SD 511 en
SD 511 en
SD 511 en
Warning
Hazard statements
H226 Flammable liquid and vapour.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H317 May cause an allergic skin reaction.
H373 May cause damage to organs through prolonged or repeated exposure.
H411 Toxic to aquatic life with long lasting effects.
Precautionary statements
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P241 Use explosion-proof electrical equipment.
P260 Do not breathe vapour.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower].
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)
according to Regulation (EU) 2015/830
Protective measures
After contact clean skin thoroughly with water and soap or use appropriate cleanser.
Environmental exposure controls
Do not allow to enter into surface water or drains. See chapter 7. No additional measures necessary.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Appearance:
Physical state: Liquid
Colour: refer to label
Odour: characteristic
Odour threshold: not applicable
pH at20 °C: n.a.
Melting point/freezing point: not applicable
Initial boiling point and boiling range: -19 °C
Source: Formaldehyde
Flash point: 24 °C
Evaporation rate: not applicable
Flammability (solid, gas):
Burning time (s): not applicable
Upper/lower flammability or explosive limits:
Lower explosion limit: 1,15 Vol-%
Upper explosion limit: 13,1 Vol-%
Source: 1-methoxy-2-propanol
Vapour pressure at20 °C: 2,493 mbar
Vapour density: not applicable
Relative density:
Density at20 °C: 1,48 g/cm³
Solubility(ies):
Water solubility (g/L) at20 °C: insoluble
Partition coefficient: n-octanol/water: see section 12
Auto-ignition temperature: 270 °C
Source: 1-methoxy-2-propanol
Decomposition temperature: not applicable
Viscosity at20 °C: > 3500 mPa·s
Keep away from strong acids, strong bases and strong oxidizing agents to avoid exothermic reactions.
10.4. Conditions to avoid
Hazardous decomposition byproducts may form with exposure to high temperatures.
10.5. Incompatible materials
No information available.
10.6. Hazardous decomposition products
Hazardous decomposition byproducts may form with exposure to high temperatures, e.g.: carbon dioxide, carbon monoxide,
smoke, nitrogen oxides.
SECTION 11: Toxicological information
Classification according to Regulation (EC) No 1272/2008 [CLP]
No data on preparation itself available.
11.1. Information on toxicological effects
Acute toxicity, calculated:
ATEmix calculated, dermal: > 5000 mg/kg
ATEmix calculated, inhalative (vapours): > 20 mg/l
Acute toxicity
n-butyl acetate
oral, LD50, Rat: 14000 mg/kg
skin corrosion/irritation; Serious eye damage/eye irritation
Based on available data, the classification criteria are not met.
Respiratory or skin sensitisation
Based on available data, the classification criteria are not met.
CMR effects (carcinogenicity, mutagenicity and toxicity for reproduction)
Based on available data, the classification criteria are not met.
Specific target organ toxicity
Based on available data, the classification criteria are not met.
Practical experience/human evidence
Other observations:
Inhaling of solvent components above the MWC-value can lead to health damage, e.g. irritation of the mucous membrane
and respiratory organs, as well as damage to the liver, kidneys and the central nerve system. Indications for this are:
headache, dizziness, fatigue, amyosthenia, drowsiness, in serious cases: unconsciousness. Solvents may cause some of the
aforementioned effects through skin resorption. Repeated or prolonged contact with the preparation may cause removal of
natural fat from the skin resulting in non-allergic contact dermatitis and/or absorption through skin. Splashing may cause eye
irritation and reversible damage.
Overall Assessment on CMR properties
The ingredients in this mixture do not meet the criteria for classification as CMR category 1A or 1B according to CLP.
Remark
There is no information available on the preparation itself .
SECTION 12: Ecological information
overall evaluation
Classification according to Regulation (EC) No 1272/2008 [CLP]
There is no information available on the preparation itself .
Do not allow to enter into surface water or drains.
12.1. Toxicity
Toxicological data are not available.
Long-term Ecotoxicity
Toxicological data are not available.
12.2. Persistence and degradability
No information available.
12.3. Bioaccumulative potential
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)
according to Regulation (EU) 2015/830
No information available.
Bioconcentration factor (BCF)
No information available.
12.4. Mobility in soil
No information available.
12.5. Results of PBT and vPvB assessment
The substances in the mixture do not meet the PBT/vPvB criteria according to REACH, annex XIII.
12.6. Other adverse effects
No information available.
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Appropriate disposal / Product
Recommendation
Do not allow to enter into surface water or drains. This material and its container must be disposed of in a safe way. Waste
disposal according to directive 2008/98/EC, covering waste and dangerous waste.
