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PART TEST-3 (PT-3)

(JEE ADVANCED PATTERN)

TARGET : JEE(MAIN +ADVANCED)2016

DATE : 09-11-2014

COURSE : VIKAAS (JA)


HINTS & SOLUTIONS ladsr ,oa gy

Part-I
Mathematics
1.
(1 + x) (1 + x + x2) .
Sol. Highest exponent in the product of first two is 3 = 1 + 2
Highest exponent in the product of first three is 6 = 1 + 2
+3
Similarly, Highest exponent in the product of first hundred
= 1 + 2 + ...... + 100 = 5050]

now

APQ and ABC are similar

vc APQ rFkk ABC le:i gS

h r PQ
=
h
6

izFke nks xq.kuQy esa x dh mPpre ?kkr 3 = 1 + 2


izFke rhu ds xq.kuQy esa x dh mPpre ?kkr 6 = 1 + 2 + 3
blh izdkj izFke lkS ds xq.kuQy esa x dh mPpre ?kkr

r
PQ
2
PQ
=
1
=
h
6
7
6

= 1 + 2 + ...... + 100 = 5050]


2.

If a,b,c are sides

;fn f=kHkqt a,b,c dh


Sol. R(b + c) = a bc

4.

sin A = b c

Sol. Put j[kus

2 bc

j[kus ij x = 1 ; ( 3)

2145

(3)
b + c 2 bc

5.

A = 90 and b = c

= (3 )

= a0 a1 + a2 a3 + ...... ;

vfUre vad 3 gS

Given the family of .

Sol. point of intersection is A ( 2, 0) . The required line will be

vr% sin A 1 tks lEHko ugh gS


hence vr% sin A = 1

4 536

nh xbZ js[kkvksa dk .

sin A 1 which is not possible.

hence

ends in 3 ]
2145

vc b ,oa c ij AM GM yxkus ij
bc

ij x = 1 ; ( 3)2145 = a0 a1 + a2 a3 + ...... ;

(3)2145 = (34)536 3

applying AM GM for b and c

bc

If (1 + x 3x2)2145 .

;fn (1 + x 3x2)2145 .

R(b + c) = 2RsinA bc

now

5
PQ
30
=
PQ =
Ans.
7
6
7

one which passes through ( 2, 0) and is perpendicular to

A = 90

the line joining ( 2, 0) and (2, 3) or taking (2, 3) as centre

(3)]

and radius equal to PA draw a circle, the required line will


3.

be a tangent to the circle at ( 2, 0) ]

A triangle has sides .

fdlh f=kHkqt dh Hkqtkvksa


Sol.

Hindi izfrPNsn

ls xqtjrh gS vkSj js[kk ( 2, 0) vkSj (2, 3) dks feykus okyh js[kk

6 h
= 3h ;
2

ds yEcor~ gSA (2, 3) dks dsUnz vkSj PA dks f=kT;k ekudj ,d

(where h is the altitude from A)


(tgk h, 'kh"kZ A ls
Also iqu%

js[kk gksxhA ]

= 21 r (using = rs) (= r.s ds mi;ksx ls)

21 r = 6 h = 3h
2
2

o`k [khpk tkrk gSA vHkh"V js[kk] o`k ds fcUnq ( 2, 0) ij Li'kZ

Mkys x;s yEc dh yEckbZ gSA)

r
2
=
h 7

fcUnq A( 2, 0) gSA vHkh"V js[kk ,d gksxh tks ( 2, 0)

6.

A, B and C are points .


A, B, C, xy lery

esa fcUnq

Sol. Locus of C is a circle 8(x2 + y2) 88x 104y + 544 = 0

(4)]
C

dk fcUnq iFk ,d o`k 8(x2 + y2) 88x 104y + 544 = 0

(4) gSA
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SOLJAPT3091114-1

7.

Number of positive .
Hindi 2002C1001 =

lehdj.k (x1 + x2 + x3)


Sol. (x1 + x2 + x3) (y1 + y2) = 11 7 or 7 11

(2002)!

In the first case (x1 + x2 + x3) = 11 and (y1 + y2) = 7, which


have 10C2 6C1 solutions (using beggar)
In the second case (x1 + x2 + x3) = 7 and (y1 + y2) = 11,
which have 6C2 10C1 solutions (using beggar)
6

(1001 !)2 esa

(x1 + x2 + x3) = 11

,oa (y1 + y2) = 7 ftlls

11.
10

C2 C1

=1

If the circles x2 + y2 + .

Sol. S1 S2 = 5ax + (c d)y + a + 1 = 0 and 5x + by a = 0


must represent the same line

,oa (y1 + y2) = 11 ftlls 6C2 10C1 gy

S1 S2 = 5ax + (c d)y + a + 1 = 0

izkIr gksrs gSA (csxj fof/k ls)

leku js[kk dks O;Dr djrh gS

gyksa dh dqy la[;k = 10C2 6C1 + 6C2 10C1 = 270 + 150

a c d a 1

1
b
a
ab = c d
and vkSj

= 420 Ans. ]
8.

(2002)!
(1001!)2

;fn o`k x2 + y2 + 2ax +.

gy

izkIr gksrs gSA (csxj fof/k ls)


(x1 + x2 + x3) = 7

'kwU;ksa dh la[;k = 2(200 + 40 + 8 + 1) = 498

vr% 'kwU;ksa dh la[;k

10

+ 150 = 420 Ans. ]


(x1 + x2 + x3) (y1 + y2) = 11 7 or 7 11

esa 'kwU;ksa dh la[;k

400 + 80 + 16 + 3 = 499

total number of solutions = C2 C1 + C2 C1 = 270


10

(2002)!
(1001)! (1001)!

The number of ten .


vadksa 1,2,3 dh lgk;rk

vkSj 5x + by a = 0

a2 + a + 1 = 0
a is imaginary only
a dsoy

dkYifud gS

so no value of a

blfy, a dk dksbZ eku ugha


Sol. Case-I
Total number in this case

12.

(2) ]

Let C be a circle .

ekuk fd C dksbZ o`k

bl fLFkfr esas dqy la[;k, gSA


1.2.1.2.1.2.1.2.1.2 = 2

(2)]

Sol. Equation of the line is

js[kk dk lehdj.k gS
y 0 = m(x + 1)

CasefLFkfr-II
Total number in this case

solving it with

x2 + m2(x + 1)2 = 1

bl fLFkfr esas dqy la[;k, gSA

(m2 + 1)x2 + 2m2x + (m2 1) = 0, m Q

2.1.2.1.2.1.2.1.2.1 = 2
Total digits dqy la[;k,a = 25 + 25 = 64
9.

....(1)

gy djus ij x2 + y2 = 1

Num ber of diviso rs


2 5 . 3 2 .5 3 ds 2 ls .

Sol. Let 2 3 5 be a divisor, th en

can t ake 1 or 2, can take the value 0 a nd


can take the valu es 0, 1, 2, 3

Num ber of wa ys = 2 1 4 = 8
ekukfd 2 3 5 ,d Hkktd gS ] rks
dk eku 1 ;k 2 gks ldrk gS ] dk eku 0 gks
ldrk gS vkS j ds eku 0, 1, 2, 3 gks ldrs gS A
dq y rjhds = 2 1 4 = 8
10.

x1x2 =

m2 1
m2 1

but ijUrq x1 = 1

x2 =

ijUrq x1 = 1 x2 =

Number of zeros .
C1001 ds

vUr esa .
(2002)!
Sol. 2002C1001 =
(1001)! (1001)!

1 m2
1 m2

1 m2
1 m2

= x coordinate of P

= P dk x

funsZ'kkad

2002

since m Q hence x will be rational.

pwfd

no. of zeros in (2002)! are


400 + 80 + 16 + 3 = 499
no. of zeroes in (1001 !)2 = 2(200 + 40 + 8 + 1) = 498
Hence no. of zeroes is

(2002)!
2

(1001!)

Q vr% x ifjes; gksxk

;fn x ifjes; gS rc y Hkh ifjes; gksxk (1) ]


13.

= 1]

If x is rational then y is also rational from (1) ]

Consider the triangle .

fp=k esa ,d f=kHkqt .

