VEDANTA

Subject : Chemistry Paper Set : 1

Standard : 11 Atomic structure SC Batch Date : 11-11-2024
Total Mark : 120 Time : 0H:0M

............ Chemistry - Section A (MCQ) ............ (A) 6.67 × 1015 (B) 6.67 × 1011
(C) 4.42 × 10−15 (D) 4.42 × 10−18
(1) Which one is the wrong statement? (8) Be2+ is isoelectronic with which of the following
(A) The uncertainty principle is ∆E × ∆t ≥ h
4π ions?
(A) H + (B) Li+
(B) Half filled and fully filled orbitals have greater
stability due to greater exchange energy, (C) N a+ (D) M g 2+
greater symmetry and more balanced (9) What is the maximum numbers of electrons that
arrangement. can be associated with the following set of
(C) The energy of 2s− orbital is less than the quantum numbers?
energy of 2p− orbital in case of hydrogen like n = 3, l = 1 and m = −1
atoms. (A) 4 (B) 2
(D) de-Broglie’s wavelength is given by λ = mv
h
, (C) 10 (D) 6
where m = mass of the particle, v = group ( 2)
(10) Based on equation E = −2.178 × 10−18 J Zn2
velocity of the particle.
certain conclusions are written. Which of themis
(2) How many electrons can fit in the orbital for not correct?
which n = 3 and l = 1 ? (A) Equation can be used to calculate the change
(A) 6 (B) 2
in energy when the electron changes orbit.
(C) 10 (D) 14
(B) For n = 1, the electron has a more negative
(3) Which of the following pairs of d− orbitals will energy than it does for n = 6 which means
have electron density along the axes ? that the electron is more loosely bound in the
(A) dz2 , dxz (B) dxz , dyz smallest allowed orbit.
(C) dz2 , dx2 −y2 (D) dxy , dx2 −y2 (C) The negative sign in equation simply means
(4) Two electrons occupying the same orbital are that the energy of electron bound to the
distinguished by nucleus is lower than it would be if the
(A) azimuthal quantum number electrons were at the infinite distance from
the nucleus.
(B) spin quantum number
(D) Larger the value of n, the larger is the orbit
(C) principal quantum number radius.
(D) magnetic quantum number (11) The value of Planck’s constant is 6.63 × 10−34 J s.
(5) Which is the correct order of increasing energy of The speed of light is 3 × 1017 nm s−1 . Which value
the listed orbitals in the atom of titanium? (At. is closest to the wavelength in nanometer of a
no. Z = 22) quantum of light with frequency of 6 × 1018 s−1 ?
(A) 4s 3s 3p 3d (B) 3s 3p 3d 4s (A) 50 (B) 75
(C) 3s 3p 4s 3d (D) 3s 4s 3p 3d (C) 10 (D) 25
(6) The angular momentum of electron in ′ d′ orbital is (12) The outer electronic configuration of
equal√to Gd (At. N o. 64) is
(A) 2 3 h̄ (B) 0 h̄ (A) 4f 5 5d4 6s1 (B) 4f 7 5d1 6s2
√ √
(C) 6 h̄ (D) 2 h̄ (C) 4f 3 5d5 6s2 (D) 4f 4 5d5 6s1
(7) Calculate the energy in joule corresponding to (13) According to law of photochemical equivalence
light of wavelength 45 nm. (Planck’s constant, the energy absorbed (in ergs/mole) is given as
h = 6.63 × 10−34 J s, speed of light, (h = 6.62 × 10−27 ergs, c = 3 × cms−1 , NA =
c = 3 × 108 m s−1 ) 6.02 × 10−23 mol−1 )

1
 (A) 1.196×108
(B) 2.859×105 (23) The total number of orbitals present for principle
quantum number, n = 4 is
λ λ

