SAFETY DATA SHEET

Section 1. Identification
Product name : CRW37 CORROSION INHIBITOR
Product code : CRW37

Relevant identified uses of the substance or mixture and uses advised against
Identified uses : Corrosion inhibitor

Print date : 1/12/2023

Validation date : 1/12/2023
Version : 1.03

Supplier's details : Baker Petrolite LLC

12645 W. Airport Blvd.
Sugar Land, TX 77478
For Product Information/SDSs Call: 800-231-3606
(8:00 a.m. - 5:00 p.m. CST, Monday - Friday) 281-276-5400

Emergency telephone : CHEMTREC: 800-424-9300 (U.S. 24 hour)

number (with hours of Baker Petrolite: 800-231-3606
operation) (001)281-276-5400
CHEMTREC Int'l 01-703-527-3887 (International 24 hour)
BPC

Section 2. Hazards identification

OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Classification of the : FLAMMABLE LIQUIDS - Category 3
substance or mixture ACUTE TOXICITY (oral) - Category 4
SERIOUS EYE DAMAGE - Category 1
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) - Category 1
AQUATIC HAZARD (ACUTE) - Category 2

GHS label elements

Hazard pictograms :

Signal word : Danger

Hazard statements : Flammable liquid and vapor.
Harmful if swallowed.
Causes serious eye damage.
Causes damage to organs. (optic nerve)
Toxic to aquatic life.
Precautionary statements

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Section 2. Hazards identification

Prevention : Wear protective gloves: > 8 hours (breakthrough time): Nitrile or Neoprene gloves..
Wear protective clothing. Wear eye or face protection. Keep away from heat, hot
surfaces, sparks, open flames and other ignition sources. No smoking. Use explosion-
proof electrical, ventilating or lighting equipment. Use non-sparking tools. Take action
to prevent static discharges. Keep container tightly closed. Avoid release to the
environment. Do not breathe vapor. Do not eat, drink or smoke when using this
product. Wash thoroughly after handling.
Response : IF exposed: Call a POISON CENTER or doctor. IF SWALLOWED: Call a POISON
CENTER or doctor if you feel unwell. Rinse mouth. IF ON SKIN (or hair): Take off
immediately all contaminated clothing. Rinse skin with water. IF IN EYES: Rinse
cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing. Immediately call a POISON CENTER or doctor.
Storage : Store locked up. Store in a well-ventilated place. Keep cool.
Disposal : Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Supplemental label : Avoid contact with skin and clothing. Wash thoroughly after handling.
elements
Hazards not otherwise : Prolonged or repeated contact may dry skin and cause irritation.
classified

Section 3. Composition/information on ingredients

Substance/mixture : Mixture

Ingredient name % CAS number

Methanol 10 - 20 67-56-1
Quaternary ammonium compounds 1-5 Trade secret.
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
There are no ingredients present which, within the current knowledge of the supplier and in the concentrations
applicable, are classified and hence require reporting in this section.
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified and hence require reporting in this section.

Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures

Description of necessary first aid measures
Eye contact : Get medical attention immediately. Call a poison center or physician. Immediately flush
the eye(s) continuously with lukewarm, gently flowing water for at least 20-60 minutes
while holding the eyelid(s) open. Check for and remove any contact lenses. Chemical
burns must be treated promptly by a physician.
Inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. If
not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial
respiration or oxygen by trained personnel. If unconscious, place in recovery position
and get medical attention immediately. Maintain an open airway. In case of inhalation
of decomposition products in a fire, symptoms may be delayed. The exposed person
may need to be kept under medical surveillance for 48 hours.
Skin contact : Get medical attention immediately. Call a poison center or physician. Wash affected
area with soap and mild detergent for at least 20 - 60 minutes. Wash skin thoroughly
with soap and water or use recognized skin cleanser. Remove contaminated clothing
and shoes. Wash contaminated clothing thoroughly with water before removing it, or
wear gloves. Chemical burns must be treated promptly by a physician. Wash clothing
before reuse. Clean shoes thoroughly before reuse.