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SOLJAPT3091114-2

Sol. cos C =

ifjes; inksa ds fy, r = 0 ;k 12

(19)2 (17)2 c 2 > 0


2 19 17

sum ;ksx = T1 + T13 = 12C0 33 + 12C12 44

c2 < (19)2 + (17)2


2

= 33 + 44 = 27 + 256 = 283 Ans.

c < (18 + 1) + (18 1)


c2 < 2(182 + 1)
c2< 650 ....(1)
c>2
and
c < 26

17.

ekuk C1 vkSj C2 , .

2 < c < 26....(2)


c is 3, 4, 5, ....... , 25
number of integral values of c is 23 Ans.
c ds iw.kkZad ekuksa dh la[;k 23 gksxh
14.

Let C1 and C2 are .

Sol.

Sides of ABC are .

ABC dh Hkq t k,a lekUrj .


pa w f d
lekUrj Js < h es a gS vkS j a < m in{b, c}
orde r of A.P. can be b, c, a or c, b, a
lekUrj Js < h ds e b, c, a ;k c, b, a gS A
if ;fn 2c = a + b the n gks ] rks cos A

Sol. Sides are in A.P. and a < m in{b, c}

Centres are (10, 0) and ( 15, 0)

dsUnz (10, 0) vkSj ( 15, 0)


r1 = 6;
d = 25
r1 + r2 < d

circles are separated o`k vyx vyx gS

b2 c 2 a2
b2 c 2 (2c b)2
=
=
2bc
2bc
4b 3c
2b
if ;fn 2 b = a + c
=

then

15.

rc cos A =

b2 c 2 (2b c)2
4c 3b
=
2bc
2c

r2 = 9

18.

PQ(min) =

d2 (r1 r2 )2 =

625 225 = 20

PQ(max) =

d2 (r1 r2 )2 =

625 9 =

616

m, n are integer with .


m, n iw.kkd

gS ftlesa .

Sol.

Consider arrangements .

ekuk v{kjks a A A B B B C D E
Sol.

A A

B B B

, C, D, E

5! = 120 ways rjhds


Required number = (number of ways in which no two B's
come together) (number of ways in which no two B's
come together and A's are together)

Area of rectangle BCDE = 4mn

vHkh"V la [ ;k = (os rjhds ftues a dks b Z Hkh nks B lkFk


lkFk ugha vkrs gks ) (os rjhds ftues a dks b Z Hkh nks B
lkFk lkFk ugha vkrs gks rFkk A lkFk lkFk vkrs gks )

vk;r BCDE dk {ks=kQy = 4mn


Area of

5! 6
C3 4! 5 C3 = 960
2!

16.

Sol. Tr + 1 = 12Cr

12

2m(m n)
= m2 mn
2
area of pentagon iapHkqt dk {ks=kQy = 4mn + m2 mn
= m2 + 3mn Ans.]

12

1
4

1
(2m)(m+n) = m(m+n)
2

ds izlkj .

Area of ACD =

12 r

ACD dk {ks=kQy =

Cr

2m(m n)
2

ABC dk {ks=kQy =

In the expansion of .

1
1
34 43

ABC =

4 r 3

3 r 4
r 3
3
4

For rational term r = 0 or 12

19.

1
(2m)(m+n) = m(m+n)
2

The distance between.


nks lekUrj js[kkvksa ds .

Sol.
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SOLJAPT3091114-3

ah bk 1
a b
2

r 2 a2 b2 ah bk 1

a2 h2 r 2 b2 k 2 r 2 2abhk 2ah 2bk 1 0

fn, x, izfrcU/k ls rqyuk djus ij


x cos ( + 3 0) = d (1) and vkSj x sin = 1 d

4a 2 5 b 2 + 6a + 1 = 0
h 2 r 2 = 4, k 2 r 2 = 5, hk = 0, 2h = 6, 2k = 0

(2)

h 3, k 0 & r 2 h2 4 5

1 d
dividing 3 cot =
, squaring equation (2) and
1 d

r 5 o`k dk dsUnz (3, 0 ), rFkk f=kT;k =

putting

1 d
dks foHkkftr djds lehdj.k (2) dk oxZ
1 d
djds tksM+us ij
1
the value of cot , x2 =
(4d2 4d + 4)
3
3 cot =

d d1
]
3

The Number of ways in .

ikap fofHkUu iqLrdksa dks .


Sol. Given answer is 150 which comes in BCD in A, it is
5
C3 3! = 60]
izkIr mkj 150 gS tks BCD esa Hkh vkrk gS rFkk A esa ;g
C3 3! = 60 gSA

x=2
cot dk

22.

eku gS x2 =

23.

A family of linear functions


,d js[kh; Qyuksa dk .
Sol. Line : y = 1 + c(x + 3) is tangent to circle
x2 + y2 = 1
js[kk : y = 1 + c(x + 3) o`k x2 + y2 = 1 dh Li'kZ

1
(4d2 4d + 4)
3

d2 d 1
x=2
]
3

p=r

A triangle ABC has


f=kHkqt ABC,
Sol. 2[a cos A + b cos B + c cos C] = a + b + c
= [sin 2A + sin 2B + sin 2C] = sin A + sin B + sin C
(using a = 2R sin A etc. dk mi;ksx)

1 3c
1 c2

20.

4
2
abc

R
= 2s
=R
R
s
4

Also 2r = R triangle is equilateral


2r = R rFkk f=kHkqt leckgq gSA

c=0
25.

= (1+x)m

Sol. Let the circle be (x h) 2 + (y k) 2 = r 2

a b

a h r
2

r 2 a2 b2 ah bk 1

b k
2

2abhk 2ah 2bk 1 0

h 3, k 0 & r 2 h2 4 5

r 5
centre of circle 3, 0 , radius 5

Hindi

ekuk fd o`k (x h ) 2 + (y k) 2 = r 2

(1), (2) ]

(1 x)nm1 1

(1 x)nm1 1

esa xm dk xq.kkad

= n+1Cm+1
S = nCm + 2. n1Cm + 3. n2Cm + ............

No w o n com paring from the give n result


4a 2 5 b 2 + 6a + 1 = 0
h 2 r 2 = 4, k 2 r 2 = 5, hk = 0, 2h = 6, 2k = 0

For an y positive .

;fn 4a 2 5b 2 + 6a + 1 = 0,

c = 3/4

= Co-efficient of xm in (1+x)m

If 4a 2 5b 2 + 6 a + 1 = 0.

ah bk 1

or

m , n fdlh /kukRed .
Sol. nCm + n1Cm + n2Cm + .............+ mCm
= Co-efficient of xm in (1+x)n + (1+x)n1 + .......+ (1+x)m
= (1+x)n + (1+x)n1 + .......+ (1+x)m esa xm dk xq.kkad

2r = R

=1

(1 + 3c)2 = 1 + c2
9c2 + 6c = c2
8c2 = 6c

4 sin A sin B sin C = sin A + sin B + sin C


4abc a b c
abc

= (a + b + c) = 2s
2R
8R3
R2

21.

js[kk gSA

S = Co-efficient of xm in
(1+x)n + 2.(1+x)n1 + 3(1+x)n2 +.......

S = (1+x)n + 2.(1+x)n1 + 3(1+x)n2 +.... m esa xm dk


xq.kkad
Let ekuk S' = (1+x)n + 2.(1+x)n1 + 3(1+x)n2 +..........+
(nm+1)(1+x)m

......(i)

S'

= (1+x)n1 + 2.(1+x)n2 +....+ (nm+1)(1+x)m1


(1 x)
......(ii)
from (i) (ii) ls

xS'
= (1+x)n + (1+x)n1 +...+(1+x)m(nm+1)(1+x)m1
1 x

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SOLJAPT3091114-4

xS'
= (1+x)m
1 x

30.

(1 x)nm1 1

One side of a rectangle.


,d vk;r dh ,d Hkqtk .
(1, 1)

Sol.

m1

(nm+1)(1+x)

n 2
m 1
m
S ' = (1 x) (1 x) (n m 1)(1 x)

x2

( 3, 1)

S = Co-efficient of x in S' = Cm+2


S = S' esa xm dk xq.kkad = n+2Cm+2
m

26.

n+2

Line perpendicular to 4x + 7y + 5 = 0 is 7x 4y + = 0
4x + 7y + 5 = 0 ds yEcor~ js[kk 7x 4y + = 0
It passes through ( 3, 1) and (1, 1)
;g ( 3, 1) rFkk (1, 1) ls xqtjrk gSA

In an e xam ination, .

