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    Group 1 Anions (CL, BR, I, CN, Fe (CN), Fe (CN), SCN)

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    Stephanie Anne Cortez
    The document describes qualitative tests to identify 6 groups of anions based on their reactions with silver nitrate and barium chloride. It provides the color of any precipitate formed, other reagents used in confirmatory tests, and the expected results of these confirmatory tests for each anion. The anions are grouped based on their behavior in the initial tests with silver nitrate and barium chloride.

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    Group 1 Anions (CL, BR, I, CN, Fe (CN), Fe (CN), SCN)

    Uploaded by

    Stephanie Anne Cortez
    585 views12 pages
    The document describes qualitative tests to identify 6 groups of anions based on their reactions with silver nitrate and barium chloride. It provides the color of any precipitate formed, other reagents used in confirmatory tests, and the expected results of these confirmatory tests for each anion. The anions are grouped based on their behavior in the initial tests with silver nitrate and barium chloride.

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    anions

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    The document describes qualitative tests to identify 6 groups of anions based on their reactions with silver nitrate and barium chloride. It provides the color of any precipitate formed, other reagents used in confirmatory tests, and the expected results of these confirmatory tests for each anion. The anions are grouped based on their behavior in the initial tests with silver nitrate and barium chloride.

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    © All Rights Reserved
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    Download as pptx, pdf, or txt
    585 views12 pages

    Group 1 Anions (CL, BR, I, CN, Fe (CN), Fe (CN), SCN)

    Uploaded by

    Stephanie Anne Cortez
    The document describes qualitative tests to identify 6 groups of anions based on their reactions with silver nitrate and barium chloride. It provides the color of any precipitate formed, other reagents used in confirmatory tests, and the expected results of these confirmatory tests for each anion. The anions are grouped based on their behavior in the initial tests with silver nitrate and barium chloride.

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    Group 1 Anions

    (Cl-, Br-, I-, CN-, Fe(CN)64-,


    3-
    Fe(CN)6 , SCN ) -

    Forms ppt. AgNO3; no ppt. formed


    with BaCl2; ppt. is insoluble in HNO3
    Name of Anion Color of precipitate Reagents used Confirmatory Test
    formed with AgNO3
    Ferricyanide Orange Ferrous Sulfate TS + ferrous sulfate = Blue ppt.
    Bromide Yellow Chloroform, HNO3, KMnO4 TS + chloroform + 10 drops 6N HNO3
    + KMnO4 = Orange to brownish red
    chloroform layer
    Iodide Yellow Chloroform, HNO3, TS + chloroform + 10 drops HNO3 +
    KMnO4 KMnO4 = Violet chloroform layer

    Reddish-brown ppt. Conc. HCl, KI, Starch TS + 5 drops conc. HCl + 5 drops KI +
    solution 2-3 drops Starch solution = Blue
    coloration

    Ferrocyanide White Ferric chloride TS + 1 -2 drops ferric chloride = Blue


    coloration
    Thiocyanate White Ferric chloride TS + 1 -2 drops ferric chloride = Blood
    red coloration

    Hypochlorite White Acetic acid, Lead acetate TS + 6N acetic acid + 1ml lead
    acetate = Brown ppt.
    Cyanide White NaOH, Ferrous sulfate, TS + 6N NaOH + ferrous sulfate +
    Ferric chloride 1drop ferric chloride = Blue ppt.

    Chloride White Mercurous nitrate TS + mercurous nitrate = White ppt.


    Group 2 Anions
    (S2-, NO2-, H2PO2-, CH3COO-)

    Forms ppt with AgNO3; no ppt formed


    with BaCl2; ppt is soluble in HNO3
    Name of Anion Color of precipitate Reagents used Confirmatory Test
    formed with AgNO3
    Sulfide Black HCl TS + HCl = evolution of
    Hydrogen Sulfide Gas

    TS + lead acetate =
    Lead acetate Black ppt.

    Hypophosphite White rapidly NaOH, HNO3, TS + 1ml 6N NaOH.


    changing to brown Ammonium Boil mixture, acidify
    or black molybdate with HNO3 and
    ammonium molybdate
    = Yellow ppt.

    Nitrite White Dilute H2SO4 TS + dilute H2SO4 =


    evolution of brown
    gas
    Acetate White Concentrated H2SO4, TS + conc. H2SO4 + 5
    Ethyl alcohol drops ethyl alcohol =
    evolution of gas with
    fruity odor
    Group 3 Anions
    (SO32-, CO32-, BO33-, C2O42-,
    C4H4O62-, C6H5O73-)

    Produces white precipitate with AgNO3;


    produces ppt with BaCl2; both are soluble in
    HNO3
    Name of Anion Reagents Used Confirmatory Test
    Sulfite BaCl2, HCl, Bromine water TS + 3-5 drops BaCl2 + HCl +
    1ml of bromine to the
    filtrate = White ppt.
    Carbonate Lime water Expose lime water to the
    odorless gas using stirring
    rod = White ppt.
    Borate Concentrated H2SO4, Methyl TS + 1ml of conc. H2SO4 +
    alcohol 3ml methyl alcohol. Light
    the solution = Green flame
    coloration
    Oxalate CaCl2, Acetic acid TS + CaCl2 + acetic acid =
    White ppt.

    Tartrate Potassium acetate, Acetic TS + potassium acetate +


    acid acetic acid = White
    crystalline ppt.
    Citrate CaCl2 TS + CaCl2 = White ppt.
    Group 4 Anions
    (PO43-, AsO43-, AsO33-
    S2O32-, CrO42-)

    Produces colored ppt with AgNO3; forms colored


    or white ppt with BaCl2; both ppt are soluble
    Name of Anion Color of precipitate Reagents used Confirmatory test
    Arsenite Yellow ppt. with HCl, Thioacetamide TS + HCl + 10%
    AgNO3 solution thioacetamide solution =
    Yellow ppt.
    Chromate Reddish brown ppt. Lead acetate TS + lead acetate = Yellow
    with AgNO3 ppt.

    Phosphate Yellow ppt. with Ammonium chloride, TS + 10 drops ammonium


    AgNO3 Magnesium mixture, chloride + 1ml magnesium
    Excess NH4OH mixture and excess NH4OH
    = White ppt.

    Thiosulfate White ppt. with Iodine TS + iodine = Immediately


    AgNO3 rapidly turning discolorized solution of
    black iodine

    Arsenate Reddish brown ppt. NH4Cl, Magnesia TS + 5 drops 3N NH4Cl + 3


    with AgNO3 mixture drops magnesia mixture =
    white crystalline ppt.
    Group 5 Anions
    - -
    (NO3 , ClO3 )

    No precipitate is produced with AgNO3 and


    BaCl2
    Name of Anion Reagents used Confirmatory Test

    Nitrate Concentrated H2SO4, TS + 1ml conc. H2SO4 and


    copper wire copper wire = Evolution
    of brown gas

    Chlorate KNO2, AgNO3, HNO3 TS + 2-3 drops KNO2 and


    AgNO3 + HNO3 = White
    ppt.
    Group 6 Anions
    2-
    (SO4 )

    Produced no ppt with AgNO3; produces white


    ppt with BaCl2, ppt is insoluble in HNO3
    Name of Anion Reagents used Confirmatory Test

    Sulfate Lead acetate, Ammonium TS + lead acetate + 1-2 ml


    acetate solution ammonium acetate
    solution = White ppt.

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