(C) 2.859×1016
λ
(D) 1.196×1016
λ (A) 12 (B) 15
(14) 4d, 5p, 5f and 6p orbitals are arranged in the order (C) 16 (D) 30
of decreasing energy. The correct option is
(A) 5f > 6p > 5p > 4d (B) 6p > 5f > 5p > 4d (24) Identify the incorrect statement from the
following.
(C) 6p > 5f > 4d > 5p (D) 5f > 6p > 4d > 5p
(A) All the five 4d orbitals have shapes similar to
(15) Which of the following series of transitions in the the respective 3d orbitals.
spectrum of hydrogen atom falls in visible region ?
(A) Lyman series (B) Balmer series (B) In an atom, all the five 3d orbitals are equal in
energy in free state.
(C) Paschen series (D) Brackett series
(C) The shapes of dxyy′ dyz , and dzx orbitals are
(16) Orbital having 3 angular nodes and 3 total nodes is
similar to each other; and dx 2 − y 2 and dz 2 are
(A) 5p (B) 3d similar to each other.
(C) 4f (D) 6d (D) All the five 5d orbitals are different in size
(17) In hydrogen atom, the de Broglie wavelength of when compared to the respective 4d orbitals.
an electron in the second Bohr orbit is [ Given
that Bohr radius, a0 = 52.9 pm] (25) If radius of second Bohr orbit of the He+ ion is
(A) 211.6 pm (B) 211.6π pm 105.8 pm, what is the radius of third Bohr orbit of
Li2+ ion?
(C) 52.9π pm (D) 105.8 pm (A) 15.87 pm (B) 1.587 pm
(18) Which one is a wrong statement ? (C) 158.7 Å (D) 158.7 pm
(A) Total orbital angular momentum of electron in
’s’ orbital is equal to zero (26) Select the correct statements from the following
A. Atoms of all elements are composed of two
(B) An orbital is designated by three quantum fundamental particles.
numbers while an electron in an atom is B. The mass of the electron is 9.10939 × 10−31 kg.
designated by four quantum numbers C. All the isotopes of a given element show same
(C) The electronic configuration of N atom is chemical properties:
D. Protons and electrons are collectively known
as nucleons.
E. Dalton’s atomic theory, regarded the atom as
an ultimate particles of matter Choose the correct
(D) The value of m for d2z is zero answer from the options given below
(A) B, C and E only (B) A, B and C only
(19) The number of protons, neutrons and electrons in
71 Lu, respectively, are :
175 (C) C, D and E only (D) A and E only
(A) 175, 104 and 71 (B) 71, 104 and 71
(27) The energy of an electron in the ground state
(C) 104, 71 and 71 (D) 71, 71 and 104 (n = 1) for He+ ion is −x J, then that for an
(20) The number of angular nodes and radial nodes in electron in n = 2 state for Be3+ ion in J is
3s orbital are (A) − x9 (B) −4x
(A) 0 and 1, respectively (B) 0 and 2, respectively (C) − 49 x (D) −x
(C) 1 and 0, respectively (D) 3 and 0, respectively
(28) Match List I with List II
(21) A particular station of All India Radio, New Delhi,
broadcasts on a frequency of 1, 368 kHz List I(Quantum Num- List II(Information
(kilohertz). The wavelength of the ber) provided)
electromagnetic radiation emitted by the A. mı I. Shape of orbital
transmitter is : [speed of light c = 3.0 × 108 ms−1 ] B. ms II. Size of orbital
(A) 219.3 m (B) 219.2 m C. 1 III. Orientation of or-
(C) 2192 m (D) 21.92 cm bital
D. n IV . Orientation of spin
(22) From the following pairs of ions which one is not of electron
an iso-electronic pair?
(A) O2− , F− (B) Na+ , Mg2+ Choose the correct answer from the options
(C) Mn2+ , Fe3+ (D) Fe2+ , Mn2+ given below :

2
(A) A − III, B − IV, C − I, D − II
(B) A − III, B − IV, C − II, D − I
(C) A − II, B − I, C − IV, D − III
(D) A − I, B − III, C − II, D − IV

3
 VEDANTA
Subject : Chemistry Paper Set : 1
Atomic structure SC Batch Date : 11-11-2024
Standard : 11
Total Mark : 120 (Answer Key) Time : 0H:0M

Chemistry - Section A (MCQ)

1-C 2-A 3-C 4-B 5-C 6-C 7-D 8-B 9-B 10 - B

11 - A 12 - B 13 - A 14 - A 15 - B 16 - C 17 - B 18 - C 19 - B 20 - B
21 - A 22 - D 23 - C 24 - C 25 - D 26 - A 27 - D 28 - A

4
 VEDANTA
Subject : Chemistry Paper Set : 1
Atomic structure SC Batch Date : 11-11-2024
Standard : 11
Total Mark : 120 (Solutions) Time : 0H:0M

............ Chemistry - Section A (MCQ) ............

