Nuclear Physics: James T. Shipman Jerry D. Wilson Charles A. Higgins, Jr. Omar Torres

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James T.

Shipman
Jerry D. Wilson
Charles A. Higgins, Jr.
Omar Torres

Chapter 1
Nuclear Physics

© 2016 Cengage Learning


Nuclear Physics
• The characteristics of the atomic nucleus are important to our
modern society
• Diagnosis and treatment of cancer and other diseases
• Geological and archeological dating
• Chemical analysis
• Nuclear energy and nuclear disposal
• Formation of new elements
• Radiation of solar energy
• Generation of electricity

© 2016 Cengage Learning


Intro
Early Thoughts about Elements
• The Greek philosophers (600–200 BCE) were the first
people to speculate about the basic substances of
matter
• Aristotle speculated that all matter on Earth is
composed of only four elements: earth, air, fire, and
water
• He was wrong on all counts!

© 2016 Cengage Learning


Section 10.1
Symbols of the Elements
• Swedish chemist,
Jons Jakob
Berzelius (early
1800’s) used one
or two letters of
the Latin name to
designate each
element

© 2016 Cengage Learning


Section 10.1
Symbols of the Elements
• Since Berzelius’ time most elements have been
symbolized by the first one or two letters of the
English name.
• You are expected to know the names and symbols of
the 35 elements listed on Table 10.2

© 2016 Cengage Learning


Section 10.1
Names and Symbols
of Common Elements

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Section 10.1
The Atom
• All matter is composed of atoms
• An atom is composed of three subatomic particles:
electrons (–), protons (+), and neutrons (neutral)
• The nucleus of the atom contains the protons and the
neutrons (also called nucleons)
• The electrons surround (orbit) the nucleus
• Electrons and protons have equal but opposite charges

© 2016 Cengage Learning


Section 10.2
Major Constituents of an Atom

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Section 10.2
The Atomic Nucleus
• Protons and neutrons have nearly the same
mass and are 2000 times more massive
than an electron
• Discovery – electron (J.J. Thomson in
1897), proton (Ernest Rutherford in 1918),
and neutron (James Chadwick in 1932)

© 2016 Cengage Learning


Section 10.2
Rutherford’s Alpha-Particle
Scattering Experiment
• J.J. Thomson’s “plum pudding” model predicted the
alpha particles would pass through the evenly
distributed positive charges in the gold atoms

a particle = helium nucleus


© 2016 Cengage Learning
Section 10.2
Rutherford’s Alpha-Particle
Scattering Experiment
• Only 1 out of 20,000 alpha particles bounced back
• Rutherford could only explain this by assuming that each
gold atom had its positive charge concentrated in a very
small “nucleus”
• Diameter of nucleus = about 10–14 m
• Electron orbit diameter = about 10–10 m
• Atomic Mass is concentrated in the nucleus
(> 99.97%)
© 2016 Cengage Learning
Section 10.2
Atomic Mass is
Concentrated in the Nucleus!
• Therefore the volume (or size) of an atom is
determined by the orbiting electrons
– The diameter of an atom is approximately 10,000 times the
diameter of the nucleus
• If only nuclear material (protons and neutrons) could
be closely packed into a sphere the size of a Ping-
Pong ball it would have the incredible mass of 2.5
billion metric tons!

© 2016 Cengage Learning


Section 10.2
Visual Representation of a Nucleus
• Tightly packed
protons and
neutrons

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Section 10.2
Atomic Designations
• Atomic Number (Z) – the # of protons in the nucleus
(“defines” the element – the # of protons is always the same
for a given element)
• Atomic Number also designates the number of electrons in
an element
• If an element either gains or loses electrons, the resulting
particle is called and ion
• For example, if a sodium atom (Na) loses an electron it
becomes a sodium ion (Na+)

© 2016 Cengage Learning


Section 10.2
More Atomic Designations
• Mass Number (A) – protons + neutrons, or the total
number of nucleons
• Isotope – when the number of neutrons vary in the
nucleus of a given element (always same number of
protons)
• Only 118 chemical elements
are known, but the total number
of isotopes is about 3000
© 2016 Cengage Learning
Section 10.2
© 2016 Cengage Learning
Isotopes
• Some elements have several isotopes (like carbon –
12C, 13C, 14C)

• Isotopes of a single element have the ’same’ chemical


properties (due to same number of electrons), but
they have different masses (due to varying number of
neutrons)
• Due to their various masses isotopes behave slightly
differently during reactions

© 2016 Cengage Learning


Section 10.2
Three Isotopes of Hydrogen

• In naturally occurring Hydrogen 1 atom in 6000 is deuterium and 1 in 10,000,000 is


tritium
• Heavy water = D2O

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Section 10.2
Determining the
Composition of an Atom – Example
• Determine the number of protons, electrons,
and neutrons in the fluorine atom 199 F.
• Atomic Number (Z) = 9
•  protons = 9 & electrons = 9
• Mass Number (A) = 19
• A = N + Z {N = neutron number}
•  N = A – Z = 19 – 9 = 10
• neutrons = 10

