Worksheet NO 3 Chemical Kinetics Class 12

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QUESTION BANK

CHAPTER: CHEMICAL KINETICS


TOPIC: Order and Molecularity of a Reaction Rate Law and Specific Rate Constant
CLASS XII
M.M.: 10
1. The correct graphical representation of first – order reaction is: 1

a. (i) and (ii) b. (ii) and (iii)

c. (iii) and (iv) d. (i) and (iv)

2. Which of the following statements about the molecularity of a reaction is 1


incorrect?
a. It is determined from the b. It can be zero.
reaction mechanism

c. It cannot be fractional. d. It is always a positive integer.

CH3COOC2H5 + H2O CH3COOH + C2H5OH


3. The reaction below is an example of: 1

a. Pseudo – first – order reaction b. First – order reaction

c. Second – order reaction d. Third – order reaction

For question no. 4 to 5 there are two statements labelled as Assertion (A) and Reason (R)
Select the most appropriate answer from the options given below:
(a) Both A and R are true and R is the correct explanation of A.
(b) Both A and R are true but R is not the correct explanation of A.
(c) A is true but R is false.
(d) A is false but R is true.
4. ASSERTION: Order of a reaction with respect to any reactant can be 1
zero, positive, negative or fractional.
REASON: The order of a reaction is determined experimentally and
is not necessarily related to the stoichiometric
coefficients of the reactants in the balanced chemical
equation.
5. ASSERTION: For a complex reaction, the order of the reaction can be 1
determined by adding the stoichiometric coefficients of
the reactants.

(i) For the reaction A + 2B C, the rate law is given by Rate = k AB2. If the
REASON: 1
6. 2
concentration of B is doubled while keeping A constant, by what factor
will the rate of the
reaction increase?
(ii) What is the unit of rate constant of second order reaction?
7. Consider the following data for the reaction: A + B C 3
[A] (M) [B] Initial Rate (M/s)

2 10-3
(M)

4 10-3
0.1 0.1

2 10-3
0.2 0.1
0.1 0.2
Determine the rate constant and overall order of the reaction.

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