Fertilizante Calmax

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TERESOPOLIS SA

Hoja de Seguridad – CALMAX®

1.- Nombre: CALMAX


Fórmula: CaSO4.2(H2O)
Sulfato de Calcio Grado Agricola

2. - Propiedades Químicas: Ver información adjunta

3.- Propiedades Físicas: Ver información adjunta

4. - Toxicidad: No tóxico (Ver Información adjunta)

5. - Reactividad: Cero (ver información adjunta)

6. - Tolerancia e intervalos No hay fecha límite de aplicación.


de pre - cosecha

7. - Modo de acción Como fuente de calcio y azufre


como enmienda de suelo
como enmienda de agua

8. - Absorción y transporte Al ser un producto soluble en el agua de riego el


calcio y el azufre son rápidamente tomados por las
raíces y transportados a los sitios de acción de la planta

9 .- Efectos sobre Patógenos El calcio es esencial en la formación de paredes sanas


lo que las hace resistentes a enfermedades y plagas.

10. - Efectos de Actividad Sulfato contenido en el CALMAX, convierte el sodio en sulfato de


sodio fácilmente lavable.
El calcio de CALMAX, desplaza del bulbo radicular, al sodio.
El azufre promueve la formación de clorofila y de nódulos fijadores
de nitrógeno en las raíces.

11 .- Recomendaciones de Uso:
Como fertilizante : 80 kg para completar 20 unidades de Calcio.

Como enmienda: de 200 a 400 kg /ha (dependiendo del PSI )

12.- Almacenamiento: Las bolsas de CALMAX se colocaran en un lugar seco y ventilado


no deben apilarse mas de 10 bolsas una sobre otra.
Las condiciones deben ser como para cualquier fertilizante.

13. - Para cualquier información adicional puede contactarse con la Ing. Estefanía Figueroa, Representante de la

División Agrícola de TERESOPOLIS S.A.

E \mail. [email protected]
Teléfonos: (01) 995564050

14.- Adjuntamos hojas de seguridad donde aparece el nombre de BEN FRANKLIN Aguacal, el cual es el nombre original
del producto en USA. Lamentablemente una empresa registro otro producto con ese nombre antes que USG
introduzca su producto en Perú. Por esta razón el producto se registro en el Perú con el nombre de
CALMAX.
MATERIAL SAFETY DATA SHEET
CALMAX®
SECTION 1
CHEMICAL PRODUCT AND IDENTIFICATION

E. Canaval Moreyra 425 Of. 34 - Lima 27, Perú - tel: 511-221-5334


CEL.995564050
PRODUCT: CALMAX® Sulfato de Calcio Grado Agricola
CHEMICAL FAMILY: Calcium Sulfate Dihydrate (CaSO4•2H2O).

SECTION 2
COMPOSITION, INFORMATION ON INGREDIENTS
MATERIAL WT% TLV (mg/m3) PEL( mg/m3) CAS NUMBER
Gypsum (CaSO4•2H2O) 100 10 15(T)/5(R) 13397-24-5
Crystalline Silica <1 0.05(R) 0.1(R) 14808-60-7
(T) – Total (R) – Respirable (NE) – Not Established mmpfc - million particles per cubic foot of air
Respirable crystalline silica: IARC: Group 1 carcinogen, NTP: Known human carcinogen. The weight percent for silica
represents total quartz and not the respirable fraction. Testing of dust from USG gypsum powders has not detected
respirable crystalline silica.
Food and Drug Administration [CFR Title 21, v.3, sec 184.1230] – Calcium Sulfate is Generally Recognized as Safe
(GRAS).
All ingredients of this product are included in the U.S. Environmental Protection Agency’s Toxic Substances Control Act
Chemical Substance Inventory. All components of this product are included in the Canadian Domestic Substances List
(DSL).

SECTION 3
HAZARD IDENTIFICATION

POTENTIAL HEALTH EFFECTS


ACUTE (continued):
Inhalation: Dust exposures generated during the handling of the product may irritate eyes, skin, nose, throat, and
upper respiratory tract. Persons subjected to large amounts of this dust will be forced to leave area because of
nuisance conditions such as coughing, sneezing and nasal irritation. Labored breathing may occur after excessive
inhalation. If respiratory symptoms persist, consult physician.
Ingestion: If ingested may cause temporary irritation to the gastrointestinal tract, especially the stomach. No known
effects.
CHRONIC:
Eyes: None known.
Skin: None known.
Ingestion: No known effects.
Inhalation: Testing of dust from USG gypsum powders has not detected respirable crystalline silica. Exposures to
respirable crystalline silica are not expected during the normal use of this product; however, actual levels must be
determined by workplace hygiene testing.
Prolonged and repeated exposure to airborne free respirable crystalline silica can result in lung disease (i.e., silicosis)
and/or lung cancer. The development of silicosis may increase the risks of additional health effects. The risk of
developing silicosis is dependent upon the exposure intensity and duration.
TARGET ORGANS: Eyes, skin and respiratory system.

