Coupon Technology: An Overview
Coupon Technology: An Overview
Coupon Technology: An Overview
An Overview
Frank Ansuini
electrochemical devices, inc.
NACE International
2009 Eastern Area Conference
EDI 2009
What are coupons?
simulated holidays
A piece of bare metal electrically
connected to the structure
similar material,
similar environment,
similar behavior?
Types of Pipeline Coupons
Weight loss coupon
bonded directly to pipe
CP coupon
bonded through test station
A. W. Peabody
Control of Pipeline Corrosion, 1967
Renewed interest generated by
SP0169
voltage (IR) drops other than those
across the structure to electrolyte
boundary must be considered ...
What Is IR Drop ?
E
M
= E
P
+ V
IR
reference electrode
anode
redrawn from: R. A. Gummow
Materials Performance, August 1998
E
M
voltage drop caused by current
flowing through an electrolyte
E
P
V
IR
Why are IR Drop-free readings
important?
IR Drop is an error in the reading
Consideration or elimination is required by
todays regulations (SP0169)
Ensure that the structure is protected
reference
damaged coating
Why not place the reference electrode
next to the pipe?
IR Drop
Then, why not place the reference right next
to a holiday?
1 cm, 50%
1.5 cm, 70%
2.5 cm, 80%
5 cm, 90%
1 cm dia. holiday
coating
IR Drop fields develop rapidly near a holiday.
Percentage of total
voltage drop to remote
earth vs. distance from
a holiday.
redrawn from: R. A. Gummow
Materials Performance, August 1998
A CP coupon creates an artificial holiday right next
to the reference electrode
it is electrically bonded to the pipe and reaches
the same potential as the pipe
when it is disconnected from the system, a
measurement should be taken before the coupon
depolarizes (instant disconnect)
the residual voltage drop in this type
measurement is usually insignificant
What CP Coupons Do
Allow measurement of instant disconnect
(IR drop free) potentials without having to
interrupt cathodic protection current to
structure
Some Currents Cannot Be
Interrupted
Sacrificial anodes
Telluric currents
Stray currents
Galvanic currents
Foreign rectifiers
In these circumstances, CP coupons may be the only way
to measure potentials free of IR Drop error.
Industry Discussions Areas
Size
Material
Shape
Orientation
Placement
TG210 meeting at NACE TCC
Coupon Size
If it is too large . . .
Sac. anode system may not supply sufficient current
Current distribution to the structure may be affected
If it is too small . . .
It could depolarize too quickly to get a valid reading
Ideal size ...
Same as the largest expected holiday
Goldilocks
criterion
Coupon Material
Ideally
identical to pipe
Realistically ... carbon steel
age without CP a couple of months
then, let it polarize a couple of months
Coupon Shape
Available shapes
Cylindrical
Ring
Disc
Plate
Rod
Which is best?
mine
Coupon Location and
Orientation
Readings are affected by
proximity to anode
soil environment
shielding by structure
shielding by foreign objects
Coupons can be stand-alone
reference coupon structure
Place coupon very close to the
reference and in the same
backfill as the structure.
Coupons can be attached to permanent
reference electrodes
reference coupon structure
Place coupon very close to the
reference and in the same
backfill as the structure.
Reference Electrode Array
Anode
Rod Coupon
Ref.: Wilkin, Dimond & Ansuini
NACE Conference Paper 03200
-1.1
-0.9
-0.7
-0.5
-0.3
24-May 13-Jul 1-Sep 21-Oct 10-Dec
V
o
l
t
s
Cell #1 Coupon #7
Two ways of making IR Drop Free
Readings
Disconnect the
rectifier (Cell #1)
Disconnect the
coupon (Coupon #7)
Ref.: Wilkin, Dimond & Ansuini
NACE Conference Paper 03200
Coupons can be attached to
test stations
reference
coupon
structure
A permanent reference electrode can
be installed in the test station riser.
Concentric Coupon
Coupon assembly is fitted to a test
station riser. Reference electrode is
inside the riser and measures potential
through the slot membrane.
Tank used for
prototype coupon
testing.
Ref.: Ansuini & Dimond
NACE Conference Paper 05039
1/2" rod coupon @ 4"
-1.20
-1.10
-1.00
-0.90
-0.80
-0.70
-0.60
1/8 coupon @ 4" facing structure
-1.20
-1.10
-1.00
-0.90
-0.80
-0.70
-0.60
Comparison of Rod and Concentric Coupons
Coupon
interrupted
Rectifier
interrupted
Current-on readings with a rod coupon
contained about 300 mV IR Drop.
Disconnecting the coupon eliminated
about a third of it.
Current-on readings with a concentric
coupon contained about 30 mV IR Drop.
Disconnecting the coupon eliminated
virtually all of it.
Ref.: Ansuini & Dimond
NACE Conference Paper 05039
Interrupting CP Current
Connect switch
between coupon
and structure leads
Hold magnet
next to switch to
interrupt current
Limitations of CP Coupons
Coupons may not give reliable data when used for:
1) Native potential
2) CP Current Density
3) Depolarization
because the coupon may not be the same material,
it may not be in the same electrolyte and
it may not be the same distance from the anode.
Conclusions
Cathodic protection coupons can be used to obtain
instant-disconnect (IR drop free) potentials of any
structure.
Concentric CP coupons can make IR drop free potential
measurements without disconnecting either the coupon
or the rectifier.
Coupons should not be used for depolarization without
additional qualification studies.
Contact
Information
[email protected]
www.edi-cp.com