04-05-2024

1751CJA101021240006 JA

PART-1 : PHYSICS

SECTION–I (a)

1) A point charge Q is located on the axis of a disc of radius R at a distance 'a' from the plane of the
disc. If one fourth (1/4th) of the flux from the charge passes through the disc, then value of a is

(A)

(B)

(C)

(D)

2) Figure shows a wire, hinged at A and B, and given the shape of half ring of radius R, the assembly
is now free to rotate about an axis passing through AB in a uniform electric field E as shown in the
figure. Linear charge density of wire is λ1 and linear mass density is λ2. If assembly is slightly
disturbed from unstable equilibrium position, then find maximum angular velocity of ring during

ensuing motion.

(A)

(B)
(C)

(D)

3) Charge is distributed within a sphere of radius R with a volume charge density ,

where A and a are constants. If Q is the total charge of this charge distribution, the radius R is :

(A)

(B)

(C)

(D)

4) Two identical uniform rods of length ℓ and mass m are placed along the same line so that their
closer ends are a distance d apart as shown. The gravitational attraction between the rods has

magnitude of

(A)

(B)

(C)

(D)

SECTION–I (b)

1) A communications Earth satellite

(A) goes round the earth from east to west

(B) can be in the equatorial plane only
(C) can be vertically above any place on the earth
(D) goes round the earth from west to east

2) A double star is a system of two stars of masses m and 2m, rotating about their centre of mass
only under their mutual gravitational attraction. If r is the separation between these two stars then
their time period of rotation about their centre of mass will be proportional to :

(A) r3/2
(B) r
(C) m1/2
(D) m–1/2

3) The position vector of a particle that is moving in space is given by

in the ground frame. All units are in SI. Choose the correct statement (s) :

(A)
The particle executes SHM in the ground frame about the mean position
(B) The particle executes SHM in a frame moving along the z-axis with a velocity of 3 m/s.

(C)
The amplitude of the SHM of the particle is m.

(D)
The direction of the SHM of the particle is given by the vector

4) Two independent harmonic oscillators of equal mass are oscillating about the origin with angular
frequencies ω1 and ω2 and have total energies E1 and E2, respectively. The variations of their

momenta p with positions x are shown in the figures. If and , then the correct equation

(s) is (are)

(A) E1ω1 = E2ω2

(B)
2
(C) ω1ω2 = n

(D)

5) If there were only one type of charge in the universe, then

(A)
on any surface.

(B)
if the charge is outside the surface.
(C)
could not be defined.

(D)
if charges of magnitude q were inside the surface.

6) Which of the following is true for the figure showing electric lines of force ?

(E is electrical field, V is potential)

(A) EA > EB
(B) EB > EA
(C) VA > VB
(D) VB > VA

7) A length-scale (ℓ) depends on the permittivity (ε) of a dielectric material, Boltzmann constant kB,
the absolute temperature T, the number per unit volume (n) of certain charged particles, and the
charge (q) carried by each of the particles, Which of the following expressions(s) for ℓ is(are)
dimensionally correct ?

(A)

(B)

(C)

(D)

8) Which of the following statement(s) is/are correct ?

If the electric field due to a point charge varies as r–2.5 instead of r–2, then the Gauss law will
(A)
still be valid.
(B) The Gauss law can be used to calculate the field distribution around an electric dipole.
If the electric field between two point charges is zero somewhere, then the sign of the two
(C)
charges is the same.
The work done by the external force in moving a unit positive charge from point A at potential
(D)
VA to point B at potential VB is (VB –VA)

SECTION–II
1) Two uniformly charged co-axial, identical rings (Radius R) are fixed as shown. A point charge q0 is
projected with speed V0 along common axis of rings from large distance. Minimum value of V0 for

which the charge particle can just pass through both rings is given as . Find n

:-

2) Four point charges are kept at the vertices of a regular tetrahedron of side R. Total electrostatic

energy of the configuration is . The value of α is :-

3) The electric field in a region is radially outwards with magnitude E = . In a sphere of radius r

centered at the origin, calculate the value of charge in coulombs if and .

4) A non conducting solid cylinder of infinite length having charge density ρ and radius of cylinder is

5R. If the flux passing through the surface ABCD as shown in figure is . Find the value of θ.