© 2016 Cengage Learning


Section 10.2
Atomic Review
• Protons & Neutrons – in nucleus
• Electrons – orbit around nucleus
• Mass Number (A) = protons + neutrons
• Atomic Number (Z) = # of protons
• Neutron Number (N) = # of neutrons
• Isotope – an element with different # of neutrons
(same # of protons)

© 2016 Cengage Learning


Section 10.2
Atomic Mass
• The weighted average mass of an atom of the element
in a naturally occurring sample
• The Atomic Mass is measured in atomic mass units
(u) – basically the weight of a proton or neutron
• The 12C atom is used as the standard, and is assigned
the Atomic Mass of exactly 12 u
• The weighted average mass of all carbon is slightly
higher than 12 (12.011) because some is 13C and 14C
© 2016 Cengage Learning
Section 10.2
Fundamental Forces of Nature –
Review
• We have previously discussed two fundamental forces of
nature – gravitational and electromagnetic
• The electromagnetic force between a proton (+) and an
electron (–) is 1039 greater than the gravitational forces
between the two particles
• Therefore the electromagnetic forces are the only
important forces on electrons and are responsible for the
structure of atoms, molecules, and all matter in general

© 2016 Cengage Learning


Section 10.2
The (Strong) Nuclear Force
• Remember that the nucleus of any atom is extremely small and
packed with a combination of neutrons and protons (+)
• According to Coulomb’s Law like charges repel each other
– Therefore the repulsive forces in a nucleus are huge and the
nucleus should fly apart
• There must exist a third fundamental force that somehow holds the
nucleus together
• This is the strong force which is attractive at distances less than
about 10–14 m

© 2016 Cengage Learning


Section 10.2
Large Nucleus & the Nuclear Force
• For a large nucleus the forces are complicated
• An individual proton is only attracted by the 6 or 7
closest nucleons, but is repelled by all the other
protons
• When the # of protons exceeds 83, the electrical
repulsion overcomes the nuclear force, and the
nucleus is unstable
• Spontaneous disintegration
or decay occurs to adjust for
the neutron-proton
imbalance
© 2016 Cengage Learning
Section 10.2
Standard Model
• Physicists have also identified a weak nuclear force within
an atom
– This is a very short-range force that reveals itself principally in
beta decay
– It is weaker than the strong force and the electromagnetic force
• Physicists have organized three of the known atomic
forces (electromagnetic, weak nuclear, and strong nuclear)
into a single unifying theory called the standard model

© 2016 Cengage Learning


Section 10.2
Atomic Review
• Mass Number (A) – protons + neutrons, or the total
number of nucleons
• Isotope – when the number of neutrons vary in the
nucleus of a given element (always same number of
protons)
• Atomic Number (Z)
– number of protons

© 2016 Cengage Learning


Section 10.2
Radioactivity
• Radioactivity (radioactive decay) – the spontaneous process
of nuclei undergoing a change by emitting particles or rays
• Nuclide – a specific type of nucleus: 238U or 14C
• Radionuclides (radioactive isotopes or radioisotopes) –
nuclides whose nuclei undergo spontaneous decay
(disintegration)
• Substances that give off such radiation are said to be
radioactive

© 2016 Cengage Learning


Section 10.3
Radioactive Decay
• Parent nucleus – the original nucleus before decay
• Daughter nucleus (or daughter product) – the
resulting nucleus after decay
• Radioactive nuclei can decay (disintegrate) in three
common ways
– Alpha decay
– Beta decay
– Gamma decay

© 2016 Cengage Learning


Section 10.3
Radioactive Decay (Disintegration)
• Alpha decay – disintegration of a nucleus into a nucleus of
another element, w/ the emission of an alpha particle ()
– a helium nucleus 
He  4
2

• Beta decay – a neutron is transformed into a proton, w/ the


emission of a beta particle ()
– an electron  0
1 e
• Gamma decay – occurs when a nucleus emits a gamma ray
() and becomes a less energetic form of the same nucleus
© 2016 Cengage Learning
Section 10.3
Three Components
of Radiation from Radionuclides
Alpha(), Beta(), Gamma()

© 2016 Cengage Learning


Section 10.3
Nuclear Decay Equations – Examples
• Alpha decay:
232
9Th  228
88 Ra  24 He

• Beta decay:
14
6 C  14
7 N  0
1 e

 82 Pb  
204 * 204
• Gamma decay: 82 Pb

• In a nuclear decay equation, the sums of the


mass numbers (A) and the sums of the atomic
numbers (Z) will be equivalent on each side
© 2016 Cengage Learning
Section 10.3
The Products of Alpha Decay –
Example
238
• 92 U undergoes alpha decay. Write the equation for the process.


238
92 U?

