Palm oil

based
surfactant
products for
petroleum
industry
 ANGGOTA
KELOMPOK 15
Caroline Fernanda
NRP :02211740000042

Dewi Farra Prasasya

NRP : 02211740000123
Introduction Meterials Results ,
And Discussion
Method ,and
conclution
Introduction
Introductio Many problems causing reduced productivity and
environmental pollutions were found in petroleum
n production process.

These problems include

 limited oil recovery
 wax deposit
 asphaltene deposit
 sludge deposit
 emulsion formation
 water and land pollution as a result of spilled oil residue

Efforts need to be done to overcome these problems as

the demand for oil is increasing and there is no other
source of energy can replace it yet.
Chemical injection is used to overcome several problems
in oil industry. The chemical used is usually petroleum-
based surfactant

It is known that surfactant plays a role in reducing

interfacial tension between fluid and fluid, fluid and rocks,
and fluid and hydrocarbon to increase the permeability of
formation in an effort to increase production rate

The common surfactant used is petroleum-based

surfactant. Therefore, innovation to solve these problems
using surfactant containing agricultural materials deserves
to be developed.
One of the innovations to be developed is oil
palm-based surfactant.
Total crude palm oil (CPO) production in
Indonesia in 2015 was 31.3 million tons.
In 2020, palm oil production is estimated to reach
40 million tons.
The Role of
Surfactant for
Oil and Gas
Industry
Surfactant or surface active agent is a molecule which has
hydrophilic and hydrophobic groups in one structure.

Surfactant reduces interfacial tension between fluid and

fluid, fluid and rocks, and fluid and hydrocarbon to
increase the permeability of formation in an effort to
increase production rate.

In addition, surfactant can break surface tension of oil

emusion bonded to the rocks (emulsion block), reduce the
occurence of water blocking, and alter the wettability of
rocks from oil-wet to water-wet. The common surfactant
used is petroleum-based surfactant.
The role of
surfactant in the
improvement of
production rate is
depicted
There are two dominant forces working in the
pores of oil reservoir rocks, namely capillary
(σ×cos θ) and viscous (v×µ) forces.

Therefore, % oil recovered indicates the percentage of

residual oil which can be taken out from the pores after
water injection. In general, the Capillary Number found in
primary production and Water Injection process lies in the The ratio between these two forces is called Capillary
range of 10-7 – 10-5 (dimensionless). Number as depicted in Figure 1 which shows the oil th
can be pushed out (% oil recovered).
 This means that there is no waterflood Sor (residual oil
saturation) which can be pushed by normal water. Therefore,
surfactant is used to reduce capillary forces and this means
increasing capillary number effectively so that the process
become operationally feasible and more economical.

Increasing Capillary Number can also be done by altering wettability (namely contact
angle, θ). If contact angle θ can be altered to 90º (and this is Neutral wettability, not
water-wet), then Cos(θ) = Cos(90º) = 0 and capillary forces becomes null (0) so that
Capillary Number becomes infinite. As a result, residual oil after waterflood can be
pushed perfectly up to 100%. It is expected that, in addtion to its function of reducing
the IFT of oil-water, surfactant can alter wettability to a netral direction.
 If surfactant solution can form microemulsion with particle size smaller
than the size of the smallest pores of porous rocks, then the surfactant
solution will most probably be able to to push residual oil out as much as
possible. Microemulsion can be formed when the IFT is very small (σ <
10-2 dyne/cm)

and surfactant solution has a tendency to dissolve in oil. In a miscible

displacement mechanism (IFT = 0, where the pushing fluid is soluble in the
pushed fluid), surfactant is able to push 100% Sor (residual oil saturation) out
from inside the pores