5) Two blocks each of mass 5 kg are at rest on the ground. The masses are connected by a massless
string passing over a smooth and light pulley. A 200 N force is applied on the pulley. Find the
difference in acceleration of blocks in m/s2. (g = 10 m/s2)

6) A body of mass 1 kg is suspended by means of a spring and a thread between two walls as shown
in the figure. The measure of both angles between the thread and the horizontal and the spring and
the horizontal is shown in the figure. What is the initial acceleration (in m/s2) of the object if the

thread breaks ? (g = 10 m/s2)

PART-2 : CHEMISTRY

SECTION–I (a)

1) For an ideal solution having two liquid A(P°A and liquid B(P°B) boiling point versus composition

graph is given below, then select incorrect statement (s) :

(A) B is less volatile than A

(B) If mole percent of A in liquid phase is 40% then mole percent of A in vapour phase is 50%
(C) If mole percent of B in liquid phase is 10% then mole percent of B in vapour phase is 40%
(D) If the mole percent of A in solution is 50% then its boiling point is 350K

2) Two liquids A and B form an ideal solution. The solution has a vapour pressure of 700 torr at
90°C. It is distilled till 2/3rd of the solution is collected as condensate. The composition of the
condensate is X'A = 0.75 and that of the residue is X''A = 0.3. If the vapour pressure of the residue at
90°C is 600 torr, which of the following option is incorrect.

(A) The composition of the original liquid was XA = 0.6.

(B) The composition of the original liquid was XA = 0.4.
(C)
= torr
(D) = 500 torr

3) The decomposition of a gaseous substance (A) to yield gaseous products (B), (C) follows first order
kinetics. If initially only (A) is present and l0 minutes after the start of the reaction, the pressure of
(A) is 200 mm Hg and the total pressure is 300mm Hg, then the rate constant for reaction A → B +
C is

(A) (1/600) ℓn 1.25 sec–1

(B) (2.303/10) log 1.5 min–1
(C) (1/10) ℓn 1.25 sec–1

(D)
sec–1

4) Given below are two statements. One is labelled as

Assertion A and the other is labelled as Reason R.
Assertion A : [6] Annulene. [8] Annulene and cis –[10] Annulene, are respectively aromatic, not-
aromatic and aromatic.

[6] Annulene

[8] Annulene

Cis-[10] Annulene
Reason R : Planarity is one of the requirements of aromatic systems.
In the light of the above statements, choose the most appropriate answer from the options given
below

(A) Both A and R are correct and R is the correct explanation of A.

(B) Both A and R are correct but R is NOT the correct explanation of A.
(C) A is correct but R is not correct.
(D) A is not correct but R is correct.

SECTION–I (b)

1) Two solutions A and B form a negative deviation solution. The B.P. of pure A is less than pure B.
Choose the CORRECT statements

(A) Boiling temperature of the mixture is always more than boiling point of A.
(B) Boiling temperature of azeotropic mixture is always less than boiling point of B.
(C) When a small amount of A is added to excess of B, B.P. of resulting mixutre increases.
(D) Boiling point of azeotropic mixture is a fixed value at any external pressure

2) An amount of 1 mole of a non-volatile solid is dissolved in 200 moles of water. The solution is
cooled to a temperature ‘T’ K (lower than the freezing point of the solution) to cause ice formation.
After the removal of ice, the remaining solution is heated to 373 K, where the vapour pressure of
solution is observed to be 740 mmHg. Identify the correct information(s) from the following (Kf of
water = 2.0 K-kg/mol).

(A) 163 moles of ice is formed at T K.

(B)

(C)
Freezing point of the original solution is – °C

(D)
Relative lowering of vapour pressure of the final solution is

3) A liquid mixture having composition corresponding to point z in the figure shown is subjected to

distillation at constant pressure. Which of the following statement is correct

about the process

(A) The composition of distillate differs from the mixture

(B) The boiling point goes on changing
(C) The mixture has lowest vapour pressure than for any other composition.
(D) Composition of an azeotrope alters on changing the external pressure.