238
92 U  ?  24 He
234
238
92 U 90 ?  42 He

• Must determine the mass number (A), the atomic number (Z), and the
chemical symbol for the daughter product

238
92 U 234
90 Th  42 He

© 2016 Cengage Learning


Section 10.3
Five Common Forms
of Nuclear Radiations

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Section 10.3
Decay Series of
Uranium-238 to Lead-206

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Section 10.3
Identifying Radionuclides
• Which nuclides are unstable (radioactive) and which are stable?
• An interesting pattern emerges:
– Most stable nuclides have an even number of both protons and neutrons (even-
even nuclides)
– Most unstable nuclides have an odd number of both protons and neutrons
(odd-odd nuclides)
• A nuclide will be radioactive if:
– Its atomic number (Z) is > than 83
– n < p (except for) 1 3
1 H and 2 He
– It is an odd-odd nuclide
2 6 10 14
H, Li, B, and N
(except for 1 3 5 7
© 2016 Cengage Learning
)
Section 10.3
Identifying Radionuclides – Example
• Identify the radionuclide in each pair, and state your
reasoning.
208 222
a) 82 Pb and 86 He  Z above 83
19 20
b) 10 Ne and 10 Ne  fewer n than p
63 64
c) 29 Cu and 29 Cu  odd-odd

© 2016 Cengage Learning


Section 10.3
The Pairing Effect in Stabilizing Nuclei

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Section 10.3
A Plot of Number of Neutrons (N) Versus
Number of Protons (Z) for the Nuclides
• Showing “band of
stability” (red dots)
• Small blue dots represent
known radioisotopes

© 2016 Cengage Learning


Section 10.3
Half-Life of a Radionuclide
• Half-Life – the time it takes for half of the nuclei of a
given sample to decay
• In other words – after one half-life has expired, only
one-half of the original amount of radionuclide
remains undecayed
• After 2 half-lives only one-quarter (½ of ½) of the
original amount of the radionuclide remains
undecayed

© 2016 Cengage Learning


Section 10.3
HALF LIFE

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Decay of Thorium-234 over Two Half-Lives
Thorium-234 has a half-life of 24 days

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Section 10.3
Decay Curve for Any Radionuclide
Section 10.3

© 2016 Cengage Learning


Finding the Number of
Half-Lives and the Final Amount
• What fraction and mass of a 40 mg sample of iodine-
131 (half-life = 8 d) will remain in 24d?
• Step 1 – find the number of half-lives that have passed
in 24 days: 24 days
 3 half-lives
8 d/half-life
• Step 2 – Start with the given amount N0 = 40 mg, and half it 3 times (3 half-lives)
– Once  N0/2 = 20 mg (after 8 days)
– Twice  N0/4 = 10 mg (after 16 days)
– Thrice  N0/8 = 5 mg (after 24 days)

© 2016 Cengage Learning


Section 10.3
Finding the Number of Half-Lives and the
Final Amount – Confidence Exercise
• What fraction of strontium-90 produced in 1963
(half-life = 29 y) will remain in 2021?
• Step 1 – find the number of half-lives that have
passed in 58 years: 58 years
 2 half-lives
29 y/half-life
• Step 2 – Start with the given amount = N0
– After 1 half-life  N0/2 = (after 29 years)
– After 2 half-lives  N0 /4 = (after 58 years)
 One fourth of the original strontium-90 remains

© 2016 Cengage Learning


Section 10.3
Finding the Elapsed Time – Example
• How long would it take a sample of 14C to decay to
one-fourth its original activity? (half-life of 14C is
5730 years).
• Solution: N0  N0/2  N0/4  14C would need to
decay for two half-lives in order to be reduced to ¼
its original activity.
• (2 half-lives)(5730 y/half-life) = 11,460 years

© 2016 Cengage Learning


Section 10.3
Determining the Half-Live of a
Radioactive Isotope (Radionuclide)
• In order to determine the half-life of a particular
radionuclide, we must monitor the activity of a
known amount in the laboratory
• Activity – the rate of emission of the decay particles
(usually in counts per minute, cpm)
• When (time) the initial activity rate has fallen to one-
half – we have reached one half-life
• Measured with a Geiger counter
© 2016 Cengage Learning
Section 10.3
Geiger Counter
When a high-energy particle from a radioactive source
enters the window it ionizes an argon atom, giving off a
small pulse of current, which is counted & amplified
into the familiar “clicks”.

© 2016 Cengage Learning


Section 10.3
Radioactive Dating
• Because of their constant decay rates, radioisotopes
can be used as nuclear “clocks”
• Scientists can determine the age of objects that
contain radioisotopes

© 2016 Cengage Learning


Section 10.3
Carbon-14 (14C) Dating
• An important dating procedure in archeology
• Used on materials that were once part of living things
– wood, bones, parchment, etc.
• 14C is formed naturally in the upper atmosphere and is
dispersed by atmospheric mixing
• All living matter contains about the same level of 14C
or an activity level of 16 counts/min per gram of total
carbon
© 2016 Cengage Learning
Section 10.3
Carbon-14 Dating
• Once an organism dies, it ceases to take in 14C, and
the 14C present at death starts to undergo radioactive
decay
• Therefore, the longer an organism has been dead, the
lower is the radioactively of each gram of carbon (the
12C and 13C are stable) in its remains

© 2016 Cengage Learning


Section 10.3
Carbon-14 Dating
Section 10.3

© 2016 Cengage Learning


Section 10.3
Limits to Carbon-14 Dating
• After about 10 half-lives, very little 14C remains, and
it is therefore barely measurable
• The limit of radiocarbon dating depends on the ability
to measure very low activity in old samples
• 40,000–50,000 years is the current limit of age-dating
using 14C

© 2016 Cengage Learning


Section 10.3
Carbon 14 Dating – Example
• An old scroll is found in a cave that has a carbon-14 activity of 4
counts/min per gram of total carbon. Approximately how old is the scroll?
• The plant from which the scroll was made originally had an activity level
of 16 counts/min per gram of carbon.
• To get to 4 cts/min
• 16 cts → (t1/2) 8 cts → (t1/2) 4 cts or 2 half-lives
• 14C has a half life of 5730 yrs
• 2×5730 = 11,460 yrs
• The scroll is between 11,000 and 12,000 years old.

