Plasticity

Plasticity
Introduction
Rapid plasticity is one of the basic tests used in the natural rubber industry and is the measurement of compression of a specimen of known thickness at a known temperature under a predetermined load for a known time. The Wallace Rapid Plastimeter, designed to conform to international standards, measures the thickness of a rubber sample to a very high degree of accuracy (0.001mm). One Wallace Rapid Plasticity unit represents a change in thickness of 0.01mm. Factors Affecting Results There are a number of test parameters which can affect the result such as platen temperature, platen parallelism, carrier paper, platen load, test duration, sample positioning and sample preparation. However, results are repeatable, provided all these parameters are controlled. During development of the P14 Rapid Plastimeter, Wallace engineers carried out detailed investigations on how these factors influenced the test results. Platen P arallelism Parallelism Lack of platen parallelism also affects the result (see table 2). This is particularly so when the alternative platen sizes allowed in the standard are used so the parallelism must be reset every time the platen is changed.
PLASTICITY
Angle of tilt ()
0.00 33.0 32.0 31.0
Plasticity number
32.5 32.0 31.0 33.0 32.0 31.5 32.5 31.5 31.0
Test P rocedure Procedure The size of the test sample (0.4cm3) is defined by the standard. Before being positioned between the platens, the specimen is placed between 2 pieces of carrier paper to protect the platens from contamination. The test pre-compresses the sample for 15 seconds to 1mm (at a temperature of 100C for natural rubber) and then further compresses the sample for 15 seconds under a load of 100N. The plasticity number is a measure of the final sample thickness, reflecting the degree of flow within the sample.
0.65
Temperature Tight temperature control is important (see table 1). The platens of the obsolete Wallace P1 and P12 instruments were steam heated leading to large temperature variations in many cases. With the current P14 Plastimeter the platens are electrically heated, and can be checked and adjusted accordingly.
Temperature (C)
102 101 100 99 98
1.30
Table 2. Effect of platen parallelism
Sample Carrier P Paper aper The dependence of the result on the sample paper used is important (see table 3 - see page 12). Use of the paper recommended by the standard will ensure that results are consistent. Other sample carriers may be used (after validation) and will produce different, but consistent results. The paper size is also important and if larger sample papers are used, the effect of the heat-shield around the platen can lead to significantly low readings.
Plasticity number
31.0 30.5 31.0 31.5 32.0 32.0 30.5 31.5 31.0 31.0 32.0 32.5 31.0 31.5 32.0 31.5 32.0 33.0
10
95
Table 1. Effect of platen temperature
Continued on page 12
P14 Rapid Plastimeter Mk V

