Answ Er Key: Hints & Solutions (Practice Paper-3)

1
Pre-foundation Career Care Programmes (PCCP) Division

1
PART-I (1 Mark)
MATHEMATICS
1. Given : a
1
, a
2
, a
3
.........AP and a
1
, a
2
, a
4
, a
8
......GP.
Let common difference of A.P. = d
a
2
= a
1
+ d
a
4
= a
1
+ 3d
a
8
= a
1
+ 7d
1
2
a
a
=
2
4
a
a
=
4
8
a
a
= r
1
1
a
d a +
=
d a
d 3 a
1
1
+
+
=
d 3 a
d 7 a
1
1
+
+
= r
(a
1
+ d)
2
= a
1
(a
1
+ 3d)
a
1
2
+ d
2
+ 2 a
1
d = a
1
2
+ 3a
1
d
d
2
= a
1
d (d = 0)
d = a
1
....(i)
Hence,
1
2
a
a
= r ;
1
1
a
d a +
= r
1
1 1
a
a a +
= r (using (i))
r = 2.
ANSWER KEY
HINTS & SOLUTIONS (PRACTICE PAPER-3)
Ques. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
Ans.
A B C B D B D A A C
B B D C A
Ques. 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30
Ans. B C B C D B B D D C C
D C A D
Ques. 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
Ans.
D C A B B C A A A B C D C C D
Ques. 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60
Ans.
A C B A B A D C D B D A D B B
Ques. 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75
Ans.
A C C C B B C D A D D D B A B
Ques. 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90
Ans.
B B D C A C B C B B D C D B C
Ques. 91 92 93 94 95 96 97 98 99 100 101 102 103 104 105
Ans. D A B C D A C C B B B D A A B
Ques. 106 107 108 109 110 111 112 113 114 115 116 117 118 119 120
Ans. C A C D B C B A B A D B A C C
id11453671 pdfMachine by Broadgun Software - a great PDF writer! - a great PDF creator! - http://www.pdfmachine.com http://www.broadgun.com
2
2
2.
k
101
T
T
1 k
k
=
till k = 10
T
k
> T
k1
Let k = 11
T
11
< T
10
T
10
is maximum at k = 10.
3. x = 2 +
3
+
6
( )
2
2 x
=
( )
2
6 3 +
x
2
+ 2 2 2 = 9 + 2 6
x
2
7 = 2 8
(x
2
7)
2
= 64 2
So, smallest possible value of n is 4.
4. Let the three players are A, B, C.
Now, each player get 0 score after playing 9 games. It happened only when each player wins 3 games
and loss 6.
So,
A win 3 games out of 9
9
C
3
B win 3 games out of remaining 6
6
C
3
C win 3 games out of remaining 3
3
C
3
So, required way =
9
C
3

6
C
3

3
C
3
=
! 6 1 2 3
! 6 7 8 9

! 3 1 2 3
! 3 4 5 6

1
= 1680.
5.
B C
A
(2, 3)
(x, y) (4, 0)
(2, z)
O
O is circumcenter
OA = OB = OC = circumradius
(2 2)
2
+ (z 3)
2
= (4 2)
2
+ (0 z)
2
z
2
+ 9 6z = 4 + z
2
9 6z = 4
5 = 6z
6
5
= z
Circumcenter =
2 2
) 2 2 ( ) 3 z ( + = | z 3 | =
3
6
5
=
6
13
.
3
3
6.
P P'
(5, 15) (21, 15) L
A
Mid point of PP =
|
.
|
\
| + +
2
15 15
,
2
21 5
L = (13, 15)
Point A will be (13, 0)
By property PA + PA = 2a
PA =
2 2
) 15 0 ( ) 5 13 ( +
=
225 64 +
=
289
= 17 cm
PA =
2 2
) 15 0 ( ) 21 13 ( +
=
225 64 +
=
289
= 17 cm
2a = PA + PA
2a = 17 + 17
2a = 34 cm
So, length of major axis = 2a = 34 cm.
7.
B C
P
(10, 10)
(a, b) (0, 6)
2x + 3y = 18
PB = PC
(10 0)
2
+ (10 6)
2
= (a 10)
2
+ (b 10)
2
100 + 16 = a
2
+ 100 20a + b
2
+ 100 20b
a
2
+ b
2
20a 20b + 84 = 0 ....(i)
Also (a, b) i.e. on 2x + 3y = 18
2a + 3b = 18
a = 9
2
b 3
Using equation (i)
2
2
b 3
9 |
.
|
\
|