© 2016 Cengage Learning


Section 10.3
Nuclear Reactions
• We know that radioactive nuclei can spontaneously
change into nuclei of other elements, a process called
transmutation
• Scientists wondered if the reverse was possible
• Could a particle (proton or neutron) be added to a
nucleus to change it into another element?
• The answer is “yes,” and this process is called a
nuclear reaction
© 2016 Cengage Learning
Section 10.4
Nuclear Reactions
• In 1919 Ernest Rutherford produced the first nuclear
reaction by bombarding 14N with alpha particles
• The result was an artificial transmutation of a
nitrogen isotope into an oxygen isotope
• 42 He  147 N  178 O  11 H

© 2016 Cengage Learning


Section 10.4
Nuclear Reaction – General Form
• 4
2 He  14
7 N  17
8 O  1
1H
• Note that the conservation of mass number and conservation of
atomic number holds in nuclear reactions, just like in nuclear decay
– 18 = total mass # on each side
– 9 = total atomic # on each side
• The general form for a nuclear reaction is
a+AB+b
– a is the particle that bombards A to form nucleus B and emitted particle b

© 2016 Cengage Learning


Section 10.4
Common Particles Encountered in
Nuclear Reactions
• In addition to the particles in the table below, protons,
 1
deuterons
1 H  1 
2
,and tritons
H  1H
3
are commonly
encountered in nuclear reactions

© 2016 Cengage Learning


Section 10.4
Completing an Equation for a
Nuclear Reaction – Example
• Complete the equation for the proton bombardment
of lithium-7.
1
1 H  73 Li  ?  01 n
••Note, the sum of the mass #’s on left = 8.
• The mass # on the right must also = 8, therefore the missing
particle must have a mass # = 7.
• The sum of the atomic #’s on left = 4
• Therefore the sum of the atomic #’s on right must also equal 4.

© 2016 Cengage Learning


Section 10.4
Completing an Equation for a
Nuclear Reaction – Example (cont.)

1
1 H  73 Li  ?  01 n
• The missing particle must have an atomic number = 4
• Therefore the missing particle has a mass number of 7
and an atomic number of 4.
• This element is 74Be (beryllium).
• Completed equation  1 H  7 Li  7 Be  1 n
1 3 4 0

© 2016 Cengage Learning


Section 10.4
Completing an Equation for a Nuclear
Reaction – Confidence Exercise
• Complete the equation for the deuteron bombardment of aluminum-27.

2
1 H 27
13 Al  ?  42 He
• Note the sum of the mass #’s on left = 29.
• The mass # on the right must also = 29, therefore the missing
particle must have a mass # = 25.
• The sum of the atomic #’s on left = 14.
• Therefore the sum of the atomic #’s on right must also equal
14.
© 2016 Cengage Learning
Section 10.4
Completing an Equation for a Nuclear
Reaction – Confidence Exercise (cont.)

2
1 H 27
13 Al  ?  42 He
• The missing particle must have an atomic number =
12
• Therefore the missing particle has a mass number of
25 and an atomic number of 12.
• This element is 12
25
Mg (magnesium).

• Completed equation  21 H  27 13 Al  25
12 Mg  4
2 He

© 2016 Cengage Learning


Section 10.4
Nuclear Reactions
• Rutherford’s discovery of the transmutation of 14N
into 17O was actually an accident!
– But the implications of this discovery were enormous!
• One element could now be changed into another
completely different element!

© 2016 Cengage Learning


Section 10.4
Nuclear Reactions
• The age-old dream of the alchemists had come true
– It was now possible to actually make gold (Au) from other
more common elements!
1
1 H  200
80 Hg  197
79 Au  4
2 He
• Unfortunately, the above process to make gold is VERY expensive.
– More than $1,000,000 per ounce!

