MANUAL ON EMERGENCY PLANNING

S.No.

Particulars

I
1.0
2.0
2.1
2.2
2.3
2.4
2.5
3.0
3.1
3.2
4.0
4.1
4.2
5.0
6.0
II
7.0
8.0
9.0
10.0
10.1
10.2
10.3
10.4
11.0
11.1
11.2
11.3
11.4
11.5
11.6
11.7
11.8
11.9
11.10
11.11
12.0

On-site Emergency Plan

Introduction
Elements of planning
Hazard Analysis
Hazard Identification
Procedure for hazard Identification
Hazardous Substances and Zones
Key personnel and their Role
Infrastructure
Emergency Control Room
Assembly points
Operational system during Emergency
Communication system
Warning system and control
Mutual Aid
Declaration of off-site Emergency
Off-site Emergency plan
Introduction
Responsibility for planning off-site plan
Industries to be covered in the plan
Compilation of general information
Geographic Information
Demographic information
Meteorological information
Seismic Data
Elements of off-site planning
List of Hazardous installations
Off-site control room
Key personnel and their duties
Communication system network
Warning system
Public Information system
Fire fighting system
Mutual Aid
Services Support System
Evacuation / Safe areas
Relief to the victims
Check list for capability assessment
1

III
i
ii
iii
iv
v
vi
vii
Viii

Annexures
Components of On-Site Emergency Plan
Components of Off-Site Emergency Plan
Duties of Crisis Management Group Members
Operational Response Group
Chemical Resistance Chart for Gloves
Chemical Resistance Properties of Suits
List of Hazardous Chemicals
Abbreviations

FOREWORD

The country has witnessed a fast growth in the industrial sector in the last decade and this
is a sure sign of development. Extreme care is needed at all the stages of work to avert any
possible danger due to industrial mishaps involving vide range of hazardous chemicals.
A number of Government agencies are functioning to deal with the matters related to
management and handling of chemicals under various statutory provisions, viz. Factories
Act 1948 (Amended in 1987), Manufacture, Storage and Import of Hazardous Chemicals
(MSIHC) Rules, 1989, (amended in 1994 & 2000), Public Liability Insurance (PLI) Act, 1991,
Central Motor Vehicle Rules, 1989, Chemical Accidents (EPPR) Rules, 1996. The agencies
responsible for implementation of these regulations ensure strict implementation in the
interest of environment and mankind. Inspite of keeping a constant vigil and strict
implementation of statutory norms possibility of occurrence of accidents can not be ruled
out. In view of this it is essential to prepare ourselves and keep ready to meet any
emergency situation arising due to industrial accidents. Prior preparations can also help in
minimizing the consequences and this requires an emergency preparedness plan to
negotiate an eventuality of chemical industries.
Though it is mandatory under various environmental rules for industries and districts
administrative authorities to prepare an on-site and off-site emergency plan but still lot
needs to be done in this area. These plans should be designed to provide measures to
control accidents and minimize the effects caused due to mishaps involving chemical spill,
escape of toxic gases, fire, explosion, processing, transportation etc. The exercise of
planning for on-site and off-site emergency are different but these should compliment each
other for an effective management.
An effort has been made to compile a manual as supportive document for the concerned
Government and industrial authorities to give them an idea about basic components which
need to be considered while preparing emergency plan. Besides, other components must
also be taken in to account, based on the local and specific needs, to improve the capability
and ability to consciously meet the obligatory needs. This useful compilation is the outcome
of work by a team of staff colleagues including Dr. (Mrs.) Reeta Kori, Sr. Scientific Officer,
Dr. A.K. Saxena, Chief Chemist and Dr. Rajendra Chaturvedi, Scientist, Emergency
Response Centre, Bhopal who have been involved in chemical accident prevention and
other emergengy activities, under the guidance of Dr. P.C. Seth, Chief Scientific Officer.
I hope this compilation, brought out by the Emergency Response Centre, M.P. Pollution
Control Board, Bhopal would prove to be useful and help to achieve the basic objectives for
the preparation of emergency plan with pious aim to protect the environment and mankind.

Sd/(Dr. A.K. Singh)

SECRETARY

Bhopal
Date :

ON-SITE EMERGENCY PLAN

1.0

Introduction :
An on-site emergency is caused by an accident that takes place in a chemical
installation and the effects are confined to the factory premises involving only the
people working in the factory. On-site emergency plan to deal with such
eventualities, is the responsibility of the occupier and is mandatory.
Apart from the provisions in the Hazardous Chemicals Rules, Section 41 B(4) of the
Factories Act, 1948 (as amended) also requires that every occupier is to draw up an
on-site emergency plan (O.S.E.P.) with detailed disaster control measures for the
factory and to educate the workers employed in the factory premises. The obligation
of an occupier of hazardous chemicals to prepare an emergency plan are stipulated
in Rule 13 of the Manufacture, Storage and Import of Hazardous Chemicals Rules,
1989, amended 1994 & 2000. The format giving components of OSEP, as
prescribed in the Rules may be referred in Annexure I. The general public living in
the vicinity are also to be Informed and educated about safety measures and actions
required to be taken in the event of an accident.
The preparation of an on-site emergency plan and furnishing relevant information to
the District Emergency Authority for the preparation of the off-site emergency plan
are statutory responsibilities of the occupier of every industry and other units
handling hazardous substances. An on-site emergency plan should contain the
following key elements :
*

basis of the plan : Hazard analysis:

accident prevention procedure/measures:

accident/emergency response procedure/measures :

recovery procedure.

2.0

Elements of Planning

2.1

Hazard Analysis
Hazard analysis is a critical component in planning for emergencies. To analyze the
safety of a major installation as well as its potential hazards, a hazard analysis
should be carried out covering the following areas :(i)

Which toxic, reactive, explosive or flammable substance in the installation

constitutes a major hazard.

2.2

(ii)

Which failures or errors could cause abnormal conditions leading to a major

accident ?

(iii)

The consequences of a major accident for the workers, people living or

working outside the installation and the environment ?

(iv)

Preventive measures for accidents.

(v)

Mitigation of the consequences of an accident.

Hazard Identification
Hazard identification is the first step in hazard analysis and entails the process of
collecting information on following points :

2.3

the types and quantities of hazardous chemicals in production, storage,

processing, transportation and disposal in an installation ;

the location of the facilities process, storage, product or use ; and

potential hazard associated with spills or releases.

Procedure for Hazard Identification

2.3.1

Identification of Hazardous Substances

Chemicals can be identified either by their CAS Number, or their ID Numbers
(UN Nos). Based on the respective criteria, chemicals can be classified as
toxic, flammable or explosive.

2.3.2

Quantities of Hazardous Substances

The estimation of the notifiable quantity of each chemical at a site should
include the amounts likely to be on-site under the control of the occupier and
should include the following :

i.

Activities involving storage, manufacture and use in process.

ii.

Vehicles used exclusively for on-site transportation since any quantity such a
vehicle is carrying, is liable to be either stored or used in the installation.

iii.

Any Vehicle, for example road or rail tanker used as a storage vessel either
on-site or within 500 meters of site.

iv.

Any off-site pipeline which is 500 meters of the boundary of the site and
connected to it. This would include pipeline used for transfer operations, to
and from a remote outlet. This may also include road tankers, ships or other
vessels.

v.

2.4

Any neighboring site within 500 meters of any part of the boundary storing,
processing or handling the same hazardous chemicals.

Charts and Maps Indicating Hazardous Substances and Zones

After assessment of hazard on the basis of above points, the charts and maps
should be placed in the premises at strategic locations. The charts and maps should
highlight the accident-prone areas of the industry so that in case of an emergency, it
provides a basis for taking any action.

2.5

Appointment of key Persons and Their Role

To deal with an emergency, the arrangement for immediate deployment or
appointment of key personnel and their specific duties must be laid out. It may be
noted that in smaller installations, two or more tasks, referred hereunder, may have
to be assigned to and performed by one person because of the availability position
of personnel to deal
with the eventuality, effectively and promptly.

2.5.1

Emergency Personnels Responsibility during normal working hours:

A.

B.

Site Controller -- The General Manager (however called) or his nominated

deputy will assume overall responsibility for the factory / storage site and its
personnel. His duties are to :
i.

assess the magnitude of the situation and decide if staff need to be

evacuated from their assembly points to identified safer places ;

ii.

exercise direct operational control over areas other than those affected;

iii.

undertake a continuous review of possible developments and assess in

consultation with key personnel as to whether shutting down of the plant or
any section of the plant and evacuation of personnel are required:

iv.

liaise with senior officials of police, Fire Brigade, Medical and Factories
Inspectorate and provide advice on possible effects on areas outside the
factory premises :

v.

look after rehabilitation of affected persons on discontinuation of emergency ;

vi.

issue authorised statements to news media and ensure that evidence is

preserved for enquiries to be conducted by the statutory authorities.

Incident Controller -- A Production Manager or an officer of similar rank of the unit

may be nominated to act as the Incident Controller Immediately on knowing about an
emergency, he will rush to the incident site and take overall charge and report to the
Site Controller. On arrival, he will assess the extent of emergency and decide if major

emergency exists and inform the communication officer accordingly. His duties will be
to :

C.

D.

i.

direct all operations to stop within the affected area taking into consideration
priorities for safety of personnel, minimize damage to the plant, property and
environment and minimize loss of materials:

ii.

provide advice and information to the Fire and Security Officers and the local
fire service:

iii.

ensure that all non-essential workers/staff of the areas affected are

evacuated to the appropriate assembly points and the areas are searched for
casualties;

iv.

set up communication points and establish contact with Emergency Control

Centre in the event of failure of electric supply and thereby Public Address
System (PAS) and internal telephones:

v.

report on all significant development to the communication officer: and

vi.

have regard to the need to preserve the evidence so as to facilitate any

enquiry into the cause and circumstances which caused or escalated the
emergency.

Personnel/Administrative Manager He will also work as Liaison Officer and will be

stationed at the main entrance (Gate House) during the emergency. He will , under the
direction of the Site Controller, handle Police, Press and other enquiries, receives
reports from assembly points and pass on the absentee information to the Incident
Controller. His responsibilities shall be :
i.

to ensure that casualties receive adequate attention / to arrange additional

help if required and inform relatives;

ii.

to control traffic movements into the factory and ensure that alternative
transport is available when need arises ;

iii.

when emergency is prolonged, arrange for the relief of personnel and

organise refreshments catering facility.

Communication officer -- He will, on hearing the alarm, proceed to Control Room

and maintain communication with the Incident Controller. He will :
i.

advise the Site Controller of the situation, recommending (if necessary)

evacuation of staff from assembly points;

ii.

recruit suitable staff to act as runners between the accident Controller and
himself if the telephone and other system of communication fail. Also
maintain contact with congregation points like Canteen etc.

iii.

Maintain prior agreed inventory in the Control Room;

iv.

maintain a log of the incident on tape ;

v.

in case of a prolonged emergency involving risk to outside areas by windblown materials contact local meteorological office to receive early
notification of changes in weather conditions.

