Worksheet Chemistry

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Bal Bharati Public School, Navi Mumbai

Class 11, 2023-24


Chemistry
Basic Principles and Techniques of Organic Chemistry

1. The IUPAC name of

(a) 2-methyl butanal (b) butan-2-aldehyde


(c) 2-ethylpropanal (d) 3-methyl isobutraldehyde

2. The bond that undergoes heterolytic cleavage most readily is


(a) C-C (b) C-O (c) C-H (d) O-H

3. The reaction

(a)carbocation formation (b) free-radical mechanism


(c) carbanion formation (d) none of these

4. Which of the following compounds will exhibit cis-trans isomerism?


(a) 2-Butene (b) 2-Butyne (c) 1-Butene (d) 2-Butanol

5. The IUPAC name of this compound is

(a) 3-Ethyl-4-chloro-1,4-pentadiene (b) 2-Chloro-3-ethyl-1,4-pentadiene


(b) 4-Chloro-3-ethyl-1-pentene (d) 3-Ethyl-4-chloro-4-pentene

6. What are hybridisation states of each carbon atom in the fol

7. lowing compounds? CH2=C=O, CH3CH=CH2, (CH3)2CO, CH2=CHCN, C6H6.

8. Write condensed and bond-line formulas for: Isopropyl alcohol, 2,3-Dimethylbutanal,


Heptan-4-one, 2, 2, 4-Trimethylpentane, 2-Hydroxy-l, 2, 3-propanetricarboxylic acid,
Hexanedial.

9. Which of the following represents the correct TUPAC name for the compounds
concerned?
(a) 2, 2-Dimethylpentane or 2-Dimethylpentane (b) 2, 4, 7-Trimethyloctane or 2, 5, 7-
Trimethyloctane (c) 2-Chloro-4-methylpentane or 4-Chloro-2-methylpentane (d) But-
3-yn- l-ol or But-4-ol-yne.

10. Draw the resonance structures for the following compounds. Show the electron shift
using curved-arrow notation.
(a) C6H5OH (b) C6H5NO2 (c) CH3CH=CHCHO (d) C6H5—CHO
(e) C6H5—CH2+ (f) CH3CH=CHCH2+

11. What are electrophiles and nucleophiles? Explain with examples.


12. Classify the following reactions:
(a) CH3CH2Br + HS– ———–> CH3CH2SH + Br–
(b) (CH3)2C=CH2 + HCl ———–> (CH3)2CCl—CH3
(c) CH3CH2Br + HO– ———–> CH2=CH2 + H2O + Br–
(d) (CH3)3C—CH2OH + HBr ———–> (CH3)2 C Br CH2CH2CH3 + H2O

13. What is the relationship between the members of following pairs of structures? Are
they structural or geometrical isomers or resonance contributors?

14. Which of the two: O2NCH2CH2O– or CH3CH2O– is expected to be more stable and
why?

15. Explain hyperconjugation effect with one example. How does hyperconjugation effect
explain the stability of alkenes ?

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