(4) Two electrons occupying the same orbital are
distinguished by
(1) Which one is the wrong statement? (A) azimuthal quantum number
(A) The uncertainty principle is ∆E × ∆t ≥ h
4π (B) spin quantum number
(B) Half filled and fully filled orbitals have greater (C) principal quantum number
stability due to greater exchange energy,
greater symmetry and more balanced (D) magnetic quantum number
arrangement.
Solution:(Correct Answer:B)
(C) The energy of 2s− orbital is less than the
energy of 2p− orbital in case of hydrogen like
atoms. (5) Which is the correct order of increasing energy of
the listed orbitals in the atom of titanium? (At.
(D) de-Broglie’s wavelength is given by λ = mv
h
, no. Z = 22)
where m = mass of the particle, v = group (A) 4s 3s 3p 3d (B) 3s 3p 3d 4s
velocity of the particle.
(C) 3s 3p 4s 3d (D) 3s 4s 3p 3d
Solution:(Correct Answer:C)
In H−like atom energy of 2s = 2p orbital Solution:(Correct Answer:C)
(2) How many electrons can fit in the orbital for Ti(22) = 1s2 2s2 2p6 3s2 3p6 4s2 3d2
which n = 3 and l = 1 ? order of energy is 3s 3p 4s 3d
(A) 6 (B) 2
(6) The angular momentum of electron in ′ d′ orbital is
(C) 10 (D) 14
equal√to
Solution:(Correct Answer:A) (A) 2 3 h̄ (B) 0 h̄
For n = 3 and l = 1, the subshell is 3p and a √ √
particular 3p orbital can accommodate only 6 (C) 6 h̄ (D) 2 h̄
electrons.
Solution:(Correct Answer:C)
√
(3) Which of the following pairs of d− orbitals will Angular momentum = l(l + 1)h̄
have electron density along the axes ? For d orbital, l = 2 √ √
(A) dz2 , dxz (B) dxz , dyz Angular momentum = 2(2 + 1)h̄ = 6h̄
(C) dz2 , dx2 −y2 (D) dxy , dx2 −y2
Solution:(Correct Answer:C) (7) Calculate the energy in joule corresponding to
light of wavelength 45 nm. (Planck’s constant,
h = 6.63 × 10−34 J s, speed of light,
c = 3 × 108 m s−1 )
(A) 6.67 × 1015 (B) 6.67 × 1011
(C) 4.42 × 10−15 (D) 4.42 × 10−18

Solution:(Correct Answer:D)
The wavelength of light is related to its energy by
the equation,
E = hc
λ
· (E = hv)
Given, λ = 45nm = 45 × 10−9 m [∵ 1nm = 10−9 m]
Hence, E = 6.63×10 45×10
−34 Js×3×108 ms−1
−9 m = 4.42 × 10−18 J
Hence, the energy corresponds to light of
wavelength 45 nm is 4.42 × 10−18 J

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(8) Be2+ is isoelectronic with which of the following quantum of light with frequency of 6 × 1018 s−1 ?
ions? (A) 50 (B) 75
(A) H + (B) Li+
(C) 10 (D) 25
(C) N a+ (D) M g 2+
Solution:(Correct Answer:A)
Solution:(Correct Answer:B) λ = VC = 3×10
17 nms−1
= 50nm
6×1013 s−1
Isoelectronic species contain same number of
electrons. Be2+ contains 2 electrons. Among the (12) The outer electronic configuration of
given options, only Li+ contains 2 electrons and Gd (At. N o. 64) is
therefore, it is isoelectronic with Be2+ H + → no (A) 4f 5 5d4 6s1 (B) 4f 7 5d1 6s2
eletron N a+ → 10e− (C) 4f 3 5d5 6s2 (D) 4f 4 5d5 6s1
Li+ → 2e−
M g 2+ → 10e− Solution:(Correct Answer:B)
Hence, Be2+ is isoelectronic with Li+
(13) According to law of photochemical equivalence
(9) What is the maximum numbers of electrons that the energy absorbed (in ergs/mole) is given as
can be associated with the following set of (h = 6.62 × 10−27 ergs, c = 3 × cms−1 , NA =
quantum numbers? 6.02 × 10−23 mol−1 )
n = 3, l = 1 and m = −1 (A) 1.196×10
8
(B) 2.859×10
5
λ λ
(A) 4 (B) 2
(C) 2.859×1016
(D) 1.196×1016
(C) 10 (D) 6 λ λ