E. Fire & Security Officer The Chief Fire and Security Officer will be responsible for the
fire fighting. On hearing the fire alarm, he shall reach the fire station immediately and
advise fire and security staff in the factory of the incident zone and cancel the alarm. He
will also announce on PAS or convey through telephones or messengers or canteens to
the Communication Officer, Incident Controller and Site Controller about the incident
zone. He will open the gates nearest to the incident and stand by to direct the
emergency services.
F. Telephone Operator on hearing the emergency alarm, he will immediately contact
Site Controller and on his advice call the local fire-brigade or mutual-aid scheme
members. In case the PAS internal/external telephone system becomes inoperative, he
shall inform the Communication Officer through a messenger. In case fire is detected
and the alarm is not in operation, he shall receive information about location from the
person who detected the fire and thereafter immediately consult the Incident Controller
and make announcement on PAS or telephone telling the staff about location of the
incident and to evacuate to their assembly points. He will continue to operate the switch
board advising the callers that staff are not available and pass all calls connected with
the incident to the Communication Officer.
G. Departmental Heads -- The Department Heads will report to Incident Controller and
provide assistance as required. They will decide the staff they require at the incident
site.
H. Engineer in-charge and Electricians - They will report the scene of the incident and
close down the services as directed by the Incident Controller.
I.

Fire-pump Attendant - Two persons identified in each shift will work as fire pump
attendants. On hearing the fire alarm, they will immediately proceed to the pump house
to ensure that pumps are operating and stand by to maintain them. At the end of
emergency, they will be relieved of their duty by the Fire and Security Officers.

2.5.2

Responsibilities of Emergency Personnel outside normal working hours of

the factory :
A.

i.

Shift Executive incharge :

As soon as he becomes aware of the emergency and its location, he will proceed to
the scene. On arrival, he shall assess the scale of the incident and direct operations
within the affected areas with the following priorities :

Secure the safety persons, which may require evacuation to the assembly
points in the event of escape of material if the wind is from an adverse
direction.

Minimise damage to plant, property and the environment.

Prevent spreading and damage to outside the premises.

Minimise loss of materials ; and

Have regard to the need for preserving evidence that may facilitate
subsequent enquiry.

ii.

Inform shift engineer-in-charge as to what services are/are not required.

iii.

Hand over charge of operations to the Incident Controller when he arrives at

the site.

iv. Advise the Fire & Security Officer at Gate House whether to make an
announcement on PAS or not to call the Senior Staff to the factory, if necessary.
B. Fire & Security Officer -- On hearing the call, he shall rush to the Gate
House. He shall advise the Fire & Security Staff at the incident point of the
factory zones. He shall cancel the fire alarm and, on advise of Shift Executive
Incharge, inform the local fire brigade (or active mutual aid system where
exists). He shall :
i. Announce over the PAS in which zone the incident has occurred and on the
advice of the Shift Executive Incharge inform the staff to evacuate the
assembly service.
ii. Inform the Shift Executive Incharge, if there is any large escape of gas.
iii. Call out in the following order :
*

Incident Controller or his nominated deputy.

Engineering Manager and Service Manager

Personnel and Administrative Manager

Departmental Head in whose plant the incident occurred.

C. First-Aid Teams
The Personnel Manager shall keep the roll call lists for the Fire and First-Aid
team on duty, Roll call leaders and first-aiders are appointed by each
Departmental Head for his shift team. Roll call leaders shall check their rolls as
members of the services and report for emergency duty. Names of unaccounted

persons or absentees will be informed to the Fire and Security officer. Members
of the first-aid teams will report to the Shift Executive Incharge/Incident
Controller on hearing the alarm and follow his directions.
D. Factory Fire Brigade Personnel -- The duty Fire-Brigade personnel under
the command of the Fire and Security Officer shall be responsible for fire fighting
and rescue. On hearing the alarm, they shall proceed to the place of incident, if
known; otherwise they will report at the Fire Station. The men at fire station
shall find out the location of the emergency, the equipment and proceed to the
site of occurrence. At the site, all the squad members will respond to the
direction given by the Incident Controller.

3.0

Infrastructure

3.1

Emergency Control Room -- Emergency Control Room is to be set up and

marked on the site plan. The Control Room will be the focal point in case of an
emergency from where the operations to handle the emergency are directed and
coordinated. It will control site activities and should be furnished with external and
internal telephone connections, list of essential telephone numbers, list of key
persons and their addresses.

3.2

Assembly Points -- Assembly points are to be set up farthest from the location of
likely hazardous events, where pre-designated persons from the works, contractors
and visitors would assemble in case of emergency. Up-to-date list of pre-designated
employees of various departments (shift wise) must be available at these points
so that roll call could be taken. Predesignated persons would take charge of these
points and mark presence as the people come into it.

4.0

Operational System during Emergency

4.1

Communication System -- There are different types of alarms to differentiate one

type of an emergency from other as described below:Fire or Gas
Emergency / Evacuation
All clear Continuous

Normal Fire Siren

High-pitched wailing siren
Fire Siren

Alarms should be followed by an announcement over Public Address System. In

case of failure of alarm system, communication should be by telephone operator
who will make announcement in industrial complex through Public Address System
which should be installed. walkie-talkie and paging system are very useful for
communication during emergency, with predetermined codes of communication. If
everything fails a messenger could be used for sending the information.
4.2

Warning System and Control -- The Control Centres should be located at an area
of the minimum risk or vulnerability in the premises concerned, taking into account
the wind direction, areas which might be affected by fire / explosion, toxic release,
etc.

10

4.2.1

Service and Control

For promptness and efficiency, the factory premises/storage sites may be
divided into X number of zones, which should be clearly marked on the site
plan.

5.0

i.

Emergency Services -- Under this each factory should describe the facilities
of fire-fighting, first-aid and rescue, alternate sources of power supply for
operating fire pumps, communication with local bodies, fire brigade, etc.
should also be clearly indicated.

ii.

An adequate number of external and internal telephone connection should be

installed.

4.2.2

Work Plan Illustration

a.

areas with large inventories of hazardous material.

b.

location of radio-active sources, if any.

c.

Sources of safety equipment.

d.

Fire-hydrant system and alternate supply sources.

e.

Stock of other fire-fighting materials.

f.

Assembly points, first-aid centres.

g.

Surrounding habitation within km distance.

h.

Availability of first-aid equipment.

Mutual Aid
It is essential to have mutual aid arrangement as it is useful in cases of major fire
and other emergencies. Mutual aid arrangements are to be worked out in the plan
to facilitate additional help in, say, fire-fighting or medical attention which might be
beyond the capacity of an individual factory / unit. To make the mutual aid plan a
success, the following are considered essential :
i.

Written procedure which spells out how call for help will be made and how it
will be responded.

ii.

The type of equipment which would be used and procedure for making
replacement.

iii.

A quick hot-line method of communication.

iv.

A brief mention of the type of hazard in each plant and fire-fighting measures.
11

6.0

v.

Orientation and joint training programme for staff.

vi.

Joint inspections and drills.

Declaration of off-site Emergency

The person responsible for declaring the emergency (Site Controller) will assess
the situation and in case its effects are likely to be felt outside the factory premises,
he would get in touch forthwith with the District authorities who will at once take over
the management of emergency situation and declare off-site emergency. The
situation should also be immediately declared by Coded Siren which will help to
inform the people in the vicinity of the industry / unit about the emergency situation.
They should be helped to move to the safer area as prescribed in the off-site plan.
The management of emergency henceforth has to be conducted by the District
Crisis Management Group from a Control Room under the supervision of the District
Collector.

12

OFF-SITE EMERGENCY PLAN

7.0

Introduction
If an accident takes place in a chemical industry / unit and its effects are felt outside
its premises, the situation thus created is called an off-site emergency. It no longer
remains the concern of the factory management alone but also becomes a concern
for the general public living outside or passing by the premises of the factory or
storage site involved. To meet such situations off-site emergency plans are to be
prepared as stipulated and put into operation as and when required.
It is mandatory under Rule 14 of the MSIHC Rules 1989, amended in 1994 & 2000
for District authorities to prepare an off-site emergency plan in respect where
accidents are likely to have an off-site adverse effect. Annexure II may be refereed
for components of Off-Site Emergency Plan. In case of Nuclear Power Plants, the
responsibility for preparation of the plan is that of the Plant authorities and Atomic
Energy Regulatory Board.
The off-site emergency plan should detail how emergency related to major
accidents on the site will be dealt with. For preparing the plan, the concerned
district authorities should consult the industries and other persons who would be
concerned with its execution should such an emergency arise. The following points
should be noted by all concerned in respect of an off-site emergency plan :
i.

The industrial or storage units to be covered under the plan should provide all
the necessary information related to industrial activities under their respective
control to the concerned authorities.

ii.

In case of any new industrial activity proposed or being set up in the area, an
on-site emergency plan should be prepared before the activity is
commenced.

iii.

All districts having major hazard installation should have an off-site

emergency plan.

iv.

The off-site emergency plan should be updated from time to time,

especially when a new process is started or new units are established.

v.

The off-site emergency plan should be tested for its efficacy through mock
drills or simulation exercises.

vi.

The persons outside the site, who may be affected by a major accident,
should be informed about :-a)

the nature of the major accident hazard

b)

safety measures to be adopted.

13

8.0

Responsibility for Planning an Off-Site Emergency

The planning for emergency response to chemical disaster requires cooperation
among the responders to know the persons responsible for various activities. This
understanding is facilitated through personal interaction and close working in
devising and updating a plan. Therefore, the pre-requisite for preparing a plan is the
formation of a planning team. The possible composition of the planning team is given
below :Planning Team-Members
Collector/Deputy Collector
Emergency Response Centre
District authorities Incharge of Fire Services, Police
Medical Services
Factory Inspectorate
Pollution Control Board
Industries and Transport
Co-opted members on need basis
District authorities concerned
Civil Defense
Publicity Department
Municipal Corporation and
Non-Officials such as elected representatives, MPs / MLAs and Voluntary
Organisation.
The District Collector or his nominated representative would be the team leader who
shall conduct the planning task in a systematic manner.

9.0

Number and Type of Industries to be covered under this Plan

A list of 652 chemicals with the threshold quantities for which off-site emergency
plan is required to be prepared is prescribed in Management, Storage & Import of
Hazardous Chemicals (Amendment) Rules, 2000. The off-site plans are also to be
prepared in case of Transit Depots, Warehousing Corporation and during
transportation of Hazardous Chemicals.

14

10.0

Compilation of Geographic, Demographic, Meteorological and Seismic

Information
Details of public transport network including information of local conditions around
the hazardous industries, are required for preparation of off-site plan. The
information required includes :-10.1

Geographic Information
Public transportation network, details of road network including conditions of
road width, traffic load and connecting road with industries and the rail
network are to be collected and shown on map.
--

Pipeline network
Details of pipeline network carrying flammable and toxic materials are
to be shown in the map to Indicate possible impact.

--

Land use (actual and future use )

Land use plan in the vicinity of the hazardous industries would require
indepth analysis to determine the likely effect of any spill in the area.

-10.2

Water supply

Demographic Information
The population of the industry as well as the neighboring areas is a key factor
for this type of planing. The information to be collected in this regard is :--

10.3

--

neighboring population

--

housing colonies of industries

--

sensitive institutions i.e. schools, hospitals

--

type of housing

--

Cattle / livestock

Meteorological Information
Meteorological data for a period of 10 years related to wind speed / direction,
humidity and temperature inversion is essential for preparation of dispersion
models for toxic gas release.

15

10.4

Seismic Data
Information regarding seismic zone and record of earthquake is considered
to be an important input in off-site planning.

