SAFETY DATA SHEET

Aqua Ammonia (20-30%)

Section 1. Identification
GHS product identifier : Aqua Ammonia (20-30%)
Other means of : Aqua Ammonia, Ammonium Hydroxide
identification
Product type : Liquid.
Product use : Synthetic/Analytical chemistry.
Synonym : Aqua Ammonia, Ammonium Hydroxide
SDS # : 001195
Supplier's details : Airgas USA, LLC and its affiliates
259 North Radnor-Chester Road
Suite 100
Radnor, PA 19087-5283
1-610-687-5253

24-hour telephone : 1-866-734-3438

Section 2. Hazards identification

OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Classification of the : SKIN CORROSION - Category 1B
substance or mixture SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract
irritation) - Category 3
AQUATIC HAZARD (ACUTE) - Category 1

GHS label elements

Hazard pictograms :

Signal word : Danger

Hazard statements : May displace oxygen and cause rapid suffocation.
Causes severe skin burns and eye damage.
May cause respiratory irritation.
Very toxic to aquatic life.
Precautionary statements
General : Read label before use. Keep out of reach of children. If medical advice is needed,
have product container or label at hand.
Prevention : Wear protective gloves. Wear protective clothing. Wear eye or face protection. Use
only outdoors or in a well-ventilated area. Avoid release to the environment. Avoid
breathing vapor.
Response : Collect spillage. Immediately call a POISON CENTER or doctor. IF SWALLOWED:
Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Take off immediately all
contaminated clothing. Rinse skin with water. IF IN EYES: Rinse cautiously with water
for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Storage : Store locked up. Store in a well-ventilated place. Keep container tightly closed.
Disposal : Dispose of contents and container in accordance with all local, regional, national and
international regulations.
Hazards not otherwise : None known.
classified

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Section 3. Composition/information on ingredients

Substance/mixture : Substance
Other means of : Aqua Ammonia, Ammonium Hydroxide
identification
Product code : 001195

CAS number/other identifiers

CAS number : Not available.
Ingredient name % CAS number
ammonium hydroxide 100 1336-21-6
ammonia 20-30 7664-41-7
WATER 70-80 7732-18-5
Any concentration shown as a range is to protect confidentiality or is due to batch variation.
There are no additional ingredients present which, within the current knowledge of the supplier and in the
concentrations applicable, are classified as hazardous to health or the environment and hence require reporting
in this section.
Occupational exposure limits, if available, are listed in Section 8.

Section 4. First aid measures

Description of necessary first aid measures
Eye contact : Get medical attention immediately. Call a poison center or physician. Immediately flush
eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and
remove any contact lenses. Continue to rinse for at least 10 minutes. Chemical burns
must be treated promptly by a physician.
Inhalation : Get medical attention immediately. Call a poison center or physician. Remove victim to
fresh air and keep at rest in a position comfortable for breathing. If it is suspected that
fumes are still present, the rescuer should wear an appropriate mask or self-contained
breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest
occurs, provide artificial respiration or oxygen by trained personnel. It may be
dangerous to the person providing aid to give mouth-to-mouth resuscitation. If
unconscious, place in recovery position and get medical attention immediately. Maintain
an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of
inhalation of decomposition products in a fire, symptoms may be delayed. The exposed
person may need to be kept under medical surveillance for 48 hours.
Skin contact : Get medical attention immediately. Call a poison center or physician. Flush
contaminated skin with plenty of water. Remove contaminated clothing and shoes.
Wash contaminated clothing thoroughly with water before removing it, or wear gloves.
Continue to rinse for at least 10 minutes. Chemical burns must be treated promptly by a
physician. Wash clothing before reuse. Clean shoes thoroughly before reuse.
Ingestion : Get medical attention immediately. Call a poison center or physician. Wash out mouth
with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a
position comfortable for breathing. If material has been swallowed and the exposed
person is conscious, give small quantities of water to drink. Stop if the exposed person
feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do
so by medical personnel. If vomiting occurs, the head should be kept low so that vomit
does not enter the lungs. Chemical burns must be treated promptly by a physician.
Never give anything by mouth to an unconscious person. If unconscious, place in
recovery position and get medical attention immediately. Maintain an open airway.
Loosen tight clothing such as a collar, tie, belt or waistband.

Most important symptoms/effects, acute and delayed

Potential acute health effects
Eye contact : No known significant effects or critical hazards.
Inhalation : May cause respiratory irritation.
Skin contact : Causes severe burns.
Frostbite : Try to warm up the frozen tissues and seek medical attention.