PRIMARY ROUTES OF ENTRY: Inhalation, eyes and skin contact.

SECTION 4
FIRST AID MEASURES
FIRST AID PROCEDURES
Eyes: In case of contact, do not rub or scratch your eyes. Flush thoroughly with water for 15 minutes to remove
particles. If irritation persists, consult physician.
Skin: Wash with mild soap and water. A commercially available hand lotion may be used to treat dry skin areas. If skin
has become cracked, take appropriate action to prevent infection and promote healing. If irritation persists, consult
physician.
Inhalation: Remove to fresh air. Leave the area of dust exposure and remain away until coughing and other symptoms
subside. Other measures are usually not necessary, however if conditions warrant, contact physician.
Ingestion: This product is not intended to be ingested or eaten. No harmful effects expected. No specific
recommendations. If gastric disturbance occurs, call physician.
MEDICAL CONDITIONS WHICH MAY BE AGGRAVATED: Pre-existing upper respiratory and lung diseases such as,
but not limited to, bronchitis, emphysema and asthma. Pre-existing skin diseases such as, but not limited to, rashes
and dermatitis.

SECTION 5
FIRE FIGHTING MEASURES.

General Fire Hazards: Not expected to burn.


Extinguishing Media: Water or use extinguishing media appropriate for surrounding fire.
Special Fire Fighting Procedures: Wear appropriate personal protective equipment (See section 8).
Unusual Fire & Explosion Hazards: None
Hazardous Combustion Products: Above 1450º C - decomposes to calcium oxide (CaO) and sulfur dioxide (SO2)
Flash Point: None Known Auto Ignition: Not Applicable
Method Used: Not Applicable
Upper Flammable Limit (UFL): Not Applicable
Flammability
Classification: Not Applicable
Lower Flammable Limit (LFL): Not Applicable Rate of Burning: Not Applicable.

SECTION 6
ACCIDENTAL RELEASE MEASURES
CONTAINMENT:
No special precautions. Wear appropriate personal protection (See Section 8).
CLEAN-UP:
Use normal clean up procedures. Wear appropriate protective equipment. Ventilate area. If dry, shovel or sweep up
material from spillage and place collected material into a container for recovery or waste disposal. Avoid dust
generation. Avoid inhalation of dust and contact with eyes and skin. Maintain proper ventilation. If vacuum is used to
collect dust, use an industrial vacuum cleaner with a high efficiency air filter. If sweeping is necessary, use dust
suppressant. Do not use compressed air for clean up. These procedures will help minimize potential exposures. If
washed down, may plug drains.
DISPOSAL:
Follow all local, state, provincial and federal regulations. Never discharge large releases directly into sewers or surface
waters. Trace amounts of residue can be flushed to a drain, using plenty of water.
SECTION 7

HANDLING AND STORAGE


HANDLING:
Minimize dust generation and accumulation. Avoid breathing dust. Wear the appropriate respiratory protection
against dust in poorly ventilated areas and if TLV is exceeded (see Sections 2 and 8). Avoid dust contact with eyes.
Wear the appropriate eye protection against dust (See Section 8).
Use good safety and industrial hygiene practices.

STORAGE:
Store at room temperature in a dry location.
Keep containers closed when not in use

SECTION 8

EXPOSURE CONTROLS / PERSONAL PROTECTION


ENGINEERING CONTROLS:
Provide ventilation sufficient to control airborne dust levels especially respirable crystalline silica.
If user operations generate airborne dust, use ventilation to keep dust concentrations below permissible exposure
limits
(See Section 2).
Where general ventilation is inadequate, use process enclosures, local exhaust ventilation, or other engineering
controls to control dust levels below permissible exposure limits (see Section 2). If engineering controls are not
possible, wear a properly fitted NIOSH/MSHA-approved particulate respirator.

RESPIRATORY PROTECTION:
Wear a NIOSH/MSHA-approved respirator equipped with particulate cartridges when dusty in poorly ventilated areas,
and if TLV is exceeded. A respiratory program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements must
be followed whenever workplace conditions warrant a respirator's use.

OTHER PERSONAL PROTECTIVE EQUIPMENT:


Eye/Face: Wear eye protection (safety glasses or goggles) to avoid particulate irritation of the eye.

Skin: Gloves or protective clothing are usually not necessary but may be desirable in specific work situations. For brief
contact, no precautions other than clean body-covering clothing should be needed. Wear gloves and protective
clothing to prevent repeated or prolonged skin contact. Barrier creams or skin lotion may be applied to face, neck,
wrist and hands when skin is exposed to help prevent drying of skin.