11.0

Elements of off-site Planning

Typical off-site emergency plan should have the following important components:
Plan Pre-requisite (Background information)
*

Plan requirement (Aims & Objectives of the plan)

Planning Team

Hazard Analysis and Quantification

Scenario development

Assessment of Capabilities

Plan Development
*

Incident information

Authority for responding

Basic Assumption

Operation of the plan

Coordination with other plans

Emergency Assistance
*

Names and addresses of the key personnel

Telephone numbers

Response Functions
--

Initial Notification

--

Control Room

--

Access

--

Direction and Control

--

Communication amongst responders

16

--

Warning System / Emergency Notification

--

Public information

--

Resources Mobilization and Management

--

Health and Medical Response

--

Public protection including evacuation

--

Fire and Rescue

--

Law and order

--

On-going Incident Assessment

Besides the above, other elements of off-site planning are containment, clean up
and Disposals; Documentation and Investigation; Plan Testing and Updating and
Community Awareness, Preparedness and Training.
For developing an off-site plan of a particular locality, the elements of relevance to
the plan should be carefully selected. The elements would be based on locational
situations, hazards present, existence of vulnerable area in the vicinity and resource
availability etc.
The main-requisite of an off-site emergency plan is to define and lay down the clearcut objectives and requirements. As stated earlier, a planning team representing
local industries, response agencies and other bodies should be formed. The plan
should be based on a systematic hazard analysis of the units in the area and
scenarios based thereon. This should be done by the units and made available for
updating the plan. Resource planning has to be based on the assessment of
capabilities in the area.
Plan development should clearly indicate the format to be used for reporting
information related to accidents, basic assumptions in preparing the plans, plan
operation and dovetailing with other plans. The plan should include the names and
contact telephone numbers of persons responsible for emergency assistance.
Complete detailing of the response functions is the most important part of the plan.
The plan should cover details about Central Control Room, access to and from the
incident area, direction and control of emergency public information, resource
management, communication during emergencies, response personnel safety, ongoing incident assessment etc.
Specific roles of the police, fire fighting and medical personnel should be worked out
in the plan. The aspect of containment, clean-up and disposal should also be
covered in the plan. If it is not done properly, there could be secondary effect from
the accident. Testing and updating of the plan needs lot of preparatory work in the
form of training of teams, developing assessment mechanisms using observes and

17

mobilisation of resources. The role of adjacent awareness are also important

aspects of the plan.
11.1

List of Hazardous Installations

It is important to identify the hazardous units located in the area. Up-to-date
information regarding the on-site plans prepared by each individual unit is
required to be compiled for formulating the off-site plan for the area.

11.2

Off-site Control Room

The control of crisis during major accidents is to be exercised through a
Control Room established at an easily accessible central location in the
area. This Control Room should be capable of functioning on being required
to be activated at any time. The Control Room for off-site plan is thus over
and above the Control Room set up by each unit for its on-site plan. The
Control Room shall :(i)

Act as a focal point of emergency management.

(ii)

Keep records of all messages.

(iii)

Inform operation officer on receipt of first information relating to

accident.

(iv)

Monitor implementation of mutual aid.

(v)

Serve as the focal point for meeting of the Crisis Management Group
(CMG).

In order to operate the Control Room round the clock, manpower and
transport are required on a shift basis. The Control Room should be
equipped with proper communication system, data processing network and
should be a storehouse of information to combat emergencies.
11.3

Key Personnel and Their Duties

The ultimate responsibility for the management of the major emergency
rests on the District Magistrate / Collector.
He will be assisted by representatives from all concerned organizations,
departments and services at the District level. This group of officials forms
the District Crisis Management Group (CMG). The designation of the key
personnel of CMC and their duties are given in Annexure - III.
The members of the group may vary according to the District and local
conditions. The CMG will:-

18

(a)

Control all emergency operations.

(b)

Guide on matters related to policy issues.

(c)

Provide official information and instructions to the general public.

An Operation Response Group (ORC) will have to be put up to implement the

directions of the CMG. Probable members of this group may be as per
Annexure-4. The duties of the ORG are as under :-

11.4

(a)

To develop an integrated response strategy based on the available

information.

(b)

To plan deployment of field units to ensure the availability of

appropriate force to deal with the situation.

(c)

To coordinate the functioning of various agencies.

(d)

To deal with crisis and implement decisions of CMC.

(e)

To monitor the progress till the crisis ends and keep the CMG posted
with the development.

Communication Systems Network

An efficient and reliable Communication System is required for the success
of the off-site emergency plan. The efficient communication system is
required to alert :
(a)

Off-site Emergency Authorities and Services.

(b)

Neighboring factories in the area and public in the vulnerable zone.

A communication network of the following type may be helpful :(i)

Radio communication between Control Room to Unit Control Rooms

of the Industrial Units and respondents out side the area.

(ii)

Hotlines between Control Room to industrial units, Emergency

Services, Meteorological Station and the Media.

(iii)

Paging system with the Control Room for alerting the members of the
CMG and ORG.

(iv)

P&T Telephone Lines.

(v)

Data Processing Network hooked to all Computers / PCs.

A communication flow chart is to be prepared and kept in the Control Room.

An up-to-date Telephone Directory of personnel concerned with the

19

emergency should be available at all times. In coordinating the

communication system efficiently, there should be a Communication Officer
in Control Room to ensure that all the modes of communication are functional
round-the-clock. All communication operators should maintain a Log-book
for the messages received in/out and actions taken. These activities should
be incorporated in the data processing system.
11.5

Warning System
In an Off-Site Management Plan, one of the most important pre-requisites is
a good Warning System. Efficient
Warning System will save lives,
prevent injuries and reduce losses. Emergency Commander will decide the
appropriate Warning System and implement it. The Commissioner of
Police will be responsible for implementation of the Warning System.
The Warning System are of the following types :(a)

Disaster Warning (Maximum Credible Loss Scenario)

High pitched Continuous Wailing Siren.

(b)

Fire/Toxic Release
Long Siren Followed by short Siren

(c)

All Clear
Long Continuous

Depending upon the nature of hazards and the area affected, other methods
of warning may be as follows :(a)

Out-Door Warning Sirens.

(b)

Public Address System with Police.

(c)

ARP Sirens.

(d)

Mass Media

(e)

Door to door visit by Civil Defense Personnel

(f)

Telephonic contact with schools and other organizations/public

institutions.

(g)

Information to be provided at common gathering places such as

canteens, shops etc.

20

11.6

Public Information System

During a crisis following an accident, the people of the area and large
number of media representatives would like to know about the situation from
time to time and the response of the district authority to the crisis. It is
important to give timely information to the public in order to prevent panic
and rumor mongering. The emergency public information could be carried out
in three phases.

i.

Before the Crisis.

This will include the safety procedure to be followed during an emergency
through posters, talks and mass media in different languages including local
languages. Leaflets containing dos/donts should be circulated to educate
the people in the vicinity.

ii.

During the Crisis

Dissemination of information about the nature of the incidents, actions taken
and instructions to the public about protective measures to be taken,
evacuation, etc. are the important steps during this phase. This can be done
by using PAS, through radio/ television/ press.

iii.

After the Crisis

Attention should be focussed on information concerning restoration of
essential services, travel restrictions, etc.
Various tasks of the public information system could include :-

11.7

(a)

Quick dissemination of emergency instructions to the public.

(b)

To receive all calls from media/public regarding emergency situations

and respond meticulously.

(c)

Obtain current information from the Central Control Room.

(d)

Prepare news release.

(e)

Brief visitors / media.

(f)

Maintain contact with hospital and get information about the

casualties.

Fire fighting System

The industrial areas having major accident-prone hazardous installations
should have special fire fighting arrangements. In most of the industries,
gaseous hydro-carbons or liquid hydro-carbons having low flash points are
used thereby posing great risk of fire explosion, spillage of hazardous liquid

21

or release of toxic gases. In order to tackle such possible situations, there is

need for constant preparedness to mobilize all available fire fighting and
toxicity control resources in minimum time. There should be an inside control
of all fire fighting resources in the affected areas under the overall charge of
the Chief Fire Officer. The operational response will be coordinated from the
Central Control Room. The planning for fire fighting should be as follows :A.

Before the Crisis

(i)

Proper road and means of escape should be identified.

(ii)

Considering the possible hazards, there must be adequate water supply.

(iii)

Training of the personnel in fire fighting duties in the industry.

(iv)

Provision of adequate and proper arrangement of fire fighting vehicles is

important.

B.

During the Crisis

Immediate response to an emergency should be coordinated by the Control
Room by matching all the resources. In a major emergency having wide offsite implications, more than one industry would be affected necessitating
concurrent fire fighting operations at a number of places. In this case, the
whole area may be divided in different fire zones. The task of the fire zone
commanders should be as under :-

11.8

i.

Command and control of all fire fighting resources in the respective

fire zones.

ii.

Deployment of additional fire resources allocated by Control Room.

iii.

Coordination of fire fighting institutes.

Mutual Aid
All the industrial units in the affected areas should have mutual aid
arrangement for getting/extending help in fire fighting facilities, special fire
fighting agents, trained manpower, etc. The Control Room will allocate
additional resources to fire zone including protective equipment kept centrally
as a pool.

22

11.9

Services Support System

11.9.1 Health and Medical

A major off-site emergency in an area may affect a number of units and the
surrounding colonies resulting in more casualties. The medical response plan
has to cater for immediate pooling of all available medical resources and
provide emergency medical treatment to the victims of the incident. For an
emergency from poisoning of all available local medical resources in the
incident area as well as the additional resources should be mobilized under
the overall charge of the District Health Department. The operational
response should be coordinated by the Chief Medical Officer from the control
Room. Before the crisis, the following actions should be carried out :i.

Specialized training of doctors relating to chemicals hazards.

ii.

Blood grouping of all employees working in the industrial unit.

iii.

Maintenance of list of blood donors group wise.

iv.

Arrangement of adequate buffer stock of essential medicines.

v.

Stocking of anti-dotes and special medicines for hazardous

substances.

vi.

Planning of additional capacity in the base hospital for large-scale

casualties.

During the crisis, medical plan in terms of manpower, transport and

equipment as per organizational response be implemented. The
organizational response be implemented. The organizational response
structure should be set up as under :
(a)

First-aid Post

(b)

Casualty Response Centre

(c)

Base Hospital

It is essential to guide medical relief and establish public health measures

like sanitation, immunization, etc. In the absence of proper information about
the chemical exposure, their symptoms, first-aid and treatment, the
physicians attending such emergencies are generally faced with great
problems. The Emergency Response Centre, Bhopal do have the information
on widely used toxic chemicals and this may be contacted in times of such
needs.

23

11.9.2 Transportation
A large number of ambulances would be necessary to transport casualties to
the casualty response centre and base hospital. For this purpose,
jeeps/matadors/special wagons which can be converted as ambulance at
short notice should be kept at the unit and the Control Room.
11.9.3 Security and Police
Security , protection of life and property and traffic control and maintenance
of law and order are the traditional and statutory functions of the police.
During an emergency, duties and responsibilities of the police may be :i.

Cordoning of the incident area

ii.

Warning public about the hazards

iii.

Traffic Control

iv.

Assist fire fighting services

v.

Assist first-aid medical teams

vi.

Assist evacuation and ensure protection of property in evacuated

areas.
Control of security operations in the area should be exercised by the
Deputy Commissioner of Police. Different phases of emergency
management practices would be as under :-

(a)

Before the Crisis

Contingency plan of manpower, transport and communication
network to coordinate possible incident areas and to regulate traffic
should be made for each industry in the area.

(b)

During the Crisis

The Security Commander of the area will set in motion the relevant
contingency plan to control the operation.

(c)

After the Crisis

Protect property in the evacuated area.

