Process Design
Process Design
Process Design
Course Content
Learning Outcomes
Method of Instruction
List of Books
List of Chemical Engineering Journals
List of Chemical/Process Design Softwares
Class Grouping for Process Design
Course Content
Scope of Design Project
Sources of Design Data
Equipment Design and Specification
Mechanical Design of Process Vessels and piping
Site Location and Layout
Process Services
Environmental Consideration
Design Report
Elements of Modular Simulation
Use of Computer Software in Design of Process
Plants(Hysys, ChemCAD, Pro II, Prosim etc)
Learning Outcomes
Scope a design project
Collect and collate design data
Design and Specify any process equipment
Work effectively in a design team
Establish passion for the use of computer
software in the design of a chemical plant
Familiarity with Hysys and other computer
softwares
Method of Instruction
Lectures
Class Exercises
Home Assignments
Assessments
Video Presentation
Industrial Visits
Invited Guest Speakers
Class Discussion
Students Expectations
How to realise these expectations
Appointment of Class Industrial liaison officer
Listing of Potential Industries to visit
List of Books
R.H. Perry and D.W. Green (Editors), The Chemical
Engineers Handbook, McGraw Hill Book
Company, 7th Edition, (1997)
M.S. Peters and K.D. Timmerhaus, Plant Design
and Economics for Chemical Engineers, McGraw
Hill Book Company, 5th Edition, (2003)
D.M. Himmelbau, Basic Principles and
Calculations in Chemical Engineering, Prentice-
Hall International, 6th Edition, (1999)
J.M. Coulson and J. F. Richardson, Chemical
Engineering, Volume 6, Pergamon Press, ( 1999 )
List of Books Cont.
B.D. Smith, Design of Equilibrium Stage
Processes, McGraw Hill Book Company, 4th
Edition, (1984)
R.K. Sinnott, An Introduction to Chemical
Engineering Design, Pergamon Press, Oxford, UK,
(1983)
W. D. Baasel, Preliminary Chemical Engineering
Plant Design, Elsevier Publishing Company Inc.,
NY, (1976)
H.Z. Kister, Distillation Design, McGraw Hill Book
Company, (1992)
List of Chemical Engineering Journals
American Institute of Chemical Engineers Journal
Nigerian Society of Chemical Engineers Journal
Chemical Engineering
The Chemical Engineer
Chemical Engineering Progress
Chemical Engineering Science
Industrial and Engineering Chemistry: Process
Design and Development
List of Chemical Engineering Journals
Cont.
Industrial and Engineering Chemistry:
Fundamentals
Hydrocarbon Processing
Chemical and Engineering News
Oil and Gas Journal
Journal of Physical Chemistry
Computer and Chemical Engineering
Chemical Engineering Education
Chemical and Processing Engineering
List of Chemical Engineering Softwares
Hysys
ChemCAD
Pro II
Prosim
Design 2000
Aspen Plus
EnviroPro
Design Scope
Definitions
Parts of Project Design Scope
Emphasis on safety during the design stage
Scoping a chemical Engineering Project
Assignment ONE
Definition of Scope
A clear definition of the project is the first
stage of plant design.
A clear definition of the project makes
preliminary process design easy, which in turn
provides a reasonably accurate cost estimates.
Items that must be included in the
Scope
The product (s)
Quantity of each product
Quality of each product
Storage requirements for each product
Raw material for each product
Quality of raw material
Storage requirement for the raw materials
By products
Process to be used, including yields and
conversion
Items of Design Scope Cont.
Waste disposal requirements
Utilities requirements
What provision should be made for future
expansion
Location of the plant
Operating hours per year
Completion date
Shipping requirements
Laboratory requirements
Special Safety consideration
Product(s)
Size of container
Size of expected orders
How much material must be sold (predicted by
marketing expert)
Technical and economic questions
Board of Directors make final decision on size of plant
Plant can be large, small, multipurpose
Containers (steel drums, filler drums, Polyethylene
drum/bags, boxes, car bays, pails, cans)
Quality
Number and types of processing steps
determine purity of products
Use very expensive raw material when small
quantity is required
Purify raw material of low quality when large
quantities are processed
Set product specification at the time of
deciding the capacity
Raw Material Storage
Ensure plant never shuts down becoase of
lack of raw material
Estimate maximum and minimum elapsed
time between placing of orders
Difference between the two determines how
much feed must be on hand when order is
placed.
