Final Dye
Final Dye
Final Dye
DYEING
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• Dye molecules are coloured because they are selectively able
to absorb and reflect some of the wavelengths of the incident
light.
• When all the visible light rays are reflected, it appears black.
• When one or more rays are reflected the viewer senses the
colour produced by the specific reflected ray or combination
of rays.
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• Organic molecules become coloured, and thus useful dye
molecules, if they contain at least one of each of the radicals
called chromophores and auxochromes.
• In general, chromophores give the dye molecule its particular
colour, while the auxochromes intensify the hue of the dye
molecules colour, and make the dye molecule water soluble.
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Color
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Colorants
• The substance that add color to the product are called as
colorants. Dyes and pigment are the two colorants. Both add
color but the process by which they are added and the effect
that are created make them different from each other.
Colorants
Dyes Pigments
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Dye
• Dye, can be said to be colored, ionizing and aromatic organic
compounds which shows an affinity towards the substrate to
which it is being applied. There are mainly two classes of dye,
natural and man-made
Natural Dyes
Natural dyes are derived from nature through organic and
inorganic materials or sources. Logwood is a natural dye
obtained from plants and prussian blue is an inorganic dye
obtained from naturally occurring minerals.
Synthetic Dyes
Synthetic dyes became popular because they were easy-to-use,
less expensive and had wider range of colors. Synthetic dyes
are obtained by adding chemicals to natural dyes. For
example, artificial alizarin is a synthetic dye synthesized from
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coal tar anthracene. Synthetic dyes are used for7modern
Pigments
• Pigments: It is the substance or powder that make up the color
of paint. Pigments are either organic (derived from plant or
animal sources, e.g. ivory black, indigo) or inorganic (derived
from salts or metallic oxide e.g. ocher, cobalt blue).
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Dyeing
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General Theory of Dyeing
In a dyeing process, efficiency of dyeing is directly
proportional to extent of diffusion of dye at the interior of
fiber.
A dye possessing higher affinity for fiber will significantly
improve rate of surface deposition, moderate surface
absorption and slower diffusion.
However, rate of diffusion can be improved by opening the
fiber structure up to some extent up using swelling agent for
natural fiber or by heating up manmade fiber to cause internal
“Brownian movement of polymer chain” which breaks up
few physical forces engaged to attach polymer chain and
make the fiber less resistant to the dye.
The dye however either react with fiber or retained by it with
physical forces called fixation.
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Theories
Theory
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Chemical Theory
Dye and fibre, both possess required group to develop dye-
fibre attachment through chemical bonding.
Nature of bond is mostly ionic, though in some cases, covalent
bond are also formed.
Fastness of dyeing depend upon number of reactive sites
attached to the fibre- the greater the number of sites
attached the better the wash fastness.
After half-time dyeing electrolyte is added for further
exhaustion of bath.
Example:- dyeing of cotton with reactive dyes. Somewhere,
rate of dyeing is so fast that retarding or leveling agents are
applied at the start of dyeing to ensure level dyeing through
reduction in rate of dyeing.
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Physical Theory
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Physico-chemical Theory
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Fibre Complex theory
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Pigment or mechanical Theory
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Solid Solution Theory
Both the phases are solid dyestuff and fiber, but when the dye
is applied under suitable condition, it gets passage inside fiber
resulting a solid-solid solution mechanism.
Dyestuff are retained within the fiber with physical forces.
Fastnesses of dyeing are good in some cases( polyester) and
not good in other cases(Nylon). Dyeing is done at higher
temperature, when the fiber structure is opened up paving
adequate passage to the dye. The dye gets mechanically
deposited on fiber surface diffuse inside and is trapped due to
collapse in fiber structure during cooling.
Example:- Dyeing of man-made with disperse dye.
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Classification of Dye
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Classification Based on Origin of Dyes:
Origin
Natural Synthetic
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Natural Dyes
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Natural Dye
Classification according to source: Depending on their origin or
the sources from which they are produced, natural dyes can be
grouped into three distinct classes:
Natural Dyes
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Dyes derived from plant sources
Plant dye
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Leaves
The dyes which are obtained from the leaves of plants are:-
Leaves
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Leaves
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Fruit
The dyes which are obtained from the fruit of plants are :-
Fruit
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Fruit
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Flower
The dyes which are obtained from the flower of plants are:-
Flower
Dhaura
Saffron Safflower
ka fool
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Flower
Dhaura ka fool:- Red /Pink/brown shades with good fastness.
