505
0.0
12.5435
12.5435
12.5435
METHY-07
35.3708
0.0
37.9829
37.9829
37.9829
3-MET-02
2.2204
0.0
2.1204
2.1204
2.1204
TERT--01
4.0737-02
0.0
2.0020-02 2.0020-02 2.0020-02
METHANE
2.8457
11.3826
0.0
9.1456
9.1456
ETHYLENE
65.0054
0.0
99.0752
97.0937
97.0937
CYCLO-01
2.2592-02
0.0
2.1665-02 2.1665-02 2.1665-02
PROPYLEN
161.7297
0.0
253.1943
393.6787
393.6787
ISOBUTAN
73.7779
0.0
97.6312
97.6312
97.6312
N-BUTANE
105.4057
0.0
121.6634
79.0812
79.0812
TRANS-BU
41.6706
0.0
65.3474
13.0695
13.0695
1-BUTENE
30.3929
0.0
40.4571
16.1828
16.1828
ISOBUTEN
77.3155
0.0
131.7312
56.6444
56.6444
CIS-2-01
33.8283
0.0
51.7626
51.7626
51.7626
2-MET-02
27.4686
0.0
29.9325
29.9325
29.9325
1:2-B-01
6.5499-03
0.0
5.5645-03 5.5645-03 5.5645-03
1:3-B-01
6.6366
0.0
11.9924
11.9924
11.9924
N-PENTAN
17.9194
0.0
17.6646
29.0234
29.0234
N-HEXANE
2.6493
0.0
2.2008
4.3085
4.3085
N-HEPTAN
0.4253
0.0
0.3000
35.9388
35.9388
BENZENE
0.0
0.0
0.0
5.2229
5.2229
NITRO-01
0.0
1.9562-02
0.0
0.0
1.9562-02
TOTAL FLOW:
LBMOL/HR
7451.1690 2399.6364 7727.5801 7735.3356 7746.6622
LB/HR
1.8132+05 1.0203+05 1.8132+05 1.8132+05 1.8182+05
CUFT/HR
3.8044+05 2605.5941 2.9637+06 2.9568+06 3.2967+06
STATE VARIABLES:
TEMP
F
658.4085
135.8486
791.1718
787.0015
730.0000
PRES
PSIA
235.0000
206.2000
35.0000
35.0000
30.0000
VFRAC
1.0000
0.0
1.0000
1.0000
1.0000
LFRAC
0.0
1.0000
0.0
0.0
0.0
SFRAC
0.0
0.0
0.0
0.0
0.0
ENTHALPY:
BTU/LBMOL
-8.7735+04 -8.9341+04 -8.4597+04 -8.4512+04 -8.5365+04
BTU/LB
-3605.3529 -2101.2628 -3605.3563 -3605.3563 -3637.0660
BTU/HR
-6.5373+08 -2.1439+08 -6.5373+08 -6.5373+08 -6.6129+08
ENTROPY:
BTU/LBMOL-R
-15.1284
-66.4249
-8.4981
-8.4936
-8.7496
BTU/LB-R
-0.6217
-1.5623
-0.3622
-0.3623
-0.3728
DENSITY:
LBMOL/CUFT
1.9586-02
0.9210 2.6074-03 2.6161-03 2.3498-03
LB/CUFT
0.4766
39.1571 6.1181-02 6.1324-02 5.5153-02
AVG MW
24.3347
42.5179
23.4643
23.4408
23.4708
STREAM ID
FROM :
TO
:
S-601
B5
B15
S-603
B-603
B8
S-604
B8
B6
S-605
B8
B-612
S-606
B-612
B45
SUBSTREAM: MIXED
PHASE:
MIXED
MIXED
VAPOR
LIQUID
LIQUID
CO2
11.3070
11.3070
11.3070 8.0145-11 8.0145-11
WATER
9233.1865 9233.1865
277.6224 8955.5642 8955.5642
METHANOL
0.1140
0.1140
0.1115 2.5719-03 2.5719-03
DME
6.6466-06 6.6466-06 6.6465-06 4.8065-11 4.8065-11
METHY-01
1.0804-05 1.0804-05 1.0788-05 1.5587-08 1.5587-08
METHY-02
7.3112-06 7.3112-06 7.3112-06 9.1987-23 9.1987-23
N-PRO-01
21.4941
21.4941
21.4941 1.2776-07 1.2776-07
METHA-01
48.0445
48.0445
11.1575
36.8870
36.8870
N-BUT-01
2.9074
2.9074
2.9074 1.8333-06 1.8333-06
METHY-03
1.5345
1.5345
1.5345 3.3346-07 3.3346-07
3-MET-01
0.5986
0.5986 3.1622-02
0.5670
0.5670
VALER-01
0.2673
0.2673
0.2673 5.7960-09 5.7960-09
ETHANOL
0.1831
0.1831
0.1827 4.1307-04 4.1307-04
CIS-C-01
1.4784
1.4784 9.8800-02
1.3796
1.3796
METHY-05
25.9896
25.9896
25.9896 8.3389-09 8.3389-09
DIETH-01
15.4042
15.4042
15.4042 2.1676-07 2.1676-07
2-MET-01
3.0470-03 3.0470-03 3.0442-03 2.8277-06 2.8277-06
METHY-06
46.3720
46.3720
46.3720 4.7059-07 4.7059-07
DIETH-02
15.4042
15.4042
15.4042 2.1676-07 2.1676-07
METHY-07
46.3720
46.3720
46.3720 4.7059-07 4.7059-07
3-MET-02
2.6112
2.6112
2.6112 2.4858-11 2.4858-11
TERT--01
3.2580-02 3.2580-02 3.2580-02 1.8541-08 1.8541-08
METHANE
9.1456
9.1456
9.1456 4.3694-14 4.3694-14
ETHYLENE
349.5930
349.5930
349.5930 7.3073-09 7.3073-09
CYCLO-01
9.8375-02 9.8375-02 9.8375-02 3.9100-07 3.9100-07
PROPYLEN
994.9095
994.9095
994.9092 3.1711-04 3.1711-04
ISOBUTAN
459.7299
459.7299
459.6410 8.8870-02 8.8870-02
N-BUTANE
583.5666
583.5666
582.9881
0.5786
0.5786
TRANS-BU
13.0695
13.0695
13.0567 1.2811-02 1.2811-02
1-BUTENE
16.1828
16.1828
16.1773 5.5786-03 5.5786-03
ISOBUTEN
56.6444
56.6444
56.6256 1.8830-02 1.8830-02
CIS-2-01
171.0384
171.0384
170.7826
0.2558
0.2558
2-MET-02
153.7638
153.7638
153.7638 4.6287-30 4.6287-30
1:2-B-01
2.0041-02 2.0041-02 1.9951-02 8.9541-05 8.9541-05
1:3-B-01
28.8417
28.8417
28.8289 1.2775-02 1.2775-02
N-PENTAN
29.0234
29.0234
29.0234 1.6981-29 1.6981-29
N-HEXANE
4.3085
4.3085
4.3085 1.0095-23 1.0095-23
N-HEPTAN
35.9388
35.9388
35.9388 4.9413-27 4.9413-27
BENZENE
5.2229
5.2229
0.5973
4.6256
4.6256
NITRO-01
1.9562-02 1.9562-02 1.9562-02 5.9292-19 5.9292-19
TOTAL FLOW:
LBMOL/HR
1.2384+04 1.2384+04 3384.4210 9000.0000 9000.0000
LB/HR
3.3112+05 3.3112+05 1.6664+05 1.6449+05 1.6449+05
CUFT/HR
9.2624+05 6.7217+05 8.6130+05 2953.9671 2954.5067
STATE VARIABLES:
TEMP
F
140.0000
159.5311
133.1914
248.1375
248.4030
PRES
PSIA
19.0000
27.0000
25.0000
29.0000
90.0000
VFRAC
0.2199
0.2192
1.0000
0.0
0.0
LFRAC
0.7801
0.7808
0.0
1.0000
1.0000
SFRAC
0.0
0.0
0.0
0.0
0.0
ENTHALPY:
BTU/LBMOL
-9.6868+04 -9.6431+04 -3.0653+04 -1.1935+05 -1.1934+05
BTU/LB
-3623.0228 -3606.6506 -622.5717 -6530.2578 -6529.9615
BTU/HR
-1.1997+09 -1.1942+09 -1.0374+08 -1.0741+09 -1.0741+09
ENTROPY:
BTU/LBMOL-R
-41.2684
-40.7137
-51.9083
-33.9402
-33.9327
BTU/LB-R
-1.5435
-1.5227
-1.0543
-1.8571
-1.8567
DENSITY:
LBMOL/CUFT
1.3371-02 1.8425-02 3.9294-03
3.0468
3.0462
LB/CUFT
0.3575
0.4926
0.1935
55.6829
55.6727
AVG MW
26.7369
26.7369
49.2362
18.2761
18.2761
S-702 S-703 S-704 S-705 S-706

-----------------------------
S-611 S-613 S-614 S-615 S-701

----------------------------STREAM ID
FROM :
TO
:
S-611
B-606
B26
S-613
B-608
B25
S-614
B87
B-610
S-615
B-610
B35
S-701
B21
B-702
SUBSTREAM: MIXED
PHASE:
VAPOR
VAPOR
LIQUID
LIQUID
LIQUID
CO2
11.0246
10.2909
10.2909
10.2909
11.3070
WATER
19.8082
0.3712
0.3712
0.3712
277.6224
METHANOL
3.1714-02 6.4705-03 6.4705-03 6.4705-03
0.1115
DME
5.3065-06 3.1160-06 3.1160-06 3.1160-06 6.6465-06
METHY-01
6.3544-06 2.1598-06 2.1598-06 2.1598-06 1.0788-05
METHY-02
4.3790-06 8.6071-07 8.6071-07 8.6071-07 7.3112-06
N-PRO-01
7.6586
0.8952
0.8952
0.8952
21.4941
METHA-01
1.6513 9.6997-02 9.6997-02 9.6997-02
11.1575
N-BUT-01
0.5139 2.4538-02 2.4538-02 2.4538-02
2.9074
METHY-03
0.4156 3.5688-02 3.5688-02 3.5688-02
1.5345
3-MET-01
1.9404-03 4.4522-05 4.4522-05 4.4522-05 3.1622-02
VALER-01
2.8364-02 4.9769-04 4.9769-04 4.9769-04
0.2673
ETHANOL
2.4332-02 8.6385-04 8.6385-04 8.6385-04
0.1827
CIS-C-01
6.9529-03 1.8407-04 1.8407-04 1.8407-04 9.8800-02
METHY-05
2.8900 7.3879-02 7.3879-02 7.3879-02
25.9896
DIETH-01
1.3403 2.4178-02 2.4178-02 2.4178-02
15.4042
2-MET-01
1.2971-04 1.3755-06 1.3755-06 1.3755-06 3.0442-03
METHY-06
3.6147 6.2978-02 6.2978-02 6.2978-02
46.3720
DIETH-02
1.3403 2.4178-02 2.4178-02 2.4178-02
15.4042
METHY-07
3.6147 6.2978-02 6.2978-02 6.2978-02
46.3720
3-MET-02
0.1222 1.1970-03 1.1970-03 1.1970-03
2.6112
TERT--01
2.9012-03 7.1061-05 7.1061-05 7.1061-05 3.2580-02
METHANE
9.0965
8.9617
8.9617
8.9617
9.1456
ETHYLENE
340.9935
318.6260
318.6260
318.6260
349.5930
CYCLO-01
8.1087-02 5.0887-02 5.0887-02 5.0887-02 9.8375-02
PROPYLEN
874.8024
632.8994
632.8994
632.8994
994.9092
ISOBUTAN
322.6666
147.8985
147.8985
147.8985
459.6410
N-BUTANE
365.8497
138.4806
138.4806
138.4806
582.9881
TRANS-BU
8.1021
3.0025
3.0025
3.0025
13.0567
1-BUTENE
10.9290
4.6824
4.6824
4.6824
16.1773
ISOBUTEN
38.1861
16.2890
16.2890
16.2890
56.6256
CIS-2-01
102.9130
36.3739
36.3739
36.3739
170.7826
2-MET-02
96.9650
20.3235
20.3235
20.3235
153.7638
1:2-B-01
1.0938-02 3.3205-03 3.3205-03 3.3205-03 1.9951-02
1:3-B-01
19.1220
7.9544
7.9544
7.9544
28.8289
N-PENTAN
15.3467
2.5434
2.5434
2.5434
29.0234
N-HEXANE
1.3048 8.0991-02 8.0991-02 8.0991-02
4.3085
N-HEPTAN
4.5664 9.8243-02 9.8243-02 9.8243-02
35.9388
BENZENE
6.0714-02 2.3715-03 2.3715-03 2.3715-03
0.5973
NITRO-01
1.9520-02 1.9403-02 1.9403-02 1.9403-02 1.9562-02
TOTAL FLOW:
LBMOL/HR
2265.1069 1350.2628 1350.2628 1350.2628 3384.4210
LB/HR
1.0784+05 5.8391+04 5.8391+04 5.8391+04 1.6664+05
CUFT/HR
1.0531+05 3.3758+04 1753.2405 1756.3338 5428.5841
STATE VARIABLES:
TEMP
F
190.1567
169.3454
46.8976
48.0328
180.0000
PRES
PSIA
150.0000
270.0000
260.0000
557.9000
530.5400
VFRAC
1.0000
1.0000
0.0
0.0
0.0
LFRAC
0.0
0.0
1.0000
1.0000
1.0000
SFRAC
0.0
0.0
0.0
0.0
0.0
ENTHALPY:
BTU/LBMOL
-1.4246+04 -3549.4407 -1.1638+04 -1.1524+04 -3.6117+04
BTU/LB
-299.2305
-82.0789 -269.1180 -266.4886 -733.5541
BTU/HR
-3.2268+07 -4.7927+06 -1.5714+07 -1.5561+07 -1.2224+08
ENTROPY:
BTU/LBMOL-R
-50.6186
-42.7509
-56.5420
-56.3269
-64.5626
BTU/LB-R
-1.0633
-0.9886
-1.3075
-1.3025
-1.3113
DENSITY:
LBMOL/CUFT
2.1510-02 3.9999-02
0.7702
0.7688
0.6234
LB/CUFT
1.0240
1.7297
33.3047
33.2460
30.6960
AVG MW
47.6072
43.2443
43.2443
43.2443
49.2362
STREAM ID
FROM :
TO
:
S-702
B-702
B19
SUBSTREAM: MIXED
PHASE:
LIQUID
CO2
1.7948-07
WATER
277.6224
METHANOL
0.1114
DME
3.8614-06
METHY-01
1.0788-05
METHY-02
7.3112-06
N-PRO-01
21.4941
METHA-01
11.1575
N-BUT-01
2.9074
METHY-03
1.5345
3-MET-01
3.1622-02
VALER-01
0.2673
ETHANOL
0.1827
CIS-C-01
9.8800-02
METHY-05
25.9896
DIETH-01
15.4042
2-MET-01
3.0442-03
METHY-06
46.3720
DIETH-02
15.4042
METHY-07
46.3720
3-MET-02
2.6112
TERT--01
3.2580-02
METHANE
1.1396-10
ETHYLENE
3.0048-05
CYCLO-01
2.4658-02
PROPYLEN
5.1660
ISOBUTAN
459.5317
N-BUTANE
582.9851
TRANS-BU
13.0566
1-BUTENE
16.1763
ISOBUTEN
56.6222
CIS-2-01
170.7823
2-MET-02
153.7638
1:2-B-01
1.9951-02
1:3-B-01
28.8280
N-PENTAN
29.0234
N-HEXANE
4.3085
N-HEPTAN
35.9388
BENZENE
0.5973
NITRO-01
1.2006-15
TOTAL FLOW:
LBMOL/HR
2024.4210
LB/HR
1.1452+05
CUFT/HR
5009.5377
STATE VARIABLES:
TEMP
F
328.4448
PRES
PSIA
531.5200
VFRAC
0.0
LFRAC
1.0000
SFRAC
0.0
ENTHALPY:
BTU/LBMOL
-5.7399+04
BTU/LB
-1014.6234
BTU/HR
-1.1620+08
ENTROPY:
BTU/LBMOL-R
-74.0649
BTU/LB-R
-1.3092
DENSITY:
LBMOL/CUFT
0.4041
LB/CUFT
22.8613
AVG MW
56.5716
S-703
B-702
B-703
S-704
B-703
B-704
S-705
B-704
B-705
S-706
B-705
----
LIQUID
LIQUID
LIQUID
LIQUID
11.3070
7.8089-20
1.3087-05
2.7851-06
1.6929-11
1.5424-15
1.0432-11
2.5617-15
5.6151-17
3.4386-14
5.9117-22
9.8798-23
1.0135-18
7.8159-21
3.0742-19
8.1362-21
2.1425-25
2.1453-20
8.1362-21
2.1453-20
2.3310-24
2.2546-20
9.1456
349.5929
7.3718-02
989.7432
0.1093
3.0077-03
5.8401-05
1.0069-03
3.3546-03
3.1004-04
4.3904-08
3.2271-09
9.1200-04
5.5279-10
7.9215-16
9.9789-20
1.4837-18
1.9562-02
11.3070
7.8089-20
1.3087-05
2.7851-06
1.6929-11
1.5424-15
1.0432-11
2.5617-15
5.6151-17
3.4386-14
5.9117-22
9.8798-23
1.0135-18
7.8159-21
3.0742-19
8.1362-21
2.1425-25
2.1453-20
8.1362-21
2.1453-20
2.3310-24
2.2546-20
9.1456
349.5929
7.3718-02
989.7432
0.1093
3.0077-03
5.8401-05
1.0069-03
3.3546-03
3.1004-04
4.3904-08
3.2271-09
9.1200-04
5.5279-10
7.9215-16
9.9789-20
1.4837-18
1.9562-02
11.3070
7.8089-20
1.3087-05
2.7851-06
1.6929-11
1.5424-15
1.0432-11
2.5617-15
5.6151-17
3.4386-14
5.9117-22
9.8798-23
1.0135-18
7.8159-21
3.0742-19
8.1362-21
2.1425-25
2.1453-20
8.1362-21
2.1453-20
2.3310-24
2.2546-20
9.1456
349.5929
7.3718-02
989.7432
0.1093
3.0077-03
5.8401-05
1.0069-03
3.3546-03
3.1004-04
4.3904-08
3.2271-09
9.1200-04
5.5279-10
7.9215-16
9.9789-20
1.4837-18
1.9562-02
11.1298
0.0
2.7661-16
1.6086-10
3.3286-18
0.0
8.3762-22
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
9.1456
342.8441
1.2309-05
1.8609
4.5214-07
1.9026-09
3.0065-11
1.8916-09
6.5245-09
1.0047-10
1.8930-16
2.9579-16
1.1949-09
5.2730-19
0.0
0.0
0.0
1.9562-02
1360.0000
5.2111+04
1859.6393
1360.0000
5.2111+04
1869.7622
1360.0000
5.2111+04
1869.7623
365.0000
1.0333+04
466.1526
95.8132
525.0000
0.0
1.0000
0.0
97.6818
670.0000
0.0
1.0000
0.0
97.6818
652.5600
0.0
1.0000
0.0
29.4241
650.0000
0.0
1.0000
0.0
6608.3651
172.4652
8.9874+06
6666.0490
173.9706
9.0658+06
6666.0490
173.9706
9.0658+06
1.2346+04
436.0844
4.5063+06
-40.1549
-1.0480
-40.0707
-1.0458
-40.0707
-1.0458
-25.3732
-0.8962
0.7313
28.0222
38.3171
0.7274
27.8705
38.3171
0.7274
27.8705
38.3171
0.7830
22.1676
28.3109
S-707 S-801
----------STREAM ID
FROM :
TO
:
SUBSTREAM: MIXED
PHASE:
CO2
WATER
METHANOL
DME
METHY-01
METHY-02
N-PRO-01
METHA-01
N-BUT-01
METHY-03
3-MET-01
VALER-01
ETHANOL
CIS-C-01
METHY-05
DIETH-01
2-MET-01
METHY-06
DIETH-02
METHY-07
3-MET-02
TERT--01
METHANE
ETHYLENE
CYCLO-01
PROPYLEN
ISOBUTAN
N-BUTANE
TRANS-BU
1-BUTENE
ISOBUTEN
CIS-2-01
2-MET-02
1:2-B-01
1:3-B-01
N-PENTAN
N-HEXANE
N-HEPTAN
BENZENE
TOTAL FLOW:
LBMOL/HR
LB/HR
CUFT/HR
STATE VARIABLES:
TEMP
F
PRES
PSIA
VFRAC
LFRAC
SFRAC
ENTHALPY:
BTU/LBMOL
BTU/LB
BTU/HR
ENTROPY:
BTU/LBMOL-R
BTU/LB-R
DENSITY:
LBMOL/CUFT
LB/CUFT
AVG MW
S-707
B-705
----
LIQUID
S-801
B20
----
MIXED
0.1772
0.0
1.3087-05
2.7849-06
1.6929-11
0.0
1.0432-11
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
4.3346-09
6.7488
7.3705-02
987.8823
0.1093
3.0077-03
5.8401-05
1.0069-03
3.3546-03
3.1004-04
4.3904-08
3.2271-09
9.1200-04
5.5279-10
0.0
0.0
0.0
1.7947-07
277.6224
0.1114
3.8616-06
1.0788-05
7.3112-06
21.4941
11.1575
2.9074
1.5345
3.1622-02
0.2673
0.1827
9.8800-02
25.9896
15.4042
3.0442-03
46.3720
15.4042
46.3720
2.6112
3.2580-02
1.1396-10
3.0046-05
2.4660-02
5.1660
459.5317
582.9851
13.0566
16.1763
56.6222
170.7823
153.7638
1.9951-02
28.8280
29.0234
4.3085
35.9388
0.5973
995.0000
4.1778+04
2147.0458
2024.4210
1.1452+05
6.3110+04
192.7007
654.1000
0.0
1.0000
0.0
186.6253
100.0000
0.4373
0.5627
0.0
9038.9606 -6.3420+04
215.2762 -1121.0604
8.9938+06 -1.2839+08
-40.5266
-0.9652
-80.5737
-1.4243
0.4634
19.4583
41.9877
3.2078-02
1.8147
56.5716
BLOCK: B-504
MODEL: RGIBBS
-----------------------------INLET STREAM:
99
OUTLET STREAM:
S-505A
NRTL
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
RENON (NRTL) / IDEAL GAS

IN
OUT
7451.17
7727.58
181322.
181322.
-0.653730E+09 -0.653731E+09
***
INPUT DATA
***
GENERATION
RELATIVE DIFF.
276.411
0.117695E-15
0.593883E-14
0.965417E-06
***
CALCULATED TEMPERATURE
F
791.17
F
791.17
SYSTEM PRESSURE DROP PSI
200.00
SPECIFIED DUTY
BTU/HR
0.0000
PROPANE
CYCLO-01
PROPYLEN
ISOBUTAN
N-BUTANE
TRANS-BU
1-BUTENE
ISOBUTEN
CIS-2-01
2-MET-02
1:2-B-01
1:3-B-01
N-PENTAN
N-HEXANE
N-HEPTAN
BENZENE
TOLUENE
N-OCT-01
NITRO-01
8.00
6.00
6.00
10.00
10.00
8.00
8.00
8.00
8.00
12.00
6.00
6.00
12.00
14.00
16.00
6.00
8.00
18.00
0.00
3.00
3.00
3.00
4.00
4.00
4.00
4.00
4.00
4.00
5.00
4.00
4.00
5.00
6.00
7.00
6.00
7.00
8.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
2.00

WATER METHANOL DME METHY-01 METHY-02 N-PRO-01 METHA-01 N-BUT-01
***
TEMPERATURE
F
PRESSURE
PSIA
VAPOR FRACTION
METHY-03 3-MET-01 1:1-D-01 VALER-01 ETHANOL CIS-C-01 METHY-05
DIETH-01 2-MET-01 METHY-06 DIETH-02 METHY-07 3-MET-02 TERT--01
PHASE
OF TYPE
PHASE FRACTION
PLACED IN STREAM
METHANOL
DME
METHY-01
METHY-02
N-PRO-01
METHA-01
N-BUT-01
METHY-03
3-MET-01
1:1-D-01
VALER-01
ETHANOL
CIS-C-01
METHY-05
DIETH-01
2-MET-01
METHY-06
DIETH-02
METHY-07
3-MET-02
TERT--01
ETHYLENE
CYCLO-01
PROPYLEN
ISOBUTAN
N-BUTANE
TRANS-BU
1-BUTENE
ISOBUTEN
CIS-2-01
2-MET-02
1:2-B-01
1:3-B-01
N-PENTAN
N-HEXANE
N-HEPTAN
WATER
ETHYLENE CYCLO-01 PROPYLEN ISOBUTAN N-BUTANE TRANS-BU 1-BUTENE

ISOBUTEN CIS-2-01 2-MET-02 1:2-B-01 1:3-B-01 N-PENTAN N-HEXANE
N-HEPTAN
ATOM MATRIX:
ELEMENT
H
H2
2.00
CO2
0.00
CO
0.00
WATER
2.00
METHANOL
4.00
DME
6.00
METHY-01
8.00
METHY-02 10.00
ACETA-01
4.00
N-PRO-01
6.00
ACROL-01
4.00
METHA-01
6.00
N-BUT-01
8.00
METHY-03
6.00
ACETONE
6.00
3-MET-01 10.00
1:1-D-01 10.00
VALER-01 10.00
METHY-04
8.00
ETHANOL
6.00
CIS-C-01
6.00
METHY-05 10.00
DIETH-01 10.00
2-MET-01 12.00
METHY-06 10.00
DIETH-02 10.00
METHY-07 10.00
3-MET-02 12.00
TERT--01 10.00
METHANE
4.00
ETHANE
6.00
ETHYLENE
4.00
C
0.00
1.00
1.00
0.00
1.00
2.00
3.00
4.00
2.00
3.00
3.00
4.00
4.00
3.00
3.00
5.00
4.00
5.00
4.00
2.00
4.00
5.00
5.00
5.00
5.00
5.00
5.00
6.00
4.00
1.00
2.00
2.00
N
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
O
0.00
2.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
2.00
1.00
1.00
2.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
RESULTS
VAPOR
VAPOR
1.000000
S-505A
0.7865437E-05
0.3432049E-09
0.5711736E-09
0.4134542E-09
0.2171227E-02
0.6217282E-02
0.2880929E-03
0.1937358E-03
0.5999130E-04
0.6883801E-16
0.2595184E-04
0.1306676E-04
0.1659014E-03
0.2785655E-02
0.1623215E-02
0.2267984E-06
0.4915236E-02
0.1623215E-02
0.4915236E-02
0.2743977E-03
0.2590664E-05
0.1282098E-01
0.2803570E-05
0.3276502E-01
0.1263413E-01
0.1574405E-01
0.8456390E-02
0.5235416E-02
0.1704689E-01
0.6698424E-02
0.3873462E-02
0.7200768E-06
0.1551892E-02
0.2285915E-02
0.2847995E-03
0.3882196E-04
0.8552774
***
791.17
35.000
1.0000
1
LBMOL/HR
7727.580
BLOCK: B-505
MODEL: RSTOIC
-----------------------------INLET STREAM:
S-505A
OUTLET STREAM:
S-505C
NRTL
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
REACTION #
8:
SUBSTREAM:MIXED
REACTION #
9:
SUBSTREAM:MIXED
***
KEY COMP:1-BUTENE CONV FRAC: 0.4000

IN
OUT
7727.58
7735.34
181322.
181322.
-0.653731E+09 -0.653731E+09
KEY COMP:TRANS-BU CONV FRAC: 0.5000E-01
INPUT DATA
***
GENERATION
7.75548
RELATIVE DIFF.
0.00000
0.160509E-15
-0.182352E-15
ONE
PHASE PQ FLASH
SPECIFIED PHASE IS VAPOR
SPECIFIED PRESSURE
PSIA
SPECIFIED HEAT DUTY
BTU/HR
SIMULTANEOUS REACTIONS
GENERATE COMBUSTION REACTIONS FOR FEED SPECIES
REACTION #
2:
SUBSTREAM MIXED
METHANE
-4.00
REACTION #
3:
SUBSTREAM MIXED
METHANE
-1.00
REACTION #
4:
SUBSTREAM MIXED
PROPYLEN
4.00
REACTION #
5:
SUBSTREAM MIXED
PROPYLEN -9.00
REACTION #
6:
SUBSTREAM MIXED
METHANE
1.00
REACTION #
7:
SUBSTREAM MIXED
PROPYLEN
4.00
***
F
PSIA
OUTLET TEMPERATURE
OUTLET PRESSURE
:
NO
***
STOICHIOMETRY MATRIX:
REACTION #
1:
SUBSTREAM MIXED
METHANE
6.00
35.0000
0.0
30
0.000100000
ETHYLENE
-9.00
BENZENE
2.00
ISOBUTEN
-5.00
N-HEXANE
4.00
1-BUTENE
-1.00
N-PENTAN
1.00
TRANS-BU
-3.00
N-HEPTAN
3.00
BENZENE
1.00
RESULTS
***
787.00
35.000
REACTION EXTENTS:
N-BUTANE
-2.00
N-HEPTAN
1.00
REACTION
NUMBER
1
2
3
4
5
6
7
8
9
BLOCK: B-507
MODEL: MIXER
----------------------------INLET STREAMS:
S-505C
OUTLET STREAM:
91
NRTL
***
ISOBUTEN
REACTION #
8:
SUBSTREAM MIXED
METHANE
-1.00
REACTION #
9:
SUBSTREAM MIXED
PROPYLEN
4.00
REACTION
EXTENT
LBMOL/HR
0.22017
0.52692
8.0914
16.337
4.7826
21.291
24.151
3.2674
5.3943
-3.00
TRANS-BU
-1.00
1-BUTENE
-3.00
N-PENTAN
REACTION CONVERSION SPECS: NUMBER=

9
REACTION #
1:
SUBSTREAM:MIXED
KEY COMP:ETHYLENE CONV
REACTION #
2:
SUBSTREAM:MIXED
KEY COMP:ISOBUTEN CONV
REACTION #
3:
SUBSTREAM:MIXED
KEY COMP:1-BUTENE CONV
REACTION #
4:
SUBSTREAM:MIXED
KEY COMP:TRANS-BU CONV
REACTION #
5:
SUBSTREAM:MIXED
KEY COMP:PROPYLEN CONV
REACTION #
6:
SUBSTREAM:MIXED
KEY COMP:N-BUTANE CONV
REACTION #
7:
SUBSTREAM:MIXED
KEY COMP:ISOBUTEN CONV
1.00
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
100

IN
7746.66
181820.
-0.655576E+09
***
OUT
7746.66
181820.
-0.655576E+09
*** INPUT DATA ***

TWO
PHASE
FLASH
FRAC: 0.2000E-01
FRAC: 0.2000E-01
BLOCK: B-601
MODEL: MIXER
----------------------------INLET STREAMS:
32
OUTLET STREAM:
47
NRTL
RELATIVE DIFF.
0.00000
-0.160069E-15
0.181839E-15
30
0.000100000
34
FRAC: 0.2000
***
FRAC: 0.7500
FRAC: 0.1700
FRAC: 0.3500
FRAC: 0.5500
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR

IN
12384.4
331121.
-0.101240E+10
)
***
INPUT DATA
***
***
OUT
12384.4
331121.
-0.101240E+10
RELATIVE DIFF.
0.00000
0.351579E-15
-0.235499E-15
TWO
PHASE
FLASH
BLOCK: B-603
MODEL: VALVE
----------------------------INLET STREAM:
17
OUTLET STREAM:
S-603
NRTL
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
12384.4
331121.
-0.119424E+10
***

INPUT DATA
***
OUT
VALVE PRESSURE DROP
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
***
28.0000
INPUT DATA

***
RESULTS

BRAKE
NET WORK REQUIRED
HP
POWER LOSSES
HP
HEAD DEVELOPED,
FT-LBF/LB
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
***
OUT
RELATIVE DIFF.
2265.11
107836.
-0.322677E+08
0.00000
0.00000
-0.100867
***
150.000
0.72000
1.00000
***
1,422.66
1,422.66
1,422.66
0.0
1,024.32
190.157
168.528
0.72000
1.00000
18,807.8
1.00000
1.11746
242,937.
105,306.
1.00000
1.00000

IN
1350.26
58391.2
-0.620734E+07
INPUT DATA
***
OUT
***
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
270.000
0.72000
1.00000
RESULTS
***
555.981
555.981
555.981
0.0
400.306
169.345
155.106
0.72000
1.00000
13,574.1
1.00000
1.13254
58,131.3
33,757.7
1.00000
1.00000
1.12484
1.13454
1.18234
1.18234

IN
1350.26
58391.2
-0.157141E+08
)
***
INPUT DATA

DRIVER EFFICIENCY
NO FLASH PERFORMED
TOLERANCE
0.00000
0.00000
-0.227901
***

BRAKE
NET WORK REQUIRED
HP
POWER LOSSES
HP
HEAD DEVELOPED,
FT-LBF/LB
BLOCK: B-610
MODEL: PUMP
---------------------------INLET STREAM:
S-614
OUTLET STREAM:
S-615
NRTL
RELATIVE DIFF.
1350.26
58391.2
-0.479268E+07

2
30
0.000100000

IN
0.00000
0.00000
0.00000
***
2265.11
107836.
-0.358876E+08
1.11244
1.11244
1.15749
1.15749
***
PSI
***
EXPONENT
EXPONENT
EXPONENT
EXPONENT
***
NPHASE
BLOCK: B-606
MODEL: COMPR
----------------------------INLET STREAM:
72
OUTLET STREAM:
S-611
NRTL
VOL.
TEMP
VOL.
TEMP
RELATIVE DIFF.
27.0000
NO
RESULTS
ISENT.
ISENT.
ACTUAL
ACTUAL
***
12384.4
331121.
-0.119424E+10
PSIA
***
AV.
AV.
AV.
AV.
BLOCK: B-608
MODEL: COMPR
----------------------------INLET STREAM:
26
OUTLET STREAM:
S-613
NRTL

IN
30
0.000100000
***
OUT
RELATIVE DIFF.
1350.26
58391.2
-0.155606E+08
0.00000
0.00000
-0.977029E-02
***
557.900
1.00000
30
0.000100000
*** RESULTS
CUFT/HR
***

PRESSURE CHANGE PSI
NPSH AVAILABLE
FT-LBF/LB
FLUID POWER HP
BRAKE POWER HP
ELECTRICITY KW
1,753.24
297.900
0.0
37.9848
60.3359
44.9925
0.62955
60.3359
1,288.03
ABSORBER OPTION
FLASH TOLERANCE
****
BLOCK: B-612
MODEL: PUMP
---------------------------INLET STREAM:
S-605
OUTLET STREAM:
S-606
NRTL
COL-SPECS
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
9000.00
164485.
-0.107413E+10
***
INPUT DATA
***
OUT
RELATIVE DIFF.
9000.00
164485.
-0.107408E+10
NO FLASH PERFORMED
TOLERANCE
***
2,953.96
61.0000
0.0
13.1048
19.1543
14.2834
0.68417
19.1543
157.750

IN
3384.42
166636.
-0.122236E+09
***
OUT
RELATIVE DIFF.
3384.42
166636.
-0.107212E+09
-0.134365E-15
0.908205E-14
-0.122913
**********************
**********************
****
INPUT PARAMETERS
NUMBER OF STAGES
ALGORITHM OPTION
PRES, PSIA
*******************
**** RESULTS ****
*******************
***
S-703
30
0.000100000
*** RESULTS
PRESSURE CHANGE PSI
NPSH AVAILABLE
FT-LBF/LB
FLUID POWER HP
BRAKE POWER HP
ELECTRICITY KW
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
0.0
1.40000
1,360.00
****
STAGE
0.00000
0.00000
-0.453732E-04
90.0000
1.00000
***
PROFILES
P-SPEC
***

DRIVER EFFICIENCY
BLOCK: B-702
MODEL: RADFRAC
------------------------------INLETS
- S-701
STAGE 13
OUTLETS - S-703
STAGE
1
S-702
STAGE 20
NRTL
LBMOL/HR

IN
****

MOLAR REFLUX RATIO
MOLAR DISTILLATE RATE
****
***
NO
STANDARD
NO
BROYDEN
NESTED
25
10
30
0.000100000
0.000100000
****
20
STANDARD
COMPONENT:
CO2
WATER
METHANOL
DME
METHY-01
METHY-02
N-PRO-01
METHA-01
N-BUT-01
METHY-03
3-MET-01
VALER-01
ETHANOL
CIS-C-01
METHY-05
DIETH-01
2-MET-01
METHY-06
DIETH-02
METHY-07
3-MET-02
TERT--01
METHANE
ETHYLENE
CYCLO-01
PROPYLEN
ISOBUTAN
N-BUTANE
TRANS-BU
1-BUTENE
ISOBUTEN
CIS-2-01
2-MET-02
1:2-B-01
1:3-B-01
N-PENTAN
N-HEXANE
N-HEPTAN
1.0000
0.0000
.11742E-03
.41902
.15692E-05
.21096E-09
.48530E-12
0.0000
0.0000
.22408E-13
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
0.0000
1.0000
1.0000
.74935
.99481
.23780E-03
.51588E-05
.44727E-05
.62241E-04
.59239E-04
.18153E-05
.28552E-09
.16174E-06
.31634E-04
.19046E-10
0.0000
0.0000
***
OUTLET STREAMS
-------------S-702
.15873E-07
1.0000
.99988
.58098
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
.12461E-10
.85950E-07
.25065
.51924E-02
.99976
.99999
1.0000
.99994
.99994
1.0000
1.0000
1.0000
.99997
1.0000
1.0000
1.0000
525.000
BENZENE
NITRO-01
***
0.0000
1.0000
1.0000
.61376E-13

