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Desmodur W

Characterization Desmodur W is a liquid cycloaliphatic diisocyanate.

Characteristic data
Property Value Unit of measurement Method
NCO content (GC) ≥ 31.8 % internal method
Hydrolyzable chlorides ≤ 10 ppm internal method
Assay (GC) ≥ 99.5 % internal method
Acidity ≤ 10 ppm internal method
Hazen color value ≤ 30 DIN EN 1557

Other data*
Property Value Unit of measurement Method
Density at 20°C 1.07 g/cm
3 DIN EN ISO 2811
Viscosity at 25°C approx. 30 mPa∙s DIN EN 3219/A.3
Vapor pressure at 25°C approx. 2.1 · 10
-5 hPa
Flash point approx. 200 °C DIN EN 22719
Total chlorides ≤ 1,000 ppm
Start of crystallization approx. 25 °C
*These values provide general information and are not part of the product specification.

Properties / Applications Desmodur W is also known as PICM, hydrogenated MDI (HMDI or H12MDI),
saturated MDI (SMDI), reduced MDI (RMDI), and dicyclohexylmethane
diisocyanate. Desmodur W diisocyanate is useful as a reactive building block
for the preparation of chemical products, reactive intermediates and polymers.
Desmodur W diisocyanate is especially useful as an organic intermediate
because the isocyanate groups can undergo addition reactions at room
temperature with compounds which contain active hydrogens. Desmodur W
diisocyanate allows the preparation of polyurethane products which have
a unique set of properties. Polyurethane resins based on Desmodur W
diisocyanate have a high degree of flexibility coupled with good mechanical
strength. They are resistant to abrasion and hydrolysis and retain gloss and
physical properties upon weathering.
A unique feature of Desmodur W diisocyanate is its ability to form optically
clear polyurethanes when combined with suitable polyol coreactants. Products
based on Desmodur W diisocyanate may be useful in coatings for flooring,

page 1 of 3
Document contains important information and must be read in its entirety.

Edition 2020-07-17 Product Datasheet

Replaces edition dated 2014-02-12
 ®
Desmodur W

roofing, maintenance, and textile applications as in cast elastomers, potting

and encapsulation compounds, optical products, medical products, adhesives,
and sealants. As with any product, use of Desmodur W in a given application
must be tested (including but not limited to field testing) in advance by the user
to determine suitability.

Regulatory Information Desmodur W is in compliance with 21 CFR 175.105 and 177.1680 for use as
a component in the manufacture of polyurethane adhesives that comply with
175.105 and polyurethane resins that comply with 177.1680 subject to these
limitations and any other applicable regulations.
Handling Information This product contains reactive H12MDI polyisocyanate/prepolymer and/or
monomeric H12MDI and should only be handled using appropriate protective
measures. Please review this product ’s Material Safety Data Sheet for a
summary of such protective measures. These products are suitable only
for and should only be sold for use by industrial or trade (commercial)
professionals. These products are not suitable for Do-It-Yourself applications.

Storage Desmodur W diisocyanate must be stored in tightly sealed containers.

Precautions must be taken to avoid contamination by moisture and air.
Processability of this material can be adversely affected by contamination.
Water or moisture in the air reacts with the product to generate pressure. If
partially filled containers are stored, it is advisable to blanket the liquid surface
with dry nitrogen before sealing.
If Desmodur W diisocyanate is stored for prolonged periods at or below a
temperature of 77°F, crystallization and settling of the isomer may occur.
Storage in a cold warehouse can cause crystals to form. These crystals can
settle to the bottom of the container. If the crystals do form, they can be melted
easily with moderate heat. It is suggested that a container the size of a drum
be warmed for 16 –24 hours at 104 –122°F (40 –50°C.) When the crystals are
melted, the container should be agitated by rolling or stirring, until the contents
are homogenous. Since heated Desmodur W diisocyanate (104-122°F) will
generate vapors more rapidly than product at 77°F, be sure to follow the
precautions listed on the MSDS in the section entitled “Personal Protection ”
whenever you open a heated container of Desmodur W diisocyanate.
Should it become necessary to transfer Desmodur W diisocyanate from the
original containers, new containers should be of plain, clean steel, or steel
lined with a suitable coating (i.e., DuPont ’s Dulux 1840¬045). If Desmodur W
diisocyanate is transferred to glass, use acid-washed amber or Pyrex glass.
Bottle caps should be aluminum foil lined for the best moisture seal. Bung
plugs used for larger containers should contain a polyethylene seal.

page 2 of 3
Document contains important information and must be read in its entirety.

Edition 2020-07-17 Product Datasheet

Replaces edition dated 2014-02-12
 ®
Desmodur W

Storage time Covestro represents that, for a period of nine months following the day
of shipment as stated in the respective transport documents, the product
will meet the specifications or values set forth in section "specifications or
characteristic data" above, what ever is applicable, provided that the product is
stored in full compliance with the storage conditions set forth in and referenced
under section "storage" above and is otherwise handled appropriately.
The lapse of the nine months period does not necessarily mean that the
product no longer meets specifications or the set values. However, prior to
using said product, Covestro recommends to test such a product if it still
meets the specifications or the set values. Covestro does not make any
representation regarding the product after the lapse of the nine months period
and Covestro shall not be responsible or liable in any way for the product failing
to meet specifications or the set values after the lapse of the nine months
period.
Health and Safety Information Appropriate literature has been assembled which provides information
concerning the health and safety precautions that must be observed when
handling this product. Before working with this product, you must read
and become familiar with the available information on its risks, proper
use, and handling. This cannot be overemphasized. Information is available
in several forms, e.g., safety data sheets and product labels. For further
information contact your Covestro LLC representative or the Product Safety
and Regulatory Affairs Department in Pittsburgh, PA.

The manner in which you use and the purpose to which you put and utilize our products, technical assistance and information (whether verbal, written
or by way of production evaluations), including any suggested formulations and recommendations, are beyond our control. Therefore, it is imperative
that you utilize our products, technical assistance and information to determine to your own satisfaction whether our products, technical assistance and
information are suitable for your intended uses and applications. This application-specific analysis must at least include testing to determine suitability
from a technical as well as health, safety, and environmental standpoint. Such testing has not necessarily been done by us. Unless we otherwise agree
in writing, all products are sold strictly pursuant to the terms of our standard conditions of sale which are available upon request. All information and
technical assistance is given without warranty or guarantee and is subject to change without notice. It is expressly understood and agreed that you
assume and hereby expressly release us from all liability, in tort, contract or otherwise, incurred in connection with the use of our products, technical
assistance, and information. Any statement or recommendation not contained herein is unauthorized and shall not bind us. Nothing herein shall be
construed as a recommendation to use any product in conflict with any claim of any patent relative to any material or its use. No license is implied
or in fact granted under the claims of any patent.
Editor: Covestro LLC
1 Covestro Circle
Pittsburgh, Pennsylvania 15205 Contact:
United States CAS Single Point of Contact APAC
www.covestro.com e-mail: [email protected]
page 3 of 3
Document contains important information and must be read in its entirety.

Edition 2020-07-17 Product Datasheet

Replaces edition dated 2014-02-12