+ b
2
20
|
.
|
\
|

2
b 3
9
20b + 84 = 0
81 +
4
b 9
2
27b + b
2
180 + 30b 20b + 84 = 0
4
b 13
2
17b 15 = 0
13b
2
68b 60 = 0
4
4
13b
2
78b + 10b 60 = 0
13b(b 6) + 10 (b 6) = 0
b = 6 or b =
13
10
When b = 6, then a = 9
2
6 3
= 0
When b =
13
10
, then a = 9 +
13 2
10 3
= 9 +
26
30
=
13
132
8a + 2b = 8
13
132
+ 2
13
10
=
79
13
20 1056
~
.
8. cosec
2
(o + |) sin
2
(| o) + sin
2
(2o |) = cos
2
(o |)
cosec
2
(o + |) + sin
2
(2o |) =
1
) ( sin ) ( cos
2 2
o | + | o
cosec
2
(o + |) = 1 sin
2
(2o |)
cosec
2
(o + |) = cos
2
(2o |)
Minimum value of cosec
2
(o + |) is 1 and maximum value of cos
2
(2o |) is 1.
They will be equal for the value 1.
o + | =
2
t
.....(i)
2o | = 0 .....(ii)
By adding (i) & (ii)
3o =
2
t
o =
6
t
| =
3
t
sin(o |) = sin (
6
t

3
t
) = sin (
6
t
) =
2
1
.
9. sinx + siny =
5
7
....(1)
cos x + cosy =
5
1
....(2)
By (1)
2
+ (2)
2
we get
2 + 2sinx siny + 2 cosx cosy = 2
5
5
sinx siny + cosx cosy = 0
cos(x y) = 0
x y = 90
By (1) (2) we get
sinx cosx + sinx cosy + siny cosx + siny cosy =
25
7
sin(90 + y)cosx + sin(x + y) + sin(x 90) cos y =
25
7
cosy cosx + sin(x + y) cosx cosy =
25
7
sin(x + y) =
25
7
.
10.
6
x
y =
0
1
(1, 1)
y = sin x
Clearly, curve meet each other twice in 2t 3t
4t 5t
6t 7t
8t 9t
10t 11t
Total 10 Times.
11. f(x) is differentiable on R.
So, it will be contincous on R.
Continuity at x = 0
LHL
0 x
lim
x
x sin
2
Put x = 0 h, then h 0
0 h
lim

h
) h 0 sin(
2
0 h
lim

h
h
h
h sin
= 0
RHL
+
0 x
lim
x
2
+ ax + b
Put x = 0 + h, then h 0
0 h
lim
h
2
+ ah + b = b
Value of f(x) at x = 0
f(0) = b.
6
6
f(x) is contineous at x = 0
LHL = RHL = f(0)
0 = b = b
b = 0
Differentiability at x = 0
LHD
0 h
lim
h
f h f
) 0 ( ) 0 (
0 h
lim