11.9.4 Media
The Control Room should release an up-to-date information to the media.

24

11.10 Evacuation Including Safe Evacuation Areas

In a disaster situation, evacuation is the movement of people from the place
of danger to places of relative safety. It is most effective action to protect
people. A comprehensive and coordinated planning is necessary to
implement orderly evacuation of population.
The process of evacuation should be based on the nature of threat.
Possibility of spreading of toxic gases and weather conditions. In this case,
the hazard analysis in maximum credible loss scenario would help in
planning of evacuation. The people of the area should be advised to leave
the threatened area and to take shelter in the nearest reception centres. The
whole process is required to be completed within quickest possible time. The
command and control of the evacuation should be under the supervision of
the District Development Officer. The evacuation process should be carried
out in three phases.
A.

Before the Crisis

(i) The public should be informed and educated properly for chemical
hazards. Local police should warn the people in this regard and install the
siren in the vulnerable places.
(ii) The probable affected should be divided in several evacuation centres
which are entirely site specific.

B.

(iii)

Detailed contingency plan of evacuation of various scenarios should

be prepared.

(iv)

Availability of all transport resources needs to be ensured. Planning of

adequate reception centers including accommodation, food, water
supply and sanitary arrangements for the affected population should
be done.

During Crisis
Implementation of the plan should be done in the quickest possible time.

C.

After the Crisis

Once the crisis is over, the affected people should be rehabilitated and the
follow up measures should be taken up.

25

11.11 Relief to the Victims

Post emergency activities include the relief to the victims. The Public Liability
Insurance Act (PLI Act), 1991 provides for the owner who has control over
handling hazardous substances to pay specified amount of money to the
victims as interim relief by taking insurance policy for this purpose. The
District Collector has definite role in implementation of the PLI act, 1991.
After proper assessment of the incident, he may invite applications for relief,
conduct an enquiry into the claims and arrange payment of the relief amount
to the victims.
12.0

Checklist for Capability Assessment

The checklist will help in assessing the preparedness, prevention and response
resources capabilities. A detailed checklist is given in Annexure IV. The points
included in the checklist are only indicative and the planner should closely examine
the local requirements while preparing the checklist.

26

Annexure -I

COMPONENTS OF ON-SITE EMERGENCY PLAN

(As per Schedule 11 of MSIHC Rules)

1.

Name and address of the person furnishing the information.

2.

Key personnel of the organization and responsibilities assigned to them in case of

an emergency

3.

Outside organizations if involved in assisting during on-site emergency :

(a)
(b)

Type of accident .
Responsibilities assigned

4.

Details of liaison arrangement between the organisations.

5.

Information on the preliminary hazard analysis :

(a)
(b)
(c)
(d)

6.

Details about the site :

(a)
(b)
(c)

7.

Type of accidents
System elements or events that can lead to a major accident
Hazards
Safety relevant components.

Location of dangerous substances.

Seat of key personnel.
Emergency control room

Description of hazardous chemicals at plant site :

(a)
(b)
(c)

Chemicals (Quantities and toxicological data).

Transformation, if any, which could occur.
Purity of hazardous chemicals.

8.

Likely dangers to the plant.

9.

Enumerate effects of :
(I)
(II)

10.

stress and strain caused during normal operation

fire and explosion inside the plant and effect, if any,
of fire and explosion out side.

Details regarding :
(i)

warning, alarm and safety and security systems.

27

(ii)
(iii)
(iv)
(v)
(vi)

alarm and hazard control plans inline with disaster control and hazard control
planing, ensuring the necessary technical and organizational precautions.
reliable measuring instruments, control units and servicing of such
equipment.
Precautions in designing of the foundation and load bearing parts of the
building.
Continuous surveillance of operations.
Maintenance and repair work according to the generally reorganized rules of
good engineering practices.

11.

Details of communication facilities available during emergency and those required

for an off-site emergency.

12

Details of fire fighting and other facilities available and those required for an off-site
emergency.

12.

Details of first aid and hospital services available and its adequacy.

28

Annexure - II

COMPONENTS OF OFF-SITE EMERGENCY PLAN

(As per Schedule 12 of MSIHC Rules)

1.

The type of accidents and release to be taken into account.

2.

Organizations involved including key personnel and responsibilities and liaison

arrangements between them.

3.

Information about the site including likely locations of dangerous substances,

personnel and emergency control rooms.

4.

Technical information such as chemical and physical characteristics and dangers of

the substance and plant.

5.

Identify the facilities and transport routes.

6.

Contact for further advice e.g. meteorological information, transport, temporary food
and accommodation, first aid and hospital services, water and agricultural
authorities.

7.

Communication links including telephones, radios and standby methods.

8.

Special equipment including fire fighting materials damage control and repair items.

9.

Details of emergency response procedures.

10.

Notify the public.

11.

Evacuation arrangements.

12.

Arrangements for dealing with the press and other media interests.

13.

Longer terms clean up

29

Annexure III
DUTIES OF CRISIS MANAGEMENT GROUP (CMG) MEMBERS

1.

Collector/District Magistrate
(a)
(b)
(c)
(d)
(e)
(f)
(g)

2.

Commissioner of Police
(a)
(b)
(c)
(d)
(e)
(f)
(g)
(h)
(i)

3.

Organise Reception Centres.

Arrange shelter, food, water, etc. for evacuees.
Co-ordinate resources of voluntary organisations.
Organise transportation arrangements for evacuation.

Deputy Director Health

(a)
(b)
(c)
(d)
(e)
(f)

5.

Maintain law & order during emergency.

Regulate traffic in and around the emergency area.
Control entry to the emergency area.
Security arrangements at each industrial unit.
Protect vital installations.
Warn public about the emergency.
Assist in evacuating and sheltering.
Protect evacuated areas.
Assist emergency services in the performance of their duties.

Municipal Commissioner
(a)
(b)
(c)
(d)

4.

As Chairman of CMG, implement off-site plan.

Exercise control on emergency operations.
Give guidance/decision on matters of basic policy.
Review operational preparedness of district emergency machinery.
Hold periodic mock/training exercise to ensure optimum operational
preparedness.
Develop off-site scenarios, domino and cascading effect based on on-site
plans of the industries.
Provide relief under Public Liability Insurance Act, 1991.

Mobilisation of emergency medical and health services.

Public health services in Reception Centres.
First aid arrangements and availability of on-site requirements for industries.
Medical supply of antidotes.
Corpe disposal services.
Co-opt voluntary organisation like Red Cross, etc.

Pollution Control Board

The Pollution Control Board shall have the following roles and responsibilities :

30

Upon receipt of information from the District Control Room, an officer of the Pollution
Control Board shall proceed to the affected site.
Pollution Control Board officer shall conduct investigation that may be necessary on
the incident including collection of data and information relating there to.
In the event of a spill, the pollution Control Board officer shall ensure that the spill
has been totally contained with no further damage possible to human and the
environment.
In case of any contamination to the environment, to arrange, with the help of the
industry and other agencies, the decontamination of the area. Further, to declare the
area fit for re-entry after the decontamination is completed.
In the case of an environmental disaster, the Pollution Control Board officer shall,
based on the contaminant released into the environment, carry out, with the help of
the industry and other agencies, such investigations as may be necessary to
establish the degree of contamination. He shall then arrange for suitable
decontamination using the resources available in the area as well as with the Board.

31

Annexure - IV
OPERATIONAL RESPONSE GROUP (ORG)

S.
No.

Members

Add.

Tel. No. Alternate Add.

Off. / Res. Member

1. Resident Deputy
Collector,
2. Principal Industrial
Health Officer
3. Representative of
Police Commissioner
4. Representative of RTO/
Divisional Controller
5. Representative of Sr.
Inspector of Factories
6. Representative of
Concerned industry
7. Representative of
Civil Defence
8. Executive Engineer
(R & D)
9. Representative of
Railways.
10. Representative of Dy.
Controller, Explosives
11. Representative of Army
12. Representative of
Telecommunications
13. Meteorological officer

32

Tel. No.
off. / Res.

Annexure V
CHEMICAL RESISTANCE CHART FOR GLOVES

Chemical

Plastic
PVC

Natural
Rubber

Neoprene

Nitrile

NR

Acids, Mineral
Chromic
Hydrochloric (HCl)

10%

Hydrochloric (HCl)

36%

Hydrofluoric

10%

Muriatic
Nitric

10%

Nitric

20%

Sulfuric

10%

Sulfuric

20%

84%

Citric

Formic

Benzyl

Ethyl

Organic Acids
Acetic

Lactic
Oxalic

88%

Alcohol

33

Methyl

Acetaldehyde

Benzaldehyde

Formaldehyde

Amm. Hydroxide

26% G

Pot. Hydroxide

45%

Sod. Hydroxide

50 % G

Benzene

NR

Stoddards

Toluene

NR

Xylene

NR

Carbon tetrachloride

NR

Chlorobenzene

NR

Perchloroethylene

NR

Trichloroethylene

NR

Aldehydes

Aliphatic Solvents
Mineral Spirits

Alkalis

Aromatic Solvents

Chlorinated Solvents

Acetates
Butyl Acetate

34

Ethyl Acetate

Diethylamine

Methylamine

Airplane Hydraulic Oil

Animal Fats

Cutting Oil

Linseed Oil

Mineral Oil

Vegetable Oil

Carbon Dioxide

Nitrous Oxide

Acetone

Methyl Ethyl (MEK)

NR

NR

Methyl Isobutyl

NR

Esters

Ethers
Ethyl Ether

Oils and Fats

Oxides

Ketones

Inorganic Salts
Copper Sulfate

35

Annexure VI
CHEMICAL RESISTANCE / PHYSICAL PROPERTIES CHART FOR SUITS

Chemgard
Clothing

Chempruf
Clothing

TYVEK
Fabric
Clothing

NR

Alcohol
Methanol, Butyl alcohol,
Glycerin Ethanol,
Isopropanol

Caustics
Ammonium hydroxide 38%
Sodium hydroxide 50%
Potassium hydroxide 50%

Chlorinated Solvents
Carbon tetrachloride
Perchlorethylene,
Trichloroethylene
Ethylene dibromide

Ketones
Methyl
Isobutyl ketone, Acetone

Petroleum Solvents
White gasoline, Naphtha,
Mineral, thinner, Kerosene

Organic Acids
Citric, Formic, Tannic, Acetic

36

Inorganic Acids
Hydrochloric 38%
Hydrochloric 10%
Sulfuric 10%, Nitric 10%
Chromic

F
F
G

P
G
P

F
G
G

Lacquer thinner

Cutting oil

Battery acid

Phenol

NR

Insecticides

Printing ink

Dyestuffs

Pentane

Formaldehyde,
Isodecaldehyde

Vegetable oil

Animal fat

Acrylonitrile, Acetonitrile

NR

Steam

Aniline

Sulfuric 98%, Nitric 70%

Hydrocarbons
Stoddard solvent, Toluene
Benzene, xylene
Coal tar distillate
Styrene

Miscellaneous

37

Hydraulic fluid

Turpentine

Linseed Oil

Soya bean oil

Carbon disulfide

Creosote

Paint and varnish remover

Abrasion resistance

Cut resistance

Snag resistance

Heat resistance

Low-temperature resistance

Flexibility

Physical Properties

Key to Ratings :
E -

Excellent Chemical has no apparent effect as tested in a laboratory.

G -

Good Chemical has very little effect.

F -

Fair - Chemical has minor or moderate effect.

P -

Poor Chemical has a pronounced effect.

NR - Glove is not recommended for use.