4) For a solution formed by mixing liquids L and M, the vapour pressure of L plotted against the
mole fraction of M in solution is shown in the following figure, Here xL and xM represent mole
fractions of L and M, respectively, in the solution. the correct statement(s) applicable to this system

is(are)

Attractive intramolecular interactions between L–L in pure liquid L and M–M in pure liquid M
(A)
are stronger than those between L–M when mixed in solution
(B) The point Z represents vapour pressure of pure liquid M and Raoult's law is obeyed when xL → 0
(C) The point Z represents vapour pressure of pure liquid L and Raoult's law is obeyed when xL → 1
The point Z represents vapour pressure of pure liquid M and Raoult's law is obeyed from xL = 0
(D)
to xL = 1
5) For the reaction A → B, the rate law expression is = k [A]1/2. If initial concentration of [A] is
[A]0, then

The integerated rate expression is k =

(A)

(B)

The graph of vs t will be

(C)
The half life period, =

(D)
The time taken for 75% completion of reaction =

6) For a first order reaction : A(g) → 2B(g)

(A) Half life of reaction is 10 sec

(B) Value of rate constant for reaction is 6.93 × 10–3 sec–1
(C) Total pressure at t = 50 sec will be 126 mm of Hg
(D) Reaction must be a complex reaction

7) Which of the following is correct order for resonance energy ?

(A)

(B)

(C)
(D)

8) Which of the given statement is correct :

(A) The C–Cl bond length in CH3CH2Cl is more than that in and CH=CH-Cl
(B) The C = C bond length in CH2 = CH2 is less than that in and CH2 = CHCl
(C) The C – C bond length in CH2 = CH2, CH3CH2 – Cl and CH2 = CHCl is equal
(D) The dipole moment of CH3CH2Cl is more than that in CH2=CHCl

SECTION–II

1) Sea water contains 29.25% NaCl and 19% MgCl2 by weight of solution. The normal boiling point
of the sea water is _____°C (Nearest integer)
Assume 100% ionization for both NaCl and MgCl2
Given : Kb(H2O) = 0.52 K kg mol–1
Molar mass of NaCl and MgCl2 is 58.5 and 95 g mol–1 respectively.

2) Elevation in boiling point of 0.25M aq. solution of weak acid HX is 0.14. What is molarity of H+ ion
in solution.
HXaq.
Given : Kb(H2O) = 0.5
Molality = Molarity
[Give answers as [H+] × 100]

3) Equal mass of A & B are present in liquid solution then total pressure exerted by vapours is X
torr, Give X/6. [A = 80 gm/mol, B = 120 gm/mol]

4) For the given first order reaction

the half life of the reaction is 0.3010 min. The ratio of the initial concentration of reactant to the
concentration of reactant at time 2.0 min will be equal to ___________. (Give your answer nearest
integer)
5) For the decomposition of azomethane.
CH3N2CH3(g) → CH3CH3(g)+N2(g) a first order reaction, the variation in partial pressure with time at

600 K is given as The half life of the reaction is _____ × 10–5s. [Nearest
integer]

6) Among the following, the number of aromatic compound(s) is :

PART-3 : MATHEMATICS

SECTION–I (a)

1)
 and

then number of solution(s) of equation is

(A) 0
(B) 1
(C) 2
(D) infinite

2) If where a1 = 1 and find ,

where [.] g.i.f.

(A) e2
(B) 2
(C) e
(D) 1

3) Find the value [x] + where [.] denotes greatest integer and {.} denotes fractional part
function.

(A) x

(B)

(C) 1
(D) –x

4)

(A)

(B)

(C)

(D)

SECTION–I (b)

1) If ƒ(x) = cos–1(cos(x + 1)) and g(x) = sin–1(sin(x + 2)), then-

(A) ƒ(1) + g(1) = (π – 1)

(B) ƒ(1) > g(1)
(C) ƒ(2) > g(2)
(D) ƒ(2) < g(2)

2) is-

(A)

(B)

(C)

(D)

3) If a, b, c are three positive real numbers, then can be never equal to

(A) 1
(B) 2

(C)

(D) 3

4) Which of the following satisfy the equation

(A)

(B)

(C)

(D)

5) Let ƒ(n) = upto n terms

(A)

(B) (1 + 4.2n) tan(ƒ(n)) = 2 + 22 + 23 + ... upto n terms

(C)

(D) (1 + 4.2n) tan(ƒ(n)) = 1 + 2 + 22 + 23 + ... upto n terms

6) If α = 4tan–1 and β = 8cot–12, then choose the correct statement(s) :-

(A)
(B)
(C)

(D)

7) Number of real solution(s) of is less than

(A) 0
(B) 1
(C) 2
(D) 3

8) Let ƒ : R → (0, π) be defined as . If range of ƒ(x) is (a, b], then -

(A) a + b = π

(B)

(C)

(D)

SECTION–II

1) If f(x) = and

g(x) = ,

then is equal to :

2) The number of possible value(s) of K for which is 'λ'

then value of 'λ' is -
3) , find

4) If , find , where [.] g.i.f.

