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    Concept Map Iuk107

    Uploaded by

    Anis Keww
    The document discusses analytical techniques for analyzing organic and inorganic samples. It focuses on biomass samples and describes several techniques for characterization including UV-vis spectroscopy, atomic absorption spectroscopy, inductively coupled plasma, infrared spectroscopy, nuclear magnetic resonance spectroscopy, gas chromatography-mass spectrometry, scanning electron microscopy with energy dispersive X-ray analysis. It provides an overview of each technique and guidance on selecting the appropriate technique depending on whether the sample contains organic or inorganic components and whether it is a solid, liquid or gas.

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    Download as PDF, TXT or read online from Scribd

    Concept Map Iuk107

    Uploaded by

    Anis Keww
    341 views18 pages
    The document discusses analytical techniques for analyzing organic and inorganic samples. It focuses on biomass samples and describes several techniques for characterization including UV-vis spectroscopy, atomic absorption spectroscopy, inductively coupled plasma, infrared spectroscopy, nuclear magnetic resonance spectroscopy, gas chromatography-mass spectrometry, scanning electron microscopy with energy dispersive X-ray analysis. It provides an overview of each technique and guidance on selecting the appropriate technique depending on whether the sample contains organic or inorganic components and whether it is a solid, liquid or gas.

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    the machine use by technologist. aas ftir and ect

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    The document discusses analytical techniques for analyzing organic and inorganic samples. It focuses on biomass samples and describes several techniques for characterization including UV-vis spectroscopy, atomic absorption spectroscopy, inductively coupled plasma, infrared spectroscopy, nuclear magnetic resonance spectroscopy, gas chromatography-mass spectrometry, scanning electron microscopy with energy dispersive X-ray analysis. It provides an overview of each technique and guidance on selecting the appropriate technique depending on whether the sample contains organic or inorganic components and whether it is a solid, liquid or gas.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    341 views18 pages

    Concept Map Iuk107

    Uploaded by

    Anis Keww
    The document discusses analytical techniques for analyzing organic and inorganic samples. It focuses on biomass samples and describes several techniques for characterization including UV-vis spectroscopy, atomic absorption spectroscopy, inductively coupled plasma, infrared spectroscopy, nuclear magnetic resonance spectroscopy, gas chromatography-mass spectrometry, scanning electron microscopy with energy dispersive X-ray analysis. It provides an overview of each technique and guidance on selecting the appropriate technique depending on whether the sample contains organic or inorganic components and whether it is a solid, liquid or gas.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 18

    Other Chem Window

    IUK107 Part 2 Other Window of Chemistry for Technologists

    1. Materials: synthetic (IUK 107 Part 1) & natural (IUK 107 Part 2) 2. Trendy natural: Biomass 3. Inorganic component is naturally contained in biomass 4. Analysis should include inorganics: Uv-vis, AAS, ICP, EDAX. 5. Previous organic analysis included: IR, NMR, (+GC-MS)
    02/12/2013 Concept Map - Part 2 IUK107 - Other Chem Window for Technologists 1

    Concept Map
    IUK107 Part 2 Other Window of Chemistry for Technologists

    5 December 2013

    1.Organic & Inorganic Samples: Preparation Concept & Analyses 2Touch up on MS of Halogenated Compounds

    02/12/2013

    Concept Map - Part 2 IUK107 - Other Chem Window for Technologists

    Summary - Inorganics
    IUK107 Part 2 Other Window of Chemistry for Technologists

    INORGANICS:
    Biomass & Materials

    New: fungus on keratinised tissue: Touch on sample preparation: matrix + filler Scanning Electron Microscopy with Energy Dispersive Analysis of X-ray Light & Absorption as Materials Response to Radiation
    02/12/2013 Concept Map - Part 2 IUK107 - Other Chem Window for Technologists 3

    IUK107 Part 2 Other Window of Chemistry for Technologists

    Summary
    AAS

    Towards relevance in intellectual capacity:


    Uv-visible Spectroscopy Atomic Absorption Spectroscopy Inductively Coupled Plasma Quiz 1
    UV-VIS ICP

    Source
    Sample Response

    Uv-vis light (many effects)


    Low E radiation

    HCL Atomise

    Plasma Ionise

    Power

    Furnace: <2000oC Furnace: >2000oC

    Group Presentation - excellent collaborative work although too detail. <End of Inorganic >
    02/12/2013 Concept Map - Part 2 IUK107 - Other Chem Window for Technologists 4

    Sample preparation
    IUK107 Part 2 Other Window of Chemistry for Technologists

    INORGANIC
    Supposedly

    Sample can contain mixture of elements Name 1 that experience inteference if in mixture
    Normally Quantitative -calibration curve

    02/12/2013

    Concept Map - Part 2 IUK107 - Other Chem Window for Technologists

    IUK107 Part 2 Other Window of Chemistry for Technologists

    Summary

    ORGANICS:
    Infra-red Spectroscopy functional groups only Nuclear Magnetic Resonance Structure proposal Mass spectroscopy structure verification Gas Chromatography-Mass Spectrometry -separation technique interfaced with speciation of fragmented molecule.
    02/12/2013 Concept Map - Part 2 IUK107 - Other Chem Window for Technologists 6