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Section 4. First aid measures

Ingestion : No known significant effects or critical hazards.
Over-exposure signs/symptoms
Eye contact : Adverse symptoms may include the following:, pain, watering, redness
Inhalation : Adverse symptoms may include the following:, respiratory tract irritation, coughing
Skin contact : Adverse symptoms may include the following:, pain or irritation, redness, blistering may
occur
Ingestion : Adverse symptoms may include the following:, stomach pains

Indication of immediate medical attention and special treatment needed, if necessary

Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
Specific treatments : No specific treatment.
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self-contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves.

See toxicological information (Section 11)

Section 5. Fire-fighting measures

Extinguishing media
Suitable extinguishing : Use an extinguishing agent suitable for the surrounding fire.
media
Unsuitable extinguishing : None known.
media

Specific hazards arising : In a fire or if heated, a pressure increase will occur and the container may burst. This
from the chemical material is very toxic to aquatic life. Fire water contaminated with this material must be
contained and prevented from being discharged to any waterway, sewer or drain.
Hazardous thermal : Decomposition products may include the following materials:
decomposition products nitrogen oxides

Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable
training.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Section 6. Accidental release measures

Personal precautions, protective equipment and emergency procedures
For non-emergency : No action shall be taken involving any personal risk or without suitable training.
personnel Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Do not breathe vapor or mist.
Provide adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Put on appropriate personal protective equipment.
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in
Section 8 on suitable and unsuitable materials. See also the information in "For non-
emergency personnel".

Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to
the environment if released in large quantities. Collect spillage.

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Section 6. Accidental release measures

Methods and materials for containment and cleaning up
Small spill : Stop leak if without risk. Move containers from spill area. Dilute with water and mop up
if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and
place in an appropriate waste disposal container. Dispose of via a licensed waste
disposal contractor.
Large spill : Stop leak if without risk. Move containers from spill area. Approach release from
upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash
spillages into an effluent treatment plant or proceed as follows. Contain and collect
spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or
diatomaceous earth and place in container for disposal according to local regulations
(see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated
absorbent material may pose the same hazard as the spilled product. Note: see
Section 1 for emergency contact information and Section 13 for waste disposal.

Section 7. Handling and storage

Precautions for safe handling
Protective measures : Put on appropriate personal protective equipment (see Section 8). Do not get in eyes or
on skin or clothing. Use only with adequate ventilation. Wear appropriate respirator
when ventilation is inadequate. Avoid release to the environment. Do not ingest.
Empty containers retain product residue and can be hazardous. Keep in the original
container or an approved alternative made from a compatible material, kept tightly
closed when not in use. Do not reuse container. Do not breathe vapor or mist.
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.

Conditions for safe storage, : Store in accordance with local regulations. Store in original container protected from
including any direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials
incompatibilities (see Section 10) and food and drink. Store locked up. Keep container tightly closed
and sealed until ready for use. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage. Do not store in unlabeled containers.
Use appropriate containment to avoid environmental contamination. See Section 10 for
incompatible materials before handling or use.

Section 8. Exposure controls/personal protection

Control parameters
Occupational exposure limits
Ingredient name Exposure limits
ammonium hydroxide None.

Appropriate engineering : Use only with adequate ventilation. If user operations generate dust, fumes, gas, vapor
controls or mist, use process enclosures, local exhaust ventilation or other engineering controls
to keep worker exposure to airborne contaminants below any recommended or statutory
limits.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.

Individual protection measures

Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
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Section 8. Exposure controls/personal protection

Eye/face protection : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn, unless
the assessment indicates a higher degree of protection: chemical splash goggles and/
or face shield. If inhalation hazards exist, a full-face respirator may be required instead.
Skin protection
Hand protection : Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. Considering the parameters specified by the glove manufacturer, check
during use that the gloves are still retaining their protective properties. It should be
noted that the time to breakthrough for any glove material may be different for different
glove manufacturers. In the case of mixtures, consisting of several substances, the
protection time of the gloves cannot be accurately estimated.
Body protection : Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before
handling this product.
Other skin protection : Appropriate footwear and any additional skin protection measures should be selected
based on the task being performed and the risks involved and should be approved by a
specialist before handling this product.
Respiratory protection : Based on the hazard and potential for exposure, select a respirator that meets the
appropriate standard or certification. Respirators must be used according to a
respiratory protection program to ensure proper fitting, training, and other important
aspects of use.