5) The sum of all those terms, of the arithmetic progression 3, 8, 13,…… 373, which are not divisible
by 3, is equal to ________.

6) Suppose a1, a2, 2, a3, a4 be in an arithmetico-geometric progression. If the common ratio of the
corresponding geometric progression is 2 and the sum of all 5 terms of the arithmetico-geometric

progression is , then a4 is equal to ________ .

 ANSWER KEYS

PART-1 : PHYSICS

SECTION–I (a)

Q. 1 2 3 4
A. B A D B

SECTION–I (b)

Q. 5 6 7 8 9 10 11 12
A. B,D A,D A,C,D B,D B,D A,D B,D C,D

SECTION–II

Q. 13 14 15 16 17 18
A. 1 6 6 6 10 8

PART-2 : CHEMISTRY

SECTION–I (a)

Q. 19 20 21 22
A. C B A D

SECTION–I (b)

Q. 23 24 25 26 27 28 29 30
A. A,C A,B,C,D C,D A,C A,B,D A,C A,B,D A,B,D

SECTION–II

Q. 31 32 33 34 35 36
A. 116 3 6 100 2 5

PART-3 : MATHEMATICS

SECTION–I (a)

Q. 37 38 39 40
A. A B A B

SECTION–I (b)

Q. 41 42 43 44 45 46 47 48
A. A,B,C A,B A,B,C A,B A,B A,C,D B,C,D A,D
 SECTION–II

Q. 49 50 51 52 53 54
A. 1 3 10 92 9525 16
 SOLUTIONS

PART-1 : PHYSICS

1)

0
cos θ =

ϕ= =

or

2a = or 4a2 = a2 + R2 or 3a2 = R2 or a =

2) Centre of charge of ring lies at its centre of mass.

Centre of charge moves by a distance "x" along electric field from 1 to 2.

Charge on ring (Q) = (λ1)πR
mass of ring (M) = (λ2)πR
Work on ring by field (w) = QEx {x = 2a}
λ1 = linear charge density

w = λ1πRE (2)
λ2 = linear mass density
w = 4λ1ER2π
 kinetic energy of ring (K) =

I (moment of inertia) =
ω → angular velocity at final position
Since initially ring is at rest –
w = k (Work energy theorem)

4πλ1ER2 =

ω2 =

ω=

3)

Q=

=
Q = 2πaA(1 – e–2R/a)

R=

4)
 5)

Theory from classnotes

6)

T2 ∝ r3/2; T2 ∝ m–1/2

7)

(A)

∴ mP =
(B) It does not excute SHM about x-axis

(C)

(D) Direction of SHM is

8)

P1 max = maω1 = b
P2 max = mRω2 = R

E1 =

E2 =
 9)

Gauss law will still be valid as it is not dependent on sign (+ve or –ve) of charge Gauss law is only
dependent only on net charge in an enclosed surface.
According to Gauss law

For option (B)

as

So,
for option (D)

10)

(i) field line density at A is more so

(ii) Potential decrease in the direction of electric field so

11)

We know,

So, dimension

= MLT–2× L2 = ML3T–2

Similarly; ⇒ dim (KBT) = dim(Energy) = ML2T–2

(A)

(B)

(C)

(D)
[∴ dimension n = ]

12)

(A) for a point charge

So Gauss law is not valid.

(B) Gauss law cannot be used to find electric field due to electric dipole because we can't find any
closed surface at which electric field is uniform.
(C) Electric field due to both charges should be antiparallel and for that sign of both charges should
be same.

(D) Electric field is conservative force so work done will only be dependent of initial & final
position and it will be equal to the change in potential energy.

if q = unit charge i.e. 1C

then

13)
Potential energy of q0 is maximum at point A for it's path from +∞ to A by energy conservation

14)
4
C2 combination are possible

15)

By Gauss Law
20r3 = Qin

Qin = 6

16)

17) 100 – 50 = 5aA

aB = 0

18) kx cos37° = T cos53°

kx cos53 + T cos37 = mg

⇒ ⇒

does not change suddenly

⇒

⇒ a = 8 m/s2

PART-2 : CHEMISTRY

19)

(A) Tbp of A = 300K; Tbp of B = 400 K;

A less volatile substance has a higher boiling point.