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Section 4. First aid measures

Ingestion : Wash out mouth with water. If material has been swallowed and the exposed person is
conscious, give small quantities of water to drink. Do not induce vomiting unless
directed to do so by medical personnel. If vomiting occurs, the head should be kept low
so that vomit does not enter the lungs. Never give anything by mouth to an unconscious
person. If unconscious, place in recovery position and get medical attention
immediately. Maintain an open airway.

Most important symptoms/effects, acute and delayed

Potential acute health effects
Eye contact : Causes serious eye damage.
Inhalation : Causes damage to organs following a single exposure if inhaled.
Skin contact : Causes damage to organs following a single exposure in contact with skin. Defatting to
the skin. May cause skin dryness and irritation.
Ingestion : Harmful if swallowed. Causes damage to organs following a single exposure if
swallowed.
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:,pain,watering,redness
Inhalation : No specific data.
Skin contact : pain or irritation,redness,dryness,cracking,blistering may occur
Ingestion : Adverse symptoms may include the following:,stomach pains

Indication of immediate medical attention and special treatment needed, if necessary

Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments : No specific treatment.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves.

See toxicological information (Section 11)

Section 5. Fire-fighting measures

Extinguishing media
Suitable extinguishing : Use dry chemical, CO₂, alcohol-resistant foam or water spray (fog).
media
Unsuitable extinguishing : Do not use water jet.
media

Specific hazards arising : Flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a
from the chemical fire or if heated, a pressure increase will occur and the container may burst, with the risk
of a subsequent explosion. The vapor/gas is heavier than air and will spread along the
ground. Vapors may accumulate in low or confined areas or travel a considerable
distance to a source of ignition and flash back. This material is toxic to aquatic life. Fire
water contaminated with this material must be contained and prevented from being
discharged to any waterway, sewer or drain.
Hazardous thermal : carbon dioxide,carbon monoxide,nitrogen oxides
decomposition products

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Section 5. Fire-fighting measures

Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire-exposed containers cool.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Section 6. Accidental release measures

Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources.
No flares, smoking or flames in hazard area. Do not breathe vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment.
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".

Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to
the environment if released in large quantities.

Methods and materials for containment and cleaning up

Small spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively,
or if water-insoluble, absorb with an inert dry material and place in an appropriate waste
disposal container. Dispose of via a licensed waste disposal contractor.
Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and
explosion-proof equipment. Approach release from upwind. Prevent entry into sewers,
water courses, basements or confined areas. Wash spillages into an effluent treatment
plant or proceed as follows. Contain and collect spillage with non-combustible,
absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in
container for disposal according to local regulations (see Section 13). Dispose of via a
licensed waste disposal contractor. Contaminated absorbent material may pose the
same hazard as the spilled product. Note: see Section 1 for emergency contact
information and Section 13 for waste disposal.
If RQ (Reportable Quantity) is exceeded, report to National Spill Response Office at 1-800-424-8802.

Section 7. Handling and storage

Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Do not get in eyes or
on skin or clothing. Do not breathe vapor or mist. Do not ingest. Avoid release to the
environment. Use only with adequate ventilation. Wear appropriate respirator when
ventilation is inadequate. Do not enter storage areas and confined spaces unless
adequately ventilated. Keep in the original container or an approved alternative made
from a compatible material, kept tightly closed when not in use. Store and use away
from heat, sparks, open flame or any other ignition source. Use explosion-proof
electrical (ventilating, lighting and material handling) equipment. Use only non-sparking
tools. Take precautionary measures against electrostatic discharges. Empty containers
retain product residue and can be hazardous. Do not reuse container.

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Section 7. Handling and storage

Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.

Conditions for safe storage, : Store in accordance with local regulations. Store in a segregated and approved area.
including any Store in a dry, cool and well-ventilated area, away from incompatible materials (see
incompatibilities Section 10). Store in original container, protected from direct sunlight. Store locked up.
Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly
closed and sealed until ready for use. Containers that have been opened must be
carefully resealed and kept upright to prevent leakage. Do not store in unlabeled
containers. Use appropriate containment to avoid environmental contamination. See
Section 10 for incompatible materials before handling or use.

