CHD Annex 111108prov Sbclogo

CATALYTIC HYDRO-DECHLORINATION METHOD (CHD) Annex to POPs Technology Specification and Data Sheet
PROVISIONAL VERSION
Table 1: Technology Overview Summary Technical Details

Technology Provider Technology Scale + Comp. treated Related comp treated PCB Validation project experience ** Applicability Ranking++ Additional Remarks Others
Kanden Engineering
Catalytic HydroDechlorination (CHD)
Kanden Engineering
Catalytic HydroDechlorination (CHD)
Kanden Engineering Kanden Engineering
Catalytic HydroDechlorination (CHD) Catalytic HydroDechlorination (CHD)
1:PCB taken from capacitors 2:PCB recovered by VTR treatment of capacitors 3:PCB separated from TCB by distillation 1:PCB taken from capacitors 2:PCB recovered by VTR treatment of capacitors 3:PCB separated from TCB by distillation PCB taken from capacitors
52 trial runs at Osaka plant in July 2006 Capacity:PCB-2t/D
PCB
Commercial operation at Osaka plant in October 2006 Capacity:PCB-2t/D Capacity:PCB-3.8kg/batch
PCB
PCB recovered by VTR treatment of capacitors
PCB
Capacity:PCB-3.8kg/batch
+Key: F - Full-scale applications completed P - Pilot/Demonstration scale completed; no F-applications B - Bench/Laboratory scale completed; no P or F-applications T - Theoretical applicable, no B, P, F applications * Vendor claims performance of demonstration, but no data provided
++Key: Applicability ranking for pesticides DA Direct applicable FS 1 Full scale within reasonable period possible 0-2 years FS 2 Full scale within considerable period possible 2-5 years **Validation on the basis of info provided in Table 2 and 3
Annex Page 1 of 6
John Vijgen, International HCH and Pesticides Association and Dr.Ir. Ron McDowall, Auckland New Zealand for Secretariat of the Basel Convention Date: 11.11.2008
PROVISIONAL VERSION
Table 2: Overview Project Experience per Technology Supplier

Technology Provider Kanden Engineering Contaminants Amount treated in tons 52 tests with amounts varying from 146 to 250 kg each of approx 10 t PCB in total Commercial operation 231t treated (2006/10~2008/6) 3,8 kg/batch Results incl. DRE, Pre-treat, Post treat Emissions, energy consumption, costs* Test results: DRE 99.9996~99.9998 % PCB <0.35 mg/kg after reaction in all 52 batches It was confirmed that the metal after cleaning and VTR treatment, and the products of CHD can be recycled for the material and catalyst and solvent can be reused. No retreating in all batches. Client References Name, address, contact person phone, Email, fax PCB treatment facility in Osaka controled under Japan goverment.
PCB Oil
Kanden Engineering
PCB Oil
PCB treatment facility in Osaka controled under Japan government.
Kanden Engineering
PCB Oil
Kanden Engineering
PCB Oil
3,8 kg/batch
PCB (pre-treat): 10%, Post treat: less than 0.5 mg/kg Catalyst performance did not change during 12 batches reaction. PCB concentrations of biphenyl which recovered after reaction by distillation and HCl solution were less than 0.5 ppm and 0.005ppm, respectively. PCB (pre-treat): 10%, Post treat: less than 0.5 mg/kg
Pilot scale test plant
Mitsui Engineering & Shipbuilding Co., Ltd. Chiba factory.
Annex Page 2 of 6
PROVISIONAL VERSION
Table 3: Overview detailed project information per project Project name (from Table 2):
Location project Pre-treat mg/kg Post-treat mg/kg DREs Emissions 1.Air (HCl, Dioxins & furans etc) 2. Water, 3. Waste (slags) 1.none 2.none 3.biphenyl, HClaq, 1.none 2.none 3.biphenyl, HClaq, Energy consumption
Costs(Capital, operating costs)
Others, remarks
PCB treatment facility in Osaka Pilot scale test plant (continuously 14 batches treating)
PCB:10%
PCB:10% every batch
0.210 ~ 0.350 0.050~0.267
99.9996 ~ 99.9998 99.9997 ~ 99.99995
Mitsui Engineering & Shipbuilding Co., Ltd. Chiba factory 3,8 kg (KC-300) PCB
no data available
Notes: 1.
PCBs concentration in the all samples after cleaning, VTR and CHD treatments in the test period at the PCB Waste Treatment Facility for Recycling of PCB in JESCO/Osaka JAPAN cleared the target value of detoxification. 2. PCB and Dioxin concentration in the air around the facility during the treatment cleared the target value (PCB: less than 0.0005 mg/m, DXN: less than 0.6pg-TEQ/m). (The exhaust gas from the each room in the facility, for example dismounting room, was treated properly, and CHD treatment is operated in the closed system, so it has no exhaust gas.)
Annex Page 3 of 6

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CATALYTIC HYDRO-DECHLORINATION METHOD (CHD) Annex to POPs Technology Specification and Data Sheet

Table 1: Technology Overview Summary Technical Details

Catalytic HydroDechlorination (CHD)

Catalytic HydroDechlorination (CHD)

Kanden Engineering Kanden Engineering

Catalytic HydroDechlorination (CHD) Catalytic HydroDechlorination (CHD)

52 trial runs at Osaka plant in July 2006 Capacity:PCB-2t/D

Commercial operation at Osaka plant in October 2006 Capacity:PCB-2t/D Capacity:PCB-3.8kg/batch

PCB recovered by VTR treatment of capacitors

Table 2: Overview Project Experience per Technology Supplier

PCB treatment facility in Osaka controled under Japan government.

Pilot scale test plant

Mitsui Engineering & Shipbuilding Co., Ltd. Chiba factory.

Costs(Capital, operating costs)

PCB:10% every batch

0.210 ~ 0.350 0.050~0.267

99.9996 ~ 99.9998 99.9997 ~ 99.99995

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