(B)
XB = 0.6; ⇒ XA = 0.4 ⇒ yA = 0.5 according to graph

(C)
for XB = 0.4; yB = 0.1

(D)
for XA = 0.5; XB = 0.5 ⇒ According to graph; Tbp = 350 K

20)

XA = 700 ..(i)
X''A = 0.30 + 0.70 = 600
if moles of A & B initially are x & y then

x = 0.75 × (x + y) + 0.3 × (x + y)

& xA = or xB =
Solving gives

xA = 0.6 torr
xB = 0.4 = 500 torr ]

21)

A→ B+ C
P0 0 0
P0–x x x
0 p0 p0
Given :
p0 – x= 200
p0 + x= 300
⇒ p0 = 250
x = 50

K=

=
= ℓn 1.25 sec–1

22)

Assertion A : Not correct , Reason R : correct

[6] – annulene

[8] – annulene
[10] – annulene
In [10] –Annulene – the hydrogen atoms in the 1 and 6 position interfere with each other and force
the molecule out of planarity

If this annulene with five cis double bonds were planar, each internal angle would be 144°. Since a
normal double bond has bond angle of 120°, this would be from ideal. This compound can be made
but it does not adopt a planar conformation and therefore is not aromatic even though it has ten p
electrons.

23)

(d) If external pressure changes, azeotropic point also changes i.e., 'Y' changes.
(c) At 'X' composition, B.P. is greater than TB.
(b) –ve deviation solution forms maximum B.P. azeotropic mixture.

24)

(A)
∴ Moles of water separated as ice = 200 - 37 = 163
 (B)

(C) For original solution :

(D) For final solution :

25)

Point z corresponds to an azeotropic solution that has similar composition in vapour, as well as,
liquid solution. These solutions cannot be separated by fractional distillation.
The azeotropic solution shown in figure has highest boiling point & ∴ lowest vapour pressure among
all possible binary solutions made by mixing the two components in variable proportions.

26)

Solution showing positive deviation from Raoult's law

∴ L – M interactions are weaker than L – L & M – M interactions.

27)

28)

A 2B
t = 0 64
t = t (64 – x) 2x

t=∞ 0 2 × 64
PTotal = 64 – x + 2x
= 64 + x
t = 20 : x = 48
t = 40 : x = 60
 29) Fact

30)

31)

Amount of solvent = 100 – (29.25 + 19) = 51.75g

ΔTb = 16.075
ΔTb = (Tb)solution – (Tb)solvent
(Tb)solution = 100 + 16.07
= 116.07°C

32)

ΔTb = i kb m
0.14 = (1 + α) × 0.5 × 0.25
α = 0.12
[H+] = 0.03 M

33) PT =

= 40 × + 30 × = 24 + 12 = 36 torr.

34)

t1/2 = 0.3010 min

A0/At at time 2 min = ?
⇒

Or

35)

For first order reaction

36) Refers to notes.

PART-3 : MATHEMATICS

37)

⇒ ƒ(g(x)) = –x
⇒ e30–2x = –x ⇒ No solution

39)

41)
ƒ(1) = cos–1(cos2) = 2
g(1) = sin–1(sin3) = (p – 3)
ƒ(1) + g(1) = (π – 1) and ƒ(1) > g(1)
ƒ(2) = cos–1(cos3) = 3
g(3) = sin–1(sin4) = (π – 4)

42)

Tr = tan–1(r + 3) – tan–1(r + 1)
sum = π – (tan–1(2) + tan–1(3))

44)

Domain :

Let where

........(1)

Case I :

happens

Case II:
becomes
Hence (1) becomes (Not possible)

45)
 46)

Also,

47) AM > GM

No solution.

48)

49)

Clearly, = (gofog) (3–) = (gof) (0+) = g(2+) = 1.]

50)
Now if k = 0 then

And if k ≠ 0 then L =
⇒ k2 – 3k – 4 = 0 ⇒ k = 4, –1

53)

Required sum = (3 + 8 + 13 + 18 + ……… + 373)

– (3 + 18 + 33 + …… + 363)

= 75 × 188 – 25 × 183
= 9525

54)

, , a, 2(a + d), 4(a + 2d)

a=2

Sum =

⇒d=1
⇒ a4 = 4 (a + 2d) = 16