,d ijh{kk esa] ,d ijh{kkFkhZ

11 4 + = 0 = 25

Sol. Num ber of wa ys h e can fail is either on e or t wo,


three o r four sub ject then t otal of ways.
4
C1 +4C2 + 4C3 +4C4 = 24 1
Sol.

7 4 + = 0 = 3
Hence lines are 7x 4y + 25 = 0, 7x 4y 3 = 0
vr% js[kk,a 7x 4y + 25 = 0, 7x 4y 3 = 0 gSA
line parallel to 4x + 7y + 5 = 0 passing through (1, 1) is 4x

mlds vlQy gksus ds rjhdksa esa og ;k rks ,d fo"k; esa ;k nks


fo"k; esa ;k rhu fo"k; esa ;k pkj fo"k;ksa esa vlQy gks ldrk
gks] vr% dqy rjhdksa dh la[;k = 4 C 1 + 4 C 2 + 4 C 3 + 4 C 4 =

+ 7y + = 0

lekUrj ljy js[kk 4x + 7y + = 0 tks


xqtjrh gSA
= 11 4x + 7y 11 = 0
4x + 7y + 5 = 0 ds

24 1
27.

(1, 1) ls

If nCr1 = 36 , nCr = 84 .

;fn n C r 1 = 3 6 , n C r .
n

Sol.

Cr 1

Cr

4x + 7y + 5 = 0

36
=
84

32.
n

and

vkS j

Cr

Cr 1

84
=
126

The circle with equation .


o`k x2 + y2 = 1, js[kk .

Sol.

3n 10 r = 3 an d vkS j 4 n 10r = 6
n=9&r=3
28.

|n r| = 6

The coefficient of .
(1 + x + y z)9 ds .

Sol. (1 + x + y z)9 = {(1 z) + (x + y)}9


= 9C0 (1 z)9 + 9C1 (1 z)8 (x + y) + 9C2 (1 z)7 (x + y)2
+....+ 9C7 (1 z)2 (x + y)7 +.......
x3y4 appears in (x + y)7 only
(x + y)7 esa

Solving y = 7x + 5 and the circle x2 + y2 = 1


js[kk y = 7x + 5 vkSj o`k x2 + y2 = 1 dks gy djus

dsoy x3y4 gksxkA

so, the required coefficientblfy,

vHkh"V xq.kkad

= 9C7 (2) . 7C4


29.

3 4
4 3
5 , 5 and vkSj B 5 , 5

mOA =

Let ABC be an .

ekuk ABC U;wudks.k f=kHkqt

4
3
; mOB =
3
4

Hence vr%

Sol.
33.

ij

AOD = 90 ACB =

= tan1(1)
4

Statement 1: The sum


oDrO;-1 : ;ksxQy 40C0 .

oDrO;-2 : 40 yM+ds vkSj 60 yM+fd;ksa esa ls 10 fo|kfFkZ;ksa ds


pquus ds ep; 100C10 gSA
Sol. Obviously Li"Vr;rk%
34.

AEF : AF = bcosA , AE = ccosA

b2 cos2 A c 2 cos2 A EF2


cosA =
2b cos A.c cos A
(EF) 2 = (b 2 + c 2 2bccosA) cos 2 A
(EF) 2 = a 2 cos 2 A
EF = a.cosA

Passing through a
Statement-1: Locus of

,d fcUnq A(6, 8) ls tkus okyh


Sol. Let P (x1, y1) then w.r.t. the circle i.e. x2 + y2 6x 8y + 5
=0
T = 0 is xx1 + yy1 + g(x + x1) + f (y + y1) + c = 0 it passes
through A(6, 8)
ekuk P (x1, y1) gS] rc o`k x2 + y2 6x 8y + 5 = 0 ds lkis{k
T = 0, xx1 + yy1 + g(x + x1) + f (y + y1) + c = 0

gS tks A(6, 8)

ls xqtjrk gSA
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SOLJAPT3091114-5

2k 1 8Ck 1 2k 8Ck .....(1)


and vkSj
2k 1 8Ck 1 2k 2 8Ck 2 .....(2)

6x + 8y 3(x + 6) 4(y + 8) + 5 = 0
3x + 4y 18 32 + 5 = 0
3x + 4y 45 = 0
S-1 is incorrect
Also the point A (6, 8) lies outside S.
fcUnq A(6, 8) Hkh S ds ckgj fLFkr gSA
Hence S-1 is false and S-2 is true.
vr% oDrO;-1 vlR; gS] oDrO;-2 lR; gSA
35.

1
2

1
2

(9 k) k

again iqu%

2
1

k 1 10 k
20 2k k 1

21 3k
k7
6k7
T6 and T7 term has the greatest coefficient
T6 vkSj T7 vf/kdre xq.kkad j[krk gS
k = 6 or ;k 7

sum;ksxQy = 6 + 7 = 13

If kth terms is having .


;fn k ok in vf/kdre .
Sol. R = (1 + 2x)n
put x = 1 to get sum of all the coefficients
x = 1 j[kus ij lHkh xq.kkdksa dk ;ksxQy gS
37.

(35) for x =

;R=

n=8

2 1

2k 1 8Ck 1 2k 2 8Ck2

1
ds fy;s i ok
2

3n = 6561 = 38
1

k 18 3k k 6

8!2k 1
2k 2 8!

(k 1)! (9 k)!
(k 2)! (10 k)!

ds fy;s

If ith terms is the


x=

8!2k 1
2k 8!

(k 1)! (9 k)! k! (8 k)!

from (1)

The value of
x=

36.

vlR; gSA

ds fy,

Ans.]

consider

2 1 2 1 2

C0

I f f '

ekuk fd

........ even

2 1 2 1 2

C0

I f f '

........

le iw.kkZad gS

since I is integer

Tr 1 Tr

2 1

40.

Number of ways in ..
bu 16 f[kykfM;ksa dks ..

2 1

28 8!
=

1
2

(16)!
(4!)4 4!

Cr

Cr 1

T5 is the greatest term


T5 vf/kdre in gS

(2r 1) Ans.
r 1

16

12 others can be divided into 4 equal groups in

(12)!
(3!)4

(11)!
(12) (11)!
=
Ans.
108
6 6 6 6

vU; 12 dks 4 leku lewgks esa foHkkftr djus ds rjhds

(2)

(2)

ge Kkr dj ldrs gS ftlesa vf/kdre xq.kkad j[krk gS

12 others

fy, ;g lR; gS

(37) again iqu% Tk +1 = 8Ck 2k xk;


Tk = 8Ck 1 2k 1 xk 1
8
k2
Tk 1 = Ck 2 2
xk 2
we want to find the term having the greatest coefficient

35
27

P1,P2,P3,P4
(39)

9 2r

r 1

4! 4! 4! 4! 4!

8!
(r 1)! (9 r)!

1
r!(8 r)!
8!

for r = 1, 2, 3, 4 this is true ds


i.e.
T5 > T 4
but for r = 5, T6 < T5

(2r 1)

28 8 7 6 5
2935
=
(24) (24) (24) (24) (24)(24)(24)

Tr+1 Tr
8

la[;k

(9 r) r

Number of ways in ..
bu f[kykfM;ksa dks pkj ..

Sol.(38) Number of ways rjhdks

(36) Tr + 1 in (1 + 2x)8 = 8Cr(2x)r = 8Cr when tc x =

Tr 1
1
Tr

39.

f+f'=1

= 8 + 1 = 9 Ans.

now vc

Number of ways .
16 f[kykfM;ks dks ..

f + f ' must be an integer

pwfd I iw.kkZad gS
f + f ' iw.kkZad gksxk
but ijUrq
0<f+f'<2

f'=1f
now vc
n + R Rf
n + R(1 f) =

38.
integer

=
(40)

(11)!
(12) (11)!
=
Ans.
108
6 6 6 6

16

P1,P2,P3,P4,P5
P6
P7 P16(10)

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SOLJAPT3091114-6

(12)!
(3!)4

3
;

10

x=1

10!
3! 7!

7
000
xxxxxxx
+P6
P1 to P5
4 players 12 players
4
12!
Now , 12
4=
(4!)3 3!
4
(12)!
(10)!
Total ways dqy rjhds =

3! 7! (4!)3 3!
=

41.

