ST - Xavier Chem..

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Aadibyo
DATE: ST. XAVIER'S SCHOOL SHAHBAD DAULATPUR CLASS: X
TIME: 3hrs CHEMISTRY (FINAL EXAM) MM: 70
SET 1 um
INSTRUCTIONS
(i) There 35 questions in this question paper with no internal

are
choice
(i) Section A consists ot 18 multiple choice question carrying 1mark each
(ii) Section B consists of7 very short answer question carrying 2 mark each
(iv) Section C consists of S short answer question carrying3 marks each.
(v) Section D consists of 2 case-based question carrying4 marks each.
(vi) Section E consists of 3 long answer question carrying 5 marks eacn.
(vii) All questions are compulsory.
(viii) use of log tables and calculators is not allowed
SECTION A
INote- The following question are multiple - choice question with one correct answer. Fach
question carries 1 mark. There is no internal choice in these questions.
1.A solution of naphthalene in benzene is 3% by mass of naphthalene. The mass % of
benzene is
(a) 9.7% (b) 0.97%
(c) 97 % (d) 0.097%
2. The molar mass of C204aH2.2H20 is
(a) 116 gm/mol (b) 126 gm/mol (c) 106 gm/mol (d) 100 gm/mol
3. The amount of cO2 that could be produced when one mole of carbon is burnt in 16gm of
Oxygen is
(a) 22gm (b) 11gm (c) 44gm (d) 16gm

4. Empirical formula of an oxide of iron which has 69.9% iron and 30.1% oxygen by mass is
(a) FeO (b) Fe02 (c) FeSO4 (d) Fe:0s

5.The inter molecular interaction between HCl and CH3COCH3s is
(a) ion-dipole (b) dipole-dipole (c) H-bond (d) dispersion force
6.Heat is transferred from system to surroundings, its conventional sign is
(a) +ve (b)-ve (c) 0 (d) +/-

7. Boiling point of a liquid does not depend on
(a) atmospheric pressure (b) vapour pressure

(c) altitude (d) freezing poin
8. The unit of Kc for reaction 2NO)+ Cl2(e) 2NOCe) is
(a) L/mol (b) mol/L (c) atm (d) mol/L'

9. The
oxidising agent in the reaction MB(+ S(s- MgS(), is
(a) Mg (b) S (c)Mgs (d) Mg &S

10. Oxidation number of AU in HAUCl4 is
(a) 0 (b) 1 (c) 2 (d) 3

11. Cyclopropane is a
(a) acyclic compound (b)heterocyclic compound

(c) homocyclic compound (d) aromatic compound
12.In the IUPAC naming -OH group is more prior than
(a)-NH2 (b)-CHO (c)-CN (d)-coOH

13. CaHsOCaHs and CH3OC3H7 show
(a) chain isomerism (b) functional group isomerism
(c) position isomerism (d) metamerism
14. CI is an example for
(a) electrophile (6) neucleophile

(c)-E effect (d)+I effect
15. Given below are two statements labelled Assertion(A) and Reason(R)
Assertion(A) : In Adiabatic process there is no transfer of heat between the system and thee
surroundings.
Reason(R) : Adiabatic process takes place in an insulted container.
Select the most appropriate answer from the option given below:
a. Both A and R are true and R is the correct explanation of A
b. Both A and R are true but R is not the correct

explanation of A
C. A is true but R is false
d. A is false but R is true
Assertion(A) : Equilibrium constant for the reverse reaction is the inverse of
the
constant for the reaction in the forward direction.
equilibrium
CH
(
Reason(R) : A reaction equilibrium is irrereversible.

at
Select the most
appropriate answer from the option given below:
a. Both A and R are true and R is the correct
explanation of A
b. Both A and R are true but R is not the
correct explanation of A
Assertion(A) :Hydrogen peroxide can act as oxidising as well as reducing agents in their
reactions.
Reason(R) :Hydrogen peroxide can undergo disproportionation reaction.

a. Both A and R are true and R is the correct
explanation of A
b. Both A and R are true but R is not the correct explanation of A
18. Given below two statements labelled

are
Assertion(A) and Reason(R)
Assertion(A) : The organic reactions which proceed through heterolytic bond cleavage are
called ionic reactions.
Reason(R): During heterolytic bond cleavage free radicals are formed.

a. Both A and R are true and R is the correct explanation of A
b. Both A and R are true but R is not the correct explanation ofA
c. A is true but R is false
SECTIONB
The following 7 questionsare very short answer type and carry 2 marks each]
19. Calculate the mass of sodium acetate [CH3coONa] required to make 500ml of 0.375
molar aqueous solution.
20. (i) Define enthalpy and entropy.