BOILUP VAPOR FLOW
MOLAR REFLUX RATIO
MOLAR BOILUP RATIO
REBOILER DUTY
****
***
F
F
LBMOL/HR
LBMOL/HR
LBMOL/HR
LBMOL/HR
PROFILES
95.8132
328.445
1,904.00
2,024.42
0.0
9,680.61
1.40000
4.78192
-0.162652+08
0.312896+08
BTU/HR
BTU/HR
DEW POINT
BUBBLE POINT
ENERGY BALANCE
****
20 0.1145E+06 0.5591E+06
****
0.79454E-06
0.57035E-06
0.16276E-05
0.24976E-04
STAGE=
STAGE=
STAGE=
STAGE=
16
16
17 COMP=3-MET-02
16
1
2
12
13
14
17
18
19
20
95.813
150.65
194.50
216.20
240.29
285.07
293.62
304.06
328.44
PRESSURE
PSIA
LIQUID
525.00
529.00
530.40
530.54
530.68
531.10
531.24
531.38
531.52
FLOW RATE
LBMOL/HR
LIQUID
VAPOR
3264.
0.000
2262.
3264.
2152.
3620.
7471.
3512.
7470.
5447.
0.1283E+05 8583.
0.1319E+05 0.1081E+05
0.1171E+05 0.1116E+05
2024.
9681.
****
MASS FLOW PROFILES
LIQUID
CO2
0.83140E-02
0.20520E-02
0.58058E-03
0.49543E-03
0.78067E-04
0.13335E-06
0.12560E-07
0.11107E-08
0.88656E-10
****
MOLE-X-PROFILE
****
WATER
METHANOL
DME
0.57416E-22
0.96227E-08
0.20478E-08
0.80321E-20
0.36678E-07
0.45045E-08
0.21930E-02
0.15149E-04
0.31140E-07
0.38710E-01
0.23663E-04
0.21326E-07
0.39156E-01
0.25009E-04
0.24148E-07
0.24895E-01
0.31915E-04
0.12554E-07
0.28746E-01
0.36535E-04
0.75908E-08
0.53168E-01
0.38963E-04
0.41616E-08
0.13713
0.55049E-04
0.19074E-08
METHY-01
0.12448E-13
0.69174E-13
0.17852E-08
0.26845E-08
0.32157E-08
0.50890E-08
0.56895E-08
0.59710E-08
0.53289E-08
STAGE
1
2
12
13
14
17
18
19
20
METHY-02
0.11341E-17
0.13498E-16
0.49758E-09
0.12908E-08
0.13603E-08
0.17542E-08
0.26414E-08
0.38420E-08
0.36115E-08
****
MOLE-X-PROFILE
****
N-PRO-01
METHA-01
N-BUT-01
0.76700E-14
0.18842E-17
0.41286E-19
0.15418E-12
0.72570E-16
0.19933E-17
0.77840E-03
0.19439E-03
0.44421E-04
0.33643E-02
0.16164E-02
0.41743E-03
0.34533E-02
0.16398E-02
0.42289E-03
0.28501E-02
0.10741E-02
0.27433E-03
0.39775E-02
0.12454E-02
0.32381E-03
0.68597E-02
0.21800E-02
0.59963E-03
0.10617E-01
0.55134E-02
0.14362E-02
METHY-03
0.25283E-16
0.67430E-15
0.44753E-04
0.23377E-03
0.23908E-03
0.18345E-03
0.25113E-03
0.45130E-03
0.75797E-03
STAGE
1
2
12
13
14
17
18
19
20
3-MET-01
0.43468E-24
0.38976E-22
0.27024E-06
0.44111E-05
0.44533E-05
0.27498E-05
0.29356E-05
0.48747E-05
0.15620E-04
****
MOLE-X-PROFILE
****
VALER-01
ETHANOL
CIS-C-01
0.72644E-25
0.74520E-21
0.57472E-23
0.91839E-23
0.44627E-19
0.45310E-21
0.18637E-05
0.31378E-05
0.94195E-06
0.37005E-04
0.26662E-04
0.13844E-04
0.37283E-04
0.27288E-04
0.13986E-04
0.22734E-04
0.20135E-04
0.86950E-05
0.24483E-04
0.27542E-04
0.93881E-05
0.43954E-04
0.52355E-04
0.15798E-04
0.13202E-03
0.90250E-04
0.48807E-04
METHY-05
0.22604E-21
0.20985E-19
0.22700E-03
0.36270E-02
0.36596E-02
0.22611E-02
0.24554E-02
0.42665E-02
0.12838E-01
FEED RATE
LBMOL/HR
VAPOR
10795.
11592.
3118.4
-1074.2
-9321.1
-34018.
-37488.
-39314.
-41951.
MIXED
HEAT DUTY
BTU/HR
-.16265+08
STAGE
1
2
12
13
14
17
18
19
20
DIETH-01
0.59824E-23
0.72825E-21
0.10395E-03
0.21303E-02
0.21461E-02
0.13048E-02
0.13654E-02
0.22274E-02
0.76092E-02
****
MOLE-X-PROFILE
****
2-MET-01
METHY-06
DIETH-02
0.15753E-27
0.15774E-22
0.59824E-23
0.25119E-25
0.19426E-20
0.72825E-21
0.20311E-07
0.30333E-03
0.10395E-03
0.42187E-06
0.64059E-02
0.21303E-02
0.42605E-06
0.64514E-02
0.21461E-02
0.26291E-06
0.39126E-02
0.13048E-02
0.28485E-06
0.40535E-02
0.13654E-02
0.50116E-06
0.64082E-02
0.22274E-02
0.15037E-05
0.22906E-01
0.76092E-02
METHY-07
0.15774E-22
0.19426E-20
0.30333E-03
0.64059E-02
0.64514E-02
0.39126E-02
0.40535E-02
0.64082E-02
0.22906E-01
.31290+08
PRODUCT RATE
LBMOL/HR
LIQUID
VAPOR
1360.0000
STAGE
1
2
12
13
14
17
18
19
20
3-MET-02
0.17140E-26
0.36449E-24
0.10816E-04
0.35682E-03
0.35869E-03
0.21473E-03
0.21892E-03
0.34138E-03
0.12898E-02
****
MOLE-X-PROFILE
****
TERT--01
METHANE
ETHYLENE
0.16578E-22
0.67247E-02
0.25705
0.11951E-20
0.42761E-03
0.66817E-01
0.45514E-06
0.13405E-03
0.20406E-01
0.46783E-05
0.12592E-03
0.17920E-01
0.47648E-05
0.73246E-05
0.33562E-02
0.32166E-05
0.87025E-09
0.10733E-04
0.39735E-05
0.35989E-10
0.12736E-05
0.74617E-05
0.14425E-11
0.14328E-06
0.16094E-04
0.56293E-13
0.14842E-07
CYCLO-01
0.54204E-04
0.10414E-03
0.31313E-03
0.20782E-03
0.21842E-03
0.93603E-04
0.53433E-04
0.27775E-04
0.12180E-04
STAGE
1
2
12
13
14
17
PROPYLEN
0.72775
0.93027
0.59954
0.43280
0.31849
0.49660E-01
****
MOLE-X-PROFILE
****
ISOBUTAN
N-BUTANE
TRANS-BU
0.80370E-04
0.22114E-05
0.42940E-07
0.29524E-03
0.10949E-04
0.21695E-06
0.19045
0.11040
0.25333E-02
0.20699
0.15539
0.35750E-02
0.27839
0.18967
0.44560E-02
0.39986
0.30199
0.72896E-02
1-BUTENE
0.74036E-06
0.30153E-05
0.49407E-02
0.58655E-02
0.77117E-02
0.11923E-01
3384.4209
2024.4209
****
STAGE
1
2
12
13
14
17
18
19
FLOW RATE
LB/HR
LIQUID
VAPOR
0.1251E+06 0.000
0.9305E+05 0.1251E+06
0.1030E+06 0.1550E+06
0.3749E+06 0.1551E+06
0.3916E+06 0.2604E+06
0.7312E+06 0.4790E+06
0.7590E+06 0.6167E+06
0.6737E+06 0.6445E+06
ENTHALPY
BTU/LBMOL
VAPOR
6608.4
6498.5
-13489.
-26537.
-33347.
-43069.
-44463.
-47296.
-57399.
STAGE
1
2
12
13
14
17
18
19
20
STAGE
1
2
12
13
14
17
18
19
20
****
STAGE TEMPERATURE
F
.11452+06
LIQUID
.16664+06
FEED RATE
LB/HR
VAPOR
MIXED
PRODUCT RATE
LB/HR
LIQUID
VAPOR
.52111+05
18
19
20
0.20524E-01
0.78045E-02
0.25518E-02
0.37163
0.31633
0.22699
0.32822
0.33302
0.28798
0.78031E-02
0.77339E-02
0.64496E-02
0.11698E-01
0.10533E-01
0.79906E-02
STAGE
1
2
12
13
14
17
18
19
20
ISOBUTEN
0.24665E-05
0.10132E-04
0.17711E-01
0.21028E-01
0.27900E-01
0.43114E-01
0.42001E-01
0.37469E-01
0.27970E-01
****
MOLE-X-PROFILE
****
CIS-2-01
2-MET-02
1:2-B-01
0.22796E-06
0.32281E-10
0.23728E-11
0.12370E-05
0.36813E-09
0.15686E-10
0.28278E-01
0.10218E-01
0.22897E-05
0.42554E-01
0.26840E-01
0.41321E-05
0.51205E-01
0.28024E-01
0.45660E-05
0.82116E-01
0.32028E-01
0.62429E-05
0.91405E-01
0.46885E-01
0.76701E-05
0.95220E-01
0.69942E-01
0.92517E-05
0.84361E-01
0.75954E-01
0.98553E-05
1:3-B-01
0.67056E-06
0.29138E-05
0.83169E-02
0.10211E-01
0.13553E-01
0.21382E-01
0.20990E-01
0.18863E-01
0.14240E-01
STAGE
1
2
12
13
14
17
18
19
20
N-PENTAN
0.40645E-12
0.58501E-11
0.14684E-02
0.47840E-02
0.49387E-02
0.46937E-02
0.67132E-02
0.10731E-01
0.14337E-01
****
MOLE-X-PROFILE
****
N-HEXANE
N-HEPTAN
BENZENE
0.58245E-18
0.73372E-22
0.10912E-20
0.22911E-16
0.76730E-20
0.62206E-19
0.82448E-04
0.28366E-03
0.71776E-05
0.62833E-03
0.49944E-02
0.84535E-04
0.63713E-03
0.50326E-02
0.85453E-04
0.43011E-03
0.30739E-02
0.53640E-04
0.55678E-03
0.33001E-02
0.58784E-04
0.11104E-02
0.58001E-02
0.99907E-04
0.21283E-02
0.17753E-01
0.29512E-03
NITRO-01
0.14384E-04
0.39445E-06
0.13039E-06
0.12665E-06
0.36416E-08
0.59094E-13
0.12901E-14
0.27626E-16
0.59308E-18
STAGE
1
2
12
13
14
17
18
19
20
CO2
0.18682E-01
0.83140E-02
0.35183E-02
0.35755E-02
0.67958E-03
0.15934E-05
0.15831E-06
0.14822E-07
0.13244E-08
****
MOLE-Y-PROFILE
****
WATER
METHANOL
DME
0.91564E-25
0.39466E-09
0.44847E-09
0.57416E-22
0.96227E-08
0.20478E-08
0.44213E-04
0.49080E-05
0.23293E-07
0.13437E-02
0.92857E-05
0.19873E-07
0.21266E-02
0.11998E-04
0.28544E-07
0.28067E-02
0.21123E-04
0.22418E-07
0.38677E-02
0.27581E-04
0.14549E-07
0.90890E-02
0.33178E-04
0.86215E-08
0.35609E-01
0.35598E-04
0.46330E-08
METHY-01
0.95099E-15
0.12448E-13
0.56819E-09
0.10938E-08
0.17016E-08
0.41836E-08
0.50441E-08
0.57550E-08
0.61053E-08
STAGE
1
2
12
13
14
17
18
19
20
METHY-02
0.37332E-19
0.11341E-17
0.78524E-10
0.30488E-09
0.42818E-09
0.84684E-09
0.14062E-08
0.24654E-08
0.38902E-08
****
MOLE-Y-PROFILE
****
N-PRO-01
METHA-01
N-BUT-01
0.13614E-15
0.16302E-19
0.27131E-21
0.76700E-14
0.18842E-17
0.41286E-19
0.77115E-04
0.10455E-04
0.19647E-05
0.47695E-03
0.11911E-03
0.27218E-04
0.66835E-03
0.16797E-03
0.38773E-04
0.90701E-03
0.19045E-03
0.43273E-04
0.13950E-02
0.24249E-03
0.56666E-04
0.27733E-02
0.47133E-03
0.12207E-03
0.60739E-02
0.14829E-02
0.42469E-03
METHY-03
0.31229E-18
0.25283E-16
0.35138E-05
0.27422E-04
0.38927E-04
0.49967E-04
0.75821E-04
0.15921E-03
0.38717E-03
STAGE
1
2
12
13
14
17
18
19
20
3-MET-01
0.13435E-26
0.43468E-24
0.70332E-08
0.16558E-06
0.24480E-06
0.28467E-06
0.33862E-06
0.63511E-06
0.26276E-05
****
MOLE-Y-PROFILE
****
VALER-01
ETHANOL
CIS-C-01
0.15574E-27
0.29173E-23
0.20708E-25
0.72644E-25
0.74520E-21
0.57472E-23
0.34995E-07
0.13850E-06
0.27421E-07
0.11419E-05
0.19226E-05
0.57716E-06
0.16901E-05
0.30274E-05
0.84807E-06
0.18571E-05
0.44545E-05
0.98272E-06
0.22603E-05
0.69997E-05
0.11803E-05
0.49806E-05
0.16170E-04
0.22392E-05
0.25538E-04
0.44430E-04
0.88957E-05
METHY-05
0.70589E-24
0.22604E-21
0.56466E-05
0.13909E-03
0.20337E-03
0.22843E-03
0.27961E-03
0.57243E-03
0.24740E-02
STAGE
1
2
12
13
DIETH-01
0.13675E-25
0.59824E-23
0.20154E-05
0.63696E-04
****
MOLE-Y-PROFILE
****
2-MET-01
METHY-06
DIETH-02
0.19287E-30
0.34857E-25
0.13675E-25
0.15753E-27
0.15774E-22
0.59824E-23
0.36332E-09
0.58288E-05
0.20154E-05
0.12445E-07
0.18586E-03
0.63696E-04
METHY-07
0.34857E-25
0.15774E-22
0.58288E-05
0.18586E-03
14
17
18
19
20
0.93899E-04
0.10572E-03
0.12377E-03
0.23301E-03
0.11020E-02
0.19749E-07
0.24719E-07
0.30445E-07
0.63797E-07
0.29150E-06
0.93899E-04
0.10572E-03
0.12377E-03
0.23301E-03
0.11020E-02
0.27292E-03
0.30692E-03
0.35431E-03
0.63445E-03
0.29581E-02
STAGE
1
2
12
13
14
17
18
19
20
3-MET-02
0.20828E-29
0.17140E-26
0.12614E-06
0.66275E-05
0.10025E-04
0.11547E-04
0.13319E-04
0.24705E-04
0.14303E-03
****
MOLE-Y-PROFILE
****
TERT--01
METHANE
ETHYLENE
0.48560E-25
0.77386E-01
0.60202
0.16578E-22
0.67247E-02
0.25705
0.17019E-07
0.26121E-02
0.11021
0.27887E-06
0.26864E-02
0.11205
0.43537E-06
0.17273E-03
0.24581E-01
0.57648E-06
0.24314E-07
0.10270E-03
0.80415E-06
0.10333E-08
0.12742E-04
0.17754E-05
0.42506E-10
0.15019E-05
0.56566E-05
0.17323E-11
0.17014E-06
CYCLO-01
0.14257E-04
0.54204E-04
0.26049E-03
0.21286E-03
0.28054E-03
0.17827E-03
0.10886E-03
0.60915E-04
0.31036E-04
STAGE
1
2
12
13
14
17
18
19
20
PROPYLEN
0.30146
0.72775
0.73495
0.64919
0.59271
0.13303
0.58486E-01
0.23784E-01
0.89029E-02
****
MOLE-Y-PROFILE
****
ISOBUTAN
N-BUTANE
TRANS-BU
0.10451E-04
0.20355E-06
0.38187E-08
0.80370E-04
0.22114E-05
0.42940E-07
0.85948E-01
0.38024E-01
0.86404E-03
0.11673
0.67648E-01
0.15522E-02
0.19955
0.10611
0.25065E-02
0.43316
0.26000
0.64269E-02
0.43224
0.30461
0.74470E-02
0.39786
0.33551
0.80485E-02
0.33501
0.34244
0.80024E-02
1-BUTENE
0.84267E-07
0.74036E-06
0.20330E-02
0.30276E-02
0.50756E-02
0.11974E-01
0.12660E-01
0.12371E-01
0.11064E-01
STAGE
1
2
12
13
14
17
18
19
20
ISOBUTEN
0.27998E-06
0.24665E-05
0.72619E-02
0.10853E-01
0.18448E-01
0.43759E-01
0.45951E-01
0.44546E-01
0.39455E-01
****
MOLE-Y-PROFILE
****
CIS-2-01
2-MET-02
1:2-B-01
0.18656E-07
0.11661E-11
0.15404E-12
0.22796E-06
0.32281E-10
0.23728E-11
0.90318E-02
0.16356E-02
0.60917E-06
0.17327E-01
0.62609E-02
0.14029E-05
0.27015E-01
0.85840E-02
0.20048E-05
0.67828E-01
0.14850E-01
0.42121E-05
0.81696E-01
0.23798E-01
0.55661E-05
0.92682E-01
0.41614E-01
0.72737E-05
0.97491E-01
0.68685E-01
0.91254E-05
1:3-B-01
0.70962E-07
0.67056E-06
0.32747E-02
0.50962E-02
0.87141E-02
0.21403E-01
0.22720E-01
0.22214E-01
0.19830E-01
STAGE
1
2
12
13
14
17
18
19
20
N-PENTAN
0.11148E-13
0.40645E-12
0.18995E-03
0.89971E-03
0.12334E-02
0.18363E-02
0.28871E-02
0.53307E-02
0.99773E-02
****
MOLE-Y-PROFILE
****
N-HEXANE
N-HEPTAN
BENZENE
0.50407E-20
0.20274E-24
0.60568E-23
0.58245E-18
0.73372E-22
0.10912E-20
0.42809E-05
0.61816E-05
0.26902E-06
0.50518E-04
0.17381E-03
0.43979E-05
0.70822E-04
0.25229E-03
0.62624E-05
0.77745E-04
0.26991E-03
0.69528E-05
0.11197E-03
0.32394E-03
0.83995E-05
0.27178E-03
0.67901E-03
0.15922E-04
0.89758E-03
0.33006E-02
0.59084E-04
NITRO-01
0.42637E-03
0.14384E-04
0.54854E-05
0.56503E-05
0.17373E-06
0.31588E-11
0.70165E-13
0.15240E-14
0.33279E-16
****
K-VALUES
****
WATER
METHANOL
DME
0.15947E-02
0.41014E-01
0.21900
0.71484E-02
0.26236
0.45462
0.20161E-01
0.32399
0.74800
0.34713E-01
0.39241
0.93187
0.54311E-01
0.47974
1.1820
0.11274
0.66186
1.7857
0.13455
0.75492
1.9166
0.17095
0.85153
2.0717
0.25967
0.64667
2.4289
METHY-01
0.76400E-01
0.17995
0.31829
0.40746
0.52916
0.82208
0.88655
0.96382
1.1457
****
K-VALUES
****
N-PRO-01
METHA-01
N-BUT-01
0.17750E-01
0.86521E-02
0.65715E-02
0.49747E-01
0.25963E-01
0.20713E-01
METHY-03
0.12352E-01
0.37495E-01
STAGE
1
2
12
13
14
17
18
19
20
STAGE
1
2
CO2
2.2471
4.0517
6.0600
7.2169
8.7052
11.949
12.604
13.345
14.939
METHY-02
0.32919E-01
0.84018E-01
0.27292E-03
0.30692E-03
0.35431E-03
0.63445E-03
0.29581E-02
12
13
14
17
18
19
20
0.15781
0.23620
0.31478
0.48276
0.53237
0.64171
1.0771
0.99070E-01
0.14177
0.19354
0.31823
0.35072
0.40429
0.57207
0.53784E-01
0.73685E-01
0.10243
0.17730
0.19471
0.21621
0.26897
0.44230E-01
0.65204E-01
0.91687E-01
0.15774
0.17500
0.20358
0.29571
0.78514E-01
0.11730
0.16282
0.27237
0.30192
0.35278
0.51080
STAGE
1
2
12
13
14
17
18
19
20
3-MET-01
0.30909E-02
0.11152E-01
0.26026E-01
0.37537E-01
0.54971E-01
0.10352
0.11535
0.13029
0.16822
****
K-VALUES
****
VALER-01
ETHANOL
CIS-C-01
0.21439E-02
0.39148E-02
0.36032E-02
0.79099E-02
0.16698E-01
0.12684E-01
0.18778E-01
0.44140E-01
0.29111E-01
0.30859E-01
0.72110E-01
0.41692E-01
0.45331E-01
0.11094
0.60637E-01
0.81691E-01
0.22123
0.11302
0.92320E-01
0.25414
0.12573
0.11332
0.30885
0.14174
0.19344
0.49230
0.18226
METHY-05
0.31229E-02
0.10771E-01
0.24875E-01
0.38348E-01
0.55574E-01
0.10102
0.11387
0.13417
0.19271
STAGE
1
2
12
13
14
17
18
19
20
DIETH-01
0.22859E-02
0.82147E-02
0.19388E-01
0.29900E-01
0.43753E-01
0.81018E-01
0.90652E-01
0.10461
0.14482
****
K-VALUES
****
2-MET-01
METHY-06
DIETH-02
0.12243E-02
0.22098E-02
0.22859E-02
0.62714E-02
0.81200E-02
0.82147E-02
0.17888E-01
0.19216E-01
0.19388E-01
0.29500E-01
0.29013E-01
0.29900E-01
0.46354E-01
0.42304E-01
0.43753E-01
0.94023E-01
0.78443E-01
0.81018E-01
0.10688
0.87409E-01
0.90652E-01
0.12730
0.99005E-01
0.10461
0.19385
0.12914
0.14482
METHY-07
0.22098E-02
0.81200E-02
0.19216E-01
0.29013E-01
0.42304E-01
0.78443E-01
0.87409E-01
0.99005E-01
0.12914
STAGE
1
2
12
13
14
17
18
19
20
3-MET-02
0.12152E-02
0.47023E-02
0.11662E-01
0.18574E-01
0.27948E-01
0.53773E-01
0.60841E-01
0.72368E-01
0.11089
****
K-VALUES
TERT--01
METHANE
0.29292E-02
11.508
0.13871E-01
15.726
0.37394E-01
19.485
0.59610E-01
21.334
0.91373E-01
23.582
0.17922
27.940
0.20238
28.711
0.23793
29.467
0.35148
30.774
CYCLO-01
0.26302
0.52048
0.83190
1.0242
1.2844
1.9045
2.0373
2.1931
2.5481
STAGE
1
2
12
13
14
17
18
19
20
PROPYLEN
0.41424
0.78230
1.2259
1.5000
1.8610
2.6788
2.8496
3.0474
3.4888
****
K-VALUES
****
ISOBUTAN
N-BUTANE
TRANS-BU
0.13004
0.92043E-01
0.88930E-01
0.27222
0.20197
0.19792
0.45129
0.34441
0.34108
0.56394
0.43534
0.43419
0.71679
0.55943
0.56251
1.0833
0.86096
0.88165
1.1631
0.92808
0.95437
1.2577
1.0075
1.0407
1.4759
1.1891
1.2408
1-BUTENE
0.11382
0.24553
0.41148
0.51617
0.65817
1.0042
1.0822
1.1745
1.3847
STAGE
1
2
12
13
14
17
18
19
20
ISOBUTEN
0.11352
0.24345
0.41003
0.51611
0.66122
1.0150
1.0940
1.1889
1.4107
****
K-VALUES
****
CIS-2-01
2-MET-02
1:2-B-01
0.81839E-01
0.36124E-01
0.64919E-01
0.18429
0.87689E-01
0.15127
0.31939
0.16007
0.26605
0.40717
0.23327
0.33952
0.52759
0.30631
0.43908
0.82600
0.46367
0.67470
0.89378
0.50758
0.72570
0.97335
0.59497
0.78621
1.1556
0.90429
0.92594
1:3-B-01
0.10583
0.23013
0.39374
0.49907
0.64298
1.0010
1.0824
1.1776
1.3926
STAGE
N-PENTAN
****
K-VALUES
N-HEXANE
N-HEPTAN
****
ETHYLENE
2.3420
3.8471
5.4010
6.2528
7.3241
9.5682
10.004
10.482
11.463
****
BENZENE
NITRO-01
1
2
12
13
14
17
18
19
20
0.27429E-01
0.69477E-01
0.12936
0.18807
0.24975
0.39124
0.43007
0.49674
0.69593
0.86543E-02
0.25423E-01
0.51922E-01
0.80401E-01
0.11116
0.18076
0.20111
0.24475
0.42174
0.27631E-02
0.95624E-02
0.21793E-01
0.34800E-01
0.50131E-01
0.87806E-01
0.98162E-01
0.11707
0.18592
0.55506E-02
0.17542E-01
0.37481E-01
0.52024E-01
0.73284E-01
0.12962
0.14289
0.15937
0.20020
29.642
36.466
42.068
44.612
47.707
53.453
54.386
55.165
56.113
STAGE
1
2
12
13
14
17
18
19
20
CO2
0.95492E-02
0.21950E-02
0.53393E-03
0.43450E-03
0.65540E-04
0.10298E-06
0.96035E-08
0.84932E-09
0.68970E-10
****
MASS-X-PROFILE
****
WATER
METHANOL
DME
0.26995E-22
0.80469E-08
0.24621E-08
0.35171E-20
0.28566E-07
0.50441E-08
0.82558E-03
0.10143E-04
0.29978E-07
0.13897E-01
0.15110E-04
0.19579E-07
0.13456E-01
0.15286E-04
0.21222E-07
0.78696E-02
0.17944E-04
0.10148E-07
0.89971E-02
0.20339E-04
0.60755E-08
0.16643E-01
0.21692E-04
0.33312E-08
0.43670E-01
0.31180E-04
0.15533E-08
METHY-01
0.19523E-13
0.10104E-12
0.22418E-08
0.32149E-08
0.36865E-08
0.53663E-08
0.59403E-08
0.62348E-08
0.56609E-08
STAGE
1
2
12
13
14
17
18
19
20
METHY-02
0.21938E-17
0.24319E-16
0.77071E-09
0.19066E-08
0.19234E-08
0.22815E-08
0.34015E-08
0.49481E-08
0.47320E-08
****
MASS-X-PROFILE
****
N-PRO-01
METHA-01
N-BUT-01
0.11626E-13
0.34466E-17
0.77694E-19
0.21766E-12
0.12363E-15
0.34935E-17
0.94472E-03
0.28471E-03
0.66933E-04
0.38938E-02
0.22577E-02
0.59981E-03
0.38261E-02
0.21925E-02
0.58169E-03
0.29046E-02
0.13211E-02
0.34709E-03
0.40135E-02
0.15165E-02
0.40565E-03
0.69226E-02
0.26549E-02
0.75127E-03
0.10900E-01
0.68309E-02
0.18306E-02
METHY-03
0.48880E-16
0.12142E-14
0.69279E-04
0.34509E-03
0.33785E-03
0.23846E-03
0.32321E-03
0.58090E-03
0.99255E-03
STAGE
1
2
12
13
14
17
18
19
20
3-MET-01
0.97712E-24
0.81600E-22
0.48640E-06
0.75714E-05
0.73172E-05
0.41560E-05
0.43929E-05
0.72955E-05
0.23783E-04
****
MASS-X-PROFILE
****
VALER-01
ETHANOL
CIS-C-01
0.16330E-24
0.89596E-21
0.10513E-22
0.19228E-22
0.49973E-19
0.77192E-21
0.33544E-05
0.30207E-05
0.13796E-05
0.63517E-04
0.24477E-04
0.19336E-04
0.61259E-04
0.23982E-04
0.18700E-04
0.34359E-04
0.16277E-04
0.10694E-04
0.36637E-04
0.22044E-04
0.11432E-04
0.65781E-04
0.41908E-04
0.19240E-04
0.20100E-03
0.73495E-04
0.60471E-04
METHY-05
0.50811E-21
0.43935E-19
0.40858E-03
0.62256E-02
0.60130E-02
0.34174E-02
0.36743E-02
0.63853E-02
0.19547E-01
STAGE
1
2
12
13
14
17
18
19
20
DIETH-01
0.13448E-22
0.15247E-20
0.18711E-03
0.36566E-02
0.35263E-02
0.19721E-02
0.20432E-02
0.33336E-02
0.11585E-01
****
MASS-X-PROFILE
****
2-MET-01
METHY-06
DIETH-02
0.36240E-27
0.35458E-22
0.13448E-22
0.53820E-25
0.40670E-20
0.15247E-20
0.37414E-07
0.54596E-03
0.18711E-03
0.74106E-06
0.10995E-01
0.36566E-02
0.71642E-06
0.10600E-01
0.35263E-02
0.40665E-06
0.59135E-02
0.19721E-02
0.43624E-06
0.60658E-02
0.20432E-02
0.76759E-06
0.95906E-02
0.33336E-02
0.23431E-05
0.34876E-01
0.11585E-01
METHY-07
0.35458E-22
0.40670E-20
0.54596E-03
0.10995E-01
0.10600E-01
0.59135E-02
0.60658E-02
0.95906E-02
0.34876E-01
STAGE
1
2
12
13
14
17
18
19
20
3-MET-02
0.44803E-26
0.88738E-24
0.22639E-04
0.71220E-03
0.68534E-03
0.37739E-03
0.38095E-03
0.59411E-03
0.22837E-02
****
MASS-X-PROFILE
****
TERT--01
METHANE
ETHYLENE
0.32069E-22
0.28155E-02
0.18820
0.21533E-20
0.16674E-03
0.45562E-01
0.70497E-06
0.44940E-04
0.11963E-01
0.69103E-05
0.40257E-04
0.10018E-01
0.67373E-05
0.22416E-05
0.17961E-02
0.41835E-05
0.24497E-09
0.52836E-05
0.51169E-05
0.10031E-10
0.62074E-06
0.96100E-05
0.40209E-12
0.69842E-07
0.21087E-04
0.15964E-13
0.73603E-08
CYCLO-01
0.59528E-04
0.10652E-03
0.27535E-03
0.17427E-03
0.17533E-03
0.69115E-04
0.39064E-04
0.20308E-04
0.90602E-05
STAGE
1
2
12
13
14
17
18
19
20
PROPYLEN
0.79923
0.95151
0.52720
0.36293
0.25567
0.36668E-01
0.15005E-01
0.57064E-02
0.18982E-02
****
MASS-X-PROFILE
****
ISOBUTAN
N-BUTANE
TRANS-BU
0.12191E-03
0.33545E-05
0.62877E-07
0.41710E-03
0.15469E-04
0.29588E-06
0.23132
0.13409
0.29701E-02
0.23974
0.17998
0.39971E-02
0.30867
0.21030
0.47693E-02
0.40781
0.30799
0.71767E-02
0.37527
0.33143
0.76063E-02
0.31947
0.33632
0.75397E-02
0.23322
0.29588
0.63966E-02
1-BUTENE
0.10841E-05
0.41122E-05
0.57928E-02
0.65581E-02
0.82539E-02
0.11739E-01
0.11403E-01
0.10268E-01
0.79250E-02
STAGE
1
2
12
13
14
17
18
19
20
ISOBUTEN
0.36117E-05
0.13817E-04
0.20765E-01
0.23511E-01
0.29862E-01
0.42446E-01
0.40942E-01
0.36528E-01
0.27740E-01
****
MASS-X-PROFILE
****
CIS-2-01
2-MET-02
1:2-B-01
0.33380E-06
0.60785E-10
0.33496E-11
0.16870E-05
0.64560E-09
0.20623E-10
0.33155E-01
0.15406E-01
0.25881E-05
0.47580E-01
0.38589E-01
0.44540E-05
0.54806E-01
0.38570E-01
0.47114E-05
0.80844E-01
0.40547E-01
0.59254E-05
0.89099E-01
0.58771E-01
0.72080E-05
0.92829E-01
0.87682E-01
0.86953E-05
0.83669E-01
0.96871E-01
0.94233E-05
1:3-B-01
0.94662E-06
0.38310E-05
0.94008E-02
0.11007E-01
0.13984E-01
0.20295E-01
0.19725E-01
0.17729E-01
0.13616E-01
STAGE
1
2
12
13
14
17
18
19
20
N-PENTAN
0.76533E-12
0.10259E-10
0.22139E-02
0.68784E-02
0.67973E-02
0.59422E-02
0.84150E-02
0.13453E-01
0.18285E-01
****
MASS-X-PROFILE
****
N-HEXANE
N-HEPTAN
BENZENE
0.13100E-17
0.19188E-21
0.22246E-20
0.47990E-16
0.18688E-19
0.11811E-18
0.14847E-03
0.59396E-03
0.11716E-04
0.10790E-02
0.99729E-02
0.13159E-03
0.10474E-02
0.96198E-02
0.12733E-03
0.65038E-03
0.54047E-02
0.73521E-04
0.83360E-03
0.57450E-02
0.79775E-04
0.16627E-02
0.10099E-01
0.13560E-03
0.32420E-02
0.31445E-01
0.40750E-03
NITRO-01
0.10516E-04
0.26858E-06
0.76330E-07
0.70704E-07
0.19460E-08
0.29047E-13
0.62789E-15
0.13447E-16
0.29368E-18
STAGE
1
2
12
13
14
17
18
19
20
CO2
0.25976E-01
0.95492E-02
0.36154E-02
0.35633E-02
0.62561E-03
0.12567E-05
0.12209E-06
0.11298E-07
0.10092E-08
****
MASS-Y-PROFILE
****
WATER
METHANOL
DME
0.52116E-25
0.39954E-09
0.65276E-09
0.26995E-22
0.80469E-08
0.24621E-08
0.18598E-04
0.36720E-05
0.25056E-07
0.54817E-03
0.67375E-05
0.20732E-07
0.80138E-03
0.80414E-05
0.27507E-07
0.90611E-03
0.12129E-04
0.18507E-07
0.12210E-02
0.15486E-04
0.11745E-07
0.28359E-02
0.18412E-04
0.68790E-08
0.11107E-01
0.19749E-04
0.36954E-08
METHY-01
0.18056E-14
0.19523E-13
0.79729E-09
0.14885E-08
0.21390E-08
0.45054E-08
0.53116E-08
0.59899E-08
0.63524E-08
STAGE
1
2
12
13
14
17
18
19
20
METHY-02
0.87427E-19
0.21938E-17
0.13590E-09
0.51174E-09
0.66387E-09
0.11248E-08
0.18264E-08
0.31651E-08
0.49924E-08
****
MASS-Y-PROFILE
****
N-PRO-01
METHA-01
N-BUT-01
0.24981E-15
0.36100E-19
0.61809E-21
0.11626E-13
0.34466E-17
0.77694E-19
0.10458E-03
0.17110E-04
0.33079E-05
0.62727E-03
0.18904E-03
0.44442E-04
0.81197E-03
0.24626E-03
0.58482E-04
0.94401E-03
0.23921E-03
0.55916E-04
0.14197E-02
0.29782E-03
0.71598E-04
0.27897E-02
0.57217E-03
0.15245E-03
0.61078E-02
0.17996E-02
0.53020E-03
METHY-03
0.73090E-18
0.48880E-16
0.60778E-05
0.46000E-04
0.60320E-04
0.66331E-04
0.98421E-04
0.20427E-03
0.49658E-03
STAGE
1
2
12
13
14
17
18
19
3-MET-01
0.36562E-26
0.97712E-24
0.14145E-07
0.32296E-06
0.44106E-06
0.43940E-06
0.51107E-06
0.94745E-06
****
MASS-Y-PROFILE
****
VALER-01
ETHANOL
CIS-C-01
0.42382E-27
0.42462E-23
0.45857E-25
0.16330E-24
0.89596E-21
0.10513E-22
0.70382E-07
0.14898E-06
0.44877E-07
0.22273E-05
0.20057E-05
0.91605E-06
0.30450E-05
0.29174E-05
0.12434E-05
0.28665E-05
0.36775E-05
0.12343E-05
0.34114E-05
0.56506E-05
0.14496E-05
0.74301E-05
0.12902E-04
0.27183E-05
METHY-05
0.19209E-23
0.50811E-21
0.11356E-04
0.27129E-03
0.36642E-03
0.35258E-03
0.42201E-03
0.85395E-03
20
0.39185E-05
0.38084E-04
0.35439E-04
0.10795E-04
0.36895E-02
STAGE
1
2
12
13
14
17
18
19
20
DIETH-01
0.37214E-25
0.13448E-22
0.40534E-05
0.12424E-03
0.16918E-03
0.16317E-03
0.18681E-03
0.34761E-03
0.16434E-02
****
MASS-Y-PROFILE
****
2-MET-01
METHY-06
DIETH-02
0.53713E-30
0.94856E-25
0.37214E-25
0.36240E-27
0.35458E-22
0.13448E-22
0.74781E-09
0.11723E-04
0.40534E-05
0.24842E-07
0.36250E-03
0.12424E-03
0.36414E-07
0.49172E-03
0.16918E-03
0.39048E-07
0.47374E-03
0.16317E-03
0.47027E-07
0.53476E-03
0.18681E-03
0.97399E-07
0.94646E-03
0.34761E-03
0.44488E-06
0.44114E-02
0.16434E-02
METHY-07
0.94856E-25
0.35458E-22
0.11723E-04
0.36250E-03
0.49172E-03
0.47374E-03
0.53476E-03
0.94646E-03
0.44114E-02
STAGE
1
2
12
13
14
17
18
19
20
3-MET-02
0.65910E-29
0.44803E-26
0.29500E-06
0.15032E-04
0.21003E-04
0.20725E-04
0.23377E-04
0.42856E-04
0.24804E-03
****
MASS-Y-PROFILE
****
TERT--01
METHANE
ETHYLENE
0.11372E-24
0.39224E-01
0.53359
0.32069E-22
0.28155E-02
0.18820
0.29455E-07
0.97846E-03
0.72194E-01
0.46808E-06
0.97592E-03
0.71183E-01
0.67502E-06
0.57963E-04
0.14425E-01
0.76573E-06
0.69901E-08
0.51630E-04
0.10445E-05
0.29046E-09
0.62634E-05
0.22792E-05
0.11810E-10
0.72973E-06
0.72593E-05
0.48117E-12
0.82640E-07
CYCLO-01
0.18954E-04
0.59528E-04
0.25595E-03
0.20283E-03
0.24694E-03
0.13443E-03
0.80267E-04
0.44395E-04
0.22612E-04
STAGE
1
2
12
13
14
17
18
19
20
PROPYLEN
0.40079
0.79923
0.72213
0.61861
0.52172
0.10032
0.43125E-01
0.17334E-01
0.64864E-02
****
MASS-Y-PROFILE
****
ISOBUTAN
N-BUTANE
TRANS-BU
0.19193E-04
0.37378E-06
0.67692E-08
0.12191E-03
0.33545E-05
0.62877E-07
0.11664
0.51604E-01
0.11320E-02
0.15363
0.89036E-01
0.19721E-02
0.24261
0.12901
0.29417E-02
0.45117
0.27081
0.64620E-02
0.44023
0.31024
0.73216E-02
0.40051
0.33775
0.78212E-02
0.33713
0.34461
0.77738E-02
1-BUTENE
0.14938E-06
0.10841E-05
0.26634E-02
0.38466E-02
0.59569E-02
0.12039E-01
0.12447E-01
0.12021E-01
0.10748E-01
STAGE
1
2
12
13
14
17
18
19
20
ISOBUTEN
0.49632E-06
0.36117E-05
0.95136E-02
0.13789E-01
0.21651E-01
0.43998E-01
0.45177E-01
0.43288E-01
0.38328E-01
****
MASS-Y-PROFILE
****
CIS-2-01
2-MET-02
1:2-B-01
0.33071E-07
0.26582E-11
0.26325E-12
0.33380E-06
0.60785E-10
0.33496E-11
0.11832E-01
0.27555E-02
0.76938E-06
0.22014E-01
0.10229E-01
0.17184E-05
0.31706E-01
0.12955E-01
0.22684E-05
0.68198E-01
0.19201E-01
0.40829E-05
0.80320E-01
0.30087E-01
0.52758E-05
0.90064E-01
0.52001E-01
0.68143E-05
0.94705E-01
0.85800E-01
0.85462E-05
1:3-B-01
0.12127E-06
0.94662E-06
0.41359E-02
0.62422E-02
0.98597E-02
0.20747E-01
0.21535E-01
0.20811E-01
0.18572E-01
STAGE
1
2
12
13
14
17
18
19
20
N-PENTAN
0.25413E-13
0.76533E-12
0.32000E-03
0.14699E-02
0.18615E-02
0.23743E-02
0.36501E-02
0.66613E-02
0.12463E-01
****
MASS-Y-PROFILE
****
N-HEXANE
N-HEPTAN
BENZENE
0.13724E-19
0.64184E-24
0.14948E-22
0.13100E-17
0.19188E-21
0.22246E-20
0.86139E-05
0.14463E-04
0.49067E-06
0.98583E-04
0.39437E-03
0.77792E-05
0.12767E-03
0.52880E-03
0.10232E-04
0.12006E-03
0.48466E-03
0.97325E-05
0.16909E-03
0.56879E-03
0.11497E-04
0.40564E-03
0.11784E-02
0.21541E-04
0.13392E-02
0.57263E-02
0.79907E-04
NITRO-01
0.37737E-03
0.10516E-04
0.35880E-05
0.35843E-05
0.10180E-06
0.15857E-11
0.34442E-13
0.73941E-15
0.16141E-16
********************************
********************************
*** DEFINITIONS ***

