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    HC28845526 Su en

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    HC28845526 Su en

    Uploaded by

    rodolfo mendez
    6 views2 pages

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    1702260500_HC28845526_SU_EN

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    6 views2 pages

    HC28845526 Su en

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    rodolfo mendez

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    of 2

    www.sigmaaldrich.

    com

    Certificate of Analysis – Certified Reference Material

    Certipur® Mercury standard solution 1000 mg/l Hg


    Product no.: 1.70226.0500
    Lot no.: HC28845526
    Description of CRM: Mercury standard solution 1000 mg/l Hg
    Expiry date: 2026/05/31
    Storage: +15°C to +25°C tightly closed in the original container
    Composition: Hg(NO3)2 in HNO3 2 mol/l

    Analyte Certified value as mass fraction Associated uncertainty, U=k·u


    (k=2) as mass fraction
    Hg 947 mg/kg ± 8 mg/kg

    Metrological traceability: Directly traceable to NIST SRM 3133, lot 160921


    Measurement method: Inductively coupled plasma optical emission spectrometry ICP-OES
    Intended use: This reference material is intended for use as a calibration standard in element
    analysis.
    Instructions for handling Shake well before use and never pipet directly from the original container. See
    and correct use: Details for correct use on page 2.
    Health and safety Please refer to the Safety Data Sheet for detailed information about the nature of
    information: any hazard and appropriate precautions to be taken.
    Accreditation: Merck KGaA, Darmstadt, Germany is accredited by the German accreditation
    authority DAkkS as registered reference material producer D-RM-15185-01-00 in
    accordance with ISO 17034.
    Certificate issue date: 2022/05/31

    CRM released by Approving Officer


    or delegate of Quality Control

    ͲZDͲϭϱϭϴϱͲϬϭͲϬϬ Dipl.-Ing. Ayfer Yildirim


    ISO 17034
    Responsible Laboratory Manager

    Merck KGaA, 64271 Darmstadt, Germany, Tel. +49(0)6151 72-2440


    EMD Millipore Corporation, 400 Summit Drive, Burlington MA 01803, USA, Tel. +1-978-715-4321
    Sigma-Aldrich Canada Co. or Millipore (Canada) Ltd. 2149 Winston Park, Dr. Oakville,
    Ontario, L6H 6J8, Phone: +1 800-565-1400

    Certificate Page 1 of 2 Certificate version 01


    Details on correct use:
    The user should be aware of the additional effect of transpiration losses of solvent through the container walls of
    the unopened bottle. The effect leads to an increase of the mass fraction in the range of 0.012 mg/kg per month.
    It is the responsibility of the user to account for this effect by correction of the certified value by
    w(t) = 0.012 · t + w(t0)
    w(t) = element mass fraction after storage time in months
    t = storage in months of the unopened bottle
    w(t0) = element mass fraction at the time of certification

    Certification process details:


    Certipur® AAS single element standards are prepared gravimetrically from high purity raw materials in either high
    purity acids or high purity bases Suprapur® and diluted with filtered (0.22 µm) high purity water (18 MΩ). All
    balances are regularly calibrated with analytical weight sets traceable to primary weights by PTB (Physikalisch
    Technische Bundesanstalt). The density of each batch is measured in g/cm3 at 20°C and is used to calculate the
    concentration in mg/l.
    Characterisation of Certipur® AAS single element standards is carried out by the accredited quality control (QC)
    laboratory at Merck KGaA, Darmstadt, Germany according to DIN EN ISO / IEC 17025 by inductively coupled plas-
    ma optical emission spectroscopy (ICP – OES).
    Homogeneity and stability studies are performed with the material according to the requirements of ISO 17034
    and ISO Guide 35.

    Associated uncertainty:
    The associated uncertainty UCRM reported with the certified values is calculated as combined expanded uncertainty
    UCRM=k·uCRM in accordance with GUM and EA-4/02, with k=2 as the coverage factor for a 95% coverage probability.

    The combined uncertainty uCRM is derived from combination of the squared uncertainty contributions:
    uCRM = √ u2Characterisation + u2Homogeneity + u2Stability

    ucharacterisation: is the uncertainty in accordance with DIN EN ISO/IEC 17025 which includes the
    contributions of the primary reference material and the measuring system. The
    characterisation measurements have been conducted by our DAkkS accredited
    calibration laboratory (D-K-15185-01).
    uhomogeneity: is the between-bottle variation in accordance with ISO 17034. The assessment of
    homogeneity is performed by analysis of a representative number of systematically
    chosen sample units.
    ustability: is the uncertainty obtained from short-term and long-term stability in accordance
    with ISO 17034. The stability studies are the basis for the quantification of the
    expiry date of this elemental standard for the unopened bottle.

    Informative values:
    The density of the elemental standard solution is 1.0555 g/cm3 at 20°C and is used to calculate the
    concentration 999 mg/l.

    For more detailed information please read the certification report on our website.

    Certificate of analysis revision history:


    Certificate version Date Reason for version
    01 2022/05/31 Initial version

    The vibrant M, Supelco, Certipur, Suprapur and Sigma-Aldrich are trademarks of Merck KGaA, Darmstadt,
    Germany or its affiliates.
    Detailed information on trademarks is available via publicly accessible resources.
    © 2022 Merck KGaA, Darmstadt, Germany and/or its affiliates. All Rights Reserved.

    The life science business of Merck KGaA, Darmstadt, Germany operates


    as MilliporeSigma in the U.S. and Canada.

    Certificate Page 2 of 2 Certificate version 01

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