BIOMOLECULES DPP-01

BIOMOLECULES DPP-01
1. Given structure is ?
(A) Aldopentose (B) Aldohexose (C) Ketopentose (D) Aldotetrose
(A) Aldopentose (B) Aldohexose (C) Ketoheptose (D) Ketohexose
(A) Aldopentose (B) Ketohexose (C) Ketoheptose (D) Aldohexose
4. Which of the following is D-glyceraldehyde ?
(A) (B) (C) (D) A and B both
2 Br
5. D-Glucose ¾¾¾®
H2O
(A) Aldonic acid (B) Adaric acid (C) Alditol (D) Tartaric acid
6. D-Glucose will form same osazone with

(A) D-Mannose (B) D-Fructose (C) D-Allose (D) Both (A) and (B)
7. Relation between D-Glucose & D-Fructose is
(A) C2-epimer (B) C3-epimer
(C) Functional isomer (D) Positional isomers
8. Which of following is Oligosaccharides ?

(A) Glucose (B) Fructose (C) Sucrose (D) Starch
9. Which of following is D-Glyceraldehyde?
(A) (B) (C) (D)
10. C2-epimer of D-Glucose is

(A) D-Gulose (B) D-Allose (C) D-Altrose (D) D-Mannose
11. C3-epimer of D-Glucose is

(A) D-Gulose (B) D-Allose (C) D-Altrose (D) D-Mannose
12. Which of following Carbohydrate is Aldohexose?

(A) D-Mannose (B) D-Glucose (C) D-Fructose (D) Both (A) and (B)
Br2
13. D-Glucose ¾¾¾®
H2O
Product in known as
(A) D-Glucitol (B) D-Gluconic acid (C) D-Glucaric acid (D) Tartaric acid
14. D-Glucose D-Fructose (X)

X is
(A) D-Allose (B) D-Altrose (C) D-Mannose (D) D-Glucose
5HIO 4
15. D-Glucose ¾¾ ¾¾®
Product is
(A) 4HCO2H, HCHO (B) 5HCO2H, HCHO (C) 4HCO2H, CO2, HCHO (D) 5HCHO, HCO2H
16. Which of following pair give same Osazone
(A) D-Glucose, Fructose (B) D-Glucose, D-Mannose
(C) D-Allose, D-Altrose (D) All
Comprehension (Q.17 to Q.20)
(A) (B)
(C) (D)
17. Relation between (A) and (B) is

(A) Anomers (B) Positional isomer (C) Functional isomer (D) Enantiomer
18. Structure of b-D-Glucopyranose is
(A) A (B) B (C) C (D) D
19. Which of compound not undergo mutarotation
(A) A (B) B (C) C (D) None
20. How many mole of acetic anhydride will consumed when it reacts with compound (A)
(A) 3 (B) 4 (C) 5 (D) 6
(i) NaBH
4®
21. ¾¾ ¾ ¾¾ (P)
+
(ii) H , H2O
Number of stereoisomer of product (P) is :

(A) 4 (C) 12 (D) 16
22. The main structural features of proteins is
(A) Ester linkage (B) Ether linkage
(C) Peptide linkage (D) All of these
23. Which compond can exist in a dipolar (Zwitter ion) structure?
(A) C6H5CH2CH(N = CH2)COOH (B) (CH3)2CHCH(NH2)COOH
(C) C6H5CONHCH2COOH (D) HOOCCH2CH2COCOOH
24. Vitamins C is chemically
(A) Ascorbic acid (B) Citric acid (C) Aspirin (D) Aspartic acid
25. In an amino acid, the carboxylic group ionises at pKa1 = 2.34 and ammonium ion at pKa2 = 9.60. The iso
electric point of the amino acid is at pH
(A) 5.97 (B) 2.34 (C) 9.60 (D) 6.97
26. Which statement is incorrect about peptide bond?
(A) C—N bond length in proteins is longer than usual bond length of C—N bond
(B) Spectroscopic analysis shows planar structure of bond
(C) C—N bond length in proteins is smaller than usual bond length of C—N bond
(D) None of these
27. A triglyceride can have how many different acyl groups?

(A) 3 (B) 2 (C) 1 (D) 4
44. Glycosidic linkage is present in

(A) Sucrose (B) Maltose (C) Lactose (D) All
45. Which of following amino acid has lowest iso electric point ?
(A) Lysine (B) Aspartic acid
(C) Glycine (D) Alanine
46. Protein on hydrolysis give
(A) a-amino acid (B) b-amino acid (C) g-amino acid (D) All
47. Which of following amino acid is optically inactive

(A) Glycine (B) Alanine (C) Valine (D) Leucine
48. Peptide linkage is present in
(A) Protein (B) Nylon-6, 6 (C) Sucrose (D) both (A) & (B)
49. Product obtained by hydroysis of lactose are
(A) Glucose & fructose (B) Glucose, mannose
(C) Mannose & fructose (D) Galactose, Glucose
50. Which of following is amino acid?
(A) NH2—CH2—CO2H (B) NH2—CH2—CH2—CO2H
(C) NH2—CH2—CH2—CH2—CO2H
51. Which of following is structure of b-D-Glucopyranose?
(A) (B)
(C) (D)
55. Maximum number of monosaccharide units present in oligosaccharides is

(A) 8 (B) 15 (C) 10 (D) 40
56. Which one of the following is non-reducing sugar?
(A) Glucose (B) Arabinose (C) Fructose (D) Sucrose
57. Which one of the following is reducing sugar?
(A) Starch (B) Cellulose
(C) Glycogen (D) Fructose
58. In solution glucose exist in how many isomeric forms?
(A) Two (B) Sixteen (C) Three (D) Four
59. Reducing property of monosaccharide is due to the presence of

