Latihan Analisis Spektrofotometer IR
Latihan Analisis Spektrofotometer IR
Latihan Analisis Spektrofotometer IR
2
Select a compound that best fits each of the following sets of IR bands (in cm-1). Each
set corresponds to a list of just a few important bands for each compound.
a.
b.
c.
d.
e.
f.
g.
h.
i.
3080 (w), nothing 3000 2800, 2230 (s), 1450 (s), 760 (s), 688 (s)
3380 (m), 3300 (m), nothing 3200 3000, 2980 (s), 2870 (m), 1610 (m), ~900 to
~700 (b)
3080 (w), nothing 3000 2800, 1315 (s), 1300 (s), 1155 (s)
2955 (s), 2850 (s), 1120 (s)
2946 (s), 2930 (m), 1550 (s), 1386 (m)
2900 (b,s), 1720 (b,s)
3030 (m), 730 (s), 690 (s)
3200 2400 (s), 1685 (b,s) 705 (s)
3350 (s), 3060 (m), 1635 (s)
Karbonil
terkonjuga
si 1780 1760
Aromatik
monosubti
tusi 900
700 (m)
CN
1350 1000
Amida
primer
3350 dan
3180 (s)
C=C
aromatic
1600
1400 (m)
Benzamide
b. 3380 (m) amida, 3300 (m) amida, nothing 3200 3000, 2980
(s) stretch N-H , 2870 (m), 1610 (m) overlap N-H dan C=O,
~900 to ~700 (b) aromatic monosubtitusi
Aromatik
monosubti
tusi 900
700 (m)
O-H
3400
3300
(b, m)
C=C
aromatic
1600
1400 (m)
Benzoic Acid
Karbonil
terkonjuga
si 1780 1760
Aromatik
monosubti
tusi 900
700 (w)
C=C
aromatic
1600
1400 (m)
Nitril
terkonjuga
si
2250 (s)
Benzonitrile
a. 3080 (w) C-H aromatik, nothing 30002800, 2230 (s) nitril, 1450 (s) C=C , 760
(s) monosubstitusi , 688 (s)
monosubstitusi
Aromatik
monosubti
tusi 900
700 (m)
C=C
aromatic
1600
1400 (m)
Biphenyl
C=C
aromatic
1600
1400 (m)
Dioxane
C=C
aromatic
1600
1400 (m)
Aromatik
monosubti
tusi 900
700 (m)
S=0
1400 dan
1200 (s)
Difenil Sulfone
Karbonil
1730
1700 (S)
CO
1320
1210
(m)
Formic
Acid
O-H
3400
3300
(b, m)
CN
1350 1000
(m)
Amin
Primer
3500 dan
3300 (w)
Isobutilamin