38

Annexure VII

HAZARDOUS CHEMICALS

S.No

Name of Chemical

C.A.S. No.

R.T.E.C.S.

Remarks

1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
13.
14.
15.
16.
17.
18.
19.
20.
21.
22.
23.
24.
25.
26.
27.
28.
29.
30.
31.
32.
33.
34.
35.
36.
37.
38.
39.
40.

Acetaldehyde
Acetic acid
Acetic anhydride
Acetone
Acetone cyanohydrin
Acetone thiosemicarbazide
Acetonitrile
Acetylene
Acetylene tetra chloride
Acrolein
Acrylamide
Acrylonitrile
Adiponitrile
Aldicarb
Aldrin
Ally alcohol
Allyl amine
Allyl chloride
Aluminium (powder)
Aluminium azide
Aluminium borohydride
Aluminium chloride
Aluminium fluoride
Aluminium phophide
Amino diphenyl
Amino pyridine
Aminophenol-2
Aminopterin
Amiton
Amiton dialate
Ammonia
Ammonium chloro platinate
Ammonium nitrate
Ammonium nitrite
Ammonium picrate
Anabasine
Aniline
Aniline2,4,6-Trimethyl
Anthraquinone
Antimony pentafluoride

75-07-0
64-19-7
108-24-7
67-64-1
75-86-5
1752-30-3
75-05-8
74-86-2
79-34-5
107-02-8
79-06-1
107-13-1
111-69-3
116-06-3
309-00-2
107-18-6
107-11-9
107-05-1
7429-90-5
39108-14-0
7446-70-0
7784-18-1
20859-73-8
92-67-1
504-29-0
95-55-6
54-62-6
78-53-5
7664-41-7
16919-58-7
6484-52-2
131-74-8
494-52-0
62-53-3
88-05-1
84-65-1
7783-70-2

AB 1925000
AF 1225000
AK 1925000
AL 3150000
OD 9275000
AL 7700000
AO 9600000
KI 8575000
AS 1050000
AS 3325000
AT 5250000
AV 2625000
IO 2100000
BA 5075000
BA 5425000
UC 7350000
BD 0330000
BD 0525000
BD 0725000
BD 1400000
DU 8925000
US 1575000
SJ 49500000
BO 0875000
BR 9050000
BS 3855000
BV 4375000
BW 6650000
CB 4725000
CC 5800000

T, F
C
C
F
T
T, F
F, R
T
T, F
T
T, F
T
T
T, F
HR-3, T, F
T
HR-3
E, F
HR-3, R
HR-3, R
HR-3, T
T
T
HR-3, T
T
T

39

T
T
HR-3, T
E
HR-3, O
HR-3, T
T
T
HR-2, T
HR-3, T

41.
42.
43.
44.
45.
46.
47.
48.
49.
50.
51.
52.
53.
54.
55.
56.
57.
58.
59.
60.
61.
62.
63.
64.
65.
66.
67.
68.
69.
70.
71.
72.
73.
74.
75.
76.
77.
78.
79.
80.
81.
82.
83.
84.
85.
86.

Antimycin A
ANTU
Arsenic pentoxide
Arsenic trioxide
Arsenous trichoride
Arsine
Asphalt
Azinphos-ethyl
Azinphos methyl
Bacitracin
Barium azide
Barium nitrate
Barium nitride
Benzal chloride
Benzenamine, 3-Trifluoromethyl
Benzene
Benzene sulfonyl chloride
Benzene, 1-(chloromethyl)-4 Nitro
Benzene arsenic acid
Benzidine
Benzidine salts
Benzimidazole, 4,5-Dichloro-2
(Trifluoromethyl)
Benzoquinone-P
Benzotrichloride
Benzoyl chloride
Benzoyl peroxide
Benzyl chloride
Beryllium (powder)
Bicyclo(2,2,1) Heptane-2carbonitrile
Biphenyl
Bis (2-chloroethyl) sulphide
Bis (Chloromethyl) Ketone
Bis (Tert-butyl peroxy) cyclohexane
Bis (Terbutylperoxy) butane
Bis (2,4,6-TriNitrophenyl) amine
Bis (Chloromethyl) Ether
Bismuth and compounds
Bisphenol-A
Bitoscanate
Boron Powder
Boron trichloride
Boron trifluoride
Boron trifluoride comp. with
methylether 1:1
Bromine
Bromine pentafluoride
Bromo chloro methane

1397-94-0
86-88-4
1303-28-2
1327-53-3
7784-34-1
7784-42-1
8052-42-4
2642-71-9
86-50-0
1405-87-4
18810-58-7
10022-31-8
12047-79-9
100-44-7
71-43-2
98-09-9
92-87-5
92-87-5
-

CD 0350000
YT 9275000
CG 2275000
CG 3325000
CG 6475000
CI 9900000
TE 1925000
CP 0175000
CQ 8500000
CQ 9625000
CY 1400000
DB 8750000
DC 9625000
DC 9625000
-

HR-3
T
HR-3, T
HR-3, T
T
T
HR-3, T
T
HR-3, T
HR-3
HR-3, E
R
HR-3, E
T

106-51-4
94-36-0
100-44-7
7440-41-7
-

DK 2625000
DM 8575000
XS 8925000
DS 1750000
-

HR-3, T
T
R, T
T, E
T
T
-

92-52-4
505-60-2
534-07-6
542-88-1
7440-69-9
80-05-7
7440-42-8
10294-34-5
7637-07-2
353-42-4

DU 8050000
ED 7350000
ED 1925000
-

T
T
R
R
T, E
T
HR-3, T
HR-3, T
T
T

7726-95-6
7789-30-2
74-97-5

EF 9100000
EF 9350000
PA 5250000

T
T, C
T

40

T, F
HR-3, T
T
T
HR-3, T
-

87.
88.
89.
90.
91.
92.
93.
94.
95.
96.
97.
98.
99.
100.
101.
102.
103.
104.
105.
106.
107.
108.
109.
110.
111.
112.
113.
114.
115.
116.
117.
118.
119.
120.
121.
122.
123.
124.
125.
126.
127.
128.
129.
130.
131.
132.
133.
134.
135.

Bromodialone
Butadiene
Butane
Butanone-2
Butyl amine tert
Butyl glycidal ether
Butyl isovalarate
Butyl peroxymaleate tert
Butyl vinyl ether
Butyl-n-mercaptan
C.1. Basic green
Cadmium oxide
Cadmium stearate
Calcium arsenate
Calcium carbide
Calcium cyanide
Camphechlor (Toxaphene)
Cantharidin
Captan
Carbachol chloride
Carbaryl
Carbofuran (Furadan)
Carbon tetrachloride
Carbon disulphide
Carbon monoxide
Carbophenothion
Carvone
Cellulose nitrate
Chloroacetic acid
Chlordane
Chlorofenvinphos
Chlorinated benzene
Chlorine
Chlorine oxide
Chlorine trifluoride
Chlormephos
Chlormequat chloride
Chloroacetal chloride
Chloroacetaldehyde
Chloroaniline-2
Chloroaniline-4
Chlorobenzene
Chloroethyl chloroformate
Chloroform
Chloroformyl morpholine
Chloromethane
Chloromethyl methyl ether
Chloronitrobenzene
Chlorophacinone

28772-56-7
106-99-0
106-97-8
78-93-3
75-64-9
2426-08-6
109-79-5
1306-19-0
7778-44-1
75-20-7
592-01-8
133-06-2
51-83-2
63-25-2
1563-66-2
56-23-5
75-15-0
630-08-0
786-19-6
8050-88-2
79-11-8
57-74-9
470-90-6
7782-50-5
10049-04-4
7090-91-2
24934-91-6
999-81-5
107-20-0
106-47-8
108-90-7
67-66-3
74-87-3
107-30-2
25167-93-5
3691-35-8

41

EJ 4200000
EL 6475000
EO 3330000
TX 4200000
EK 6300000
EV 1930000
CG 0830000
EV 9400000
EW 0700000
GW 5075000
GA 0875000
FC 5950000
FB 9450000
FG 4900000
FF 6650000
FG 3500000
AF 8575000
PB 9800000
FO 2100000
FO 3000000
FO 2800000
TD 5170000
AB 2450000
CZ 0175000
FS 9100000
PA 6300000
KN 6650000
CZ 0855000
NK 5335000

R
F
T, R
HR-3, T, F
HR-D
T
T
HR-3
HR-3
HR-3
T
T
T
T, F
T, F
T
E, F
HR-3
T
T
T
HR-3
C
T, F
T
T
T
HR-D
HR-3

136.
137.
138.
139.
140.
141.
142.
143.
144.
145.
146.
147.
148.
149.
150.
151.
152.
153.
154.
155.
156.
157.
158.
159.
160.
161.
162.
163.
164.
165.
166.
167.
168.
169.
170.
171.
172.
173.
174.
175.
176.
177.
178.
179.
180.
181.
182.

Chlorosulphonic acid
Chlorothiophos
Chloroxuron
Chromic acid
Chromic chloride
Chromium powder
Cobalt carbonyl
Cobalt Nitrilmethylidyne compound
Cobalt (powder)
Colchicine
Copper and compounds
Copper oxychloride
Coumafuryl
Coumaphos
Coumateralyl
Crimidine
Crotenaldehyde
Crotonaldehyde
Cumene
Cyanogen bromide
Cyanogen iodide
Cyanophos
Cyanothoate
Cyanuric fluoride
Cyclo hexylamine
Cyclohexane
Cyclohexanone
Cycloheximide
Cyclopentadiene
Cyclopentane
Cyclotetramethylenetetranitramine
CyclotrimethylenetrinitraMine
Cypermethrin
DDT
Decaborane (1:4)
Demeton
Demeton S-Methyl
Di-n-propyl peroxydicarbonate
(Conc. 80%)
Dialifos
Diazodinitrophenol
Dibenzyl peroxydicarbonate (Conc >
= 90%)
Diborane
Dichloroaceylene
Dichlorobenzalkonium chloride
Dichloroethyl ether
Dichloromethyl phenylisilane
Dichlorophenol-2,6

7790-94-5
21923-23-9
1982-47-4
1333-82-0
10025-73-7
7740-47-3
10210-68-1
7440-48-4
64-86-8
7440-50-8
56-72-4
123-73-9
4170-30-3
98-82-8
108-91-8
110-82-7
108-94-1
66-81-9
542-92-7
287-92-3
121-82-4
50-29-3
17702-41-9
298-03-3
919-86-8
-

TF 1590000
GB 6650000
GB 4200000
GG 0300000
GF 8750000
GL 5325000
GP 9499000
GR 8575000
GX 0700000
GU 6300000
GW1050000
GY 1000000
GY 2390000
XY 9450000
KJ 3325000
HD 1400000
TF 3125000
TG 1750000
-

E
E
HR-3, T
HR-3
HR-3, T
HR-3
R

T
E
-

19287-45-7
7572-29-4
87-65-0

HQ 9275000
AP 1080000
SK 8750000

HR-3
HR-3

42

C
HR-3
T, E
T, E
T, E
T
T
HR-3, T
T
T
T
T, F
T
T, F
T
T, F

183.
184.
185.
186.
187.
188.
189.
190.
191.
192.
193.
194.
195.
196.
197.
198.
199.
200.
201.
202.
203.
204.
205.
206.
207.
208.
209.
210.
211.
212.
213.
214.
215.
216.
217.
218.
219.
220.
221.
222.
223.
224.
225.
226.
227.
228.