(1,0)

family of circles touches the line x 1 = 0 at (1, 0) is


js[kk x 1 = 0 dks fcUnq (1, 0) ij Li'kZ djus okys o`k

fudk; dk lehdj.k gS
(x 1)2 + (y 0)2 + (x 1) = 0
passing through (3, 2)
4 + 4 + 2 = 0

=4
vHkh o`k (3, 2) xqtjrk gS vr% 4 + 4 + 2 = 0
= 4
x2 + y2 6x + 5 = 0

12!

20 k = 20 Ans.]
(4!)3

The radius of the circle

o`kks S1 = 0 ; S2 = 0 ,oa ..
42.

If the circle S = 0 is ..
;fn o`k S = 0, o`kksa S1 = 0

43.

The radius of the circle


o`kks S1 = 0 ,oa S2 = 0 dks .

(3,2)

radius f=kT;k =

Sol.

9 5 = 2 Ans.]

Part-II
Physics

S1
S2
1.

(1,0)

A uniform solid cuboid of mass m..................


m

(1,0)

nzO;eku dk ,d Bksl ?kukHk fpduh..................

Sol. F0 (a) = mg
(41)
t=

S1

S3 = 0

(1,0)

mgb
2ak

2.

(0,1)

(a,b)

Equal volumes of two immiscible..................

leku vk;ru ds rFkk 3?kuRo..................

r
(0,0)

b
2

1
S3

r = a + b + 1 = (a + 1)2 + b2 + 4 and
(a + 1)2 + b2 + 4 = a2 + (b + 1)2 + 4

Sol.

2a + 4 = 0
2a = 2b
a = 2, b = 2

r = 3 Ans.
x=1
S2 S3
y=1
Radical centre ewyk{k dsUnz = (1, 1)
r2 = 9

(42) S1 S2 = 0

radius

f=kT;k LT =

S1 = 1

P0 +
v1 =

equation of circle is o`k dh lehdj.k gS


(x 1)2 + (y 1)2 = 1

radius f=kT;k = 1
and ,oa
a + b + r = 3 Ans.
(43)

a=1 ; b=1

P 0+
v2 =

1
1
gh
+ v2 = P0 + 0 + v12
2
2
3
2gh
3

1
1
3gh
+gh+ v2 = P0 + 0 +
3 v22
2
2
3
4gh
3

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SOLJAPT3091114-7

3.

A sphere made of material of specific..................


8 fof'k"V

Sol.

4.

xq:Ro ds inkFkZ ds xksys esa..................

4 3
4 3 4
3
3 R1 3 R2 8g = 3 R1 g

9.

A thin uniform rod of mass M and..................

nzO;eku M rFkk yEckbZ L dh ,d iryh..................


tkZ laj{k.k ls

Sol. By conservationof energy

A uniform rod of length L and weight..................


L yEckbZ

rFkk WR Hkkj dh ,dleku NM+..................

Sol. The forces on rod hinged at O, which cause torque about


O are as shown.

ij fuyfEcr dh xbZ NM+ ij cy tks O ds ifjr% cyk?kw.kZ


mRiUu djrs gS] fn[kk;s x;s gSA
O

Since net torque on rod about hinge at O is zero

pwafd NM+ ij fuyEcu ds ifjr% usV vk?kw.kZ 'kwU; gSA

/2

T sin

T sin = WR

1 2
L
2 + 0 = 0 + 2 I

L
1 ML2 2
Mg
=

2 2 3
Mg

WR

+W
2

WR
W
2
or ;k T =
sin
6.

Speed of end point of the rod = L =

A circular wooden loop of mass m..................


m nzO;eku

ywi dh nzO;eku dsUnz ds ifjr% dks.kh; laosx laj{k.k }kjk


2
2
mVR
R
R
2
= m R m m w
2
2
2

V = 3 R

7.

10.

rFkk yEckbZ dh ,d NM+..................

izkjfEHkd laosx _.kkRed x-v{k ds vuqfn'k gSA vr% fudk; dk


vfUre laosx Hkh _.kkRed x-v{k ds vuqfn'k gksxkA
A cylinder A rolls without slipping..................

,d csyu A tks fd r[rs B ij fcuk..................


Sol. For rolling,

3gL

A smooth disc is rotating with uniform..................

og cy tks CykWd pdrh ij vkjksfir djrk gS pdrh ds ?kw.kZu


v{k ds lekUrj gSA ;g vfrfjDr cy pdrh ij dksbZ vk?kw.kZ
mRiUu ugh djrk gSA blfy;s pdrh dk dks.kh; laosx leku
jgrk gSA pwafd CykWd rFkk pdrh ds chp dksbZ ?k"kZ.k ugh gS]
blfy;s CykWd viuh fLFkfr esa gh jgsxkA

A rod of mass M and length is..................


M nzO;eku

3gL

,d fpduh pdrh ,d leku dks.kh; ..................


Sol. The only force block exerts on disc is parallel to axis of
rotation of disc. This additional force does not cause any
torque on disc,
Hence angular momentum of disc remains same.
Since there is no friction between block and disc, the block
remains in its position.

V
Ans. (B)
3R

Sol. Initial momentum is along negative x-axis. Hence final


total momentum of system will also be along negative
x-direction.

8.

NM+ ds vfUre fljs dh pky = L =

o R f=kT;k dk ,d o`kkdkj..................

Sol. Conservation of angular momentum about C.O.M. of m of


loop of mass m gives

3g
L

11.

Two vessels A and B of different shapes..................


fHkUu fHkUu vkdkj ds nks crZu A vkSj B..................

Sol. WA > WB as mass of water in A is more than in B


WA > WB pwafd A dk nzO;eku B ls T;knk gS
PA = P B
Area of A = Area of B
A dk {ks=kQy = B dk {ks=kQy
or ;k

vA = 2 m/s

PA AreaA = PB AreaB

PA {ks=kQyA = PB {ks=kQyB

yksVuh (rolling) xfr ds fy, vA = 2 m/s

or ;k
FA = F B .
An equilateral prism of mass m rests..................
m nzO;eku dk ,d leckgq fizTe ?k"kZ.k..................
Sol. The tendency of rotating will be about the pont C. For
minimum force, the torque of F about C has to be equal to
the torque of mg about C.
12.

or 4 1. = 2
or = 2 rad/sec. (clockwise) (nf{k.kkorZ)

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SOLJAPT3091114-8

fizTe dh fcUnq C ds izfr ?kw.kZu xfr djus dh izo`fr gSA U;wure


cy ds fy;s F dk fcUnq C ds ifjr% cy vk?kw.kZ mg dk C ds
ifjr% cy vk?kw.kZ ds cjkcj gksuk pkfg,
F

3
a
a
= mg
2
2

F=

mg

,d pDdj iwjk djrh gSA


;fn A ,d pDdj iw.kZ djrh gS rks bl le; vUrjky esa B nks
pDdj iwjs djrh gSA
fdlh Hkh {k.k ij A dk dks.kh; osx B ds dks.kh; osx ds leku
gksxk
fdlh Hkh {k.k ij A dk dks.kh; Roj.k B ds dks.kh; Roj.k ds
leku gksxk

Ans.

13.

At any instant, the angular velocity of A is equal to angular


velocity of B.
At any instant, the angular acceleration of A is equal to
angular acceleration of B.
;fn B ,d pDdj iw.kZ djrh gS rks bl le; vUrjky esa A Hkh

In the shown figure a force F is..................


m nzO;eku rFkk yEckbZ dh le:i..................

17.

A uniform rigid body, (mass M, Radius R)....................


,d le:i n`<+ oLrq (nzO;eku M, f=kT;k R) ....................
Sol. Applying energy conservation

tkZ laj{k.k }kjk


1
1
mv 2 2
mgh =
2
2

Sol. The force applied by the hinge may act in the same
direction as force F.
The force applied by the hinge may act in the opposite
direction as force F.
The force applied by the hinge may be zero.
vkyEcu }kjk NM+ ij vkjksfir fd;k x;k cy] cy F ds leku

fn'kk esa gks ldrk gSA


vkyEcu }kjk NM+ ij vkjksfir fd;k x;k cy] cy F ds
foifjr fn'kk esa gks ldrk gSA
vkyEcu }kjk NM+ ij vkjksfir fd;k x;k cy 'kwU; gks ldrk
gSA
14.