h
b
h
sinh
2
0 h
lim

2
2
h
h sin
= 1
RHD
0 h
lim

h
) 0 ( f ) h 0 ( f +
0 h
lim

h
b b ah h
2
+ +
0 h
lim

h
) a h ( h +
= a.
f(x)is differentiable at x = 0, LHD = RHD
a = 1.
12. Let point p(x
1
, y
1
) is on the curve y
2
= 4x.
y
1
2
= 4x
1
x
1
=
4
y
2
1
PA =
2
1
2
1
) 3 y ( ) 0 x ( +
AP
2
= x
1
2
+ y
1
2
6y
1
+ 9
AP
2
= x
1
2
+ y
1
2
6y
1
+ 9
Let AP = z
z
2
= x
1
2
+ y
1
2
6y
1
+ 9
z
2
=
2
2
1
4
y
|
|
.
|
\
|
+ y
1
2
6y
1
+ 9
z
2
=
16
y
4
1
+ y
1
2
6y
1
+ 9
Diff. w.r.t. y
1
2z
1
dy
dz
=
16
y 4
3
1
+ 2y
1
6
2z
1
dy
dz
=
4
y
3
1
+ 2y
1
6
=
4
24 y 8 y
1
3
1
+
2z
1
dy
dz
= (y
1
2) (y
1
2
+ 2y
1
+ 12)
7
7
For the critical points
1
dy
dz
= 0
(y
1
2)(y
1
2
+ 2y
1
+ 12) = 0
y
1
= 2
y
1
2
= 4x
1
(2)
2
= 4x
1
x
1
= 1.
2
2
1
dy
dz
|
|
.
|
\
|
+ 2z 2
1
2
dy
z d
= (y
1
2
+ 2y
1
+ 12) + (y
1
2) ( 2y
1
+ 2)
= y
1
2
+ 2y
1
+ 12 + 2y
1
2
4y
1
+ 2y
1
4
= 3y
1
2
+ 8.
when y
1
= 2 and
1
dy
dz
= 0
2
1
2
dy
z d
> 0
z is min at (1, 2)
Minimum distance =
2 2
) 3 2 ( ) 0 1 ( + = 1 1+ = 2 .
13. We can find the answer through option as the sum of weight of packet taken from trucks is 1022870 gm
and its unit digit is 0. The truck that have heavier bags have unit digit 0. So, the truck have lighter bags in
which the sum of weight of bags must have unit digit 0.
So, according to option D. i.e. truck no. 2, 8
Track 2 have 2
1
bags and total weight = 2
1
999 gm = .......8 gm
Truck have 2
7
bags and total weight = 2
7
999 = 128 999 gm = ......2 gm
So, the unit digit of the weight contain by truck 2, 8 together is 0.
14.
dx ) ] x 2 cos([ ) x cos(
1
0
}
t t
=
dx 0 cos ) x cos(
2 / 1
0
}
t
+
dx cos ) x cos(
1
2 / 1
}
t t
=
dx ) x cos(
2 / 1
0
}
t

dx ) x cos(
1
2 / 1
}
t
=
(
t
tx sin
2 / 1
0

(
t
tx sin
1
2 / 1
= (
t
1
(
1
0
=
t
2
.
8
8
15. I
N
= (
n
x ) nx cos(
10
1
0
+
}
1
0
9
n
dx x ) nx cos(
10
= 0 +
(
(
(
(
(
}
(
1
0
8
1
0
n
dx x ) nx sin(
n
9
n
10
n
x ) nx sin(
9
=
(
(
}
1
0
8
2
dx x ) nx sin(
n
9 10
=
(
(
}
1
0
10
dx ) nx sin(
n
! 10
= 0 as Denom
16. y = x
2
& y = 1 x
2
Point of intersections of graphs x
2
= 1 x
2
2x
2
= 1
x =
2
1
Point of intersections =
|
|
.
|
\
|
2
1
,
2
1
and
|
|
.
|
\
|
2
1
,
2
1
.
Area under graph :
= }

2 / 1
2 / 1
2 2
) x 1 ( x
= }
2 / 1
2 / 1
2
1 x 2
=
2 / 1
2 / 1
3
x
3
x 2
(
(
= 2
2
1
2 6
2
= 2
2 6
6 2
=
2 3
4
=
3
2 2
.
17. k 4 i 3 a

= and b
= k 12 j 5

+
( ) 5 4 ) 3 ( a
2 2
= + =
and ( ) 13 12 ) 5 ( b
2 2
= + =
Therefore, a vector which bisects the angle is 13 ( ) k 4 i 3

+ 5 ( k 12 j 5

+ ) = k 8 j 25 i 39

+ + .
9
9
19. Let ...... 5 . 3 . 2 M
3 2 1
x x x
= , ...... 5 . 3 . 2 N
3 2 1
y y y
= x
i
& y
i

e
w
m / d
d
=
N / d
d

|
|
.
|
\
|
1 2
1 2
1
x

|
|
.
|
\
|
1 3
1 3
2
x
|
|
.
|
\
|
1 5
1 5
3
x
....... =
|
|
.
|
\
|
|
|
.
|
\
|
1 3
1 3
1 2
1 2
2 1
y y
.........
N / d
M / d
d / 1
d / 1
=
....
1 3 / 1
1
3
1
1 2 / 1
1
2
1
....
1 3 / 1
1
3
1
1 2 / 1
1
2
1
2 1
2 1
y y
x x
|
|
|
|
|
.
|
\
|
|
.
|
\
|
|
|
|
|
|
.
|
\
|
|
.
|
\
|
|
|
|
|
|
.
|
\
|
|
.
|
\
|
|
|
|
|
|
.
|
\
|
|
.
|
\
|

