Food Preservation: Chemical Preservation: Dr. Pradeep Parihar

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FOOD PRESERVATION:

CHEMICAL PRESERVATION

Dr. PRADEEP PARIHAR


DIVISION OF
ACADEMIC AFFAIRS
Food Preservation Methods

• Inhibition
• Inactivation
• Avoid contamination
Inhibition
• low T storage
• reduction of aw
• decrease O2, increase
CO2, vacuum
• acidification
• fermentation
• freezing
• surface coating
• structural modification
Inactivation

• sterilization
• pasteurization
• radiation
• electrifying
• high pressure
• blanching
• cooking
• frying
Avoid recontamination
• packaging
• hygienic processing
• hygienic storage
• aseptic processing
Preservatives
• acidification
– pH change
– antimicrobial property
• other preservatives
– antimicrobial
– antioxidant
– enzyme inhibitor
– control redox potential
Control of redox potential

• CA/MAP
– prevent postharvest
ripening
– reduce microbial
activity
Preservatives
• Legally allowed
1. toxicity
2. soluble in food
3. food pH
- inhibition of chemical/biochemical reactions
- antimicrobial effect
Organic acids
acidity, antimicrobial effect
 
benzoic acid, Na- or Ca-benzoate
parabens (p-OH-methyl or propylbenzoate)
mold and yeast inhibitor
at low pH antibacterial, 0.1%
jams, preserves, bakery products, salad
dressing
fruit juices
Organic acids
sorbate (2,4-hexadienoic acid), K/Ca/Na salts
mold and yeast inhibitor
cheese, fruit juices, salads, bakery products
 
propionic acid, Ca/Na salts
rope inhibitors in bread, cheese, spreads
mold inhibitor at high pH
Organic acids
acetic acid
rope inhibitor, mold inhibitor
bakery products 

lactic acid antimicrobial

citric acid acidulant


ion chelator
reduce oxidation
Nitrites and nitrates
(NO2/NO3)

color stabilization
C. botulinum inhibitor
Sulfur compounds
(SO2, HSO3-, SO32-, S2O52-)
• antioxidant
browning inhibitor
antibacterial
• limited use due to allergic reactions in some
people
• wines, dried fruits, vegetables
Salt (NaCl)
• control of water
• antimicrobial
Antioxidants

rancidity inhibitors
BHA, BHT, tocopherols
ascorbic acid
EDTA (ion chelator)
Smoke (phenols, formaldehyde, ketones,
alcohols, acids)

antioxidant
antibacterial, C. botulinum
Carbon dioxide

antimicrobial
carbonated beverages
Antibiotics
nisin
antibotulinal, antibacterial
processed cheese

natamycin
mold inhibitor
salami, cured cheese
Ethylene oxide

antimicrobial
spices, nuts
aseptic packaging
Other antimicrobials
chlorine (Na, Ca hypochlorite)
ozone
hydrogen peroxide
fresh fruits, vegetables
Gaseous Chemosterilizers

– Chemicals that sterilize in a closed chamber


– Ethylene oxide is the gas most frequently used
for sterilization.
– Other examples include propylene oxide and
beta-propiolactone.
– It penetrates most materials and kills all
microorganisms by protein denaturation.
– It requires long exposure and is toxic and
explosive when in pure form.
Peroxygens
(Oxidizing Agents)
• Ozone, peroxide, and peracetic acid are
used as antimicrobial agents.
• They exert their effect by oxidizing
molecules inside cells.
• Used on contaminated surfaces; some
deep wounds, in which they are very
effective against oxygen-sensitive
anaerobes.
Microbial Characteristics and
Microbial Control

• Gram-negative bacteria are generally more resistant than


gram-positive bacteria to disinfectants and antiseptics.
• Mycobacteria, endospores, and protozoan cysts and
oocysts are very resistant to disinfectants and
antiseptics.
• Non-enveloped viruses are generally more resistant than
non-enveloped viruses to disinfectants and antiseptics.
Decreasing order of
resistance of
microorganisms to
chemical biocides.

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