A uniform rigid body is given initial..................


,d le:i n`< oLrq dks izkjfEHkd..................
Sol. When the centre of mass of the body has moved a
distance on the incline, the gain in rotational kinetic

mgh =

V=

18.

1
1
V
mv 2 mK 2
2
2
R

2gh
K
1
R

A disc is performing pure rolling on.................

,d pdrh ,d leku dks.kh; osx ls.................


Sol. As the disc is in combined rotation and translation, each
point has a tangential velocity and a linear velocity in the
forward direction.

oLrq }kjk izkIr ?kw.kZu xfrt tkZ 'kwU;gSA

pdrh ?kw.khZ rFkk js[kh; xfr nksuksa dj jgh gSA vr% izR;s d fcUnq]
dh Li'kZ js[kh; osx rFkk js[kh; osx vxz fn'kk esa gksxk
From figure fp=kkuqlkj

When the centre of mass of the body has moved a


distance on the incline, the gain in total kinetic energy is

vnet (for lowest point) = v R= v v = 0.


vnet (fuEure fcUnq ij) = v R= v v = 0.

energy is zero.

tc oLrq dk nzO;eku dsUnz urry ij nwjh r; djrk gS rc

mgsin.

tc oLrq dk nzO;eku dsUnz urry ij nwjh r; djrk gS rc


oLrq }kjk izkIr dqy xfrt tkZ mgsingSA
15.

A vegetable vendor has a weighing..................


lCth fosrk ds ikl ,d Hkkjrqyk..................
Sol. If r1 = r2, then the balance will provide correct weight of the
vegetables weighted, on that balance.
If r1 > r2, then the customer will get lesser amount of
vegetables, as compared to the measured weight on that
balance.
;fn r1 = r2 gks, rks rqyk] lCth dh lgh ek=kk iznku djrh gSA

16.

and Acceleration =

vkSj Roj.k =

v2
v2
+0=
R
R

(Since linear speed is constant) (vr%

js[kh; osx fu;r gS)

Hence vr%

;fn r1 > r2 gks, rks rqyk }kjk xzkgd dks iznku dh lCth dh
ek=kk] ekfir Hkkj dh rqyuk esa de gksxhA

19.

Two discs A and B of radius R and 2R................

Sol.

nks pdrh;k A rFkk B ftudh f=kT;k R o 2R................


Sol. If B is rotated one complete revolution, then A has rotated
one complete revolution in that time.
If A is rotated one complete revolution, then B has rotated
two complete revolution in that time.

v2
v2
+0=
R
R

A nonuniform sphere at rest on a rough.................


fp=k esa n'kkZ;h vuqlkj ,d [kqjnjs {kSfrt.................

VP = Vcm rcm, but the Centre of mass C can be at any


distance rCM from P. Hence Vp can be in forward or

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SOLJAPT3091114-9

backward direction or can be zero. Consequently friction


can act in backward direction or forward or can be zero.
C nzO;eku dsUnz gS

Initially centripetal acceleration of point P is zero


( ac =

v2 0
0)
r
r

Acceleration of point P is
VP = Vcm rcm,

ijUrq nzO;eku dsUnz C fcUnq P ls fdlh nwjh


gSA vr% Vp dk eku 'kwU; ;k vxz fn'kk esa ;k i'p fn'kk
esa dqN Hkh gks ldrk gS vkSj blh izdkj ?k"kZ.k cy Hkh 'kwU; ;k
vxz fn'kk esa ;k i'p fn'kk esa dqN Hkh gks ldrk gSA

izkjEHk esa fcUnq P dk vfHkdsfUnz; Roj.k 'kwU; gS


v2 0
0 )
( ac =
r
r

rCM ij

20.

fcUnq P dk Roj.k

A uniform rod AB of mass m and.................


m nzO;eku

o yEckbZ dh ,d.................

Sol. Impulse = change in momentum


vkosx = laosx ifjorZu

= at = L =

aC2 a2t

3
g cos
2

24.

m 2
P.
=
.
2
12
(AB ds dsUnz ds ifjr%)
6P
=
m

For =
ds fy, ;
= t t =
=
2
2
2 6p
2
(about centre of AB)

m
t=
12p

aC2 a2t

A rigid body undergoing pure rolling.................


,d n`<+ oLrq {kSfrt n`<+ iFk AB rFkk BC.................
Sol. Angular momentum will be conserved as external torque
is zero.

dks.kh; laosx lajf{kr jgsxk D;ksafd ck cyk/kw.kZ 'kwU; gSA


25.

,d iryh NM+ AB nks yEcor~ fLFkj.................


Sol. The point D is the instantaneous centre of rotation.
rkR{kf.kd ?kw.kZu dsUnz fcUnq D gSA
1
1
1
2
2
2
K.E.= D = A = B
2
2
2

Ans.

21.

A uniform body of circular cross-section.................


o`kkdkj dkV {ks=k (f=kT;k R) dh ,d.................
Sol. Body comes to rest and applying angular momentum
conservation about any point on the ground.

A thin rod AB is sliding between.................

A block of density 2000 kg/m3 and mass 10 kg.................


?kuRo 2000 kg/m3 o nzO;eku 10 kg.................
Sol. Kx = V(2000) (10) V (1000) (10)
26.

oLrq fLFkj voLFkk esa vk tk;sxh rFkk tehu ij fLFkr fdlh


fcUnq ds lkis{k dks.kh; laosx laj{k.k ds }kjk
mv0R mK20 = 0
22.

Two men of equal masses stand.................

fu;r dks.kh; osx ls ?kweus okyh ,d.................


Sol. 11 = 22
Since, men move towards middle of turn table 2
decreases hence 2 increases.
pwafd, O;fDr dsUnz dh vksj xfr djrs gS blfy, 2 ?kVsxk
QyLo:i 2 c<sxkA
1
1
K =
112
222
2
2
2
1
=
112 1 2 . 22
2
1 1

1
2
11
2

Ustored =

At the shown instant a uniform disc.................


iznf'kZr {k.k ij M nzO;eku rFkk R f=kT;k.................
Sol. The magnitude of angular momentum of disc about a point

xfrt tkZ c<sxhA

rFkk M nzO;eku dh ,d.................


Sol. About point O (fcUnq O ds lkis{k cyk?kw.kZ)
Torque = I

L
ML
cos) =

2
3

1
1 2500
50
(100)
= 12.5 J
=
2
2 100
100

27.

B (as shown) is

L yEckbZ

Mg (

... (b)
2

A uniform pole of length L and.................

10
[ 1000 10]
2000

Kx = 50 N

2
1 < 0
1

So kinetic energy increases. vr%

23.

3g
cos
2L

The magnitude of angular momentum of disc about a point


C (as shown) is

1
MR2
2
1
MR2
2

The magnitude of angular momentum of disc about a point


D (as shown) is

1
MR2
2

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SOLJAPT3091114-10

28.

iznf'kZr fcUnq B ds ifjr% pdrh ds dks.kh; laosx dk ifjek.k


1
MR2gSa
2
iznf'kZr fcUnq C ds ifjr% pdrh ds dks.kh; laosx dk ifjek.k
1
MR2gSa
2
iznf'kZr fcUnq D ds ifjr% pdrh ds dks.kh; laosx dk ifjek.k
1
MR2gSa
2
A circular disc of radius R rolls.............
R f=kT;k dh ,d o`kkdj pdrh.............

Sol.

About the centre of mass frame all the sectors AOB, BOC,
COD, DOA have the same rotational kinetic energy.
Sol. fcUnq D ds lkis{k rkR{kf.kd v{k ysus ij Hkkx AOB rFkk BOC

dh xfrt tkZ leku gSA pwafd nksauks Hkkx fcUnq D ds lkis{k


lefer :i ls fLFkr gSA
blfy, nksauks Hkkxksa dh fcUnq D ls xqtjus okyh v{k ds ifjr%
?kw.kZu xfrt tkZ leku gSA nzO;eku dsUnz ds funsZ'k rU=k esa
Hkkx AOB, BOC, COD, DOA dh ?kw.kZu xfrt tkZ leku gSA
32.

A rod AB is free to rotate on a smooth.............


