Hydrogen Production
Hydrogen Production
Hydrogen Production
Hydrogen offers sustainable solutions to our nations energy and climate challenges.
Table of Contents
Producing Hydrogen................1 Hydrogen Production Technologies ..........................3 Challenges and Research Needs......................4 Technology Summaries ...........6 Distributed Natural Gas Reforming ....................8 Bio-Derived Liquids Reforming ...........................9 Coal and Biomass Gasification .......................10 Thermochemical Production ........................11 Water Electrolysis ..............12 Photoelectrochemical Hydrogen Production .........13 Biological Hydrogen Production ........................14 Next Steps............................16 Hydrogen provides a pathway for energy diversity. It can store the energy from diverse domestic resources (including clean coal, nuclear, and intermittently available renewables) for use in mobile applications and more.
Energy Security
Hydrogen-powered vehicles could significantly reduce imports of foreign oil.
Sustainability
Hydrogen production technologies can potentially take advantage of abundant renewable energy resources (e.g., solar, wind, geothermal, hydroelectric).
Climate Change
Vehicles produce near-zero carbon emissions when operating on hydrogen produced from renewable resources, nuclear energy, or fossil energy with carbon capture and storage.
Economic Vitality
The United States can secure a share of future global energy markets by leading the development and commercialization of hydrogen and fuel cell technology.
Producing Hydrogen
Hydrogen can increase Americas energy security.
Delivering the potential for clean, safe, affordable, and secure energy from abundant domestic resources*
Vehicles operating on hydrogen can dramatically reduce our nations dependence on oil and significantly reduce tailpipe emissions. Hydrogen offers a potential means to store and deliver energy from abundant, domestically available resourceswhile reducing our nations carbon footprint.
Researchers are working to produce hydrogen economically from diverse sources. Sustainable
production technologies offer exciting possibilities for the future. Meanwhile, hydrogen produced from fossil fuels (like natural gas) can help to build early markets and infrastructure. The ability to generate hydrogen from a variety of feedstocks using diverse energy sources makes hydrogen a particularly promising energy carrier.
Distributed Production
Technologies deigned to produce hydrogen on-site at refueling stations will have an economic edge in early markets. Such technologies will use locally available feedstocks and power in compact systems. In the near-term, they may use existing utilities and infrastructure. In remote locations, they may be useful on an ongoing basis.
Central Production
Ultimately, large-scale production at centralized sites will produce the economies of scale needed to achieve low-cost hydrogen. Centralized production, of course, requires an efficient, low-cost delivery infrastructure, which is still in development.
Thermal Processes
One type of thermal process uses the energy stored in such resources as coal or biomass to simply release the hydrogen contained within their molecular structures. Another type uses heat in combination with closed chemical cycles to produce hydrogen from feedstocks, such as water; these are known as thermochemical processes.
Distributed Natural Gas Reforming Bio-Derived Liquids Reforming Coal and Biomass Gasification Thermochemical Production
Electrolytic Processes
Water electrolysis uses electricity to split water into hydrogen and oxygen. Hydrogen produced via electrolysis can result in zero greenhouse gas emissions, depending on the source of the electricity used.
Water Electrolysis
Photolytic Processes
Photolytic processes use light energy to split water into hydrogen and oxygen. Currently in the very early stages of research, these processes offer long-term potential for sustainable hydrogen production with low environmental impact.
Technology
Summaries
Only by developing and deploying a range of technologies as they move from research into commercial readiness will we ultimately arrive at the sustainable energy solution we seek. This chart provides a broad overview of the challenges and research needed for each of seven hydrogen production technologies. A far more detailed treatment of these topics is available in the Hydrogen Production Roadmap produced by the Hydrogen Production Technical Team. The following pages summarize some of the key challenges common to these technologies and provide a snapshot of each technology today. Further research will help to identify the most sustainable technologies for Americas energy future.