Section 9. Physical and chemical properties

Appearance
Physical state : Liquid.
Color : Clear.
Odor : Pungent.
Odor threshold : 5 ppm
pH : Approx. 11.6 for 1 N Sol’n. in water
Melting point : -35⁰F (20% solution) to -115⁰F(30% solution)
Boiling point : Lowest known value: 38°C (100.4°F) (ammonium hydroxide).
Critical temperature : Not available.
Flash point : Not available.
Evaporation rate : Not available.
Flammability (solid, gas) : Extremely flammable in the presence of the following materials or conditions: Oxidizing
Lower and upper explosive : Lower: 16%
(flammable) limits Upper: 25%
Vapor pressure : 3-10 PSI @ 16 ◦C
Vapor density : Vapor density 0.6 (Air = 1) (ammonia)
Specific Volume (ft 3/lb) : 20.79
Gas Density (lb/ft ) 3
: 0.0481
Relative density : 0.6
Solubility : Soluble in water. Soluble in alcohol and ether.
Solubility in water : Complete 540 g/l
Partition coefficient: n- : Not available.
octanol/water
Auto-ignition temperature : 651°C (1203.8°F)
Decomposition temperature : Not available.
Viscosity : Not available.
Flow time (ISO 2431) : Not available.

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Section 10. Stability and reactivity

Reactivity : No specific test data related to reactivity available for this product or its ingredients.

Chemical stability : The product is stable.

Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions

Conditions to avoid : No specific data.

Incompatible materials : Yellow Metals (brass & copper)

Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should
products not be produced.

Hazardous polymerization : Under normal conditions of storage and use, hazardous polymerization will not occur.

Section 11. Toxicological information

Information on toxicological effects
Acute toxicity
Product/ingredient name Result Species Dose Exposure
ammonium hydroxide LD50 Oral Rat 350 mg/kg -
Irritation/Corrosion
Product/ingredient name Result Species Score Exposure Observation
ammonium hydroxide Eyes - Severe irritant Rabbit - 250 ug -
Eyes - Severe irritant Rabbit - 0.5 minutes 1 -
mg
Sensitization
Not available.
Mutagenicity
Not available.
Carcinogenicity
Not available.
Reproductive toxicity
Not available.
Teratogenicity
Not available.
Specific target organ toxicity (single exposure)
Name Category Route of Target organs
exposure
ammonium hydroxide Category 3 - Respiratory tract
irritation
Specific target organ toxicity (repeated exposure)
Not available.
Aspiration hazard
Not available.

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Section 11. Toxicological information

Information on the likely : Not available.

routes of exposure
Potential acute health effects
Eye contact : No known significant effects or critical hazards.
Inhalation : May cause respiratory irritation.
Skin contact : Causes severe burns.
Ingestion : No known significant effects or critical hazards.

Symptoms related to the physical, chemical and toxicological characteristics

Eye contact : Adverse symptoms may include the following:, pain, watering, redness
Inhalation : Adverse symptoms may include the following:, respiratory tract irritation, coughing
Skin contact : Adverse symptoms may include the following:, pain or irritation, redness, blistering may
occur
Ingestion : Adverse symptoms may include the following:, stomach pains

Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Long term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Potential chronic health effects
Not available.

General : No known significant effects or critical hazards.

Carcinogenicity : No known significant effects or critical hazards.
Mutagenicity : No known significant effects or critical hazards.
Teratogenicity : No known significant effects or critical hazards.
Developmental effects : No known significant effects or critical hazards.
Fertility effects : No known significant effects or critical hazards.

Numerical measures of toxicity

Acute toxicity estimates
Not available.

Section 12. Ecological information

Toxicity
Product/ingredient name Result Species Exposure
ammonium hydroxide Acute LC50 37 ppm Fresh water Fish - Gambusia affinis - Adult 96 hours

Persistence and degradability

Not available.

Bioaccumulative potential
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Section 12. Ecological information

Not available.

Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)

Other adverse effects : No known significant effects or critical hazards.

Section 13. Disposal considerations

Disposal methods : The generation of waste should be avoided or minimized wherever possible. Disposal
of this product, solutions and any by-products should at all times comply with the
requirements of environmental protection and waste disposal legislation and any
regional local authority requirements. Dispose of surplus and non-recyclable products
via a licensed waste disposal contractor. Waste should not be disposed of untreated to
the sewer unless fully compliant with the requirements of all authorities with jurisdiction.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers.

Section 14. Transport information

DOT TDG Mexico IMDG IATA
UN number UN2672 UN2672 UN2672 UN2672 UN2672

UN proper Ammonium AMMONIA AMMONIA AMMONIA Ammonia solution

shipping name Hydroxide or SOLUTION SOLUTION SOLUTION
Ammonia solutions
Transport 8 8 8 8 8
hazard class(es)

Packing group III III III III III

Environmental No. Yes. Yes. The Yes. Yes. The
hazards environmentally environmentally
hazardous hazardous
substance mark is substance mark is
not required. not required.
“Refer to CFR 49 (or authority having jurisdiction) to determine the information required for shipment of the
product.”