© 2016 Cengage Learning


Section 10.4
Nuclear Reactions
• Neutrons produced in nuclear reactions can be used to
induce other nuclear reactions
– Hence, a “chain reaction” is possible
• Since neutrons have an electrical charge, they are
particularly efficient in penetrating the nucleus and
inducing a reaction
– Without an electrical charge neutrons are not influenced by
positive and negative atomic charges

© 2016 Cengage Learning


Section 10.4
Transuranium Elements
• Transuranium Elements – those with atomic number
greater than 92
– All of these elements are synthetic.
– Created in the lab by bombarding a lighter nucleus with
alpha particles or neutrons
– For Example … 01 n  238 92 U  239
93 Np  0
1 e
58
26 Fe  209
83 Bi  266
109 Mt  01 n

© 2016 Cengage Learning


Section 10.4
Nucleosynthesis
• H, He, and Li are thought to have formed in the Big
Bang
• Be up to Fe were likely made in the cores of stars by
fusion
• Atoms heavier then Fe are thought to have formed
during supernova explosions of stars, when there was
an abundance of neutrons and medium-sized atoms

© 2016 Cengage Learning


Section 10.4
Uses of Radionuclides
• Radionuclides have many uses in medicine,
chemistry, biology, geology, agriculture, and industry
• One medical use involves a radioactive isotope of
iodine, 123I, it is used in a diagnostic measurement of
the thyroid gland
• Americum-241, a synthetic transuranium
radionuclide, is used in most common home smoke
detectors

© 2016 Cengage Learning


Section 10.4
Smoke Detector
• A weak radioactive source ionizes the air and sets up a small
current
– If smoke particles enter, the current is reduced, causing an alarm

© 2016 Cengage Learning


Section 10.4
Uses of Radionuclides
• In both chemistry and biology, radioactive “tracers”
(14C & 3H) are used to “tag” an atom within a molecule
– In this way the reaction pathways of drugs & hormones may
be determined
• In geology, the predictable decay rate of radioactive
elements in rocks and minerals allow age determination
• In industry, tracer radionuclides help manufacturers test
durability

© 2016 Cengage Learning


Section 10.4
Nuclear Fission
• Fission – the process in which a large nucleus “splits”
into two intermediate-size nuclei
– with the emission of neutrons and …
– the conversion of mass into energy
• For example, 236U fissions into two smaller nuclei,
emits several neutrons, and releases energy:
236
92 U 140
54 Xe  94
38 Sr  01 n
236
92 U 132
50 Sn  101
42 Mo  3 1
0n

© 2016 Cengage Learning


Section 10.5
Completing the Equation for Fission –
Example
• Complete the following equation for fission.
236
92 U 88
36 Kr  144
56 Ba  ?

• Atomic #’s are balanced, 92 on both sides


• Therefore the atomic # for the unknown is 0.
• Mass #’s are not balanced.
– 236 on the left & 232 on the right
• Therefore 4 additional units of mass are needed on the right.

© 2016 Cengage Learning


Section 10.5
Completing the Equation for Fission –
Example (cont.)
• 236
92 U 88
36 Kr  144
56 Ba  ?

• The missing particle must have:


– an atomic number of 0
– a mass number of 4
• But no single particle exists with those properties
• Therefore the missing “particle” is actually 4 neutrons.
236
92 U 88
36 Kr  144
56 Ba  4 1
0n

© 2016 Cengage Learning


Section 10.5
Completing the Equation
for Fission – Confidence Exercise
• Complete the following equation for fission.
236
92 U 90
38 Sr  ?  2 01 n

• Atomic #’s are not balanced.


– The atomic # for the unknown must be 54.
• Mass #’s are not balanced.
• The mass # for the unknown must be 144.
144
• The unknown must be 54 Xe.
236
92 U 90
38 Sr  144
54 Xe  2 1
0n
© 2016 Cengage Learning
Nuclear Fission –
Three Important Features
• The products of fission are always radioactive
– Some of the products have half-lives of thousands of years
– Nuclear waste disposal problems
• Relatively large amounts of energy are produced
• Neutrons are released

© 2016 Cengage Learning


Section 10.5
Chain Reaction
• In an expanding chain reaction, one initial reaction
triggers a growing number of subsequent reactions
• In the case of 236U each fission emits two neutrons
– Each of these two neutrons can hit another 235U, resulting
in the fission of two additional 235U nuclei and the release
of energy and four neutrons
• As the chain expands, the number of neutrons emitted
and the energy output increases

© 2016 Cengage Learning


Section 10.5
Fission
• U absorbs a neutron, initially changes into 236U and
235

then immediately undergoes fission, releasing two


neutrons and energy

© 2016 Cengage Learning


Section 10.5
Chain Reaction
• If all of the emitted neutrons hit another 235U nucleus,
this results in an increasing number of emitted
neutrons, fission reactions, and energy release
• An expanding chain reaction occurs

© 2016 Cengage Learning


Section 10.5
Self-Sustaining Chain Reaction
• A steady release of energy can be attained when each fission
event causes only one more fission event – a self-sustaining chain
reaction
• For a self-sustaining chain reaction to proceed, the correct amount
and concentration of fissionable material (235U) must be present
• If there is too much fissionable material present an expanding
chain reaction occurs
• If there is too little fissionable material present the chain reaction
will stop

© 2016 Cengage Learning


Section 10.5
Critical Mass
• Critical Mass – the minimum amount of fissionable
material necessary to sustain a chain reaction
– About 4 kg (baseball size) of pure 235U
• Subcritical Mass – no chain reaction occurs
• Supercritical Mass – an expanding chain reaction
occurs