Maximum amount sets the size of the storage
facilities
Product Storage
Product storage must be large enough that it
does not impede production
Consider whether product has a steady
market or vary with season of the year
Waste Disposal, Utilities, shipping and
laboratory requirements
Which of these will be constructed?
Which services will be bought?
Which are already present?
Which will be expanded?
Omission of these items can cause capital
costs to greatly exceed estimates.
Plans for future Expansion
Provision for future expansion will reduce cost
of that expansion
Design some equipment with excess capacity
to facilitate future expansion
Put in extra capacity in continuous units
Plan layout that will easily allow addition of
batch units
Hours of Operation
There are 8,760 hours in a year
For a small plant involving new technology,
allow 90 percent of total time (7900 hours)
For a large plant using well documented
processes, use 95 percent
Consider shift arrangements
In general design for 300 days in the year
Completion Date
Completion date has effect on cost and
profitability
Prices change with time
However rushing can cause increase in
prices(You speed up equipment delivery and
do things in more expensive ways to save
time)
It takes two to three years after the scope is
written before the plant is ready for start up
Safety
A major design consideration
Bury tanks, provide fire walls, separate parts of the plant
Provide a sprinkler system
Storage facilities should be at least 500m form processing
equipment
Record all dangerous aspects of chemicals and processes
Safety consideration will reduce the probability that some
safety features will be omitted
Such omission can cause injury to man, equipment and
environment
Prepare hazard sheets for all chemicals
Class Exercise
Think of a process plant
Develop a design scope for the process plant
Draw up a hazard sheet for one of the
hazardous chemicals.
(20 minutes)
Home Assignment
Get a recent copy of one of the national
dailies and find a scope of a project.
Write out the important sub-heads of the
scope.
Get a copy of the article stated below and
read and do a summary write up on it.
Glen Rosentrater, Preliminary and Final
Engineering Scope of Work, Chemical
Engineering Progress, vol.97, no.12, Dec. 2001
Course Assignment one
Alkylbenzene sulphonate (ABS) can be prepared from
hydrocarbon intermediates in a refinery. Dodecene
(Propylene tetramer) is popularly used for the
alkylation of benzene to get Alkylbenzene with C12 for
the alkyl side chain. The alkylation step is followed by
sulphonation and neutralization.
(i) Carry out a literature survey to get the following:
- Different manufacturing schemes for ABS
- Process description for the production of sodium
dodecylbenzene sulphonate
(ii) Sketch the process flow diagram using computer
(iii) Write on safety consideration for the process
Lecture Number 2
Design Information and Data
Sources of Information on Manufacturing
Processes
Sources of Physical/Chemical properties
Accuracy Required of Engineering data
Prediction of Physical Properties (density, heat
capacity, latent heat of vapourisation, vapour
pressures, diffusion coefficients, surface tension,
critical constants, enthalpy of reactions, enthalpy
of formation, phase equilibria data)
Design Data Book
Sources of Information on
Manufacturing Processes
Information on manufacturing processes,
equipment parameters, materials of construction,
costs , physical and chemical properties of
process materials are needed in various stages of
process design (initial screening of possible
processes, plant start up and production)
For new processes, data and information must be
obtained from literature, or by experiments
(research laboratory, pilot plant studies) or
purchased from other companies.
Information on Manufacturing
Processes
They can be obtained from general literature
They are useful during the initial stages of process
design
They are descriptive and may not be useful for detailed
design/evaluation.
They lack the detailed information on reaction kinetics,
process conditions, equipment parameters, and
physical properties.
They help to search for possible process route during
the drawing of process flowsheet.
Most information on manufacturing processes can be
obtained from the following:
Information on Manufacturing
Processes
Kirk and Othmer (2001), Encyclopedia of
Chemical Processes
Mcketta (2001), Encyclopedia of Chemical
Processes and Design data, Marcel Dekker
Shreves Chemical Process Industries, (1998)
Edition updated by Austin G.T. and Basta, N.,
McGraw Hill
Ullman (2002), Encyclopedia of Industrial
Chemistry, 5th Edition, VCH, Germany
Info. On Manuf. Processes Cont.
Books become outdated quickly and many of the
processes described in them may be obsolete.
Up to date description of processes in current use can
be found in technical journals, e.g. Hydrocarbon
Processing Petrochemical handbooks, patents.
Word Wide Web (WWW). Search for information on
the internet processes, equipment, products and
physical properties.
