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Tetraethyl orthosilicate
CAS: 78-10-4;1109-96-2;11099-06-2
Molecular Formula: C8H20O4Si
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Polyethyl silicate-40 - Names and Identifiers View Polyethyl silicate-40 structural

formula
Name Tetraethyl orthosilicate

Synonyms TEOS
Si-28
Ethyl silicate
Ethyl silicate28
Tetraethoxysilan
zhangjiagang xinya chemical co. ，ltd
Ethylpolysilikat
Silicon ethoxide Featured Products Multiple Specifications
Tetraethoxysilane
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Ethyl Silicate 50
Teraethoxysilane Product Name: ethyl silicate
Ethyl silicate-28 Request for quotation
Ethyl Silicate 32
CAS: 78-10-4
Ethyl polysilicate
Tel: +86-0512-58980899；+86-0512-58228
ethoxy(oxo)silanol
762
diethoxy(oxo)silane
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Silane, tetraethoxy-
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Silane Coupling Agent
Mobile: +86-13915696858
Polyethyl silicate-40
QQ: 42516274
etylukrzemian(polish)
Silicon tetraethoxide Wechat: 13915696858
Ethyl Polysilicate 28 WhatsApp: 86 13915696858
ETHYL SILICATE POLYMER
Tetraethyl orthosilicate
Silicic acid, ethyl ester
tetraethyl orthosilicate-40
tetraethyl orthosilicate-28 Qianyan Chemical Technology (Wuhan) Co.,
Silane Coupling Agent Si-40 Ltd
Tetraethoxysilanemincolorlessliq
tetraethyl silicate ethyl silicate Spot supply

Ethyl silicate40(Polyethyl silicate-40)

Product Name: Tetraethyl orthosilicate
Tetraethyl Orthosilicate 〔Ethyl Silicate〕
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Tetraethoxysilaneredistilledinquartzforlowmetalimpurities
Orthosilicic acid tetraethyl ester, Tetraethoxysilane Request for quotation

CAS 78-10-4 CAS: 78-10-4

1109-96-2 Tel:
11099-06-2 Email: [email protected]
Mobile: 13247110337
EINECS 201-083-8 QQ: 2972965813

InChI InChI=1/C17H20N2O2S.Si/c1-3-20-15-9-5-13(6-10-15)18-17(22)19-14-7-11-16(12-8-14) Product List: View Catalog

21-4-2;/h5-12H,3-4H2,1-2H3,(H2,18,19,22);/q;+4

InChIKey BOTDANWDWHJENH-UHFFFAOYSA-N

Polyethyl silicate-40 - Physico-chemical Properties Suzhou Changwei Pharmaceutical Co., LTD

Multiple Specifications Spot supply

Molecular C8H20O4Si
Formula Product Name: Tetraethyl orthosilicate
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Molar Mass 208.33
CAS: 78-10-4
Density 0.933 g/mL at 20 °C(lit.) Tel: 008618931102411
Email: [email protected]
Melting Point -77 °C
Mobile: 008618931102411
Boling Point 168°C(lit.) QQ: 68367678
Wechat: 86 18931102411
Flash Point 116°F WhatsApp: 0086 189 3110 2411
Linkedin: https://www.linkedin.com/feed/
Water Solubility Hydrolysis

Solubility Soluble in ethanol and 2-propanol.

Vapor Presure <1 mm Hg ( 20 °C)

Vapor Density 7.2 (vs air)

Guangzhou Yuanda New Material Co.,Ltd
Appearance Liquid
Multiple Specifications

Specific Gravity 0.934 Product Name: Tetraethyl orthosilicate

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Color Colorless
CAS: 78-10-4
Exposure Limit ACGIH: TWA 10 ppmOSHA: TWA 100 ppm(850 mg/m3)NIOSH: IDLH 700 ppm; TWA
Tel: +86 19849939632
10 ppm(85 mg/m3)
Email: [email protected]
Merck 14,3851 Mobile: +86 19849939632
QQ: 2470479589
BRN 1422225 Wechat: +86 19849939632

Storage Store below +30°C.

Condition

Stability Stable. Flammable. Incompatible with strong oxidizing agents, water, alkalies, miner
Hefei TNJ Chemical Industry Co.,Ltd.
al acids.
Multiple Specifications
Sensitive Moisture Sensitive
Product Name: Tetraethyl orthosilicate
Explosive Limit 1.3-23%(V) Request for quotation

Refractive Index n20/D 1.382(lit.) CAS: 11099-06-2

Tel: 0086-551-65418684
Physical and Colorless flammable liquid with pungent odor.
Email: [email protected]
Chemical melting point 110 ℃
[email protected]
Properties boiling point 168.1 ℃
Mobile: 0086 189 4982 3763
freezing point -77 ℃
QQ: 2881500840
relative density 0.9356
Wechat: 0086 189 4982 3763
flash point 51.67 ℃
WhatsApp: 0086 189 4982 3763
solubility insoluble in water, soluble in ethanol, benzene-soluble.
Product List: View Catalog