List of proposed waste codes/waste designations in accordance with EWC
080111 Waste paint and varnish containing organic solvents or other dangerous substances
packaging
Recommendation
Non-contaminated packages may be recycled. Vessels not properly emptied are special waste.
SECTION 14: Transport information
14.1. UN number
UN 1263
14.2. UN proper shipping name
Land transport (ADR/RID): Paint
Sea transport (IMDG): PAINT
Air transport (ICAO-TI / IATA-DGR): Paint
14.3. Transport hazard class(es)
3
14.4. Packing group
III
14.5. Environmental hazards
Land transport (ADR/RID) UMWELTGEFÄHRDEND
Marine pollutant p / reaction product: bisphenol-A-(epichlorhydrin)
14.6. Special precautions for user
Transport always in closed, upright and safe containers. Make sure that persons transporting the product know what to do in
case of an accident or leakage.
Advices on safe handling: see parts 6 - 8
Further information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU legislation
Directive 2010/75/EU on industrial emissions
VOC-value (in g/L): 410
National regulations
Restrictions of occupation
Observe employment restrictions under the Maternity Protection Directive (92/85/EEC) for expectant or nursing mothers.
Observe restrictions to employment for juvenils according to the 'juvenile work protection guideline' (94/33/EC).
Other regulations, restrictions and prohibition regulations
15.2. Chemical Safety Assessment
For the following substances of this preparation a chemical safety assessment has been carried out:
EC No. Chemical name REACH No.
CAS No.
215-535-7 Xylene 01-2119488216-32
1330-20-7
231-944-3 trizinc bis(orthophosphate) 01-2119485044-40
7779-90-0
203-539-1 1-methoxy-2-propanol 01-2119457435-35
107-98-2
204-658-1 n-butyl acetate 01-2119485493-29
123-86-4
215-222-5 zinc oxide 01-2119463881-32
1314-13-2
SECTION 16: Other information
Full text of classification in section 3:
Skin Irrit. 2 / H315 skin corrosion/irritation Causes skin irritation.
Eye Irrit. 2 / H319 Serious eye damage/eye irritation Causes serious eye irritation.
Skin Sens. 1 / H317 Respiratory or skin sensitisation May cause an allergic skin reaction.
Acute Tox. 4 / H312 Acute toxicity (dermal) Harmful in contact with skin.
Acute Tox. 4 / H332 Acute toxicity (inhalative) Harmful if inhaled.
STOT SE 3 / H335 Specific target organ toxicity (single May cause respiratory irritation.
exposure)
STOT RE 2 / H373 Specific target organ toxicity (repeated May cause damage to organs (or state all
exposure) organs affected, if known) through prolonged or
repeated exposure (state route of exposure if it
is conclusively proven that no other routes of
exposure cause the hazard).
Asp. Tox. 1 / H304 Aspiration hazard May be fatal if swallowed and enters airways.
Flam. Liq. 3 / H226 Flammable liquids Flammable liquid and vapour.
Aquatic Acute 1 / H400 Hazardous to the aquatic environment Very toxic to aquatic organisms.
Aquatic Chronic 1 / H410 Hazardous to the aquatic environment Very toxic to aquatic life with long lasting
effects.
STOT SE 3 / H336 Specific target organ toxicity (single May cause drowsiness or dizziness.
exposure)
Abbreviations and acronyms
ADR Accord européen relatif au transport international des marchandises dangereuses par route (European
Agreement concerning the International Carriage of Dangerous Goods by Road)
AGW (WEL) Occupational Exposure Limit Value
CAS Chemicals Abstract Service
CLP Classification, Labelling and Packaging
CMR Carcinogenic, Mutagenic and Reprotoxic
DNEL Derived No-Effect Level
IATA-DGR International Air Transport Association – Dangerous Goods Regulations
ICAO-TI International Civil Aviation Organization Technical Instructions for the Safe Transport of Dangerous
Goods by Air
IMDG Code International Maritime Code for Dangerous Goods
PBT persistent, bioaccumulative, toxic
Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)
according to Regulation (EU) 2015/830
The information supplied on this safety data sheet complies with our current level of knowledge as well as with national and
EU regulations. Without written approval, the product must not be used for purposes different from those mentioned in
chapter 1. It is always the user's duty to take any necessary measures for meeting the requirements laid down by local rules
and regulations. The details in this safety data sheet describe the safety requirements of our product and are not to be
regarded as guaranteed attributes of the product.