Collisional Alignment and Orientation Parameters of Ra Atom at 75 Ev

IOSR Journal of Applied Physics (IOSR-JAP)
ISSN: 2278-4861. Volume 2, Issue 1 (Sep-Oct. 2012), PP 19-23

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Collisional Alignment and Orientation Parameters of Ra Atom at
75 eV.

Kapil Sirohi
1
,

P.S.Negi
2
, Sachin Kumar
3
, B.P. Yadav
4
, Pushpendra Singh
5,

Nempal Singh
6

1, 2
Deptt. Of Physics, Meerut College, Meerut. (UP) INDIA
3,4
Deptt. Of Chemistry, Meerut College, Meerut. (UP) INDIA
5,6
Deptt. Of Physics, N.A.S. College, Meerut. (UP) INDIA

Abstract: Collision is basically an interaction between two or more particles. Its study for atoms and
molecules has proved quite useful from the pt of view of basic as well as applied research activities in atomic
and molecular physics.In this paper we shall study the collision dynamics of the excitation process of Ra atom
using distorted wave approximation theory.Results are presented for the alignment and orientation parameters
at 75eV.
Key Words; distorted wave approximation theory,alignment and orientation parameters, excitation process,
Ra atom,

I. Introduction
In the atomic and molecular physics, The subject of electron-atom collision has received the
maximum attention. [1,2,7,8, 9,10 ]. There has been considerable interest and progress in the recent years for
both theoretically and experimentally in the study of electron impact excitation of atoms [3,5,6,8]. In the present
paper we carried out various set of parameters in the excitation of n
1
D state of Ra atom from ground state n
1
S.
Results are presented at incident electron energy 75 eV . Though there is no experimental and theoretical data
to compare with our results. We have carried out two types of calculations viz. Relativistic Distorted Wave
(RDW) and Non-Relativistic Distorted Wave (DW) approximation methods. The results obtained from these
two methods are compared with each other. The comparison thus provides the importance of relativistic effect.

II. Theoretical Consideration
The earlier traditional experiments had focused attention, mostly, in measuring the cross sections
results. However the current efforts are now to perform perfect scattering experiments which can provide
complete information about the dynamics of electron- atom scattering process
The scattering experiments where the polarization of the light emitted during the decay of excited atoms is
measured in coincidence with the scattered electrons are called as scattered electron-emitted photon coincidence
experiments. It is well known that in order to determine the polarization state of any radiation following
measurements are needed,
(i)
,
3
q
which determine the degree of linear polarization with respect to x and y-axes (in collision frame),
I
I I
I I
I I ) 90 ( ) 0 (
) 90 ( ) 0 (
) 90 ( ) 0 (
0 0
0 0
0 0
3
=
+
= q (1)
where, ) (| I denotes the intensity of light transmitted by a linear polarization analyzer oriented at an angle
' ' | relative to the direction of incident beam (i.e., z-axis in collision frame). I is the total intensity of the
emitted radiation.
(ii) ,
1
q which determine the degree of linear polarization with respect to two orthogonal axes oriented at 45 to
the z-axis (in collision frame),
I
I I
I I
I ) 135 ( ) 45 (
) 135 ( ) 45 (
) 135 ( ) 45 ( 1
0 0
0 0
0 0
1
=
+
= q (2)
(iii) ,
2
q which determine the degree of circular polarization which is defined as
I
I I
I I
I I
+
+
+
=
+
=
2
q
(3)
Collisional Alignment and Orientation Parameters of Ra Atom At 75 eV.
) 1 , ( ) ,....., 2 , 1 ( ) 1 ,....., 2 , 1 (
) (
) ( ) (
+ u = +
+ +
N k F N A N
f i
DW
if if if
_
where, I
+
and I
-
are intensities of light transmitted by polarization analyzers with positive (i.e. left handed
circularly (LHC) polarized light) and negative helicities i.e. (right handed circularly (RHC) polarized light
respectively.
Stokes parameters gives us complete information about the S-D excitation process. But for a better
physical interpretation of stokes parameters we may also express them in terms of these parameters.
L
= 2P
3
(1 h), (4)
h= , (5)
= P
1
+ iP
2
, (6)
Where
L
is the angular momentum transferred perpendicular to the scattering plane, (Also called orientation of excited
state of charge cloud of the atom)
is the alignment angle of charge cloud of the exited D state,
h is the height of charge cloud
is the linear polarization.
Though the S-D excitation process is triple coincidence (D-P-S) The helicity of P-S photon is
+ or - so above relations can be written as defined as
, (7)
(8)
Where
, (9)

