Chapter 9: Phase Diagrams III: The Fe - Fe C Phase Diagram: Issues To Address..
Chapter 9: Phase Diagrams III: The Fe - Fe C Phase Diagram: Issues To Address..
Chapter 9: Phase Diagrams III: The Fe - Fe C Phase Diagram: Issues To Address..
When we combine iron and carbon what kinds of steels do we get? In particular, if we specify the composition, what kinds of microstructures are created & how do they control the properties Steel is the most important structural material created by humans so what is the terminology of the Fe-Fe3C diagram & microstructures What are these microstructures, how are they created, what are their properties, and what applications are they used for?
Chapter 9 - 1
Chapter 9 -
Chapter 9 -
Cast Irons
Steels
Chapter 9 -
The Worlds First First Cast Iron Bridge, 1-1-1781 Ironbridge, Shropshire, England
Chapter 9 -
Monadnock Building, 1891-1893 Chicago The First Steel Skyscraper, AT Least of It Was
Chapter 9 -
Chapter 9 -
Chapter 9 -
Iron-Carbon (Fe-C) Phase Diagram and Steel Microstructures 2 important points - Eutectic (A):
L + Fe3C T(C)
1600
A
+Fe3C
- Eutectoid (B):
+ Fe3C
L+Fe3C
727C = T eutectoid
+Fe3C 0.76
1 2 3 4
120 m
4.30
6.7
C, wt% C
727 C
Second 2 or 3 numbers give %C content x 100 YY80 has 0.80 wt% C YY100 has 1.0 wt.% C
Chapter 9 -
Chapter 9 -
Chapter 9 -
Chapter 9 -
.
Chapter 9 -
100 m
Hypoeutectoid steel
pearlite
proeutectoid ferrite
Chapter 9 -
100 m
Hypoeutectoid steel
pearlite
proeutectoid ferrite
Chapter 9 -
Hypereutectoid Steel
T(C)
1600
1400
L
1148C
+Fe3C
Fe3C (cementite)
Fe3C
+L 1200 (austenite)
0.76 1 C0 2 3
+Fe3C
4 5 6
6.7
Adapted from Figs. 9.24 and 9.32,Callister & Rethwisch 8e. (Fig. 9.24 adapted from Binary Alloy Phase Diagrams, 2nd ed., Vol. 1, T.B. Massalski (Ed.-in-Chief), ASM International, Materials Park, OH, 1990.)
C, wt%C
60 mHypereutectoid steel
pearlite
proeutectoid Fe3C
Chapter 9 - 17
Activity Identify and Describe Microstructural Components in Steels that are Hypoeutectoid, Eutectoid, & Hypereutectoid
For each micrograph identify each microstructural component by: 1) Labeling each one, 2) Describing each one, & 3) Stating how each got there
Chapter 9 -
Teutectoid + 1 C
Teutectoid + 1 C
727C 727C
Describe how the microstructure developed Describe how the microstructure developed
0.76
Teutectoid + 1 C Teutectoid - 1 C
Teutectoid - 1 C
Teutectoid - 1 C
Describe how the microstructure developed Describe how the microstructure developed Describe how the microstructure developed
Chapter 9 -
Summary
The phase diagram of steel helps explain microstructure & properties: Given the temperature and composition of the system. -- number and types of phases present, -- composition of each phase, -- weight fraction of each phase For steel the most important phase transformation is the eutectoid Steels with %C less thatn, equal to, and greater than the euectoid composition are call hypoeutectoid, eutectoid, & hypereutectoid The microstructure of hypoeutectid steels contain proeutecoid ferrite & the microstructure of hypereuteoid steels contain proeutectoid carbide & the microstructure of eutectoid steel contains pearlite The microstructures and associated properties of steel depend on -- its composition, and -- the manner in which it was cooled.
Chapter 9 - 20
1.
For a 0.30 wt% C steel (1030) at 728C and then at 726C, identify the phases present, the chemical composition of each phase, the fraction of each phase, and draw the microstructure and label the components of the microstructure. For a 1.20 wt% C steel (10120) at 728C and then at 726C, identify the phases present, the chemical composition of each phase, the fraction of each phase, and draw the microstructure and identify the components of the microstructure The microstructure of the reinforcing rod of Frank Lloyds Fallingwater house in Pennsylvania was studied and is shown at the right. Specify the microstructural components present and the wt% C in the steel.
2.
3.
4. The properties of steels are controlled by the carbon content, the alloy content, and the thermal treatment. When a steel is cooled faster from the gamma (austenite region) below the eutectoid temperature, the lamellar, alternating platelets of ferrite and carbide in pearlite get thinner and are more closely spaced. Why do you think that this is so? What do you think will happen to the strength and ductility of the steel which has been cooled faster and why do you think that is so? Chapter 9 -
Point of Interest:
Muddiest Point:
Very Much
Learning Point:
Chapter 9 - 22