(A) —OH group (B) Keto group
(C) Acetal group (D) Anomeric hydroxyl group (a Hemiacetal)
60. Which one of the following carbohydrates will show mutarotation ?(B) Maltose
(A) Sucrose (D) Both
(C) Lactose (B) & (C)
61. Glucose and mannose are
(A) Anomers (B) Positional isomers
(C) Functional isomers (D) Epimers
62. Which of the following pairs are epimers
(A) and (B) and
(C) and (D) and
63. Glucose molecule reacts with 'X' number of molecule of phenylhydrazine to yield osazone. The value of X is
(A) Three (B) Two (C) One (D) Four
64. Which of the following reagents cannot distinguish between glucose and fructose?
(A) Tollen's reagent (B) Fehling's solution (C) Benedict's solution (D) All of these
65. Cellulose is a polymer of

(A) Glucose (B) Fructose (C) Ribose (D) Sucrose
66. Which of the following is an example of Ketohexose?

(A) Mannose (B) Galactose (C) Maltose (D) Fructose
67. When glucose reacts with bromine water, the main product is
(A) Acetic acid (B) Saccharic acid (C) Glyceraldehyde (D) Gluconic acid
68. All monosaccharide ....... Tollen's reagent
(A) oxidises (B) reduces (C) condense with (D) add to
69. The number of chiral centres in (+) glucose is
(A) 4 (B) 3 (C) 2 (D) 1
70. Protein is polymer of
(A) Amino acid (B) a-Amino acid (C) g-Amino acid (D) b-Amino acid
71. Amino acid may be

(A) Neutral (B) Basic (C) Acidic (D) Any one of these
72. The given structure of a-amino acid will exist at which pH ?
(A) 7 (B) 14 (C) 0 (D) 12
73. Peptide linkage is
(A) (B) (C) (D)

74. Complete hydrolysis of cellulose gives
(A) L-glucose (B) D-fructose (C) D-ribose (D) D-glucose
75. Number of chiral carbons in b-D-(+)-glucose is
(A) six (B) three (C) four (D) five
76. The pair of compounds in which both the compounds give positive test with Tollen's reagent is
(A) glucose and sucrose (B) fructose and sucrose
(C) acetophenone and hexanal (D) glucose and fructose
77. Among cellulose, polyvinyl chloride, nylon, and natural rubber, the polymer in which the intermolecular force
of attraction is the weakest is
(A) polyvinyl chloride (B) natural rubber (C) nylon (D) cellulose
78. D-Glucose & L-Glucose are
(A) Enantiomers (B) Diastereomers (C) Epimers (D) Anomers
79. Identify the pair of Epimers
(A) D-Glucose & D-Fructose (B) D-Glucose & L-Glucose
(C) D-Glucose & D-Mannose (D) D-Glucose & D-Gulose
80. The number of Stereogenic centres in a-D-Glucose are
(A) 4 (B) 5 (C) 3 (D) 2
81. a-D-Glucose and b-D-Glucose are
(A) Epimers (B) Anomers (C) Enantiomers (D) Acetals
82. Identify the non reducing sugar
3
3
(A) (B)
3
3
(C) (D)
1. A 2. C 3. D 4. C 5. A 6. D 7. C
8. C 9. B 10. D 11. B 12. D 13. B 14. C
15. B 16. D 17. A 18. B 19. D 20. C 21. B
22. C 23. B 24. A 25. A 26. A 27. A
44. D 45. B 46. A 47. A 48. D 49. D

50. A 51. B 52. B 53. A 54. B 55. C 56. D
57. D 58. C 59. D 60. D 61. D 62. C 63. A
64. D 65. A 66. D 67. D 68. B 69. A 70. B
71. D 72. C 73. D 74. D 75. D 76. D 77. B
78. A 79. C 80. B 81. B 82. D

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(A) Aldopentose (B) Aldohexose (C) Ketopentose (D) Aldotetrose

(A) Aldopentose (B) Aldohexose (C) Ketoheptose (D) Ketohexose

(A) Aldopentose (B) Ketohexose (C) Ketoheptose (D) Aldohexose

4. Which of the following is D-glyceraldehyde ?

(A) (B) (C) (D) A and B both

6. D-Glucose will form same osazone with

8. Which of following is Oligosaccharides ?

9. Which of following is D-Glyceraldehyde?

(A) (B) (C) (D)

10. C2-epimer of D-Glucose is

11. C3-epimer of D-Glucose is

12. Which of following Carbohydrate is Aldohexose?

14. D-Glucose D-Fructose (X)

Comprehension (Q.17 to Q.20)

17. Relation between (A) and (B) is

Number of stereoisomer of product (P) is :

27. A triglyceride can have how many different acyl groups?

44. Glycosidic linkage is present in

47. Which of following amino acid is optically inactive

51. Which of following is structure of b-D-Glucopyranose?

55. Maximum number of monosaccharide units present in oligosaccharides is

59. Reducing property of monosaccharide is due to the presence of

(A) and (B) and

(C) and (D) and

65. Cellulose is a polymer of

66. Which of the following is an example of Ketohexose?

71. Amino acid may be

(A) 7 (B) 14 (C) 0 (D) 12

73. Peptide linkage is

(A) (B) (C) (D)

82. Identify the non reducing sugar

44. D 45. B 46. A 47. A 48. D 49. D

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