Palm oil-based surfactant is expected to be able to substitute petroleum-based

surfactant. Palm oil based-surfactant developed by SBRC IPB is biodegradable as
it is made from plam oil which is abundant in Indonesia so that its sustainability is
ensured. Palm oil-based surfactant is more resistant to Ca2+ and Mg2+ ions and
salinity. It has an IFT value ≤ 10-03 dyne/cm and adsorption value < 400 µg/g core.
It is stable at reservoir temperature for 3 months, produced at Phase III / II(-), and it
has a Filtration Ratio ≤ 1.2.
Palm Oil-based
Surfactant for
Various
Purposes
Based on the its ionic charge of hydrophilic groups after it
is dissociated in liquid medium, surfactant is classified into
four types, namely
(1) anionic; its hydrophilic group contains negative
charge,
(2) cationic; its hydrophilic group contains positive charge,
(3) non ionic; its hydrophilic group contains almost no
charge
(4) amphoteric; molecules in its hydrophilic group
contains positive or negative charge depending on the
medium pH [2]. All types of surfactants can be
synthesized from palm oil because of its physicochemical
properties
Some palm oil-based surfactants developed by SBRC IPB and had potential for applications in oil industry in
Indonesia include glycerol ester, diethanolamide, alkyl polyglycoside, and methyl ester sulphonate.
Various derivative products of palm oil-based surfactant, whether in their formulation process, surfactant ia
used as a single component or there is a another additive substance added in, are potential to be used as a
substitute for petroleum-based surfactant.
This surfactant can be used in many applications including chemical flooding, stimulation, asphaltene dissolver,
wax dissolver, emulsion breaker, sludge breaker, well cleaning, oil spill dispersant, and enhanced
bioremediation.
Some palm oil-based surfactants developed by SBRC IPB and had potential
for applications in oil industry in Indonesia include glycerol ester,
diethanolamide, alkyl polyglycoside, and methyl ester sulphonate.
Various derivative products of palm oil-based surfactant, whether in their
formulation process, surfactant ia used as a single component or there is a
another additive substance added in, are potential to be used as a substitute
for petroleum-based surfactant. This surfactant can be used in many
applications including chemical flooding, stimulation, asphaltene dissolver,
wax dissolver, emulsion breaker, sludge breaker, well cleaning, oil spill
dispersant, and enhanced bioremediation.
 Chemical flooding is a method used to obtain more oil after the reduction
of primary production process (natural) by using natural energy originating
from the reservoir itself (natural reservoir drive) [7]. Chemical flooding is
Surfactant for obtaining oil by injecting materials from outside the reservoir [8]. Surfactant
to be used for chemical flooding should have the following properties: pH
chemical 7-8, IFT value ≤ 10-3 dyne/cm, adsorption value < 400 µg/g core. It
should also be stable for > 3 months at thermal stability test (± 10-3
flooding dyne/cm), produced at Phase III / II(-), have a filtration ratio ≤ 1.2, and
have incremental oil recovery in a coreflooding test of about 15.0-20.0 %
IOIP.
Surfactan
t for
Stimulatio 3.2. Stimulation is a process of oil well repairement in order to increase formation
permeability in an effort to increase production rate. This process causes dissolution
n of particles blocking porous space of rocks. Acidizing and surfactant injection are
the stimulation methods commonly used in oil industry [9]. In surfactant stimulation
process, reservoir rocks are soaked in surfactant to give time to surfactant to
penetrate into reservoir rocks. Surfactant penetration is expected to alter rock
wettability to water wet, reduce interfacial tension, reduce capillary force, and
reduce water cut occurence. This way, permeability and well productivity can be
improved. In surfactant stimulation process, surfactant can make contact with high
reservoir temperature for a long period of time [10]. SPRC IBP has developed
surfactant for stimulating agent with the following properties: IFT value ≤ 10-3
dyne/cm, stable at reservoir temperature, stable at stability thermal test (IFT value
≤10-3 dyne/cm), and filtration ratio value <1.
 The use of solvent in asphaltene deposit handling can only remove about
50% of asphaltene deposit. The addition of surfactant in deposit handling
Surfactan makes surfactant dispersed in asphaltene molecules by breaking down the
bonds between asphaltene molecules. This, in turn, will inhibit the
t for reformation of asphaltene deposit. Temperature, pressure, oil composition
changes and injection of chemical substances in oil production process
Asphalten result in the disruption of balance and stability of asphaltene miscelles in oil.
This disruption is initiated by the release of resin from asphaltene surface.
e Then there is an interaction among asphaltene molecules and a solid phase
is formed through a precipitation process. Further, the solid phase moves
Dissolver up to the surface causing the formation of asphaltene deposition [11

The asphaltene dissolver produced by SBRC IPB has asphaltene solubility level
of 99.38% and it can alter the contact angle of rocks from 48.60º too 80.89º. It
was shown from wetting characteristic test that this asphaltene dissolver has an
ability to increase wettability on a metal surface. This is characterized by the
small amount of deposit remain which is left on the metal surface and
asphaltene removal which reachs 99.66%.
Surfactan
t for Well Surfactant for Well Cleaning Well cleaning is surfactant
developed as an agent to clean holes of perforation well,
Cleaning pipe lines, and oil production equipment from blocking oil
remains so that oil production process can be optimum.
Well Results of palm the performance test of oil-based
surfactant showed as a well cleaning agent show that
there are two phases formed and there is no
macroemulsion phase is formed in the phase behavior
test. This sufactant is also shown to have IFT value of 10-
2 dyne/cm and it is stable at reservoir temperature in a
thermal stability test.
Surfactan
t for Wax Wax is formed as a result of lowered temperature under
oil pouring point. Wax deposit is formed around tubing and
Dissolver production pipe causing a decrease in oil production by
10-35%. Surfactant plays an important role in increasing
oil production in highly depleted wells by reducing
interfacial tension, altering wettability of rocks, and
cleaning oil wells from organic sediment. The use of
surfactant in a solvent is a way of handling wax
chemically. Dissolving wax is more effective by using a
solvent and surfactant than by using a solvent only. Wax
dissolver developed from palm oil-based surfactant by
SBRC IPB is able to reduce the viscosity of crude oil with
high wax content from 149.05 cP to 14.96 cP at 40⁰ C.
4
conclution
Various palm oil-based surfactants have been specifically
developed at SBRC IPB for oil and gas industry needs.
Surfactants can be specifically produced for either
improved oil recovery (IOR) or enhanced oil recovery
(EOR), well stimulation, asphaltene deposit removal, well
cleaning agent and wax removal agent.