Section 8. Exposure controls/personal protection

Control parameters
Occupational exposure limits
Ingredient name Exposure limits
Methanol ACGIH TLV (United States, 1/2022). Absorbed through
skin.
STEL: 328 mg/m³, 0 times per shift, 15 minutes.
STEL: 250 ppm, 0 times per shift, 15 minutes.
TWA: 262 mg/m³, 0 times per shift, 8 hours.
TWA: 200 ppm, 0 times per shift, 8 hours.
NIOSH REL (United States, 10/2020). Absorbed
through skin.
STEL: 325 mg/m³, 0 times per shift, 15 minutes.
STEL: 250 ppm, 0 times per shift, 15 minutes.
TWA: 260 mg/m³, 0 times per shift, 10 hours.
TWA: 200 ppm, 0 times per shift, 10 hours.
OSHA PEL (United States, 5/2018).
TWA: 260 mg/m³, 0 times per shift, 8 hours.
TWA: 200 ppm, 0 times per shift, 8 hours.
OSHA PEL 1989 (United States, 3/1989). Absorbed
through skin.
STEL: 325 mg/m³, 0 times per shift, 15 minutes.
STEL: 250 ppm, 0 times per shift, 15 minutes.
TWA: 260 mg/m³, 0 times per shift, 8 hours.
TWA: 200 ppm, 0 times per shift, 8 hours.
Quaternary ammonium compounds None.
Consult local authorities for acceptable exposure limits.
If OSHA permissible exposure levels are shown above they are the OSHA 1989 levels or are from subsequent
OSHA regulatory actions. Although the 1989 levels have been vacated the 11th Circuit Court of Appeals, Baker
Hughes recommends that these lower exposure levels be observed as reasonable worker protection.

Appropriate engineering : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
controls other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.

Individual protection measures

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Section 8. Exposure controls/personal protection

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Eye/face protection : Wear chemical safety goggles. When transferring material wear face-shield in addition
to chemical safety goggles. If inhalation hazards exist, a full-face respirator may be
required instead.
Hand protection : Chemical-resistant gloves: Nitrile or Neoprene gloves.
Skin protection : Wear long sleeves and chemical resistant apron to prevent repeated or prolonged skin
contact.
Respiratory protection : If a risk assessment indicates it is necessary, use a properly fitted supplied air respirator
complying with an approved standard. Respirator selection must be based on known or
anticipated exposure levels, the hazards of the product and the safe working limits of
the selected respirator.

Section 9. Physical and chemical properties

The conditions of measurement of all properties are at standard temperature and pressure unless otherwise indicated.

Appearance
Physical state : Liquid.
Color : Yellow.
Odor : Amine like.
Odor threshold : Not available.
pH : 7.8 to 8.2 [Conc. (% w/w): 5%]
: 5% in water
Melting point/freezing point : Not available.
Initial Boiling Point : Not available.
Boiling point, initial boiling : Not available.
point, and boiling range
Flash point : Closed cup: 39°C (102.2°F) [SFCC]
Burning time : Not applicable.
Burning rate : Not applicable.
Evaporation rate : Not available.
Flammability : Flammable in the presence of the following materials or conditions: open flames, sparks
and static discharge and heat.
Lower and upper explosion : Lower: 6%
limit/flammability limit Upper: 36.5%
Vapor pressure : 35.2 kPa (263.7 mm Hg, 5.1 psig) @ 54.4°C, 130 F (Reid)
Relative vapor density : >1 [Air = 1]
Relative density : 1.02 (16°C)
Density : 8.5 (lbs/gal)
Solubility in water : Soluble
Partition coefficient: n- : Not applicable.
octanol/water
Auto-ignition temperature : Not available.
Decomposition temperature : Not available.
Viscosity : Dynamic (16°C): 8.7 cP

VOC : Not available.

