Lecture Presentation 04

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Chapter 4

Carbon and the


Molecular
Diversity of Life

Lecture Presentations by
Nicole Tunbridge and
© 2021 Pearson Education, Inc. Kathleen Fitzpatrick
Figure 4.1

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Figure 4.1a

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CONCEPT 4.1: Organic chemistry is key to the
origin of life
• Organic chemistry is the study of compounds that
contain carbon, regardless of origin
• Organic compounds range from simple molecules to
colossal ones

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Organic Molecules and the Origin of Life on
Earth
• Stanley Miller’s classic experiment demonstrated
the abiotic synthesis of organic compounds
• Experiments support the idea that abiotic synthesis
of organic compounds, perhaps near volcanoes,
could have been a stage in the origin of life

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Figure 4.2

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• The overall percentages of the major elements of
life—C, H, O, N, S, and P—are quite uniform from
one organism to another
• Because carbon can form four bonds, these
building blocks can be used to make an
inexhaustible variety of organic molecules
• The great diversity of organisms on the planet is
due to the versatility of carbon

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CONCEPT 4.2: Carbon atoms can form diverse
molecules by bonding to four other atoms
• Electron configuration is the key to an atom’s
chemical characteristics
• Electron configuration determines the kinds and
number of bonds an atom will form with other
atoms

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The Formation of Bonds with Carbon
• With four valence electrons, carbon can form four
covalent bonds with a variety of atoms
• This enables carbon to form large, complex
molecules
• In molecules with multiple carbons, each carbon
bonded to four other atoms has a tetrahedral shape
• However, when two carbon atoms are joined by a
double bond, the atoms joined to the carbons are
in the same plane as the carbons

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Figure 4.3

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• The number of unpaired electrons in the valence
shell of an atom is generally equal to its valence,
the number of covalent bonds it can form

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Figure 4.4

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• The electron configuration of carbon gives it
covalent compatibility with many different elements
• The most frequent bonding partners of carbon are
hydrogen, oxygen, and nitrogen

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Molecular Diversity Arising from Variation
in Carbon Skeletons
• Carbon atoms can partner with atoms other than
hydrogen, such as the following:
– Carbon dioxide: CO2
O O

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– Urea: CO(NH2)2

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– Carbon atoms can also be linked into chains as
shown for C3H8

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• Carbon chains form the skeletons of most organic
molecules
• Carbon chains vary in length and shape

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Figure 4.5

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Animation: Diversity of Carbon-Based
Molecules

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Hydrocarbons
• Hydrocarbons are organic molecules consisting of
only carbon and hydrogen
• Many organic molecules, such as fats, have
hydrocarbon components
• Hydrocarbons can undergo reactions that release a
large amount of energy

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Figure 4.6

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Isomers
• Isomers are compounds with the same molecular
formula but different structures and properties
– Structural isomers have different covalent
arrangements of their atoms
– Cis-trans isomers (also called geometric isomers)
have the same covalent bonds but differ in their
spatial arrangements
– Enantiomers are isomers that are mirror images
of each other

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Figure 4.7

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Animation: Isomers

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• Enantiomers are important in the pharmaceutical
industry
• Two enantiomers of a drug may have different
effects
• Often only one enantiomer is biologically active
• Differing effects of enantiomers demonstrate that
organisms are sensitive to even subtle variations
in molecules

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Figure 4.8

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CONCEPT 4.3: A few chemical groups are key to
molecular function
• Distinctive properties of organic molecules depend
on the carbon skeleton and the chemical groups
attached to it
• These groups help give each molecule its unique
properties

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The Chemical Groups Most Important in the
Processes of Life
• Estradiol and testosterone are both steroids with
a common carbon skeleton, in the form of four
fused rings
• These sex hormones differ only in the chemical
groups attached to the rings of the carbon skeleton

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UNF04-06

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• Functional groups are the components of organic
molecules that are most commonly involved in
chemical reactions
• The number and arrangement of functional groups
give each molecule its unique properties

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• The seven functional groups that are most
important in the chemistry of life are the following:
– Hydroxyl group
– Carbonyl group
– Carboxyl group
– Amino group
– Sulfhydryl group
– Phosphate group
– Methyl group

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Figure 4.9

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Animation: Functional Groups

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ATP: An Important Source of Energy for Cellular
Processes
• An important organic phosphate is adenosine
triphosphate (ATP)
• ATP consists of an organic molecule called
adenosine attached to a string of three phosphate
groups
• ATP stores the potential to react with water
• This reaction releases energy that can be used by
the cell

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UNF04-07

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UNF04-08

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The Chemical Elements of Life: A Review
• The versatility of carbon makes possible the great
diversity of organic molecules
• Variation at the molecular level lies at the
foundation of all biological diversity on our planet

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Figure 4.UN01a

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Figure 4.UN01b

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Figure 4.UN08

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Figure 4.UN09

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Figure 4.UN10

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Figure 4.UN11

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Figure 4.UN12

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