Name ................................................

VE RSI ON

Batch.................... Roll No. ...............

02-03-2020
OBJECTIVE EXAM - CHEMISTRY
C1
LT20R/TP/C/[C1] Chemical and Ionic Equlibrium BATCH : TVM, SAPS

1. Of the given anions, the strongest Bronsted base is

1) ClO– 2) ClO 2 3) ClO3 4) ClO 4
2. With increase in temperature, ionic product of water
1) decreases 2) increases 3) remain same 4) may increase or decrease
3. The pH value of 0.001M aqueous solution of NaCl is
1) 7 2) 4 3) 11 4) un predictable
4. For a hypothetical reaction, A g   B g   X g   Y g  . Occuring in a single step, the specific rate constants
are 2.0  10 2 and 5.0  103 respectively for the forward and the backward reactions. The equilibrium
constant is
1) 4.0  10 4 2) 2.5 106 3) 2.5  105 4) 4.0  10 6

5. If Kp for a reaction, A g   2B g   3C g   D g  is 0.05 atm at 1000K. Its Kc in terms of R will be

5 105
1) 20000 R 2) 0.02 R 3) 5  105 R 4)
R
6. In the system CaF2bsg   2+
Ca b2aq g  2 Fbaq g , increasing the concentration of Ca ions four times will cause the
eq. concentration of F- ions to change to............ times the initial value:
1) 4 2) 1/2 3) 2 4) 1/4
7. -1
If the solubility of Ca3(PO4)2 is ‘s’ mol L , then the solubility product in terms of ‘s’ is:
1) 27 s4 2) 3 s2 3) s5 4) 108 s5
8. When HCl gas is passed through a saturated aq. solution of NaCl
1) there is no change 2) the Ksp of NaCl increases
3) the Ksp of NaCl decreases 4) some NaCl precipitates out
9. A buffer solution has equal volumes of 0.2M NH 4OH and 0.02M NH 4Cl . The pKb of the base is 5. The
pH is
1) 9 2) 10 3) 7 4) 4
10. Precipitation of salts from their solutions takesplace when the ionic product
1) equals their solubility product 2) exceeds their solubility product
3) is less than their solubility product 4) is almost zero
11. Equilibrium constant for the thermal decomposition of HI
2HI g   H 2 g   I 2 g  at T K is 2.25. The percentage dissociation of HI at this temperature is:
1) 95 2) 50 3) 25 4) 75
12. A) 2NH 3 g   3I2 g   N 2 g   6HI g  ; K1 B) H 2 g   I2 g   2HI g  ; K 2

C) N 2 g   3H 2 g   2NH3 g  ; K 3
How is K3 related to K1 and K2?

1 K 32 K1 K13
1) K 3  K K 3 2) K 3  3) K 3  K 3 4) K 3 
1 2 K1 2 K2
LT20R/TP/C/[C1] 2 N- CHEMISTRY

13. What would be the vapour density of the system at equilibrium 2NH 3g  N 2g  3H 2g at 600K when it is
only 25% dissociated?
1) 5.1 2) 6.8 3) 3.4 4) 2.55
14. According to Lowary Bronsted concept, which one of the following is considered as an acid?
1) H3O+ 2) BF3 3) OH 4) Cl
15. The pH of a 0.1 M aqueous solution of a weak acid (HA) is 3. What is its degree of dissociation?
1) 1% 2) 10% 3) 50% 4) 25%
16. The p of 0.1 M solution of the following salts increases in the order :
H