Solution:(Correct Answer:A)
Solution:(Correct Answer:B) E = hcN A

The orbital of the electron having = 3, l = 1 and

λ
6.62×10−27 ×3×1010 ×6.02×1023
=
m = −1 is 3pz ( as n/m) and an orbital can have a λ
ergsl mol−1
8 1.196×108
maximum of two electrons with opposite spins. = 1.1955×10
λ
= λ
therefore, 3pz orbital contains only two electrons (14) 4d, 5p, 5f and 6p orbitals are arranged in the order
or only 2 electrons are associated with of decreasing energy. The correct option is
n = 3, l = 1, m = −1 (A) 5f > 6p > 5p > 4d (B) 6p > 5f > 5p > 4d
( 2)
(10) Based on equation E = −2.178 × 10−18 J Zn2 (C) 6p > 5f > 4d > 5p (D) 5f > 6p > 4d > 5p
certain conclusions are written. Which of themis Solution:(Correct Answer:A)
not correct? According to (n + l) rule, correct order of energy
(A) Equation can be used to calculate the change is 5f > 6p > 5p > 4d
in energy when the electron changes orbit. For same value of (n + l); higher is the value of n,
(B) For n = 1, the electron has a more negative higher will be the energy.
energy than it does for n = 6 which means
(15) Which of the following series of transitions in the
that the electron is more loosely bound in the
spectrum of hydrogen atom falls in visible region ?
smallest allowed orbit.
(A) Lyman series (B) Balmer series
(C) The negative sign in equation simply means
(C) Paschen series (D) Brackett series
that the energy of electron bound to the
nucleus is lower than it would be if the Solution:(Correct Answer:B)
electrons were at the infinite distance from In spectrum of hydrogen atom, spectral lines of
the nucleus. Balmer series lie in visible region
(D) Larger the value of n, the larger is the orbit
(16) Orbital having 3 angular nodes and 3 total nodes is
radius.
(A) 5p (B) 3d
Solution:(Correct Answer:B) (C) 4f (D) 6d
for n = 1 the electron has more negative energy
than it does for n = 6 which means that the Solution:(Correct Answer:C)
electrons less loosely bound in the smallest Orbital having angular node (ℓ) = 3
allowed orbit. Total node = Radial node + angular node
=n−ℓ−1+ℓ
(11) The value of Planck’s constant is 6.63 × 10−34 J s. 3=n−1
The speed of light is 3 × 1017 nm s−1 . Which value n=4
is closest to the wavelength in nanometer of a Subshell nℓ = 4f

6
(17) In hydrogen atom, the de Broglie wavelength of (kilohertz). The wavelength of the
an electron in the second Bohr orbit is [ Given electromagnetic radiation emitted by the
that Bohr radius, a0 = 52.9 pm] transmitter is : [speed of light c = 3.0 × 108 ms−1 ]
(A) 211.6 pm (B) 211.6π pm (A) 219.3 m (B) 219.2 m
(C) 52.9π pm (D) 105.8 pm (C) 2192 m (D) 21.92 cm
Solution:(Correct Answer:B)
nλ = 2πr Solution:(Correct Answer:A)
nλ = 2π nz a0
2
γ = Cλ
2
nλ = 2π × nZ × 52.9pm λ = Cγ
λ = 2π × 52.9 × 2pm 3×108
λ = 1368×10 3
= 211.6πpm λ = 219.29 = 219.3 m
(18) Which one is a wrong statement ?
(A) Total orbital angular momentum of electron in (22) From the following pairs of ions which one is not
’s’ orbital is equal to zero an iso-electronic pair?
(B) An orbital is designated by three quantum (A) O2− , F− (B) Na+ , Mg2+
numbers while an electron in an atom is (C) Mn2+ , Fe3+ (D) Fe2+ , Mn2+
designated by four quantum numbers
(C) The electronic configuration of N atom is Solution:(Correct Answer:D)
Not isoelectronic
Fe+2
↓
24e−
(D) The value of m for d2z is zero
Mn+2
Solution:(Correct Answer:C) ↓
The correct configuration of ’N ’ is 23e−

(23) The total number of orbitals present for principle

quantum number, n = 4 is
(19) The number of protons, neutrons and electrons in
(A) 12 (B) 15
71 Lu, respectively, are :
175