Key Benefits
Most viable approach to begin building hydrogen market in near term Lowest current cost Existing feedstock infrastructure
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Key Benefits
Most viable renewable hydrogen pathway in the near term Existing infrastructure for some feedstocks
Key Benefits
Provides low-cost synthetic fuel in addition to hydrogen Uses abundant and affordable coal feedstock
Thermochemical
Critical Challenges
Cost-effective reactor Effective and durable materials of construction Longer-term technology
Water Electrolysis
Critical Challenges
Low system efficiency and high capital costs Integration with renewable energy sources Design for manufacturing
Photoelectrochemical
Critical Challenges
Effective photocatalyst material Low system efficiency Cost-effective reactor Longer-term technology
Biological
Critical Challenges
Efficient microorganisms for sustainable production Optimal microorganism functionality in a single organism Reactor materials Longer-term technology
Key Benefits
Produces hydrogen using only water, energy from the sun or nuclear reactors, and chemicals that are recycled. Clean and sustainable
Key Benefits
Produces virtually no pollution with renewable energy sources Uses existing infrastructure Uses fuel cell advances
Key Benefits
Operates at low temperatures Clean and sustainable using only water and solar energy
Key Benefits
Clean and sustainable Tolerant of diverse water conditions Self-sustaining
Hydrogen Quality:
Purity is a major issue for any hydrogen intended for use in fuel cells aboard vehicles. The problem arises because the platinum catalysts used in most vehicle fuel cells can be easily poisoned by impurities in the hydrogen, ultimately reducing catalyst effectiveness. Hydrogen production technologies must therefore either produce high-purity hydrogen outright or incorporate additional purification processes.
All hydrogen production technologies will be required to meet the strictest safety requirements. The permitting process demands proven reliability and safeguards. Production units for placement at fueling stations, in particular, must be designed to operate without manual assistance. This capability will require use of back-up and fail-safe modes, remote monitoring capability, exception-based reporting, and infrequent maintenance.
Timeframes To Market
Some technology options necessarily appear at more than one location along this timeline as market readiness is affected by the specific feedstock, energy source, and production scale.
technology uses high-temperature steam to reform the methane in natural gas into hydrogen and carbon dioxide. Steam reforming of natural gas has been used commercially for many years in large, centralized industrial facilities. The challenge of this option is to scale down the equipment so that it operates cost-effectively in a distributed mode at fueling stations.
An interim solution: The Hydrogen Production Technical Team and DOE consider this production technology as an interim option only because it will raise U.S. demand for natural gas and still release some carbon dioxide. DOEs near-term, technical and projected cost targets for this technology have been met; market success will require the private sector to conduct additional work on system integration, optimization, and technology validation.
Most hydrogen today is produced through natural gas reforming at large refineries.
Near Term
Mid Term
Long Term
Improving hydrogen yield: All of these technologies may potentially use a variety of bio-liquid feedstocks, such as sugars, sugar alcohols (like ethanol), bio-oils, and less-refined sugar streams (such as cellulose from non-edible plants). Researchers are trying to find better catalysts to improve the hydrogen yield of these technologies.
Aqueous-phase reforming may offer an efficient way to produce hydrogen from sugar alcohols derived from a broad variety of potential biomass feedstocks.
Near Term
Mid Term
Long Term
Coal gasifiers are now in commercial use to produce power, chemicals, and synthetic fuels, but they generate substantial amounts of carbon dioxide (CO2). The challenges are to optimize the system for hydrogen production, develop downstream processes, and develop better, lower-cost methods to capture and store the carbon. Gasification of biomass instead of coal would minimize carbon impacts, but biomass cost and supply issues would present other challenges.
Feedstock:
Near Term
Gasification technologies can use coal or biomass as feedstock, or a combination of the two simultaneously. Co-gasification of coal and biomass helps to address both the carbon issues related to coal and the cost and supply issues related to biomass.
Mid Term
Long Term
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Thermochemical Production
(Using a Heat-Driven Chemical Reaction To Split Water)
Sustainable, closed-loop process: Solar energy can be concentrated with mirrors focusing on a special lens to generate temperatures close to 2,000C. These temperatures can be used to trigger a series of chemical reactions that split water molecules to produce hydrogen without generating any harmful emissions. Since the chemicals used are recycled, this proposed process consumes only water and produces only hydrogen and oxygen. The high temperatures enable extremely fast reaction rates that significantly accelerate production. Multiple pathways to study: Researchers have
identified more than 300 possible chemical reaction cycles for analysis and are in the process of selecting the most promising for further development and demonstration. This technology is relatively immature and requires extensive research in basic chemistry and materials. DOE is also developing similar thermochemical processes designed to use the waste heat from nuclear plants.