III. Distorted Wave Approximation Theory
Consider electrons having energy 'E
i
' incident on an atom (with nuclear charge 'Z' and N electrons) in
ground state, denoted by 'a'. As a result of collision, electrons excite the target to a higher state, denoted by 'b'
and they scattered with energy 'E
b
'.
Than the T-matrix for the electron-impact excitation of an atom from initial state i to final state f in distorted
wave approximation can be written as.
) 1 ,....., 2 , 1 ( | ) 1 ( | ) 1 ,....., 2 , 1 ( + + + =
+
N N U V N T
i f f
DW
if
_ _
(10)

where V is the target-projectile interaction given by
| |
1
1
1
1 +
=
+

E + =
N j
N
j
N
r r r
Z
V (11)

Where r
j
= (j=1, 2, . N) is the position cordinate of the target electrons and r
n+1
is the projectile electron with
respect to the nucleus of the atom.
U
f
is the distertion potential which is taken to be a function of radial cordinates of the projectile electrons only.
The wave function
) ( +
if
X is the combined wave function of the target atomic wave function
if
|
and the
projectile electron distorted wave function
) (
) (
+ DW
f i
f
(12)

) f ( i
k is the projectile electron and scattered electron wave vector after the excitation process. A is the
antisymmetrization operator which takes into account the effect of electron exchange between projectile and
target atom electrons.

3.1 Non-Relativistic Distorted wave Approximation Theory : In the non-relativistic distorted wave (DW)
method the target is described by Hartree-Fock wave functions which is obtained by Fisher code [4] and
distorted wave projectile electron wave function are obtained by solving Schrodinger wave equation.

3.2 Relativistic Distorted wave Approximation Theory : In the relativistic distorted wave (RDW) method, the
target atom is represented by multi-configuration Dirac-Fock wave functions which is obtained by using Graphs
92 programme of Prapia [11] and the projectile wave function are obtained by Dirac equations.

Fig.1

Fig.2

Fig.1&2 Alignment parameters[+,-] for the excitation of Ra atom

Fig.3

Fig.4

Fig.3&4 Orientation Parameters [L
+, L
-] for the excitation of Ra atom

IV. Result and Discussion :
Here we have carried out the calculations for achieving the various set of
parameters( ) for the excitation of Ra atom from ground state 6
1
S to the excited state 6
1
D
state by the electron impact at 75 eV . We do not have any other theoretical or experimental data to compare
with our calculations. We therefore compare the two types of calculations using DW and RDW. We find that
both DW and RDW calculations agree qualitatively and quantatively in reasonable manners at this energy
level.

V. Conclusions
We have presented our DW and RDW Culculation for various set of parameters ( ) in
excitation of Ra atom. The nature of the curve show good behavior at incident electron energy at 75eV. It would
be interesting to have other theory and experimental Confirmation of these results.

References:
[1] B Bederson, comments At. Mol. Phy. I, 41 (1969)
[2] B Bederson, comments At. Mol. Phy. I, 65 (1969)
[3] Bray, I, Fursa, D. V., McLaughlin, D. T., Donnelly, B.P. and Crowe, A., "Theoretical and Experimental Investigation of Electr on-
Helium Scattering", XIX International Conference on the Physics of Electronic and Atomic Physics (ICPEAC), eds.: Dube, L.,
Mitehell, J. B. A., McConkey, J. W. and Brion, C. E., Whistler, Canada, p. 785 (1995).
[4] Fisher, F.C., "A Multi-configuration Hartree-fock Program," Comput. Phys. Comm., 1, 151 (1969).
[5] Khare, S. P., "Introduction to the Theory of Collisions of Electrons with Atoms and Molecules", eds. Burke, P. G. and
Kleinpoppen, H., Kluwer Academic/Plenum Publishers, New York (2002).
[6] Kheifets, A., Bray, I., Lahmam-Bennani, A., Duguet, A. and Taouil, I., "A Comparative Experimental and Theoretical
Investigation of the Electron Impact Double lonization of He in KeV Regime", J. Phys. B: At Mol. Opt. Phys. 32 5047 (1999).
[7] N Anderson and K Bartschat, Adv. At. Mol. Opt. Phy.36, 1 (1996)
[8] N Anderson and K Bartschat, Polarization, alignment and orientalion in atomic collisions eds. Drake and G Ecker (Sprienger
Vorlag, Berlin, Heidelberg, (2000)
[9] N Anderson, K Bartschat, J T Broad, I V Hertrel, Phys. Rep. 270,251, (1997)
[10] N Anderson, K Bartschat, J , Phys. B30, 507, 1 (1997)
[11] Parpia, F. A., Froese Fischer, C. and Grant, I. P., "GRASP92: a package for large-scale relativistic atomic structure calculations",
Computer Phys. Commun., 94, 249 (1996).

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IOSR Journal of Applied Physics (IOSR-JAP)

ISSN: 2278-4861. Volume 2, Issue 1 (Sep-Oct. 2012), PP 19-23

-] for the excitation of Ra atom

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