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Section 9. Physical and chemical properties

Pour Point : -23°C (-9.4°F)
Particle characteristics
Median particle size : Not applicable.

Section 10. Stability and reactivity

Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Chemical stability : The product is stable.

Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions

Conditions to avoid : Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not
allow vapor to accumulate in low or confined areas.

Incompatible materials : Reactive or incompatible with the following materials: oxidizing materials and reducing
materials.
Methanol is incompatible and may react with acetyl bromide, alkyl aluminum solutions,
beryllium hydride, boron trichloride, nitric acid, cyanuric chloride, dichloromethane,
diethylzinc, metals (granulated forms of aluminum and magnesium – including
aluminum and zinc salts), phosphorus III oxide, and potassium tert-butoxide.

Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should
products not be produced.

Section 11. Toxicological information

Information on toxicological effects
Acute toxicity
Product/ingredient name Result Species Dose Exposure
Methanol LC50 Inhalation Gas. Rat 145000 ppm 1 hours
LC50 Inhalation Gas. Rat 64000 ppm 4 hours
LD50 Dermal Rabbit 15800 mg/kg -
LD50 Oral Human 500 mg/kg -
LD50 Oral Rat 5600 mg/kg -
Irritation/Corrosion
No available toxicity data.
Sensitization
No available toxicity data.
Mutagenicity
No available toxicity data.
Carcinogenicity
Classification
No available toxicity data.
Reproductive toxicity
No available toxicity data.
Teratogenicity

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Section 11. Toxicological information

No available toxicity data.
Specific target organ toxicity (single exposure)
Name Category Route of Target organs
exposure
Methanol Category 1 oral optic nerve

Specific target organ toxicity (repeated exposure)

Not applicable.
Aspiration hazard
Not available.

Information on the likely : Routes of entry anticipated: Dermal, Inhalation.

routes of exposure
Potential acute health effects
Eye contact : Causes serious eye damage.
Inhalation : Causes damage to organs following a single exposure if inhaled.
Skin contact : Causes damage to organs following a single exposure in contact with skin. Defatting to
the skin. May cause skin dryness and irritation.
Ingestion : Harmful if swallowed. Causes damage to organs following a single exposure if
swallowed.

Symptoms related to the physical, chemical and toxicological characteristics

Eye contact : Adverse symptoms may include the following:,pain,watering,redness
Inhalation : No specific data.
Skin contact : pain or irritation,redness,dryness,cracking,blistering may occur
Ingestion : Adverse symptoms may include the following:,stomach pains

Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Long term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Potential chronic health effects
General : Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/or
dermatitis.
Carcinogenicity : No known significant effects or critical hazards.
Mutagenicity : No known significant effects or critical hazards.
Reproductive toxicity : No known significant effects or critical hazards.

Numerical measures of toxicity

Acute toxicity estimates

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Section 11. Toxicological information

Product/ingredient name Oral (mg/ Dermal Inhalation Inhalation Inhalation
kg) (mg/kg) (gases) (vapors) (dusts and
(ppm) (mg/l) mists) (mg/
l)
CRW37 CORROSION INHIBITOR 659.7 2113.7 Not 21.1 Not
available. available.
Methanol 100 300 64000 3 Not
available.
Quaternary ammonium compounds 500 Not Not Not Not
available. available. available. available.

Section 12. Ecological information

Toxicity
Product/ingredient name Result Species Exposure
Methanol Acute EC50 16.912 mg/l Marine water Algae - Ulva pertusa 96 hours
Acute EC50 10000000 µg/l Fresh water Daphnia - Daphnia magna 48 hours
Acute LC50 2500000 µg/l Marine water Crustaceans - Crangon crangon 48 hours
Acute LC50 100 mg/l Fresh water Fish - Pimephales promelas 96 hours
Chronic NOEC 9.96 mg/l Marine water Algae - Ulva pertusa 96 hours

Persistence and degradability

Not available.