    Sample preparation
    IUK107 Part 2 Other Window of Chemistry for Technologists

    ORGANIC
    Borrowed pic dont confuse Required due to instrument limitation at handling mixture Name one technique thats capable

    Consequence

    02/12/2013

    Concept Map - Part 2 IUK107 - Other Chem Window for Technologists

    Spectral Responses
    IUK107 Part 2 Other Window of Chemistry for Technologists

    SEM/EDAX: Electron image | EDX: Intensity vs energy (keV) UV-VIS: 200-800 nm; analyte responses: A vs l (nm) AAS: HCL source; atomisation; atoms A; A vs l (nm) ICP: Plasma source and ioniser; ions A; A vs l (nm)
    IR: wavelength =0.78-1000 mm: % transmittance vs 1/l (cm-1 : 400-4000) NMR: nucleus resonance; probe dependent; Intensity vs chemical shift (ppm) GC-MS: GC Separation:intensity vs tR | MS Fragment: Abundance vs m/z (speciation)
    02/12/2013 Concept Map - Part 2 IUK107 - Other Chem Window for Technologists 8

    IUK107 Part 2 Other Window of Chemistry for Technologists

    Sample Form

    Uv-visible Spectroscopy All - colour Atomic Absorption Spectroscopy Inductively Coupled Plasma SEM/EDX S, organic, inorganic-EDX Infra-red Spectroscopy:L/S/G Nuclear Magnetic Resonance: PROBE - L/S Gas Chromatography-Mass Spectrometry L/G volatile, stable <400oC.
    Inorganic

    organic

    liquid quantitative
    9

    02/12/2013

    Concept Map - Part 2 IUK107 - Other Chem Window for Technologists

    Stepwise Analysis - organics


    IUK107 Part 2 Other Window of Chemistry for Technologists

    Uv-vis where colour is present

    IR
    Scan the functional group of a molecule Pure or reference/standard/expertise /familliarity required

    Functional region: 15004000 cm-1

    NMR
    structural elucidation Pure or simple mixture

    Fingerprint:
    500-1500 cm-1
    Atlas/Database match

    MS
    verify/confirm elucidated structure Must pure or need standards
    Concept Map - Part 2 IUK107 - Other Chem Window for Technologists 10

    Mixture is ridiculous
    02/12/2013

    Stepwise Analysis Inorganics


    IUK107 Part 2 Other Window of Chemistry for Technologists

    Uv-vis where colour is present

    SEM/EDX
    Check types of elements Proceed with quantitative techniques

    AAS
    Decide on hollow cathode lamp Prepare standards Find sample digestion procedure

    ICP
    Allows us to skip SEM/EDX and AAS To some extent, ICPMS rules out the need for XRD, XRF, XPS

    02/12/2013

    Concept Map - Part 2 IUK107 - Other Chem Window for Technologists

    11

    Stepwise Analysis Totally unknown (s & l)


    IUK107 Part 2 Other Window of Chemistry for Technologists

    Start off: SEM/EDX

    If (l): Start off: IR for Image identify variation (# of forms) functional Semiquantitative via EDX group.
    Check the types of elements present Check presence of C
    If none check ash % If C present, analysis of inorganics requires ashing procedure Next proceed woth analysis.

    02/12/2013

    Concept Map - Part 2 IUK107 - Other Chem Window for Technologists

    12

    Important Examples
    CH2Cl2
    Calculate MW. This is for M+ Check radioisotopic probability:
    M+ and all M+ +2 Abundance: 50:50% (note complexity)

    Draw: Indication:
    IUK107 - Part 2. Separation and Speciation: GC-MS

    13

    Mass Spectroscopy
    IUK107 Part 2 Other Window of Chemistry for Technologists

    1. CH2CCl2

    02/12/2013

    Concept Map - Part 2 IUK107 - Other Chem Window for Technologists

    14

    Important Examples
    CH2Br2
    Calculate MW. This is for M+ Check radioisotopic probability:
    M+ and all M+ +2 Abundance: 50:50% (note complexity)

    Draw: Indication:
    IUK107 - Part 2. Separation and Speciation: GC-MS

    15

    Mass Spectroscopy
    IUK107 Part 2 Other Window of Chemistry for Technologists

    1. CH2Br2

    02/12/2013

    Concept Map - Part 2 IUK107 - Other Chem Window for Technologists

    16

    Questions
    IUK107 Part 2 Other Window of Chemistry for Technologists

    1. Quiz 1 2. Quiz 2

    02/12/2013

    Concept Map - Part 2 IUK107 - Other Chem Window for Technologists

    17

    Concept Map - together


    IUK107 Part 2 Other Window of Chemistry for Technologists

    02/12/2013

    Concept Map - Part 2 IUK107 - Other Chem Window for Technologists

    18

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