WHERE:
STAGE
1
2
12
13
14
17
18
19
20
STAGE
1
2
12
13
14
17
18
19
20
*******************
*** SECTION
1 ***
*******************
TEMPERATURE
F
VAPOR TO
150.65
162.23
216.20
240.29
259.38
293.62
304.06
328.44
328.44
LIQUID FROM
95.813
150.65
194.50
216.20
240.29
285.07
293.62
304.06
328.44
MARANGONI INDEX
DYNE/CM
-2.0452
0.25369
-1.7034
-.43151
-.40786
0.88077E-01
1.1756
4.1496
0.33233
0.22659
0.23577
0.51295
0.52449
0.49302
0.49614
0.49915
2
16
GLITSCH
DESIGN PARAMETERS
FLOODING FACTOR
HOLE AREA/ACTIVE AREA
1.00000
1.00000
0.80000
1.00000
0.100000
0.12000
QR
CUFT/HR
14239.
17262.
18235.
29394.
31636.
75178.
79974.
70117.
0.0000
FT
SIEVE
1
2.00000
FT
WEIGHT
VAPOR TO
38.317
40.081
44.161
47.807
50.879
57.069
57.738
57.758
VISCOSITY
SURFACE TENSION
CP
DYNE/CM
LIQUID FROM
0.58684E-01 0.10257E-01
4.1070
0.46272E-01 0.10221E-01
2.0619
0.53928E-01 0.10666E-01
1.7902
0.62118E-01 0.10650E-01
4.3183
0.64769E-01 0.10636E-01
3.8868
0.69782E-01 0.10560E-01
1.9359
0.68310E-01 0.10654E-01
2.0240
0.66973E-01 0.11025E-01
3.1997
0.68263E-01
7.3493
FLOW PARAM

ENDING STAGE NUMBER
TRAY SPECIFICATIONS
------------------TRAY TYPE
NUMBER OF PASSES
TRAY SPACING
MASS FLOW
VOLUME FLOW
MOLECULAR
LB/HR
CUFT/HR
LIQUID FROM
0.12507E+06 0.12507E+06 4463.1
40412.
38.317
93047.
0.14516E+06 3658.9
45679.
41.141
0.10297E+06 0.15508E+06 4019.1
48009.
47.855
0.37491E+06 0.26038E+06 14088.
77094.
50.182
0.39160E+06 0.27707E+06 15408.
79163.
52.422
0.73121E+06 0.61668E+06 33708.
0.16443E+06 56.991
0.75904E+06 0.64451E+06 35985.
0.17217E+06 57.559
0.67366E+06 0.55913E+06 31854.
0.15404E+06 57.553
0.11452E+06 0.0000
5009.5
0.0000
56.572
DENSITY
LB/CUFT
1
28.022
3.0948
2
25.430
3.1778
12
25.620
3.2303
13
26.611
3.3775
14
25.415
3.5000
17
21.692
3.7503
18
21.093
3.7435
19
21.148
3.6298
20
22.861
STAGE
1
2
12
13
14
17
18
19
20
************************************
************************************

COLUMN DIAMETER
DC AREA/COLUMN AREA
DOWNCOMER VELOCITY
FLOW PATH LENGTH
SIDE WEIR LENGTH
CENTER WEIR LENGTH
16
15.4334
0.13474
0.28642
9.49331
2.97005
12.1683
0.0
0.0
0.0
0.0
0.0
0.0
FT
FT/SEC
FT
FT
FT
FT
FT
FT
FT
FT
FT

STAGE
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
REDUCED F-FACTOR
(LB-CUFT)**.5/HR
71093.
81429.
86286.
0.14168E+06
0.14810E+06
0.31844E+06
0.33311E+06
0.29348E+06
0.0000
BLOCK:
B-703
DIAMETER
FT
5.7242
6.1295
6.2380
6.2612
6.2613
6.2495
6.2218
6.1682
6.0844
5.9956
5.9548
9.9451
10.551
11.800
15.433
MODEL: PUMP
TOTAL AREA
SQFT
25.735
29.508
30.562
30.790
30.790
30.675
30.403
29.882
29.075
28.232
27.850
77.680
87.436
109.36
187.07
ACTIVE AREA
SQFT
19.155
21.684
22.393
22.546
22.546
22.469
22.289
21.943
21.410
20.858
20.645
52.886
59.516
75.615
136.66
SIDE DC AREA
SQFT
3.2899
3.9120
4.0846
4.1219
4.1221
4.1027
4.0571
3.9691
3.8326
3.6874
3.6027
12.397
13.960
16.874
25.206
---------------------------INLET STREAM:
S-703
OUTLET STREAM:
S-704
NRTL
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
1360.00
52111.3
0.898738E+07
***
INPUT DATA
***
OUT
RELATIVE DIFF.
1360.00
52111.3
0.906583E+07
670.000
1.00000
NO FLASH PERFORMED
TOLERANCE
30
0.000100000
*** RESULTS
PRESSURE CHANGE PSI
NPSH AVAILABLE
FT-LBF/LB
FLUID POWER HP
BRAKE POWER HP
ELECTRICITY KW
BLOCK: B-704
MODEL: VALVE
----------------------------INLET STREAM:
S-704
OUTLET STREAM:
S-705
NRTL
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
***
1,859.64
145.000
0.0
19.6107
30.8321
22.9915
0.63605
30.8321
745.122

INPUT DATA
***
OUT
TOTAL BALANCE
****
2
30
0.000100000
***
PSI
17.4400

IN
***
OUT
****
COL-SPECS
****
PROFILES
***
LBMOL/HR
RELATIVE DIFF.
PRES, PSIA
S-706
***
0.0
1.20000
365.000
****
STAGE
COMPONENT:
CO2
METHANOL
DME
METHY-01
N-PRO-01
METHANE
ETHYLENE
CYCLO-01
PROPYLEN
ISOBUTAN
N-BUTANE
TRANS-BU
1-BUTENE
ISOBUTEN
CIS-2-01
2-MET-02
1:2-B-01
1:3-B-01
N-PENTAN
NITRO-01
17
STANDARD
NO
STANDARD
NO
BROYDEN
NESTED
25
10
30
0.000100000
0.000100000
****

MOLAR REFLUX RATIO
MOLAR DISTILLATE RATE
0.00000
0.00000
0.00000
652.560
NO
RESULTS
BLOCK: B-705
MODEL: RADFRAC
------------------------------INLETS
- S-705
STAGE
6
OUTLETS - S-706
STAGE
1
S-707
STAGE 17
NRTL
RELATIVE DIFF.
***
NPHASE
***
INPUT PARAMETERS
NUMBER OF STAGES
ALGORITHM OPTION
ABSORBER OPTION
FLASH TOLERANCE
*******************
**** RESULTS ****
*******************
1360.00
52111.3
0.906583E+07
PSIA
***
****
1360.00
52111.3
0.906583E+07
***
0.00000
-0.117284E-13
-0.328460
**********************
**********************
P-SPEC

IN
VALVE PRESSURE DROP
0.00000
0.00000
-0.865340E-02
***

DRIVER EFFICIENCY
***
1360.00
52111.3
0.135001E+08

IN
1360.00
52111.3
0.906583E+07
.98433
.21167E-10
.57742E-04
.19658E-06
.80294E-10
1.0000
.98070
.16692E-03
.18796E-02
.41353E-05
.63244E-06
.51469E-06
.18781E-05
.19445E-05
.32399E-06
.43110E-08
.91643E-07
.13099E-05
.95379E-09
1.0000
***
OUTLET STREAMS
-------------S-707
.15669E-01
1.0000
.99994
1.0000
1.0000
.47386E-09
.19303E-01
.99983
.99812
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
.13545E-13
***
650.000

BOILUP VAPOR FLOW
MOLAR REFLUX RATIO
MOLAR BOILUP RATIO
REBOILER DUTY
****
F
F
LBMOL/HR
LBMOL/HR
LBMOL/HR
LBMOL/HR
BTU/HR
BTU/HR
DEW POINT
BUBBLE POINT
ENERGY BALANCE
****
PROFILES
29.4240
192.701
438.000
995.000
0.0
2,509.94
1.20000
2.52256
-2,068,830.
6,503,030.
****
0.17591E-05
0.68036E-06
0.41689E-05
0.52469E-04
STAGE=
STAGE=
STAGE=
STAGE=
4
4
3 COMP=NITRO-01
4
1
2
4
5
6
7
15
16
17
29.424
40.348
68.887
93.057
104.69
105.61
174.57
187.07
192.70
STAGE
1
2
4
5
6
7
15
16
17
PRESSURE
PSIA
LIQUID
650.00
652.00
652.28
652.42
652.56
652.70
653.82
653.96
654.10
FLOW RATE
LBMOL/HR
LIQUID
VAPOR
803.0
0.000
519.8
803.0
359.2
986.8
263.3
724.2
1897.
628.3
1909.
902.2
2551.
1076.
3505.
1556.
995.0
2510.
****
LIQUID
MIXED
-.20688+07
.65030+07
PRODUCT RATE
LBMOL/HR
LIQUID
VAPOR
365.0000
995.0000
MASS FLOW PROFILES
CO2
0.30493E-01
0.34793E-01
FEED RATE
LBMOL/HR
VAPOR
9855.6
14922.
14533.
14199.
14110.
14550.
11927.
11238.
10860.
HEAT DUTY
BTU/HR
1360.0000
FLOW RATE
LB/HR
LIQUID
VAPOR
0.2273E+05 0.000
0.1509E+05 0.2273E+05
0.1201E+05 0.2921E+05
9508.
0.2235E+05
0.7044E+05 0.1984E+05
0.7091E+05 0.2867E+05
0.1052E+06 0.4182E+05
0.1464E+06 0.6343E+05
0.4178E+05 0.1046E+06
STAGE
1
2
ENTHALPY
BTU/LBMOL
VAPOR
12346.
12806.
10324.
8697.5
8232.0
8259.4
7831.6
8487.4
9039.0
****
STAGE
1
2
4
5
6
7
15
16
17
0.25177E-01
0.15925E-01
0.12151E-01
0.12502E-01
0.19460E-02
0.66762E-03
0.17806E-03
0.19650E-10
0.51850E-09
0.70032E-08
0.69663E-08
0.76314E-08
0.88103E-08
0.13153E-07
0.26446E-09
0.77699E-09
0.16245E-08
0.16197E-08
0.17703E-08
0.19873E-08
0.27989E-08
0.18648E-15
0.15799E-14
0.92413E-14
0.91955E-14
0.77720E-14
0.79074E-14
0.17014E-13
0.61676E-17
0.22712E-15
0.55441E-14
0.55119E-14
0.42441E-14
0.35609E-14
0.10484E-13
STAGE
1
2
4
5
6
7
15
16
17
METHANE
0.25056E-01
0.40138E-02
0.13556E-02
0.14620E-02
0.15491E-02
0.33087E-03
0.46856E-09
0.50123E-10
0.43555E-11
****
MOLE-X-PROFILE
****
ETHYLENE
CYCLO-01
PROPYLEN
0.93930
0.33712E-07
0.50967E-02
0.92746
0.37661E-06
0.33728E-01
0.61724
0.10215E-04
0.35622
0.42537
0.24961E-04
0.55720
0.35176
0.43882E-04
0.63442
0.35269
0.43776E-04
0.63437
0.60660E-01
0.50322E-04
0.93728
0.22925E-01
0.56174E-04
0.97629
0.67822E-02
0.74075E-04
0.99285
ISOBUTAN
0.12384E-08
0.30054E-07
0.35178E-05
0.17388E-04
0.61110E-04
0.60847E-04
0.55070E-04
0.59421E-04
0.10985E-03
STAGE
1
2
4
5
6
7
15
16
17
N-BUTANE
0.52112E-11
0.19073E-09
0.47963E-07
0.33582E-06
0.16528E-05
0.16449E-05
0.14053E-05
0.14498E-05
0.30226E-05
****
MOLE-X-PROFILE
****
TRANS-BU
1-BUTENE
ISOBUTEN
0.82349E-13
0.51810E-11
0.17870E-10
0.31673E-11
0.15193E-09
0.51358E-09
0.86962E-09
0.24758E-07
0.81911E-07
0.63063E-08
0.14010E-06
0.46442E-06
0.32051E-07
0.55891E-06
0.18615E-05
0.31896E-07
0.55640E-06
0.18531E-05
0.27226E-07
0.49290E-06
0.16400E-05
0.28049E-07
0.52433E-06
0.17438E-05
0.58692E-07
0.10119E-05
0.33713E-05
CIS-2-01
0.27520E-12
0.11749E-10
0.39040E-08
0.30788E-07
0.16961E-06
0.16878E-06
0.14246E-06
0.14497E-06
0.31159E-06
STAGE
1
2
4
5
6
7
15
16
17
2-MET-02
0.51853E-18
0.55435E-16
0.10649E-12
0.19108E-11
0.23526E-10
0.23395E-10
0.18387E-10
0.16507E-10
0.44123E-10
****
MOLE-X-PROFILE
****
1:2-B-01
1:3-B-01
N-PENTAN
0.81022E-18
0.32728E-11
0.14444E-20
0.45646E-16
0.10290E-09
0.21578E-18
0.25488E-13
0.19323E-07
0.77412E-15
0.25391E-12
0.11761E-06
0.18339E-13
0.17521E-11
0.50435E-06
0.29506E-12
0.17431E-11
0.50203E-06
0.29339E-12
0.14346E-11
0.43975E-06
0.22814E-12
0.14112E-11
0.46387E-06
0.19844E-12
0.32432E-11
0.91654E-06
0.55555E-12
NITRO-01
0.53595E-04
0.29271E-05
0.97573E-06
0.11665E-05
0.12771E-05
0.10806E-06
0.13326E-15
0.65464E-17
0.26631E-18
STAGE
1
2
4
5
6
7
15
16
17
CO2
0.22861E-01
0.30493E-01
0.32525E-01
0.27856E-01
0.24387E-01
0.25356E-01
0.80144E-02
0.30762E-02
0.86169E-03
****
MOLE-Y-PROFILE
****
METHANOL
DME
METHY-01
0.61492E-21
0.24987E-13
0.14449E-21
0.75893E-18
0.44059E-12
0.91175E-20
0.11620E-12
0.30536E-10
0.69387E-17
0.97471E-11
0.13140E-09
0.92505E-16
0.21729E-09
0.32588E-09
0.66210E-15
0.22095E-09
0.32918E-09
0.66905E-15
0.25280E-08
0.86268E-09
0.15641E-14
0.41019E-08
0.11127E-08
0.18642E-14
0.70890E-08
0.16656E-08
0.42975E-14
N-PRO-01
0.64277E-26
0.22947E-23
0.48177E-19
0.30593E-17
0.95181E-16
0.96401E-16
0.25183E-15
0.25539E-15
0.81659E-15
STAGE
1
2
4
5
6
7
15
16
17
METHANE
0.14363
0.25056E-01
0.10473E-01
0.13300E-01
0.15168E-01
0.32576E-02
0.67372E-08
0.76530E-09
0.68266E-10
****
MOLE-Y-PROFILE
****
ETHYLENE
CYCLO-01
PROPYLEN
0.83193
0.24909E-08
0.64609E-03
0.93930
0.33712E-07
0.50967E-02
0.87433
0.14589E-05
0.82645E-01
0.77955
0.50841E-05
0.17926
0.72392
0.10481E-04
0.23647
0.73224
0.10583E-04
0.23912
0.22891
0.27610E-04
0.76304
0.95102E-01
0.35137E-04
0.90177
0.29324E-01
0.49077E-04
0.96972
ISOBUTAN
0.41425E-10
0.12384E-08
0.24047E-06
0.17455E-05
0.72879E-05
0.73527E-05
0.16137E-04
0.20050E-04
0.39429E-04
****
STAGE TEMPERATURE
F
4
5
6
7
15
16
17
LIQUID
FEED RATE
LB/HR
VAPOR
MIXED
PRODUCT RATE
LB/HR
LIQUID
VAPOR
.10333+05
.52111+05
.41778+05
****
MOLE-X-PROFILE
****
METHANOL
DME
METHY-01
0.75893E-18
0.44059E-12
0.91175E-20
0.60793E-15
0.63135E-11
0.44787E-18
N-PRO-01
0.22947E-23
0.60617E-21
STAGE
N-BUTANE
****
MOLE-Y-PROFILE
TRANS-BU
1-BUTENE
****
ISOBUTEN
CIS-2-01
1
2
4
5
6
7
15
16
17
0.11385E-12
0.52112E-11
0.22536E-08
0.23794E-07
0.14074E-06
0.14205E-06
0.31040E-06
0.37140E-06
0.82623E-06
0.17063E-14
0.82349E-13
0.39198E-10
0.43140E-09
0.26429E-08
0.26680E-08
0.59307E-08
0.71110E-08
0.15901E-07
0.14137E-12
0.51810E-11
0.14467E-08
0.12283E-07
0.58716E-07
0.59264E-07
0.13118E-06
0.16109E-06
0.33103E-06
0.50081E-12
0.17870E-10
0.48161E-08
0.40639E-07
0.19464E-06
0.19642E-06
0.43359E-06
0.53323E-06
0.10987E-05
0.51089E-14
0.27520E-12
0.16049E-09
0.19366E-08
0.12903E-07
0.13027E-07
0.28974E-07
0.34345E-07
0.78915E-07
STAGE
1
2
4
5
6
7
15
16
17
2-MET-02
0.37560E-20
0.51853E-18
0.18470E-14
0.52824E-13
0.80080E-12
0.80912E-12
0.18274E-11
0.19353E-11
0.55599E-11
****
MOLE-Y-PROFILE
****
1:2-B-01
1:3-B-01
N-PENTAN
0.11289E-19
0.83457E-13
0.73823E-23
0.81022E-18
0.32728E-11
0.14444E-20
0.81371E-15
0.10499E-08
0.99301E-17
0.12643E-13
0.95863E-08
0.38399E-15
0.10641E-12
0.49292E-07
0.76858E-14
0.10748E-12
0.49750E-07
0.77708E-14
0.24194E-12
0.11040E-06
0.18236E-13
0.27836E-12
0.13495E-06
0.18846E-13
0.68491E-12
0.28442E-06
0.56880E-13
NITRO-01
0.92764E-03
0.53595E-04
0.20611E-04
0.27494E-04
0.31623E-04
0.26856E-05
0.42678E-14
0.21827E-15
0.90360E-17
STAGE
1
2
4
5
6
7
15
16
17
CO2
0.74973
0.87640
1.2919
1.7493
2.0070
2.0281
4.1184
4.6077
4.8393
****
K-VALUES
****
METHANOL
DME
METHY-01
0.81024E-03
0.56712E-01
0.15848E-01
0.12484E-02
0.69785E-01
0.20357E-01
0.59136E-02
0.11547
0.37209E-01
0.18799E-01
0.16911
0.58553E-01
0.31028E-01
0.20061
0.71646E-01
0.31717E-01
0.20324
0.72758E-01
0.33127
0.48731
0.20124
0.46558
0.55993
0.23575
0.53898
0.59508
0.25259
N-PRO-01
0.28011E-02
0.37855E-02
0.78116E-02
0.13470E-01
0.17168E-01
0.17489E-01
0.59337E-01
0.71720E-01
0.77893E-01
****
K-VALUES
****
ETHYLENE
CYCLO-01
PROPYLEN
0.88569
0.73887E-01
0.12677
1.0128
0.89515E-01
0.15111
1.4165
0.14282
0.23201
1.8326
0.20368
0.32172
2.0580
0.23883
0.37274
2.0762
0.24175
0.37695
3.7736
0.54867
0.81409
4.1485
0.62550
0.92367
4.3236
0.66254
0.97671
ISOBUTAN
0.33451E-01
0.41205E-01
0.68359E-01
0.10038
0.11926
0.12084
0.29303
0.33742
0.35893
STAGE
1
2
4
5
6
7
15
16
17
METHANE
5.7324
6.2426
7.7257
9.0973
9.7916
9.8457
14.379
15.268
15.673
STAGE
1
2
4
5
6
7
15
16
17
N-BUTANE
0.21847E-01
0.27322E-01
0.46987E-01
0.70853E-01
0.85151E-01
0.86355E-01
0.22088
0.25618
0.27335
****
K-VALUES
****
TRANS-BU
1-BUTENE
ISOBUTEN
0.20721E-01
0.27286E-01
0.28025E-01
0.25999E-01
0.34101E-01
0.34796E-01
0.45075E-01
0.58436E-01
0.58799E-01
0.68407E-01
0.87676E-01
0.87504E-01
0.82461E-01
0.10505
0.10456
0.83647E-01
0.10651
0.10599
0.21783
0.26615
0.26439
0.25352
0.30724
0.30578
0.27093
0.32713
0.32590
CIS-2-01
0.18564E-01
0.23423E-01
0.41110E-01
0.62902E-01
0.76073E-01
0.77186E-01
0.20338
0.23692
0.25327
STAGE
1
2
4
5
6
7
15
16
17
2-MET-02
0.72436E-02
0.93538E-02
0.17344E-01
0.27644E-01
0.34039E-01
0.34585E-01
0.99385E-01
0.11724
0.12601
****
K-VALUES
****
1:2-B-01
1:3-B-01
N-PENTAN
0.13933E-01
0.25500E-01
0.51108E-02
0.17750E-01
0.31806E-01
0.66941E-02
0.31925E-01
0.54335E-01
0.12828E-01
0.49794E-01
0.81507E-01
0.20938E-01
0.60735E-01
0.97733E-01
0.26048E-01
0.61664E-01
0.99097E-01
0.26487E-01
0.16865
0.25105
0.79933E-01
0.19725
0.29093
0.94970E-01
0.21118
0.31032
0.10239
NITRO-01
17.308
18.310
21.123
23.571
24.762
24.852
32.027
33.342
33.931
STAGE
1
2
4
5
6
7
15
16
17
CO2
0.47402E-01
0.52740E-01
0.33139E-01
0.19410E-01
0.14402E-01
0.14810E-01
0.20770E-02
0.70356E-03
0.18663E-03
****
MASS-X-PROFILE
****
METHANOL
DME
METHY-01
0.85895E-18
0.71695E-12
0.19354E-19
0.67092E-15
0.10018E-10
0.92703E-18
0.18831E-10
0.36437E-09
0.33517E-15
0.46013E-09
0.99137E-09
0.26295E-14
0.60434E-08
0.20155E-08
0.14957E-13
0.60085E-08
0.20085E-08
0.14875E-13
0.59302E-08
0.19778E-08
0.11327E-13
0.67599E-08
0.21923E-08
0.11379E-13
0.10037E-07
0.30709E-08
0.24351E-13
N-PRO-01
0.47076E-23
0.12126E-20
0.10713E-16
0.36533E-15
0.86721E-14
0.86173E-14
0.59779E-14
0.49524E-14
0.14502E-13
STAGE
1
2
4
5
6
7
15
16
17
METHANE
0.14199E-01
0.22178E-02
0.65043E-03
0.64959E-03
0.66932E-03
0.14288E-03
0.18230E-09
0.19255E-10
0.16642E-11
****
MASS-X-PROFILE
****
ETHYLENE
CYCLO-01
PROPYLEN
0.93077
0.50109E-07
0.75756E-02
0.89615
0.54585E-06
0.48885E-01
0.51788
0.12857E-04
0.44831
0.33050
0.29091E-04
0.64938
0.26577
0.49732E-04
0.71900
0.26633
0.49586E-04
0.71856
0.41270E-01
0.51354E-04
0.95652
0.15400E-01
0.56603E-04
0.98375
0.45315E-02
0.74239E-04
0.99504
ISOBUTAN
0.25424E-08
0.60165E-07
0.61151E-05
0.27991E-04
0.95660E-04
0.95198E-04
0.77625E-04
0.82702E-04
0.15207E-03
STAGE
1
2
4
5
6
7
15
16
17
N-BUTANE
0.10699E-10
0.38183E-09
0.83377E-07
0.54059E-06
0.25873E-05
0.25735E-05
0.19809E-05
0.20178E-05
0.41842E-05
****
MASS-X-PROFILE
****
TRANS-BU
1-BUTENE
ISOBUTEN
0.16320E-12
0.10268E-10
0.35416E-10
0.61208E-11
0.29360E-09
0.99248E-09
0.14593E-08
0.41545E-07
0.13745E-06
0.97995E-08
0.21770E-06
0.72168E-06
0.48431E-07
0.84456E-06
0.28129E-05
0.48172E-07
0.84033E-06
0.27988E-05
0.37046E-07
0.67068E-06
0.22315E-05
0.37685E-07
0.70445E-06
0.23429E-05
0.78429E-07
0.13522E-05
0.45050E-05
CIS-2-01
0.54540E-12
0.22705E-10
0.65511E-08
0.47842E-07
0.25630E-06
0.25490E-06
0.19385E-06
0.19477E-06
0.41637E-06
STAGE
1
2
4
5
6
7
15
16
17
2-MET-02
0.13215E-17
0.13776E-15
0.22980E-12
0.38183E-11
0.45714E-10
0.45436E-10
0.32173E-10
0.28519E-10
0.75820E-10
****
MASS-X-PROFILE
****
1:2-B-01
1:3-B-01
N-PENTAN
0.15480E-17
0.62531E-11
0.36812E-20
0.85040E-16
0.19170E-09
0.53621E-18
0.41234E-13
0.31260E-07
0.16705E-14
0.38038E-12
0.17619E-06
0.36647E-13
0.25524E-11
0.73474E-06
0.57334E-12
0.25379E-11
0.73097E-06
0.56979E-12
0.18819E-11
0.57686E-06
0.39919E-12
0.18278E-11
0.60083E-06
0.34285E-12
0.41781E-11
0.11808E-05
0.95463E-12
NITRO-01
0.53032E-04
0.28243E-05
0.81749E-06
0.90500E-06
0.96350E-06
0.81487E-07
0.90531E-16
0.43913E-17
0.17767E-18
STAGE
1
2
4
5
6
7
15
16
17
CO2
0.37679E-01
0.47402E-01
0.48349E-01
0.39735E-01
0.33988E-01
0.35120E-01
0.90706E-02
0.33220E-02
0.91004E-03
****
MASS-Y-PROFILE
****
METHANOL
DME
METHY-01
0.73788E-21
0.43109E-13
0.32519E-21
0.85895E-18
0.71695E-12
0.19354E-19
0.12576E-12
0.47515E-10
0.14084E-16
0.10123E-10
0.19620E-09
0.18018E-15
0.22049E-09
0.47543E-09
0.12600E-14
0.22282E-09
0.47728E-09
0.12654E-14
0.20831E-08
0.10221E-08
0.24172E-14
0.32252E-08
0.12579E-08
0.27490E-14
0.54508E-08
0.18413E-08
0.61975E-14
N-PRO-01
0.13981E-25
0.47076E-23
0.94512E-19
0.57590E-17
0.17506E-15
0.17621E-15
0.37613E-15
0.36397E-15
0.11381E-14
STAGE
1
2
4
5
6
7
15
16
METHANE
0.86294E-01
0.14199E-01
0.56752E-02
0.69158E-02
0.77061E-02
0.16448E-02
0.27795E-08
0.30127E-09
****
MASS-Y-PROFILE
****
ETHYLENE
CYCLO-01
PROPYLEN
0.87404
0.39255E-08
0.10182E-02
0.93077
0.50109E-07
0.75756E-02
0.82849
0.20736E-05
0.11747
0.70882
0.69342E-05
0.24449
0.64313
0.13966E-04
0.31512
0.64651
0.14016E-04
0.31669
0.16514
0.29879E-04
0.82573
0.65467E-01
0.36282E-04
0.93114
ISOBUTAN
0.90170E-10
0.25424E-08
0.47209E-06
0.32883E-05
0.13414E-04
0.13450E-04
0.24121E-04
0.28596E-04
17
0.26281E-10
0.19741E-01
0.49559E-04
0.97924
0.54995E-04
STAGE
1
2
4
5
6
7
15
16
17
N-BUTANE
0.24782E-12
0.10699E-10
0.44243E-08
0.44824E-07
0.25905E-06
0.25984E-06
0.46396E-06
0.52971E-06
0.11524E-05
****
MASS-Y-PROFILE
****
TRANS-BU
1-BUTENE
ISOBUTEN
0.35854E-14
0.29704E-12
0.10523E-11
0.16320E-12
0.10268E-10
0.35416E-10
0.74285E-10
0.27417E-08
0.91272E-08
0.78451E-09
0.22337E-07
0.73903E-07
0.46959E-08
0.10433E-06
0.34584E-06
0.47113E-08
0.10465E-06
0.34685E-06
0.85573E-08
0.18928E-06
0.62563E-06
0.97902E-08
0.22179E-06
0.73413E-06
0.21410E-07
0.44571E-06
0.14793E-05
CIS-2-01
0.10735E-13
0.54540E-12
0.30415E-09
0.35218E-08
0.22926E-07
0.23004E-07
0.41806E-07
0.47286E-07
0.10625E-06
STAGE
1
2
4
5
6
7
15
16
17
2-MET-02
0.10149E-19
0.13215E-17
0.45012E-14
0.12353E-12
0.18297E-11
0.18373E-11
0.33907E-11
0.34264E-11
0.96264E-11
****
MASS-Y-PROFILE
****
1:2-B-01
1:3-B-01
N-PENTAN
0.22868E-19
0.16906E-12
0.19947E-22
0.15480E-17
0.62531E-11
0.36812E-20
0.14867E-14
0.19182E-08
0.24200E-16
0.22166E-13
0.16807E-07
0.89795E-15
0.18228E-12
0.84434E-07
0.17561E-13
0.18298E-12
0.84694E-07
0.17646E-13
0.33654E-12
0.15357E-06
0.33836E-13
0.36947E-12
0.17912E-06
0.33366E-13
0.88905E-12
0.36919E-06
0.98482E-13
NITRO-01
0.97319E-03
0.53032E-04
0.19502E-04
0.24964E-04
0.28053E-04
0.23677E-05
0.30746E-14
0.15004E-15
0.60744E-17
********************************
********************************
5
6
7
15
16
17
9507.6
19841.
70443.
28665.
70913.
29135.
0.10521E+06 63431.
0.14637E+06 0.10459E+06
41778.
0.0000
DENSITY
LB/CUFT
1
22.168
3.4400
2
21.891
3.4381
4
25.714
3.3936
5
26.285
3.4025
6
26.189
3.4187
7
26.121
3.4249
15
22.276
3.8399
16
20.510
3.8934
17
19.458
STAGE
1
2
4
5
6
7
15
16
17
MARANGONI INDEX
DYNE/CM
-.24919
1.4466
0.55126
-.68648
-.38689E-01
-.78955
-.52772
-.21345
361.71
2689.8
2714.8
4723.0
7136.6
2147.0
5831.4
8385.0
8506.8
16519.
26864.
0.0000
36.107
37.131
37.150
41.234
41.761
41.988
31.578
31.774
31.883
40.753
41.672
VISCOSITY
SURFACE TENSION
CP
DYNE/CM
LIQUID FROM
0.48156E-01 0.96878E-02
0.94909
0.49852E-01 0.98047E-02
0.69989
0.54864E-01 0.10315E-01
2.6955
0.54739E-01 0.10402E-01
3.2468
0.53576E-01 0.10408E-01
3.2071
0.53501E-01 0.10417E-01
3.1684
0.39618E-01 0.10531E-01
0.87065
0.37018E-01 0.10502E-01
0.34293
0.35892E-01
0.12948
FLOW PARAM
QR
CUFT/HR
2832.4
3192.2
2567.4
2248.6
3249.0
3304.6
7538.9
13004.
0.0000
0.39393
0.23524
0.19528
0.17240
0.88787
0.88133
0.68864
0.60973
REDUCED F-FACTOR
(LB-CUFT)**.5/HR
12257.
13713.
12130.
10756.
15504.
15743.
32370.
53008.
0.0000
*** DEFINITIONS ***

WHERE:
STAGE
1
2
4
5
6
7
15
16
17
************************************
************************************
*******************
*** SECTION
1 ***
*******************
TEMPERATURE
F
VAPOR TO
40.348
48.241
93.057
104.69
105.61
106.65
187.07
192.70
192.70
LIQUID FROM
29.424
40.348
68.887
93.057
104.69
105.61
174.57
187.07
192.70
MASS FLOW
LB/HR
1
22734.
22734.
2
15093.
25426.
4
12012.
22345.
VOLUME FLOW
CUFT/HR
1025.5
6608.6
689.45
7395.4
467.11
6584.5

ENDING STAGE NUMBER
2
16
GLITSCH
DESIGN PARAMETERS
FLOODING FACTOR
1.00000
1.00000
0.80000
1.00000
0.100000
0.12000
TRAY SPECIFICATIONS
------------------TRAY TYPE
NUMBER OF PASSES
TRAY SPACING
FT
FT
SIEVE
1
2.00000
MOLECULAR WEIGHT
LIQUID FROM
28.311
29.034
33.436
VAPOR TO
28.311
28.736
30.853

COLUMN DIAMETER
FT
16
6.55396
DC AREA/COLUMN AREA
DOWNCOMER VELOCITY
FLOW PATH LENGTH
SIDE WEIR LENGTH
CENTER WEIR LENGTH
0.22011
0.26696
2.98849
1.78274
5.83295
0.0
0.0
0.0
0.0
0.0
0.0
FT/SEC
FT
FT
FT
FT
FT
FT
FT
FT
FT

STAGE
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
DIAMETER
FT
2.3695
2.5031
2.0273
1.8560
3.3245
3.3482
3.3503
3.3467
3.3433
3.3504
3.3993
3.5686
4.0161
4.9640
6.5540
TOTAL AREA
SQFT
4.4097
4.9207
3.2280
2.7054
8.6806
8.8047
8.8157
8.7970
8.7787
8.8162
9.0753
10.002
12.668
19.353
33.736
BLOCK: B-806
MODEL: RGIBBS
-----------------------------INLET STREAM:
3
OUTLET STREAM:
1
NRTL
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
ACTIVE AREA
SQFT
3.0481
3.4057
2.3893
2.0640
3.8988
3.9706
3.9733
3.9550
3.9316
3.9328
4.0529
4.5527
6.0715
10.022
18.885