Additional information
DOT Classification : Reportable quantity 1000 lbs / 454 kg [2493.4 gal / 9438.7 L]. Package sizes shipped
in quantities less than the product reportable quantity are not subject to the RQ
(reportable quantity) transportation requirements.
TDG Classification : Product classified as per the following sections of the Transportation of Dangerous
Goods Regulations: 2.40-2.42 (Class 8), 2.7 (Marine pollutant mark).
The marine pollutant mark is not required when transported by road or rail.
IMDG : The marine pollutant mark is not required when transported in sizes of ≤5 L or ≤5 kg.
IATA : The environmentally hazardous substance mark may appear if required by other
transportation regulations.

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Section 14. Transport information

Special precautions for user : Transport within user’s premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.

Transport in bulk according : Not available.

to IMO instruments

Section 15. Regulatory information

U.S. Federal regulations : TSCA 8(a) CDR Exempt/Partial exemption: Not determined
Clean Water Act (CWA) 311: ammonium hydroxide

Clean Air Act Section 112 : Not listed

(b) Hazardous Air
Pollutants (HAPs)
Clean Air Act Section 602 : Not listed
Class I Substances
Clean Air Act Section 602 : Not listed
Class II Substances
DEA List I Chemicals : Not listed
(Precursor Chemicals)
DEA List II Chemicals : Not listed
(Essential Chemicals)
SARA 302/304
Composition/information on ingredients
No products were found.
SARA 304 RQ : Not applicable.
SARA 311/312
Classification : Refer to Section 2: Hazards Identification of this SDS for classification of substance.
SARA 313
Product name CAS number %
Form R - Reporting ammonium hydroxide 1336-21-6 100
requirements
Supplier notification ammonium hydroxide 1336-21-6 100

SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include
copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.
State regulations
Massachusetts : The following components are listed: AMMONIUM HYDROXIDE; AMMONIUM WATER
New York : The following components are listed: Ammonium hydroxide
New Jersey : The following components are listed: AMMONIUM HYDROXIDE
Pennsylvania : The following components are listed: AMMONIUM HYDROXIDE
California Prop. 65
This product does not require a Safe Harbor warning under California Prop. 65.
International regulations
Chemical Weapon Convention List Schedules I, II & III Chemicals
Not listed.
Montreal Protocol
Not listed.
Stockholm Convention on Persistent Organic Pollutants

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Section 15. Regulatory information

Not listed.
Rotterdam Convention on Prior Informed Consent (PIC)
Not listed.
UNECE Aarhus Protocol on POPs and Heavy Metals
Not listed.
Inventory list
Australia : All components are listed or exempted.
Canada : All components are listed or exempted.
China : All components are listed or exempted.
Europe : All components are listed or exempted.
Japan : Japan inventory (ENCS): All components are listed or exempted.
Japan inventory (ISHL): All components are listed or exempted.
New Zealand : All components are listed or exempted.
Philippines : All components are listed or exempted.
Republic of Korea : All components are listed or exempted.
Taiwan : All components are listed or exempted.
Thailand : Not determined.
Turkey : All components are listed or exempted.
United States : All components are active or exempted.
Viet Nam : All components are listed or exempted.

Section 16. Other information

Hazardous Material Information System (U.S.A.)
Health / 3

Flammability 0
Physical hazards 0

Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks. Although HMIS® ratings and the associated label are not required on
SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS®
ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered trademark and service
mark of the American Coatings Association, Inc.
The customer is responsible for determining the PPE code for this material. For more information on HMIS®
Personal Protective Equipment (PPE) codes, consult the HMIS® Implementation Manual.
National Fire Protection Association (U.S.A.)

0 Flammability
Health 3 0 Instability/Reactivity
Special

Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency
Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is
not the complete and official position of the National Fire Protection Association, on the referenced subject
which is represented only by the standard in its entirety.
Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to
be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of
chemicals. The user is referred to certain limited number of chemicals with recommended classifications in
NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA
or not, anyone using the 704 systems to classify chemicals does so at their own risk.
Procedure used to derive the classification
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Section 16. Other information

Classification Justification
SKIN CORROSION - Category 1B Expert judgment
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract Calculation method
irritation) - Category 3
AQUATIC HAZARD (ACUTE) - Category 1 Calculation method
History
Date of printing : 1/14/2021
Date of issue/Date of : 1/14/2021
revision
Date of previous issue : 2/15/2018
Version : 1
Key to abbreviations : ATE = Acute Toxicity Estimate
BCF = Bioconcentration Factor
GHS = Globally Harmonized System of Classification and Labelling of Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From Ships, 1973
as modified by the Protocol of 1978. ("Marpol" = marine pollution)
UN = United Nations
References : Not available.
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.

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