1) NaCl < NH4Cl < NaCN < HCl 2) HCl < NH4Cl < NaCl < NaCN
3) NaCN < NH4Cl < NaCl < HCl 4) HCl < NaCl < NaCN < NH4Cl
17. The buffer system in our blood is
1) NH4OH + NH4Cl 2) NH4OH + (NH4)2 SO4
3) H2CO3 + NaHCO3 4) citric acid + sodium citrate
18. At infinite dilution, the percentage ionisation for both strong and weak electrolytes is
1) 1% 2) 20% 3) 50% 4) 100%
19. The value of ionic product of water at 393K is
1) Less than 1 1014 2) Greater than 1 1014
3) Equal to 1 1014 4) Equal to 1 10 7
20. The rate constants of forward and backward reactions are 8.5x10-5 & 2.125 x 10-4 units respectively. The
equilibrium constant is (unit excluded):
1) 0.35 2) 0.48 3) 2.5 4) 0.4
21. Consider the reaction: SO2 Cl 2  Heat  SO2  Cl2 when Cl2 is added to the equilibrium mixture at constant
volume
1) The temperature of the system increases 2) The temperature of the system decreases
3) More SO2 is formed 4) The temperature remains unchanged
1
22. For the reaction SO 2  O 2  SO3 , if we write Kp  K c  RT  , then x becomes
x

1) -1 2) 1 2 3) 1 2 4) 1
23. When pressure is applied to the equilibrium system ice water. Which one of the following phenomena
will happen:
1) more ice will be formed 2) water will evaporate
3) more water will be formed 4) equilibrium is not disturbed
24. Which will not affect the degree of ionization
1) Temperature 2) concentration 3) type of solvent 4) current
25. In a vessel containing SO3(g), SO2(g) and O2(g) at equilibrium, some helium gas is introduced so that the total
pressure increases while temperature and volume remain constant. According to Le-Chatelier principle, the
dissociation of SO3
1) Increases 2) Decreases
3) Remains unaltered 4) Leads to completion
26. For the reaction 2NH 3 g   N 2 g   3H 2 g  , the units of Kp will be

2)  atm  3)  atm  4)  atm 

3 2 2
1) atm
LT20R/TP/C/[C1] 3 N- CHEMISTRY

27. Which diagram is correct w.r.t chemical equilibrium?

1) only I is correct 2) only II is correct

3) only III is correct 4) all are correct
28. Write the equilibrium constant K for CH 3COOH  H 2 O H 3O   CH 3COO

H 3O  H 2 O H 3O  CH 3COO
1) K  2) K 
CH 3COO CH 3COOH CH 3COOH

H 3O   H 2 O H 2 O  CH 3COO
3) K  4) K 
CH 3COOH CH 3COO H 2 O CH 3COOH

29. In which of the following KP = KC:

1) PCl5 PCl3 + Cl2 2) N2 + 3H2 2NH3

3) 2CO + O2 2CO2 4) N2 + O2 2NO
30. The conjugate base of H2PO4– is
1) P2O5 2) H3PO4 3) HPO42– 4) PO43–
31. The conjugate base of NH 2 is
1) NH3 2) NH2- 3) NH 4 4) N13
32. Of the given anions, the strongest bronsted base is
1) CIO– 2) ClO3– 3) ClO2– 4) ClO4–
33. What would happen to a reversible dissociation reaction at equilibrium when an inert gas is added while the
pressure remains unchanged?
1) Less of the products will be formed 2) More of the products will be formed
3) More of the reactants will be formed 4) It remains unaffected
34. A base, as defined by Bronsted theory, is a substance which can
1) lose a pair of electrons 2) donate protons
3) gain a pair of electrons 4) accept protons
35. CH 3COO  ion is a
1) Weak conjugate base 2) Strong conjugate base
3) Weak conjugate acid 4) Strong conjugate acid
36. For the reaction , the equilibrium constant Kp changes with
1) Total pressure 2) Catalyst
3) Amount of H 2 & I 2 present 4) Temperature
37 . For which of the following gaseous equilibria is Kp < Kc?
 2NO
1) N2 + O2   2 NO + Cl
2) 2NOCl  2

