Solution (1)
Solution (1)
Solution (1)
1701CJA101038240031 JA
PART-1 : PHYSICS
SECTION-I
1) A ring of radius R having a linear charge density λ moves towards a solid imaginary sphere of
radius so that the centre of ring passes through the centre of sphere. The axis of the ring is
perpendicular to the line joining the centres of the ring and the sphere. The maximum flux through
(A)
(B)
(C)
(D)
2) A short dipole is at a distance r from a point charge q and oriented so that makes angle θ with
position vector from q to . If θ is variable, then what is ratio of minimum and maximum
magnitudes of force on the dipole:
(A)
(B)
(C) 0
(D) 1
0
3) If the particle shown is the figure is projected with orbital speed v = , it returns after time
T. If it is projected such that time period of revolution is 8T then what is maximum distance of the
particle from the centre of the earth ?
(A) 7R
(B) 3R
(C) 14R
(D) 15R
4) Two Stars of mass 4m and m respectively are revolving under mutual gravitation force of
attraction. Assume no other external forces are present. Ratio of their kinetic energies will be :
(A) 1 : 4
(B) 1 : 5
(C) 1 : 1
(D) 1 : 2
5) Two wires of same material are at same temperature connected to two identical ideal cells as
(A)
Ω
(B)
Ω
(C) 29 Ω
(D)
Ω
7) At pressure P and absolute temperature T a mass M of an ideal gas fills a closed container of
volume V. An additional mass 2M of the same gas is added into the container and the volume is then
reduced to and the temperature to . The pressure of the gas will now be:
(A)
(B) P
(C) 3 P
(D) 9 P
8) For two thermodynamic process temperature and volume diagram are given. In first process, it is
a straight line having initial and final coordinates as (V0, T0) and (2V0, 2T0), where as in second
process it is a rectangular hyperbola having initial and final coordinates (V0, T0) and (2V0, T0/2). Then
(A) 1 : 2
(B) 2 : 1
(C) 1 : 1
(D) None of these
9) For a gas sample with N0 number of molecules, function N(V) is given by : N(V) =
0
and N(V) = 0 for V > V . Where dN is number of molecules in speed range V to V+
dV. The rms speed of the molecules is :
(A)
(B)
(C)
(D)
10) An ideal gas undergoes a cyclic process, in which one process is isochoric, one process is
isothermal and one process is adiabatic. During the isothermal process, 40 J heat is released by the
gas, and during the isochoric process, 80 J heat is absorbed by the gas. If work done by the gas
during adiabatic process is W1 and during isothermal process is W2 then will be equal to:
(A) –2
(B) 2
(C) 4
(D) –1/2
11) A carnot refrigeration cycle absorbs heat at 270 K and rejects heat at 300 K. If the cycle is
absorbing 1260 kJ/min at 270 K, then work required per second is :
13) A container of a large uniform cross-sectional area A resting on a horizontal surface holds two
immiscible, non-viscous and incompressible liquids of densities ' d ' and ' 2 d ' each of height (1/2)H
as shown. The smaller density liquid is open to atmosphere. A homogeneous solid cylinder of length
L cross-sectional area (1/5) A is immersed such that it floats with its axis vertical to the
liquid-liquid interface with length (1/4) L in denser liquid. If D is the density of the solid cylinder
then :
(A)
D=
D=
(B)
(C)
D=
(D)
D=
14) Some liquid is filled in a cylindrical vessel of radius R. Let F1 be the magnitude of force applied
by the liquid on the bottom of the cylinder. Now the same liquid is poured into a vessel of uniform
square base of side R. Let F2 be the magnitude of force applied by the liquid on the bottom of this
new vessel, both vessels are placed on horizontal surface. Then
(A) F1 = πF2
(B)
F1 =
(C) F1 = F2
(D) F1 = F1
15) A U-tube of base length “ℓ” filled with same volume of two liquids of densities ρ and 2ρ is moving
with an acceleration “a” on the horizontal plane. If the height difference between the two surfaces
(A)
(B)
(C)
(D)
16) The velocity of the liquid coming out of a small hole of a large vessel containing two different
liquids of densities 2ρ and ρ as shown in figure is :
(A)
(B)
(C)
(D)
17) A space 2.5 cm wide between two large plane surfaces is filled with oil. Force required to drag a
very thin plate of area 0.5 m2 just midway the surfaces at a speed of 0.5 m/sec is 1N. The coefficient
of viscosity in kg–s/m2 is :
(A) 5 × 10–2
(B) 2.5 × 10–2
(C) 1 × 10–2
(D) 7.5 × 10–2
18) A sphere of mass m and radius r is projected in a gravity free space with speed v. If coefficient of
viscosity of the medium in which it moves the distance travelled by the body before it stops is :
(A)
(B)
(C)
(D)
19) A Soap bubble of radius R is surrourded by another soap bubble of radius 2R, as shown. Take
surface tension = S. Then, the pressure inside the smaller soap bubble, in excess of the atmospheric
pressure will be :
(A)
(B)
(C)
(D)
20) When a metallic surface is illuminated with monochromatic light of wavelength λ, the stopping
potential is 5 V0. When the same surface is illuminated with light of wavelength 3λ, the stopping
potential is V0. Then the work function of the metallic surface is :
(A)
(B)
(C)
(D)
SECTION-II
2) A wire has a length of 2.0 m and a resistance of 3.0 Ω. Find the electric field (in V/m) existing
inside the wire if it carries a current of 2 A.