IN
OUT
1361.45
1530.46
49269.4
49269.4
-0.899985E+08 -0.840951E+08
***
SIDE DC AREA
SQFT
0.68076
0.75752
0.41937
0.32073
2.3909
2.4170
2.4212
2.4210
2.4235
2.4417
2.5112
2.7246
3.2980
4.6656
7.4258
INPUT DATA
***
GENERATION
RELATIVE DIFF.
169.015
-0.297131E-15
-0.295354E-14
-0.655940E-01
***
SYSTEM TEMPERATURE
F
887.00
F
887.00
35.000
WATER METHANOL DME METHY-01 METHY-02 N-PRO-01 N-BUT-01 METHY-03
WATER
METHANOL
DME
METHY-01
METHY-02
ACETA-01
N-PRO-01
ACROL-01
METHA-01
N-BUT-01
METHY-03
ACETONE
3-MET-01
1:1-D-01
VALER-01
METHY-04
ETHANOL
CIS-C-01
METHY-05
DIETH-01
2-MET-01
METHY-06
DIETH-02
METHY-07
3-MET-02
TERT--01
METHANE
ETHANE
ETHYLENE
PROPANE
CYCLO-01
PROPYLEN
ISOBUTAN
N-BUTANE
TRANS-BU
1-BUTENE
ISOBUTEN
CIS-2-01
2-MET-02
1:2-B-01
1:3-B-01
N-PENTAN
N-HEXANE
N-HEPTAN
BENZENE
TOLUENE
N-OCT-01
NITRO-01
2.00
4.00
6.00
8.00
10.00
4.00
6.00
4.00
6.00
8.00
6.00
6.00
10.00
10.00
10.00
8.00
6.00
6.00
10.00
10.00
12.00
10.00
10.00
10.00
12.00
10.00
4.00
6.00
4.00
8.00
6.00
6.00
10.00
10.00
8.00
8.00
8.00
8.00
12.00
6.00
6.00
12.00
14.00
16.00
6.00
8.00
18.00
0.00
0.00
1.00
2.00
3.00
4.00
2.00
3.00
3.00
4.00
4.00
3.00
3.00
5.00
4.00
5.00
4.00
2.00
4.00
5.00
5.00
5.00
5.00
5.00
5.00
6.00
4.00
1.00
2.00
2.00
3.00
3.00
3.00
4.00
4.00
4.00
4.00
4.00
4.00
5.00
4.00
4.00
5.00
6.00
7.00
6.00
7.00
8.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
2.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
2.00
1.00
1.00
2.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
*** RESULTS
TEMPERATURE
F
PRESSURE
PSIA
HEAT DUTY
BTU/HR
VAPOR FRACTION
3-MET-01 1:1-D-01 VALER-01 ETHANOL CIS-C-01 METHY-05 DIETH-01

2-MET-01 METHY-06 DIETH-02 METHY-07 3-MET-02 TERT--01 ETHYLENE
CYCLO-01 PROPYLEN ISOBUTAN N-BUTANE CIS-2-01 2-MET-02 1:2-B-01
1:3-B-01
ATOM MATRIX:
ELEMENT
H2
CO2
CO
H
2.00
0.00
0.00
C
0.00
1.00
1.00
N
0.00
0.00
0.00
O
0.00
2.00
1.00
PHASE
OF TYPE
PHASE FRACTION
PLACED IN STREAM
WATER
METHANOL
DME
METHY-01
METHY-02
N-PRO-01
N-BUT-01
METHY-03
VAPOR
VAPOR
1.000000
1
0.5657823
0.1148136E-04
0.8612849E-09
0.1377762E-08
0.8875514E-09
0.1016810E-02
0.1468740E-03
0.8053657E-05
***
887.00
30.000
0.59034E+07
1.0000
1
3-MET-01
1:1-D-01
VALER-01
ETHANOL
CIS-C-01
METHY-05
DIETH-01
2-MET-01
METHY-06
DIETH-02
METHY-07
3-MET-02
TERT--01
ETHYLENE
CYCLO-01
PROPYLEN
ISOBUTAN
N-BUTANE
CIS-2-01
2-MET-02
1:2-B-01
1:3-B-01
0.2910624E-04
0.3979346E-16
0.1438500E-04
0.1771165E-04
0.4235348E-04
0.9623707E-03
0.6168212E-03
0.2791097E-06
0.1808873E-02
0.6168212E-03
0.1808873E-02
0.1058155E-03
0.2708356E-05
0.5444425E-01
0.1654046E-04
0.1296382
0.7807622E-01
0.1087778
0.2571841E-01
0.2670067E-01
0.3121407E-05
0.3633071E-02
LBMOL/HR
VAPOR
LIQUID
2-PHASE
VAPOR
LIQUID
2-PHASE
VAPOR
COLD
COLD
COLD
COLD
COLD
COLD
COLD
LIQUID
2-PHASE
2-PHASE
2-PHASE
VAPOR
VAPOR
VAPOR
***
BTU/HR-SQFT-R
BTU/HR-SQFT-R
BTU/HR-SQFT-R
BTU/HR-SQFT-R
BTU/HR-SQFT-R
BTU/HR-SQFT-R
BTU/HR-SQFT-R
OVERALL RESULTS
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
***
STREAMS:
84
T=
P=
V=
13
T=
P=
V=
-------------------------------------|
|
----->|
HOT
|----->
1.9289D+02 |
|
3.7500D+02 |
|
1.0000D+00 |
|
|
|
<-----|
COLD
|<----1.4236D+02 |
|
3.7000D+01 |
|
0.0000D+00 |
|
--------------------------------------
83
T=
P=
V=
1.0000D+02
3.7200D+02
0.0000D+00
10
T=
P=
V=
9.0000D+01
4.0000D+01
0.0000D+00
1530.460
BLOCK: B2
MODEL: HEATX
----------------------------HOT SIDE:
84
OUTLET STREAM:
83
NRTL
COLD SIDE:
10
OUTLET STREAM:
13
NRTL
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
HOT
HOT
HOT
HOT
HOT
HOT
HOT
DUTY AND AREA:

7492.75
155000.
-0.807813E+09
***
INPUT DATA
RELATIVE DIFF.
7492.75
155000.
-0.807813E+09
0.00000
0.00000
0.00000
***

TWO
PHASE
FLASH
PRESSURE DROP:
HOTSIDE, TOTAL
COLDSIDE, TOTAL
30
0.000100000
30
0.000100000

COUNTERCURRENT
HEAT EXCHANGER
SPECIFIED HOT OUTLET TEMP
SPECIFIED VALUE
F
PSI
PSI

HOT LIQUID
COLD LIQUID
BTU/HR-SQFT-R
HOT 2-PHASE
COLD LIQUID
BTU/HR-SQFT-R
BTU/HR-SQFT-R
BTU/HR-R
100.0000
1.00000
3.0000
3.0000
3.0000
3.0000

HOT SIDE:
COLD SIDE:
71465.
87980.
ZONE RESULTS
***

HOT
------------------------------------------------------------|
|
|
|
84
|
VAP
|
COND
|
LIQ
| 83
------> |
|
|
|------>
192.9 |
141.6|
141.1|
| 100.0
|
|
|
|
13
|
LIQ
|
LIQ
|
LIQ
| 10
<------ |
|
|
|<-----142.4 |
136.0|
103.3|
|
90.0
|
|
|
|
------------------------------------------------------------COLD
ZONE
149.6937
149.6937
149.6937
331718.8159
1.0000
18.0527
1
PSI
PSI
***

TWO
PHASE
FLASH
***
OUT
5988421.6662
2215.9845
2215.9845
0.0000

LMTD (CORRECTED)
F

IN

UA (DIRTY)
BTU/HR
SQFT
SQFT
HEAT DUTY
BTU/HR
740950.804
AREA
SQFT
243.5268
LMTD
F
20.3254
AVERAGE U
BTU/HR-SQFT-R
149.6937
UA
BTU/HR-R
36454.4233
2
3
3757095.762
1490375.100
1496.1982
476.2594
BLOCK: B3
MODEL: HEATER
-----------------------------INLET STREAM:
69
OUTLET STREAM:
73
NRTL
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
16.7749
20.9049
4429.17
79792.7
-0.437112E+09
***
223971.3824
71293.0103

IN
149.6937
149.6937
INPUT DATA
TWO
PHASE TP FLASH
PRESSURE DROP
***
OUT
4429.17
79792.7
-0.437112E+09
235.0000
1.00000
PSI
PSI
3.0000
3.0000
RELATIVE DIFF.
0.00000
0.00000
0.00000
***
F
PSI

COUNTERCURRENT
HEAT EXCHANGER
SPECIFIED VALUE
F
707.000
5.00000
30
0.000100000

HOT LIQUID
COLD LIQUID
BTU/HR-SQFT-R
HOT 2-PHASE
COLD LIQUID
BTU/HR-SQFT-R
HOT VAPOR
COLD LIQUID
BTU/HR-SQFT-R
HOT LIQUID
COLD 2-PHASE
BTU/HR-SQFT-R
HOT 2-PHASE
COLD 2-PHASE
BTU/HR-SQFT-R
HOT VAPOR
COLD 2-PHASE
BTU/HR-SQFT-R
HOT LIQUID
COLD VAPOR
BTU/HR-SQFT-R
HOT 2-PHASE
COLD VAPOR
BTU/HR-SQFT-R
HOT VAPOR
COLD VAPOR
BTU/HR-SQFT-R
***
OVERALL RESULTS
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
***
STREAMS:
*** RESULTS
OUTLET TEMPERATURE
F
OUTLET PRESSURE
PSIA
HEAT DUTY
BTU/HR
***
707.00
455.00
0.0000
1.0000
3596.4
47
T=
P=
V=
35
T=
P=
V=

COMP
WATER
F(I)
1.0000
BLOCK: B4
MODEL: HEATX
----------------------------HOT SIDE:
47
OUTLET STREAM:
49
NRTL
COLD SIDE:
29
OUTLET STREAM:
35
NRTL
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
X(I)
1.0000
Y(I)
1.0000
DUTY AND AREA:


TWO
PHASE
FLASH
TWO
PHASE
FLASH
INPUT DATA
BTU/HR
SQFT
SQFT
***
OUT
RELATIVE DIFF.
12828.5
339121.
-0.106580E+10
0.00000
0.00000
0.335548E-15
***
PRESSURE DROP:
HOTSIDE, TOTAL
COLDSIDE, TOTAL
BTU/HR-SQFT-R
BTU/HR-R
30
0.000100000
2.3500D+02
2.2000D+01
1.0000D+00
29
T=
P=
V=
2.2000D+02
2.0000D+01
0.0000D+00
149.6937
235670.5063
1.0000
21.9724
1
PSI
PSI
3.0000
3.0000

HOT SIDE:
COLD SIDE:
***
30
0.000100000
49
T=
P=
V=
5178242.6004
1574.3520
1574.3520
0.0000

LMTD (CORRECTED)
F
12828.5
339121.
-0.106580E+10
***

UA (DIRTY)

IN
K(I)
7.0755
-------------------------------------|
|
----->|
HOT
|----->
2.6888D+02 |
|
2.5000D+01 |
|
1.0000D+00 |
|
|
|
<-----|
COLD
|<----2.1948D+02 |
|
1.7000D+01 |
|
6.6837D-01 |
|
--------------------------------------
15.622
40945.
ZONE RESULTS
***

HOT
------------------------------------------------------------|
|
|
47
|
VAP
|
VAP
| 49
------> |
|
|------>
268.9
|
235.5|
| 235.0
|
|
|
35
|
BOIL
|
LIQ
| 29
<------ |
|
|<-----219.5 |
227.9|
| 220.0
|
|
|
------------------------------------------------------------COLD
ZONE
1
2
HEAT DUTY
BTU/HR
5109435.695
68806.906
AREA
SQFT
1531.9964
42.3556
BLOCK: B5
MODEL: HEATX
----------------------------HOT SIDE:
49
OUTLET STREAM:
S-601
NRTL
COLD SIDE:
43
OUTLET STREAM:
45
NRTL
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
LMTD
F
22.2798
10.8522
INPUT DATA
RELATIVE DIFF.
289927.
0.533112E+07
-0.350449E+11
0.00000
0.00000
0.00000
***
PRESSURE DROP:
HOTSIDE, TOTAL
COLDSIDE, TOTAL
30
0.000100000

COUNTERCURRENT
HEAT EXCHANGER
SPECIFIED VALUE
F
140.0000
1.00000
PSI
PSI
3.0000
3.0000

HOT LIQUID
COLD LIQUID
BTU/HR-SQFT-R
HOT 2-PHASE
COLD LIQUID
BTU/HR-SQFT-R
HOT VAPOR
COLD LIQUID
BTU/HR-SQFT-R
HOT LIQUID
COLD 2-PHASE
BTU/HR-SQFT-R
HOT 2-PHASE
COLD 2-PHASE
BTU/HR-SQFT-R
HOT VAPOR
COLD 2-PHASE
BTU/HR-SQFT-R
HOT LIQUID
COLD VAPOR
BTU/HR-SQFT-R
HOT 2-PHASE
COLD VAPOR
BTU/HR-SQFT-R
HOT VAPOR
COLD VAPOR
BTU/HR-SQFT-R
OVERALL RESULTS
***
BTU/HR-SQFT-R
BTU/HR-R
43
T=
P=
V=
9.0000D+01
4.0000D+01
0.0000D+00
149.6937
2659669.1703
1.0000
68.4608
1
3.0000
3.0000

HOT SIDE:
COLD SIDE:
24.608
50.882
ZONE RESULTS
***

HOT
------------------------------------------------------------|
|
|
49
|
VAP
|
COND
| S-601
------> |
|
|------>
235.0 |
218.3|
| 140.0
|
|
|
45
|
LIQ
|
LIQ
| 43
<------ |
|
|<-----128.5 |
128.0|
|
90.0
|
|
|
------------------------------------------------------------COLD
ZONE
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
S-601
T= 1.4000D+02
P= 1.9000D+01
V= 2.1991D-01
182083015.8416
17767.4140
17767.4140
0.0000
PSI
PSI
***
30
0.000100000

TWO
PHASE
FLASH
***
***
OUT
BTU/HR
SQFT
SQFT

LMTD (CORRECTED)
F

TWO
PHASE
FLASH
45
T=
P=
V=
-------------------------------------|
|
----->|
HOT
|----->
2.3500D+02 |
|
2.2000D+01 |
|
1.0000D+00 |
|
|
|
<-----|
COLD
|<----1.2850D+02 |
|
3.7000D+01 |
|
0.0000D+00 |
|
--------------------------------------

UA (DIRTY)
289927.
0.533112E+07
-0.350449E+11
***
49
T=
P=
V=
DUTY AND AREA:


IN
AVERAGE U
UA
BTU/HR-SQFT-R
BTU/HR-R
149.6937
229330.1450
149.6937
6340.3614
STREAMS:
1
2
HEAT DUTY
BTU/HR
2515336.871
179567678.970
AREA
SQFT
171.1654
17596.2487
BLOCK: B6
MODEL: COMPR
----------------------------INLET STREAM:
S-604
OUTLET STREAM:
7
NRTL
***
LMTD
F
98.1696
68.1718
AVERAGE U
UA
BTU/HR-SQFT-R
BTU/HR-R
149.6937
25622.3734
149.6937
2634046.7969
***
IN
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
OUT
3384.42
166636.
-0.103740E+09
)
***
INPUT DATA
RELATIVE DIFF.
3384.42
166636.
-0.982008E+08
***

***
65.0000
0.72000
1.00000
RESULTS
***

BRAKE
NET WORK REQUIRED
HP
POWER LOSSES
HP
HEAD DEVELOPED,
FT-LBF/LB
***
2,177.01
2,177.01
2,177.01
0.0
1,567.45
210.647
189.699
0.72000
1.00000
18,624.7
1.00000
1.10956
861,354.
374,548.
1.00000
1.00000
1.10523
1.10523
1.14737
1.14737
1831.74
63053.8
0.251075E+08
***
INPUT DATA

TWO
PHASE
FLASH
TWO
PHASE
FLASH
COUNTERCURRENT
HEAT EXCHANGER
1831.74
63053.8
0.251075E+08
3.0000
3.0000

HOT LIQUID
COLD LIQUID
BTU/HR-SQFT-R
HOT 2-PHASE
COLD LIQUID
BTU/HR-SQFT-R
HOT VAPOR
COLD LIQUID
BTU/HR-SQFT-R
HOT LIQUID
COLD 2-PHASE
BTU/HR-SQFT-R
HOT 2-PHASE
COLD 2-PHASE
BTU/HR-SQFT-R
HOT VAPOR
COLD 2-PHASE
BTU/HR-SQFT-R
HOT LIQUID
COLD VAPOR
BTU/HR-SQFT-R
HOT 2-PHASE
COLD VAPOR
BTU/HR-SQFT-R
HOT VAPOR
COLD VAPOR
BTU/HR-SQFT-R
***
OVERALL RESULTS
RELATIVE DIFF.
0.00000
0.00000
0.00000
***
16
T=
P=
V=
30
0.000100000
***
81
T=
P=
V=
-------------------------------------|
|
----->|
HOT
|----->
4.5000D+01 |
|
6.5000D+02 |
|
1.0000D+00 |
|
|
|
<-----|
COLD
|<-----6.0471D-01 |
|
4.8000D+01 |
|
1.0000D+00 |
|
--------------------------------------
PRESSURE DROP:
HOTSIDE, TOTAL
COLDSIDE, TOTAL
BTU/HR
SQFT
SQFT
36
T=
P=
V=
1.1608D+01
6.4700D+02
0.0000D+00
80
T=
P=
V=
2.5530D+00
5.1000D+01
4.3278D-01
3434865.9273
827.6252
827.6252
0.0000
BTU/HR-SQFT-R
BTU/HR-R
149.6937
123890.2468
1.0000
27.7251
1
PSI
PSI
3.0000
3.0000

HOT SIDE:
COLD SIDE:
***
30
0.000100000
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
STREAMS:

LMTD (CORRECTED)
F

***
OUT
1.0000
1.00000
PSI
PSI

UA (DIRTY)

IN
DUTY AND AREA:

BLOCK: B7
MODEL: HEATX
----------------------------HOT SIDE:
16
OUTLET STREAM:
36
NRTL
COLD SIDE:
80
OUTLET STREAM:
81
NRTL
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
0.00000
0.00000
-0.533955E-01
SPECIFIED COLD VAPOR FRACTION

SPECIFIED VALUE
0.15689E+06
9861.9
ZONE RESULTS
***

HOT
------------------------------------------------------------|
|
|
|
16
|
VAP
|
COND
|
LIQ
| 36
------> |
|
|
|------>
45.0 |
39.1|
38.9|
|
11.6
|
|
|
|
81
|
BOIL
|
BOIL
|
BOIL
| 80
<------ |
|
|
|<------0.6 |
-0.6|
1.2|
|
2.6
|
|
|
|
------------------------------------------------------------COLD
ZONE
HEAT DUTY
BTU/HR
58224.163
1911785.126
1464856.639
1
2
3
AREA
SQFT
9.1426
330.6929
487.7897
BLOCK: B8
MODEL: RADFRAC
------------------------------INLETS
- S-603
STAGE
2
OUTLETS - S-604
STAGE
1
S-605
STAGE
7
NRTL
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
LMTD
F
42.5431
38.6199
20.0613
UA
BTU/HR-R
1368.5925
49502.6248
73019.0295

IN
12384.4
331121.
-0.119424E+10
AVERAGE U
BTU/HR-SQFT-R
149.6937
149.6937
149.6937
***
OUT
RELATIVE DIFF.
12384.4
331121.
-0.117787E+10
-0.587509E-15
0.359665E-12
-0.137049E-01
**********************
**********************
****
INPUT PARAMETERS
****
NUMBER OF STAGES
ALGORITHM OPTION
ABSORBER OPTION
FLASH TOLERANCE
****
COL-SPECS
****

MOLAR REFLUX RATIO
MOLAR BOTTOMS RATE
****
PROFILES
P-SPEC
7
STANDARD
NO
STANDARD
NO
BROYDEN
NESTED
25
10
30
0.000100000
0.000100000
LBMOL/HR
1.00000
0.60000
9,000.00
****
STAGE
CO2
WATER
METHANOL
DME
METHY-01
METHY-02
N-PRO-01
METHA-01
N-BUT-01
METHY-03
3-MET-01
VALER-01
ETHANOL
CIS-C-01
METHY-05
DIETH-01
2-MET-01
METHY-06
DIETH-02
METHY-07
3-MET-02
TERT--01
METHANE
ETHYLENE
CYCLO-01
PROPYLEN
ISOBUTAN
N-BUTANE
TRANS-BU
1-BUTENE
ISOBUTEN
CIS-2-01
2-MET-02
1:2-B-01
1:3-B-01
N-PENTAN
N-HEXANE
N-HEPTAN
BENZENE
NITRO-01
***
PRES, PSIA
*******************
**** RESULTS ****
*******************
25.0000
S-604
COMPONENT:
***
F
F
LBMOL/HR
LBMOL/HR
LBMOL/HR
LBMOL/HR
PROFILES
133.229
248.138
2,030.65
9,000.00
3,384.42
3,197.70
0.60000
0.35530
-0.384368+08
0.548032+08
BTU/HR
BTU/HR
DEW POINT
BUBBLE POINT
ENERGY BALANCE
****
***
.70824E-11
.96993
.22559E-01
.72264E-05
.14418E-02
0.0000
.59428E-08
.76769
.63067E-06
.21739E-06
.94717
.21691E-07
.22572E-02
.93317
.32112E-09
.14078E-07
.92897E-03
.10156E-07
.14078E-07
.10156E-07
.95355E-11
.56990E-06
.47727E-14
.20884E-10
.39716E-05
.31849E-06
.19316E-03
.99068E-03
.97951E-03
.34446E-03
.33218E-03
.14943E-02
0.0000
.44647E-02
.44260E-03
0.0000
0.0000
0.0000
.88561
0.0000

BOILUP VAPOR FLOW
MOLAR REFLUX RATIO
MOLAR BOILUP RATIO
REBOILER DUTY
****
1.0000
.30067E-01
.97744
.99999
.99856
1.0000
1.0000
.23231
1.0000
1.0000
.52829E-01
1.0000
.99774
.66831E-01
1.0000
1.0000
.99907
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
1.0000
.99981
.99901
.99902
.99966
.99967
.99851
1.0000
.99554
.99956
1.0000
1.0000
1.0000
.11439
1.0000
****
0.22033E-03
0.84014E-04
0.40590E-06
0.29179E-04
STAGE=
STAGE=
STAGE=
STAGE=
1
1
4 COMP=METHY-07
1
****
***
OUTLET STREAMS
-------------S-605
STAGE TEMPERATURE
PRESSURE
ENTHALPY
BTU/LBMOL
HEAT DUTY
1
2
3
5
6
7
PSIA
LIQUID
133.23
215.91
236.74
245.72
247.10
248.14
25.000
27.000
27.400
28.200
28.600
29.000
-0.10901E+06 -30652.
-0.11694E+06 -72472.
-0.11847E+06 -92043.
-0.11917E+06 -0.10075E+06
-0.11926E+06 -0.10150E+06
-0.11935E+06 -0.10188E+06
STAGE
1
2
3
5
6
7
FLOW RATE
LBMOL/HR
LIQUID
VAPOR
2031.
3384.
0.1207E+05 2700.
0.1216E+05 3072.
0.1219E+05 3179.
0.1220E+05 3189.
9000.
3198.
****
LIQUID
FEED RATE
LBMOL/HR
VAPOR
2715.2015
MIXED
BTU/HR
-.38437+08
.54803+08
PRODUCT RATE
LBMOL/HR
LIQUID
VAPOR
3384.4209
9669.2194
9000.0000
MASS FLOW PROFILES
FLOW RATE
LB/HR
LIQUID
VAPOR
0.5136E+05 0.1666E+06
0.2394E+06 0.9410E+05
0.2295E+06 0.7487E+05
0.2246E+06 0.6138E+05
0.2239E+06 0.6008E+05
0.1645E+06 0.5938E+05
****
STAGE
1
2
3
5
6
7
VAPOR
LIQUID
FEED RATE
LB/HR
VAPOR
.12390+06
MIXED
PRODUCT RATE
LB/HR
LIQUID
VAPOR
.16664+06
.20722+06
.16449+06
STAGE
1
2
3
5
6
7
CO2
0.52986E-04
0.15105E-05
0.35947E-07
0.18055E-10
0.40318E-12
0.88979E-14
****
MOLE-X-PROFILE
****
WATER
METHANOL
DME
0.82271
0.41521E-04
0.28930E-09
0.95594
0.12964E-04
0.48989E-10
0.98065
0.74730E-05
0.86499E-11
0.99197
0.17992E-05
0.23076E-12
0.99352
0.78987E-06
0.36781E-13
0.99506
0.28582E-06
0.53368E-14
STAGE
1
2
3
5
6
7
METHY-02
0.46379E-10
0.13495E-12
0.40053E-15
0.21809E-20
0.47809E-23
0.10228E-25
****
MOLE-X-PROFILE
****
N-PRO-01
METHA-01
N-BUT-01
0.84361E-03
0.94673E-02
0.33682E-03
0.39760E-04
0.61316E-02
0.26396E-04
0.23070E-05
0.63482E-02
0.29401E-05
0.59954E-08
0.59078E-02
0.26395E-07
0.29766E-09
0.52687E-02
0.24016E-08
0.14193E-10
0.40981E-02
0.20374E-09
METHY-03
0.98930E-04
0.63082E-05
0.61803E-06
0.50010E-08
0.44315E-09
0.37064E-10
STAGE
1
2
3
5
6
7
3-MET-01
0.65906E-04
0.63888E-04
0.65558E-04
0.65946E-04
0.65295E-04
0.62995E-04
****
MOLE-X-PROFILE
****
VALER-01
ETHANOL
CIS-C-01
0.17715E-04
0.78140E-04
0.17971E-03
0.89650E-06
0.16389E-04
0.16171E-03
0.60925E-07
0.62597E-05
0.16640E-03
0.20958E-09
0.63238E-06
0.16677E-03
0.11896E-10
0.18457E-06
0.16351E-03
0.64411E-12
0.45926E-07
0.15329E-03
METHY-05
0.23100E-02
0.68095E-04
0.23516E-05
0.16261E-08
0.39730E-10
0.92730E-12
STAGE
1
2
3
5
6
7
DIETH-01
0.15998E-02
0.72695E-04
0.44825E-05
0.11230E-07
0.53370E-09
0.24095E-10
****
MOLE-X-PROFILE
****
2-MET-01
METHY-06
DIETH-02
0.13759E-05
0.61982E-02
0.15998E-02
0.22940E-06
0.28636E-03
0.72695E-04
0.74655E-07
0.16668E-04
0.44825E-05
0.56029E-08
0.32738E-07
0.11230E-07
0.14279E-08
0.13472E-08
0.53370E-09
0.31451E-09
0.52329E-10
0.24095E-10
METHY-07
0.61982E-02
0.28636E-03
0.16668E-04
0.32738E-07
0.13472E-08
0.52329E-10
STAGE
1
3-MET-02
0.32656E-03
****
MOLE-X-PROFILE
****
TERT--01
METHANE
ETHYLENE
0.89991E-05
0.10165E-04
0.16781E-02
CYCLO-01
0.36893E-05
METHY-01
0.12293E-08
0.35894E-09
0.14150E-09
0.18139E-10
0.60747E-11
0.17307E-11
2
3
5
6
7
0.56412E-05
0.10956E-06
0.19843E-10
0.24053E-12
0.27665E-14
0.64328E-06
0.65699E-07
0.41026E-09
0.30174E-10
0.20630E-11
0.56956E-04
0.16043E-05
0.11494E-08
0.30744E-10
0.81121E-12
0.59203E-06
0.96050E-07
0.21794E-08
0.32138E-09
0.43412E-10
STAGE
1
2
3
5
6
7
PROPYLEN
0.24517E-01
0.29108E-02
0.32535E-03
0.35396E-05
0.36440E-06
0.35207E-07
****
MOLE-X-PROFILE
****
ISOBUTAN
N-BUTANE
TRANS-BU
0.33511E-01
0.58076E-01
0.13355E-02
0.82549E-02
0.16778E-01
0.38244E-03
0.24021E-02
0.62737E-02
0.14245E-03
0.17229E-03
0.73068E-03
0.16386E-04
0.44113E-04
0.23436E-03
0.52214E-05
0.98670E-05
0.64237E-04
0.14224E-05
1-BUTENE
0.13185E-02
0.34266E-03
0.10890E-03
0.92764E-05
0.25745E-05
0.61938E-06
STAGE
1
2
3
5
6
7
ISOBUTEN
0.46485E-02
0.12041E-02
0.38013E-03
0.31837E-04
0.87601E-05
0.20907E-05
****
MOLE-X-PROFILE
****
CIS-2-01
2-MET-02
1:2-B-01
0.18797E-01
0.16437E-03
0.26974E-05
0.56104E-02
0.48229E-08
0.89194E-06
0.22325E-02
0.10019E-12
0.42147E-06
0.29211E-03
0.96412E-23
0.76719E-07
0.98787E-04
0.74731E-28
0.30166E-07
0.28398E-04
0.51552E-33
0.99417E-08
1:3-B-01
0.25042E-02
0.66622E-03
0.21970E-03
0.20031E-04
0.57343E-05
0.14184E-05
STAGE
1
2
3
5
6
7
N-PENTAN
0.57111E-04
0.27954E-08
0.90194E-13
0.17928E-22
0.19549E-27
0.18922E-32
****
MOLE-X-PROFILE
****
N-HEXANE
N-HEPTAN
BENZENE
0.15416E-04
0.45934E-03
0.76108E-03
0.32784E-08
0.58997E-07
0.59604E-03
0.93292E-12
0.38385E-11
0.61520E-03
0.36544E-19
0.21862E-20
0.60780E-03
0.65592E-23
0.37696E-25
0.58143E-03
0.11240E-26
0.55087E-30
0.51394E-03
NITRO-01
0.90876E-08
0.49656E-10
0.21194E-12
0.36887E-17
0.15532E-19
0.65804E-22
STAGE
1
2
3
5
6
7
CO2
0.33409E-02
0.21281E-03
0.59356E-05
0.31009E-08
0.68977E-10
0.15129E-11
****
MOLE-Y-PROFILE
****
WATER
METHANOL
DME
0.82028E-01
0.32932E-04
0.19639E-08
0.56183
0.60309E-04
0.89064E-09
0.84134
0.50103E-04
0.19249E-09
0.97169
0.13686E-04
0.54439E-11
0.98325
0.60698E-05
0.86689E-12
0.98918
0.22085E-05
0.12528E-12
METHY-01
0.31875E-08
0.28524E-08
0.14054E-08
0.19240E-09
0.64440E-10
0.18301E-10
STAGE
1
2
3
5
6
7
METHY-02
0.21603E-08
0.96696E-10
0.53029E-12
0.37022E-17
0.83349E-20
0.18208E-22
****
MOLE-Y-PROFILE
****
N-PRO-01
METHA-01
N-BUT-01
0.63509E-02
0.32979E-02
0.85906E-03
0.19138E-02
0.88040E-02
0.60887E-03
0.15623E-03
0.12089E-01
0.10372E-03
0.45749E-06
0.12305E-01
0.10888E-05
0.22873E-07
0.11015E-01
0.10030E-06
0.10955E-08
0.85631E-02
0.85875E-08
METHY-03
0.45339E-03
0.19904E-03
0.24788E-04
0.21466E-06
0.19008E-07
0.15861E-08
STAGE
1
2
3
5
6
7
3-MET-01
0.93434E-05
0.46699E-04
0.66503E-04
0.74531E-04
0.74273E-04
0.71769E-04
****
MOLE-Y-PROFILE
****
VALER-01
ETHANOL
CIS-C-01
0.78967E-04
0.53984E-04
0.29194E-04
0.34960E-04
0.10532E-03
0.13130E-03
0.35228E-05
0.64264E-04
0.18638E-03
0.13939E-07
0.77139E-05
0.20761E-03
0.79918E-09
0.22873E-05
0.20480E-03
0.43565E-10
0.57479E-06
0.19225E-03
METHY-05
0.76792E-02
0.39528E-02
0.26758E-03
0.24623E-06
0.62121E-08
0.14894E-09
STAGE
1
2
3
5
6
7
DIETH-01
0.45515E-02
0.27254E-02
0.28565E-03
0.88370E-06
0.42850E-07
0.19680E-08
****
MOLE-Y-PROFILE
****
2-MET-01
METHY-06
DIETH-02
0.89948E-06
0.13702E-01
0.45515E-02
0.17599E-05
0.10015E-01
0.27254E-02
0.90051E-06
0.11253E-02
0.28565E-03
0.79463E-07
0.29414E-05
0.88370E-06
0.20526E-07
0.12497E-06
0.42850E-07
0.45617E-08
0.49915E-08
0.19680E-08
METHY-07
0.13702E-01
0.10015E-01
0.11253E-02
0.29414E-05
0.12497E-06
0.49915E-08
****
0.11114E-06
0.96425E-09
0.67932E-13
0.57352E-15
0.48499E-17
MOLE-Y-PROFILE
****
STAGE
1
2
3
5
6
7
3-MET-02
0.77153E-03
0.46979E-03
0.22167E-04
0.59611E-08
0.75829E-10
0.90972E-12
TERT--01
0.96265E-05
0.12828E-04
0.25277E-05
0.20618E-07
0.15621E-08
0.10929E-09
METHANE
0.27023E-02
0.46340E-04
0.43673E-06
0.31017E-10
0.25961E-12
0.21740E-14
ETHYLENE
0.10329
0.69551E-02
0.22381E-03
0.16504E-06
0.43905E-08
0.11499E-09
CYCLO-01
0.29067E-04
0.11832E-04
0.23262E-05
0.55739E-07
0.82068E-08
0.11037E-08
STAGE
1
2
3
5
6
7
PROPYLEN
0.29397
0.85204E-01
0.11438E-01
0.13075E-03
0.13429E-04
0.12909E-05
****
MOLE-Y-PROFILE
****
ISOBUTAN
N-BUTANE
TRANS-BU
0.13581
0.17226
0.38579E-02
0.90820E-01
0.14217
0.32327E-02
0.32409E-01
0.65740E-01
0.14986E-02
0.24652E-02
0.81451E-02
0.18393E-03
0.63061E-03
0.26113E-02
0.58609E-04
0.14050E-03
0.71316E-03
0.15914E-04
1-BUTENE
0.47799E-02
0.34450E-02
0.13447E-02
0.12155E-03
0.33705E-04
0.80773E-05
STAGE
1
2
3
5
6
7
ISOBUTEN
0.16731E-01
0.12122E-01
0.47254E-02
0.42095E-03
0.11578E-03
0.27531E-04
****
MOLE-Y-PROFILE
****
CIS-2-01
2-MET-02
1:2-B-01
0.50461E-01
0.45433E-01
0.58950E-05
0.44368E-01
0.18693E-03
0.59065E-05
0.21963E-01
0.18951E-07
0.34757E-05
0.30645E-02
0.42342E-17
0.67448E-06
0.10363E-02
0.36847E-22
0.26516E-06
0.29690E-03
0.28506E-27
0.87088E-07
1:3-B-01
0.85181E-02
0.64117E-02
0.26138E-02
0.25354E-03
0.72552E-04
0.17882E-04
STAGE
1
2
3
5
6
7
N-PENTAN
0.85756E-02
0.63244E-04
0.10984E-07
0.55498E-17
0.68518E-22
0.74569E-27
****
MOLE-Y-PROFILE
****
N-HEXANE
N-HEPTAN
BENZENE
0.12730E-02
0.10619E-01
0.17653E-03
0.18418E-04
0.46965E-03
0.60413E-03
0.12882E-07
0.23183E-06
0.83656E-03
0.74457E-15
0.41203E-15
0.90826E-03
0.13967E-18
0.83553E-20
0.87267E-03
0.25017E-22
0.14379E-24
0.77139E-03
NITRO-01
0.57800E-05
0.43313E-07
0.19512E-09
0.33829E-14
0.14097E-16
0.59063E-19
CO2
63.045
140.87
165.11
171.75
171.08
170.03
****
K-VALUES
WATER
METHANOL
0.99731E-01
0.79350
0.58773
4.6522
0.85794
6.7045
0.97955
7.6064
0.98967
7.6845
0.99408
7.7270
****
STAGE
1
2
3
5
6
7
METHY-02
46.579
716.48
1323.9
1697.6
1743.4
1780.2
****
K-VALUES
N-PRO-01
METHA-01
7.5266
0.34842
48.128
1.4358
67.715
1.9042
76.306
2.0829
76.843
2.0906
77.185
2.0895
****
STAGE
1
2
3
5
6
7
3-MET-01
0.14182
0.73095
1.0144
1.1302
1.1375
1.1393
****
K-VALUES
VALER-01
ETHANOL
4.4571
0.69107
38.992
6.4262
57.817
10.266
66.508
12.198
67.180
12.392
67.635
12.515
****
STAGE
1
2
3
5
6
7
DIETH-01
2.8447
37.485
63.720
78.692
80.287
81.675
****
K-VALUES
2-MET-01
METHY-06
0.65387
2.2102
7.6711
34.967
12.062
67.503
14.182
89.846
14.374
92.765
14.504
95.386
****
STAGE
1
2
3
5
6
7
DME
6.7882
18.179
22.252
23.591
23.569
23.475
N-BUT-01
2.5503
23.064
35.276
41.252
41.764
42.150
CIS-C-01
0.16250
0.81191
1.1200
1.2449
1.2525
1.2542
DIETH-02
2.8447
37.485
63.720
78.692
80.287
81.675
METHY-01
2.5931
7.9462
9.9315
10.607
10.608
10.574
METHY-03
4.5845
31.549
40.105
42.923
42.893
42.793
METHY-05
3.3241
58.043
113.78
151.42
156.35
160.62
METHY-07
2.2102
34.967
67.503
89.846
92.765
95.386
3-MET-02
2.3624
83.270
202.31
300.41
315.25
328.83
****
K-VALUES
TERT--01
METHANE
1.0701
265.75
19.941
416.88
38.474
452.89
50.257
456.58
51.770
452.67
52.977
448.27
****
STAGE
1
2
3
5
6
7
PROPYLEN
11.989
29.269
35.154
36.938
36.852
36.666
****
K-VALUES
ISOBUTAN
N-BUTANE
4.0526
2.9661
11.001
8.4733
13.491
10.478
14.308
11.147
14.296
11.142
14.239
11.102
****
STAGE
1
2
3
5
6
7
TRANS-BU
2.8888
8.4522
10.520
11.225
11.225
11.188
1-BUTENE
3.6253
10.053
12.348
13.103
13.092
13.041
STAGE
1
2
3
5
6
7
ISOBUTEN
3.5993
10.067
12.430
13.222
13.216
13.169
****
K-VALUES
****
CIS-2-01
2-MET-02
1:2-B-01
2.6846
276.18
2.1855
7.9076
38743.
6.6217
9.8373
0.18910E+06
8.2464
10.491
0.43914E+06
8.7915
10.490
0.49303E+06
8.7899
10.455
0.55294E+06
8.7599
1:3-B-01
3.4016
9.6232
11.897
12.657
12.652
12.607
STAGE
1
2
3
5
6
7
N-PENTAN
150.03
22614.
0.12174E+06
0.30953E+06
0.35048E+06
0.39406E+06
****
K-VALUES
****
N-HEXANE
N-HEPTAN
BENZENE
82.526
23.099
0.23200
5616.1
7956.5
1.0135
13806.
60370.
1.3598
20373.
0.18844E+06
1.4943
21293.
0.22163E+06
1.5009
22256.
0.26101E+06
1.5009
NITRO-01
635.80
872.12
920.56
917.10
907.60
897.57
STAGE
1
2
3
5
6
7
CO2
0.92193E-04
0.33528E-05
0.83828E-07
0.43130E-10
0.96678E-12
0.21427E-13
****
MASS-X-PROFILE
****
WATER
METHANOL
DME
0.58597
0.52599E-04
0.52692E-09
0.86858
0.20950E-04
0.11383E-09
0.93611
0.12688E-04
0.21115E-10
0.97002
0.31293E-05
0.57705E-12
0.97522
0.13790E-05
0.92325E-13
0.98086
0.50111E-06
0.13453E-13
METHY-01
0.29208E-08
0.10879E-08
0.45058E-09
0.59169E-10
0.19891E-10
0.56911E-11
STAGE
1
2
3
5
6
7
METHY-02
0.13591E-09
0.50451E-12
0.15731E-14
0.87744E-20
0.19308E-22
0.41481E-25
****
MASS-X-PROFILE
****
N-PRO-01
METHA-01
N-BUT-01
0.19371E-02
0.26235E-01
0.96019E-03
0.11647E-03
0.21676E-01
0.95997E-04
0.70999E-05
0.23577E-01
0.11233E-04
0.18901E-07
0.22477E-01
0.10331E-06
0.94196E-09
0.20121E-01
0.94354E-08
0.45104E-10
0.15717E-01
0.80383E-09
METHY-03
0.28974E-03
0.23569E-04
0.24259E-05
0.20109E-07
0.17887E-08
0.15023E-09
STAGE
1
2
3
5
6
7
3-MET-01
0.22443E-03
0.27754E-03
0.29921E-03
0.30832E-03
0.30644E-03
0.29689E-03
****
MASS-X-PROFILE
****
VALER-01
ETHANOL
CIS-C-01
0.60325E-04
0.14232E-03
0.49799E-03
0.38946E-05
0.38079E-04
0.57167E-03
0.27806E-06
0.15280E-04
0.61801E-03
0.97987E-09
0.15813E-05
0.63448E-03
0.55829E-10
0.46329E-06
0.62443E-03
0.30357E-11
0.11577E-06
0.58790E-03
METHY-05
0.78665E-02
0.29582E-03
0.10733E-04
0.76025E-08
0.18646E-09
0.43703E-11
STAGE
1
2
3
5
DIETH-01
0.54478E-02
0.31580E-03
0.20458E-04
0.52502E-07
****
MASS-X-PROFILE
****
2-MET-01
METHY-06
DIETH-02
0.47951E-05
0.21107E-01
0.54478E-02
0.10199E-05
0.12440E-02
0.31580E-03
0.34870E-06
0.76074E-04
0.20458E-04
0.26808E-07
0.15306E-06
0.52502E-07
METHY-07
0.21107E-01
0.12440E-02
0.76074E-04
0.15306E-06
ETHYLENE
61.545
122.10
139.50
143.59
142.81
141.75
CYCLO-01
7.8782
19.984
24.218
25.575
25.536
25.424
6
7
0.25047E-08
0.11356E-09
0.68582E-08
0.15170E-08
0.63224E-08
0.24662E-09
0.25047E-08
0.11356E-09
0.63224E-08
0.24662E-09
STAGE
1
2
3
5
6
7
3-MET-02
0.12932E-02
0.28497E-04
0.58146E-06
0.10788E-09
0.13127E-11
0.15162E-13
****
MASS-X-PROFILE
****
TERT--01
METHANE
ETHYLENE
0.26372E-04
0.64475E-05
0.18612E-02
0.24048E-05
0.89929E-07
0.80588E-04
0.25804E-06
0.81967E-09
0.23847E-05
0.16506E-08
0.59155E-13
0.17502E-08
0.12186E-09
0.50131E-15
0.46994E-10
0.83671E-11
0.42572E-17
0.12452E-11
CYCLO-01
0.61379E-05
0.12565E-05
0.21417E-06
0.49780E-08
0.73686E-09
0.99956E-10
STAGE
1
2
3
5
6
7
PROPYLEN
0.40788E-01
0.61778E-02
0.72544E-03
0.80850E-05
0.83549E-06
0.81064E-07
****
MASS-X-PROFILE
****
ISOBUTAN
N-BUTANE
TRANS-BU
0.77007E-01
0.13345
0.29624E-02
0.24199E-01
0.49184E-01
0.10822E-02
0.73979E-02
0.19322E-01
0.42349E-03
0.54356E-03
0.23052E-02
0.49902E-04
0.13970E-03
0.74219E-03
0.15962E-04
0.31380E-04
0.20429E-03
0.43668E-05
1-BUTENE
0.29247E-02
0.96967E-03
0.32375E-03
0.28251E-04
0.78705E-05
0.19015E-05
STAGE
1
2
3
5
6
7
ISOBUTEN
0.10311E-01
0.34074E-02
0.11301E-02
0.96959E-04
0.26780E-04
0.64184E-05
****
MASS-X-PROFILE
****
CIS-2-01
2-MET-02
1:2-B-01
0.41697E-01
0.46885E-03
0.57685E-05
0.15876E-01
0.17550E-07
0.24333E-05
0.66372E-02
0.38303E-12
0.12080E-05
0.88963E-03
0.37758E-22
0.22526E-06
0.30200E-03
0.29378E-27
0.88907E-07
0.87181E-04
0.20352E-32
0.29424E-07
1:3-B-01
0.53553E-02
0.18176E-02
0.62969E-03
0.58812E-04
0.16900E-04
0.41979E-05
STAGE
1
2
3
5
6
7
N-PENTAN
0.16291E-03
0.10172E-07
0.34482E-12
0.70212E-22
0.76850E-27
0.74700E-32
****
MASS-X-PROFILE
****
N-HEXANE
N-HEPTAN
BENZENE
0.52523E-04
0.18197E-02
0.23504E-02
0.14249E-07
0.29816E-06
0.23482E-02
0.42600E-11
0.20380E-10
0.25463E-02
0.17094E-18
0.11891E-19
0.25771E-02
0.30798E-22
0.20581E-24
0.24746E-02
0.53001E-26
0.30203E-29
0.21966E-02
NITRO-01
0.10065E-07
0.70158E-10
0.31460E-12
0.56088E-17
0.23708E-19
0.10086E-21
STAGE
1
2
3
5
6
7
CO2
0.29863E-02
0.26872E-03
0.10718E-04
0.70673E-08
0.16115E-09
0.35853E-11
****
MASS-Y-PROFILE
****
WATER
METHANOL
DME
0.30014E-01
0.21432E-04
0.18375E-08
0.29040
0.55445E-04
0.11772E-08
0.62191
0.65872E-04
0.36385E-09
0.90654
0.22709E-04
0.12988E-10
0.94033
0.10324E-04
0.21201E-11
0.95959
0.38106E-05
0.31079E-12
METHY-01
0.38906E-08
0.49182E-08
0.34654E-08
0.59877E-09
0.20558E-09
0.59223E-10
STAGE
1
2
3
5
6
7
METHY-02
0.32522E-08
0.20564E-09
0.16128E-11
0.14211E-16
0.32796E-19
0.72675E-22
****
MASS-Y-PROFILE
****
N-PRO-01
METHA-01
N-BUT-01
0.74916E-02
0.46947E-02
0.12581E-02
0.31892E-02
0.17705E-01
0.12597E-02
0.37232E-03
0.34767E-01
0.30688E-03
0.13760E-05
0.44666E-01
0.40660E-05
0.70523E-07
0.40983E-01
0.38394E-06
0.34261E-08
0.32320E-01
0.33344E-07
METHY-03
0.68216E-03
0.42306E-03
0.75346E-04
0.82351E-06
0.74751E-07
0.63270E-08
STAGE
1
2
3
5
6
7
3-MET-01
0.16345E-04
0.11541E-03
0.23504E-03
0.33245E-03
0.33961E-03
0.33288E-03
****
MASS-Y-PROFILE
****
VALER-01
ETHANOL
CIS-C-01
0.13815E-03
0.50511E-04
0.41560E-04
0.86397E-04
0.13921E-03
0.26405E-03
0.12450E-04
0.12148E-03
0.53601E-03
0.62177E-07
0.18404E-04
0.75358E-03
0.36542E-08
0.55937E-05
0.76200E-03
0.20206E-09
0.14259E-05
0.72562E-03
METHY-05
0.13434E-01
0.97685E-02
0.94567E-03
0.10983E-05
0.28404E-07
0.69082E-09
STAGE
1
2
DIETH-01
0.79624E-02
0.67353E-02
****
MASS-Y-PROFILE
****
2-MET-01
METHY-06
DIETH-02
0.16104E-05
0.23970E-01
0.79624E-02
0.44509E-05
0.24749E-01
0.67353E-02
METHY-07
0.23970E-01
0.24749E-01
3
5
6
7
0.10096E-02
0.39418E-05
0.19593E-06
0.91279E-08
0.32571E-05
0.36275E-06
0.96050E-07
0.21653E-07
0.39769E-02
0.13121E-04
0.57143E-06
0.23151E-07
0.10096E-02
0.39418E-05
0.19593E-06
0.91279E-08
0.39769E-02
0.13121E-04
0.57143E-06
0.23151E-07
STAGE
1
2
3
5
6
7
3-MET-02
0.15695E-02
0.13501E-02
0.91101E-04
0.30921E-07
0.40319E-09
0.49066E-11
****
MASS-Y-PROFILE
****
TERT--01
METHANE
ETHYLENE
0.14492E-04
0.88049E-03
0.58855E-01
0.27281E-04
0.21330E-04
0.55982E-02
0.76878E-05
0.28748E-06
0.25762E-03
0.79146E-07
0.25769E-10
0.23977E-06
0.61467E-08
0.22109E-12
0.65385E-08
0.43623E-09
0.18781E-14
0.17371E-09
CYCLO-01
0.24843E-04
0.14285E-04
0.40166E-05
0.12147E-06
0.18333E-07
0.25010E-08
STAGE
1
2
3
5
6
7
PROPYLEN
0.25124
0.10287
0.19749E-01
0.28493E-03
0.29998E-04
0.29252E-05
****
MASS-Y-PROFILE
****
ISOBUTAN
N-BUTANE
TRANS-BU
0.16032
0.20335
0.43963E-02
0.15146
0.23710
0.52041E-02
0.77291E-01
0.15678
0.34501E-02
0.74203E-02
0.24517E-01
0.53442E-03
0.19458E-02
0.80571E-02
0.17457E-03
0.43974E-03
0.22321E-02
0.48081E-04
1-BUTENE
0.54470E-02
0.55457E-02
0.30957E-02
0.35317E-03
0.10039E-03
0.24404E-04
STAGE
1
2
3
5
6
7
ISOBUTEN
0.19066E-01
0.19515E-01
0.10879E-01
0.12231E-02
0.34483E-03
0.83180E-04
****
MASS-Y-PROFILE
****
CIS-2-01
2-MET-02
1:2-B-01
0.57504E-01
0.66577E-01
0.64764E-05
0.71424E-01
0.38697E-03
0.91668E-05
0.50562E-01
0.56105E-07
0.77143E-05
0.89044E-02
0.15821E-16
0.18894E-05
0.30865E-02
0.14113E-21
0.76139E-06
0.89702E-03
0.11075E-26
0.25366E-06
1:3-B-01
0.93581E-02
0.99508E-02
0.58012E-02
0.71022E-03
0.20833E-03
0.52085E-04
STAGE
1
2
3
5
6
7
N-PENTAN
0.12567E-01
0.13092E-03
0.32519E-07
0.20737E-16
0.26243E-21
0.28971E-26
****
MASS-Y-PROFILE
****
N-HEXANE
N-HEPTAN
BENZENE
0.22282E-02
0.21611E-01
0.28007E-03
0.45539E-04
0.13502E-02
0.13540E-02
0.45552E-07
0.95316E-06
0.26813E-02
0.33229E-14
0.21381E-14
0.36741E-02
0.63894E-18
0.44445E-19
0.36187E-02
0.11609E-21
0.77587E-24
0.32447E-02
NITRO-01
0.32886E-05
0.34813E-07
0.22428E-09
0.49077E-14
0.20964E-16
0.89096E-19
********************************
********************************
*** DEFINITIONS ***