© 2016 Cengage Learning


Section 10.5
Subcritical and Supercritical Masses

© 2016 Cengage Learning


Section 10.5
Uranium
• Natural uranium contains 99.3% 238U and only 0.7% is the
fissionable 235U isotope
• Therefore, the 235U must be concentrated or “enriched” in
order to create either a self-sustaining or expanding chain
reaction
• In U.S. nuclear reactors the 235U has been enriched to about
3%, enough for a self-sustaining chain reaction
• In contrast, nuclear weapons require an enrichment of 90%
or more 235U, enough for a sudden release of energy

© 2016 Cengage Learning


Section 10.5
Atomic Bomb
• In order to create a fission bomb (“atomic bomb”), a
supercritical mass of fissionable material must be formed and
held together
• Subcritical portions of the fissionable material are held apart
until detonation
• A conventional explosion brings the subcritical segments
together to create a supercritical mass capable of a explosive
release of energy
– This energy sudden energy release is due to an expanding chain
reaction of the fissionable material

© 2016 Cengage Learning


Section 10.5
Nuclear Reactors
• Nuclear reactors must have a controlled and continual release of
fission energy
• Within the reactor core, long fuel rods and control rods are placed
• The fuel rods contain the fissionable material.
– This is the heat source
• The control rods contain neutron-absorbing material, such as B or
Cd
– These rods “control” the rate of nuclear fission and thereby the amount of
heat produced

© 2016 Cengage Learning


Section 10.5
Nuclear Reactor Vessel
Section 10.6

© 2016 Cengage Learning


Nuclear Reactors
• Since the fission rate in the fuel rods cannot be directly
controlled …
• The control rods are inserted or withdrawn from between the
fuel rods to control the number of neutrons being absorbed
• The reactor core is basically a heat source
– The heat is continually removed by the coolant (H 2O) flowing
through the core
• This heat is used to generate steam in the steam generator
– The steam turns a generator – producing electricity

© 2016 Cengage Learning


Section 10.5
Nuclear Reactor
Note that the hot water
circuit is completely
“contained,” thereby
allowing no radioactive
contamination.
Hot water
circuit

© 2016 Cengage Learning


Section 10.5
Nuclear Reactors – Coolant
• The reactors coolant (H2O) performs two critical functions:
1) The coolant transfers the heat from the reactor core to
the steam generator
2) The coolant serves as a moderator
– The neutrons that are initially emitted from the fuel rods are
moving too fast to cause 235U fission efficiently
– After colliding with several H2O molecules the neutrons have
slowed enough to induce 235U fission more efficiently

© 2016 Cengage Learning


Section 10.5
Nuclear Reactors – Potential Dangers
• Potential dangers exist with a continuous-fission chain
reaction
• The amount of heat generated must be controlled
– The fission rate is controlled through the insertion (slow down)
or withdrawal (speed up) of the control rods between the fuel
rods
• The heat generated must be continually removed from the
core
– The heat is removed by the circulation of the coolant

© 2016 Cengage Learning


Section 10.5
Nuclear Reactors – Potential Dangers
• Improper control or removal of core generated heat can
result in the fusing or “meltdown” of the fuel rods
• The uncontrolled fissioning mass will become
extremely hot and will literally melt through the floor
of the containment structure
– At this point, the extremely hot and uncontrollable
radioactive material will enter the outside environment
(ground, water, atmosphere)

© 2016 Cengage Learning


Section 10.5
Nuclear Accidents
• Three nuclear accidents have occurred:
– Three Mile Island (TMI) Pennsylvania in 1979
– Chernobyl, Ukraine in 1986
– Fukushima Daiichi generating facility, Japan, in 2011
• At TMI, an accidental shutdown of the coolant led to a partial meltdown
– This resulted in very little escape of radioactive gases
• At Chernobyl, a complete meltdown occurred due to poor human judgment and design problems
– This resulted in an explosion & fire in the reactor core and significant regional contamination
• At Fukushima, a severe earthquake caused power loss and tsunami waves disabled backup
generators
– This resulted in a partial exposure of three reactor cores, causing a hydrogen-gas buildup,
which exploded, releasing radioactive material

© 2016 Cengage Learning


Section 10.5
Breeder Reactor
• Besides 235U, another fissionable nuclide is 239Pu
• 239Pu is produced by the bombardment of 238U (the
non-fissionable U) with “fast” neutrons during the
normal operation of a nuclear reactor
• In a breeder reactor the production of 239Pu is
promoted
• The 239Pu is later separated and may be used in an
ordinary nuclear reactor or in weapons
© 2016 Cengage Learning
Section 10.5
Breeder Reactor
• Therefore 239Pu is a natural by-product of a nuclear
reactor
• 20 breeder reactors running for a full year produce
enough 239Pu to run another reactor for a full year
• Breeder reactors run at a higher temperature than
conventional reactors and use liquid sodium as a
coolant

© 2016 Cengage Learning


Section 10.5
Pebble-Bed Gas Reactor
• Possible next generation of nuclear reactors
• Use graphite-uranium pebbles instead of fuel rods
• Reactor is cooled by nonexplosive helium gas instead of
water
– Helium is inert and doesn’t become radioactive
– Graphite is a good moderator, slowing down the fission neutrons
• Designed to dissipate heat on their own and may be shut
down by removing pellets
– No meltdown

© 2016 Cengage Learning


Section 10.5
Nuclear Fusion
• Fusion – the process in which smaller nuclei combine
to form larger nuclei
– along with the release of energy
– does not require a critical mass
• Fusion is the source of energy for the Sun and other
stars
• In the Sun,
4 11 Hthe
fusion
4
2 He process
2 produces a helium
1 e  energy
1

nucleus from four protons (hydrogen nuclei)


© 2016 Cengage Learning
Section 10.6
Examples of Fusion Reactions
H 
2 10.6
Section
• 1
2
1 H  3
1 H  1
1H

• Two deuterons fuse to form a triton and a proton.