Safflower petals contain carthamin, which produces red, and
safflower yellow B, which produces an orange-yellow color.
Healthline adds that safflowers were traditionally used to dye
silk yellow or red.
Saffron's blossoms contain a coloring pigment in their
stigmas, which are the long tube-like structures inside the
middle of the blossoms. This coloring pigment is called crocin,
and it is a distant relative of vitamin A. The stigmas are dried
and used for dyeing.
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Roots
The dyes which are obtained from the roots of plants are
Roots
Himalayan Al (Ali ki
Turmeric Alizarin
rhubard Lakdi)
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Roots
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Bark
The dyes which are obtained from the leaves of plants are
Bark
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Bark
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Nuts
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Insect origin
Insect
Tyrian
Cochineal Kermes LAC
Purple
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Insects
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Mineral Origin
• The most important mineral pigments are as follows:
Mineral
Lapis Lampblack
Ochre Charcoal
Lazuli and Soot
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Minerals
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Synthetic Dye
A synthetic dye is any of the organic dyes originally derived from
coal tar derivatives, but currently synthesized from benezene and
its derivatives. The first human-made organic dye, mauveine was
discovered by William Henry Perkin in 1856.
Synthetic dyes
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Water
soluble
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Direct
Water soluble
Fabric dyed:- (cotton, viscose) .
Auxilaries used :- Dye bath + salt.
Fastness properties :-Moderate light fastness & Poor washing
fastness.
Advantage: cheap, easily dyed on fibers
Disadvantage: poor wet fastness and somedyes have poor
light fastness
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Basic
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Acid
Water soluble (anionic)
Fabric dyed:- Protein fibres (wool, silk)
Auxilaries Used:- Acid + glaubers salt
Fastness Properties:-Good light fastness.
Products:- Carpet yarns, dress goods, Suitings, overcoats ,
knitting yarns.
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Reactive
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Water
insouble
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Vat
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Disperse
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Sulphur
Water Insoluble.
Produce dull colours such as navy blue, brown and black.
Fabric dyed:- natural and manmade cellulosic fibres
particularly cottons and Rayon’s.
Auxilaries used :- Sodium sulphite.
Products:- used for heavy woven and knitted cotton as well as
linen and jute.
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Ingrain dye:
a) Azoic Dyes:-Produced within the fiber surface.
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Azoic dye
One of the compounds is known as naphthol or coupling
component and the second diazotised amine or diazo
component.
They react with each other to produce water insoluble dye.
Thus the method of application consists of treatment of the
cloth first with naphthol followed by treatment with diazotised
amine. After the development of shade the fabric must be
thoroughly soaped to remove the loosely held pigment.
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Classification of Synthetic dyes
according to application
Name of Dyes Application
Man made fiber (Nylon),
Acid dye Natural fiber (Silk, Wool)
Man made fiber (Viscose),
Direct Dye Natural fiber (Cotton)
Man made fiber (Viscose),
Vat dye Natural fiber (Cotton, Silk, Wool)
Disperse dye Nylon, Polyester, Acrylic, Tri-acetate, Di-acetate
Basic dye Jute, Acrylic
Reactive dye Cotton, Wool, Silk, Viscose, Nylon
Sulfur dye Cotton, Viscose
Mordant dye Cotton, Wool, Silk
Pigment Cotton, Man made fiber
Mineral Cotton, Wool, Silk
Azoic dye Cotton, Viscose
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Classification of dye according to
chemical constitution:-
Nitro & Nitroso group
Azo Dyes
Triarylmethane Dyes
Anthraquinone Dyes
Indigo Dyes
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Nitro Dyes
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Azo Dyes
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Triarylmethane dyes
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Anthraquinone
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Indigo
• The primary use for indigo is as a dye for cotton yarn, which is
mainly for the production of denim cloth for blue jeans
• Small amounts are used for dyeing wool and silk.
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Selection of dyes
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DYEING FORMS
FIBRE
YARN
FABRIC
GARMENTS
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SEMI – CONTINUOUS DYEING
In this method the fabric is impregnated (about 500-1000 mts.)