WHERE:
STAGE
1
2
TEMPERATURE
F
VAPOR TO
184.42
236.74
LIQUID FROM
133.23
215.91
3
5
6
7
236.74
245.72
247.10
248.14
243.20
247.10
248.14
248.14
MASS FLOW
VOLUME FLOW
MOLECULAR
LB/HR
CUFT/HR
LIQUID FROM
1
51363.
0.21800E+06 1032.8
0.14971E+07 25.294
2 0.23936E+06 74875.
4475.5
0.83796E+06 19.827
3 0.22946E+06 64973.
4186.8
0.85693E+06 18.872
5 0.22457E+06 60081.
4043.1
0.84581E+06 18.423
6 0.22387E+06 59384.
4025.1
0.83755E+06 18.353
7 0.16449E+06 0.0000
2954.0
0.0000
18.276
WEIGHT
VAPOR TO
40.258
24.371
20.572
18.838
18.571

COLUMN DIAMETER
DC AREA/COLUMN AREA
DOWNCOMER VELOCITY
FLOW PATH LENGTH
SIDE WEIR LENGTH
CENTER WEIR LENGTH
2
7.41315
0.099999
0.28804
5.09321
1.15997
5.38647
0.0
0.0
0.0
0.0
0.0
0.0
FT
FT/SEC
FT
FT
FT
FT
FT
FT
FT
FT
FT

DENSITY
LB/CUFT
1
49.731
0.14561
2
53.482
0.89353E-01
3
54.805
0.75820E-01
5
55.543
0.71033E-01
6
55.618
0.70901E-01
7
55.683
STAGE
1
2
3
5
6
7
MARANGONI INDEX
DYNE/CM
-2.8723
-.88714
-.11917
-.75547E-01
-.45027E-01
VISCOSITY
SURFACE TENSION
CP
DYNE/CM
LIQUID FROM
0.39828
0.10766E-01
56.501
0.26125
0.12916E-01
55.510
0.23910
0.13189E-01
54.623
0.23086
0.13288E-01
54.244
0.22947
0.13314E-01
54.169
0.22836
54.123
FLOW PARAM
QR
CUFT/HR
81130.
34280.
31896.
30267.
29923.
0.0000
0.12749E-01
0.13067
0.13136
0.13367
0.13460
REDUCED F-FACTOR
(LB-CUFT)**.5/HR
0.57129E+06
0.25048E+06
0.23596E+06
0.22543E+06
0.22302E+06
0.0000
STAGE
2
3
4
DIAMETER
FT
7.4131
7.2345
7.1351
TOTAL AREA
SQFT
43.161
41.106
39.985
ACTIVE AREA
SQFT
34.529
32.885
31.988
************************************
***** TRAY RATING CALCULATIONS *****
************************************
*******************
*** SECTION
1 ***
*******************
ENDING STAGE NUMBER
PEAK CAPACITY FACTOR
OVERALL TRAY EFFICIENCY
************************************
************************************
SIDE DC AREA
SQFT
4.3161
4.1106
3.9984
2
4
GLITSCH
1.00000
1.00000
1.00000
TRAY SPECIFICATIONS
------------------*******************
*** SECTION
1 ***
*******************
ENDING STAGE NUMBER
2
4
GLITSCH
DESIGN PARAMETERS
FLOODING FACTOR
1.00000
1.00000
0.80000
1.00000
0.100000
0.12000
TRAY SPECIFICATIONS
------------------TRAY TYPE
NUMBER OF PASSES
TRAY SPACING
FT
FT
SIEVE
1
2.00000
!
! !
!
A
! !
! !-----------------!
! !
!
! !
A
!
!-----------------! !
!
! !
!
! !
SINGLE CROSSFLOW TRAY
NUMBER OF PASSES
DIAMETER
TRAY SPACING
DECK THICKNESS
TRAY TYPE
HOLE DIAMETER
DOWNCOMER DIMENSIONS
-------------------WEIR HEIGHT
DC CLEARANCE
TOP DC WIDTH
AA
AA
FT
1
7.50000
2.00000
0.011167
SIEVE
0.12000
0.041667
FT
FT
FT
0.16667
0.12500
1.17375
FT
FT
FT
***** RATING RESULTS *****

DIAMETER
STAGE-MAX FLOODING FACTOR
FLOODING FACTOR
STAGE-MAX DC BACKUP/TRAY SPACE
DC BACKUP
DC BACKUP/TRAY SPACING
STAGE-MAX DC VELOCITY
DC VELOCITY
STAGE-MAX WEIRLOADING
WEIR LOADING
SECTION PRESSURE DROP
MAX APPROACH TO SYSTEM LIMIT
STAGE-MAX SYSTEM LIMIT
FT
7.50000
2
0.78360
2
0.86192
0.43096
2
0.28134
2 (PANEL A)
102.388
0.37346
0.37630
2
FT
FT/SEC
GPM/FT
PSI
**** RATING PROFILES ****

FLOODING
STAGE FACTOR
2
3
4
0.7836
0.7502
0.7319
DC VELOCITY
FT/SEC
0.2813
0.2632
0.2565
BLOCK: B9
MODEL: HEATX
----------------------------HOT SIDE:
7
OUTLET STREAM:
121
NRTL
COLD SIDE:
52
OUTLET STREAM:
53
NRTL
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
DC BACKUP/
TRAY SPACE
DC BACKUP
FT
0.8619
0.8094
0.7892
0.4310
0.4047
0.3946
INPUT DATA
***
OUT
RELATIVE DIFF.
33914.1
716636.
-0.384121E+10
0.00000
0.00000
0.00000
***
7
T=
P=
V=
53
T=
P=
V=
PRESSURE DROP:
HOTSIDE, TOTAL
COLDSIDE, TOTAL

TWO
PHASE
FLASH
30
0.000100000

COUNTERCURRENT
HEAT EXCHANGER
SPECIFIED VALUE
F
PSI
PSI
BTU/HR
SQFT
SQFT
110.0000
1.00000
5.0000
5.0000
121
T= 1.1000D+02
P= 6.0000D+01
V= 6.6928D-01
52
T=
P=
V=
9.0000D+01
4.0000D+01
0.0000D+00
20029159.1672
3693.3344
3693.3344
0.0000
BTU/HR-SQFT-R
BTU/HR-R
149.6937
552868.7370
1.0000
36.2277
1
PSI
PSI
5.0000
5.0000

HOT SIDE:
COLD SIDE:
***
30
0.000100000
***
-------------------------------------|
|
----->|
HOT
|----->
2.1065D+02 |
|
6.5000D+01 |
|
1.0000D+00 |
|
|
|
<-----|
COLD
|<----1.2850D+02 |
|
3.5000D+01 |
|
0.0000D+00 |
|
--------------------------------------

LMTD (CORRECTED)
F

TWO
PHASE
FLASH
OVERALL RESULTS

UA (DIRTY)
33914.1
716636.
-0.384121E+10
***
***
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
STREAMS:
DUTY AND AREA:


IN
PRES. DROP
PSI
0.1291
0.1234
0.1209

HOT LIQUID
COLD LIQUID
BTU/HR-SQFT-R
HOT 2-PHASE
COLD LIQUID
BTU/HR-SQFT-R
HOT VAPOR
COLD LIQUID
BTU/HR-SQFT-R
HOT LIQUID
COLD 2-PHASE
BTU/HR-SQFT-R
HOT 2-PHASE
COLD 2-PHASE
BTU/HR-SQFT-R
HOT VAPOR
COLD 2-PHASE
BTU/HR-SQFT-R
HOT LIQUID
COLD VAPOR
BTU/HR-SQFT-R
HOT 2-PHASE
COLD VAPOR
BTU/HR-SQFT-R
HOT VAPOR
COLD VAPOR
BTU/HR-SQFT-R
688.00
7008.6
ZONE RESULTS
***

HOT
------------------------------------------------------------|
|
|
7
|
VAP
|
COND
| 121
------> |
|
|------>
210.6 |
177.4|
| 110.0
|
|
|
53
|
LIQ
|
LIQ
| 52
<------ |
|
|<-----128.5 |
123.9|
|
90.0
|
|
|
------------------------------------------------------------COLD
ZONE
1
2
HEAT DUTY
BTU/HR
2440379.718
17588779.449
AREA
SQFT
243.9478
3449.3867
BLOCK: B10
MODEL: FSPLIT
-----------------------------INLET STREAM:
140
OUTLET STREAMS:
54
NRTL
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
55
40
2399.64
102028.
-0.166441E+09
INPUT DATA
FRACTION OF FLOW
***
RESULTS
SPLIT=
RELATIVE DIFF.
2399.64
102028.
-0.166441E+09
0.00000
0.00000
0.179056E-15
INPUT DATA

TWO
PHASE
FLASH
TWO
PHASE
FLASH
COUNTERCURRENT
HEAT EXCHANGER
SPECIFIED VALUE
0
0
0
0
STREAM-ORDER=
58
T=
P=
V=
***
OUT
7456.10
209301.
-0.719985E+09
1
2
3
4
57
T=
P=
V=
BTU/HR
SQFT
SQFT
0.00000
0.00000
0.00000
***
PRESSURE DROP:
HOTSIDE, TOTAL
COLDSIDE, TOTAL
BTU/HR-SQFT-R
BTU/HR-R
30
0.000100000
1.0000
1.00000
3.1595D+02
8.4458D+01
6.8944D-02
44
T=
P=
V=
2.3441D+02
1.0500D+02
2.0198D-01
149.6937
1080619.8221
1.0000
46.6894
1
PSI
PSI
5.0000
5.0000

HOT SIDE:
COLD SIDE:
***
30
0.000100000
59
T=
P=
V=
50453511.6329
7218.8752
7218.8752
0.0000

LMTD (CORRECTED)
F
RELATIVE DIFF.
***
-------------------------------------|
|
----->|
HOT
|----->
3.2000D+02 |
|
8.9458D+01 |
|
1.0000D+00 |
|
|
|
<-----|
COLD
|<----2.9645D+02 |
|
1.0000D+02 |
|
1.0000D+00 |
|
--------------------------------------

UA (DIRTY)
7456.10
209301.
-0.719985E+09
***
KEY=
OVERALL RESULTS
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
STREAMS:
0.22000
0.25000
0.18000

IN
***
***
0.22000
0.25000
0.18000
0.35000
5.0000
5.0000

HOT LIQUID
COLD LIQUID
BTU/HR-SQFT-R
HOT 2-PHASE
COLD LIQUID
BTU/HR-SQFT-R
HOT VAPOR
COLD LIQUID
BTU/HR-SQFT-R
HOT LIQUID
COLD 2-PHASE
BTU/HR-SQFT-R
HOT 2-PHASE
COLD 2-PHASE
BTU/HR-SQFT-R
HOT VAPOR
COLD 2-PHASE
BTU/HR-SQFT-R
HOT LIQUID
COLD VAPOR
BTU/HR-SQFT-R
HOT 2-PHASE
COLD VAPOR
BTU/HR-SQFT-R
HOT VAPOR
COLD VAPOR
BTU/HR-SQFT-R
***
FRAC=
FRAC=
FRAC=
PSI
PSI
DUTY AND AREA:

BLOCK: B11
MODEL: HEATX
----------------------------HOT SIDE:
58
OUTLET STREAM:
59
NRTL
COLD SIDE:
44
OUTLET STREAM:
57
NRTL
***

104
***
OUT
STRM=54
STRM=55
STRM=40
STREAM= 54
55
40
104
AVERAGE U
UA
BTU/HR-SQFT-R
BTU/HR-R
149.6937
36517.4364
149.6937
516351.3006

IN
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
LMTD
F
66.8278
34.0636
3459.3
1175.5
ZONE RESULTS
***

HOT
------------------------------------------------------------|
|
58
|
COND
| 59
------> |
|------>
320.0 |
| 315.9
|
|
57
|
BOIL
| 44
<------ |
|<-----296.5 |
| 234.4
|
|
------------------------------------------------------------COLD
INLET STREAM:
OUTLET STREAM:

ZONE
1
HEAT DUTY
BTU/HR
50453511.633
AREA
SQFT
7218.8752
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
1361.45
49269.4
-0.899985E+08
***
VALVE PRESSURE DROP

INPUT DATA
***
OUT
***
25.0000
NO
RESULTS
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
2
30
0.000100000
***
PSIA
BLOCK: B13
MODEL: PUMP
---------------------------INLET STREAM:
S-501
OUTLET STREAM:
20
NRTL
65.0000

IN
2399.64
102028.
-0.214387E+09
)
***
0.00000
0.147677E-15
-0.331142E-15
***
NPHASE
INPUT DATA
***
OUT
RELATIVE DIFF.
2399.64
102028.
-0.214186E+09
0.00000
0.00000
-0.933598E-03
***

DRIVER EFFICIENCY
*** RESULTS
CUFT/HR

PRESSURE CHANGE PSI
NPSH AVAILABLE
FT-LBF/LB
FLUID POWER HP
BRAKE POWER HP
ELECTRICITY KW
BLOCK: B14
MODEL: COMPR
-----------------------------
2761.27
127660.
-0.902401E+08
30
0.000100000
***
2,605.59
278.800
0.0
52.8320
78.6622
58.6584
0.67163
78.6622
1,025.29
INPUT DATA
***
OUT
RELATIVE DIFF.
2761.27
127660.
-0.848534E+08
***
55.0000
0.72000
1.00000
RESULTS
***

BRAKE
NET WORK REQUIRED
HP
POWER LOSSES
HP
HEAD DEVELOPED,
FT-LBF/LB
BLOCK: B15
MODEL: FLASH3
-----------------------------INLET STREAM:
S-601
8
FIRST LIQUID OUTLET:
12
SECOND LIQUID OUTLET: 15
NRTL
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
2,117.07
2,117.07
2,117.07
0.0
1,524.29
235.076
209.077
0.72000
1.00000
23,641.7
1.00000
1.11667
984,527.
374,308.
1.00000
1.00000
1.11116
1.11116
1.15498
1.15498

IN
12384.4
331121.
-0.119966E+10
*** INPUT DATA

THREE PHASE PQ FLASH
PRESSURE DROP
PSI
SPECIFIED HEAT DUTY
BTU/HR
NO KEY COMPONENT IS SPECIFIED
KEY LIQUID STREAM:
15
***
OUTLET TEMPERATURE
F
OUTLET PRESSURE
PSIA
VAPOR FRACTION
1ST LIQUID/TOTAL LIQUID
0.00000
0.00000
-0.596934E-01
***

485.000
1.00000
NO FLASH PERFORMED
TOLERANCE

IN
***
RELATIVE DIFF.
1361.45
49269.4
-0.899985E+08
PSI
***

IN
AVERAGE U
UA
BTU/HR-SQFT-R
BTU/HR-R
149.6937
1080619.8221
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
BLOCK: B12
MODEL: VALVE
----------------------------INLET STREAM:
30
OUTLET STREAM:
3
NRTL
***
LMTD
F
46.6894
8
9
NRTL
RESULTS
***
OUT
12384.4
331121.
-0.119966E+10
RELATIVE DIFF.
0.587509E-15
-0.351579E-15
0.165994E-05
***
1.00000
0.0
30
0.000100000
***
138.38
18.000
0.22296
1.0000
V-L1-L2 PHASE EQUILIBRIUM :

COMP
CO2
WATER
METHANOL
DME
METHY-01
METHY-02
N-PRO-01
METHA-01
N-BUT-01
METHY-03
3-MET-01
VALER-01
ETHANOL
CIS-C-01
METHY-05
DIETH-01
2-MET-01
METHY-06
DIETH-02
METHY-07
3-MET-02
TERT--01
METHANE
ETHYLENE
CYCLO-01
PROPYLEN
ISOBUTAN
N-BUTANE
TRANS-BU
1-BUTENE
ISOBUTEN
CIS-2-01
2-MET-02
1:2-B-01
1:3-B-01
N-PENTAN
N-HEXANE
N-HEPTAN
BENZENE
NITRO-01
F(I)
0.913E-03
0.746
0.921E-05
0.537E-09
0.872E-09
0.590E-09
0.174E-02
0.388E-02
0.235E-03
0.124E-03
0.483E-04
0.216E-04
0.148E-04
0.119E-03
0.210E-02
0.124E-02
0.246E-06
0.374E-02
0.124E-02
0.374E-02
0.211E-03
0.263E-05
0.738E-03
0.282E-01
0.794E-05
0.803E-01
0.371E-01
0.471E-01
0.106E-02
0.131E-02
0.457E-02
0.138E-01
0.124E-01
0.162E-05
0.233E-02
0.234E-02
0.348E-03
0.290E-02
0.422E-03
0.158E-05
X1(I)
0.393E-04
0.919
0.861E-05
0.166E-09
0.506E-09
0.172E-10
0.300E-03
0.428E-02
0.901E-04
0.345E-04
0.582E-04
0.542E-05
0.134E-04
0.142E-03
0.599E-03
0.394E-03
0.204E-06
0.141E-02
0.394E-03
0.141E-02
0.618E-04
0.181E-05
0.792E-05
0.125E-02
0.220E-05
0.158E-01
0.166E-01
0.254E-01
0.577E-03
0.625E-03
0.220E-02
0.788E-02
0.120E-04
0.103E-05
0.116E-02
0.383E-05
0.132E-05
0.244E-04
0.488E-03
0.719E-08
BLOCK: B16
MODEL: PUMP
---------------------------INLET STREAM:
12
OUTLET STREAM:
14
NRTL
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
X2(I)
0.393E-04
0.919
0.861E-05
0.166E-09
0.506E-09
0.172E-10
0.300E-03
0.428E-02
0.901E-04
0.345E-04
0.582E-04
0.542E-05
0.134E-04
0.142E-03
0.599E-03
0.394E-03
0.204E-06
0.141E-02
0.394E-03
0.141E-02
0.618E-04
0.181E-05
0.792E-05
0.125E-02
0.220E-05
0.158E-01
0.166E-01
0.254E-01
0.577E-03
0.625E-03
0.220E-02
0.788E-02
0.120E-04
0.103E-05
0.116E-02
0.383E-05
0.132E-05
0.244E-04
0.488E-03
0.719E-08
K1(I)
101.
0.155
1.31
11.0
4.24
150.
22.5
0.583
8.20
12.6
0.241
14.4
1.46
0.276
12.2
10.7
1.93
8.46
10.7
8.46
11.8
3.04
415.
97.6
12.7
19.3
6.57
4.83
4.71
5.89
5.84
4.38
0.463E+04
3.57
5.52
0.274E+04
0.118E+04
529.
0.390
982.
K2(I)
101.
0.155
1.31
11.0
4.24
150.
22.5
0.583
8.20
12.6
0.241
14.4
1.46
0.276
12.2
10.7
1.93
8.46
10.7
8.46
11.8
3.04
415.
97.6
12.7
19.3
6.57
4.83
4.71
5.89
5.84
4.38
0.463E+04
3.57
5.52
0.274E+04
0.118E+04
529.
0.390
982.
***
OUT
BLOCK: B18
MODEL: MIXER
----------------------------INLET STREAMS:
14
OUTLET STREAM:
17
NRTL
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
)
***
INPUT DATA
RELATIVE DIFF.
12384.4
331121.
-0.119424E+10
*** INPUT DATA ***

TWO
PHASE
FLASH
BLOCK: B19
MODEL: VALVE
----------------------------INLET STREAM:
S-702
OUTLET STREAM:
6
NRTL
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
2024.42
114525.
-0.116199E+09
)
***

0.00000
0.00000
-0.199641E-15
30
0.000100000

IN
INPUT DATA
***
OUT
RELATIVE DIFF.
2024.42
114525.
-0.116199E+09
0.449262E-15
-0.168329E-08
0.415829E-08
***
PSIA
***
9623.15
203462.
-0.110939E+10
0.00000
0.572173E-15
-0.328525E-04
55.0000
1.00000
*** RESULTS
CUFT/HR
12384.4
331121.
-0.119424E+10
***
OUT
100.000
NO
RESULTS
2
30
0.000100000
***
RELATIVE DIFF.
***
NO FLASH PERFORMED
TOLERANCE
9

IN
VALVE PRESSURE DROP

9623.15
203462.
-0.110942E+10
37.0000
0.0
10.1324
14.3243
10.6816
0.70736
14.3243
98.6045
NPHASE

IN

DRIVER EFFICIENCY
Y(I)
0.396E-02
0.142
0.113E-04
0.183E-08
0.215E-08
0.259E-08
0.674E-02
0.249E-02
0.739E-03
0.435E-03
0.140E-04
0.779E-04
0.195E-04
0.392E-04
0.733E-02
0.421E-02
0.393E-06
0.119E-01
0.421E-02
0.119E-01
0.730E-03
0.550E-05
0.328E-02
0.122
0.280E-04
0.305
0.109
0.123
0.272E-02
0.368E-02
0.129E-01
0.345E-01
0.556E-01
0.367E-05
0.640E-02
0.105E-01
0.156E-02
0.129E-01
0.190E-03
0.706E-05
PRESSURE CHANGE PSI

NPSH AVAILABLE
FT-LBF/LB
FLUID POWER HP
BRAKE POWER HP
ELECTRICITY KW
30
0.000100000
***
BLOCK: B20
MODEL: HEATX
----------------------------HOT SIDE:
6
OUTLET STREAM:
S-801
NRTL
COLD SIDE:
27
OUTLET STREAM:
18
NRTL
***
3,765.43
PSI
431.520

IN
***
OUT
RELATIVE DIFF.
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
5408.84
281161.
-0.250625E+09
)
***
INPUT DATA
5408.84
281161.
-0.250625E+09
0.00000
0.00000
0.00000
***

TWO
PHASE
FLASH
HOTSIDE, TOTAL
COLDSIDE, TOTAL
PSI
PSI

HOT SIDE:
COLD SIDE:
***
30
0.000100000

TWO
PHASE
FLASH
30
0.000100000

COUNTERCURRENT
HEAT EXCHANGER
SPECIFIED VALUE
F
180.0000
1.00000
PSI
PSI
0.0000
0.0000

HOT LIQUID
COLD LIQUID
BTU/HR-SQFT-R
HOT 2-PHASE
COLD LIQUID
BTU/HR-SQFT-R
HOT VAPOR
COLD LIQUID
BTU/HR-SQFT-R
HOT LIQUID
COLD 2-PHASE
BTU/HR-SQFT-R
HOT 2-PHASE
COLD 2-PHASE
BTU/HR-SQFT-R
HOT VAPOR
COLD 2-PHASE
BTU/HR-SQFT-R
HOT LIQUID
COLD VAPOR
BTU/HR-SQFT-R
HOT 2-PHASE
COLD VAPOR
BTU/HR-SQFT-R
HOT VAPOR
COLD VAPOR
BTU/HR-SQFT-R
OVERALL RESULTS
18
T=
P=
V=
HEAT DUTY
BTU/HR
12189673.771
AREA
SQFT
1180.1973
BLOCK: B21
MODEL: VALVE
----------------------------INLET STREAM:
18
OUTLET STREAM:
S-701
NRTL
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
DUTY AND AREA:

UA (DIRTY)
9.1052D+01
5.5790D+02
0.0000D+00
BTU/HR-SQFT-R
BTU/HR-R
12189673.7713
1180.1973
1180.1973
0.0000
149.6937
176668.0511
***
AVERAGE U
UA
BTU/HR-SQFT-R
BTU/HR-R
149.6937
176668.0511
3384.42
166636.
-0.122236E+09
INPUT DATA
***
OUT
530.540
NO
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
RESULTS
2
30
0.000100000
***
PSI
BLOCK: B23
MODEL: PUMP
---------------------------INLET STREAM:
33
OUTLET STREAM:
21
NRTL
0.00000
0.00000
0.00000
***
PSIA
VALVE PRESSURE DROP
RELATIVE DIFF.
3384.42
166636.
-0.122236E+09
NPHASE
***
1.0000
68.9976
1
LMTD
F
68.9976