NM+ AB fpdus {kSfrt ry ij fljs A ls.............
Sol. angular momentum of rod plus particle system about point
A is conserved during collision.
VDdj ds nkSjku d.k rFkk NM+ fudk; dk fcUnq A ds lkis{k

dks.kh; laosx lajf{kr jgrk gSA


angular momentum of rod plus particle system about point
E may increase after collision
VDdj ds i'pkr~ d.k rFkk NM+ fudk; dk fcUnq E ds lkis{k

a, v

dks.kh; laosx c<+ ldrk gSA


a, v

33.
29.

STATEMENT-1 : The necessary condition.............


oDrO;-1 : yksVuh (Rolling) xfr dh vko';d.............
Sol. For pure rolling presence of nonzero friction force is not
required. Hence statement-I is wrong. Statement-2 is
correct.

Figure shows a container filled with.............

fp=k esa n'kkZ;s x;s ik=k esa ?kuRo


Sol. According to Pascal's law,

dk.............

ikLdy ds fu;ekuqlkj]
PB = P D
because B and D lie on the same horizontal plane.
D;ksafd B o D leku {kSfrt Lrj ij gSA
Let l be the side of the square. Then the vertical distance
between A and C is l 2 .
ekuk oxZ dh Hkqtk l gSA rc A

rFkk C ds e/; m/okZ/kj nwjh l

2 gSSA
PB = PD = PC g

'kq) yksVuh xfr ds fy, v'kwU; ?k"kZ.k gksuk vko';d ugh gSA
blfy;s dFku-1 xyr gSA o dFku-2 lgh gSA
34.

STATEMENT-1 : A wooden cylinder floats.............


oDrO;1 : ,d ydM+h dk csyu ikuh ds rkykc.............
Sol. To float a cylinder vertically in a liquid its centre of gravity
should exist below centre of buoyancy of the submerged
part of it.Hence statement-2 is True.

nzo esa /okZ/kj rSjrs gq;s csyu dk xq:Roh; dsUnz] mlds Mqcs
gq;s Hkkx ds mRIykou ds dsUnz ds uhps mifLFkr gksxkA vr%
oDrO;-2 lR; gSA

....(i)

2
35.

Let the value of horizontal distance.............


ekuk csyu dh ryh ls ml fcUnq dh.............

36.

As long as water comes out of hole.............

tSls tSls ty fNnz ls ckgj dh vksj.............


Similarly, blh

PB = P D =

izdkj PB = PD = PA + g

.....(ii)

PA PC
2

The duration of time for which.............


fdl le;kUrjky ds fy, ty.............

Sol. 35 to 37
The initial velocity of water coming out of hole is horizontal

30.

Two isotropic blocks A and B are.............


nks lenSf'kd CykWd A rFkk B fp=kkuqlkj.............
Sol. Because in both the situation liquid displaced is equal to
the weight of blocks

D;ksafad nksauks fLFkfr;ksa esa foLFkkfir nzo CykWd ds Hkkj ds cjkcj


gksxkA
31.

37.

A rigid uniform circular disc rolls.............


fp=kkuqlkj fu;r pky ls /kukRed.............
Sol. Taking the instantaneous axis of rotation about point D,
sector AOB and BOC have same kinetic energy since
these sectors are symmetrically located with respect to
point D, hence have the same rotational kinetic energy
about the axis passing through point D.

and hole is at a height

h
from ground. Hence time taken
4

by water to reach ground is t =

2(h / 4)
which remains
g

constant.
x = vt
where v is velocity of effux....
Since v decreases wth time x will decrease.

v
v

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SOLJAPT3091114-11

Let y be the height of water surface above hole

a 2gy
av
dy
=
=
A
A
dt
0

dy

6g
7L
mg
mg
L
2mg
maCM =
N N =
m
N =

2
2
4
7
=

2gy

3h / 4

a
dt
A

t=

A
a

3h
2g

fNnz ds ckgj vkus ij ty dk izkjfEHkd osx {kSfrt gS rFkk fNnz


h
{kSfrt lrg ls
pkbZ ij gSA vr% ty }kjk {kSfrt lrg
4

2(h / 4)
rd igqpus es yxk; le; t =
g

gksxk tks fu;r

41.

The moment of inertia of system.............

oy; ds v{k ds lkis{k fudk; .............


42.

The acceleration of centre of mass.............


fudk; ds nzO;eku dsUnz.............

43.

The minimum value of coefficient.............

fQlyu jksdus ds fy, U;wure.............


Sol. (41 to 43)

jgrk gSA

12

x = vt

tgk v ckgj vkus dk osx ....


pawfd v le; ds lkFk ?kV jgk gSa
y

M R 2
= I

2
R
2 = 20 kgm 2.
M
4 mR
2

(4M + m)g sin f = (4M + m)a.

f.R. =

a
R

F

vr% x ?kVsxkA ekuk fNnz ls ty lrg dh apkbZ y gS

a 2gy
av
dy
=
=
A
A
dt

dy

3h / 4

t=

A
a

2gy

gy djus ij
7g
a
24

Solving

a
dt
A

f = 20a (4M + m)g cos 30

3h
2g

12 3
39.

The friction force acting on.............


NM+ ij vjksfir ?k"kZ.k cy.............
Sol. N + T = mg sin30
Net = 0, mg sin30

min =

12 3 12 3

L 3L
=
T
4
4

Part-III
Chemistry
1.

An aqueous solution having pH = 7 .............


80C ij pH = 7 okyk

tyh; foy;u ------------------

Sol. As temp, Kw so at 80C, neutral point will at pH < 7


solution of pH = 7 will be basic.
T=
40.

mg
f = mg cos30 =
6

3mg
2

Sol.

rki, Kw vr% 80C ij mnklhu fcUnq pH < 7 ij gksxkA


pH = 7 dk

foy;u {kkjh; gksxkA

Just after the string is cut, the normal.............

jLlh dks dkVus ds rqjUr i'pkr~.............


Sol. Torque about the point at which normal acts.
tgkW vfHkyEc cy dk;Zjr gSA ml fcUnq ds lkis{k cyk?kw.kZ
mg L

=
2 4
2
mL2
mgL
L

4 = 8
12

2.

Following five solutions of Ca(OH)2 ................

dejs ds rki ij Ca(OH)2 ds fuEu ikp foy;u -------------------Sol. All solutions have [Ca(OH)2] = 0.01M

lHkh foy;u esa [Ca(OH)2] = 0.01M gSA

[OH ] = 2 102M
pOH = 1.7
pH = 12.3

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SOLJAPT3091114-12

3.

Initially for the equilibrium x2 + y2

lkE; x2 + y2
Sol.

2xy ds
x2

fy, izkjEHk esa .................

y2

2xy

2
M
5

2
M
5

at equilibrium 0.4a

0.4a

Initial conc.

fdl fLFkfr esa -ca/k ;qXe rFkk cU/k ------------------

2xy ...................

Sol.

12.

Sol. OF is derivative of O2 and isoelectronic with O2.

[x2]eq = [y2]eq = 0.05M


Sol.

x2

y2

2
M
5

izkjfEHkd

So (1s)2 (*1s)2 (2s)2 (*2s)2 (2pz)2 (2p2x =

2xy

2p2y ) (*2px2 = *2p1y)

2
M
5

The bond order of OF 1/2(10 7) = 1.5.

gy % OF v.kq O2 dk O;qRiUu gS vkSj O2 ls lebysDVkWfud gSA

lkanzrk
lkE; ij

A simplified application of MO theory ...............

,d dkYifud 'v.kq' OF ds fy, MO fl)kUr ---------------------

2a = 0.7
a = 0.35M

(I, m)

0.4a

0.4a

vr% (1s)2 (*1s)2 (2s)2 (*2s)2 (2pz)2 (2p2x =

2a = 0.7
a = 0.35M

2p2y ) (*2px2 = *2p1y)

[x2]eq = [y2]eq = 0.05M

OF
4.

dk ca/k e 1/2(10 7) = 1.5.

For a real gas (vander Waal's gas) behaving ...............

,d okLrfod xSl okMajoky xSl tks vkn'kZ -------------------------

13.

Sol. A real gas behaves ideally at Boyle's temperature.

