The organometallic active site of [Fe]hydrogenase: models and entatic states (Q34915335)

5 August 2017

title

The organometallic active site of [Fe]hydrogenase: models and entatic states (English)

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5 August 2017

author

Marcetta Y. Darensbourg

series ordinal

1

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5 August 2017

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Erica J Lyon

2

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5 August 2017

Xuan Zhao

series ordinal

3

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5 August 2017

Irene P Georgakaki

series ordinal

4

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5 August 2017

language of work or name

English

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publication date

17 March 2003

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Proceedings of the National Academy of Sciences of the United States of America

5 August 2017

published in

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5 August 2017

volume

100

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5 August 2017

issue

7

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5 August 2017

page(s)

3683-3688

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Hydrogenase: a bacterial enzyme activating molecular hydrogen: The properties of the enzyme

5 August 2017

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1 reference

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8 July 2018

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Hydrogenases: hydrogen-activating enzymes

8 July 2018

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8 July 2018

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8 July 2018

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Modeling the active sites in metalloenzymes. 3. Density functional calculations on models for [Fe]-hydrogenase: structures and vibrational frequencies of the observed redox forms and the reaction mechanism at the Diiron Active Center

8 July 2018

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8 July 2018

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8 July 2018

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Binding of exogenously added carbon monoxide at the active site of the iron-only hydrogenase (CpI) from Clostridium pasteurianum

8 July 2018

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The crystal structure of a reduced [NiFeSe] hydrogenase provides an image of the activated catalytic center

8 July 2018

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8 July 2018

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8 July 2018

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8 July 2018

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8 July 2018

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8 July 2018

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Molecular hydrogen complexes: coordination of a .sigma. bond to transition metals

8 July 2018

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Crystallographic and FTIR spectroscopic evidence of changes in Fe coordination upon reduction of the active site of the Fe-only hydrogenase from Desulfovibrio desulfuricans.

21 January 2018

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A capable bridging ligand for Fe-only hydrogenase: density functional calculations of a low-energy route for heterolytic cleavage and formation of dihydrogen

21 January 2018

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21 January 2018

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Coordination sphere flexibility of active-site models for Fe-only hydrogenase: studies in intra- and intermolecular diatomic ligand exchange

21 January 2018

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Requirements for functional models of the iron hydrogenase active site: D2/H2O exchange activity in ((mu-SMe)(mu-pdt)[Fe(CO)2(PMe3)]2+)[BF4-].

21 January 2018

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Transient FTIR spectroelectrochemical and stopped-flow detection of a mixed valence (Fe(I)-Fe(II)) bridging carbonyl intermediate with structural elements and spectroscopic characteristics of the di-iron sub-site of all-iron hydrogenase.

26 October 2018

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Hydrogenase sophistication

26 October 2018

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Infrared studies of the CO-inhibited form of the Fe-only hydrogenase from Clostridium pasteurianum I: examination of its light sensitivity at cryogenic temperatures

21 January 2018

1 reference

12 December 2020

The pH dependence of proton-deuterium exchange, hydrogen production and uptake catalyzed by hydrogenases from sulfate-reducing bacteria

1 reference

12 December 2020

Iron carbonyl sulfides, formaldehyde, and amines condense to give the proposed azadithiolate cofactor of the Fe-only hydrogenases

1 reference

12 December 2020

Biomimetic hydrogen evolution catalyzed by an iron carbonyl thiolate

1 reference

12 December 2020

Infrared studies on the interaction of carbon monoxide with divalent nickel in hydrogenase from Chromatium vinosum

1 reference

12 December 2020

Reversible carbon monoxide binding and inhibition at the active site of the Fe-only hydrogenase

1 reference

12 December 2020

Carbon Monoxide and Cyanide Ligands in a Classical Organometallic Complex Model for Fe-Only Hydrogenase

1 reference

12 December 2020

A low-spin iron with CN and CO as intrinsic ligands forms the core of the active site in [Fe]-hydrogenases

1 reference

12 December 2020

Carbon Monoxide and Cyanide as Intrinsic Ligands to Iron in the Active Site of [NiFe]-Hydrogenases

1 reference

12 December 2020

1 reference

12 December 2020

Identifiers

DOI

10.1073/PNAS.0536955100

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5 August 2017

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5 August 2017

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