IN
***
BTU/HR
SQFT
SQFT

LMTD (CORRECTED)
F
PRESSURE DROP:
S-801
T= 1.8663D+02
P= 1.0000D+02
V= 4.3727D-01
27
T=
P=
V=
***
HOT
------------------------------------------------------------|
|
6
|
COND
| S-801
------> |
|------>
227.9 |
| 186.6
|
|
18
|
LIQ
| 27
<------ |
|<-----180.0 |
|
91.1
|
|
------------------------------------------------------------COLD
ZONE
STREAMS:
6
T=
P=
V=
ZONE RESULTS
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
-------------------------------------|
|
----->|
HOT
|----->
2.2787D+02 |
|
1.0000D+02 |
|
9.2002D-01 |
|
|
|
<-----|
COLD
|<----1.8000D+02 |
|
5.5790D+02 |
|
0.0000D+00 |
|
--------------------------------------
0.0000
0.0000
***
***
0.0000
0.0000
27.3600

IN
4429.17
79792.7
-0.516528E+09
***
OUT
4429.17
79792.7
-0.516390E+09
RELATIVE DIFF.
0.00000
0.00000
-0.268327E-03
***
INPUT DATA
***

DRIVER EFFICIENCY
500.000
1.00000
NO FLASH PERFORMED
TOLERANCE
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
30
0.000100000
***
1,581.98
292.600
3.80549
33.6645
54.4713
40.6192
0.61802
54.4713
835.362
BTU/HR-SQFT-R
BTU/HR-SQFT-R
BTU/HR-SQFT-R
BTU/HR-SQFT-R
OVERALL RESULTS
149.6937
149.6937
149.6937
149.6937
***
-------------------------------------|
|
S-613
----->|
HOT
|----->
T= 1.6935D+02 |
|
P= 2.7000D+02 |
|
V= 1.0000D+00 |
|
|
|
25
<-----|
COLD
|<----T= 1.2185D+02 |
|
P= 3.5000D+01 |
|
V= 0.0000D+00 |
|
--------------------------------------

UA (DIRTY)
INPUT DATA
***
OUT
RELATIVE DIFF.
13839.7
283391.
-0.153602E+10
0.00000
0.00000
0.00000
***
PRESSURE DROP:
HOTSIDE, TOTAL
COLDSIDE, TOTAL
30
0.000100000

COUNTERCURRENT
HEAT EXCHANGER
SPECIFIED VALUE
F
PSI
PSI

HOT LIQUID
COLD LIQUID
BTU/HR-SQFT-R
HOT 2-PHASE
COLD LIQUID
BTU/HR-SQFT-R
HOT VAPOR
COLD LIQUID
BTU/HR-SQFT-R
HOT LIQUID
COLD 2-PHASE
BTU/HR-SQFT-R
HOT 2-PHASE
COLD 2-PHASE
BTU/HR-SQFT-R
100.0000
1.00000
5.0000
5.0000
BTU/HR-SQFT-R
BTU/HR-R
1.0000D+02
2.6500D+02
3.9632D-01
24
T=
P=
V=
9.0000D+01
4.0000D+01
0.0000D+00
149.6937
326840.0684
1.0000
20.6625
1
5.0000
5.0000

HOT SIDE:
COLD SIDE:
25300.
41959.
ZONE RESULTS
***

HOT
------------------------------------------------------------|
|
|
S-613
|
VAP
|
COND
| 19
------> |
|
|------>
169.3 |
155.9|
| 100.0
|
|
|
25
|
LIQ
|
LIQ
| 24
<------ |
|
|<-----121.9 |
120.3|
|
90.0
|
|
|
------------------------------------------------------------COLD
ZONE
149.6937
149.6937
149.6937
149.6937
149.6937
19
T=
P=
V=
6753325.6549
2183.3929
2183.3929
0.0000
PSI
PSI
***
30
0.000100000

TWO
PHASE
FLASH
BTU/HR
SQFT
SQFT

LMTD (CORRECTED)
F

TWO
PHASE
FLASH
2-PHASE
VAPOR
VAPOR
VAPOR
DUTY AND AREA:

13839.7
283391.
-0.153602E+10
***
COLD
COLD
COLD
COLD
***

IN
VAPOR
LIQUID
2-PHASE
VAPOR
STREAMS:
*** RESULTS
PRESSURE CHANGE PSI
NPSH AVAILABLE
FT-LBF/LB
FLUID POWER HP
BRAKE POWER HP
ELECTRICITY KW
BLOCK: B25
MODEL: HEATX
----------------------------HOT SIDE:
S-613
OUTLET STREAM:
19
NRTL
COLD SIDE:
24
OUTLET STREAM:
25
NRTL
HOT
HOT
HOT
HOT
1
2
BLOCK:
HEAT DUTY
BTU/HR
330644.192
6422681.463
B26
AREA
SQFT
53.5657
2129.8272
MODEL: HEATX
LMTD
F
41.2354
20.1451
AVERAGE U
UA
BTU/HR-SQFT-R
BTU/HR-R
149.6937
8018.4486
149.6937
318821.6198
----------------------------HOT SIDE:
S-611
OUTLET STREAM:
11
NRTL
COLD SIDE:
71
OUTLET STREAM:
90
NRTL
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR

18917.6
407836.
-0.207391E+10
***
INPUT DATA
0.00000
0.00000
0.00000
30
0.000100000
30
0.000100000
110.0000
1.00000
PSI
PSI
5.0000
5.0000

HOT LIQUID
COLD LIQUID
BTU/HR-SQFT-R
HOT 2-PHASE
COLD LIQUID
BTU/HR-SQFT-R
HOT VAPOR
COLD LIQUID
BTU/HR-SQFT-R
HOT LIQUID
COLD 2-PHASE
BTU/HR-SQFT-R
HOT 2-PHASE
COLD 2-PHASE
BTU/HR-SQFT-R
HOT VAPOR
COLD 2-PHASE
BTU/HR-SQFT-R
HOT LIQUID
COLD VAPOR
BTU/HR-SQFT-R
HOT 2-PHASE
COLD VAPOR
BTU/HR-SQFT-R
HOT VAPOR
COLD VAPOR
BTU/HR-SQFT-R
OVERALL RESULTS
149.6937
358434.2017
PSI
PSI
5.0000
5.0000
3941.5
23558.
ZONE RESULTS
***

HOT
------------------------------------------------------------|
|
|
S-611
|
VAP
|
COND
| 11
------> |
|
|------>
190.2 |
164.2|
| 110.0
|
|
|
90
|
LIQ
|
LIQ
| 71
<------ |
|
|<-----128.3 |
124.1|
|
90.0
|
|
|
------------------------------------------------------------COLD
1
2
HEAT DUTY
BTU/HR
1215126.140
9651271.860
AREA
SQFT
161.7981
2232.6534
BLOCK: B27
MODEL: MIXER
----------------------------INLET STREAMS:
38
OUTLET STREAM:
44
NRTL
***
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
11
T=
P=
V=
1.1000D+02
1.4500D+02
5.9611D-01
71
T=
P=
V=
9.0000D+01
4.0000D+01
0.0000D+00
10866397.9992
1.0000
30.3163
1

HOT SIDE:
COLD SIDE:
ZONE
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
-------------------------------------|
|
S-611
----->|
HOT
|----->
T= 1.9016D+02 |
|
P= 1.5000D+02 |
|
V= 1.0000D+00 |
|
|
|
90
<-----|
COLD
|<----T= 1.2830D+02 |
|
P= 3.5000D+01 |
|
V= 0.0000D+00 |
|
--------------------------------------
BTU/HR
BTU/HR-SQFT-R
BTU/HR-R
STREAMS:
DUTY AND AREA:

PRESSURE DROP:
HOTSIDE, TOTAL
COLDSIDE, TOTAL
***

COUNTERCURRENT
HEAT EXCHANGER
SPECIFIED VALUE
F
***
RELATIVE DIFF.
***

TWO
PHASE
FLASH
***
OUT
18917.6
407836.
-0.207391E+10

TWO
PHASE
FLASH
2394.4515
2394.4515
0.0000

LMTD (CORRECTED)
F

IN

UA (DIRTY)
SQFT
SQFT
LMTD
F
50.1701
28.8775
AVERAGE U
UA
BTU/HR-SQFT-R
BTU/HR-R
149.6937
24220.1438
149.6937
334214.0578
41

IN
4125.59
149301.
-0.380314E+09
***
OUT
4125.59
149301.
-0.380314E+09
*** INPUT DATA ***

TWO
PHASE
FLASH
BLOCK: B29
MODEL: HEATER
-----------------------------INLET STREAM:
31
OUTLET STREAM:
23
NRTL
RELATIVE DIFF.
0.00000
0.194934E-15
-0.313450E-15
30
0.000100000
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR

IN
4125.59
149301.
-0.299043E+09
ONE
PHASE TP FLASH
PRESSURE DROP
*** INPUT DATA ***

SPECIFIED PHASE IS
F
PSI
*** RESULTS
F
PSIA
BTU/HR
OUTLET TEMPERATURE
OUTLET PRESSURE
HEAT DUTY
***
OUT
RELATIVE DIFF.
4125.59
149301.
-0.272723E+09
VAPOR
932.000
5.00000
30
0.000100000
***
932.00
90.000
0.26320E+08
BLOCK: B31
MODEL: HEATX
----------------------------HOT SIDE:
120
OUTLET STREAM:
32
NRTL
COLD SIDE:
57
OUTLET STREAM:
31
NRTL
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
385.50
INPUT DATA
PSI
PSI
RELATIVE DIFF.
8763.35
298602.
-0.602404E+09
0.00000
0.194934E-15
-0.424977E-10
***

ONE
PHASE
FLASH
SPECIFIED PHASE IS
COUNTERCURRENT
HEAT EXCHANGER
SPECIFIED VALUE
F
***
OUT
***
-------------------------------------|
|
120
----->|
HOT
|----->
T= 7.0542D+02 |
|
P= 3.0000D+01 |
|
V= 1.0000D+00 |
|
|
|
31
<-----|
COLD
|<----T= 6.6500D+02 |
|
P= 9.5000D+01 |
|
V= 1.0000D+00 |
|
--------------------------------------
BTU/HR
SQFT
SQFT
PRESSURE DROP:
HOTSIDE, TOTAL
COLDSIDE, TOTAL
BTU/HR-SQFT-R
BTU/HR-R
3.4352D+02
2.5000D+01
1.0000D+00
57
T=
P=
V=
2.9645D+02
1.0000D+02
1.0000D+00
149.6937
705862.4010
1.0000
43.6594
1
PSI
PSI
5.0000
5.0000

HOT SIDE:
COLD SIDE:
***
32
T=
P=
V=
30817555.7740
4715.3795
4715.3795
0.0000

LMTD (CORRECTED)
F

ONE
PHASE
FLASH
SPECIFIED PHASE IS
OVERALL RESULTS

UA (DIRTY)
8763.35
298602.
-0.602404E+09
***
***
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
STREAMS:
DUTY AND AREA:


IN
0.00000
0.00000
-0.880139E-01

HOT LIQUID
COLD LIQUID
BTU/HR-SQFT-R
HOT 2-PHASE
COLD LIQUID
BTU/HR-SQFT-R
HOT VAPOR
COLD LIQUID
BTU/HR-SQFT-R
HOT LIQUID
COLD 2-PHASE
BTU/HR-SQFT-R
HOT 2-PHASE
COLD 2-PHASE
BTU/HR-SQFT-R
HOT VAPOR
COLD 2-PHASE
BTU/HR-SQFT-R
HOT LIQUID
COLD VAPOR
BTU/HR-SQFT-R
HOT 2-PHASE
COLD VAPOR
BTU/HR-SQFT-R
HOT VAPOR
COLD VAPOR
BTU/HR-SQFT-R
131.93
542.51
ZONE RESULTS
***
VAPOR
30
0.000100000
VAPOR
30
0.000100000
665.0000
1.00000
5.0000
5.0000

HOT
------------------------------------------------------------|
|
120
|
VAP
| 32
------> |
|------>
705.4 |
| 343.5
|
|
31
|
VAP
| 57
<------ |
|<-----665.0 |
| 296.5
|
|
------------------------------------------------------------COLD
ZONE
1
HEAT DUTY
BTU/HR
30817555.774
AREA
SQFT
4715.3795
BLOCK: B32
MODEL: VALVE
----------------------------INLET STREAM:
21
OUTLET STREAM:
56
NRTL
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
LMTD
F
43.6594

IN
4429.17
79792.7
-0.516390E+09
)
***

INPUT DATA
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
RESULTS
2
30
0.000100000
***
25.0000

IN
OUT
4859.07
5016.61
98068.0
98068.0
-0.466740E+09 -0.466740E+09
***
0.00000
0.00000
0.00000
475.000
NO
PSI
BLOCK: B34
MODEL: RGIBBS
-----------------------------INLET STREAM:
95
OUTLET STREAM:
68
NRTL
RELATIVE DIFF.
***
NPHASE
***
***
OUT
4429.17
79792.7
-0.516390E+09
PSIA
VALVE PRESSURE DROP
AVERAGE U
UA
BTU/HR-SQFT-R
BTU/HR-R
149.6937
705862.4010
INPUT DATA
***
GENERATION
RELATIVE DIFF.
157.549
0.543890E-15
0.845800E-14
0.229157E-06
***
F
923.85
F
923.85
30.000
SPECIFIED DUTY
BTU/HR
0.0000
CO
WATER
METHANOL
DME
METHY-01
METHY-02
ACETA-01
N-PRO-01
ACROL-01
METHA-01
N-BUT-01
METHY-03
ACETONE
3-MET-01
1:1-D-01
VALER-01
METHY-04
ETHANOL
CIS-C-01
METHY-05
DIETH-01
2-MET-01
METHY-06
DIETH-02
METHY-07
3-MET-02
TERT--01
METHANE
ETHANE
ETHYLENE
PROPANE
CYCLO-01
PROPYLEN
ISOBUTAN
N-BUTANE
TRANS-BU
1-BUTENE
ISOBUTEN
CIS-2-01
2-MET-02
1:2-B-01
1:3-B-01
N-PENTAN
N-HEXANE
N-HEPTAN
BENZENE
TOLUENE
N-OCT-01
NITRO-01
0.00
2.00
4.00
6.00
8.00
10.00
4.00
6.00
4.00
6.00
8.00
6.00
6.00
10.00
10.00
10.00
8.00
6.00
6.00
10.00
10.00
12.00
10.00
10.00
10.00
12.00
10.00
4.00
6.00
4.00
8.00
6.00
6.00
10.00
10.00
8.00
8.00
8.00
8.00
12.00
6.00
6.00
12.00
14.00
16.00
6.00
8.00
18.00
0.00
1.00
0.00
1.00
2.00
3.00
4.00
2.00
3.00
3.00
4.00
4.00
3.00
3.00
5.00
4.00
5.00
4.00
2.00
4.00
5.00
5.00
5.00
5.00
5.00
5.00
6.00
4.00
1.00
2.00
2.00
3.00
3.00
3.00
4.00
4.00
4.00
4.00
4.00
4.00
5.00
4.00
4.00
5.00
6.00
7.00
6.00
7.00
8.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
2.00

***
TEMPERATURE
F
PRESSURE
PSIA
VAPOR FRACTION
PHASE
OF TYPE
PHASE FRACTION
PLACED IN STREAM
WATER
METHANOL
DME
METHY-01
METHY-02
N-PRO-01
METHA-01
N-BUT-01

N-HEPTAN
ATOM MATRIX:
ELEMENT
H
C
N
O
H2
2.00 0.00 0.00 0.00
CO2
0.00 1.00 0.00 2.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
2.00
1.00
1.00
2.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
RESULTS
VAPOR
VAPOR
1.000000
68
0.9595153
0.2175165E-04
0.1672885E-08
0.2242928E-08
0.1177869E-08
0.1320801E-02
0.1592929E-02
0.1668745E-03
***
923.85
420.00
1.0000
1
METHY-03
3-MET-01
1:1-D-01
VALER-01
ETHANOL
CIS-C-01
METHY-05
DIETH-01
2-MET-01
METHY-06
DIETH-02
METHY-07
3-MET-02
TERT--01
ETHYLENE
CYCLO-01
PROPYLEN
ISOBUTAN
N-BUTANE
TRANS-BU
1-BUTENE
ISOBUTEN
CIS-2-01
2-MET-02
1:2-B-01
1:3-B-01
N-PENTAN
N-HEXANE
N-HEPTAN
0.1836969E-03
0.2757928E-04
0.1365000E-14
0.1428941E-04
0.2777926E-04
0.5332514E-04
0.8100559E-03
0.5367923E-03
0.2597716E-06
0.1556453E-02
0.5367923E-03
0.1556453E-02
0.7857367E-04
0.2800217E-05
0.4389216E-02
0.1269474E-05
0.8656995E-02
0.3668596E-02
0.5312232E-02
0.1772740E-02
0.1314192E-02
0.3262501E-02
0.1442393E-02
0.1106975E-02
0.2576748E-06
0.2424300E-03
0.7292586E-03
0.8716948E-04
0.1130566E-04
NO FLASH PERFORMED
TOLERANCE
*** RESULTS ***

1,472.84
PRESSURE CHANGE PSI
497.900
NPSH AVAILABLE
FT-LBF/LB
-0.036253
FLUID POWER HP
53.3327
BRAKE POWER HP
87.4515
ELECTRICITY KW
65.2126
0.60985
87.4515
1,795.88
NEGATIVE NPSH MAY BE DUE TO VAPOR IN THE FEED OR UNACCOUNTED SUCTION HEAD.
BLOCK: B38
MODEL: VALVE
----------------------------INLET STREAM:
2
OUTLET STREAM:
38
NRTL
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
1905.25
109301.
-0.121379E+09
***

50
51
RELATIVE DIFF.
1905.25
109301.
-0.121379E+09
0.00000
0.00000
0.00000
***

IN
3384.42
166636.
-0.134426E+09
BLOCK: B36
MODEL: PUMP
---------------------------INLET STREAM:
123
OUTLET STREAM:
51
NRTL
PSIA
***
OUT
RELATIVE DIFF.
3384.42
166636.
-0.134426E+09
0.00000
0.00000
0.221701E-15
30
0.000100000
***
VALVE PRESSURE DROP
BLOCK: B40
MODEL: RGIBBS
-----------------------------INLET STREAM:
97
OUTLET STREAM:
85
NRTL
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
1119.31
58800.7
-0.823424E+08
***

DRIVER EFFICIENCY
***
0.0

IN
OUT
5542.04
5702.06
120404.
120404.
-0.516838E+09 -0.516838E+09
***
GENERATION
RELATIVE DIFF.
160.017
-0.159503E-15
-0.459263E-14
0.449880E-10

IN
RESULTS
2
30
0.000100000
PSI
***
***
105.000
NO
NPHASE
*** INPUT DATA ***

TWO
PHASE
FLASH
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
INPUT DATA
***
OUT
5016.615
BLOCK: B35
MODEL: MIXER
----------------------------INLET STREAMS:
S-615
OUTLET STREAM:
27
NRTL
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR

IN
***
LBMOL/HR
30
0.000100000
INPUT DATA
***
OUT
RELATIVE DIFF.
1119.31
58800.7
-0.821199E+08
0.00000
-0.123739E-15
-0.270231E-02
INPUT DATA
***
F
895.77
F
895.77
40.000
SPECIFIED DUTY
BTU/HR
0.0000
***
557.900
1.00000

PHASE
OF TYPE
PHASE FRACTION
PLACED IN STREAM
METHANOL
DME
METHY-01
METHY-02
N-PRO-01
METHA-01
N-BUT-01
METHY-03
3-MET-01
1:1-D-01
VALER-01
ETHANOL
CIS-C-01
METHY-05
DIETH-01
2-MET-01
METHY-06
DIETH-02
METHY-07
3-MET-02
TERT--01
ETHYLENE
CYCLO-01
PROPYLEN
ISOBUTAN
N-BUTANE
TRANS-BU
1-BUTENE
ISOBUTEN
CIS-2-01
2-MET-02
1:2-B-01
1:3-B-01
N-PENTAN
N-HEXANE
N-HEPTAN
WATER

N-HEPTAN
ATOM MATRIX:
ELEMENT
H
H2
2.00
CO2
0.00
CO
0.00
WATER
2.00
METHANOL
4.00
DME
6.00
METHY-01
8.00
METHY-02 10.00
ACETA-01
4.00
N-PRO-01
6.00
ACROL-01
4.00
METHA-01
6.00
N-BUT-01
8.00
METHY-03
6.00
ACETONE
6.00
3-MET-01 10.00
1:1-D-01 10.00
VALER-01 10.00
METHY-04
8.00
ETHANOL
6.00
CIS-C-01
6.00
METHY-05 10.00
DIETH-01 10.00
2-MET-01 12.00
METHY-06 10.00
DIETH-02 10.00
METHY-07 10.00
3-MET-02 12.00
TERT--01 10.00
METHANE
4.00
ETHANE
6.00
ETHYLENE
4.00
PROPANE
8.00
CYCLO-01
6.00
PROPYLEN
6.00
ISOBUTAN 10.00
N-BUTANE 10.00
TRANS-BU
8.00
1-BUTENE
8.00
ISOBUTEN
8.00
CIS-2-01
8.00
2-MET-02 12.00
1:2-B-01
6.00
1:3-B-01
6.00
N-PENTAN 12.00
N-HEXANE 14.00
N-HEPTAN 16.00
BENZENE
6.00
TOLUENE
8.00
N-OCT-01 18.00
NITRO-01
0.00
C
0.00
1.00
1.00
0.00
1.00
2.00
3.00
4.00
2.00
3.00
3.00
4.00
4.00
3.00
3.00
5.00
4.00
5.00
4.00
2.00
4.00
5.00
5.00
5.00
5.00
5.00
5.00
6.00
4.00
1.00
2.00
2.00
3.00
3.00
3.00
4.00
4.00
4.00
4.00
4.00
4.00
5.00
4.00
4.00
5.00
6.00
7.00
6.00
7.00
8.00
0.00
N
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
2.00
***
TEMPERATURE
F
PRESSURE
PSIA
VAPOR FRACTION
O
0.00
2.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
2.00
1.00
1.00
2.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
RESULTS
VAPOR
VAPOR
1.000000
85
0.2089080E-04
0.1708829E-08
0.2838222E-08
0.1885720E-08
0.2052686E-02
0.2970141E-02
0.3110727E-03
0.3152666E-03
0.6393386E-04
0.1800812E-14
0.3196064E-04
0.3336157E-04
0.9521184E-04
0.2054006E-02
0.1327183E-02
0.5895818E-06
0.3881401E-02
0.1327183E-02
0.3881401E-02
0.2374363E-03
0.5415553E-05
0.5340594E-02
0.1737634E-05
0.1316640E-01
0.7622196E-02
0.1071955E-01
0.3351675E-02
0.2398486E-02
0.6278266E-02
0.2713569E-02
0.2740504E-02
0.3745013E-06
0.4139026E-03
0.1767358E-02
0.2530345E-03
0.3937038E-04
0.9245838
LBMOL/HR
5702.060
BLOCK: B41
MODEL: VALVE
----------------------------INLET STREAM:
5
OUTLET STREAM:
41
NRTL
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
2220.34
40000.0
-0.258935E+09
)
***

***

IN
INPUT DATA
RELATIVE DIFF.
2220.34
40000.0
-0.258935E+09
105.000
NO
2
30
0.000100000
1
***
RESULTS
***

VALVE PRESSURE DROP
PSI
0.00000
0.00000
0.00000
***
PSIA
NPHASE
895.77
370.00
1.0000
***
OUT
102.400
BLOCK: B43
MODEL: VALVE
----------------------------INLET STREAM:
78
OUTLET STREAM:
80
NRTL
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR

IN
831.736
35000.0
0.285393E+07
)
***

INPUT DATA
***
OUT
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
51.0000
NO
RESULTS
2
30
0.000100000
***
VALVE PRESSURE DROP

INPUT DATA
RESULTS

BRAKE
NET WORK REQUIRED
HP
POWER LOSSES
HP
HEAD DEVELOPED,
FT-LBF/LB
***
OUT
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
125.000
0.72000
1.00000
***
RESULTS
2
30
0.000100000
***
65.0000
831.736
35000.0
0.736698E+07
INPUT DATA

***
423.741
423.741
423.741
0.0
305.093
87.2693
63.7622
0.72000
1.00000
17,259.6
1.00000
1.16808
85,364.2
39,054.5
1.00000
1.00000
1.15888
1.15888
1.22398
1.22398
25.0000
NO

IN
***
0.00000
0.00000
0.00000
***
PSIA
RELATIVE DIFF.
9000.00
164485.
-0.107408E+10
PSI
RELATIVE DIFF.
0.00000
0.00000
-0.146353
***
OUT
NPHASE
***
831.736
35000.0
0.736698E+07
INPUT DATA
BLOCK: B46
MODEL: COMPR
----------------------------INLET STREAM:
82
OUTLET STREAM:
84
NRTL

9000.00
164485.
-0.107408E+10
***
318.000
831.736
35000.0
0.628880E+07
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
***

IN
0.00000
0.00000
0.00000

IN
***
PSI
BLOCK: B44
MODEL: COMPR
----------------------------INLET STREAM:
81
OUTLET STREAM:
82
NRTL
RELATIVE DIFF.
***
NPHASE
***
***
831.736
35000.0
0.285393E+07
PSIA
VALVE PRESSURE DROP
BLOCK: B45
MODEL: VALVE
----------------------------INLET STREAM:
S-606
OUTLET STREAM:
46
NRTL
RESULTS

BRAKE
NET WORK REQUIRED
HP
POWER LOSSES
HP
HEAD DEVELOPED,
FT-LBF/LB
***
OUT
RELATIVE DIFF.
831.736
35000.0
0.884236E+07
0.00000
0.00000
-0.166853
***
375.000
0.72000
1.00000
***
579.845
579.845
579.845
0.0
417.488
192.886
164.653
0.72000
1.00000
23,617.9
1.00000
1.14506
39,054.5
15,532.0
1.00000
1.00000
1.13695
1.13695
1.19148
1.19148
BLOCK: B48
MODEL: MIXER
----------------------------INLET STREAMS:
66
OUTLET STREAM:
67
NRTL
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
***
73

4861.10
98157.7
-0.467071E+09
***
OUT
4861.10
98157.7
-0.467071E+09
RELATIVE DIFF.
*** INPUT DATA ***

TWO
PHASE
FLASH
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
0.00000
0.148250E-15
-0.127614E-15
***
30
0.000100000
BLOCK: B52
MODEL: VALVE
----------------------------INLET STREAM:
54
OUTLET STREAM:
93
NRTL
105
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR

***
OUT
5546.57
120604.
-0.517576E+09
*** INPUT DATA ***

TWO
PHASE
FLASH
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
0.00000
0.603295E-15
-0.575806E-15
30
0.000100000

***
OUT
7462.50
181820.
-0.655575E+09
*** INPUT DATA ***

TWO
PHASE
FLASH
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
***
OUT
RELATIVE DIFF.
527.920
22446.1
-0.366170E+08
0.00000
0.00000
0.00000

INPUT DATA
***
PSIA
410.000
NO
NPHASE
RESULTS
2
30
0.000100000
***
PSI
45.0000
110
7462.50
181820.
-0.655575E+09
BLOCK: B51
MODEL: VALVE
----------------------------INLET STREAM:
40
OUTLET STREAM:
66
NRTL
RELATIVE DIFF.
VALVE PRESSURE DROP

IN
5.00000
527.920
22446.1
-0.366170E+08
***
BLOCK: B50
MODEL: MIXER
----------------------------INLET STREAMS:
94
OUTLET STREAM:
87
NRTL
***

IN
***
5546.57
120604.
-0.517576E+09
RESULTS
2
30
0.000100000
PSI
***

IN
450.000
NO
NPHASE
VALVE PRESSURE DROP
BLOCK: B49
MODEL: MIXER
----------------------------INLET STREAMS:
93
OUTLET STREAM:
70
NRTL
***

IN
INPUT DATA
PSIA
RELATIVE DIFF.
0.00000
-0.480208E-15
0.363679E-15
BLOCK: B53
MODEL: VALVE
----------------------------INLET STREAM:
55
OUTLET STREAM:
94
NRTL
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
599.909
25506.9
-0.416103E+08
30
0.000100000
***
431.935
18365.0
-0.299594E+08
***
OUT
431.935
18365.0
-0.299594E+08
INPUT DATA
RELATIVE DIFF.
0.00000
0.00000
0.00000
***
VALVE PRESSURE DROP
BLOCK:
B55
MODEL: PUMP
RESULTS
PSI
***
OUT
RELATIVE DIFF.
599.909
25506.9
-0.416103E+08
0.00000
0.00000
0.00000
***
PSIA
235.000
NO
NPHASE

IN

IN
2
30
0.000100000
***
220.000
---------------------------INLET STREAM:
125
OUTLET STREAM:
50
NRTL
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
MASS(LB/HR
)
ENTHALPY(BTU/HR

IN
914.847
49444.4
-0.369268E+08
)
***
INPUT DATA
***
OUT
***
RELATIVE DIFF.
914.847
49444.4
-0.367454E+08
107836.
-0.358876E+08
0.00000
-0.441463E-15
-0.491120E-02
VALVE PRESSURE DROP

NO FLASH PERFORMED
TOLERANCE
30
0.000100000
1,441.65
412.900
0.0
43.2914
71.2751
53.1498
0.60738
71.2751
1,733.60
***
VALVE PRESSURE DROP

INPUT DATA
***
OUT
BLOCK: B58
MODEL: VALVE
----------------------------INLET STREAM:
124
OUTLET STREAM:
26
NRTL
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
0.00000
-0.430001E-15
0.321403E-15
***
25.0000
NO
NPHASE
2
30
0.000100000
***
***
TOTAL BALANCE
MOLE(LBMOL/HR)
***
3.00000
RESULTS
VAPOR
30
0.000100000
***
PSIA
BLOCK: B59
MODEL: RGIBBS
-----------------------------INLET STREAM:
63
OUTLET STREAM:
64
NRTL
0.00000
0.00000
0.00000
NO
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
RELATIVE DIFF.
1350.26
58391.2
-0.620734E+07
142.000

IN
OUT
1402.70
1576.84
50762.4
50762.4
-0.927257E+08 -0.866435E+08
***
GENERATION
RELATIVE DIFF.
174.137
0.144196E-15
0.659335E-14
-0.655940E-01
***
PSIA
BLOCK: B57
MODEL: VALVE
----------------------------INLET STREAM:
122
OUTLET STREAM:
72
NRTL
INPUT DATA
***
OUT
PSI
***
1350.26
58391.2
-0.620734E+07
***
***
RESULTS
57.0000

IN
RELATIVE DIFF.
1402.70
50762.4
-0.927257E+08
PSI
***
***
PHASE
1402.70
50762.4
-0.927257E+08
***
RESULTS
PSIA
VALVE PRESSURE DROP


IN
2
30
0.000100000
***

PRESSURE CHANGE PSI
NPSH AVAILABLE
FT-LBF/LB
FLUID POWER HP
BRAKE POWER HP
ELECTRICITY KW
***
3.00000
NO
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
***
PSI
NPHASE
557.900
1.00000
BLOCK: B56
MODEL: VALVE
----------------------------INLET STREAM:
61
OUTLET STREAM:
63
NRTL
-0.404836E-15
0.207609E-15
***

DRIVER EFFICIENCY
*** RESULTS
CUFT/HR
INPUT DATA
107836.
-0.358876E+08
INPUT DATA
***
65.0000
SYSTEM TEMPERATURE
F
887.00
F
887.00
35.000

IN
***
OUT

RELATIVE DIFF.
2265.11
2265.11
0.00000

1:3-B-01
ATOM MATRIX:
ELEMENT
H
H2
2.00
CO2
0.00
CO
0.00
WATER
2.00
METHANOL
4.00
DME
6.00
METHY-01
8.00
METHY-02 10.00
ACETA-01
4.00
N-PRO-01
6.00
ACROL-01
4.00
METHA-01
6.00
N-BUT-01
8.00
METHY-03
6.00
ACETONE
6.00
3-MET-01 10.00
1:1-D-01 10.00
VALER-01 10.00
METHY-04
8.00
ETHANOL
6.00
CIS-C-01
6.00
METHY-05 10.00
DIETH-01 10.00
2-MET-01 12.00
METHY-06 10.00
DIETH-02 10.00
METHY-07 10.00
3-MET-02 12.00
TERT--01 10.00
METHANE
4.00
ETHANE
6.00
ETHYLENE
4.00
PROPANE
8.00
CYCLO-01
6.00
PROPYLEN
6.00
ISOBUTAN 10.00
N-BUTANE 10.00
TRANS-BU
8.00
1-BUTENE
8.00
ISOBUTEN
8.00
CIS-2-01
8.00
2-MET-02 12.00
1:2-B-01
6.00
1:3-B-01
6.00
N-PENTAN 12.00
N-HEXANE 14.00
N-HEPTAN 16.00
BENZENE
6.00
TOLUENE
8.00
N-OCT-01 18.00
NITRO-01
0.00
C
0.00
1.00
1.00
0.00
1.00
2.00
3.00
4.00
2.00
3.00
3.00
4.00
4.00
3.00
3.00
5.00
4.00
5.00
4.00
2.00
4.00
5.00
5.00
5.00
5.00
5.00
5.00
6.00
4.00
1.00
2.00
2.00
3.00
3.00
3.00
4.00
4.00
4.00
4.00
4.00
4.00
5.00
4.00
4.00
5.00
6.00
7.00
6.00
7.00
8.00
0.00
N
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
2.00
O
0.00
2.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
2.00
1.00
1.00
2.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
***
TEMPERATURE
F
PRESSURE
PSIA
HEAT DUTY
BTU/HR
VAPOR FRACTION
RESULTS
OF TYPE
PHASE FRACTION
PLACED IN STREAM
WATER
METHANOL
DME
METHY-01
METHY-02
N-PRO-01
N-BUT-01
METHY-03
3-MET-01
1:1-D-01
VALER-01
ETHANOL
CIS-C-01
METHY-05
DIETH-01
2-MET-01
METHY-06
DIETH-02
METHY-07
3-MET-02
TERT--01
ETHYLENE
CYCLO-01
PROPYLEN
ISOBUTAN
N-BUTANE
CIS-2-01
2-MET-02
1:2-B-01
1:3-B-01
VAPOR
1.000000
64
0.5657823
0.1148136E-04
0.8612849E-09
0.1377762E-08
0.8875514E-09
0.1016810E-02
0.1468740E-03
0.8053657E-05
0.2910624E-04
0.3979346E-16
0.1438500E-04
0.1771165E-04
0.4235348E-04
0.9623707E-03
0.6168212E-03
0.2791097E-06
0.1808873E-02
0.6168212E-03
0.1808873E-02
0.1058155E-03
0.2708356E-05
0.5444425E-01
0.1654046E-04
0.1296382
0.7807622E-01
0.1087778
0.2571841E-01
0.2670067E-01
0.3121407E-05
0.3633071E-02
LBMOL/HR
1576.838
BLOCK: B61
MODEL: HEATER
-----------------------------INLET STREAM:
64
OUTLET STREAM:
65
NRTL
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR

IN
1576.84
50762.4
-0.866435E+08
)
***
INPUT DATA
TWO
PHASE PQ FLASH
PRESSURE DROP
SPECIFIED HEAT DUTY
***
887.00
30.000
0.60822E+07
1.0000
1
RELATIVE DIFF.
1576.84
50762.4
-0.925468E+08
0.00000
0.143334E-15
0.637878E-01
***
PSI
BTU/HR
*** RESULTS
OUTLET TEMPERATURE
F
OUTLET PRESSURE
PSIA
***
OUT
0.0
-5,903,360.
30
0.000100000
***
709.12
30.000
1.0000
0.0000

PHASE
VAPOR
COMP
WATER
F(I)
0.56578
X(I)
0.97460
Y(I)
0.56578
K(I)
114.69
METHANOL
DME
METHY-01
METHY-02
N-PRO-01
N-BUT-01
METHY-03
3-MET-01
VALER-01
ETHANOL
CIS-C-01
METHY-05
DIETH-01
2-MET-01
METHY-06
DIETH-02
METHY-07
3-MET-02
TERT--01
ETHYLENE
CYCLO-01
PROPYLEN
ISOBUTAN
N-BUTANE
CIS-2-01
2-MET-02
1:2-B-01
1:3-B-01
0.11481E-04
0.86128E-09
0.13778E-08
0.88755E-09
0.10168E-02
0.14687E-03
0.80537E-05
0.29106E-04
0.14385E-04
0.17712E-04
0.42353E-04
0.96237E-03
0.61682E-03
0.27911E-06
0.18089E-02
0.61682E-03
0.18089E-02
0.10582E-03
0.27084E-05
0.54444E-01
0.16540E-04
0.12964
0.78076E-01
0.10878
0.25718E-01
0.26701E-01
0.31214E-05
0.36331E-02
BLOCK: B60
MODEL: SEP
--------------------------INLET STREAM:
67
OUTLET STREAMS:
95
NRTL
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
0.27689E-05
0.41404E-10
0.15976E-09
0.13737E-11
0.17476E-04
0.56718E-05
0.23675E-06
0.44942E-04
0.33375E-06
0.29890E-05
0.58162E-04
0.16969E-04
0.15274E-04
0.39875E-07
0.49643E-04
0.15274E-04
0.49643E-04
0.13841E-05
0.17857E-06
0.34690E-03
0.70815E-06
0.37369E-02
0.62364E-02
0.11507E-01
0.29498E-02
0.39806E-06
0.43252E-06
0.33758E-03
653.23
290.70
159.12
4313.6
294.45
202.59
129.89
56.408
277.72
461.89
54.895
121.31
15.704
138.52
17.381
15.704
17.381
215.38
396.55
674.70
278.05
327.42
178.26
156.46
163.76
331.72
115.20
188.69
METHA-01
N-BUT-01
METHY-03
ACETONE
3-MET-01
1:1-D-01
VALER-01
METHY-04
ETHANOL
CIS-C-01
METHY-05
DIETH-01
2-MET-01
METHY-06
DIETH-02
METHY-07
3-MET-02
TERT--01
METHANE
ETHANE
ETHYLENE
PROPANE
CYCLO-01
PROPYLEN
ISOBUTAN
N-BUTANE
TRANS-BU
1-BUTENE
ISOBUTEN
CIS-2-01
2-MET-02
1:2-B-01
1:3-B-01
N-PENTAN
N-HEXANE
N-HEPTAN
BENZENE
TOLUENE
N-OCT-01
NITRO-01
96