3) 4 moles of H2 at 500 K is kept in an adiabatic rigid container. After some time it was found that 1
mole of the gas dissociated into H atoms . The dissociation energy per mole of H2 gas is 2000 cal,Let
the new temperature of the gas be 100T. The integral value of T is : (Use R= 2cal/mole-K)
4) Two different vertical positions (a) & (b) of a capillary tube are shown in figure with the lower end
inside water. For position (a), contact angle is & water rises to height h above the surface of
water while for position (b) height of the tube outside water is kept insufficient & equal to then
5) A metal surface has work function 1.1 eV. Photon of wavelength 6200 Å is absorbed by an
electron which makes a collision with lattice before coming to surface. If it is observed that it comes
out with kinetic energy 0.4 eV then percentage loss of kinetic energy during collision with lattice is
x% (approximately). Then find x:
PART-2 : CHEMISTRY
SECTION-I
(B)
(C)
(D)
3)
In which of the following pairs, the bromination of first member is easier than the second member ?
(A)
(B)
(A)
(B)
(C)
(D)
(A)
(B)
(C)
(D)
7) Half life of a first order reaction : A(aq.) → 2B(aq.) is 40 min at 27ºC and 20 min at 37ºC. The
activation energy of reaction is (ln2 = 0.7, R = 2.0 cal mol–1K–1)
9) Densities of diamond and graphite are 3.5 and 2.4 g/ml, respectively. The increase in pressure
(constant temperature) at the equilibrium C(Diamond) C(Graphite) will
10) A mixture of NH3(g) and N2H4(g) is placed in sealed container at 300K. The total pressure is 0.5
atm. The container is heated to 1200 K at which NH3(g) and N2H4(g) decomposes completely as
follows.
2NH3(g) —→ N2(g) + 3H2(g)
N2H4(g) —→ N2(g) + 2H2(g)
After decomposition, the total pressure at 1200 K is found to be 4.5 atm. The mole% of N2H4 in the
original mixture at 300 K is :
(A) 20%
(B) 25%
(C) 50%
(D) 75%
(A) Neutral
(B) Slightly acidic
(C) Slightly basic
(D) Strongly basic
(A) 10–8
(B) 10–10
(C) 10–15
(D) 10–7
13) Calculate volume of H2SO4 solution (in mℓ) which is 9.8% by mass and has density of 1.25 g/mℓ,
which is required to produce 2.5 litre of solution of pH = 1
(A) 200 mℓ
(B) 100 mℓ
(C) 50 mℓ
(D) 150 mℓ
14)
An ammonia-ammonium chloride buffer has a pH value of 9 with [NH3] = 0.25M. What will be the
new pH if 500 ml 0.1 M KOH is added to 200 ml buffer solution (Kb = 2 × 10–5)
[log2 = 0.3]
(A) 8.4
(B) 9.6
(C) 5.6
(D) 4.4
15) Calculate concentration of 'A' at equilibrium for a reaction, A(g) B(g), Kc = 1050, if the initial
concentration of 'A' is 2M ?
(A) 4 × 10–40M
(B) 2 × 10–40M
(C) 4 × 10–50M
(D) 2 × 10–50M
16) In a reaction carried out at 400 K, 0.0001% of the total number of molecules are in activated
state. The energy of activation of reaction is -
(A) 0
(B) 7.37 Kcal/mol
(C) 9.21 Kcal/mol
(D) 11.05 Kcal/mol
17) The reaction A → Product, follows first order kinetics and the progress of reaction is depicted in
(A) 10 s
(B) 100 s
(C) 500 s
(D) 1000 s
18) Which compound is formed when excess KCN is added to aqueous solution of copper sulphate ?
(A) Cu(CN)2
(B) K2[Cu(CN)4]
(C) K[Cu(CN)2]
(D) K3[Cu(CN)4]
19)
Which of the following will not give positive chromyl chloride test?