,d okLrfod xSl ckW;y rki ij vkn'kZ O;ogkj djrh gSA

PVM
Z=
=1
RT

Select correct statement(s) .................

lgh dFku@dFkuksa dks pqfu, --------------------------Sol. KP

of

particular

reaction

depends

only

on

temperature.

a
R
RT
Rb = a
P=
=
VM
VM
VM .b

On increasing pressure reaction NH4HS(s)


NH3(g) + H2S(g) moves in backward direction, so
dissociation is suppressed.
High pressure is favourable for metting of ice.
During dissociation of PCl5(g), number of moles

5.

At critical temperature, which of the .................

kfUrd rki ij dkSulk xzkQ --------------------

increases, so Mavg decreases.


Sol.

Sol. TC < TB (Boyle's temperature)

gSA

So

blfy,

nkc c<+kus ij vfHkf;k NH4HS(s)

H2S(g) i'p

PV

Sol. TC < TB (ckW;y

,d fuf'pr vfHkf;k dkKP dsoy rki ij fuHkZj djrk

P
rki)

fn'kk esa tkrh gS vr% fo;kstu ?kV tkrk gSA

mPp nkc cQZ ds fi?kyus ds i{k esa gksrk gSA

PCl5(g) ds
Mavg ?kVrk
14.

PV

NH3(g) +

fo?kVu ds nkSjku] eksyksa dh la[;k c<+rh gS vr%

gSA

For the endothermic reaction


3A(g)

B(g) + C(g) ......................

"ek'kks"kh vfHkf;k ds fy,

P
6.

3A(g)

If K1 and K2 are the equilibrium ...............

;fn ,d mRe.kh; vfHkf;k ds fy, T1K ------------------Sol. If H = 0

[A(g)] will increase.


On decreasing volume, concentration of all species
will increase.

K1 = K2 at all temperature.
Sol.

On adding B(g), reaction will move in backward

;fn H = 0

direction, [A(g)] will increase.

rks lHkh rki ij K1 = K2

Sol.

9.

B(g) + C(g) ................

Sol. On temp, reaction moves in backward direction,

In which case the -bond pair ..............

rki ij] vfHkf;k i'p fn'kk esa tkrh gS [A(g)] c<+sxhA


vk;ru ?kVkus ij] lHkh fLi'kht dh lkUnzrk c<+sxhA

B(g) feykus

ij, vfHkf;k i'p fn'kk tk;sxh] [A(g)] c<+sxhA

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SOLJAPT3091114-13

17.
15.

For the reaction

The reaction pKa = 14 pKb is ...............

fuEu esa ls fdl ;qXe@;qXeksa ds fy, pKa .............

H2(g) + I2(g)

2HI(g) ...............

Sol. pKa = 14 pKb is applicable for weak conjugate acid base

2HI(g) .................

Sol.

vfHkf;k ds fy,

pair.

H2(g) + I2(g)

Sol. Changing volume will change partial pressure of all

nqcZy la;qXeh vEy {kkj ;qXe ds fy, pKa = 14 pKb ykxw gksrk
gSA

species.
Changing temperature will change KP, so partial

18.

pressure of all species will change


Adding inert gas at constant volume & temperature
will not change the partial pressure of any

species.

lgh dFku@dFkuksa dk p;u -------------------Sol. Vc = 3b = 3(4VNA) = 12(VNA)


= 12 (Volume of 1 mole of gaseous molecules)

Adding inert gas at constant pressure & temperature


will
Sol.

increase volume, so
species will decrease.

partial

pressure

of

all

Tb > Tc, so gas can't be liquefied above Tb.

V=

lHkh Lih'kht dk vkaf'kd nkc cny tkrk gSA

fLFkj vk;ru o rkieku ij vf; xSl feykus ij fdlh

At Boyle's temperature, second virial coefficient

fLFkj nkc o rki ij vf; xSl feykus ij lHkh Lih'kht

Consider the reaction ...............

KC=10

12

TB =

vfHkf;k P(g) + 2Q(g)


Sol.

R(g) + S(g) ..........

P(g) + 2Q(g)

R(g) + S(g)

KC = 1012 =

x(2x)2

nRT
+ nb
P
ckW;y rki ij] f}rh;d fofj;y xq.kkad 'kwU; gksxk nh xbZ

mPp nkc ij (P) (V-nb) = nRT


V=

x = 104M

lehdj.k dks gy djus ij f}rh;d fofj;y xq.kkad


gksxkA
RT 2

P(g) + 2Q(g)

R(g) + S(g)

2M

KC = 1012
4M

TB =

lkUnzrk
D;ksafd KC cgqr vf/kd gS] vfHkf;k yxHkx iw.kZ gks tk;sxhA
lkE; lkUnzrk ij

2x

2M

(x 0)

(2)(2)
x(2x)2

[P(g)]eq = 104M
[Q(g)eq = 2 104M

xSl Tb ds ij nzohr ugha gksxhA

[R(g) = [S(g) = 2M

KC = 1012 =

xSlh; v.kqvksa dk vk;ru)

[Q(g)eq = 2 104M

izkjfEHkd

=0

Tb > Tc, vr%

[P(g)]eq = 104M

Sol.

RTB2

= 12 (1 eksy

(x 0)

(2)(2)

Sol. Vc = 3b = 3(4VNA) = 12(VNA)

12

KC = 10
Initial conc. 2M
4M
0
0
Since KC it very large, reaction will almost take place to
completion.
at equilibrium conc.
x
2x
2M
2M

the given equation


comes out to be


.
RT 2

dk vkaf'kd nkc ?kV tkrk gSA


16.

nRT
+ nb
P

becomes zero, on solving


second virial coefficient

Hkh Lih'kht dk vkaf'kd nkc ifjofrZr ugha gksrk gSA

At high pressure (P) (V-nb) = nRT

vk;ru cnyus ij lHkh fLi'kht dk vkaf'kd nkc cny

tkrk gSA

Select correct statement .................

19.
2M

RTB2

=0

A vessel contains a mixture of H2 ...............

,d ik=k esa H2 o D2 xSlksa dk feJ.k ---------------------Sol. D2 is heavier than H2 hence rate of effusion of D2 is less

x = 104M

than that of H2.


Mole fraction of D2 in the gas remaining in the vessel
will increase with time.
The average molecular mass of gas remaining in the
vessel will increase with time.

[R(g) = [S(g) = 2M

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SOLJAPT3091114-14

Sol. D2 ,H2 ls

Hkkjh gksrh gSA vr% D2 dh folj.k dh nj H2 dh rqyuk

Sol. (A) IInd has higher resonance energy than Ist due to
extended conjugated while in first cross conjugated is

esa de gksrh gSA


ik=k

present.

esa 'ks"k cph xSl esa D2 dk eksy fHkUu le; ds lkFk

(B) Resonance in IInd taking place upto greater extent

c<+rk gSA

than that of first therefore IInd will have higher resonance

ik=k esa 'ks"k cph xSl dk vkSlr vkf.od nzO;eku le; ds

energy.

lkFk c<+rk gSA

(C) Resonance in IInd taking place upto greater extent


than that of first therefore second will have higher

20.

Which of the following will occur .................

resonance energy.

fuEu esa ls D;k ?kfVr gksxk] ;fn fu;r -------------------

(D) Both are having same resonance energy since both


are the resonance energy of same compound.

Sol. From Ostward's dilution law at constant temperature as

Sol. (A) IInd ;kSfxd

C, , [H+], pH
Sol.

vkWLVokYM fu;e ls] fLFkj rki ij C, , [H+], pH

21.

The equilibrium constant for some gaseous ...............

dh vuquknh tkZ izlkfjr la;qXeu ds dkj.k Ist

ls vf/kd gksrh gSA tcfd izFke ;kSfxd esa kWl la;qXeu ik;k
tkrk gSA
(B) IInd

uhps dqN xSlh; vfHkf;kvksa ds fy, lkE; --------------------------

ik;k tkrk gSA blfy, IInd dh vuquknh tkZ vf/kd gksxhA

1
Sol. Stability of Reactant
equilibrium cons tan t

(C) IInd

most stable oxide NO

f;kdkjd dk LFkk;hRo

;kSfxd esa vuqukn izFke dh rqyuk esa vf/kd ek=kk esa

ik;k tkrk gSA blfy, f}rh; ;kSfxd dh vuquknh vf/kd gksxhA

least stable oxide NO2


Sol.