IN
4861.10
98157.7
-0.467071E+09
0.11481E-04
0.86128E-09
0.13778E-08
0.88755E-09
0.10168E-02
0.14687E-03
0.80537E-05
0.29106E-04
0.14385E-04
0.17712E-04
0.42353E-04
0.96237E-03
0.61682E-03
0.27911E-06
0.18089E-02
0.61682E-03
0.18089E-02
0.10582E-03
0.27084E-05
0.54444E-01
0.16540E-04
0.12964
0.78076E-01
0.10878
0.25718E-01
0.26701E-01
0.31214E-05
0.36331E-02
***
OUT
RELATIVE DIFF.
4861.10
98157.7
-0.467071E+09
-0.187096E-15
-0.148250E-15
0.522386E-11
***
***
INPUT DATA
HEAT DUTY
0.0
30
0.000100000
FLASH SPECS FOR STREAM 96

TWO
PHASE TP FLASH
PRESSURE DROP
PSI
CPT= H2
CO2
CO
WATER
METHANOL
DME
METHY-01
METHY-02
ACETA-01
N-PRO-01
ACROL-01
***
***

TWO
PHASE TP FLASH
PRESSURE DROP
PSI
FRACTION OF FEED
SUBSTREAM= MIXED
STREAM= 96
RESULTS
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
1.00000
0.0
30
0.000100000
FRACTION=
0.0
1.00000
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
BTU/HR
COMPONENT = CO2
STREAM
SUBSTREAM
96
MIXED
SPLIT FRACTION
1.00000
COMPONENT = CO
STREAM
SUBSTREAM
95
MIXED
SPLIT FRACTION
1.00000
COMPONENT = WATER
STREAM
SUBSTREAM
95
MIXED
SPLIT FRACTION
1.00000
COMPONENT = METHANOL
STREAM
SUBSTREAM
95
MIXED
SPLIT FRACTION
1.00000
COMPONENT = DME
STREAM
SUBSTREAM
95
MIXED
SPLIT FRACTION
1.00000
COMPONENT = METHANE
STREAM
SUBSTREAM
95
MIXED
SPLIT FRACTION
1.00000
-0.24399E-02
COMPONENT = NITRO-01
STREAM
SUBSTREAM
96
MIXED
OUTLET STREAMS:
SPLIT FRACTION
1.00000
99
NRTL
***
BLOCK: B63
MODEL: HEATER
-----------------------------INLET STREAM:
1
OUTLET STREAM:
88
NRTL
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR

IN
1530.46
49269.4
-0.840951E+08
)
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
INPUT DATA
TWO
PHASE PQ FLASH
PRESSURE DROP
SPECIFIED HEAT DUTY
***
OUT
RELATIVE DIFF.
1530.46
49269.4
-0.899985E+08
0.00000
0.295354E-15
0.655940E-01
***
PSI
BTU/HR
*** RESULTS
OUTLET TEMPERATURE
F
OUTLET PRESSURE
PSIA
0.0
-5,903,360.
30
0.000100000
703.51
30.000
1.0000
0.0000

COMP
WATER
METHANOL
DME
METHY-01
METHY-02
N-PRO-01
N-BUT-01
METHY-03
3-MET-01
VALER-01
ETHANOL
CIS-C-01
METHY-05
DIETH-01
2-MET-01
METHY-06
DIETH-02
METHY-07
3-MET-02
TERT--01
ETHYLENE
CYCLO-01
PROPYLEN
ISOBUTAN
N-BUTANE
CIS-2-01
2-MET-02
1:2-B-01
1:3-B-01
F(I)
0.56578
0.11481E-04
0.86128E-09
0.13778E-08
0.88755E-09
0.10168E-02
0.14687E-03
0.80537E-05
0.29106E-04
0.14385E-04
0.17712E-04
0.42353E-04
0.96237E-03
0.61682E-03
0.27911E-06
0.18089E-02
0.61682E-03
0.18089E-02
0.10582E-03
0.27084E-05
0.54444E-01
0.16540E-04
0.12964
0.78076E-01
0.10878
0.25718E-01
0.26701E-01
0.31214E-05
0.36331E-02
BLOCK: B62
MODEL: SEP
--------------------------INLET STREAM:
87
X(I)
0.97460
0.27689E-05
0.41404E-10
0.15976E-09
0.13737E-11
0.17476E-04
0.56718E-05
0.23675E-06
0.44942E-04
0.33375E-06
0.29890E-05
0.58162E-04
0.16969E-04
0.15274E-04
0.39875E-07
0.49643E-04
0.15274E-04
0.49643E-04
0.13841E-05
0.17857E-06
0.34690E-03
0.70815E-06
0.37369E-02
0.62364E-02
0.11507E-01
0.29498E-02
0.39806E-06
0.43252E-06
0.33758E-03
Y(I)
0.56578
0.11481E-04
0.86128E-09
0.13778E-08
0.88755E-09
0.10168E-02
0.14687E-03
0.80537E-05
0.29106E-04
0.14385E-04
0.17712E-04
0.42353E-04
0.96237E-03
0.61682E-03
0.27911E-06
0.18089E-02
0.61682E-03
0.18089E-02
0.10582E-03
0.27084E-05
0.54444E-01
0.16540E-04
0.12964
0.78076E-01
0.10878
0.25718E-01
0.26701E-01
0.31214E-05
0.36331E-02
K(I)
110.62
631.91
284.93
155.73
4391.1
291.09
200.16
128.36
54.680
275.57
449.58
53.298
121.90
15.751
136.29
17.449
15.751
17.449
217.06
393.85
666.01
272.78
321.70
174.71
153.20
160.21
344.88
112.87
184.67

IN
7462.50
181820.
-0.655575E+09
***
INPUT DATA
***
OUT
RELATIVE DIFF.
7462.50
181820.
-0.655575E+09
0.00000
0.160069E-15
0.401182E-09
***

TWO
PHASE TP FLASH
PRESSURE DROP
PSI
0.0
30
0.000100000

TWO
PHASE TP FLASH
PRESSURE DROP
PSI
0.0
30
0.000100000
FRACTION OF FEED
SUBSTREAM= MIXED
STREAM= 100
***
100
CPT= H2
CO2
CO
WATER
METHANOL
DME
METHY-01
METHY-02
ACETA-01
N-PRO-01
ACROL-01
METHA-01
N-BUT-01
METHY-03
ACETONE
3-MET-01
1:1-D-01
VALER-01
METHY-04
ETHANOL
CIS-C-01
METHY-05
DIETH-01
2-MET-01
METHY-06
DIETH-02
METHY-07
3-MET-02
TERT--01
METHANE
ETHANE
ETHYLENE
PROPANE
CYCLO-01
PROPYLEN
ISOBUTAN
N-BUTANE
TRANS-BU
1-BUTENE
ISOBUTEN
CIS-2-01
2-MET-02
1:2-B-01
FRACTION=
0.0
1.00000
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
1:3-B-01
N-PENTAN
N-HEXANE
N-HEPTAN
BENZENE
TOLUENE
N-OCT-01
NITRO-01
***
HEAT DUTY
RESULTS
0.0
0.0
0.0
0.0
0.0
0.0
0.0
1.00000
***
BTU/HR
COMPONENT = CO2
STREAM
SUBSTREAM
100
MIXED
SPLIT FRACTION
1.00000
COMPONENT = CO
STREAM
SUBSTREAM
99
MIXED
SPLIT FRACTION
1.00000
COMPONENT = WATER
STREAM
SUBSTREAM
99
MIXED
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
99
MIXED
SPLIT FRACTION
1.00000
COMPONENT = DME
STREAM
SUBSTREAM
99
MIXED
SPLIT FRACTION
1.00000
COMPONENT = METHY-01
STREAM
SUBSTREAM
99
MIXED
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
99
MIXED
SPLIT FRACTION
1.00000
COMPONENT = N-PRO-01
STREAM
SUBSTREAM
99
MIXED
SPLIT FRACTION
1.00000
COMPONENT = METHA-01
STREAM
SUBSTREAM
99
MIXED
SPLIT FRACTION
1.00000
COMPONENT = N-BUT-01
STREAM
SUBSTREAM
99
MIXED
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
99
MIXED
SPLIT FRACTION
1.00000
COMPONENT = 3-MET-01
STREAM
SUBSTREAM
99
MIXED
SPLIT FRACTION
1.00000
COMPONENT = 1:1-D-01
STREAM
SUBSTREAM
99
MIXED
SPLIT FRACTION
1.00000
COMPONENT = VALER-01
STREAM
SUBSTREAM
99
MIXED
SPLIT FRACTION
1.00000
-0.26300
COMPONENT = ETHANOL
STREAM
SUBSTREAM
99
MIXED
SPLIT FRACTION
1.00000
COMPONENT = CIS-C-01
STREAM
SUBSTREAM
99
MIXED
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
99
MIXED
SPLIT FRACTION
1.00000
COMPONENT = DIETH-01
STREAM
SUBSTREAM
99
MIXED
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
99
MIXED
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
99
MIXED
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
99
MIXED
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
99
MIXED
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
99
MIXED
SPLIT FRACTION
1.00000
COMPONENT = TERT--01
STREAM
SUBSTREAM
99
MIXED
SPLIT FRACTION
1.00000
COMPONENT = METHANE
STREAM
SUBSTREAM
99
MIXED
SPLIT FRACTION
1.00000
COMPONENT = ETHYLENE
STREAM
SUBSTREAM
99
MIXED
SPLIT FRACTION
1.00000
COMPONENT = CYCLO-01
STREAM
SUBSTREAM
99
MIXED
SPLIT FRACTION
1.00000
COMPONENT = PROPYLEN
STREAM
SUBSTREAM
99
MIXED
SPLIT FRACTION
1.00000
COMPONENT = ISOBUTAN
STREAM
SUBSTREAM
99
MIXED
SPLIT FRACTION
1.00000
COMPONENT = N-BUTANE
STREAM
SUBSTREAM
99
MIXED
SPLIT FRACTION
1.00000
COMPONENT = TRANS-BU
STREAM
SUBSTREAM
99
MIXED
SPLIT FRACTION
1.00000
COMPONENT = 1-BUTENE
STREAM
SUBSTREAM
SPLIT FRACTION
99
MIXED
1.00000
***
COMPONENT = ISOBUTEN
STREAM
SUBSTREAM
99
MIXED
SPLIT FRACTION
1.00000
COMPONENT = CIS-2-01
STREAM
SUBSTREAM
99
MIXED
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
SPLIT FRACTION
1.00000
COMPONENT = 1:2-B-01
STREAM
SUBSTREAM
99
MIXED
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
99
MIXED
SPLIT FRACTION
1.00000
COMPONENT = N-PENTAN
STREAM
SUBSTREAM
99
MIXED
SPLIT FRACTION
1.00000
COMPONENT = N-HEXANE
STREAM
SUBSTREAM
99
MIXED
SPLIT FRACTION
1.00000
COMPONENT = N-HEPTAN
STREAM
SUBSTREAM
99
MIXED
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
100
MIXED
SPLIT FRACTION
1.00000
1530.46
49269.4
-0.840951E+08
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
99
MIXED

IN
***
INPUT DATA
TWO
PHASE PQ FLASH
PRESSURE DROP
SPECIFIED HEAT DUTY
***
OUT
RELATIVE DIFF.
1530.46
49269.4
-0.899985E+08
0.00000
0.295354E-15
0.655940E-01
***
PSI
BTU/HR
*** RESULTS
OUTLET TEMPERATURE
F
OUTLET PRESSURE
PSIA
0.0
-5,903,360.
30
0.000100000
***
703.51
30.000
1.0000
0.0000
BLOCK: B64
MODEL: VALVE
----------------------------INLET STREAM:
104
OUTLET STREAM:
106
NRTL
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR

IN
839.873
35709.6
-0.582544E+08
)
***

INPUT DATA
***
0.00000
0.00000
0.00000
360.000
NO
RESULTS
PSI
RELATIVE DIFF.
839.873
35709.6
-0.582544E+08
***
PSIA
NPHASE
VALVE PRESSURE DROP
***
OUT
2
30
0.000100000
***
COMP
WATER
METHANOL
DME
METHY-01
METHY-02
N-PRO-01
N-BUT-01
METHY-03
3-MET-01
VALER-01
ETHANOL
CIS-C-01
METHY-05
DIETH-01
2-MET-01
METHY-06
DIETH-02
METHY-07
3-MET-02
TERT--01
ETHYLENE
CYCLO-01
PROPYLEN
ISOBUTAN
N-BUTANE
CIS-2-01
2-MET-02
1:2-B-01
1:3-B-01
F(I)
0.56578
0.11481E-04
0.86128E-09
0.13778E-08
0.88755E-09
0.10168E-02
0.14687E-03
0.80537E-05
0.29106E-04
0.14385E-04
0.17712E-04
0.42353E-04
0.96237E-03
0.61682E-03
0.27911E-06
0.18089E-02
0.61682E-03
0.18089E-02
0.10582E-03
0.27084E-05
0.54444E-01
0.16540E-04
0.12964
0.78076E-01
0.10878
0.25718E-01
0.26701E-01
0.31214E-05
0.36331E-02
BLOCK: B66
MODEL: SEP
--------------------------INLET STREAM:
107
OUTLET STREAMS:
108
NRTL
Y(I)
0.56578
0.11481E-04
0.86128E-09
0.13778E-08
0.88755E-09
0.10168E-02
0.14687E-03
0.80537E-05
0.29106E-04
0.14385E-04
0.17712E-04
0.42353E-04
0.96237E-03
0.61682E-03
0.27911E-06
0.18089E-02
0.61682E-03
0.18089E-02
0.10582E-03
0.27084E-05
0.54444E-01
0.16540E-04
0.12964
0.78076E-01
0.10878
0.25718E-01
0.26701E-01
0.31214E-05
0.36331E-02
K(I)
110.62
631.91
284.93
155.73
4391.1
291.09
200.16
128.36
54.680
275.57
449.58
53.298
121.90
15.751
136.29
17.449
15.751
17.449
217.06
393.85
666.01
272.78
321.70
174.71
153.20
160.21
344.88
112.87
184.67
111
95.0000
***
BLOCK: B65
MODEL: HEATER
-----------------------------INLET STREAM:
119
OUTLET STREAM:
89
NRTL
X(I)
0.97460
0.27689E-05
0.41404E-10
0.15976E-09
0.13737E-11
0.17476E-04
0.56718E-05
0.23675E-06
0.44942E-04
0.33375E-06
0.29890E-05
0.58162E-04
0.16969E-04
0.15274E-04
0.39875E-07
0.49643E-04
0.15274E-04
0.49643E-04
0.13841E-05
0.17857E-06
0.34690E-03
0.70815E-06
0.37369E-02
0.62364E-02
0.11507E-01
0.29498E-02
0.39806E-06
0.43252E-06
0.33758E-03
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR

IN
6546.46
156313.
-0.591589E+09
***
OUT
6546.46
156313.
-0.591589E+09
RELATIVE DIFF.
-0.277858E-15
-0.186189E-15
0.109178E-09
***
***
INPUT DATA
HEAT DUTY
TWO
PHASE TP FLASH
PRESSURE DROP
PSI
0.0
30
0.000100000

TWO
PHASE TP FLASH
PRESSURE DROP
PSI
FRACTION OF FEED
SUBSTREAM= MIXED
STREAM= 111
CPT= H2
CO2
CO
WATER
METHANOL
DME
METHY-01
METHY-02
ACETA-01
N-PRO-01
ACROL-01
METHA-01
N-BUT-01
METHY-03
ACETONE
3-MET-01
1:1-D-01
VALER-01
METHY-04
ETHANOL
CIS-C-01
METHY-05
DIETH-01
2-MET-01
METHY-06
DIETH-02
METHY-07
3-MET-02
TERT--01
METHANE
ETHANE
ETHYLENE
PROPANE
CYCLO-01
PROPYLEN
ISOBUTAN
N-BUTANE
TRANS-BU
1-BUTENE
ISOBUTEN
CIS-2-01
2-MET-02
1:2-B-01
1:3-B-01
N-PENTAN
N-HEXANE
N-HEPTAN
BENZENE
TOLUENE
N-OCT-01
NITRO-01
RESULTS
***
***
0.0
30
0.000100000
FRACTION=
0.0
1.00000
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
1.00000
BTU/HR
COMPONENT = CO2
STREAM
SUBSTREAM
111
MIXED
SPLIT FRACTION
1.00000
COMPONENT = CO
STREAM
SUBSTREAM
108
MIXED
SPLIT FRACTION
1.00000
COMPONENT = WATER
STREAM
SUBSTREAM
108
MIXED
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
108
MIXED
SPLIT FRACTION
1.00000
COMPONENT = DME
STREAM
SUBSTREAM
108
MIXED
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
108
MIXED
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
108
MIXED
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
108
MIXED
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
108
MIXED
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
108
MIXED
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
108
MIXED
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
108
MIXED
SPLIT FRACTION
1.00000
COMPONENT = 1:1-D-01
STREAM
SUBSTREAM
108
MIXED
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
108
MIXED
SPLIT FRACTION
1.00000
COMPONENT = ETHANOL
STREAM
SUBSTREAM
108
MIXED
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
108
MIXED
SPLIT FRACTION
1.00000
-0.64588E-01
STREAM
108
SUBSTREAM
MIXED
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
108
MIXED
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
108
MIXED
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
108
MIXED
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
108
MIXED
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
108
MIXED
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
108
MIXED
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
108
MIXED
SPLIT FRACTION
1.00000
COMPONENT = METHANE
STREAM
SUBSTREAM
108
MIXED
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
108
MIXED
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
108
MIXED
STREAM
SUBSTREAM
108
MIXED
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
108
MIXED
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
108
MIXED
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
108
MIXED
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
108
MIXED
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
108
MIXED
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
111
MIXED
SPLIT FRACTION
1.00000
BLOCK: B67
MODEL: MIXER
----------------------------INLET STREAMS:
86
OUTLET STREAM:
107
NRTL
***
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
108
MIXED
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
108
MIXED
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
108
MIXED
SPLIT FRACTION
1.00000
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
STREAM
SUBSTREAM
108
MIXED
SPLIT FRACTION
1.00000
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
108
MIXED
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
108
MIXED
SPLIT FRACTION
1.00000

IN
6546.46
156313.
-0.591589E+09
***
OUT
BLOCK: B68
MODEL: RGIBBS
-----------------------------INLET STREAM:
108
OUTLET STREAM:
109
NRTL
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
0.00000
-0.186189E-15
-0.201507E-15
30
0.000100000

IN
OUT
6537.97
6854.09
155940.
155940.
-0.590206E+09 -0.590206E+09
***
RELATIVE DIFF.
6546.46
156313.
-0.591589E+09
*** INPUT DATA ***

TWO
PHASE
FLASH
***
STREAM
SUBSTREAM
108
MIXED
106
INPUT DATA
***
GENERATION
316.123
RELATIVE DIFF.
0.265387E-15
0.335943E-14
0.207674E-08
***
F
910.77
F
910.77
100.00
SPECIFIED DUTY
BTU/HR
0.0000

VAPOR FRACTION
1.0000
1
PHASE
OF TYPE
PHASE FRACTION
PLACED IN STREAM
METHANOL
DME
METHY-01
METHY-02
N-PRO-01
METHA-01
N-BUT-01
METHY-03
3-MET-01
1:1-D-01
VALER-01
ETHANOL
CIS-C-01
METHY-05
DIETH-01
2-MET-01
METHY-06
DIETH-02
METHY-07
3-MET-02
TERT--01
ETHYLENE
CYCLO-01
PROPYLEN
ISOBUTAN
N-BUTANE
TRANS-BU
1-BUTENE
ISOBUTEN
CIS-2-01
2-MET-02
1:2-B-01
1:3-B-01
N-PENTAN
N-HEXANE
N-HEPTAN
WATER

N-HEPTAN
ATOM MATRIX:
ELEMENT
H
H2
2.00
CO2
0.00
CO
0.00
WATER
2.00
METHANOL
4.00
DME
6.00
METHY-01
8.00
METHY-02 10.00
ACETA-01
4.00
N-PRO-01
6.00
ACROL-01
4.00
METHA-01
6.00
N-BUT-01
8.00
METHY-03
6.00
ACETONE
6.00
3-MET-01 10.00
1:1-D-01 10.00
VALER-01 10.00
METHY-04
8.00
ETHANOL
6.00
CIS-C-01
6.00
METHY-05 10.00
DIETH-01 10.00
2-MET-01 12.00
METHY-06 10.00
DIETH-02 10.00
METHY-07 10.00
3-MET-02 12.00
TERT--01 10.00
METHANE
4.00
ETHANE
6.00
ETHYLENE
4.00
PROPANE
8.00
CYCLO-01
6.00
PROPYLEN
6.00
ISOBUTAN 10.00
N-BUTANE 10.00
TRANS-BU
8.00
1-BUTENE
8.00
ISOBUTEN
8.00
CIS-2-01
8.00
2-MET-02 12.00
1:2-B-01
6.00
1:3-B-01
6.00
N-PENTAN 12.00
N-HEXANE 14.00
N-HEPTAN 16.00
BENZENE
6.00
TOLUENE
8.00
N-OCT-01 18.00
NITRO-01
0.00
TEMPERATURE
PRESSURE
C
0.00
1.00
1.00
0.00
1.00
2.00
3.00
4.00
2.00
3.00
3.00
4.00
4.00
3.00
3.00
5.00
4.00
5.00
4.00
2.00
4.00
5.00
5.00
5.00
5.00
5.00
5.00
6.00
4.00
1.00
2.00
2.00
3.00
3.00
3.00
4.00
4.00
4.00
4.00
4.00
4.00
5.00
4.00
4.00
5.00
6.00
7.00
6.00
7.00
8.00
0.00
N
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
2.00
***
F
PSIA
O
0.00
2.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
2.00
1.00
1.00
2.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
RESULTS
VAPOR
VAPOR
1.000000
109
0.2268107E-04
0.2042595E-08
0.3440165E-08
0.2291612E-08
0.2718524E-02
0.4953867E-02
0.4250976E-03
0.2959317E-03
0.8841575E-04
0.1816272E-14
0.4505898E-04
0.3654417E-04
0.1625687E-03
0.2706494E-02
0.1772739E-02
0.6755330E-06
0.5160540E-02
0.1772739E-02
0.5160540E-02
0.3239538E-03
0.5943488E-05
0.9484171E-02
0.3296142E-05
0.2359608E-01
0.1076406E-01
0.1537852E-01
0.6079665E-02
0.4434276E-02
0.1128020E-01
0.4935491E-02
0.4007620E-02
0.9556262E-06
0.9682737E-03
0.2614416E-02
0.3865263E-03
0.6205070E-04
0.8803521
LBMOL/HR
6854.092
BLOCK: B69
MODEL: MIXER
----------------------------INLET STREAMS:
68
OUTLET STREAM:
102
NRTL
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
96

IN
5018.65
98157.7
-0.467071E+09
***
OUT
5018.65
98157.7
-0.467071E+09
*** INPUT DATA ***

TWO
PHASE
FLASH
***
910.77
260.00
BLOCK: B70
MODEL: MIXER
-----------------------------
RELATIVE DIFF.
0.00000
0.296501E-15
-0.127614E-15
30
0.000100000
INLET STREAMS:
OUTLET STREAM:
85
103
NRTL
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
98
***

IN
5706.59
120604.
-0.517576E+09
***
OUT
*** INPUT DATA ***

TWO
PHASE
FLASH
BLOCK: B71
MODEL: HEATX
----------------------------HOT SIDE:
92
OUTLET STREAM:
101
NRTL
COLD SIDE:
135
OUTLET STREAM:
69
NRTL
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
***
69
T=
P=
V=
-------------------------------------|
|
----->|
HOT
|----->
8.4900D+02 |
|
1.7950D+03 |
|
1.0000D+00 |
|
|
|
<-----|
COLD
|<----7.0700D+02 |
|
4.6000D+02 |
|
1.0000D+00 |
|
--------------------------------------

UA (DIRTY)
INPUT DATA
***
OUT
RELATIVE DIFF.
6429.17
115823.
-0.641400E+09
0.00000
0.00000
0.275065E-07
***
PRESSURE DROP:
HOTSIDE, TOTAL
COLDSIDE, TOTAL
30
0.000100000

COUNTERCURRENT
HEAT EXCHANGER
SPECIFIED VALUE
F
PSI
PSI

HOT LIQUID
COLD LIQUID
BTU/HR-SQFT-R
HOT 2-PHASE
COLD LIQUID
BTU/HR-SQFT-R
HOT VAPOR
COLD LIQUID
BTU/HR-SQFT-R
HOT LIQUID
COLD 2-PHASE
BTU/HR-SQFT-R
HOT 2-PHASE
COLD 2-PHASE
BTU/HR-SQFT-R
HOT VAPOR
COLD 2-PHASE
BTU/HR-SQFT-R
HOT LIQUID
COLD VAPOR
BTU/HR-SQFT-R
HOT 2-PHASE
COLD VAPOR
BTU/HR-SQFT-R
HOT VAPOR
COLD VAPOR
BTU/HR-SQFT-R
707.0000
1.00000
5.0000
5.0000
BTU/HR-SQFT-R
BTU/HR-R
135
T= 4.5976D+02
P= 4.6500D+02
V= 1.0000D+00
149.6937
150210.3782
1.0000
62.8704
1
5.0000
5.0000

HOT SIDE:
COLD SIDE:
77118.
4064.0
ZONE RESULTS
***

HOT
------------------------------------------------------------|
|
|
92
|
VAP
|
COND
| 101
------> |
|
|------>
849.0 |
620.3|
| 620.1
|
|
|
69
|
VAP
|
VAP
| 135
<------ |
|
|<-----707.0 |
602.3|
| 459.8
|
|
|
------------------------------------------------------------COLD
ZONE
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
101
T= 6.2009D+02
P= 1.7900D+03
V= 7.0293D-01
9443788.5304
1003.4519
1003.4519
0.0000
PSI
PSI
***
30
0.000100000

TWO
PHASE
FLASH
BTU/HR
SQFT
SQFT

LMTD (CORRECTED)
F

TWO
PHASE
FLASH
30
0.000100000
6429.17
115823.
-0.641400E+09
0.00000
0.482636E-15
-0.230322E-15
92
T=
P=
V=
DUTY AND AREA:


IN
***
STREAMS:
RELATIVE DIFF.
5706.59
120604.
-0.517576E+09
OVERALL RESULTS
1
2
HEAT DUTY
BTU/HR
4050249.758
5393538.773
AREA
SQFT
450.2970
553.1549
BLOCK: B72
MODEL: MIXER
----------------------------INLET STREAMS:
111
OUTLET STREAM:
112
NRTL
LMTD
F
60.0868
65.1364
AVERAGE U
BTU/HR-SQFT-R
149.6937
149.6937
109
UA
BTU/HR-R
67406.6018
82803.7764
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR

IN
6862.59
156313.
-0.591589E+09
***
OUT
RELATIVE DIFF.
6862.59
156313.
-0.591589E+09
0.00000
0.372378E-15
0.00000
*** INPUT DATA ***

TWO
PHASE
FLASH
DUTY AND AREA:

BLOCK: B73
MODEL: HEATX
----------------------------HOT SIDE:
126
OUTLET STREAM:
134
NRTL
COLD SIDE:
56
OUTLET STREAM:
113
NRTL
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
INPUT DATA
***
OUT
RELATIVE DIFF.
4956.50
89292.7
-0.569599E+09
0.00000
0.00000
0.209286E-15
***

TWO
PHASE
FLASH
30
0.000100000
30
0.000100000

COUNTERCURRENT
HEAT EXCHANGER
SPECIFIED HOT VAPOR FRACTION
SPECIFIED VALUE
0.0000
1.00000
PSI
PSI
5.0000
5.0000

HOT LIQUID
COLD LIQUID
BTU/HR-SQFT-R
HOT 2-PHASE
COLD LIQUID
BTU/HR-SQFT-R
HOT VAPOR
COLD LIQUID
BTU/HR-SQFT-R
HOT LIQUID
COLD 2-PHASE
BTU/HR-SQFT-R
HOT 2-PHASE
COLD 2-PHASE
BTU/HR-SQFT-R
HOT VAPOR
COLD 2-PHASE
BTU/HR-SQFT-R
HOT LIQUID
COLD VAPOR
BTU/HR-SQFT-R
HOT 2-PHASE
COLD VAPOR
BTU/HR-SQFT-R
HOT VAPOR
COLD VAPOR
BTU/HR-SQFT-R
***
PRESSURE DROP:
HOTSIDE, TOTAL
COLDSIDE, TOTAL
OVERALL RESULTS
***
STREAMS:
--------------------------------------
BTU/HR-SQFT-R
BTU/HR-R
56
T=
P=
V=
3.8573D+02
4.7500D+02
0.0000D+00
149.6937
384214.6444
1.0000
19.1825
1
5.0000
5.0000

HOT SIDE:
COLD SIDE:
0.59033E+06
0.26729E+06
ZONE RESULTS
***

HOT
------------------------------------------------------------|
|
126
|
COND
| 134
------> |
|------>
450.0 |
| 448.8
|
|
113
|
LIQ
| 56
<------ |
|<-----447.3 |
| 385.7
|
|
------------------------------------------------------------COLD
ZONE
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
134
T= 4.4882D+02
P= 4.1679D+02
V= 0.0000D+00
7370181.3675
2566.6729
2566.6729
0.0000
PSI
PSI
***

TWO
PHASE
FLASH
BTU/HR
SQFT
SQFT

LMTD (CORRECTED)
F
4956.50
89292.7
-0.569599E+09
***

UA (DIRTY)

IN
30
0.000100000
|
|
126
----->|
HOT
|----->
T= 4.5000D+02 |
|
P= 4.2179D+02 |
|
V= 1.0000D+00 |
|
|
|
113
<-----|
COLD
|<----T= 4.4729D+02 |
|
P= 4.7000D+02 |
|
V= 0.0000D+00 |
|
--------------------------------------
HEAT DUTY
BTU/HR
7370181.367
AREA
SQFT
2566.6729
BLOCK: B74
MODEL: HEATX
----------------------------HOT SIDE:
136
OUTLET STREAM:
137
NRTL
COLD SIDE:
113
OUTLET STREAM:
135
LMTD
F
19.1825
AVERAGE U
UA
BTU/HR-SQFT-R
BTU/HR-R
149.6937
384214.6444
NRTL
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR

IN
9429.17
169869.
-0.101057E+10
)
***
INPUT DATA
***
OUT
RELATIVE DIFF.
9429.17
169869.
-0.101057E+10
0.00000
0.00000
0.00000
***

TWO
PHASE
FLASH
30
0.000100000

COUNTERCURRENT
HEAT EXCHANGER
SPECIFIED VALUE
1.0000
1.00000
PSI
PSI
5.0000
5.0000

HOT LIQUID
COLD LIQUID
BTU/HR-SQFT-R
HOT 2-PHASE
COLD LIQUID
BTU/HR-SQFT-R
HOT VAPOR
COLD LIQUID
BTU/HR-SQFT-R
HOT LIQUID
COLD 2-PHASE
BTU/HR-SQFT-R
HOT 2-PHASE
COLD 2-PHASE
BTU/HR-SQFT-R
HOT VAPOR
COLD 2-PHASE
BTU/HR-SQFT-R
HOT LIQUID
COLD VAPOR
BTU/HR-SQFT-R
HOT 2-PHASE
COLD VAPOR
BTU/HR-SQFT-R
HOT VAPOR
COLD VAPOR
BTU/HR-SQFT-R
OVERALL RESULTS
PSI
PSI
DUTY AND AREA:

UA (DIRTY)
BTU/HR
SQFT
SQFT
BTU/HR-SQFT-R
BTU/HR-R
137
T= 5.1522D+02
P= 8.0681D+02
V= 0.0000D+00
11562.
9114.2
ZONE RESULTS
1
2
HEAT DUTY
BTU/HR
61767943.735
695992.603
AREA
SQFT
6513.1212
69.1349
BLOCK: B75
MODEL: FSPLIT
-----------------------------INLET STREAM:
23
OUTLET STREAMS:
30
NRTL
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
INPUT DATA
***
STREAM= 30
117
61
1.0000
RESULTS
SPLIT=
BLOCK: B77
MODEL: VALVE
----------------------------INLET STREAM:
117
OUTLET STREAM:
118
NRTL
***
TOTAL BALANCE
MOLE(LBMOL/HR)
***
OUT
RELATIVE DIFF.
4125.59
149301.
-0.272723E+09
0.00000
0.194934E-15
0.00000
***
STRM=30
STRM=117
113
T= 4.4729D+02
P= 4.7000D+02
V= 0.0000D+00
AVERAGE U
UA
BTU/HR-SQFT-R
BTU/HR-R
149.6937
974972.9293
149.6937
10349.0508
117
61
4125.59
149301.
-0.272723E+09
***
149.6937
985321.9801
LMTD
F
63.3535
67.2518

IN
FRACTION OF FLOW
62463936.3386
6582.2561
6582.2561
0.0000
***
HOT
------------------------------------------------------------|
|
|
136
|
COND
|
LIQ
| 137
------> |
|
|------>
520.0 |
519.3|
| 515.2
|
|
|
135
|
BOIL
|
BOIL
| 113
<------ |
|
|<-----459.8 |
452.7|
| 447.3
|
|
|
------------------------------------------------------------COLD
***
-------------------------------------|
|
136
----->|
HOT
|----->
T= 5.2000D+02 |
|
P= 8.1181D+02 |
|
V= 1.0000D+00 |
|
|
|
135
<-----|
COLD
|<----T= 4.5976D+02 |
|
P= 4.6500D+02 |
|
V= 1.0000D+00 |
|
--------------------------------------
5.0000
5.0000
***
STREAMS:
63.3944
1

HOT SIDE:
COLD SIDE:
ZONE
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
PRESSURE DROP:
HOTSIDE, TOTAL
COLDSIDE, TOTAL
***
30
0.000100000

TWO
PHASE
FLASH
***
LMTD (CORRECTED)
FRAC=
FRAC=
0.33000
0.33000
***
0.33000
0.33000
0.34000
KEY=
0
0
0
STREAM-ORDER=

IN
1361.45
***
OUT
1361.45
RELATIVE DIFF.
0.00000
1
2
3
MASS(LB/HR
)
ENTHALPY(BTU/HR
49269.4
-0.899985E+08
)
***
VALVE PRESSURE DROP

INPUT DATA
49269.4
-0.899985E+08
***
PSI
25.0000
NO
NPHASE
***
RESULTS
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
65.0000

IN
OUT
1361.45
1530.46
49269.4
49269.4
-0.899985E+08 -0.840951E+08
***
2
30
0.000100000
***
PSIA
BLOCK: B78
MODEL: RGIBBS
-----------------------------INLET STREAM:
118
OUTLET STREAM:
119
NRTL
0.147677E-15
-0.331142E-15
INPUT DATA
***
GENERATION
RELATIVE DIFF.
169.015
-0.297131E-15
-0.295354E-14
-0.655940E-01
***
SYSTEM TEMPERATURE
F
887.00
F
887.00
35.000
ETHANOL
CIS-C-01
METHY-05
DIETH-01
2-MET-01
METHY-06
DIETH-02
METHY-07
3-MET-02
TERT--01
METHANE
ETHANE
ETHYLENE
PROPANE
CYCLO-01
PROPYLEN
ISOBUTAN
N-BUTANE
TRANS-BU
1-BUTENE
ISOBUTEN
CIS-2-01
2-MET-02
1:2-B-01
1:3-B-01
N-PENTAN
N-HEXANE
N-HEPTAN
BENZENE
TOLUENE
N-OCT-01
NITRO-01
6.00
6.00
10.00
10.00
12.00
10.00
10.00
10.00
12.00
10.00
4.00
6.00
4.00
8.00
6.00
6.00
10.00
10.00
8.00
8.00
8.00
8.00
12.00
6.00
6.00
12.00
14.00
16.00
6.00
8.00
18.00
0.00
2.00
4.00
5.00
5.00
5.00
5.00
5.00
5.00
6.00
4.00
1.00
2.00
2.00
3.00
3.00
3.00
4.00
4.00
4.00
4.00
4.00
4.00
5.00
4.00
4.00
5.00
6.00
7.00
6.00
7.00
8.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
2.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
*** RESULTS
TEMPERATURE
F
PRESSURE
PSIA
HEAT DUTY
BTU/HR
VAPOR FRACTION

1:3-B-01
ATOM MATRIX:
ELEMENT
H
H2
2.00
CO2
0.00
CO
0.00
WATER
2.00
METHANOL
4.00
DME
6.00
METHY-01
8.00
METHY-02 10.00
ACETA-01
4.00
N-PRO-01
6.00
ACROL-01
4.00
METHA-01
6.00
N-BUT-01
8.00
METHY-03
6.00
ACETONE
6.00
3-MET-01 10.00
1:1-D-01 10.00
VALER-01 10.00
METHY-04
8.00
C
0.00
1.00
1.00
0.00
1.00
2.00
3.00
4.00
2.00
3.00
3.00
4.00
4.00
3.00
3.00
5.00
4.00
5.00
4.00
N
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
O
0.00
2.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
1.00
2.00
1.00
1.00
2.00
1.00
1.00
PHASE
OF TYPE
PHASE FRACTION
PLACED IN STREAM
WATER
METHANOL
DME
METHY-01
METHY-02
N-PRO-01
N-BUT-01
METHY-03
3-MET-01
1:1-D-01
VALER-01
ETHANOL
CIS-C-01
METHY-05
DIETH-01
2-MET-01
METHY-06
DIETH-02
METHY-07
3-MET-02
TERT--01
ETHYLENE
CYCLO-01
PROPYLEN
VAPOR
VAPOR
1.000000
119
0.5657823
0.1148136E-04
0.8612849E-09
0.1377762E-08
0.8875514E-09
0.1016810E-02
0.1468740E-03
0.8053657E-05
0.2910624E-04
0.3979346E-16
0.1438500E-04
0.1771165E-04
0.4235348E-04
0.9623707E-03
0.6168212E-03
0.2791097E-06
0.1808873E-02
0.6168212E-03
0.1808873E-02
0.1058155E-03
0.2708356E-05
0.5444425E-01
0.1654046E-04
0.1296382
***
887.00
30.000
0.59034E+07
1.0000
1
ISOBUTAN
N-BUTANE
CIS-2-01
2-MET-02
1:2-B-01
1:3-B-01
0.7807622E-01
0.1087778
0.2571841E-01
0.2670067E-01
0.3121407E-05
0.3633071E-02
LBMOL/HR
1530.460
BLOCK: B79
MODEL: MIXER
----------------------------INLET STREAMS:
88
OUTLET STREAM:
120
NRTL
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR

HOT LIQUID
COLD LIQUID
BTU/HR-SQFT-R
HOT 2-PHASE
COLD LIQUID
BTU/HR-SQFT-R
HOT VAPOR
COLD LIQUID
BTU/HR-SQFT-R
HOT LIQUID
COLD 2-PHASE
BTU/HR-SQFT-R
HOT 2-PHASE
COLD 2-PHASE
BTU/HR-SQFT-R
HOT VAPOR
COLD 2-PHASE
BTU/HR-SQFT-R
HOT LIQUID
COLD VAPOR
BTU/HR-SQFT-R
HOT 2-PHASE
COLD VAPOR
BTU/HR-SQFT-R
HOT VAPOR
COLD VAPOR
BTU/HR-SQFT-R
89
65

IN
4637.76
149301.
-0.272544E+09
)
***
***
INPUT DATA
***
OUT
BLOCK: B80
MODEL: HEATX
----------------------------HOT SIDE:
102
OUTLET STREAM:
105
NRTL
COLD SIDE:
114
OUTLET STREAM:
127
NRTL
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
INPUT DATA
***
OUT
RELATIVE DIFF.
6168.65
118875.
-0.592983E+09
0.00000
0.00000
-0.201033E-15
***
PRESSURE DROP:
HOTSIDE, TOTAL
COLDSIDE, TOTAL
30
0.000100000

COUNTERCURRENT
HEAT EXCHANGER
SPECIFIED VALUE
F
PSI
PSI
650.0000
1.00000
5.0000
5.0000
105
T= 6.5000D+02
P= 4.1500D+02
V= 1.0000D+00
114
T= 6.0000D+02
P= 1.8000D+03
V= 0.0000D+00
13887752.0806
793.7678
793.7678
0.0000
BTU/HR-SQFT-R
BTU/HR-R
149.6937
118822.0111
1.0000
116.8786
1
PSI
PSI
5.0000
5.0000

HOT SIDE:
COLD SIDE:
***
30
0.000100000

TWO
PHASE
FLASH
BTU/HR
SQFT
SQFT

LMTD (CORRECTED)
F

TWO
PHASE
FLASH

UA (DIRTY)
6168.65
118875.
-0.592983E+09
***
30
0.000100000
-------------------------------------|
|
102
----->|
HOT
|----->
T= 9.2375D+02 |
|
P= 4.2000D+02 |
|
V= 1.0000D+00 |
|
|
|
127
<-----|
COLD
|<----T= 8.5010D+02 |
|
P= 1.7950D+03 |
|
V= 1.0000D+00 |
|
-------------------------------------DUTY AND AREA:

IN
0.776582E-13
0.923986E-13
-0.126407E-12
***
TWO
PHASE
FLASH
***
STREAMS:
RELATIVE DIFF.
4637.76
149301.
-0.272544E+09
OVERALL RESULTS
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
2205.1
0.35193E+06
ZONE RESULTS
***

HOT
------------------------------------------------------------|
|
|
|
102
|
VAP
|
VAP
|
VAP
| 105
------> |
|
|
|------>
923.7 |
878.8|
673.5|
| 650.0
|
|
|
|
127
|
VAP
|
BOIL
|
LIQ
| 114
<------ |
|
|
|<-----850.1 |
620.5|
620.8|
| 600.0
|
|
|
|
------------------------------------------------------------COLD
ZONE
1
2
3
HEAT DUTY
BTU/HR
2338006.647
10393300.664
1156444.770
AREA
SQFT
106.1417
537.0496
150.5765
BLOCK: B81
MODEL: HEATX
----------------------------HOT SIDE:
103
OUTLET STREAM:
86
NRTL
COLD SIDE:
128
OUTLET STREAM:
129
NRTL
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
LMTD
F
147.1486
129.2813
51.3055
INPUT DATA
***
OUT
RELATIVE DIFF.
7006.59
144024.
-0.659911E+09
0.00000
0.00000
0.00000
***
|
|
|
|
|
|
--------------------------------------
PRESSURE DROP:
HOTSIDE, TOTAL
COLDSIDE, TOTAL
30
0.000100000
30
0.000100000

COUNTERCURRENT
HEAT EXCHANGER
SPECIFIED VALUE
F
650.0000
1.00000
PSI
PSI
5.0000
5.0000

HOT LIQUID
COLD LIQUID
BTU/HR-SQFT-R
HOT 2-PHASE
COLD LIQUID
BTU/HR-SQFT-R
HOT VAPOR
COLD LIQUID
BTU/HR-SQFT-R
HOT LIQUID
COLD 2-PHASE
BTU/HR-SQFT-R
HOT 2-PHASE
COLD 2-PHASE
BTU/HR-SQFT-R
HOT VAPOR
COLD 2-PHASE
BTU/HR-SQFT-R
HOT LIQUID
COLD VAPOR
BTU/HR-SQFT-R
HOT 2-PHASE
COLD VAPOR
BTU/HR-SQFT-R
HOT VAPOR
COLD VAPOR
BTU/HR-SQFT-R
OVERALL RESULTS
BTU/HR
SQFT
SQFT
15758683.4991
995.4928
995.4928
0.0000
BTU/HR-SQFT-R
BTU/HR-R
149.6937
149018.9551
5.0000
5.0000
1405.2
0.27440E+06
ZONE RESULTS
***

HOT
------------------------------------------------------------|
|
|
|
103
|
VAP
|
VAP
|
VAP
| 86
------> |
|
|
|------>
895.6 |
854.6|
671.0|
| 650.0
|
|
|
|
129
|
VAP
|
BOIL
|
LIQ
| 128
<------ |
|
|
|<-----855.2 |
620.5|
620.8|
| 600.0
|
|
|
|
------------------------------------------------------------COLD
1
2
3
HEAT DUTY
BTU/HR
2702435.840
11748954.216
1307293.443
AREA
SQFT
163.7472
657.3891
174.3565
BLOCK: B82
MODEL: FLASH2
-----------------------------INLET STREAM:
121
122
NRTL
***
STREAMS:
***
6.5000D+02
3.6500D+02
1.0000D+00
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
TWO
PHASE
PQ
AVERAGE U
BTU/HR-SQFT-R
149.6937
149.6937
149.6937
UA
BTU/HR-R
24511.9162
98406.9811
26100.0578
3384.42
166636.
-0.118230E+09
FLASH
LMTD
F
110.2499
119.3915
50.0878

IN
***
128
1.0000
105.7495
1

HOT SIDE:
COLD SIDE:
ZONE
86
T=
P=
V=
6.0000D+02
1.8000D+03
0.0000D+00
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
-------------------------------------|
|
103
----->|
HOT
|----->
T= 8.9558D+02 |
|
P= 3.7000D+02 |
|
V= 1.0000D+00 |
|
|
|
129
<-----|
COLD
|<-----
T=
P=
V=
PSI
PSI
***

TWO
PHASE
FLASH
***
8.5516D+02
1.7950D+03
1.0000D+00

LMTD (CORRECTED)
F

TWO
PHASE
FLASH
T=
P=
V=

UA (DIRTY)
7006.59
144024.
-0.659911E+09
***
UA
BTU/HR-R
15888.7441
80392.9216
22540.3454
DUTY AND AREA:


IN
AVERAGE U
BTU/HR-SQFT-R
149.6937
149.6937
149.6937
INPUT DATA
***
***
OUT
3384.42
166636.
-0.118230E+09
RELATIVE DIFF.
-0.134365E-15
0.174655E-15
0.623659E-06
PRESSURE DROP
PSI
SPECIFIED HEAT DUTY
BTU/HR
***
F
PSIA
OUTLET TEMPERATURE
OUTLET PRESSURE
VAPOR FRACTION
0.0
0.0
30
0.000100000
RESULTS
***
110.00
60.000
0.66928
*** INPUT DATA

TWO
PHASE PQ FLASH
PRESSURE DROP
PSI
SPECIFIED HEAT DUTY
BTU/HR
OUTLET TEMPERATURE
OUTLET PRESSURE
VAPOR FRACTION
***
F
PSIA
RESULTS
***
0.0
0.0
30
0.000100000
***
110.00
145.00
0.59611

COMP
CO2
WATER
METHANOL
DME
METHY-01
METHY-02
N-PRO-01
METHA-01
N-BUT-01
METHY-03
3-MET-01
VALER-01
ETHANOL
CIS-C-01
METHY-05
DIETH-01
2-MET-01
METHY-06
DIETH-02
METHY-07
3-MET-02
TERT--01
METHANE
ETHYLENE
CYCLO-01
PROPYLEN
ISOBUTAN
N-BUTANE
TRANS-BU
1-BUTENE
ISOBUTEN
CIS-2-01
2-MET-02
1:2-B-01
1:3-B-01
N-PENTAN
N-HEXANE
N-HEPTAN
BENZENE
NITRO-01
F(I)
0.33409E-02
0.82028E-01
0.32932E-04
0.19639E-08
0.31875E-08
0.21603E-08
0.63509E-02
0.32979E-02
0.85906E-03
0.45339E-03
0.93434E-05
0.78967E-04
0.53984E-04
0.29194E-04
0.76792E-02
0.45515E-02
0.89948E-06
0.13702E-01
0.45515E-02
0.13702E-01
0.77153E-03
0.96265E-05
0.27023E-02
0.10329
0.29067E-04
0.29397
0.13581
0.17226
0.38579E-02
0.47799E-02
0.16731E-01
0.50461E-01
0.45433E-01
0.58950E-05
0.85181E-02
0.85756E-02
0.12730E-02
0.10619E-01
0.17653E-03
0.57800E-05
BLOCK: B83
MODEL: FLASH2
-----------------------------INLET STREAM:
11
124
NRTL
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
X(I)
0.25228E-03
0.23033
0.71243E-04
0.11972E-08
0.39609E-08
0.26197E-08
0.12361E-01
0.84958E-02
0.21384E-02
0.99961E-03
0.26518E-04
0.21343E-03
0.14149E-03
0.82061E-04
0.20637E-01
0.12565E-01
0.26038E-05
0.38200E-01
0.12565E-01
0.38200E-01
0.22237E-02
0.26515E-04
0.43893E-04
0.76828E-02
0.15445E-04
0.10730
0.12237
0.19399
0.44265E-02
0.46888E-02
0.16474E-01
0.60635E-01
0.50745E-01
0.80527E-05
0.86722E-02
0.12219E-01
0.26835E-02
0.28028E-01
0.47951E-03
0.37648E-07
Y(I)
0.48672E-02
0.87449E-02
0.14001E-04
0.23427E-08
0.28054E-08
0.19332E-08
0.33811E-02
0.72929E-03
0.22689E-03
0.18347E-03
0.85663E-06
0.12522E-04
0.10742E-04
0.30698E-05
0.12759E-02
0.59171E-03
0.57265E-07
0.15958E-02
0.59171E-03
0.15958E-02
0.53930E-04
0.12808E-05
0.40159E-02
0.15054
0.35798E-04
0.38621
0.14245
0.16152
0.35769E-02
0.48250E-02
0.16858E-01
0.45434E-01
0.42808E-01
0.48288E-05
0.84420E-02
0.67752E-02
0.57606E-03
0.20160E-02
0.26812E-04
0.86176E-05
K(I)
19.292
0.37966E-01
0.19651
1.9568
0.70826
0.73797
0.27353
0.85839E-01
0.10610
0.18354
0.32303E-01
0.58670E-01
0.75919E-01
0.37407E-01
0.61821E-01
0.47092E-01
0.21992E-01
0.41775E-01
0.47092E-01
0.41775E-01
0.24251E-01
0.48302E-01
91.495
19.595
2.3178
3.5992
1.1641
0.83258
0.80807
1.0290
1.0233
0.74930
0.84360
0.59964
0.97345
0.55449
0.21467
0.71924E-01
0.55914E-01
228.91

IN
2265.11
107836.
-0.431341E+08
***
OUT
2265.11
107836.
-0.431341E+08
RELATIVE DIFF.
0.401523E-15
0.674727E-15
-0.206768E-06

COMP
CO2
WATER
METHANOL
DME
METHY-01
METHY-02
N-PRO-01
METHA-01
N-BUT-01
METHY-03
3-MET-01
VALER-01
ETHANOL
CIS-C-01
METHY-05
DIETH-01
2-MET-01
METHY-06
DIETH-02
METHY-07
3-MET-02
TERT--01
METHANE
ETHYLENE
CYCLO-01
PROPYLEN
ISOBUTAN
N-BUTANE
TRANS-BU
1-BUTENE
ISOBUTEN
CIS-2-01
2-MET-02
1:2-B-01
1:3-B-01
N-PENTAN
N-HEXANE
N-HEPTAN
BENZENE
NITRO-01
F(I)
0.48672E-02
0.87449E-02
0.14001E-04
0.23427E-08
0.28054E-08
0.19332E-08
0.33811E-02
0.72929E-03
0.22689E-03
0.18347E-03
0.85663E-06
0.12522E-04
0.10742E-04
0.30698E-05
0.12759E-02
0.59171E-03
0.57265E-07
0.15958E-02
0.59171E-03
0.15958E-02
0.53930E-04
0.12808E-05
0.40159E-02
0.15054
0.35798E-04
0.38621
0.14245
0.16152
0.35769E-02
0.48250E-02
0.16858E-01
0.45434E-01
0.42808E-01
0.48288E-05
0.84420E-02
0.67752E-02
0.57606E-03
0.20160E-02
0.26812E-04
0.86176E-05
BLOCK: B84
MODEL: HEATX
----------------------------HOT SIDE:
112
OUTLET STREAM:
110
NRTL
COLD SIDE:
130
OUTLET STREAM:
131
NRTL
X(I)
0.80204E-03
0.21246E-01
0.27593E-04
0.23944E-08
0.45851E-08
0.38458E-08
0.73929E-02
0.16996E-02
0.53495E-03
0.41526E-03
0.20723E-05
0.30460E-04
0.25652E-04
0.73994E-05
0.30782E-02
0.14386E-02
0.14028E-06
0.38823E-02
0.14386E-02
0.38823E-02
0.13222E-03
0.30935E-05
0.14727E-03
0.24449E-01
0.33011E-04
0.26442
0.19104
0.24853
0.55742E-02
0.68280E-02
0.23935E-01
0.72733E-01
0.83775E-01
0.83262E-05
0.12207E-01
0.13995E-01
0.13378E-02
0.48840E-02
0.63792E-04
0.12745E-06
Y(I)
0.76214E-02
0.27494E-03
0.47920E-05
0.23077E-08
0.15995E-08
0.63744E-09
0.66300E-03
0.71861E-04
0.18173E-04
0.26430E-04
0.32973E-07
0.36858E-06
0.63977E-06
0.13633E-06
0.54714E-04
0.17906E-04
0.10187E-08
0.46641E-04
0.17906E-04
0.46641E-04
0.88651E-06
0.52627E-07
0.66370E-02
0.23597
0.37687E-04
0.46872
0.10953
0.10256
0.22237E-02
0.34678E-02
0.12064E-01
0.26938E-01
0.15051E-01
0.24592E-05
0.58910E-02
0.18837E-02
0.59981E-04
0.72758E-04
0.17569E-05
0.14370E-04
K(I)
9.5026
0.12941E-01
0.17367
0.96379
0.34885
0.16575
0.89680E-01
0.42280E-01
0.33971E-01
0.63647E-01
0.15911E-01
0.12100E-01
0.24940E-01
0.18425E-01
0.17775E-01
0.12447E-01
0.72616E-02
0.12014E-01
0.12447E-01
0.12014E-01
0.67049E-02
0.17012E-01
45.066
9.6515
1.1416
1.7726
0.57336
0.41265
0.39892
0.50788
0.50401
0.37037
0.17966
0.29536
0.48258
0.13460
0.44837E-01
0.14897E-01
0.27541E-01
112.75

***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR

IN
8862.59
192344.
-0.810567E+09
)
***
INPUT DATA
RELATIVE DIFF.
8862.59
192344.
-0.810567E+09
0.00000
0.00000
0.00000
***

TWO
PHASE
FLASH
PRESSURE DROP:
HOTSIDE, TOTAL
COLDSIDE, TOTAL
30
0.000100000

COUNTERCURRENT
HEAT EXCHANGER
SPECIFIED VALUE
F
650.0000
1.00000
PSI
PSI
5.0000
5.0000

HOT LIQUID
COLD LIQUID
BTU/HR-SQFT-R
HOT 2-PHASE
COLD LIQUID
BTU/HR-SQFT-R
HOT VAPOR
COLD LIQUID
BTU/HR-SQFT-R
HOT LIQUID
COLD 2-PHASE
BTU/HR-SQFT-R
HOT 2-PHASE
COLD 2-PHASE
BTU/HR-SQFT-R
HOT VAPOR
COLD 2-PHASE
BTU/HR-SQFT-R
HOT LIQUID
COLD VAPOR
BTU/HR-SQFT-R
HOT 2-PHASE
COLD VAPOR
BTU/HR-SQFT-R
HOT VAPOR
COLD VAPOR
BTU/HR-SQFT-R
OVERALL RESULTS
***
STREAMS:
-------------------------------------|
|
112
----->|
HOT
|----->
T= 9.1049D+02 |
|
P= 2.6000D+02 |
|
V= 1.0000D+00 |
|
|
|
131
<-----|
COLD
|<----T= 7.5091D+02 |
|
P= 1.7950D+03 |
|
V= 1.0000D+00 |
|
--------------------------------------
110
T= 6.5000D+02
P= 2.5500D+02
V= 1.0000D+00
130
T= 6.0000D+02
P= 1.8000D+03
V= 0.0000D+00
628.10
0.12531E+06
ZONE RESULTS

UA (DIRTY)
BTU/HR
SQFT
SQFT
BTU/HR-SQFT-R
BTU/HR-R

LMTD (CORRECTED)
F
22375552.2362
1249.0014
1249.0014
0.0000
149.6937
186967.5826
1.0000
119.6761
***

HOT
------------------------------------------------------------|
|
|
|
112
|
VAP
|
VAP
|
VAP
| 110
------> |
|
|
|------>
910.5 |
884.7|
674.3|
| 650.0
|
|
|
|
131
|
VAP
|
BOIL
|
LIQ
| 130
<------ |
|
|
|<-----750.9 |
620.5|
620.8|
| 600.0
|
|
|
|
------------------------------------------------------------COLD
1
2
3
HEAT DUTY
BTU/HR
2289481.615
18075122.910
2010947.711
AREA
SQFT
73.7009
915.4947
259.8057
BLOCK: B85
MODEL: HEATX
----------------------------HOT SIDE:
91
OUTLET STREAM:
S-506
NRTL
COLD SIDE:
132
OUTLET STREAM:
133
NRTL
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
LMTD
F
207.5205
131.8931
51.7069
AVERAGE U
UA
BTU/HR-SQFT-R
BTU/HR-R
149.6937
11032.5562
149.6937
137043.7539
149.6937
38891.2725

IN
8296.66
191729.
-0.715794E+09
)
***
DUTY AND AREA:

5.0000
5.0000

HOT SIDE:
COLD SIDE:
ZONE
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
PSI
PSI
***
30
0.000100000

TWO
PHASE
FLASH
***
***
OUT
INPUT DATA

COUNTERCURRENT
HEAT EXCHANGER
8296.66
191729.
-0.715794E+09
RELATIVE DIFF.
0.00000
0.00000
0.00000
***

ONE
PHASE
FLASH
SPECIFIED PHASE IS
TWO
PHASE
FLASH
***
OUT
VAPOR
30
0.000100000
30
0.000100000

SPECIFIED VALUE
730.0000
1.00000
PSI
PSI
5.0000
5.0000

HOT LIQUID
COLD LIQUID
BTU/HR-SQFT-R
HOT 2-PHASE
COLD LIQUID
BTU/HR-SQFT-R
HOT VAPOR
COLD LIQUID
BTU/HR-SQFT-R
HOT LIQUID
COLD 2-PHASE
BTU/HR-SQFT-R
HOT 2-PHASE
COLD 2-PHASE
BTU/HR-SQFT-R
HOT VAPOR
COLD 2-PHASE
BTU/HR-SQFT-R
HOT LIQUID
COLD VAPOR
BTU/HR-SQFT-R
HOT 2-PHASE
COLD VAPOR
BTU/HR-SQFT-R
HOT VAPOR
COLD VAPOR
BTU/HR-SQFT-R
***
OVERALL RESULTS
<------ |
|
|
|<-----660.8 |
620.5|
620.8|
| 600.0
|
|
|
|
------------------------------------------------------------COLD
ZONE
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
***
STREAMS:
-------------------------------------|
|
91
----->|
HOT
|----->
T= 7.8684D+02 |
|
P= 3.5000D+01 |
|
V= 1.0000D+00 |
|
|
|
133
<-----|
COLD
|<----T= 6.6078D+02 |
|
P= 1.7950D+03 |
|
V= 1.0000D+00 |
|
--------------------------------------
S-506
T= 7.3000D+02
P= 3.0000D+01
V= 1.0000D+00
132
T= 6.0000D+02
P= 1.8000D+03
V= 0.0000D+00
1
2
3
HEAT DUTY
BTU/HR
193012.268
4970606.930
552936.234
AREA
SQFT
8.9290
240.4494
30.2269
BLOCK: B86
MODEL: HEATX
----------------------------HOT SIDE:
S-506
OUTLET STREAM:
34
NRTL
COLD SIDE:
141
OUTLET STREAM:
22
NRTL
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR

UA (DIRTY)
BTU/HR
SQFT
SQFT
5716555.4328
279.6053
279.6053
0.0000
BTU/HR-SQFT-R
BTU/HR-R

LMTD (CORRECTED)
F
PRESSURE DROP:
HOTSIDE, TOTAL
COLDSIDE, TOTAL
1.0000
136.5795
1
PSI
PSI
5.0000
5.0000

HOT SIDE:
COLD SIDE:
***
149.6937
41855.1377
61.147
0.17817E+07
ZONE RESULTS
***

HOT
------------------------------------------------------------|
|
|
|
91
|
VAP
|
VAP
|
VAP
| S-506
------> |
|
|
|------>
786.8 |
784.9|
735.5|
| 730.0
|
|
|
|
133
|
VAP
|
BOIL
|
LIQ
| 132
UA
BTU/HR-R
1336.6175
35993.7489
4524.7712
10146.3
283848.
-0.875479E+09
AVERAGE U
BTU/HR-SQFT-R
149.6937
149.6937
149.6937

IN
***
DUTY AND AREA:
LMTD
F
144.4035
138.0964
122.2020
INPUT DATA
***
OUT
RELATIVE DIFF.
10146.3
283848.
-0.875479E+09
0.00000
0.00000
0.00000
***

TWO
PHASE
FLASH
30
0.000100000

TWO
PHASE
FLASH
30
0.000100000

COUNTERCURRENT
HEAT EXCHANGER
SPECIFIED VALUE
F
707.0000
1.00000
PSI
PSI
5.0000
5.0000

HOT LIQUID
COLD LIQUID
BTU/HR-SQFT-R
HOT 2-PHASE
COLD LIQUID
BTU/HR-SQFT-R
HOT VAPOR
COLD LIQUID
BTU/HR-SQFT-R
HOT LIQUID
COLD 2-PHASE
BTU/HR-SQFT-R
HOT 2-PHASE
COLD 2-PHASE
BTU/HR-SQFT-R
HOT VAPOR
COLD 2-PHASE
BTU/HR-SQFT-R
HOT LIQUID
COLD VAPOR
BTU/HR-SQFT-R
HOT 2-PHASE
COLD VAPOR
BTU/HR-SQFT-R
HOT VAPOR
COLD VAPOR
BTU/HR-SQFT-R
***
STREAMS:
OVERALL RESULTS
***
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
-------------------------------------|
|
S-506
----->|
HOT
|----->
T= 7.3000D+02 |
|
P= 3.0000D+01 |
|
V= 1.0000D+00 |
|
|
|
22
<-----|
COLD
|<----T= 7.0700D+02 |
|
P= 4.5500D+02 |
|
V= 1.0000D+00 |
|
-------------------------------------DUTY AND AREA:
UA (DIRTY)
BTU/HR-SQFT-R
BTU/HR-R
141
T= 1.3830D+02
P= 4.6000D+02
V= 0.0000D+00
149.6937
483410.7136
1.0000
98.7676
1
5.0000
5.0000

HOT SIDE:
COLD SIDE:
68.892
9933.1
ZONE RESULTS
***

HOT
------------------------------------------------------------|
|
|
|
|
S-506
|
VAP
|
VAP
|
VAP
|
COND
| 34
------> |
|
|
|
|------>
730.0 |
508.0|
285.2|
232.5|
| 231.8
|
|
|
|
|
22
|
VAP
|
BOIL
|
LIQ
|
LIQ
| 141
<------ |
|
|
|
|<-----707.0 |
287.8|
210.3|
167.3|
| 138.3
|
|
|
|
|
------------------------------------------------------------COLD
ZONE
1
2
3
4
HEAT DUTY
BTU/HR
21295841.560
19593132.909
4355315.149
2501036.845
AREA
SQFT
1629.4197
971.1357
415.9394
212.8386
BLOCK: B87
MODEL: HEATX
----------------------------HOT SIDE:
19
OUTLET STREAM:
S-614
NRTL
138
139
NRTL
***
47745326.4645
3229.3333
3229.3333
0.0000
PSI
PSI
***
2.3179D+02
2.5000D+01
9.8170D-01
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
LMTD
F
87.3089
134.7785
69.9497
78.4994
AVERAGE U
UA
BTU/HR-SQFT-R
BTU/HR-R
149.6937
243913.7889
149.6937
145372.8488
149.6937
62263.4843
149.6937
31860.5917

IN
1944.36
83391.2
-0.114409E+08
)
***
BTU/HR
SQFT
SQFT

LMTD (CORRECTED)
F
PRESSURE DROP:
HOTSIDE, TOTAL
COLDSIDE, TOTAL
34
T=
P=
V=
COLD SIDE:
OUTLET STREAM:
INPUT DATA
RELATIVE DIFF.
1944.36
83391.2
-0.114409E+08
0.00000
0.00000
0.00000
***

TWO
PHASE
FLASH
30
0.000100000

TWO
PHASE
FLASH
30
0.000100000

COUNTERCURRENT
HEAT EXCHANGER
SPECIFIED HOT VAPOR FRACTION
SPECIFIED VALUE
0.0000
1.00000
PSI
PSI
5.0000
5.0000

HOT LIQUID
COLD LIQUID
BTU/HR-SQFT-R
HOT 2-PHASE
COLD LIQUID
BTU/HR-SQFT-R
HOT VAPOR
COLD LIQUID
BTU/HR-SQFT-R
HOT LIQUID
COLD 2-PHASE
BTU/HR-SQFT-R
HOT 2-PHASE
COLD 2-PHASE
BTU/HR-SQFT-R
HOT VAPOR
COLD 2-PHASE
BTU/HR-SQFT-R
HOT LIQUID
COLD VAPOR
BTU/HR-SQFT-R
HOT 2-PHASE
COLD VAPOR
BTU/HR-SQFT-R
HOT VAPOR
COLD VAPOR
BTU/HR-SQFT-R
***
OVERALL RESULTS
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
149.6937
***
STREAMS:
-------------------------------------|
|
----->|
HOT
|----->
1.0000D+02 |
|
2.6500D+02 |
|
3.9632D-01 |
|
|
|
139
<-----|
COLD
|<----T= -2.7958D+00 |
|
P= 4.6000D+01 |
|
V= 9.5450D-01 |
|
-------------------------------------19
T=
P=
V=
DUTY AND AREA:

***
OUT

BTU/HR
SQFT
SQFT
BTU/HR-SQFT-R
S-614
T= 4.6898D+01
P= 2.6000D+02
V= 0.0000D+00
138
T= 0.0000D+00
P= 5.1000D+01
V= 0.0000D+00
4168101.2351
401.0612
401.0612
0.0000
149.6937
UA (DIRTY)
BTU/HR-R
60036.3221

LMTD (CORRECTED)
F
PRESSURE DROP:
HOTSIDE, TOTAL
COLDSIDE, TOTAL
1.0000
69.4263
1
PSI
PSI
5.0000
5.0000

HOT SIDE:
COLD SIDE:
***
COMP
CO2
CO
WATER
METHANOL
DME
METHANE
NITRO-01
78969.
45491.
ZONE RESULTS
F(I)
0.47120E-02
0.77364E-06
0.51998E-01
0.13831
0.80022
0.47435E-02
0.81521E-05
BLOCK: B90
MODEL: VALVE
----------------------------INLET STREAM:
20
OUTLET STREAM:
141
NRTL
***
X(I)
0.12299E-02
0.14128E-06
0.15075
0.10154
0.74526
0.12172E-02
0.14993E-05
Y(I)
0.47120E-02
0.77364E-06
0.51998E-01
0.13831
0.80022
0.47435E-02
0.81521E-05
K(I)
78.760
112.58
7.0911
28.003
22.074
80.119
111.78

***
HOT
------------------------------------------------------------|
|
|
19
|
COND
|
COND
| S-614
------> |
|
|------>
100.0 |
47.2|
|
46.9
|
|
|
139
|
BOIL
|
LIQ
| 138
<------ |
|
|<------2.8 |
2.5|
|
0.0
|
|
|
------------------------------------------------------------COLD
ZONE
1
2
HEAT DUTY
BTU/HR
4126984.894
41116.341
AREA
SQFT
395.0650
5.9962
BLOCK: B88
MODEL: HEATER
-----------------------------INLET STREAM:
22
OUTLET STREAM:
140
NRTL
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR
LMTD
F
69.7848
45.8072
)
***
VALVE PRESSURE DROP

INPUT DATA
***
OUT
25.0000
NO
NPHASE
0.00000
0.00000
0.00000
***
PSI
***
RELATIVE DIFF.
2399.64
102028.
-0.214186E+09
RESULTS
2
30
0.000100000
***
PSIA
460.000
98
2399.64
102028.
-0.166441E+09
***
UA
BTU/HR-R
59138.7265
897.5956
2399.64
102028.
-0.214186E+09
BLOCK: B89
MODEL: SEP
--------------------------INLET STREAM:
70
OUTLET STREAMS:
97
NRTL

IN
AVERAGE U
BTU/HR-SQFT-R
149.6937
149.6937
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR

IN
INPUT DATA
TWO
PHASE TP FLASH
PRESSURE DROP
*** RESULTS
OUTLET TEMPERATURE
F
OUTLET PRESSURE
PSIA
HEAT DUTY
BTU/HR
***
OUT
2399.64
102028.
-0.166441E+09
RELATIVE DIFF.
0.00000
0.00000
0.00000
***********************************************************************
*
*
*
ERRORS IN BLOCK CALCULATIONS
*
*
*
*
SFLASH CONVERGENCE ERROR
*
*
*
***********************************************************************
***
F
PSI
707.000
0.0
30
0.000100000
***
TOTAL BALANCE
MOLE(LBMOL/HR)
MASS(LB/HR
)
ENTHALPY(BTU/HR

IN
5546.57
120604.
-0.517576E+09
***
OUT
RELATIVE DIFF.
5546.57
120604.
-0.517576E+09
0.114782E-14
0.434372E-14
0.132147E-10
***
707.00
455.00
0.0000
1.0000
0.0000
***
TWO
PHASE TP FLASH
PRESSURE DROP
PSI
INPUT DATA
***
0.0
30
0.000100000

TWO
PHASE TP FLASH
PRESSURE DROP
PSI
FRACTION OF FEED
SUBSTREAM= MIXED
STREAM= 98
0.0
30
0.000100000
CPT= H2
CO2
CO
WATER
METHANOL
DME
METHY-01
METHY-02
ACETA-01
N-PRO-01
ACROL-01
METHA-01
N-BUT-01
METHY-03
ACETONE
3-MET-01
1:1-D-01
VALER-01
METHY-04
ETHANOL
CIS-C-01
METHY-05
DIETH-01
2-MET-01
METHY-06
DIETH-02
METHY-07
3-MET-02
TERT--01
METHANE
ETHANE
ETHYLENE
PROPANE
CYCLO-01
PROPYLEN
ISOBUTAN
N-BUTANE
TRANS-BU
1-BUTENE
ISOBUTEN
CIS-2-01
2-MET-02
1:2-B-01
1:3-B-01
N-PENTAN
N-HEXANE
N-HEPTAN
BENZENE
TOLUENE
N-OCT-01
NITRO-01
***
HEAT DUTY
COMPONENT = CO2
STREAM
SUBSTREAM
98
MIXED
RESULTS
FRACTION=
0.0
1.00000
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
1.00000
***
BTU/HR
SPLIT FRACTION
1.00000
-0.68397E-02
COMPONENT = CO
STREAM
SUBSTREAM
97
MIXED
SPLIT FRACTION
1.00000
COMPONENT = WATER
STREAM
SUBSTREAM
97
MIXED
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
97
MIXED
SPLIT FRACTION
1.00000
COMPONENT = DME
STREAM
SUBSTREAM
97
MIXED
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
97
MIXED
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
97
MIXED
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
97
MIXED
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
97
MIXED
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
97
MIXED
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
97
MIXED
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
97
MIXED
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
97
MIXED
SPLIT FRACTION
1.00000
COMPONENT = ETHANOL
STREAM
SUBSTREAM
97
MIXED
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
97
MIXED
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
97
MIXED
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
97
MIXED
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
97
MIXED
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
SPLIT FRACTION
97
MIXED
1.00000
STREAM
SUBSTREAM
97
MIXED
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
97
MIXED
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
97
MIXED
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
97
MIXED
SPLIT FRACTION
1.00000
COMPONENT = METHANE
STREAM
SUBSTREAM
97
MIXED
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
97
MIXED
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
97
MIXED
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
97
MIXED
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
97
MIXED
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
97
MIXED
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
97
MIXED
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
97
MIXED
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
97
MIXED
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
97
MIXED
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
97
MIXED
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
97
MIXED
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
97
MIXED
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
97
MIXED
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
97
MIXED
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
97
MIXED
SPLIT FRACTION
1.00000
STREAM
SUBSTREAM
98
MIXED
SPLIT FRACTION
1.00000

Propylene From Biomass

Uploaded by

Copyright:

Available Formats

Propylene From Biomass

Uploaded by

Document Information

Original Description:

Copyright

Available Formats

Share this document

Share or Embed Document

Sharing Options

Did you find this document useful?

Is this content inappropriate?

Copyright:

Available Formats

Propylene From Biomass

Uploaded by

Copyright:

Available Formats

University of Pennsylvania

Department of Chemical & Biomolecular

PROPYLENE FROM BIOMASS

This paper is posted at ScholarlyCommons. http://repository.upenn.edu/cbe_sdr/23

PROPYLENE FROM BIOMASS

This working paper is available at ScholarlyCommons: http://repository.upenn.edu/cbe_sdr/23

Professor Wen Shieh

Dear Professor Shieh, Professor Fabiano, and Mr. Wismer,

Project Originator: Mr. John Wismer

Letter of Transmittal ................................................................................................................ 1

Tile Page .................................................................................................................................. 2

Introduction and Project Charter ............................................................................................. 9

Market Analysis ..................................................................................................................... 17

Process Flow Diagram and Material Balances ...................................................................... 20

Process Description ............................................................................................................... 47

Equipment List and Unit Descriptions ............................................................................... 76

Block 100 Solids Handling .................................................................................................... 76

Block 200 - Gasification ........................................................................................................... 80

Specification Sheets ......................................................................................................... 125

Equipment Cost Summary ............................................................................................... 230

Energy Balance and Utility Requirements ....................................................................... 235

Overview: ................................................................................................................................ 235

Fixed-Capital Investment Summary ................................................................................ 243

Operating Cost and Economic Analysis .......................................................................... 247

Cash Flow and Profitability Analysis: .................................................................................... 251

Other Considerations ....................................................................................................... 260

Plant Startup ............................................................................................................................ 260

Conclusions and Recommendations ................................................................................ 262

Acknowledgements .......................................................................................................... 264

Bibliography .................................................................................................................... 266

Appendices ....................................................................................................................... 273

Sample Calculations ................................................................................................................ 273

R-401 Costing Calculations Microchannel Reactor: ............................................................ 294

Introduction and Project Charter

Design and basic optimization of the propylene production process using

Specific handling and optimization of fuel byproducts or steam produced

Detailed solids handling and gasification reactor design

Detailed optimization, sensitivity analysis, or process control design

Equipment specifications, designs, and cost estimates

Flowsheet diagrams and simulation results

Economic and profitability analyses, with an emphasis on overall feasibility

February 22nd: Material balance and process flow diagram

March 15th: Syngas to DME reactor design

March 22nd: All major equipment designs

March 29th: Financial analysis

April 5th: All analyses and reports completed

Process Flow Diagram and Material Balances

Block 100 Solids Handling

Total Flow, 15% Moisture Chips [lb/hr]

Moisture Removed [lb/hr]

Block 200 Gasification

S-207 S-207 Moisture S-205

S-210 S-210 filtered

Block 300 MEA Absorption

-3406.12 -3389.63 -13965.1 -13903.1 -929.045

S-316 S-316R S318

199754.9 1.48E+06 1.48E+06 1.48E+06 1.28E+06 1.28E+06

200000 1.33E+06 1.33E+06 1.46E+05 1.33E+06

Block 400 DME Formation