(A) CuCl2
(B) HgCl2
(C) ZnCl2
(D) C6H5NH3Cl
20)
Reagent, 1-naphthylamine and sulphanilic acid in acetic acid is used for the detection of
(A) N2O
–
(B) NO3
(C) NO
–
(D) NO2
SECTION-II
1)
How many compounds out of following use two or more moles of Grignard reagent to convert into
alcohol after complete hydrolysis.
2)
3)
4) The following results were obtained during kinetic studies of the reaction : 2A + B → Products
Initial Rate
[A] [B]
Experiment of reaction
(in mol–1 L ) (in mol L–1)
(in mol L–1 min–1)
PART-3 : MATHEMATICS
SECTION-I
(Where {x} denotes fractional part, [x] denotes greatest integer function, Sgn(x) denotes signum
function)
then find the area bounded by the graph of f(x) and x-axis over the interval [–3, 3] is :
(A) 5
(B)
(C)
(D)
2) The area of the region in the first quadrant inside the circle x2 + y2 = 8 and outside the parabola
y2 = 2x is equal to :
(A)
(B)
(C)
(D)
3) The area (in sq. units) of the region described by {(x,y) : y2< 2x, and y > 4x –1} is
(A)
(B)
(C)
(D)
(A) 50
(B) 100
(C) 200
(D) 300
(A)
(B)
(C)
(D)
6) Let y = y(x) be the solution curve of the differential equation secy + 2xsiny = x3cosy, y(1) = 0.
Then is equal to :
(A)
(B)
(C)
(D)
7) A curve 'C' has the property that if the tangent at any point P on 'C' meets the co-ordinate axis at
A and B, then P is the mid point of AB. If the curve passes through the point (1, 1), then equation of
curve is equal to -
(A) xy = 2
(B) xy = 1
(C) x2y = 1
(D) xy2 = 4
8) Consider a twice differentiable function f(x) satisfying f(x) + f ″ (x) = 2f ′ (x) where
f(0) = 0, f(1) = e. [Note : e denotes napier's constant]
Match List-I with List-II and select the correct answer using the code given below the list.
List-I List-II
(A)
(B)
(C) 2π
(D)
(A)
(B)
(C)
(D)
11) Let = 1, a > b be an ellipse, whose eccentricity is and the length of the latus rectum
(B)
(C)
(D)
12) If the ellipse is inscribed in a square of side length , then area of ellipse is
(A) 4π
(B) 8π
(C) 10π
(D) 12π
(A) 0
(B)
(C)
14) Let the line y = mx and the ellipse 2x2 + y2 = 1 intersect at a point P in the first quadrant. If the
normal to this ellipse at P meets the co-ordinate axes at and (0,b), then b is equal to
(A)
(B)
(C)
(D)
15) Statement-I : Foci of the hyperbola and its conjugate hyperbola are F1, F2 and F3, F4
respectively, then F1, F2, F3, F4 form an square.
Statement-II : Area of quadrilateral formed by F1, F2, F3, F4 is 50 square units.
16) Let P(x1, y1) & Q(x2, y2) are points lying on hyperbola . If tangents drawn at the points
(A)
(B)
(C)
(D)
(A)
(B)
(C)
(D)
18) Let e be the eccentricity of a hyperbola and f(e) be the eccentricity of its conjugate hyperbola
(A)
(B)
(C)
(D)
19) If where C is the constant of integration
and g(1) = 1 then (g'(1) + g"(1) + k) is equal to :
(A) 30
(B) 32
(C) 34
(D) 36
20)
(A)
(B)
(C)
(D)
SECTION-II
2) The sum of the absolute values of the coefficients in the expansion of (2x2 – 3x3 + 4x4 + 2x6)15 is
equal to (a)15, then a is equal to
5) Let [t] denotes the greatest integer ≤ t. If the constant term in the expansion of is
α, then [α] is equal to ________.
ANSWER KEYS
PART-1 : PHYSICS
SECTION-I
Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. D A C A B A C B B A A A D D B B B C B A
SECTION-II
Q. 21 22 23 24 25
A. 7 3 4 3 25
PART-2 : CHEMISTRY
SECTION-I
Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. C B A C C D B B B B B C B B D D D D B D
SECTION-II
Q. 46 47 48 49 50
A. 7 7 6 5 9
PART-3 : MATHEMATICS
SECTION-I
Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. C B D A A C B B D A C D C D C C C C C C
SECTION-II
Q. 71 72 73 74 75
A. 3 11 33 5 1275
SOLUTIONS
PART-1 : PHYSICS
1)
Flux will be maximum when maximum length of ring is inside the sphere.