2 1
2 1
2 1
2 1
y y
y y
x x
x x
3 2
)...... 1 3 )( 1 2 (
..... 3 2
)..... 1 3 )( 1 2 (
= 1
M
N
> .
20.
m
m
2
C
A from element
one only
C C
n mC n m n m m
2 1 0
+ + +

(1 + n)
m
PHYSICS
27. Sphere is hollow so potential inside sphere will be same as that on surface.
28. Heat supplied Q = du + AW (at contat pressure)
PV = RT
PdV = RdT
dT =
R
PdV
Q = C
V
dT + PdV
Q = C
V

R
PdV
+ PdV
Work done at constant pressue, W
W = PdV
PdV
PdV
R
PdV
C
W
Q
V
+
=
1
R
CV
W
Q
+ = ( For diatomic gos, CV = R
2
5
)
1
R 2
R 5
W
Q
+ =
2
7
W
Q
=
7
2
Q
W
=
10
10
29.
series balmer For
3
1
2
1
R
1
series yman l For
2
1
1
1
R
1
2 2
2 2
|
.
|
\
|
=
|
.
|
\
|
=
|
o
(
36
4 9
9
1
4
1
= )
36 / 5
4 / 3
=
o
|
=
5
27
5
9
1
3
=
27
5
=
|
o
30.
q
A
q
B
unchanged
charge divides
2
q
and
2
q
Than, on touching
2
q
sphere to q
Charge divides
4
q 3
2
q 2 / q
=
+
force between
4
q 3

2
q
R

f'=
2
2
R 8
q 3 K
f' =
8
3
F
8
3
R
kq
2
2
=
31. Intially block enters in the magnetic filed rate of change in flux will be constant so costant current will
produce, when it mass in side the magnetic field there is no change in magnetic flux, current I = 0, when
it use the filed the rate of the change in flux will be again constant between in decrecaing order so contant
current will induced on opposite.
32. No change in moment of inertia
34.
E
A
O
+q q
Electric field at each point of OA obtained to it and opposite to direction of dipole moment.
11
11
38.
m
a
Total force in upward direction m (g + a) because mass m is stationary on inclined plane and whole
system is accelerated with acceleatration a in upward.
39. Force of positve charge = Electric force + Magnetic force
F = (qE + qVB)
This force is in upward direction so no any particle will pass through the hole.
40. Potential energy at H height = Kinetic energy at the lowest point of circular path.
mgH =
2
1
mv
2
To complete the circular motion minmum velocity at lowest point will be V = gR 5
mgH =
2
1
m (5gR)
H =
2
5
R
CHEMISTRY
41. According to Grahams law
Rate of diffusion
mass Molar
1
due to highest molar mass of CO
2
rate of diffusion is slowest.
42. Moles of H
2
=
2
3
, Moles of O
2
=
32
4
Kinetic energy of n moles of gas =
2
3
nRT
so,
oxygen of energy Kinetic
hydrogen of energy Kinetic
=
RT n
2
3
RT n
2
3
2
1
=
2
1
n
n
=
32 / 4
2 / 3
= 12 : 1
12
12
44. ClF
3
sp
3
d hybridisation,
but due to presence of two lp on central atom Cl, according to VSEPR theory shape is T
45. HCO
3
+ H
+
H
2
CO
3
Bronsted base
HCO
3
H
+
+ CO
3
2
Bronsted acid
47. Isoelectronic means same no. of electrons
CO has 6 + 8 = 14 electrons
CN
has 6 + 7 + 1 = 14 electrons
48. CO
2
, due to sp hybridisation bond angle = 180
49. Diethyl ether, because it is inert towards the Grignard reagent
50. CH
3
CH
2
CH
2
CHO + CH
3
CH
2
CH
2
MgBr
CH CH CH C CH CH CH
3 2 2 2 2 3
H
OMgBr
H O
3
+
CH CH CH C CH CH CH
3 2 2 2 2 3
H
OH
Achiral Secondary alcohol
51. [Ni (PPh
3
)
2
Cl
2
] dsp
2
hybridisation, because PPh
3
is strong ligand hence pairing of electrons
takes place
[NiCl
4
]
2
sp
3
hybridisation, because Cl
is weak ligand hence pairing of electrons is not

takes place
52.
16H + 2MnO + 5COO
+
4
COO
53. Suppose equilibrium constant for the following reaction is K

