Chemistry-IIT JEE Mains 2014, 6 April: Topper's Choice Prof. Pawan Babel (PKB)

1. Consider separate solutions of 0.
500 M
C
2
H
5
OH(aq), 0.100 M Mg
3
(PO
4
)
2
(aq),
0.250 M KBr(aq) and 0.125 M Na
3
PO
4
(aq)
at 258C. Which statement is true about
these solutions, assuming all salts to be
strong electrolytes ?
(1) 0.100 M Mg
3
(PO
4
)
2
(aq) has the
highest osmotic pressure.
(2) 0.125 M Na
3
PO
4
(aq) has the highest
osmotic pressure.
(3) 0.500 M C
2
H
5
OH(aq) has the
highest osmotic pressure.
(4) They all have the same osmotic
pressure.
2. Which one of the following bases is not
present in DNA ?
(1) Adenine
(2) Cytosine
(3) Thymine
(4) Quinoline
3. Considering the basic strength of amines
in aqueous solution, which one has the
smallest pK
b
value ?
(1) CH
3
NH
2
(2) (CH
3
)
3
N
(3) C
6
H
5
NH
2
(4) (CH
3
)
2
NH
Chemistry- IIT JEE Mains 2014, 6 April
4. The metal that cannot be obtained by
electrolysis of an aqueous solution of its
salts is :
(1) Ca
(2) Cu
(3) Cr
(4) Ag
5. On heating an aliphatic primary amine
with chloroform and ethanolic potassium
hydroxide, the organic compound formed
is :
(1) an alkanediol
(2) an alkyl cyanide
(3) an alkyl isocyanide
(4) an alkanol
6. For the reaction SO
2(g)
1
2
1
O
2(g)
SO
3(g)
,
if K
P
5K
C
(RT)
x
where the symbols have
usual meaning then the value of x is :
(assuming ideality)
(1)
1
2
2
(2)
1
2
(3) 1
(4) 21
Topper's Choice Prof. Pawan Babel (PKB)
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7. Given below are the half - cell reactions :
Mn
21
12e
2
Mn ; E
o
521.18 V
2(Mn
31
1e
2
Mn
21
) ; E
o
511.51 V
The E
o
for 3Mn
21
Mn12Mn
31
will be :
(1) 22.69 V ; the reaction will occur
(2) 20.33 V ; the reaction will not occur
(3) 20.33 V ; the reaction will occur
(4) 22.69 V ; the reaction will not occur
8. If Z is a compressibility factor,
van der Waals equation at low pressure
can be written as :
(1) Z512
a
VRT
(2) Z512
Pb
RT
(3) Z511
Pb
RT
(4) Z511
RT
Pb
9. In the reaction,
4 5
LiAlH PCl Alc. KOH
3
CH COOH A B C
,
the product C is :
(1) Acetylene
(2) Ethylene
(3) Acetyl chloride
(4) Acetaldehyde
10. Among the following oxoacids, the correct
decreasing order of acid strength is :
(1) HClO
4
> HOCl > HClO
2
> HClO
3
(2) HClO
4
> HClO
3
> HClO
2
> HOCl
(3) HClO
2
> HClO
4
> HClO
3
> HOCl
(4) HOCl > HClO
2
> HClO
3
> HClO
4
11. The ratio of masses of oxygen and nitrogen
in a particular gaseous mixture is 1 : 4. The
ratio of number of their molecule is :
(1) 7 : 32
(2) 1 : 8
(3) 3 : 16
(4) 1 : 4
12. Which one of the following properties is
not shown by NO ?
(1) It is a neutral oxide
(2) It combines with oxygen to form
nitrogen dioxide
(3) Its bond order is 2.5
(4) It is diamagnetic in gaseous state
13. Which series of reactions correctly
represents chemical relations related to
iron and its compound ?
(1)