One closed chemical cycle uses zinc oxide and solar energy to make hydrogen.
Near Term
Mid Term
Long Term
cycles under study involve corrosive chemicals at high temperatures. The economic feasibility of this production pathway relies on the identification of materials with sufficient corrosion resistance under these process conditions. Potential candidate classes of materials include refractory metals, reactive metals, super alloys, ceramics, polymers, and coatings.
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hydrogen is by splitting water using electricity (electrolysis). This involves passing an electric current through the water to split it into hydrogen and oxygen. Electrolysis is less efficient than a direct chemical path but offers virtually no pollution or toxic byproducts if the electric current is generated using renewable energy (including geothermal and hydropower).
electrolysis is a process that takes up relatively little space and can use the existing water and electricity infrastructure. For these reasons, this option could be used to make hydrogen on-site at fueling stations in the near term. The major drawbacks to this technology are the cost of electricity and uncertain impacts on carbon emissions, which depend on the energy sources used by the utilities.
Using wind power or waste heat from nuclear reactors would generate hydrogen without emitting greenhouse gases.
Feedstock: Water Energy Source: Grid Wind Solar Nuclear Production: Distributed Semi-Central Central
Near Term
powered water electrolysis (e.g., wind or solar) at central or semi-central facilities could overcome these challenges. These facilities may take advantage of technology advances or receive cost breaks from the utilities by using off-peak power. Water electrolysis facilities at centrally located nuclear plants could produce hydrogen using heat from the reactors. This high-temperature process would require a third less electricity than low-temperature electrolysis.
Mid Term
Long Term
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directly from water using sunlight and a special class of semiconductor materials. These highly specialized semiconductors absorb sunlight and use the light energy to completely separate water molecules into hydrogen and oxygen.
This technology requires a material that is both highly durable and highly efficient at photoelectrochemical hydrogen production. Scientists have identified some materials that split water efficiently and others that offer high durability, but the search continues for a material that meets both of these criteria. Researchers are currently working to discover photoelectrochemical materials and coatings that can efficiently convert a wide spectrum of lightyet remain stable when they come into contact with electrolytes.
Researchers focus light on a semiconductor immersed in water to directly split water into hydrogen and oxygen.
Near Term
approaches to solve the materials hurdles, including use of nanomaterial coatings, metal doping, and various hybrid materials. Photoelectrochemical water splitting is in the very early stages of reserach, but offers long-term potential for sustainable hydrogen production with low environmental impact.
Mid Term
Long Term
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This conversion pathway produces hydrogen by using sunlight and specialized microorganisms, such as green algae and cyanobacteria, to split water. Just as plants produce oxygen from photosynthesis, these microbes consume water and produce hydrogen as a byproduct of their natural metabolic processes. Photolytic conversion holds great promise for the long term, but major challenges remain.
Scientists are pursuing innovative ways to improve photolytic hydrogen production in green algae. Specifically, they are working to increase both the oxygen tolerance of critical enzymes and algaes efficiency at harvesting light.
Feedstock:
A key challenge is that the oxygen produced along with the hydrogen tends to accumulate and impede the work of the hydrogen-evolving enzymes. Researchers are searching for more oxygen-tolerant enzymes and also exploring new genetic forms of the organisms that sustain hydrogen production in the presence of oxygen. An alternative approach uses a metabolic switch (sulfur deprivation) to cycle algal cells back and forth between phases for photosynthetic growth and hydrogen production. Another challenge is that the chlorophyll in microalgae under bright sunlight absorbs photons at a far faster rate than they can be used in photosynthesiswasting up to 80% of the photon energy. Researchers are using molecular genetics along with new diagnostic tools to find ways for sunlight to penetrate deeper into the microalgae culture. Success would enable more cells to perform useful photosynthesisincreasing solar conversion efficiency and hydrogen productivity.