With the dye liquor by padding and it is wound on a roller
known as batch roller,
After winding certain length of cloth on the roller the process
is discontinued and the subsequent length of cloth are
impregnated with the same dye liquor or other depending on
the shades required.
Thus several batches of cloth are made in this way,
Each batch is then wrapped up with polyethylene sheet and
stored for 2- 24 hrs., depending on the dyeing conditions.
During this period the fixation of dye would take place.
All the batches are then subjected to washing.
This particular method is most suitable for dyeing of cotton
with reactive dye and is know as pad – batch method.
CONTINUOUS METHOD
In this method of dyeing, the fixation or development and the
washing of the unfixed dye is carried out in a continuous
manner.
The undyed cloth fed at one end of the machine. It comes out
from other end in completely dyed and dry condition.
All these equipment run in tandem and their speeds are
synchronized. The continuous dyeing range is most
economical when large yardages of cloth are to be dyed in a
single shade.
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Batch Method
• In this method the dyeing is carried out in small batches.
About 500 – 2500 mts. of fabric can be at a time depending on
the type of equipment used.
• The equipments available are designed on three principles:
fabric stationary, dye liquor moving: - beam dyeing m/c.
• For the dyeing of pet or pet/cotton blends. Both fabric and dye
liquor moving: - jet dyeing m/c.
• In winch and jet dyeing m/c. The fabric is dyed in the rope
form, whereas, in case of all other m/cs. The dyeing of fabric
is carried out in the open width form.
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Method of
Dyeing
Beck/Win
Dope Stock Skein Paddle
ch
Rotary
Gel Top Package Jet
Drum
Space Beam
Pad
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Solution Dyeing
• This is the method of dyeing in which the dye or pigment is
added to the spinning solution before the extraction of
filaments/ fibres through the spinnerets. The addition of dye or
pigment to the spinning solution before it is forced through
the spinnerets. Solution dyeing, also called mass pigmentation
and dope dyeing. This method of dyeing is generally used in
the production of manmade fibres so as to save a great deal of
money and time. Most olefin fibres are solution dyed.It can be
categorized into two such as:-
Dope Dyeing
Gel Dyeing
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Dope Dyeing
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Dope Dyeing
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• Fiber Dyeing: Fiber Dyeing is the method of dyeing fibers
before blending with other colors to give fancy yarns or
fabrics.It can be categorized into three such as:-
Stock Dyeing
Top Dyeing
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Stock Dyeing
Stock dyeing refers to the dyeing of fibres, or stock, before it
is spun in to yarn.
It is done by putting loose, unspun fibres in to large vats
containing the dye solutions, which are then heated to proper
temperature. From 500-3000 pounds of fibre are dyed at one
time. The average being about 1000 pounds.
Stock dyeing usually results in excellent penetration of the dye
in to the fibre and evenness of colour throughout
Stock dyeing is not used for worsted since the combing
process removes short fibres. This would be a waste of money.
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Stock Dyeing
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Top Dyeing
Top is the wool that has been combed to take out the short
fibres, and then delivered from the combs in the rope like form
about ¼ th inches thick.
Tops, the loose ropes of wool from the combing machine, are
wound in to balls, placed on perforated spindles, and enclosed
in a tank.
The dye is pumped back and forth through the wool.
Continuous processes on loose fibre and wool tops are also
used using a pad-steam technique.
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Yarn Dyeing
• Yarn dyeing as the name implies dyeing of yarns before they
have been woven or knitted in to fabrics. Yarn dyeing is used
to create interesting checks, stripes and plaids with different-
colored yarns in the weaving process. In yarn dyeing, dyestuff
penetrates the fibers in the core of the yarn. This is one of the
oldest systems of dyeing textiles. The dyeing is done after the
fibre has been spun in to yarns. Yarns may be dyed in different
forms such as:-
Skein (Hank) Dyeing
Package dyeing
Warp beam dyeing
Space dyeing
Chain Dyeing
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Hank dyeing
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Hank Dyeing
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Package Dyeing
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Package Dyeing
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Warp Beam Dyeing
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Wrap Beam Dyeing
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Space dyeing
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Fabric Dyeing
• The dyeing of cloth after it is being woven or knitted is known as piece
dyeing. The various methods used for this type of dyeing include jet
dyeing. Jig dyeing, pad dyeing and beam dyeing. This is very popular
method of dyeing as the dyed fabrics will be processed further to garment
industries very easily. The fabric dyeing can be categorized into five
categories such as:-
Beck/Winch Dyeing
JIG dyeing
Jet Dyeing
Pad Dyeing
Union dyeing
Cross Dyeing
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Beck dyeing
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Winch/Beck Dyeing
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JIG dyeing
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Jig Dyeing
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Jet Dyeing
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Union Dyeing
This is suitable for fabrics containing two fibres to dye them in
a single uniform colour, each dye suitable for one kind of fibre
in the blend.