Bioaccumulative potential
Product/ingredient name LogPow BCF Potential
Methanol -0.77 <10 low

Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)

Other adverse effects : No known significant effects or critical hazards.

Section 13. Disposal considerations

Disposal methods : Dispose of surplus and non-recyclable products via a licensed waste disposal contractor.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Vapor from product residues may create a highly flammable or
explosive atmosphere inside the container. Do not cut, weld or grind used containers
unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material
and runoff and contact with soil, waterways, drains and sewers.

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Section 14. Transport information

DOT Classification TDG Classification IMDG IATA
UN number UN1993 UN1993 UN1993 UN1993

UN proper FLAMMABLE LIQUID, FLAMMABLE LIQUID, FLAMMABLE LIQUID, FLAMMABLE LIQUID,

shipping name N.O.S. (Contains: N.O.S. (Contains: N.O.S. (Contains: N.O.S. (Contains:
Methanol) Methanol) Methanol) Methanol)
Transport 3 3 3 3
hazard class(es)

Packing group III III III III

Environmental No. No. No. No.
hazards

Additional information
DOT Classification : This product may be re-classified as "Combustible Liquid," unless transported by vessel
or aircraft. Non-bulk packages (less than or equal to 119 gal) of combustible liquids are
not regulated as hazardous materials in package sizes less than the product reportable
quantity.
Reportable quantity 35228.6 lbs / 15993.8 kg [4142.3 gal / 15680.2 L]. Package sizes
shipped in quantities less than the product reportable quantity are not subject to the RQ
(reportable quantity) transportation requirements.
TDG Classification : Product classified as per the following sections of the Transportation of Dangerous
Goods Regulations: 2.18-2.19 (Class 3).
IMDG : Emergency schedules F-E S-D

Special precautions for user : Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.

Transport in bulk according : Not available.

to IMO instruments
DOT Reportable Methanol, 4145 gal of this product.
Quantity

Marine pollutant Not available.

North-America NAERG : 128

Section 15. Regulatory information

U.S. Federal regulations : TSCA 12(b) one-time export: No products were found.
TSCA 12(b) annual export notification: No products were found.
United States inventory (TSCA 8b): All components are active or exempted.
Clean Water Act (CWA) 307: No products were found.
Clean Water Act (CWA) 311: No products were found.
United States - Clean Air Act Section 112(b) Hazardous Air Pollutants (HAPs) :

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Section 15. Regulatory information

List name Status Ingredient name Name on list Conc.
United States - Clean Air Act Section Listed Methanol Methanol 10 - 20
112(b) Hazardous Air Pollutants
(HAPs)

SARA 302/304 : No products were found.

SARA 311/312
Classification : FLAMMABLE LIQUIDS - Category 3
ACUTE TOXICITY (oral) - Category 4
SERIOUS EYE DAMAGE - Category 1
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) - Category 1
HNOC - Defatting irritant
SARA 313
Product name CAS number %

Supplier notification Methanol 67-56-1 10 - 20

California Prop. 65
WARNING: This product can expose you to methanol, which is known to the State of California to cause birth
defects or other reproductive harm. For more information go to www.P65Warnings.ca.gov.
Canada
Canada (CEPA DSL): : All components are listed or exempted.

Section 16. Other information

National Fire Protection Association (U.S.A.)

2 Flammability BPC
Health 2 0 Instability
Special

History
Date of printing : 1/12/2023
Key to abbreviations : ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
N/A = Not available
SGG = Segregation Group
UN = United Nations
Indicates information that has changed from previously issued version.
Notice to reader
NOTE: The information on this SDS is based on data which is considered to be accurate. Baker Hughes, however,
makes no guarantees or warranty, either expressed or implied of the accuracy or completeness of this
information.

The conditions or methods of handling, storage, use and disposal of the product are beyond our control and may
be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim
liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or
disposal of this product.
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Section 16. Other information

This SDS was prepared and is to be used for this product. If the product is used as a component in another
product, this SDS information may not be applicable.

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