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Photosynthetic Bacterial Production: Sunlight is the driver for bacteria to break down organic material, thus releasing hydrogen. Purple, non-sulfur bacteria with a specialized enzyme can produce hydrogen gas when exposed to near-infrared light energy. Dark Fermentative Production: Bacteria can act on organic material and decompose it into hydrogen and other byproducts without the aid of sunlight. This process uses anaerobic bacteria that grow in the dark on carbohydrate-rich substrates. These bacteria break down biomass, which is relatively inexpensive, plentiful, and high in carbohydrate content. Researchers are working to identify specific strains of bacteria that can directly and efficiently ferment organic material (or cellulose) to hydrogen. Researchers will then develop mutations that selectively block the generation of waste acids and solvents that reduce ongoing hydrogen productivity. Microbial-aided Electrolysis: Microbial electrolysis cells use bacteria to efficiently extract energy from organic matter. As the bacteria decompose the organic materials, they produce a low voltage at the anode. Hydrogen is produced at the fully submerged cathode with the input of a tiny amount of additional energy. Optimizing the environment to expedite this natural process could potentially produce hydrogen with much greater efficiency than standard electrolysis. Combination: Perhaps the most promising biological
production pathway incorporates some or all of these technologies into a single system. This integrated approach could alleviate the need to overcome all barriers to individual technologies, as long as the overall system is cost-competitive. Integrated systems may use the byproducts of some production pathways as inputs to others in a nearly closed-loop system that produces hydrogen at each stage.
Microbial electrolysis cells use bacteria to break up acetic acid from plant waste and produce hydrogen gas using a bit of added electricity. The process produces more than 250% more energy than the electricity required to extract it.
A system using multiple biological processes can provide internally generated feedstock and produce hydrogen at each step.
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Next Steps
Energy prices, supply uncertainties, and climate concerns are intensifying the need for diverse forms of energy from sustainable domestic resources. Guided by the Hydrogen Production Roadmap, the FreedomCAR & Fuel Partnership and the DOE Hydrogen Program are working with researchers in national laboratories, universities, and industry to accelerate the development and commercial readiness of hydrogen production technologies and the supporting infrastructure. The hydrogen initially available at consumer fueling stations will help to establish the markets, standards, and infrastructure. As research progresses, the technologies used to produce the hydrogen are expected to shift toward those that produce no net greenhouse gas emissions. While some of the hydrogen production technologies now under development may be supplanted by competing or improved approaches, a variety of production technologies are likely to find long-term use in regions that offer an abundance of their required feedstock and renewable energy resource. Fuel costs to consumers will gradually decrease as these technologies and the delivery infrastructure are optimized and grow to maturity. Ultimately, hydrogen represents an important component of our national strategy to diversify energy resources. The Hydrogen Production Roadmap is helping to align public and private R&D priorities and technology investments to accelerate progress in bringing this clean, domestic energy carrier into widespread use. For more information on the technologies, please visit our website at www.hydrogen. energy.gov
The nozzle used for refueling a hydrogen fuel cell vehicle is designed to form a seal around the filler pipe rather than function as a spout.
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The FreedomCAR and Fuel Partnership is a publicprivate partnership between the U.S. Department of Energy; five major energy producers, including BP America, Chevron Corporation, ConocoPhillips, ExxonMobil Corporation, and Shell Hydrogen LLC; USCAR, whose members include Chrysler, Ford, and General Motors; and two major utilities DTE Energy and Southern California. The Partnership envisions a clean and sustainable transportation energy future that reduces our nations dependence on foreign oil and minimizes regulated emissions and CO2, yet preserves freedom of mobility and vehicle choice for consumers.
Disclaimer
This report was prepared as an account of work sponsored by an Agency of the United States Government. Neither the United States Government nor any Agency thereof, nor any of their employees, makes any warranty, expressed or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference herein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise does not necessarily constitute or imply its endorsement, recommendation, or favoring by the United States Government or any Agency thereof. The views and opinions expressed by the authors herein do not necessarily state or reflect those of the United States Government or any Agency thereof.
The Partnerships Hydrogen Production Technical Team works closely with the DOE Hydrogen, Fuel Cells & Infrastructure Technologies (HFCIT) Program, which is the lead federal agency for directing and integrating activities in hydrogen production, storage, and delivery with transportation and stationary fuel cell activities. The Hydrogen Production Tech Team provides guidance to DOEs hydrogen production activities: Identifying technical goals Clarifying R&D needs Establishing technical performance targets Monitoring progress
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January 2009
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