– Termed a D-D (deuteron-deuteron) reaction

2
1H  31 H  24 He  01 n

• One deuteron and a tritium form an alpha


particle and a neutron
– Termed a D-T (deuteron-tritium) reaction
© 2016 Cengage Learning
D-T Fusion Reaction

© 2016 Cengage Learning


Section 10.6
Nuclear Fusion – Technical Hurdles
• The repulsive force between two positively charged
nuclei is very great
• To overcome these strong repulsive forces and
initiate fusion, the particles must be heated to extreme
temperatures (100 million K)
• At these extreme temperatures the H atoms exist as a
plasma
– A plasma is gas of electrons and nucleons

© 2016 Cengage Learning


Section 10.6
Nuclear Fusion – Technical Hurdles
• The plasma must also be confined at a high enough
density for protons to frequently collide
• Even with today’s technology, it is a significant
challenge to reach the necessary temperature and
confinement requirements

© 2016 Cengage Learning


Section 10.6
Nuclear Fusion – Inertial Confinement
• Inertial Confinement – simultaneous high-energy
laser pulses from all sides cause a fuel pellet of D &
T to implode, resulting in compression and high
temperatures
• If the pellet can be made to stay intact for a sufficient
time, fusion is initiated
• Research into this method is being conducted at Los
Alamos and Lawrence Livermore labs

© 2016 Cengage Learning


Section 10.6
Nuclear Fusion – Magnetic
Confinement
• Magnetic Confinement – a doughnut-shaped magnetic
field holds the plasma, while electric currents raise the
temperature of the plasma
• Magnetic and electric fields are useful since a plasma gas
is a gas of charged particles
– Charged particles can be controlled and manipulated with
electric and magnetic fields
• The leading labs for fusion research using magnetic
confinement are MIT and Princeton

© 2016 Cengage Learning


Section 10.6
Fusion Advantages over Fission
• Low cost and abundance of deuterium
– Deuterium can be extracted inexpensively from water
• Dramatically reduced nuclear waste disposal
– Relatively few radioactive by-products with relatively
short half-lives
• Fusion reactors cannot get out of control
– In the event of a system failure, quick cool down
– Not dependent on a critical mass

© 2016 Cengage Learning


Section 10.6
Nuclear Reactions and Energy
• In 1905 Einstein published his special theory of
relativity
• This work deals with the changes that occur in mass,
length, and time as an object’s speed approaches the
speed of light (c)
• This theory predicts the mass (m) and energy (E) are
not separate entities but rather related by his famous
equation E = mc2

© 2016 Cengage Learning


Section 10.6
Nuclear Reactions and Energy
• Einstein’s predictions have proved correct
• Scientists have been able to change mass into energy and, on a
very small scale, energy into mass
• For example, using Einstein’s equation what is the equivalent
energy of 1 gram mass?
• E = mc2 = (0.001 kg)(3.00×108 m/s2)
• = 90×1012 J = 90 trillion joules
• 90 trillion joules = same amount of energy released by 20,000
tons of TNT

© 2016 Cengage Learning


Section 10.6
Nuclear Reactions and Energy
• Calculations with Einstein’s formula, E=mc2, have
convinced many scientists that small amounts of mass that
are “lost” in nuclear reactions could be a tremendous
source of energy
• To determine the change in mass in a nuclear reaction, we
simply add up the masses of all the reactants and subtract
the masses of all the products
• Generally during a nuclear reaction mass is either gained
or lost
© 2016 Cengage Learning
Section 10.6
Mass Defect
• MeV = Mega electron volts = 1.60×10–13 J
• Endoergic – an increase in mass has taken place during
the reaction
– Absorbs energy by the number of atomic mass units times 931
MeV/u
• Exoergic – a decrease in mass has taken place during the
reaction
– Releases energy by the number of atomic mass units times 931
MeV/u

© 2016 Cengage Learning


Section 10.6
Calculating Mass and Energy Changes
in Nuclear Reactions – Example
• Calculate the mass defect and the corresponding energy
released during this typical fission reaction (using the masses
of the atoms.)
236
92 U  88
36 Kr  144
56 Ba  4 1
0n

• (236.04556 u)  (87.91445 u) + (143.92284 u) + (4×1.00867 u)


• Total mass on left side = 236.04556 u
• Total mass on right side = 235.87197 u
• Difference of 0.17359 u = mass defect
• (0.17359 u)(931 MeV/u) = 162 MeV of energy released
© 2016 Cengage Learning
Section 10.6
Calculating Mass and Energy Changes in
D-T Fusion Reaction – Confidence Exercise
• Calculate the mass defect and the corresponding
energy released during a D-T fusion reaction.
2
1 H  3
1 H  4
2 He  1
0n