Accurate control of temperature time & load Semi-automatic setting of 1mm gap Choice of 3 different upper platens Choice of 4 models
When the instruments operating handle is rotated, the test sequence starts automatically. The final thickness of the test piece, expressed in units of 0.01mm, is the plasticity number, which is displayed digitally on the front panel. Tight control of the sample temperature is fundamental to the validity of the test, so two LEDs on the front panel are illuminated in green, indicating that the upper & lower platen temperatures are within acceptable limits throughout the test. A 10mm diameter upper platen is fitted as standard with 7.3 & 14mm alternatives supplied loose. Each model is supplied with a hand operated constant volume specimen cutter.( Ref. P1/4) Four instrument models are offered: P14/1 Basic, stand alone P14/2 With printer P14/3 With printer & data terminal P14/VT Variable platen temperature with printer & data terminal The data input terminal contains a16 character, two line LCD display and QWERTY keypad. It supplies additional information on the P14s operation and offers the user several new options. Test parameters are more easily set. Data for operator & sample identification can be entered. The duration of the conditioning and test load can also be adjusted and pre-set.
PLASTICITY
The Rapid Plastimeter measures the plasticity of natural or unvulcanised rubber to international testing standards. The instrument may be used in conjunction with the Wallace Ageing Chamber (see page 13) to determine the Plasticity Retention Index (PRI) of raw natural rubbers. The variable temperature model (P14/ VT) characterises the flow behaviour of synthetic rubber compounds as, unlike the other models, its platen temperatures can be varied between 60C & 180C. For some applications the P14/VT offers a quick, low cost alternative to a Mooney Viscosity test. The P14 features an attractive C frame design, providing easy access for the operator when loading and removing samples from between the heated platens. Clear instructions are displayed on the front LCD panel so that the user can have the instrument calibrated and ready for sample testing in seconds.
SPECIFICATION
PLASTIMETER Dimensions, w x d x h , mm 300 x 360 x 420 Weight, kg 20 Platen temp. P14/1,2,3 1000C P14/ VT 600C - 1800C Upper platen dia., mm 10 (fitted) 7.3, 14 Lower platen dia., mm 16 Test duration, secs. 15 conditioning 15 load Compressive load, N 100 PRINTER Characters, per line Paper width, mm Dimensions, w x d x h , mm Weight, kg DATA TERMINAL QWERTY keypad 16 characters, 2 line LCD display Dimensions, w x d x h , mm 290 x 150 x 140 Weight, kg 0.495
SPECIMEN CUTTER Sample thickness, mm 3 Sample volume, cm3 0.4 Dimensions, w x d x h, mm 80 x 335 x 260 4.0 Weight, kg
24 58 105 x 195 x 90 0.63
STANDARDS BS 903: Pt. A59 ASTM D3194 ISO 2007
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Platen L oad Load The load specified in the standard is 100 1N. If the load is decreased to 97N the plasticity result will increase by approximately 1.5 units compared to the standard load. Alternatively, if the load is increased to 103N, the result will decrease by a similar amount. The platen load is accurately applied in the P14 with a calibrated weight arm applying the load. Load Duration Use of the obsolete P1 Plastimeter which is timed manually, can lead to significant errors in the final result - a variation of 1 second in the time of application of the test force can make a difference to the final result of as much as one plasticity unit. With the P14 the application of the load is timed very accurately by a quartz crystal controlled timer. Sample P ositioning Positioning The operator should take care to place the sample exactly at the centre of the lower platen. A few millimetres deviation from this point does not measurably influence the results. However, once the top platen compresses the edge of the sample (corresponding to about 5mm offcentre) the plasticity number drops by about 1 unit. The results will continue to drop as less of the sample is compressed. Sample P reparation Preparation Because the plastimeter is measuring to an accuracy of 0.001mm, it is essential that the rubber test sample conforms to the dimensions defined by the standard. All samples should be prepared from a 3mm thick sheet and be cut to a volume of 0.4 0.04 cm. The Wallace constant volume specimen cutter (ref. P1/4), which is supplied with each Plastimeter, conforms to this requirement. But it is very important that this cutter is kept in good condition. Adjusting screws on the cutter allow the cutting faces to be set parallel and the cutting depth maintained at 3mm. Plasticity Retention Index The Wallace Rapid Plastimeter was adopted by the Rubber Research Institute of Malaysia for determining the Plasticity Retention Index of Natural Rubber in the Standard Malaysian Rubber (SMR) scheme. It has since been adopted by all other countries producing Technically Specified Rubbers. The Plasticity Retention Index, PRI is a measure of the resistance of natural rubber to thermal oxidation. The procedure consists of a plasticity test (P0) on a non-aged specimen, followed by a test (P30) of a specimen that has been aged for 30 minutes at a temperature of 140C 0.2C. Median Value of P30 results x 100 Median Value of P0 results So in addition to a Plastimeter, the PRI test requires an ageing oven, which must control temperature very accurately as research indicates that a temperature variation of 1C from the standard 140C can produce a difference of 3 PRI units at 50 PRI. PRI = Also a variation in the ageing time of a few minutes will affect the result by a few units, the exact deviation being dependent on the type of rubber. For this reason the test standard specifies an ageing time within close limits ( 0.25 mins) to ensure reliability and repeatability. It is important in PRI testing to watch out for significant changes in the pattern of results. While they may meet the grade requirement, a move away from the norm is a pointer to other differences in the material.
PLASTICITY
Paper Type
Cigarette paper Hand towel paper Hard toilet paper Wrapper fill Toilet tissue Photocopy paper Tissue paper Tracing paper Brown paper Mylar paper Cling film
Plasticity number
36.5 37.0 33.0 35.0 35.0 37.0 38.0 38.0 46.5 44.0 53.0 43.0 52.0 53.0 49.0 57.0 59.5 58.0 32.5 33.0 23.0 22.0 36.0 34.0 36.5 36.0 45.0 49.0 51.5 52.0 57.0 34.0 23.0
Table 3. Effect of carrier paper
12

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Table 2. Effect of platen parallelism

Table 1. Effect of platen temperature

P14 Rapid Plastimeter Mk V

24 58 105 x 195 x 90 0.63

STANDARDS BS 903: Pt. A59 ASTM D3194 ISO 2007

Continued from page 10

Table 3. Effect of carrier paper

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