SULPHUR VISCOSITY INDEX

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SULPHUR VISCOSITY INDEX

S No TEMP ◦F TEMP ◦C VISCOSITY C.St


1 250 ◦F 121.1 ◦C 11.5
2 280 ◦F 137.8 ◦C 9.0
3 300 ◦F 148.9 ◦C 6.8
4 309 ◦F 153.9 ◦C 6.6
5 316.5 ◦F 158.1 ◦C 8.0
6 318.5 ◦F 159.2 ◦C 10.0
7 321 ◦F 160.6 ◦C 20.0
8 321 ◦F 160.6 ◦C 100.0
9 322 ◦F 161.6 ◦C 1000.0
10 324 ◦F 162.2 ◦C 4000.0
11 325 ◦F 162.8 ◦C 6,000.0
12 326 ◦F 163.3 ◦C 10,000.0
13 329 ◦F 165.0 ◦C 20,000.0
14 336 ◦F 168.9 ◦C 40,000.0
15 344 ◦F 173.3 ◦C 60,000.0
16 350 ◦F 176.7 ◦C 73,000.0
17 370 ◦F 187.8 ◦C 92,000.0

FIC-122 /102/103 OUT PUT & VALVE ACTION


B A CONTROLLER
OUTPUT
0% 0% 0%
25% 0% 20%
50% 25% 40%
75% 50% 60%
100% 75% 80%
100% 100% 100%

92-PIC-3001 OUT PUT &ITS EFFECT ON UNITS


EFFECT VALVE OUT PUT
NO EFFECT 40%-60%
▲ TO UNIT ON S-1 60 % TO 70 %
▼ TO UNIT ON S-1 40 % TO 30 %
▲ TO UNIT ON S-2 70 % TO 80 %
▼ TO UNIT ON S-2 30 % TO 20 %
▲ TO UNIT ON S-3 80 % TO 90 %
▼ TO UNIT ON S-3 20% TO 10 %

TV-529 OUT PUT & VALVE ACTION


TO E-109 TO E-107 CONTROLLER
OUTPUT
100% 0% 0%
75% 25% 25%
50% 50% 50%
25% 75 75
0% 100% 100%
REFRACTORY COLOR CODE
REFRACTORY COLOR TEMP. ◦C
RED JUST VISIBLE 480-540◦C
DARK RED 540-590◦C
DARK CHERRY 590-650◦C
MEDIUM CHERRY 650-700◦C
CHERRY OR FULL RED 700-760◦C
BRIGHT RED 760-820◦C
SALMON 820-930◦C
ORANGE 930-1100◦C
YELLOW 1100-1230◦C
BRIGHT YELLOW 1320-1540◦C
WHITE 1540-HIGHER
STOICHIOMETRIC REACTION FURNACE OPERATION
THE TARGET VALUE OF STOICHIOMETRIC FUEL GAS FIRING IS 99+_2 % AT
STOICHIOMETRIC. THE DESIGN ANALYTICAL FOR STOICHIOMETRIC FUEL GAS COMBUSTION
HAVE AN OXYGEN CONTENT 0.1 TO 0.2MOLE% OR LESS THEN 0.5 TO 0.9 CARBON-MONOXIDE O
N DRY BASES
STOICHIOMETRIC FUEL FIRING IS DEFINED AS :
1- ALL HYDROGEN BURNED TO WATER
2- ALL CARBON BURNED TO CARBON DI-OXIDE
3- ALL HYDROGEN SULPHIDE (H2S ) IF PRESENT BURNED TO WATER & SULPHUR DI-OXIDE
PURPOSE OF STOICHIOMETRIC FIRING:
TO PREVENT CARBON SOOT FORMATION OR OXYGEN BREAKTHROUGH ON D/S OF R/F
ACTUAL F.G FLOW = (FIC-104)( PI-301 +1.01)
4.9

AIR DEMAND IN A.G FIRING


AIR DEMAND= FEED x H2S CONCENTRATION
41.8
= FEED x H2S CONCENTRATION x 0.02386

CONCENTRATION OF OXYGEN IN AIR = 20.9 ( 20.9 x 2 = 41.8)

( 7.16 M3 AIR IS REQUIRED TO BURN 1 M3 OF H2S. SO FOR BURNING 1/3 OF H2S


7.16 / 3= 2 .386 M3)
SO AIR = FEED x H2S CONCENTRATION x 2.386
100

= FEED x H2S CONCENTRATION x 0.02386

AIR DEMAND =FEED x H2S CONCENTRATION


41.8
AIR DEMAND =FEED x H2S CONCENTRATION(FIC-104+H.C IN FEED)
41.8

IF AIR IS MORE THEN THE REQUIRED , R.F TEMP WILL INCREASE AND V-103 TEMP WILL GO
DOWN & VISE VERSA
FORMULA FOR SULPHUR PRODUCTION
SULPHUR PRODUCTION( PER DAY) = H2S CONCENTRATION x 32 x A/G FLOW x 24 x0.98
100 x 22.414
“ “ “ “ = H2S CONCENTRATION x A/G FLOW x 0.3358
HENCE
24 = 24 Hrs
32= SULPHUR MOLECULAR WEIGHT
0.98= PLANT EFFICIENCY
22.411=

TRI SODIUM PHOSPHATE REACTION


Na3PO4 + CaCO3 ________ Ca PO4 + NaCO3

IF THE PH WILL GO MORE THEN 11.0 IT WILL CAUSE IMBRITILMENT ( SOFTEN THE METAL )
CBA SEQUENCE PHASES
CONTROLLER SETPOINT/ PHASE STEP
TARGET
TI-553 280◦C V-104 HEAT-UP 1 ,2 , 3
TI-553 300◦C V-104 PLATEAU 4
TI-553 315◦C V-104 HEAT SOAK 5
- 30 MIN TIMER V-104 HEAT SOAK 6
TI-553 250◦C V-104 PRE-COOL 7 , 8, 9
ADSORB / ADSORB V-105 / V-104 10……..18
TI-555 280◦C V-105 HEAT-UP 19 , 20 , 21
TI-555 300◦C V-105 PLATEAU 22
TI-555 315◦C V-105 HEAT SOAK 23
- 30 MIN TIMER V-105HEAT SOAK 24
TI-555 250◦C V-105 PRE-COOL 25 , 26 , 27
ADSORB / ADSORB V-104 / V-105 28………36

HEAT-UP
DURING THIS PHASE CATALYST BED IS HEATED UP TO THE POINT WHERE SULPHUR BEGINS
TO BE REMOVE FROM CATALYST BED
PLATEAU
SULPHUR ACTIVELY REMOVED FROM CATALYST BED
HEAT SOAK
FINAL REMOVEL OF ANY RESIDUAL FROM CATALYST BED

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