• (2.0140 u) + (3.0161 u)  (4.0026 u) + (1.0087 u)


• Total mass on left side = 5.0301 u
• Total mass on right side = 5.0113 u
• Difference of 0.0188 u = mass defect
• (0.0188 u)(931 MeV/u) = 17.5 MeV of energy released

© 2016 Cengage Learning


Fusion vs. Fission
• On a kilogram-for-kilogram comparison, more
energy comes from fusion than from fission
• The fission of 1 kg of 235U provides energy equal to
the burning of 2 million kg of coal
• The fusion of 1 kg of deuterium releases energy equal
to the burning of 40 million kg of coal

© 2016 Cengage Learning


Section 10.6
Energy Release in Both
Nuclear Fission and Fusion

Any reaction that leads upward on the curve releases energy


because such a reaction is accompanied by a mass defect.
© 2016 Cengage Learning
Section 10.6
Energy Release in Both Nuclear
Fission and Fusion (cont.)

• Fission proceeds from right to left.


• Fusion proceeds from left to right.
• Note that at the top of the curve is 56Fe. No net energy will be released by either splitting 56Fe or by fusing several
56Fe.

© 2016 Cengage Learning


Section 10.6
Biological Effects of Radiation
• Ionizing Radiation – radiation that is strong enough
to knock electrons off atoms and form ions
• Ionizing Radiation includes: alpha particles, beta
particles, gamma particles, neutrons, gamma rays,
and X-rays
• These types of radiation can also harm or kill living
cells, and are especially harmful if they affect
molecules involved in cell reproduction

© 2016 Cengage Learning


Section 10.7
Effects of Radiation on Living
Organisms
• Ionizing radiation cannot be seen, smelled, felt, or tasted
• Film badges worn by workers is commonly used to measure
radiation exposure
• The effects of radiation on living organisms can be classified
into two categories:
• Somatic Effects – short- and long-term effects on the recipient
of the radiation
• Genetic Effects – defects in the recipient’s subsequent
offspring

© 2016 Cengage Learning


Section 10.7
Radiation Units
• The rem (roentgen equivalent for man) is the unit
used to discuss biological effects of radiation
• This unit takes into consideration the relative ionizing
power of each type of radiation and its affects on
humans
• The average U.S. citizens receives 0.2 rem per year,
from a number of different sources (both natural and
anthropogenic)

© 2016 Cengage Learning


Section 10.7
Sources of Exposure to Radiation
• 0.2 rem –
average annual
radiation
exposure for
person in U.S.

© 2016 Cengage Learning


Section 10.7
Radiation Sources
• Natural Sources – cosmic radiation (high altitude areas),
bedrock, radionuclides that are ingested (carbon-14,
potassium-40)
– Radon gas, from bedrock, varies greatly with location, but is
thought to cause from 10,000 to 130,000 lung cancers deaths
per year in the U.S.
• Anthropogenic Sources – medical X-rays and treatment,
TV’s, tobacco smoke, nuclear waste, certain household
products
© 2016 Cengage Learning
Section 10.7
Long-Term Somatic Effects
• Long-term cumulative effects of radiation exposure
are not fully understood
• Without a doubt the most common long-term somatic
effect is an increased likelihood of developing cancer
• Many early workers of radionuclides died of cancer –
these scientists were generally exposed to small doses
for many years

© 2016 Cengage Learning


Section 10.7
Penetration of Radiation
• But – there does not
appear to be any lower
limit, below which the
effects are negligible
•  any exposure to
radiation should be
taken seriously
• Alpha and beta particles are electrically charged and can be easily stopped.
• Gamma rays, X-rays, and neutrons are more difficult to stop because they
are not charged particles
© 2016 Cengage Learning
Section 10.7
Elementary Particles
• By the 1930s, scientists identified 4 subatomic
particles: electron, proton, neutron, photon
• More than 200 elementary particles – mostly from
within the nucleus
• Example: exchange particles responsible for the 4
fundamental interactions: electromagnetic, strong,
weak, and gravitational

© 2016 Cengage Learning


Section 10.8
Particle Accelerators
• Used to study elementary particles
• LHC – Large Hadron Collider – near Geneva
– Became operational in 2010 after almost 20 years of building
– Largest particle accelerator built so far

© 2016 Cengage Learning


Section 10.8
Higgs Boson
• There is an inconsistency in the standard model due to large mass
difference between exchange particles
• This lead to the proposal of the Higgs boson
– It would explain why particles have mass
• In 2012, a new particle was discovered consistent with the Higgs
boson

© 2016 Cengage Learning


Section 10.8
Antimatter
• Every particle has its antiparticle
• The antiparticle for the electron is the positron  0
1 e

• When particles and antiparticles mix they annihilate each


other and release energy

© 2016 Cengage Learning


Section 10.8
Chapter 10 - Important Equations
• N = A – Z Neutron Number = Mass Number –
Atomic Number
• E = mc2 Mass-Energy relationship

© 2016 Cengage Learning


Review

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