1
N
2
+ 3H
2
2NH
3
; K
1
=
3
2 2
2
3
] H ][ N [
] NH [
-------- (i)
and equilibrium constant for the following reaction is K
2
2
1
N
2
+
2
3
H
2
NH
3
; K
2
= 2 / 3
2
2 / 1
2
3
] H [ ] N [
] NH [
-------- (ii)
square the both side of equation (ii)
K
2
2
=
3
2 2
2
3
] H ][ N [
] NH [
K
2
2
= k
1
[by equation (i)
K
2
=
1
k
K
2
= 41 [ K
1
= 41]
K
2
= 6.4
13
13
54. Suppose reaction is 2A Product
according to rate law
Rate R = k [A]
2
or
2
1
R
R
=
2
2
2
1
] A [
] A [
according to question
2
1
R
R
=
2
1
2
1
2
] A [
] A [
|
.
|
\
| )
`
=
2
] A [
] A [
1
2

2
1
R
R
= 4
R
2
=
4
R
1
55. HCO
3
H
+
+ CO
3
2
Conjugate base
NH
3
H
+
+ NH
2
Conjugate base
56. (II) & (IV)
Because both have close system of conjugated double bond and follow Huckels (4n+2) t e
rule.
57.
N
H
p of N takes part in resonance with conjugated double bonds, so it is not easily available on N for the
protonation.
N

p is not taken part in resonance so easily available for the protonation.
N

H
O
due to high E.N. of O availability of p on N decreases.
N

H
No extra effect, so availability of p on N increases.
14
14
58. Gauche conformer.
because angle between same groups is 60
59. Suppose initial quantity = N
o
after 75% completion of the reaction
remaining quantity N = N
o

100
25
=
4
N
o
T =
K
303 . 2
log
|
.
|
\
|
N
N
o
T =
K
303 . 2
log
|
|
.
|
\
|
4 / N
N
o
o
T =
K
386 . 1
-------- (i)
T
1/2
=
K
693 . 0
K =
30
693 . 0
-------- (ii)
so by equation (i) and (ii)
T =
30 / 693 . 0
386 . 1
T = 60 min.
60. Concentration of H
+
ions in H
2
SO
4
solution = 2 0.1 = 0.2 M
So no. of moles of H
+
ions in 10 ml H
2
SO
4
solution =
1000
10 2 . 0
= 0.002
concentration of OH
ions in 0.1 KOH solution

= 1 0.1
= 0.1 M
So no. of moles of OH
ions in 10 ml KOH
solution =
1000
10 1 . 0
= 0.001
after mixing remaining moles of H
+
ions = 0.002 0.001
= 0.001
so concentration of H
+
ions in mixture of
solutions =
10 10
001 . 0
+
1000 = 0.05 M
15
15
PART-II (2 Mark)
MATHEMATICS
81. p(x) = a
0
+ a
1
x + ........+ a
n
x
n
p(0) = 7
a
0
= 7
p(1) = a
0
+ a
1
+ a
2
+ ............+ a
n
= 9
p( 1) = a
0
a
1
+ a
2
........... = 1
p(2) = a
0
+ 2a
1
+ 4a
2
+ .......... = 13
p( 2) = a
0
2a
1
+ 4a
2
........... = 15
p(1) + p( 1) = 2[a
0
+ a
2
+ .........] = 10
a
0
+ a
2
+ a
4
= 5 .....(1)
7 + a
2
+ a
4
= 5
a
2
+ a
4
= 2 .....(2)
p(2) + p( 2) = 13 15
2(a
0
+ 4a
2
+ .........) = 2
a
0
+ 4a
2
+ 16a
4
= 1
4a
2
+ 16a
4
= 8 .....(2)
p(3) = 25
a
0
+ 3a
1
+ 9a
2
+ ........ = 25
a
0
+ 3a
1
+ 9a
2
+ 27a
3
+ 81a
4
+ 243a
5
= 25 .....(3)
From (1) and (2)
4a + 4a = 8
2 4
4a + 16a = 8
2 4
+
a = 0 and a = 2
4 2
Smallest possible value of n is 3.
82.
>
abc
2
0 ) b a (
1
ab
a
2
>
|a b| < c ...... (1) [Triangle inequalities]

|b c| < a ...... (2)
|c a| < b ...... (3)
Squaring and adding
a
2
+ b
2
+ c
2
< 2ab + 2bc + 2ca
2
ab
a
2
<
So, b e [1,2).
83. y = 4 | 3 x | 5
6
1 3 7
12
O