Dichlorophenol-2,4
Dichlorophenoxy acetic acid
Dichloropropane-2,2
Dichlorosalicylic acid-3,5
Dichlorvos (DDVP)
Dicrotophos
Dieldrin
Diepoxy butane
Diethyl carbamazine citrate
Diethyl chlorophosphate
Diethyl ethanolamine
Diethyl peroxydicarbonate (Conc. 30
%)
Diethyl phenylene diamine
Diethylamine
Diethylene glycol
Diethylene glycol dinitrate
Diethylene triamine
Diethyleneglycol butyl ether
Diglycidyl ether
Digitoxin
Dihydroperoxypropane (Conc > =
30%)
Diisobutyl peroxide
Dimefox
Dimethoate
Dimethyl dichlorosilane
Dimethyl hydrazine
Dimethyl nitrosoamine
Dimethyl P phenylene diamine
Dimethyl phosphoramido cyanidic
acid (TABUM)
Dimethyl phosphorochloridothioate
Dimethyl sufolane (DMS)
Dimethyl sulphide
Dimethylamine
Dimethylaniline
Dimethlcarbonyl chloride
Dimetilan
Dinitro O-cresol
Dinitrophenol
Dinitrotoluene
Dinoseb
Dinoterb
Dioxane-p
Dioxathion
Dioxine N
Diphacinone
Diphosphoramide octamethyl

120-83-2
94-75-7
594-20-7
320-72-9
62-73-7
141-66-2
60-57-1
298-18-0
1642-54-2
814-49-3
100-37-8
-

SK 8575000
AG 6825000
VO 2450000
TC 0350000
TC 3850000
IO 1750000
EJ 8400000
TL 1225000
TD 1400000
KK 5075000
-

HR-3
HR-3
HR-3
HR-3
T
HR-3
HR-3
HR-3
HR-3
HR-3
R

109-89-7
111-46-6
693-21-0
111-40-0
112-34-5
2238-07-5
71-63-6
-

HZ 8750000
ID 5950000
ID 6825000
IE 1225000
KJ 9100000
KN 2350000
IH 2275000
-

HR-2, T
HR-3
HR-3, E
HR-3
HR-3
HR-3
HR-3
R

115-26-4
60-51-5
75-78-5
57-14-7
62-75-9
99-98-9
-

MV 2450000
IQ 05250900
ST 0874000
-

R
T
HR-3
HR-3
HR-3
T

2524-03-0
1003-78-7
75-18-3
124-40-3
121-69-7
1335-85-9
25550-58-7
25321-14-6
123-91-1
78-34-2
1746-01-6
82-66-6
-

TD 1830000
XN 0525000
IP 8750000
BX 4725000
GO 9450000
SL 2625000
XT 1300000
JG 8225000
TE 3350000
HP 3500000
-

HR-3
HR-3
HR-3
HR-3
HR-3, T
T
HR-3
HR-3, T, E
HR-3
HR-3, T, F
HR-3
T
-

43

229.
230.
231.
232.
233.
234.
235.
236.
237.
238.
239.
240.
241.
242.
243.
244.
245.
246.
247.
248.
249.
250.
251.
252.
253.
254.
255.
256.
257.
258.
259.
260.
261.
262.
263.
264.
265.
266.
267.
268.
269.
270.
271.
272.
273.
274.
275.

Diphenyl methane di-isocynate

(MDI)
Dipropylene Glycol Butyl ether
Dipropylene glycol methylether
Disec-butyl peroxydicarbonate (conc.
> 80 %)
Disufoton
Dithiazamine iodide
Dithiobiurate
Endosulfan
Endothion
Endrin
Epichlorohydrine
EPN
Ergocalciferol
Ergotamine tartarate
Ethanesulfenyl chloride, 2 chloro
Ethanol 1-2 dichloracetate
Ethion
Ethoprophos
Ethyl acetate
Ethyl alcohol
Ethyl benzene
Ethyl bis amine
Ethyl bromide
Ethyl carbamate
Ethyl ether
Ethyl hexanol-2
Ethyl mercaptan
Ethyl mercuric phosphate
Ethyl methacrylate
Ethyl nitrate
Ethyl thiocyanate
Ethylamine
Ethylene
Ethylene chlorohydrine
Ethylene dibromide
Ethylene diamine
Ethylene diamine hydrochloride
Ethylene flourohydrine
Ethylene glycol
Ethylene glycol dinitrate
Ethylene oxide
Ethyleneimine
Ethylene di chloride
Fenamiphos
Femitrothion
Fensulphothion
Fluenetil

101-68-8

NQ 9350000

HR-3

29911-28-2
34590-94-8
-

UA 8225000
JM 1575000
-

HR-2
HR-1
-

298-04-4
541-53-7
115-29-7
2778-04-3
72-20-8
106-89-8
2104-64-5
50-14-6
379-79-3
563-12-2
13194-48-4
141-78-6
64-17-5
100-41-4
74-96-4
60-29-7
75-08-1
97-63-2
625-58-1
542-90-5
75-04-7
74-85-1
107-07-3
106-93-4
107-15-3
371-62-0
107-21-1
628-96-6
75-21-8
151-56-4
75-34-3
22224-92-6
122-14-5
115-90-2
-

TD 9275000
EC 1575000
RB 9275000
TF 8225000
IO 1575000
TX 4900000
TB 1925000
KE 1050000
TE 4550000
AH 5425000
KQ 6300000
DA 0700000
KH 6475000
KI 5775000
KI 9625000
QU 7900000
XK 9900000
KH 2100000
KU 5340000
KK 0875000
KH 9275000
KH 8575000
KW 2975000
KW 5600000
KX 2450000
KX 5075000
KI 0175000
TB 3675000
TF 3850000
-

T
HR-3
HR-3
HR-3
T, F
T
HR-3
T
HR-3, F
HR-3, F
HR-3
T
HR-3
T, F
HR-3, TER
HR-3
HR-3
T
HR-3
C, F
HR-3
HR-3, T, E
HR-3, TFR
T, F
T

44

276.
277.
278.
279.
280.
281.
282.
283.
284.
285.
286.
287.
288.
289.
290.
291.
292.
293.
294.
295.
296.
297.
298.
299.
300.
301.
302.
303.
304.
305.
306.
307.
308.
309.
310.
311.
312.
313.
314.
315.
316.
317.
318.
319.
320.

Fluorine
Fluoro 2-hydroxy butyric acid amide
salt ester
Fluoroacetamide
Fluoroacetic acid amide salts and
esters
Fluoroacetylchloride
Fluorobutric acid amide salt esters
Flurocrotonic acid amides salts esters
Fluorouracil
Fonofos
Formaldehyde
Formetanate hydrochloride
Formic acid
Formoparanate
Formothion
Fosthiotan
Fuberidazole
Furan
Gallium Trichloride
Glyconitrile (Hydroxyacetonitrile)
Guanyl-4-nitrosaminoguynyl-1tetrazene
Heptachlor
Hexa methyl terta-oxyacyclononate
(conc. 75%)
Hexachlorobenzene
Hexachlorocyclohexan (Lindane)
Hexachlorocyclopentadiene
Hexachlorodibenzo-p-dioxin
Hexachloronapthalene
Hexafluoropropanone sesquihydrate
Hexamethyl phosphoroamide
Hexamethylene diamine N N dibutyl
Hexane
Hexanitrostilbene 2,2,4,4,6,6
Hexene
Hydrogen selenide
Hydrogen sulphide
Hydrazine
Hydrazine nitrate
Hydrochloric acid (Gas)
Hydrogen
Hydrogen bromide
Hydrogen cyanide
Hydrogen fluoride
Hydrogen peroxide
Hydroquinone
Indene

7782-41-4
-

LM 6475000
-

HR-3, T
T

640-19-7
-

AC 1225000
-

HR-3, T
T

51-21-8
944-22-9
50-00-0
64-18-6
17702-57-7
2540-82-1
21548-32-3
110-00-9
7440-55-3
107-16-4
-

YR 0350000
TA 5950000
LP 8925000
LQ 4900000
FB 9880000
LT 8524000
LW 8610000
AM 0350000
-

T
T
HR-3
HR-3, T
HR-3
HR-3
HR-3
HR-3
E

76-44-8
-

PC 0700000
-

HR-3, E
R

118-74-1
58-89-9
77-47-4
57653-85-7
1335-87-1
13098-39-0
680-31-9
110-54-3
592-41-6
7783-07-5
7783-06-4
302-01-2
7647-01-0
1333-74-0
10035-10-6
74-90-8
7664-39-3
7722-84-1
123-31-9
95-13-6

DA 2975000
GV 4900000
GY 1225000
HP 3280000
QJ 7350000
UC 2660000
TD 0875000
MN 9275000
MP 6600100
MX 1050000
MX 1225000
MU 7175000
MW4025000
MW8900000
MW3850000
MW6825000
MW7875000
MX 0900000
MX 3500000
NK 8225000

HR-3
HR-3
HR-3
HR-3
HR-3
HR-3
HR-3
E
HR-3
HR-3, T
HR-3, T, F
HR-3
HR-3, T
HR-3, F, R
T, F
T, C
HR-3
HR-3
HR-3

45

321.
322.
323.
324.
325.
326.
327.
328.
329.
330.
331.
332.
333.
334.
335.
336.
337.
338.
339.
340.
341.
342.
343.
344.
345.
346.
347.
348.
349.
350.
351.
352.
353.
354.
355.
356.
357.
358.
359.
360.
361.
362.
363.
364.
365.

Indium powder
Indomethacin
Iodine
Iridium tetrachloride
Iron penta carbonyl
Isobenzan
Isoamyl alcohol
Isobutyl alcohol
Isobutyro nitrile
Isocyanic acid 3 4-dichlorophenyl
ester
Isodrin
Isofluorophosphate
Isophorone diisocyanate
Isopropyl alcohol
Isopropyl chlorocarbonate
Isopropyl formate
Isopropyl methyl pyrazolyl dimethyl
carbamate
Juglone (5-Hydroxy Napthalene-1, 4
dione)
Ketene
Lactonitrile
Lead arsenite
Lead at high temp (molten)
Lead azide
Lead styphanate
Leptophos
Lenisite
Liquified petroleum gas
Lithium hydride
N-Dinitrobenzene
Magnesium powder or ribbon
Malathion
Maleic anhydride
Malononitrile
Managanese Tricarbonyl
cyclopentadiene
Mechlor ethamine
Mephospholan
Mercuric chloride
Mercuric oxide
Mercury acetate
Mercury fulminate
Mercury methyl chloride
Mesitylene
Methaacrolein diacetate
Methacrylic anhydride
Methacrylonitrile

7440-74-6
53-86-1
7553-56-2
10025-97-5
13463-40-6
297-78-9
123-51-3
78-83-1
78-82-0
102-36-3

NL 1050000
NL 3500000
NN 1575000
NO 3610000
NO 4900000
EL 5425000
NP 9625000
TZ 4900000
NQ 8760000

HR-3
HR-3
HR-3
T
HR-3
HR-3
HR-3
HR-3

465-73-6
4098-71-9
67-63-0
108-23-6
625-55-8
-

IO 1925000
NQ 5400000
NT 8050000
LQ 6475000
LQ 8750000
-

HR-3, T
HR-3
HR-3
HR-3
HR-3
-

463-51-4
78-97-7
10031-13-7
7439-92-1
13424-46-9
21609-90-5
68476-85-7
7580-67-8
7439-95-4
121-75-5
108-31-6
109-77-3
-

OA 7700000
OD 8225000
OF 8600000
OF 7525000
OF 8650000
TB 1720000
SE 7545000
OJ 6300000
OM 2100000
WM8400000
ON 3675000
OO 3150000
-

HR-3
HR-3
HR-3
HR-3, E
HR-3
HR-2
HR-3
HR-3
HR-3, T
HR-3
-

950-10-7
7487-94-7
21908-53-2
7439-97-6
628-86-4
115-09-3
108-67-8
10476-95-6
760-93-0
126-98-7

JP 1050000
OW 8750000
OV 4550000
OW 4050000
OW 1225000
OX 6825000
OZ 5700000
UD 1400000

HR-3
HR-3
HR-3, E
HR-3
HR-3
HR-3
-

46

366.
367.
368.
369.
370.
371.
372.
373.
374.
375.
376.
377.
378.
379.
380.
381.
382.
383.
384.
385.
386.
387.
388.
389.
390.
391.
392.
393.
394.
395.
396.
397.
398.
399.
400.
401.
402.
403.
404.
405.
406.
407.
408.
409.
410.
411.
412.

