Lecture 11 and 12

Download as pptx, pdf, or txt
Download as pptx, pdf, or txt
You are on page 1of 20

Environmental Chemistry

by

Dr. Muhammad Ashfaq


Assistant Professor in Chemistry University of Gujrat

Water pollution
Water Pollution
defined as the presence of a substance in the environment that, because if its chemical composition or quantity, prevent the functioning of natural processes and produces undesirable environmental and health effects. almost always the byproducts of worthy and essential activities
producing crops, creating comfortable home providing energy and transportation manufacturing products removing biological wastes.

Water pollution
Water pollution is since civilization began More population more demand for water Therefore: Problems of scarcity and contamination of water increased many fold Mining, industry, Farming and Land clearing adversely affect water quality Developing countries are typical in this regard: Water is rarely treated before consumption

Water pollution

Many materials used widely are nonbiodegradable They resist attack and breakdown by detritus feeders and decomposers.
Examples include plastics. Aluminum cans and synthetic organic chemicals

Any part of the environment may be affected Our goal should be to manage materials that are man made so that the environment will not be jeopardized for future generations.

Water pollution

Strategy to avoid or manage pollutants Identify the sources of the pollutants Identify the material or materials that are causing the pollution Develop and implement pollution control strategies to prevent the pollutants from entering the environment Develop and implement alternative means of meeting the need that do not produce the pollution by-product.

Water pollution
Water pollution affects plants and organisms living in these bodies of water and, in almost all cases the effect is damaging not only to individual species and populations, but also to the natural biological communities. Water pollution is a major problem in the global context. It has been suggested that it is the leading worldwide cause of deaths and diseases, and that it accounts for the deaths of more than 14,000 people daily. Water is typically referred to as polluted when it is impaired by anthropogenic contaminants. Natural phenomena such as volcanoes, algae blooms (Rapid increase in the population of algae in an aquatic system), storms, and earthquakes also cause major changes in water quality and the ecological status of water.

Exposing many to the risk of water Ground water contaminated with nitrates, Lakes and reservoirs increase -Their capacity to support aquatic life is being threatened Rivers carry heavy loads of Heavy/Toxic metals and industrial and domestic wastes through Rivers to Sea Making more aware more people of what is happening to their water supplies may be of the most effective ways of slowing down water pollution Water amount cannot be increased or decreased Global water- 1360 million cubic kilometer covers 70% of the earth surface Only 3% water is fresh and its < 1% is available for Human consumption i.e. Rivers, Canals etc

Ample fresh water available but not at places where it is required Water is polluted by industry, Agriculture, Mining and at domestic levels. This reduces further the good quality of water Sewage, Nutrients, Toxic metals and Industrial and Agriculture chemicals are main water pollutants along with Organic matter in domestic sewage Third world countries untreated drinking water causes around 25,000 deaths daily B/C either infected water is consumed or because its use leads indirectly to infectious diseases Water pollution started in the third World Countries in the 20th Century with start of Industrialization and Urbanization- But no adequate treatment practices and Poor Sanitation Services

Industrialized countries also discharge intensively industrial wastes and agriculture chemicals (Fertilizers & Pesticides) going to Canals, Rivers and Sea

Resultantly Algal Blooms and related health and Social damages

Water Distribution in Nature


Total water: 1360 million cubic meters
3% is fresh water 29 million km3 is loaded in snow and ice 8 million km3 is ground water About 200 000 km3 in Rivers and Lakes

Fresh water renewed in Hydrological cycle of evaporation and Precipitation Annual average rainfall over land is about 110 000 km3 but 70 000 km3 lost through evaporation before reaching Sea This Leaves 40 000 km3 of Runoff (About one-third of total rainfall over land) for use

Per Capita Water Availability in Selected Countries


Category
Very low Low Medium High

Per capita availability


1000 m3/year or less 1000-5000 m3/year 5000-10 000 m3/year 10 000 m3/year and more

Countries
14 37 14 35

Agriculture particularly irrigation accounts for more than two third of all human water use of which 50-80% is simply lost

Water Use and Water Quality


Different levels of water quality for different uses are needed Five basic categories of water use are: 1. 2. 3. 4. 5. Public water supply (mainly for human consumption) Water for Agriculture Water for Recreation Water for Industry Water for Fisheries and Wildlife

Public water supply (PWS)


Microbiological indicators are the most important parameters for PWS Several pollutants like Nitrates, Fluorides (KALALANWAKA Case), Arsenic and Iodine in high concentrations adversely affects human health Mercury and Lead affect central nervous system of human beings Among organic micronutrients include Benzene (carcinogenic) Salinity is not health hazard

Agriculture
Sodium Absorption Ratio (SAR) important in Agriculture SAR can pollute soil structure and crops

Industry
Process water (raw material) Transport medium Cleaning agent and steam source As coolant (mostly in power plants)

Fisheries and Wildlife


Dissolved Oxygen critical to fish survival- Industrial and Agriculture Pollutants Organic and Inorganic micro pollutants like poly nuclear aromatic hydrocarbons (PAHs) and chlorinated organic compounds like poly chlorinated biphenyls (PCBs) and hexachloro benzene (HCB) can cause tumors, spinal curvatures, and other deformities in fish---Indirect food pollution

Recreation
Bacteria and its ill health effects on human health

Water pollution Sources


Surface water and groundwater have often been studied as separate resources, although they are interrelated. Sources of surface water pollution are generally grouped into two categories based on their origin:

Point source pollution:


It refers to contaminants that enter a waterway through a discrete conveyance, such as a pipe or ditch. Examples of sources in this category include discharges from a sewage treatment plant, a factory, or a city storm drain.

Non point source pollution:


It refers to diffuse contamination that does not originate from a single discrete source. NPS pollution is often the cumulative effect of small amounts of contaminants gathered from a large area. The leaching out of nitrogen compounds from agricultural land which has been fertilized is a typical example.

Groundwater pollution
Interactions between ground water and surface water are complex. Consequently, groundwater pollution, sometimes referred to as groundwater contamination, is not as easily classified as surface water pollution.

By its very nature, groundwater aquifers (wet underground layers) are susceptible to contamination from sources that may not directly affect surface water bodies, and the distinction of point vs. nonpoint source may be irrelevant.

Water pollution
Throughout history, the quality of drinking water has been a factor in determining human welfare. There are many causes for water pollution but two general categories exist: Direct and indirect contaminant sources. Direct sources include effluent outfalls from factories, refineries, waste treatment plants etc.. that emit fluids of varying quality directly into urban water supplies. In the United States and other countries, these practices are regulated, although this doesn't mean that pollutants can't be found in these waters. Indirect sources include contaminants that enter the water supply from soils/groundwater systems and from the atmosphere via rain water. Soils and groundwater contain the residue of human agricultural practices (fertilizers, pesticides, etc..) and improperly disposed of industrial wastes. Atmospheric contaminants are also derived from human practices (such as gaseous emissions from automobiles, factories and even bakeries). Contaminants can be broadly classified into organic, inorganic, radioactive and acid/base.

You might also like