6
x

4
2

x
x

1
2
5
When, x < 1
y = | 3 x 4 | 5
y = x 1 5
y = x 6
When 1 s x < 3
y = | 3 x 4 | 5
= | x 1| 5
= x + 1 5
= x 4
When, 3 s x < 7
y = |x 7| 5
y = 7 x 5
y = 2 x
16
16
When, x > 7
y = | x 7| 5
= x 7 5
= x 12.
Area bounded region
= }

1
6
dx ) 6 x (
+ }

3
1
dx ) 4 x (
+
}

7
3
dx ) x 2 (
+
}

12
7
dx ) 12 x (
=
1
6
2
x 6
2
x

(
(
+
3
1
2
x 4
2
x
(
(
+
7
3
2
2
x
x 2
(
(
+
12
7
2
x 12
2
x
(
(
=
|
.
|
\
|
+
6
2
1

|
.
|
\
|
+
36
2
36
+
|
.
|
\
|
12
2
9

|
.
|
\
|
+ 4
2
1
+
|
.
|
\
|

2
49
14

|
.
|
\
|

2
9
6
+
|
.
|
\
|
144
2
144

|
.
|
\
|
84
2
49
=
2
11
18
2
15

2
9

2
21

2
3
72 +
2
119
=
2
130

2
48
90
= 65 24 90
= 49 sq. unit.
84.
b
b
a b
a
A
B
D
C
cosu =
ab 2
a b a
2 2 2
+
=
a 2
b
....(i)
cos(180 u) =
2
2 2 2
b 2
a b b +
cosu =
2
2 2
b 2
a b 2
cosu =
2
2 2
b 2
b 2 a
....(ii)
From (i) & (ii)
2
2 2
b 2
b 2 a
=
a
b
2
3
b
a
|
.
|
\
|
2
|
.
|
\
|
b
a
1 = 0
17
17
Let
b
a
= x
x
3
2x 1 = 0
(x + 1)(x
2
x 1) = 0
x = 1 or x =
2
) 1 )( 1 ( 4 1 1
=
2
5 1
x cannot be negative
x =
2
1
) 1 5 ( +
85. a
n
=
2
a 1
1 n
+
a
1
=
2
a 1
0
+
a
1
=
2
cos 1 u +
a
1
=
2
2
cos 2
2
u
a
1
=
2
cos
u
a
2
=
2
a 1
1
+
=
2
2
cos 1
u
+
=
2
4
cos 2
2
u
= cos
2
2
u
-
-
a
n
= cos
n
2
u
n
lim
4
n
(1 a
n
)
n
lim
4
n
|
.
|
\
| u
n
2
cos 1
18
18
n
lim
4
n
2sin
2

1 n
2
+
u
n
lim

1 n 1 n
1 n
2 n 2
2 2
2
sin 2 2
+ +
+
u
u
u

1 n 1 n
2 2
+ +
u
u
n
lim

2
2
u
1 n 1 n
1 n
2
2 2
2
sin
+ +
+
u
u
u
=
2
2
u
.
86. f(x) = (sin x)
sinx
f(x) =
x sin log x sin
e
Minimum value of sinxlog(sinx) is 0.
Maximum value of (sin x)
sinx
is e
0
= 1.
Maximum value of sinxlog(sinx) is
e
1
.
Minimum value of (sin x)
sinx
is
e
1
e
.
87.
}
10
1
dx
x
1
= | | x log
10
1
= log10 = 2.303
B = 1 +
2
1
+ ....+
9
1
= 1 + 0.5 + 0.33 + 0.25 + 0.20 + 0.16 + 0.14 + 0.12 + 0.11 ~ 2.81
C =
2
1
+ ....+
9
1
+
10
1
~ 2.81 1 + 0.1 =1.91
So, C < A < B and B A ~ 0.51, A C = 2.303 1.91 ~ 0.40. So, B A > A C.
88.
r
r r
r
60
60
r
r
A B
C
D
As we want the distance between two point is at least r. Now when the point A, B are at distance r.Then
the angle made arc BA is 60.
Now as chord AB come closer to centre the length of chord AB is increased that is it is greater than r and
the angle is also increases i.e. from 60 to 180 and now when chord AB move way from centre then the
length of chord AB decreases , when chord AB reach CD the length of AB equal to r and the angle chang
from 180 to 60
19
19
So, the angle required for desired conditions = 2(180 60) = 240
Total angle for all around the circle = 360
So, required propability =
360
240
=
3
2
89. Let a
N
be p
th
digit no.
So
1 5
) 5 ( 4
1 P
< N s
1 5
) 1 5 ( 4
P
2 10
P1
< a
N