Methacryloyl oxyethyl isocyanate

Methanidophos
Methane
Methanesulphonyl fluoride
Methidathion
Methiocarb
Methonyl
Methoxy ethanol (2-methyl
cellosolve)
Methoxyethyl mercuric acetate
Methyacrylol chloride
Methyl 2-chloroacrylate
Methyl alcohol
Methyl amine
Methyl bromide (Bromomethane)
Methyl chloride
Methyl chloroform
Methyl chloroformate
Methyl cyclohexene
Methyl disulphide
Methyl ethyl ketone peroxide (conc.
60 %)
Methyl formate
Methyl hydrazine
Methyl isobutyl ketone
Methyl isocyanate
Methyl isothiocyanate
Methyl mercuric dicyanamide
Methyl Mercaptan
Methyl Methacrylate
Methyl phencapton
Methyl phosphoric dichloride
Methyl thiocyanate
Methyl trichlorosilane
Methyl vinyl ketone
Methylene bis (2-chloroaniline)
Methylene chloride
Methylenebis-4, 4(2-chloroaniline)
Metolcarb
Mevinphos
Mezacarbate
Mitomycin C
Molybdenum Powder
Monocrotophos
Morpholine
Muscinol
Mustard gas
N-Butyl acetate
N-Butyl alcohol

74-82-8
558-25-8
950-37-8
16752-77-5
-

PA 1490000
PB 2975000
-

HR-3
HR-3
-

151-38-2
80-63-7
67-56-1
74-89-5
74-83-9
74-87-3
71-55-6
79-22-1
591-47-9
1338-23-4

OV 6300000
AS 6380000
PC 1400000
PF 6300000
PA 4300000
PA 6300000
KJ 2975000
EL 9450000

HR-3
HR-3
HR-3, F
HR-3, C, F
T
T
T, F
HR-2, F
R

107-31-3
60-34-4
108-10-1
624-83-9
8066-01-1
502-39-6
74-93-1
80-62-6
3735-23-7
676-97-1
556-64-9
75-79-6
79-84-4
101-14-4
75-09-2
101-14-4
1129-41-5
7786-34-7
315-18-4
50-07-7
7439-98-7
6923-22-4
110-91-8
2763-96-4
505-60-2
123-86-4
71-36-3

LQ 8925000
MV 5600000
SA 9275000
NQ 9450000
TX 9665000
PB 4375000
OZ 5075000
TD 6125000
TA 1840000
XL 1575000
VV 4550000
CY 1050000
PA 8050000
CY 1050000
GQ 5250000
QA 4680000
TC 4375000
QD 6475000
-

HR-3
HR-3
HR-3, T, F
HR-3
HR-3
HR-3
HR-3
HR-3
HR-3
HR-3
T
T
T
HR-3
HR-3
HR-3
-

47

413.
414.
415.
416.
417.
418.
419.
420.
421.
422.
423.
424.
425.
426.
427.
428.
429.
430.
431.
432.
433.
434.
435.
436.
437.
438.
439.
440.
441.
442.
443.
444.
445.
446.
447.
448.
449.
450.
451.
452.
453.
454.

N-Hexane
N-Methyl-N, 2,4,6-Tetranitroaniline
Naphtha
Naphtha solvent
Naphthalene
Naphthyl amine
Nickel carbonly/nickel tetracarbonyl
Nickel Powder
Nicotine
Nicotine sulphate
Nitric acid
Nitric oxide
Nitrobenzene
Nitrocellulose (dry)
Nitrochlorobenzene
Nitrocyclohexane
Nitrogen
Nitrogen dioxide
Nitrogen oxide
Nitrogen trifluoride
Nitroglycerine
Nitropropane-1
Nitropropane-2
Nitroso dimethyl amine
Nonane
Norbormide
O-Cresol
O-Nitro Toluene
O-Toluidine
O-Xylene
O/P Nitroaniline
Oleum
OO Diethyl S ethyl suphinyl Methyl
phosphorothioate
OO Diethyl S propylthio methyl
phosdithiodate
OO Diethyl S
ethylsulphinylmethylphosphorothioat
e
OO Diethyl S
ethylsulphonylmethylphosphorothioa
te
OO Diethyl S
ethylthiomethylphosphorothioate
Organo rhodium complex
Orotic acid
Osmium tetroxide
Oxabain
Oxamyl

110-54-3
479-45-8
8030-30-6
91-20-3
134-32-7
13463-39-3
7440-02-0
54-11-5
65-30-5
7697-37-2
10102-43-9
2491-52-3
9004-70-0
100-00-5
1122-60-7
7727-37-9
10102-44-0
10024-97-2
7783-54-2
55-63-0
108-03-2
79-46-9
156-10-5
27214-95-8
991-42-4
95-48-7
88-72-2
95-53-4
95-47-6
100-01-6
-

MN 9275000
BY 6300000
DE 3030000
QJ 0525000
QM 1400000
QR 6300000
QR 5950000
QS 5250000
QS 9525000
QU 5775000
QX 0525000
CN 2710000
CZ 1050000
GV 6600000
QW9700000
QW9800000
QX 1350000
QX 1925000
QX 2100000
TZ 5075000
TZ 5250000
JK 0175000
RA 8550000
RB 8750000
GO 6300000
TX 3150000
XU 2975000
ZE 2450000
BY 7000000
-

C, F
HR-3, E
E
F
HR-3, T
HR-3, T, F
HR-3, T
HR-3
HR-3
T
HR-3, T
HR-3
HR-3
HR-3, T
HR-3, T
HR-3
HR-3, T, E
HR-3
HR-3, T, F
HR-3
HR-1
HR-3
T

65-86-1
20816-12-0
23135-22-0

RM 3180000
RN 1140000
-

HR-2
HR-3
-

48

455.
456.
457.
458.
459.
460.
461.
462.
463.
464.
465.
466.
467.
468.
469.
470.
471.
472.
473.
474.
475.
476.
477.
478.
479.
480.
481.
482.
483.
484.
485.
486.
487.
488.
489.
490.
491.
492
493.
494
495.
496.
497.
498.
499.

Oxetane 3,3-bis(chloromethyl)
Oxidiphenoxarsine
Oxy disulfoton
Oxygen (liquid)
Oxygen difluoride
Ozone
P-nitrophenol
Paraffin
Paraxon (Diethyl 4 Nitrophenyl
phosphate)
Paraquat
Paraquat methosulphate
Parathion
Parathion methyl
Paris green
Penta borane
Penta chloro ethane
Penta chlorophenol
Pentabromophenol
Pentachloro naphthalene
Pentadecyl-amine
Pentaerythaiotol tetranitrate
Pentane
Pentanone
Perchloric acid
Perchloroethylene
Peroxyacetic acid
Phenol
Phenol, 2,2-thiobis (4,6-Dichloro)
Phenol 2,2-thiobis (4 chloro 6 methyl
phenol)
Phenol, 3-(1-methyl ehtyl)methylcarbamate
Phenyl hydrazine hydrochloride
Phenyl mercury acetate
Phenyl silatrane
Phenyl thiourea
Phenylene p-diamine
Phorate
Phosazetin
Phosfolan
Phosgene
Phosmet
Phosphamidon
Phosphine
Phosphoric acid
Pohsphoric acid dimethyl (4-methyl
thio) phenyl
Phosphorothioic acid dimethyl S(2-

2497-07-6
7782-44-7
7783-41-7
10028-15-6
8002-74-2
311-45-5

TD 8600000
RS 2060000
RS 2100000
RS 8225000
RV 0350000
-

HR-3, T
HR-3, T
HR-3, O
HR-3, T
HR-3
T

1910-42-5
56-38-2
298-00-0
19624-22-7
76-01-7
87-86-5
608-71-9
1321-64-8
2570-26-5
78-11-5
109-66-0
107-87-9
7601-90-3
127-18-4
79-21-0
108-95-2
-

DW 275000
TF 4550000
TG 0175000
RY 8925000
KI 6300000
SM 6300000
SM 6125000
QK 0300000
RZ 2450000
RZ 2620000
RZ 9450000
SA 7875000
SC 7500000
KX 3850000
SD 8750000
SJ 3325000
-

HR-3, T
T
HR-3, T, F
HR-3
HR-3, T
HR-3
HR-3
HR-3
HR-3, T, E
HR-2
HR-3
HR-3
HR-3
HR-3/T
-

59-88-1
62-38-4
2097-19-0
103-85-5
106-50-3
298-02-2
4104-14-7
947-02-4
75-44-5
13171-21-6
7803-51-2
7664-38-2
3254-63-5

YJ 9050000
YU 1400000
SS 8050000
TD 9450000
NJ 6475000
SY 5600000
SY 7525000
TB 6300000
-

HR-3
HR-3
HR-3
HR-3, T
T
HR-3
HR-3, T
T
HR-3, T, F
HR-3
T

49

500.
501.
502.
503.
504.
505.
506.
507.
508.
509.
510.
511.
512.
513.
514.
515.
516.
517.
518.
519.
520.
521.
522.
523.
524.
525.
526.
527.
528.
529.
530.
531.
532.
533.
534.
535.
536.
537.
538.
539.
540.
541.
542.
543.
544.
545.
546.

bis) Ester
Phosphorothioic acid methyl (ester)
Phosphorothioic acid, OO Dimethyl
S-(2methyl)
Phosphorothioic, methyl-ethyl ester
Phosphorous
Phosphorous oxychloride
Phosphorous pentoxide
Phosphorous trichloride
Phosphorous penta chloride
Phthalic anhydride
Phylloquinone
Physostignine
Physostignine salicylate (1:1)
Picric acid (2,4,6-trinitrophenol)
Picrotoxin
Piperidine
Piprotal
Pirinifos-ethyl
Platinous chloride
Platinum tetrachloride
Potassium arsenate
Potassium chlorate
Potassium cyanide
Potassium hydroxide
Potassium nitride
Potassium nitrite
Potassium peroxide
Potassium silver cyanide
Powdered metals and mixtures
Promecarb
Promurit
Propanesultone
Propargyl alcohol
Propargyl bromide
Propen-1,-2-chloro-1,3-diol diacetate
Propiolactone beta
Propionitrile
Propionitrile, 3-chloro
Propiophenone, 4-amino
Propyl chloroformate
Propylene dichloride
Propylene glycol allylether
Propylene imine
Propylene oxide
Prothoate
Pseudocumene
Pyrazoxon
Pyrene