General: Selection of Personal Protective Equipment will depend on environmental working conditions and
operations.
SECTION 9
PHYSICAL AND CHEMICAL PROPERTIES

SECTION 10

CHEMICAL STABILITY AND REACTIVITY


STABILITY: Stable.
CONDITIONS TO AVOID: Contact with incompatibles.
INCOMPATIBILITY: None known.
HAZARDOUS POLYMERIZATION: Will not occur.
HAZARDOUS DECOMPOSITION: Above 1450º C - decomposes to calcium oxide (CaO) and sulfur dioxide (SO2)

SECTION 11

TOXICOLOGICAL INFORMATION
ACUTE EFFECTS:
Direct contact may cause eye, skin and/or respiratory irritation.
LD50: Not Available for product. LC50: Not Available for product.

CHRONIC EFFECTS / CARCINOGENICITY:

Crystalline silica: Testing of dust from USG gypsum powders has not detected respirable crystalline silica. Exposures to
respirable crystalline silica are not expected during the normal use of this product; however, actual levels must be
determined by workplace hygiene testing.

Prolonged and repeated exposure to airborne free respirable crystalline silica can result in lung disease (i.e., silicosis)
and/or lung cancer. The development of silicosis may increase the risks of additional health effects. The risk of
developing silicosis is dependent upon the exposure intensity and duration.

In June, 1997, IARC classified crystalline silica (quartz and cristobalite) as a human carcinogen. In making the overall
evaluation, the IARC Working Group noted that carcinogenicity in humans was not detected in all industrial
circumstances studied. Carcinogenicity may be dependent on inherent characteristics of the crystalline silica or on
external factors affecting its biological activity or distribution of its polymorphs.

IARC states that crystalline silica inhaled in the form of quartz or cristobalite from occupational sources is carcinogenic
to humans (Group 1).

SECTION 12

ECOLOGICAL INFORMATION
ENVIRONMENTAL TOXICITY: This product has no known adverse effect on the ecology. A large discharge directly into
waterways would not be expected to kill aquatic life.
Ecotoxicity value: Not determined.
SECTION 13

DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD:
Dispose of material in accordance with Federal, State, Provincial, and Local regulations. Consult with environmental
regulatory agencies for guidance on acceptable disposal practices. Never discharge directly into sewers or surface
waters.

SECTION 14
TRANSPORT INFORMATION
SECTION 15
REGULATORYAINFORMATION

NTP – National Toxicology Program (Health and Human Services Dept., Public Health Service, NIH/NIEHS)
1- Known to be carcinogen
2- Anticipated to be carcinogens
ACGIH – American Conference of Governmental Industrial Hygienists
A1 – Confirmed human carcinogen
A2 – Suspected human carcinogen
A3 – Animal carcinogen
A4 - Not classifiable as a carcinogen
A5 – Not suspected as a human carcinogen
CAL-65 – California Proposition 65 “Chemicals known to the State of California to Cause Cancer”
SECTION 16

OTHER INFORMATION
Label Information
ΔWARNING!
Dust created from product may cause eye, skin, nose, throat or upper respiratory irritation. Avoid inhalation of dust
and eye contact. Use in a well-ventilated area. Wear a NIOSH/MSHA-approved respirator when dusty. Use proper
ventilation to reduce dust exposure. Wear eye protection. If eye contact occurs, flush thoroughly with water for 15
minutes. If irritation persists, call physician. Wash thoroughly with soap and water after use. Do not ingest. If ingested
call physician.
Product safety information: or [email protected]

KEEP OUT OF REACH OF CHILDREN.


Key/Legend
TLV Threshold Limit Value
PEL Permissible Exposure Limit
CAS Chemical Abstracts Service (Registry Number)
NIOSH National Institute for Occupational Safety and Health
MSHA Mine Safety and Health Administration
OSHA Occupational Health and Safety Administration
ACGIH American Conference of Governmental Industrial Hygienists
IARC International Agency for Research on Cancer
DOT United States Department of Transportation
EPA United States Environmental Protection Agency
NFPA National Fire Protection Association
HMIS Hazardous Materials Identification System
PPE Personal Protection Equipment
TSCA Toxic Substances Control Act
DSL Canadian Domestic Substances List
NDSL Canadian Non-Domestic Substances List
SARA Superfund Amendments and Reauthorization Act of 1986
RCRA Resource Conservation and Recovery Act
CERCLA Comprehensive Environmental Response, Compensation and Liability Act of 1980
UN/NA# United Nations/North America number
CFR Code of Federal Regulations
WHMIS Workplace Hazardous Material Information System

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