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Endohedral actinide fullerenes are rare and a little is known about their molecular properties. Here we characterize U2@C80 system, which was recently detected experimentally by means of mass spectrometry (Akiyama et al., JACS 2001,... more
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      Materials ScienceChemistryComputational ChemistryInorganic Chemistry
The syntheses, structures and optical properties of polymethylene-vaulted trans-bis(2-aminotroponato) palladium(II) complexes are described. A series of Pd complexes incorporating nona-, deca-, undeca-and dodecamethylene bridges (1a: n ¼... more
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      Inorganic ChemistryOrganometallic ChemistryOrganometalic Chemistry
The palladium−nickel binary nanocluster is reported as a new catalyst system for Suzuki−Miyaura cross-coupling of orthoheterocycle- tethered sterically hindered aryl bromides. The inferior results obtained with the reported Pd/Ni... more
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      Suzuki Miyaura cross-couplingNano CatalystOrganometalic Chemistry
ArN᎐ ᎐ V(NMe 2 ) 2 (HNMe 2 ) 2 1 and ArN᎐ ᎐ VCl 2 (HNMe 2 ) 2 2 (Ar ‫؍‬ 2,6-i-Pr 2 C 6 H 3 ) is described along with the molecular structure of 2 and preliminary ethylene polymerization catalytic studies.
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      Inorganic ChemistryPolymer ChemistryCatalysisOrganometalic Chemistry
Catalysis is an important field in both academic and industrial research because it leads to more efficient reactions in terms of energy consumption and waste production. The common feature of these processes is a catalytically active... more
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      Inorganic ChemistryOrganic ChemistryOrganic SynthesisComplexes
Mixed ligand complexes of bivalent metal ions, viz ; M= Co(II),Ni(II),Cu(II), Zn(II), Cd (II), and Hg(II) of the composition [M(Anth) 2 (TMP)] in 1:2:1 molar ratio, (where. AnthrH= Anthranilic acid (C 7 H 7 NO 2) and Trimethoprime (TMP) =... more
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    • Organometalic Chemistry
Heterometallic alkoxides are those alkoxides having two or more different metals linked via bridging alkoxy groups, via oxo-groups or sometimes metal-metal bonding. The large majority of heterometallic alkoxides corresponds to derivatives... more
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      Sol-Gel TechnologyMetal-organic chemistryMetal alkoxidesSol-gel Synthesis