Linear Alkylbenzene Sulfonate

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CHEMICAL PROCESS INDUSTRIES


LINEAR ALKYLBENZENE SULFONATE is the
PRODUCTION OF primary cleaning agent used in many laundry
detergents and cleaners. They are one of the
LINEAR oldest and most widely used synthetic detergents
and may be found in numerous personal-care
ALKYLBENZENE products (soaps, shampoos, toothpaste etc.) and
household-care products (laundry detergent,
SULFONATE dishwashing liquid, spray cleaner etc.). LINEAR
ALKYLBENZENE SULFONATE is produced by
sulfonation of LAB (LINEAR ALKYLBENZENE)
with a variety of sulfonating agents.
PROCESS FLOW DIAGRAM
LINEAR ALKYLBENZENE SULFONATE
HISTORY OF THE LINEAR ALKYL HISTORY OF PRODUCTION IS LINEAR ALKYL BENZENE
01 BENZENE SULFONATE 02 03
SULFONATE STILL BEING
PRODUCED?
Linear alkylbenzene sulfonate (LAS) The first alkylbenzene
is an anionic surfactant. It was sulfonates were obtained by the According to the study, the
introduced in 1964 as the Friedel–Crafts alkylation of consumption of LAS will
readily biodegradable benzene with propylene probably remain stable in the
replacement for highly tetramer. Nearly all LAB (Linear largely advanced regions; it'll
branched alkylbenzene Alkylbenzene) is converted to increase by 3.0-6.0 per time in
sulfonates (ABS). Linear linear alkylbenzene sulfonate some lower developed regions
alkylbenzene sulfonate is a mixture (LAS) by sulfonation. or countries, similar as the
of closely related isomers and Middle East, Africa, and India,
homologues, each containing where greasepaint cleansers
an aromatic ring sulfonated at are still a veritably large part of
the para position and attached the laundry soup request. As a
to a linear alkyl chain. result of the rapid-fire growth of
LAS demand in the Asia Pacific
region, demand in the region
reckoned for roughly half of
global demand in 2020.
WHAT ARE NOW THE The available acute toxicity data by the
MANUFACTURING oral route of exposure indicate that LAS
exhibits slight acute oral toxicity, with
PROCESS OF LAS? symptoms of toxicity and mortality at
high doses but not at lower doses.
Processes for preparing linear
WHAT ARE SOME OF THE alkylbenzene have been developed that
CURRENT avoid the use of chloroparaffins, but
IMPROVEMENT OR instead use olefins or n-paraffins as the
source of the alkyl group. Such
RESEARCH? processes involve Friedel-Crafts
alkylation of benzene with an olefin in
the presence of a suitable HF or solid
catalyst. These processes produce
alkylbenzene having greatly decreased
amounts of undesirable byproducts.
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CHEMICAL PROCESS INDUSTRIES

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