Use Mainly used in optical glass, chemical resistant coatings and heat resistant coatings
and adhesives; Anti-corrosion coating modification; Crosslinking agent, binder, deh
ydrating agent; Catalyst skeleton, high purity ultrafine silica manufacturing.
Zhejiang Hangyu API Co., Ltd
Polyethyl silicate-40 - Risk and Safety
Multiple Specifications
Hazard Xn - Harmful
Symbols Product Name: Ethyl silicate
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Risk Codes R10 - Flammable CAS: 11099-06-2

R20 - Harmful by inhalation Tel: +86 19943533199
R36/37 - Irritating to eyes and respiratory system. Email: [email protected]
R36/37/38 - Irritating to eyes, respiratory system and skin. Mobile: +86 18134193529
QQ: 535948114
Safety S16 - Keep away from sources of ignition.
WhatsApp: +86 19943533199
Description S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection.
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek
medical advice.
S24/25 - Avoid contact with skin and eyes.

UN IDs UN 1292 3/PG 3 Hangzhou Verychem Science And

Technology Co.Ltd
WGK Germany 1
Product Name: Ethyl silicate
RTECS VV9450000
Request for quotation

TSCA Yes CAS: 11099-06-2

Tel: +86-571-88162785
HS Code 2920 90 70
Email: [email protected]
Hazard Class 3 Mobile: +86-13606544505
QQ: 472954302
Packing Group III Product List: View Catalog

Toxicity LD50 orally in Rabbit: 6270 mg/kg LD50 dermal Rabbit 5860 mg/kg View History

Polyethyl silicate-40
Polyethyl silicate-40 - Introduction ETHYL SILICATE POLYMER
Ethyl silicate is also known as tetraethyl silicate and tetraethoxysilane. Colorless transparent liquid
with special odor. It is stable in the presence of no water, decomposes into ethanol and silicic acid in
water, becomes turbid in humid air, and is soluble in organic solvents such as alcohol and ether.
Toxic, strong irritation to human eyes and respiratory tract. It is prepared by distillation after the
action of silicon tetrachloride and absolute ethanol. It is used to make heat-resistant and chemical-
resistant coatings and silicone solvents. It can also be used for organic synthesis, basic raw materials
for preparing advanced crystals, optical glass treatment agents, binders, insulating materials for the
electronic industry, etc.

Last Update：2023-12-21 00:21:33

Polyethyl silicate-40 - Reference Information

freezing point -77 ℃

NIST chemical information provided by: webbook.nist.gov (external link)

information

EPA chemical information provided by: ofmpeb.epa.gov (external link)

substance
information

Introduction ethyl silicate, also known as tetraethyl silicate, tetraethoxysilane. Colorless

transparent liquid, with special odor. Stable in the presence of anhydrous, water
decomposition into ethanol and silicic acid, turbid in humid air, soluble in
alcohol, ether and other organic solvents. Toxic, strong irritation to the human
eye and respiratory tract. Obtained by distillation after the action of silicon
tetrachloride and anhydrous ethanol. It is used in the preparation of heat-
resistant and chemical-resistant coatings and organic silicon solvents. It can also
be used in organic synthesis, basic raw materials for the preparation of advanced
Crystal, optical glass treatment agents, bonding agents, insulating materials for
the electronics industry, etc.

refractory ethyl silicate itself has no binding capacity, if ethyl silicate is used as a binder for
material refractory materials, must be hydrolyzed before use. The hydrolysis reaction of
principle ethyl silicate proceeds very slowly under the condition of only water, and the
hydrolysis rate is greatly accelerated once it is catalyzed by acid (H) or base
(OH-). Hydrochloric acid is generally used as a catalyst, because the use of alkali
as a catalyst will make the hydrolysis solution quickly gel and the hydrolysis Sol
lose stability, thus losing the binding ability, ethyl silicate in the acid catalyzed
hydrolysis reaction is as follows:
The hydrolysis reaction is essentially the replacement of the ethoxy group
(C2H5O-) in the ethyl silicate by the hydroxyl group (-OH) in water, resulting in
the conversion from the ethyl silicate (Si4-OC2H5) to the silanol group (Si4-OH).
Silanol groups are highly reactive and can continue to undergo acid exchange or
etherification reactions with other ethyl silicates or silanol groups.
However, the degree of hydrolysis reaction must be controlled to produce stable
ethyl silicate hydrolysate. Otherwise, as a result of the continuous reaction, the
body-type polyorganosilicon will be formed to lose stability and become an
insoluble gel, thereby losing workability. The stability of ethyl silicate hydrolysate
is mainly adjusted by the addition of acid or alkali. When the pH value is
between 1.5 and 2.5, the gel time is longer, and the hydrolysate is the most
stable, lower than or higher than this range. The hydrolysate is prone to gel, and
the pH value is between 5 and 6, The hydrolysate is the most unstable.
Therefore, the general hydrolysis liquid should be controlled between 2.0~2.5, in
order to maintain its stability, in order to maintain a certain operation time
(construction or forming time) after mixing with refractory materials. The
hydrolysis solution of ethyl silicate can be used as a binder for refractory
materials of precision casting mold, and can also be used as a binder for
products such as clay, high alumina, corundum, zircon, mullite, silicon carbide
and castables.