s
9
8
(10
P
1)
5
P1
1 < N s 5
P
1
min
N
N log
a log
|
|
.
|
\
|
=
) 1 5 ln(
) 10 2 ln(
P
1 P
=
5 ln 5 10
) 1 5 ( ) 10 (ln 10
P 1 P
P 1 P
=
5 ln
10 ln
=
10
5
log
max
N
N log
a log
|
|
.
|
\
|
=
) 1 5 ln(
) 1 10 (
9
8
ln
1 P
P
=
5 ln 5 ) 1 10 (
9
8
) 1 5 ( 10 ln 10
9
8
1 P P
1 P P
=
10
5
log
By sandwitch therom limit is
10
5
log .
90. S =
s s s n j i 1
| j i |
= |11| + |1 2| + -------- |1n| =
2
n ) 1 n (
|2 2| + -------- |2 n| =
2
) 1 n )( 2 n (
.......
S =
=
+
N
1 r
2
) 1 r n )( r n (
=
3
C
1 n +
PHYSICS
91. Mass of sphere of radius r
m =
3
3
R
Mr
|
|
|
|
.
|
\
|
=
t
3
R
3
4
M
X
cm
=
m M
) r R ( m 0 M

|
|
|
|
.
|
\
|
=
t
t
m
R 3 / 4
M r
3
4
3
3
X
cm
=
|
|
.
|
\
|

3
3
3
3
R
M R
M ) r R (
R
Mr
20
20
=
) r rR R )( r R (
) r R ( r
R
r R
R
) r R ( r
2 2
3
3
3 3
3
3
+ +

=
|
|
.
|
\
|

X
cm
=
2 2
3
r rR R
r
+ +
92. For planeo convex lens
R
1
) 1 (
F
1
L
=
F
L
=
1
R

Refraction through less
u
1
R
1
V
1
+

=
This v must be centre of mirror

u
1
1 r
R
1
R
1
+
|
.
|
\
|
= u =
R
93. In cyclic process Au = 0
Au =AW = Area of loop
= (P
1
P
2
) (V
2
V
1
)
94. On comparing both the figures
x =
R 6 ) x R (
) R 6 )( x R (
+ +
+
x
2
+ xR

6R
2
= 0
x =
2
) R 6 4 ( R x
2 2
+
x = R 2
2
R 5 R
=
+
95. Torque about point A
R sin mg MR MR
5
2
2
2
u = o |
.
|
\
|
+
f
A
O
o =
R 7
sin g 5 u
Applying Newtons law,
Ma = Mgsinu Mgcosu
gcosu > gsinu
7
sin g 5 u
gcosu >
7
sin g 2 u
u = tan
1

2
7
Velocity of sound =
M
RT
T | Velocity of sound +
21
21
96.
H
F
a/2
A
mg
For height greater than H
Balancing torque about point A
F H =
2
a
mg .........(1)
For height less than H
F = gh .........(2)
From (1) and (2)
=
H 2
a
97.
mV /r
2
mg
N
(
(
u + u + u = u sin
r
mv
cos mg sin mg cos
r
MV
2 2
sinu
(
(

+
r
V
g
2
= cosu
(
(

r
V
g
2
tanu =
rg V
rg V
2
2
+

98.
3
5
4
S
1
S
2
Path difference = 5 4 = 1 m
For constructive interference
n
1
= 1m
For destructive interference
For n = 1,
1
= 1m,
2
= 2m
m 1
2
) 1 n 2 (
2
=