This will occur when the chord AB is maximum. Now maximum length of chord AB = diameter
of sphere. In this case the arc of ring inside the sphere subtends an angle of at the centre of
ring.
2)
Fmax =
Fmin =
3)
T1 = T a1 = 2R ; T2 = 2T a2 = ?
a2 = (64 × 8R)1/3 = 8R
If rmin & rmax are minimum & maximum distance from centre of earth then
rmin + rmax = 2a2
2R + rmax = 16R
rmax = 14R
4)
m1v1 = m2v2
= =
5)
Vd =
7)
0
If M is molecular mass of the gas then for initial condition PV = . RT ...(1)
After 2M mass has been added
P′ . = . R . ...(2)
By dividing (2) by (1)
P' = 3P
8)
Hence, P = =
∴ W2 =
9)
= here = N(V)
Vrms2 = V2 dV
0 0
2 2
= V dV = V ⇒ Vrms = .V .
10)
11)
= = = =9
W= = kJ/min = kJ/sec.
12)
Let A & B are two points on an isothermal curve. Join A & B by any curve C. Then on this curve
c, ΔU = 0, where c is not an isothermal curve.
15)
(B) For the given situation, liquid of density 2 ρ should be behind that of ρ.
From right limb :
PA = Patm + ρ gh
PB = PA + ρ a = Patm + ρ gh + ρ a
PC = PB + (2ρ) a = Patm + ρ gh + ρ a ℓ .... (1)
But from left limb :
PC = Patm + (2ρ )gh .... (2)
From (1) and (2) :
Patm + ρ gh + ρ a ℓ = Patm+2 ρ gh
⇒h= ℓ
16)
Pressure at (1) :
(B)
P1 = Patm + ρ g (2h)
Applying Bernoulli's theorum between points (1) and (2)
= Patm + (2 ρ) g (0) + (2 ρ) v2
⇒ v=2 Ans.
17)
Velocity gradient =
as force on the plate due to viscocity is from upper as well as lower portion of the oil, equal
from each part,
Then, F = 2 η A = 2 × η × (0.5)
18)
= –6πhrv = – rv
⇒ ⇒ x= .
0
20) = 5 eV + ϕ
0
= eV + ϕ ⇒ = 4eV0 ⇒ ϕ= Ans.
21) =
= M'
22) , V= IR
23)
= 2000 + +
T’ = = 100 T
T=4
24) h = .............. (i)
= ............. (ii)
PART-2 : CHEMISTRY
28)
ln =
33) ;
s=
s = 1.9 × 10–5
Hence answer is (B)
35) Let the initial mixture contains a and b moles of NH3(g) and N2H4(g)
Total moles of gases originally present = a + b
Total moles of gases after decomposition= 2a + 3b
0.5 × V = (a + b) × R × 300
4.5 × V = (2a + 3b) × R × 1200
3b = a
% mole N2H4(g) =
39)
m moles of KOH added = 50
40)
Kc = = 1050
⇒ y = [A] = 2 × 10–50 M.
k=
t1/2 =
44)
HgCl2 is very weakly ionised in aqueous medium due to more covalent character.
45)
46)
49)
6.93 × 10–3 = k (0.10)
k = 6.93 × 10–2
t = required to consume
half of A =
PART-3 : MATHEMATICS
51)
Area = 3 + 1 + 1 + ×3
52)
Required area = Ar(circle from 0 to 2) – ar(para from 0 to 2)
⇒
53)
Shaded area
Shaded area
Put y = Vx
Let 1 – 4 V2 = t
⇒ – 8V dV = dt
given y(1) = 0
sec2y + 2xtany = x3
tany = t ⇒
, If
x2 = Z ⇒
y(1) = 0 ⇒ c = 0 ⇒
57)
58) We have
59)
IF =
IF = x2 + 4
y × (x2 + 4) =
y(x2 + 4) =
0=0+c=c=0
y(x2 + 4) = tan–1
y at x = 2
y(4 + 4) = tan–1(1)
∵ B2 = A2(1 – e2)
61)
62) The vertices of the square will lie on director's circle of ellipse
⇒ vertices of square lies on x2 + y2 = 16 + b2
∴ 2(side of square)2 = (diameter of director's circle)2
⇒ Radius of director's circle = 5 ⇒ 16 + b2 = 25 or b = ± 3
∴ Area of ellipse = sq. units
= 12π sq. units
or
(reject)
66)
m1m2 = –1
and
∴ Given integral =
g(e) =
⇒C=0
69) Multiply Nr & Dr by x2
g(x) = x2
70)
71)
x = sin2θ
73)
so for integral terms r = 0, 8, 16, ... , 256 total 33 terms
75)
∴ constant term is
[α] = 1275