;kSfxd esa vuqukn izFke dh rqyuk esa vR;f/kd ek=kk esa

(D)

;kSfxd leku gSA

lkE; fLFkjkad

lokZf/kd LFkk;h vkWDlkbM NO

nksuksa ;kSfxdksa dh vuquknh tkZ leku gksxh D;ksafd nksuksa

28.

U;wure LFkk;h vkWDlkbM NO2

Which of the following compound ..............


fuEu esa ls dkSuls ;kSfxd ,sjkseSfVd ------------------

Sol. (A) Non aromatic uksu ,sjkseSfVd


22.

A vessel containing N2 gas at 1atm .............

(B) Aromatic ,sjkseSfVd

nkc ij N2 ;qDr ,d ik=k -------------------

(C) Aromatic ,sjkseSfVd

1atm

(D) Aromatic ,sjkseSfVd

Sol. In the vessel PN = 1 atm


2

33.

In the room PN = 0.8 atm


2

oDkO;-1 : pH = 5 okys IL foy;u dks 100L ---------------------

PO2 = 0.2 atm

Sol.

Statement-1 : On diluting IL of a solution .............

Sol. On diluting 1L of a solution of pH = 5 to 100 L new pH will

So O2 will effuse into the vessel & N2 will effuse out from

be less than 7, since contribution of water will also be

the vessel.

considered.

ik=k esa PN2 = 1 atm

Sol. pH = 5

okys 1L foy;u dks 100 L rd ruq djus ij ubZ pH 7

ls de gksxh] vr% ty dk ;ksxnku Hkh tksMk tkrk gSA

dejs esa PN2 = 0.8 atm

PO2 = 0.2 atm

34.

vr% O2 ik=k esa rFkk N2 ik=k ls fulfjr gksxhA

Statement-1 : Carbonoxygen bonds .............

oDkO;-1 : dkcZu&vkWDlhtu cU/k ,lhVsV --------------------Sol. Acetate ion have two equivalent resonating structure and

27.

Which of the following is/are .............

fuEu esa ls fdlesa f}rh; dh vuquknh ------------------

thus both the bonds have identical bond length.

gy. ,lhVsV vk;u dh nks leku vuquknh lajpuk gksrh gSA vr%
nksuksa cU/k leku cU/k yEckbZ ds gksrs gSaA

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SOLJAPT3091114-15

35.

The initial partial pressure of C2H4 .............


C2H4 dk

Sol.

38.

izkjfEHkd vkaf'kd nkc .................

vfHkf;k ds fy, lkE; fLFkjkad -------------------Sol.

PC2H4 + PCO + PN2 = 250 mm of Hg

P
O2

added

What is the equilibrium constant ..............

2HI(g)
Initial mole

at equilibrium mole

H2(g) + I2(g)
0

= 250 mm of Hg

(PTotal)after reaction = 370 mm of Hg

P
CO2

(PCO2 ) + PN2 + V.P. of H2O + PO2 left

(PTotal)after reaction =
370 = 200 + 20 +

PN2 + PO2
let

left

PC2H4 = a

= 150 mm of Hg

C2H4 + 3O2

PN2 = 250ab PCO2

P
O2

= 3a +

used

left

lkE; eksy

What is the degree of dissociation ...............

;fn iz;ksx dks ,d eksy HI ----------------------

b
2

Sol. If I2(g) is also taken initially, then degree of dissociation of


HI will be less than 25%.
Sol.

;fn izkjEHk esa I2(g) dks fy;k tkrk gS rks HI dk fo;kstu 25% ls
de gksrk gSA

8a + 3b = 700

40.

....(iii)

Solving equation (ii) & (iii)

What is the degree of dissociation ...............

;fn vfHkf;k dks ,d eksy HI ------------------------Sol. If one mole He is also taken initially then degree of

lehdj.k (ii) ls (iii) dks gy djus ij

dissociation will remain same at same temperature.

PC2H4

;fn izkjEHk esa ,d eksy He dks Hkh fy;k tkrk gS rks leku rki
ij fo;kstu dh ek=kk leku jgrh gSA

b = 100 = PCO

Total O2 consumed in mm ................

dqy mi;ksx gksus okyh O2 mm ...............

b
= 150 + 50 = 200 mm
2

43.

Which of the following hydrogen ...........

fuEu esa ls dkSu gkbMkstu cU/k -------------------Sol. Because of highest electronegativity of F, hydrogen
bonding in F H - - - - F is strongest.
Sol. F

37.

The sum of initial pressure of CO .................

LikfdZx (sparking) ls igys CO -----------------------Sol.


.
2
1
2 2 = (0.25)
KC =
=
= 0.027
2
2
36
(1 )
4 (0.75)

39.

b
(250 a b) + (250 3a
) = 150
2

Sol. O2 used = 3a +

= 200 = 2a + b ....(ii)

formed

b
2

= 250 3a

2CO2 + 2H2O()

lehdj.k (i) ls

36.

izkjfEHkd eksy

H2(g) + I2(g)

.......(i)

from equation (i)

a = 50 =

2HI(g)

1
CO +
O2
CO2
2

PCO = b

O2

Sol.

PN2 + PO2 left


.
2
1
2 2 = (0.25)
KC =
=
= 0.027
2
2
36
(1 )
4 (0.75)

= 200 mm of Hg

formed

dh fo|qr_.krk vf/kd gksus ls F H - - - - F esa gkbMkstu

ca/kqrk izcy gksrh gSA

PCO PO2 = 100 + 250 = 350 MM

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SOLJAPT3091114-16

PART TEST-3 (PT-3)


(JEE ADVANCED PATTERN)

TARGET : JEE(MAIN +ADVANCED)2016

DATE : 09-11-2014

COURSE : VIKAAS (JA)


ANSWER KEY

CODE-0
MATHEMATICS
1.

(B)

2.

(C)

3.

(C)

4.

(B)

5.

(A)

6.

(D)

7.

(C)

8.

(B)

9.

(A)

10.

(B)

11.

(B)

12.

(D)

13.

(BC)

14.

(BD)

15.

(ABCD) 16.

(ABC) 17.

(BD)

18.

(BCD) 19.

(AC)

20.

(BC)

21.

(BD)

22.

(BCD) 23.

(AB)

24.

(ABCD) 25.

(ABC) 26.

(CD)

27.

(ABCD) 28.

(BD)

29.

(BC)

30.

(ACD) 31.

(BCD) 32.

(BD)

33.

(A)

34.

(D)

35.

(C)

36.

(B)

37.

(D)

(D)

(B)

40.

(D)

41.

(C)

42.

(D)

43.

(C)

7.

(B)

38.

39.

PHYSICS
1.

(C)

2.

(B)

3.

(D)

4.

(D)

5.

(B)

6.

(B)

8.

(A)

9.

(C)

10.

(C)

11.

(B)

12.

(A)

13.

(BCD) 14.

(CD)

15.

(AB)

16.

(ABCD) 17.

(AC)

18.

(BD)

19.

(ABC) 20.

(AC)

21.

(ABC)

22.

(BCD) 23.

(AB)

24.

(BC)

25.

(ABD) 26.

(BC)

27.

(BCD) 28.

(ABCD)

29.

(ABD) 30.

(AB)

31.

(ABCD) 32.

(BC)

33.

(D)

34.

(D)

35.

(B)

36.

(C)

(A)

38.

(B)

(C)

40.

(C)

41.

(A)

42.

(C)

43.

(B)

37.

39.

CHEMISTRY
1.

(B)

2.

(C)

3.

(D)

4.

(C)

5.

(A)

6.

(D)

7.

(D)

8.

(D)

9.

(C)

10.

(B)

11.

(A)

12.

(B)

13.

(BD)

14.

(ACD)

15.

(B)

16.

(ACD) 17.

(AB)

18.

(ACD) 19.

(BC)

20.

(ABC) 21.

(AB)

22.

(AB)

23.

(ACD) 24.

(ACD) 25.

(ABD) 26.

(CD)

27.

(ABC) 28.

(BCD)

29.

(AB)

30.

(AB)

31.

(ACD) 32.

(BC)

33.

(D)

34.

(B)

35.

(B)

36.

(C)

37.

(D)

38.

(B)

(A)

40.

(C)

41.

(D)

42.

(D)

43.

(D)

39.

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SOLJAPT3091114-17

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