 2HI
3) H2 + I2   2SO
4) 2 SO2 + O2  3
LT20R/TP/C/[C1] 4 N- CHEMISTRY

38. In a reversible reaction, two substances are in equilibrium. If the concentration of product is reduced to half,
the equilibrium constant will be
1) Reduced to half of its original value 2) Doubled
3) Same 4) Reduced to one fourth of its original value
39. The solubility product of AgCl is 4.0  1010 at 298 K. The solubility of AgCl in 0.04 m CaCl2 will be
1) 2.0  105 m 2) 1.0  104 m 3) 5.0  109 m 4) 2.2  104 m
40. The equilibrium constant (KC) for the reaction N 2 g   O 2 g   2NO g  at temperature T is 4  104 . The
1 1
value of KC for the reaction NO g   N 2 g   O2 g  at the same temperature is
2 2
1) 50.0 2) 0.02 3) 2.5  102 4) 4  104
41. Le Chatelier’s principle is not applicable to
 FeS S
1) Fe S  SS   2HI g 
2) H 2 g   I2 g  

 2NH 3 g 
3) N 2 g   3H 2 g    2NO g 
4) N 2 g   O 2 g  
 C + D starting with 1 mol each of A and B in a one litre containes, 0.8
42. In the reversible reaction A + B 
mol of C was found to be formed when eqm was attained at a given temp. The KC of the reaction at this
temp is
1) 0.64 2) 4 3) 8 4) 16
43. Which of the following is not a conjugate acid - base pair?
1) NH4+ & NH3 2) HCO3– & CO32–
3) C6H5NH3+ & C6H5NH2 4) H3O+ & OH–
44. The pH of an aq. solution of the salt of a weak acid and a strong base is given by the formula
1 1
1) pH   pK w  pK a  log C  2) pH   pK w  pK b  log C 
2 2

1 1
3) pH   pK w  pK a  pK b  4) pH   pK a  pK b  pK w 
2 2
45. For the equilibrium 2NOClbgg b g , Kc  3.75  10 at 1069 K. Kp =
2NObgg  Cl2 g 6

.  105
1) 33 2) 3.6  108 3) 3.33  102 4) 4.0  1010
Name ................................................
VE RSI ON

Batch.................... Roll No. ...............

02-03-2020
OBJECTIVE EXAM - CHEMISTRY
C1
LT20R/TP/C/[C1] Chemical and Ionic Equlibrium BATCH : TVM, SAPS

1. 1
2. 2
3. 1
K f 2  102
4. 4 K   4  106
K b 5  10 3

5. 4 ng  4  3  1
5  105
K p  K c  RT  or 0.05  K c 1000R  or K c 
n

R
6. 2
7. 4
8. 4

pOH  pKb  log

Salt 
9. 2
 Base
0.02
pOH  5  log  5  log 10 1   5  1  4
0.2
Now, pH  pOH  14 ; pH  14  pOH  14  4  10
10. 2
11. 4
12. 2
13. 2
14. 1
15. 1 HA  H   A  ;
 H    c  103  pH  3 ; ie, 0.1    10 3 or   102  1%

16. 2 NaCl = neutral (pH = 7); NH4Cl = slightly acidic (pH < 7), NaCN = basic (pH > 7); HCl =
strongly acidic (pH <<7)
 Order will be : HCl < NH4Cl < NaCl < NaCN
17. 3
18. 4 Ionisation is 100% at infinite dilution
19. 2 Ionic product of water increases with increase of temperature.

Kf 8.5x10 5
20. 4 K   0.4
K b 2,125x10 4
21. 1
 1
Kp  K C  RT  ; n  1   1    1 2
n
22. 2
 2
LT20R/TP/C/[C1] 2 N- CHEMISTRY

23. 3 The density of ice is less than that of water hence application of pressure favours the formation of
water
24. 4 Current does not effect the degree of ionisation
25. 3
26. 3
27. 4
28. 2
29. 4

30. 3 Acid 

 H
 conjugate base
31. 2 Conjugate acid  conjugate base + H+ . Hence , conjugate base of NH 2  NH 2 
32. 1 HClO is the weakest acid. Its conjugate base, ClO– is the strongest base
33. 2 In these of inert gas added the volume increases. To maintain constant value of Kc degree of
dissociation increases
34. 4 Base accepts proton and acid donates electrons
35. 2
36. 4 Kp varies only with temp
37. 4
38. 3
39. 3
40. 1
41. 1
42. 4
43. 4
44. 1
45. 3