Union dyeing is same as cross dyeing except that instead of
multi-colour effects. One solid colour is produced. The dyer
accomplishes this by using two or more classes of dye, each of
the same colours.
Used typically to dye blends of fibres.
It is a single step to dye a garment that comprises of a
cellulosic fibre, such as cotton or rayon, with either wool,
another animal fibre and nylon.
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Union Dyeing( Cotton/Polyester Blend)
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Pad Dyeing
Pad dyeing is the method in which the fabric is run through the
dye bath in open width and then between the squeeze rollers
that force the dye in to the fabric.
Pad dyeing, like jig dyeing places tension on the fabric while it
is passing through the pad, with a tendency towards flattering
and loss of the full hand of a material.
Most pad dyeing is done as part of a continuous dye system or
continuous dye range.
Large quantities of fabric are continuously run through a pad,
then in to a heat or steam chambers (to set the dye), then in to
washers, rinsers and dryers and finally emerging as completely
dyed fabrics.
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Pad Dyeing
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Cross Dyeing
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Cross dyeing (Silk& linen)
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Garment/Product Dyeing
• Garment dyeing, as its name implies, is the dyeing of complete
garments such as shirts. It is performed by placing garments
into mesh or net bags and immersing them into vats of dye.
Garments inside the bag should be loosely packed for even
coloring. This type of dyeing method is not suitable for
tailored clothing such as suits and dresses due to possible
distortion. The types of apparel that can be dyed are mostly
non-tailored and simpler forms, such as sweaters, sweatshirts,
T-shirts, hosiery, and pantyhose. It can be categorized into two
form such as :-
Paddle Dyeing
Rotary Drum
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Paddle Dyeing
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Rotary Drum
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References
• Aspland, J. R. (1997) Textile Dyeing and Coloration. Research Triangle
Park, N.C.: American Association of Textile Chemists and Colorists.
• Chakraborty, J.N. (2010) “Fundamentals and practices in colouration of
textiles”, New Delhi, Woodhead Publications.
• Corbman, B.P. (1985) Textiles fibre to fabric, McGraw-Hill Book
Company.
• Daniel, M., Arya, A. and Raole, V.M. (2006) Natural Dyes: Scope and
challenges”, Vadodara, Scientific Publicater.
• Vatsala, R. (2003) Text book of textiles and clothing, Indian council of
agricultural research. viii)Hall. A.J., 1955, Hand book of Textiles dyeing
and printing, The National Trade Press.
• Venkatraman, K. (1952) “The chemistry of synthetic dyes” Volume-I, New
York, Academic press.
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• Gohl, E.P.G and Vilensky, L.D. (1987) Textile science, CBS Publishers and
distributors. pp: 120.
• Gopalkrishanan, D. and Karthik, T. (2016) “Basic of textile chemical
processing”, New Delhi, Daya Publication.
• Norma Hollen and Jane Saddler (1979) Textiles, 5 th Edition, Macmillan
Publishings.Co., Inc. New York.
• Perkins, Warren S. (1996) Textile Coloration and Finishing. Durham, N.C.:
Carolina Academic Press.
• Sharma, R.N. (1972) A handbook of dye, pigment and colour technology”,
Ist edition, Delhi, Emerson printing.
• Shenai, V.A. (1987) “Chemistry of dyes and principles of dyeing”, 3 rd
edition, Mumbai, Sevak Publications.
• Society of Dyers and Colourists, and the American Association of Textile
Chemists and Colorist. (1971-1992) The Colour Index International. 3rd
ed. West Yorkshire, England: Bradford.
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