Many manufacturing and governments departments
maintain web sites (information on Health and
environmental effects of products)
Internet Sources
Key words Chemical Engineering Information
www.hw.ac.uk/lib
www.che.ufl.edu/
www.ciw.uni-karlsruhe.de/chem-eng
Many of the important sources of engineering
information are subscription services
Knovel organisation: Provides on line access to most
standard reference books. Although subscriptive, it can
be accessed through many libraries including
professional engineering ihstitutions and some
universities
Subscription
http://www.che.com
http://www.cepmagazine.org
http://www.aiche.org
http://www.ualberta.ca/cmeng
www.sciencedirect
http://www.blueskythinker.co.uk (genius-
Director of information), (Exploitation of Science,
technology, innovation and technology transfer)
General Sources of Physical Properties
International Critical Tables, now available as EBook. It
can be referenced on Internet through Knovel (2003)
Handbook on Chemical Engineering e.g. Perrys
Chemical Engineers Handbook, Handbook of Chemical
and Environmental Engineering calculations.
ESDU The Engineering Science Data Unit(www.
Ihsesdu.com). Set up to provide validated data for
engineering design. Developed under guidance and
approval of engineers from industry, universities and
research institutions. Includes equipment design data,
software and high quality physical data.
Sources of Physical Properties Contd.
Results of Research work (Journal of Chemical
Engineering data, Engineering Information
and web based references owned by Elsevier
Information . www.ei.org
PP DS (Physical Property data Services) now
available from NEL (www.nel.uk)
DIPPR TM databases (Design Institute for
Physical Properties of AIChE)
www.aiche.org/dippr/projects.htm
Prediction of Physical Properties
Use textbooks . Reid et al (1987), Poling et al
(2000)
Group contribution techniques for estimation
of physical properties of a compound based
on a knowledge of structural formula of the
compound
Carry out a project on the Estimation of
Physical Properties of Terpens using Group
Contribution technique.
Estimation of Properties
Specific heat capacity, latent heat of vapourisation
Vapour Pressures, use the equation
B
InP A
T C
A, B, C are called Antoine Constants compiled by Ohe
(1976, 1989,1990)
Enthalpy of Reaction/Formation
Phase Equilibria Data
Diffusion Coefficients needed in the design of mass
transfer processes of gas absorption, liquid-liquid
extraction
Take Home Assignment
Write a technical paper on any one of the
following:
Estimation of vapour pressures
Determination of liquid phase diffusion
coefficients
Thermal conductivity of solids/liquid/gases
Vapour-Liquid equilibria
Determination of heat of reaction for the
transesterification of Palm Kernel Oil (PKO)
Course Assignment Two (To be carried
out in groups)
Develop a Design Data Book on the Following Projects:
Group A Sulphuric Acid from iron Pyrites
Group B - Nitric Acid
Group C Ammonia from natural gas
Group D Ethanol from Natural Gas
Group E Methanol from Natural Gas
Group F Urea from Natural Gas
Group G Pulp and Paper from Bamboo
Group H Animal Feed Concentrate from raw fish
Group I Liquid Soap from rubber seed oil
Group J Furfural from Agricultural wastes
Group K Sustitute Natural Gas from Coal
Submission date on or before 5th June 2010.
On line submission preferred:
Email [email protected]
Development of Design Data Book
Product (uses, form, quality and quantity)
Reactants (nature, availability, impurities, specification)
Reactions (basic reactions, Thermodynamics, Equilibrium, catalyst, by
products)
Physical Properties of Reactants, Products and by products (s.g., electrical
cond., dielectric const., maximum inerts, freezing pt., density of vapour,
latent heat , heat capacity, maximum heating value etc.)
Chemical Properties of reactants, products and by products (oxidation
ability, reaction with chlorine, reaction with metals, reaction with non-
metals)
Environmental consideration (Hazards, Toxic effects, Government
regulations)
Flow sheet for various manufacturing schemes
Material and Energy Balances
Lecture Number 3
Equipment Design and Specification
Classification of Processing Equipment
Design Equations
Codes and Standards
Equipment Specification Sheet
Classification of Processing Equipment
Unit process principles are used in the design of
major pieces of equipment. These equipment are
classified as follows:
I. Columns (distillation) separation. No of plates,
operating conditions, column diameter and
height, materials of construction, plate layout
etc.
II. Vessels size (dictated by hold up time),
materials of construction, parking/baffles to be
specified.
Classification of Vessels Contd.
III. Reactors: Catalyst type and size, bed
diameter and thickness, heat exchange
facilities, recycle and regeneration
arrangement, materials of construction.