(i) Which physical state is the state of lowest entropy?
2. State
LeChatelier's principle. Explain the effect of pressure change
22.
on
equilibriu
Balance the
following in acidic medium
Cr:0 aSO Cr SO
23. Explain the combination reaction and decompositon reactions with example.
24. Write the lUPAC
names of the following compounds. I t - 3 ) : -2
(a) (CHs):NCHs
(b) CH,CH:CoCH-CH,
CH
OH
(c) CH-CH-CH:-CN (d 2+(-2?)
CHc
25. Explain-R effect with 2 ct-1) -2

an example.
x (-8) -2 2 -2 +
SECTION IC -2+8
[ The following 5 questions are short answer type and carry 3 marks each]
26. Calculate molarity, molality and molefraction of 69% (w/w) HNO; Solution. The
of solution is 1.41gm/ml. density
27. The reaction of

NH CN with oxygen was affected in a bomb
calorimeter and AU was
found to be -742.7 kgmol at 298K. Calculate the
enthalpy change for the reaction at the
same temperature.
NHCN + 3/2 0zgNi+COz)+ H:O
28. A mixture of 1.57 mol N2, 1.92 mol H2 and 8.13 mol NH3 are
introduced into a 20L
reaction vessel at S00K. At this temperature, the equilibrium constant Kc for
the reaction
EIven asS
N21)t 3H2 2NHs(E

1.7x10. Is this reaction at equilibrium? if not, what is the direction of the net reaction?
29.(a) Write the bond line notation of HOCH(CN): and also calculate the number of ohdn
bond
(b)How can you convert benzene to (i) Nitrobenzene and (ii) Chlorobenzene
30. (a) What is hyperconjugation?

(b) Write the structure for the following:
i) But-2-ene-1,4-dioic acid
ii) 2-Nitrocyclohexane-carboxamide
2-Bum-1,1 dieltAd
SECTIOND
The following questions are case Dased question. Each
question carry 4 marks. Read the
passage carefully and answer the questions that follow
31AHis negative for exothermic reactions which evolve heat

AHis positive for endothermic reactions which absorb heatduring
fron
the reaction and
the
The difference between Hand U is not usually surroundirngs,
significant for systems consistingof
only solids and /orliquids.Solids
and liguids do not suffer any significant volume
upon heating.The difference, however becomes significant when
change
gases are involved. The
calculations involve the difference between the number of moles of
gaseous products
minus number of moles of gaseous reactants.
(a) Write the relation between enthalpy change and entropy change for a system
consisting gases.
(6) For what type of reaction A4 is +ve?
(c) Write any value of 'R'.
(d) Ang) Stands for what?
32.Place a strip of metalic zinc in an aqueous solution of copper nitrate for about an hour.
The strip becomes coated with reddish metallic copperand the blue colour of the solution
disappears. Formation of Zn" ions among the products can easily be judged when the
biue colour of the solution disappears .Zinc has lost electrons and copper has gained
electrons.lf hydrogen sulphide gas is passed through the colourless solution ,appearance
of white ZnS can be seen on making the solution alkaline with ammonia.
(a) Draw the diagram for the above reaction.

(b) What is the specific name of this reaction?
(c) Name the element oxidised and reduced.
(d) Write the chemical equation for the above.
SECTION E
The following questions are long answer type and carry 5 marks each.]
33. (a) Find the value of Kc for the following equilibrium, from the value of Kp.
2NOCI2NOg+Clai Kp= 1.8x10 atm at 500K.
(b) Which of the following is not a Lewis acid? BF, H,0, H, NH"
(c) Calculate the pH of 0.005M NaOH (log5 = 0.6990).
d) Write the conjugate acid and conjugate base for HCO3

34. (a) Explain Daniell cell with diagram.
i) Which electrode is negatively charged?
i) Which electrode is positively charged?
ii) Write the individual reaction at each electrode.
(b) Write the difference between metal displacement and non-metal
displacement with
Example
35. Explain the following name reactions with an example each.

(a) Decarboxylation
(b) Wurtz reaction
(c) Anti Markonikov rule
(d) B-elimination reaction
(e) Friedel-crafts acylation reaction

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(

(i) There 35 questions in this question paper with no internal

(a) 9.7% (b) 0.97%

(c) 97 % (d) 0.097%

2. The molar mass of C204aH2.2H20 is

(a) 22gm (b) 11gm (c) 44gm (d) 16gm

(a) FeO (b) Fe02 (c) FeSO4 (d) Fe:0s

(a) ion-dipole (b) dipole-dipole (c) H-bond (d) dispersion force

6.Heat is transferred from system to surroundings, its conventional sign is

(a) +ve (b)-ve (c) 0 (d) +/-

(a) atmospheric pressure (b) vapour pressure

(a) L/mol (b) mol/L (c) atm (d) mol/L'

(a) Mg (b) S (c)Mgs (d) Mg &S

(a) 0 (b) 1 (c) 2 (d) 3

(a) acyclic compound (b)heterocyclic compound

12.In the IUPAC naming -OH group is more prior than

(a)-NH2 (b)-CHO (c)-CN (d)-coOH

(a) electrophile (6) neucleophile

a. Both A and R are true and R is the correct explanation of A

b. Both A and R are true but R is not the correct

d. A is false but R is true

Reason(R) : A reaction equilibrium is irrereversible.

d. A is false but R is true

Reason(R) :Hydrogen peroxide can undergo disproportionation reaction.

C. A is true but R is false

d. A is false but R is true

18. Given below two statements labelled

Reason(R): During heterolytic bond cleavage free radicals are formed.

a. Both A and R are true and R is the correct explanation of A

c. A is true but R is false

d. A is false but R is true

20. (i) Define enthalpy and entropy.

25. Explain-R effect with 2 ct-1) -2

27. The reaction of

NHCN + 3/2 0zgNi+COz)+ H:O

N21)t 3H2 2NHs(E

30. (a) What is hyperconjugation?

31AHis negative for exothermic reactions which evolve heat

(a) Draw the diagram for the above reaction.

(c) Calculate the pH of 0.005M NaOH (log5 = 0.6990).

d) Write the conjugate acid and conjugate base for HCO3

35. Explain the following name reactions with an example each.

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