T
T

7723-14-0
10025-87-3
1314-56-3
7719-12-2
10026-13-8
85-44-9
84-80-0
57-47-6
57-64-7
88-89-1
124-87-8
110-89-4
5281-13-0
23505-41-1
10025-65-7
13454-96-1
10124-50-2
3811-04-9
151-50-8
1310-58-3
29285-24-3
7758-09-0
17014-71-0
506-61-6
2631-37-0
5836-73-7
1120-71-4
107-19-7
57-57-8
107-12-0
109-61-5
78-87-5
1331-17-5
75-55-8
75-56-9
2275-18-5
95-63-6
129-00-0

TH 3495000
TH 4798000
TH 3945000
TH 3675000
TB 6125000
TI 3150000
TJ 2100000
TJ 2450000

T
HR-3, T, F
T, F
HR-3, T, F
HR-3, T, F
HR-3, T, F
HR-3
HR-3
HR-3
T, E
HR-3
HR-3
HR-3
HR-3
HR-3
HR-3
HR-3
HR-3
HR-3
HR-3
HR-3
HR-3
HR-3
T
F
HR-3
R
T
HR-3

50

TJ 9100000
TM 3500000
BF 4911000
TP 2275000
TP 2275500
CG 3800000
FO 0350000
TS 8750000
TT 2100000
TT 3750000
TT 4450000
TT 5775000
RP 5425000
UK 5075000
RQ 7350000
UF 9625000
TX 9625000
UA 4900000
CM 8050000
TZ 2975000
DC 3325000
UR 2450000

547.
548.
549.
550.
551.
552.
553.
554.
555.
556.
557.
558.
559.
560.
561.
562.
563.
564.
565.
566.
567.
568.
569.
570.
571.
572.
573.
574.
575.
576.
577.
578.
579.
580.
581.
582.
583.
584.
585
586.
587.
588.
589.
590.
591.
592.
593.

Pyridine
Pyridine, 2-methyl-3-vinyl
Pyridine, 4-nitro-1-oxide
Pyridine 4-nitro-1-oxide
Pyriminil
Quinaliphos
Quinone
Rhodium trichloride
Salcomine
Sarin
Selenious acid
Selenium Hexafluoride
Selenium oxychloride
Semicarbazide hydrochloride
Silane (4-aminio butyl) diethoxymeth
Sodium
Sodium anthra-quinone-1-sulphonate
Sodium arsenate
Sodium arsenite
Sodium azide
Sodium cacodylate
Sodium chlorate
Sodium cyanide
Sodium fluoro-acetate
Sodium hydroxide
Sodium pentachloro-phenate
Sodium picramate
Sodium selenate
Sodium selenite
Sodium sulphide
Sodium tellorite
Stannane acetoxy triphenyl
Stibine (Antimony hydride)
Strychnine
Strychnine sulphate
Styphinic acid (2,4-6trinitroresorcinol)
Styrene
Sulphotep
Sulphoxide, 3-chloropropyl octyl
Sulphur dichloride
Sulphur dioxide
Sulphur monochloride
Sulphur tetrafluoride
Sulphur trioxide
Sulphuric acid
Tellurium (Powder)
Tellurium hexafluoride

110-86-1
140-76-1
53558-25-1
106-51-4
10049-07-7
14167-18-1
7783-00-8
7783-79-1
7791-23-3
563-41-7
-

UR 8400000
YT 9690000
DK 2625000
VI 9275000
VS 9450000
-

HR-3, T
HR-3
T, F
HR-3
-

7440-23-5
128-56-3
7631-89-2
7784-46-5
26628-22-8
124-65-2
7775-09-9
143-33-9
62-74-8
1310-73-2
131-52-2
13410-01-0
10102-18-8
1313-82-2
10102-20-2
7803-52-3
57-24-9
60-41-3
82-71-3

VY 0686000
CG 3675000
VY 8050000
FO 0525000
VZ 7525000
AH 9100000
WB 4900000
SM 6490000
VS 7350000
WE 1905000
WY 2450000
WJ 0700000
WL 2275000
WL 2550000
VH 3540000

HR-3
HR-3
HR-3
HR-3, T
HR-3
HR-3
HR-3, ERO
HR-3
T, D
HR-3, T, E
HR-3
HR-3
HR-3
HR-3
HR-3
HR-3

100-42-5
3689-24-5
10545-99-0
7446-09-5
10025-67-9
7783-60-0
7446-11-9
7664-93-9
13494-80-9
7783-80-4

WL 3675000
XN 4375000
WS 4500000
WS 4550000
WS 4300000
WT 4800000
WS 5600000
WY 2625000
WY 2800000

HR-3
T
HR-3, T
HR-3, T
HR-3
HR-3
HR-3
HR-3
HR-3

51

594.
595.
596.
597.
598.
599.
600.
601.
602.
603.
604.
605.
606.
607.
608.
609.
610.
611.
612.
613.
614.
615.
616.
617.
618.
619.
620.
621.
622.
623.
624.
625.
626.
627.
628.
629.
630.
631.
632.
633.
634.
635.

TEPP (Tetraethyl pyrophosphate)

Terbufos
Tert-Butyl alcohol
Tert-Butyl peroxy carbonate
Tert-Butyl peroxy isopropyl
Tert-Butyl peroxyacetate (Conc > =
70 %)
Tert-Butyl peroxypivalate (Conc >=
77%)
Tert-Butylperoxyiso-butyrate
Tetra hydrofuran
Tetra methyl lead
Tetra nitromethane
Tetra-chlorodibenzo-p-dioxin
1,2,3,7,8,(TCDD)
Tetraethyl lead
Tetrafluoriethyne
Tetramethylene disulphotetramine
Thallic oxide
Thallium carbonate
Thallium sulphate
Thallous chloride
Thallous malonate
Thallous sulphate
Thiocarbazide
Thiocynamicacid, 2(Benzothioazolyethio) methyl
Thiofamox
Thiometon
Thionazin
Thionyl chloride
Thiophenol
Thiosemicarbazide
Thiourea (2-chloro-phenyl)
Thiourea (2-methyl phenyl)
Tirpate (2,4-diemthyl 1-1,3-dithiolane)
Titanium powder
Titanium tetra-chloride
Toluene
Toluene 2,4-di-isocyanate
Toluene 2,6-di isocyanate
Trans 1 4-di chloro-butane
Tri nitro anisole
Tri (Cyclohexyl) methylstannyl 1,2,4
triazole)
Tri(Cyclohexyl) stannyl-1H-1,2,3triazole
Triaminotrinitrobenzene

107-49-3
13071-79-9
75-65-0
-

UX 6825000
-

HR-3, T
-

927-07-1

109-99-9
75-74-1
509-14-8
-

LU 5950000
TP 4725000
PB 4025000
-

HR-3,T, F
HR-3
HR-3
-

78-00-2
116-14-3
1314-32-5
6533-73-9
10031-59-1
7791-12-0
2757-18-8
7446-18-6
2231-57-4
21564-17-0

TP 4550000
XG 2975000
XG 4000000
XG 6600000
XG 4200000
OO 1770000
XG 6800000
-

HR-3
T
HR-3, T
HR-3, T
HR-3, T
HR-3, T
HR-3, T
HR-3, T
-

39196-18-4
640-15-3
7719-09-7
108-98-5
79-19-6
5344-82-1
-

XM 5150000
DC 0525000
VT 4200000
-

HR-3, C
HR-3
T

7440-32-6
7550-45-0
108-88-3
584-84-9
584-84-9
-

XR 1702000
XR 1925000
XS 5250000
CZ 6300000
CZ 6300000
-

HR-3
HR-3
HR-3, T
HR-3, T, F
T
-

3058-38-0

HR-3

52

636.
637.
638.
639.
640.
641.
642.
643.
644.
645.
646.
647.
648.
649.
650.
651.
652.
653.
654.
655.
656.
657.
658.
659.
660.
661.
662.
663.
664.
665.
666.
667.
668.
669.
670.
671.
672.
673.
674.
675.
676.
677.
678.
679.
680.
681.
682.
683.
684.

Triamphos
Triazophos
Tribromophenol 2,4,6
Trichloro napthalene
Trichloro chloromethyl silane
Trichloroacetyl chloride
Trichlorodichlorophenylsilane
Trichloroethyl silane
Trichloroethylene
Trichloromethane sulphenyl chloride
Trichloronate
Trichorophenol 2,3,6
Trichlorophenol 2,4,5
Trichlorophenyl silane
Trichlorophon
Triethoxy silane
Triethylamine
Triehtylene melamine
Trimethyl chlorosilane
Trimethyl propane phosphite
Trimethyl tin chloride
Trinitro aniline
Trinitro benzene
Trinitro benzoic acid
Trinitro phenetole
Trinitro-m-cresol
Trinitrotoluene
Tri orthocresyl phosphate
Triphenyl tin chloride
Tris (2-chloroethyl) amine
Turpentine
Uranium and its compounds
Valinomycin
Vanadium pentoxide
Vinyl acetate mononer
Vinyl bromide
Vinyl chloride
Vinyl cyclohexane dioxide
Vinyl fluoride
Vinyl norbornene
Vinyl toluene
Vinyledene chloride
Warfarin
Warfarin Sodium
Xylene dichloride
Xylidine
Zinc dichloropentanitrile
Zinc phosphide
Zirconium & compounds

1031-47-6
24017-47-8
118-79-6
1321-65-9
1558-25-4
76-02-8
79-01-6
594-42-3
327-98-0
933-75-5
95-95-4
98-13-5
998-30-1
121-44-8
75-77-4
824-11-3
1066-45-1
99-35-4
129-66-8
602-99-3
118-96-7
78-30-8
639-58-7
8006-64-2
2001-95-8
1314-62-1
108-05-4
593-60-2
75-01-4
106-87-6
75-02-5
3048-64-4
25013-15-4
75-35-4
81-81-2
28347-13-9
1300-73-8
1300-73-8
1314-84-7
7440-67-7

53

TF 5635000
SN 1225000
QK 4025000
AO 7140000
KX 4550000
PB 0370000
SN 1300000
SN 1400000
VV 6650000
VV 6682000
YE 0175000
VV 2710000
DC 3850000
DI 0920000
GP 3675000
XU 0180000
TD 0350000
YO 8400000
YV 9468000
YW 2450000

HR-3
HR-3
HR-3
HR-2
HR-3
HR-3
HR-3
HR-3
HR-3
HR-3
HR-2
HR-3
HR-3, T, E
HR-3, T, E
T, E
HR-3, T, E
HR-3
HR-3
T
HR-3
HR-3, T

KU 8400000
KU 9625000
RN 8640000
YZ 7351000
RC 0350000
WL 5075000
YZ 8061000
GN 4550000
ZE 8575000
ZH 4900000
ZH 7070000

HR-3
HR-3, T
HR-3
HR-3, T
HR-1
T, F
HR-3
T, E
HR-3, T
HR-3
F

Abbreviations

CAS

--

Chemical Abstract Society

--

Corrosive

CMG

--

Crisis Management Group

--

Explosive

EPPR

--

Emergency Preparedness, Planning & Response

--

Flammable

HR

--

Hazard Rating

ID

--

Identity

MSIHC

--

Manufacture, storage & Import of Haz. Chemicals

--

Oxidizer

OSEP

--

On-site Emergency Plan

ORG

--

Operation Response Group

PLI

--

Public Liability Insurance

PVC

--

Polyvinyl chloride

PAS

--

Public Address System

--

Reactive

RTECS

--

Registry of Toxic effects of chemical substances

RTO

--

Road Transport Office

--

Toxic

UN

--

United Nations

54