IV. Heat Exchangers/Furnaces: Duty, corrected
log mean temperature difference, percent
vapourised, pressure drop desired, materials
of construction.
Classification of Equipment Contd.
V. Pumps and Compressor: Specify types, power
requirement, pressure difference, gravities,
viscosities, working pressures, material of
construction.
VI. Instruments: Designate function and any
particular requirements
VII. Special Equipment: Specification for
mechanical separators, mixers, driers etc.
Equipment Specification
Standard equipment should be selected. If equipment
is standard, manufacturer may have desire size in
stock. Manufacturer will quote a lower price and give
better guarantees than for special equipment.
A lot of valuable information can be obtained from
equipment manufacturers who specialise in particular
types of equipment.
Before contacting a manufacturer, the engineer
evaluates the design needs and prepare a preliminary
specification sheet for the equipment.
Preliminary Specification Sheet
Used by engineers as basis for the preparation of
the final specification
It can be sent to a manufacturer with a request
for suggestion and fabrication information
It should show the following: Identification,
Function, Operation, Material Handled, Basic
Design data, Essential controls, Insulation
requirements, Allowable tolerances, Special
information and details of particular equipment
e.g. materials of construction, insulation,
necessary delivery date, supports, comments.
Specification Sheet Contd.
Potential Manufacturer make suggestions before detailed
specification is prepared.
The final design include small changes that reduce first cost
with no decrease in the effectiveness of the equipment.
E.g. the tubes in standard heat exchangers are 8, 12, 16, or
20 feet long. These lengths are keep in stock by
manufacturers and maintenance departments. If a design
specification calls for 15 feet long, the manufacturer would
use 16 feet tubes cut off to the specified length. Thus an
increase from 15 to 16 feet for the specified length could
cause a reduction in the total cost of the unit. Labour cost
for cutting the standard length tube is eliminated.
Replacement of tubes after some service time would be
less for 16 feet tubes than for 15 feet tubes.
Specification Sheet Contd.
The details of mechanical design, such as
thicknesses of shell, headers will be
considered later.
Location and sizes of outlets, supports and
other fabrication information can be
presented with the specification in the form of
comments or drawings.
Specification Sheet for a Heat
Exchanger
Identification
Heat Exchanger
Item Condenser Date : 30/05/2010
Item No. H-5 By : Dr. S. E. OGBEIDE
No required 1
Function : Condense over head vapour from methanol fractionation column
Operation : Continuous
Type: Horizontal
Fixed Tube sheet
Expanding ring in shell
Duty 3,00,000 BTU/h outside area: 470 sq ft
Tube side Tubes: 1in. Dia. 14 BWG
Fluid Handled Cooling water 1.25 centimetre Pattern
Flow rate 380 gpm 225 tubes each 8ft long
Pressure 20 psig 2 passes
Temperature 15OC to 25OC Tube material Carbon Steel
Head material Carbon steel
Shell side Shell: 22 in dia. 1 pass
Fluid Handled: Methanol vapour Transverse baffles , Tube support required
Flow rate 7000 lb/h Longitudinal baffles 0 required
Pressure 0 psig Shell material Carbon Steel
Temperature 65OC to a constant temperature
Utilities : Untreated cooling water . Controls : cooling water rate controlled by vapour temperature in vent line. Insulation: 2 in rock cork or
equivalent weather proof. Tolerances: TEMA Standards. Comments on Drawing: Location and sizes of inlets and outlets as shown in drawing.
Specification Sheet for Sieve Tray
Distillation Column
Identification
Item Distillation Column
Date : 30/05/2010
Item No. DC 121-4 By: Dr. S. E. Ogbeide
No Required 1
Function : separation of a mixture
Operation: Continuous
Materials Handled: Feed Overhead Reflux Bottoms
Quantity: ------------- ---------------- ------------- -------------------
Composition: ------------- ---------------- -------------- -------------------
Temperature: ------------- ---------------- -------------- -------------------
Design data: No of trays: ---------------- Reflux Ratio: ------------------------------
Pressure: ----------------- Tray spacing: ------------------------------
Functional height: ---------------- Skirt Height: ------------------------------
Material of construction: --------
Diameter: ------------------
Max. Allowable
vapour velocity: ft/s -----------------
Max. vapour
flow rate: ft3/s ----------------
Recommended inside
diameter: ---------------
Hole sizes and arrangement: -------
Tray thickness: ----------------------