22
22
99. Two small blocks slide without losing contact with the surface along two frictionless tracks 1 and 2,
starting at the same time with same initial speed v. Track 1 is perfectly horizontal, while track 2 has a
dip in the middle, as shown.
1
2
V
V
Finish Start
Which block reaches the finish line first ?
[Hint : Use velocity-time graph to solve]
(A) Block on track 1 reaches the finish line first
(B*) Block on track to reaches the finish line first
(C) Both blocks reach the finish line at the same time
(D) It depends on the length of the dip in the second track, relative to the total length of the tracks.
100. AQ = Au + PAV (1
st
law of thermodynamics )
m
v
= Au + 1.01 10
5
(
3
10
1
8 . 1 / 1
1
)
Au
~
20.8 10
5
J kg
1
CHEMISTRY
101. Millimoles of NH
4
OH in 10 ml of 0.1 M NH
4
OH solution = 0.1 10 = 1
millimoles of NH
4
Cl in 10 ml of 1M NH
4
Cl solution = 1 10 = 10
pOH = pK
b
+ log
] Base [
] Salt [
6 = pK
b
+ log
10 10 / 1
10 10 / 10
+
+
[ pOH = 14 pH = 14 8 = 6]
6 = pK
b
+ log10
pK
b
= 6 1
pK
b
= 5
102. 2C
4
H
10
+ 13O
2
8CO
2
+ 10H
2
O AH = 2658 kJ/mol
Butane present in cylinder = 11.6 kg
= 11600 g
=
58
11600
mol
Combustion of 1 mol of C
4
H
10
gives = 2658 kJ energy
Combustion of 11600/58 mol of C
4
H
10
gives =
58
11600 2658
kJ
= 531600 kJ energy
energy consumes in 1 day = 15000 kJ
so 531600 kJ energy will be consumed in =
15000
531600

~
35 days
103. W = d V = 0.879 50 = 43.95 , K
f
= 5.12 Kg kg mol
1
= 5120K g mol
1
AT
f
=
mW
w K
o f
5.51 5.03 =
95 . 43 m
643 . 0 5120

m =
096 . 21
16 . 3292
m = 156 g mol
1
23
23
104. Zn + 2Ag
+
Zn
2+
+ 2Ag
(0.04M) (0.28M)
E
cell
= E
n
059 . 0
log
] Zn [ ] Ag [
] Ag ][ Zn [
2
2 2
+
+
E
cell
= 2.57
2
059 . 0
log
1 ) 04 . 0 (
1 28 . 0
2
2
{ [Ag] = [Zn] = 1}
by solving the equation we get
E
cell
~ 2.50 V
105. Co + Con. HCl
2+
CoCl
4
2
HOH
(excess)
[Co(H O) ]
2 6
2+
Pink
106. ln k =
T
11067
+ 31.33
2.303 log k =
T
11067
+ 31.33
suppose k
1
and T
1
are rate constant and temperature in case-I
and k
2
and T
2
are rate constant and temperature in case-II
So, 2.303 log k
1
=
1
T
11067
+ 31.33 --------- (1)
2.303 log k
2
=
2
T
11067
+ 31.33 --------- (2)
by subracting equation (2) from equation (1)
2.303 log
2
1
k
k
= 11067
|
|
.
|
\
|
2 1
T
1
T
1
2.303 log
1
1
k 2
k
= 11067
|
|
.
|
\
|
2
T
1
298
1
[ k
2
= 2k
1
]
2.303 (0.3010) =
2
T
11067
298
11067
+
by solving the above equation we get
T
2
~ 303.7 K
T
2
~ 31C
24
24
107. K
1
=
] Br ][ CuCl [
] Cl ][ Br CuCl [
2
4
2
3
------- (i)
K
2
=
] Br ][ Br CuCl [
] Cl ][ Br CuCl [
2
3
2
2 2
------- (ii)
K
3
=
] Br ][ Br CuCl [
] Cl ][ CuClBr [
2
2 2
2
3
------- (iii)
K
4
=
] Br ][ CuClBr [
] Cl ][ CuBr [
2
3
2
4
------- (iv)
equilibrium constant for given equation
K =
3 2
4
3 2
3
] Br ][ CuCl [
] Cl ][ CuClBr [
------- (v)
by multiplying the right hand side of equation (i), (ii) and (iii) we get right hand side of equation (v)
it means K = K
1
K
2
K
3
108.
OH
Br in CS
2 2
HBr
Br
NaOH
H O
2
OH
Br
ONa
MeI NaI
Br
OMe
(X)
(Y)
109. e y He x Pb Th
0
1
4
2
206
82
234
90
+ +
By comparing mass no.
234 = 206 + 4x + oy
x = 7
By comparing nuclear charge
90 = 82 + 2x 1y
y = 82 + 2 7 90
y = 6
110.
O
AlCl
3
I
2
/NaOH
OH OH
II
O
Me
II
O
Me
II
O
OH
Haloform
reaction
fries
rearrangement

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1

Pre-foundation Career Care Programmes (PCCP) Division

Therefore, a vector which bisects the angle is 13 ( ) k 4 i 3

is weak ligand hence pairing of electrons is not

53. Suppose equilibrium constant for the following reaction is K

ions in 0.1 KOH solution

|a b| < c ...... (1) [Triangle inequalities]

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