(A) 175, 104 and 71 (B) 71, 104 and 71 (C) 16 (D) 30
(C) 104, 71 and 71 (D) 71, 71 and 104
Solution:(Correct Answer:C)
Solution:(Correct Answer:B)
175 કક્ષકાેની સં ા = n2 = 42 = 16
71 Lu
p+ = 71
n0 = 175 − 71 = 104 (24) Identify the incorrect statement from the
e− = 71 following.
(20) The number of angular nodes and radial nodes in (A) All the five 4d orbitals have shapes similar to
3s orbital are the respective 3d orbitals.
(A) 0 and 1, respectively (B) 0 and 2, respectively (B) In an atom, all the five 3d orbitals are equal in
(C) 1 and 0, respectively (D) 3 and 0, respectively energy in free state.

Solution:(Correct Answer:B) (C) The shapes of dxyy′ dyz , and dzx orbitals are
similar to each other; and dx 2 − y 2 and dz 2 are
Number of radial nodes = n − 1 − 1
similar to each other.
Number of angular nodes = 1
For 3 s orbital, Number of radial nodes (D) All the five 5d orbitals are different in size
=3−0−1=2 when compared to the respective 4d orbitals.
Number of angular nodes = 0

(21) A particular station of All India Radio, New Delhi, Solution:(Correct Answer:C)
broadcasts on a frequency of 1, 368 kHz

7
 electron in n = 2 state for Be3+ ion in J is
(A) − x9 (B) −4x
(C) − 49 x (D) −x
Solution:(Correct
( 2 ) Answer:D)
En = −RH Zn2 J
For He+ (n = 1),
( 2)
En = −x = −RH 2
12
= −4RH
∴ RH = x4
For B 3+ (n = 2),
( 2)
En = −RH nz 2 J
( )
(25) If radius of second Bohr orbit of the He+ ion is = − x4 × 4×4 =−×J
105.8 pm, what is the radius of third Bohr orbit of
2×2

Li2+ ion? (28) Match List I with List II

(A) 15.87 pm (B) 1.587 pm
List I(Quantum Num- List II(Information
(C) 158.7 Å (D) 158.7 pm ber) provided)

Solution:(Correct Answer:D) A. mı I. Shape of orbital

Acc. to Bohr’s atomic model B. ms II. Size of orbital

3rd orbit of
2
r ∝ nz C. 1 III. Orientation of or-
Li +2
n1 = 3, Z1 = 3 bital
⇒ 2nd orbit of D. n IV . Orientation of spin
He +
n2 = 2, Z2 = 2 of electron
n21
Choose the correct answer from the options
(r3 )L+2
(r2 ) +
= n2 × ZZ21
given below :
He 2
(r3 )Li+2
= 3×3 × 23
(A) A − III, B − IV, C − I, D − II
105.8pm 2×2
(r3 )Li+2 = 158.7 pm
(B) A − III, B − IV, C − II, D − I
(26) Select the correct statements from the following
A. Atoms of all elements are composed of two (C) A − II, B − I, C − IV, D − III
fundamental particles. (D) A − I, B − III, C − II, D − IV
B. The mass of the electron is 9.10939 × 10−31 kg.
C. All the isotopes of a given element show same Solution:(Correct Answer:A)
chemical properties: - Magnetic quantum number m1 informs about
D. Protons and electrons are collectively known orientation of orbital.
as nucleons. - Spin quantum number ms informs about
E. Dalton’s atomic theory, regarded the atom as orientation of spin of electron.
an ultimate particles of matter Choose the correct - Azimuthal quantum number (l) informs about
answer from the options given below shape of orbital
(A) B, C and E only (B) A, B and C only
- Principal quantum number (n) informs about
(C) C, D and E only (D) A and E only size of orbital
Solution:(Correct Answer:A)
- Atoms consist of three fundamental particles :
Electrons, protons and neutrons
- The mass of the electron is 9.10939 × 10−31 kg
- All the isotopes of a given element show same
chemical properties.
- Protons and neutrons present in the nucleus are
collectively called as nucleons.
- Dalton’s atomic theory, regarded the atom as
the ultimate particle of matter
So, the correct statements are B, C, E only

(27) The energy of an electron in the ground state

(n = 1) for He+ ion is −x J, then that for an