O ,
Fe FeO
heat

dil H
2 2
SO
4
he
at
FeSO
4
Fe
(2)
Cl
2
,

heat heat,
air
Fe FeCl
3

Zn
FeCl
2
Fe
(3)
O
2
,

he
at CO
, 600
8C
Fe Fe O
3 4

FeO
CO, 7
008C
Fe
(4)
H SO
2 4
, O
2
dil H SO
Fe
2 4
FeSO
4

heat
Fe (SO
2 4
)
3
Fe
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14. For which of the following molecule
significant m0 ?
(a) (b)
(c) (d)
(1) (a) and (b)
(2) Only (c)
(3) (c) and (d)
(4) Only (a)
15. CsCl crystallises in body centred cubic
lattice. If a is its edge length then which
of the following expressions is correct ?
(1)
Cs Cl
3a
r r
2
1 2
1 5
(2)
Cs Cl
3
r r a
2
1 2
1 5
(3)
Cs Cl
r r 3a
1 2
1 5
(4)
Cs Cl
r r 3a
1 2
1 5
16. Which one is classified as a condensation
polymer ?
(1) Neoprene
(2) Teflon
(3) Acrylonitrile
(4) Dacron
17. For the estimation of nitrogen, 1.4 g of an
organic compound was digested by
Kjeldahl method and the evolved ammonia
was absorbed in 60 mL of
M
10
sulphuric
acid. The unreacted acid required 20 mL
of
M
10
sodium hydroxide for complete
neutralization. The percentage of nitrogen
in the compound is :
(1) 10%
(2) 3%
(3) 5%
(4) 6%
18. For complete combustion of ethanol,
C
2
H
5
OH(l)13O
2
(g) 2CO
2
(g)13H
2
O(l),
the amount of heat produced as measured
in bomb calorimeter, is 1364.47 kJ mol
21
at 258C. Assuming ideality the Enthalpy
of combustion, D
c
H, for the reaction will
be :
(R58.314 kJ mol
21
)
(1) 21361.95 kJ mol
21
(2) 21460.50 kJ mol
21
(3) 21350.50 kJ mol
21
(4) 21366.95 kJ mol
21
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19. The octahedral complex of a metal ion
M
31
with four monodentate ligands L
1
,
L
2
, L
3
and L
4
absorb wavelengths in the
region of red, green, yellow and blue,
respectively. The increasing order of ligand
strength of the four ligands is :
(1) L
1
< L
3
< L
2
< L
4
(2) L
3
< L
2
< L
4
< L
1
(3) L
1
< L
2
< L
4
< L
3
(4) L
4
< L
3
< L
2
< L
1
20. The most suitable reagent for the
conversion of R2CH
2
2OH R2CHO
is :
(1) K
2
Cr
2
O
7
(2) CrO
3
(3) PCC (Pyridinium Chlorochromate)
(4) KMnO
4
21. In which of the following reactions H
2
O
2
acts as a reducing agent ?
(a) H
2
O
2
1 2H
1
12e
2
2H
2
O
(b) H
2
O
2
22e
2
O
2
1 2H
1
(c) H
2
O
2
12e
2
2OH
2
(d) H
2
O
2
1 2OH
2
22e
2
O
2
12H
2
O
(1) (c), (d)
(2) (a), (c)
(3) (b), (d)
(4) (a), (b)
22. The correct statement for the molecule,
CsI
3

, is :
(1) it contains Cs
1
and I
3
2
ions.
(2) it contains Cs
31
and I
2
ions.
(3) it contains Cs
1
, I
2
and lattice I
2
molecule.
(4) it is a covalent molecule.
23. The major organic compound formed by
the reaction of 1, 1, 12 trichloroethane
with silver powder is :
(1) Ethene
(2) 2 - Butyne
(3) 2 - Butene
(4) Acetylene
24. The equivalent conductance of NaCl at
concentration C and at infinite dilution are
l
C
and l
:
, respectively. The correct
relationship between l
C
and l
:
is given
as :
(where the constant B is positive)
(1) l
C
5l
:
2(B)C
(2) l
C
5l
:
2(B)
C
(3) l
C
5l
:
1(B)
C
(4) l
C
5l
:
1(B)C
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25. Resistance of 0.2 M solution of an
electrolyte is 50 V. The specific
conductance of the solution is 1.4 S m
21
.
The resistance of 0.5 M solution of the same
electrolyte is 280 V. The molar
conductivity of 0.5 M solution of the
electrolyte in S m
2
mol
21
is :
(1) 5310
23
(2) 5310
3
(3) 5310
2
(4) 5310
24
26. Sodium phenoxide when heated with CO
2
under pressure at 1258C yields a product
which on acetylation produces C.
The major product C would be :
(1)
(2)
(3)
(4)
27. The equation which is balanced and
represents the correct product(s) is :
(1) [ CoCl ( NH
3
)
5
]
1
15H
1
Co
21
15 NH
4
1
1Cl
2
(2) [ Mg ( H
2
O)
6
]
2 1
1( E DT A)
4 2
excess N
aOH
[ Mg ( EDTA) ]
2 1
1 6H
2
O
(3) CuSO
4
14KCNK
2
[ Cu( CN)
4
]
1K
2
SO
4
(4) Li
2
O12KCl 2LiCl1K
2
O
28. The correct set of four quantum numbers
for the valence electrons of rubidium atom
(Z537) is :
(1) 5, 1, 0,
1
2
1
(2) 5, 1, 1,
1
2
1
(3) 5, 0, 1,
1
2
1
(4) 5, 0, 0,
1
2
1
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29. For the non - stoichiometre reaction
2A1B C1D, the following kinetic data
were obtained in three separate
experiments, all at 298 K.

Initial
Concentration
(A)
Initial
Concentration
(B)
Initial rate of
formation of C
(mol L
2
S
2
)
0.1 M 0.1 M
1.2
3
10
2
3
0.1 M 0.2 M
1.2
3
10
2
3
0.2 M 0.1 M
2.4
3
10
2
3
The rate law for the formation of C is :
(1)
dc
dt
5k[A]
2
[B]
(2)
dc
dt
5k[A] [B]
2
(3)
dc
dt
5k[A]
(4)
dc
dt
5k[A] [B]
30. In S
N
2 reactions, the correct order of
reactivity for the following compounds :
CH
3
Cl, CH
3
CH
2
Cl, (CH
3
)
2
CHCl and
(CH
3
)
3
CCl is :
(1) CH
3
Cl > CH
3
CH
2
Cl

> (CH
3
)
2
CHCl
> (CH
3
)
3
CCl
(2) CH
3
CH
2
Cl > CH
3
Cl

> (CH
3
)
2
CHCl
> (CH
3
)
3
CCl
(3) (CH
3
)
2
CHCl > CH
3
CH
2
Cl

> CH
3
Cl
> (CH
3
)
3
CCl
(4) CH
3
Cl > (CH
3
)
2
CHCl

> CH
3
CH
2
Cl
> (CH
3
)
3
CCl
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Chemistry-IIT JEE Mains 2014, 6 April: Topper's Choice Prof. Pawan Babel (PKB)

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