Application ethyl silicate (TEOS) is a colorless liquid, mainly used as heat-proof coating,
chemical-resistant coating, silane coupling agents, organic synthesis
intermediates, and precursors of chemical vapor deposition (CVD)SiO2 thin films
in the semiconductor field. Ethyl silicate has a melting point of -77 °c and a
boiling point of 165.5 °c. It is slightly soluble in water and soluble in ethanol and
ether.
The electronic industry is used as an insulating material, and is also used as an
optical glass treatment and coagulant
for precision casting, as a binder for sand mold; The metal surface treated with
ethyl silicate vapor can be anticorrosive and waterproof. Ethyl silicate can be
used to infiltrate silicon on the metal surface, and the optical glass can be
treated to improve the transmittance. The extremely fine silicon oxide powder
produced after complete hydrolysis can be used to manufacture the fluorescent
powder. Ethyl silicate is the raw material of organic silicone oil. Ethyl silicate can
also be used in the manufacture of heat-resistant, chemical-resistant coatings. In
Japan, 90% of ethyl silicate is used as a binder for anti-corrosion coatings (zinc-
rich paints).
mainly used in chemical-resistant coatings and heat-resistant coatings, organic
silicon solvents and precision adhesives. After complete hydrolysis to produce
very fine silicon oxide powder, used in the production of fluorescent powder,
can also be used as a chemical reagent.
tetraethoxysilane is mainly used for optical glass, chemical-resistant coatings,
heat-resistant coatings and adhesives; Modification of anti-corrosion coatings;
Crosslinking agent, binder, dehydrating agent; Catalyst skeleton, manufacture of
high-purity ultrafine silica
tetraethyl orthosilicate is mainly used for optical glass, chemical-resistant
coatings, heat-resistant coatings and adhesives; Modification of anti-corrosion
coatings; Crosslinking agents, binders, dehydrating agents; Catalyst framework,
fabrication of high-purity ultrafine silica.
insulating materials for electronic industry, Coatings, optical glass treatment
agents, coagulants, organic synthesis, solvents for the preparation of silicones
In the intercalation compounds forming H +-magadiite, for the study of mixed
metal bioactive glass. Commonly used as a precursor in the preparation of
xerogels

production is obtained by esterification of silicon tetrachloride and ethanol at normal

method temperature and pressure.

category flammable liquid

toxicity grade poisoning

Acute toxicity oral-rat LD50: 6270 mg/kg; Inhalation-rat LCL0: 85g/m3

stimulation data Skin-rabbits 500 mg/24 h moderate; eye-rabbit 500 mg/24 h mild

explosive explosive when mixed with air

hazard
characteristics

flammability flammable; Toxic silica fume emitted from fire scene

hazard
characteristics

storage and The warehouse is ventilated and dried at low temperature; Storage and
transportation transportation is separated from oxidant
characteristics

fire foam, dry powder, carbon dioxide, sand

extinguishing
agent

Occupational TWA 85 mg/m3; Tel 170 mg/m3

Standard

spontaneous 230°C
combustion
temperature

toxic substance information provided by: pubchem.ncbi.nlm.nih.gov (external link)

data

immediate life- 700 ppm

and health-
threatening
concentration

Last Update：2023-12-21 00:21:33

Polyethyl silicate-40 - Nature

melting point -77 °C
boiling point 168 °C(lit.)
density 0.933 g/mL at 20 °C(lit.)
vapor density 7.2 (vs air)
Vapor pressure <1mm Hg ( 20 °C)
refractive index n20/D 1.382(lit.)
flash point 116 °F
storage conditions Store below +30°C.
solubility Soluble in ethanol and 2-propanol.
morphology Liquid
Specific gravity 0.934
color Colorless
explosion limit value
1.3-23%(V)
(explosive limit)
water solubility Hydrolysis
freezing point -77℃
hydrolysis sensitivity 7: reacts slowly with moisture/water
sensitivity Moisture Sensitive
Merck 14,3851
BRN 1422225
Stable. Flammable. Incompatible with strong oxidizing agents, water,
stability
alkalies, mineral acids.
InChIKey BOTDANWDWHJENH-UHFFFAOYSA-N
NIST chemical information Silicic acid (H4sio4), tetraethyl ester(78-10-4)
EPA chemical information Tetraethyl silicate (78-10-4)

Last Update：2024-01-02 23:10:35

Polyethyl silicate-40 - Nature

colorless flammable liquid with pungent smell. Insoluble in water, soluble in ethanol, slightly soluble
in benzene.

Last Update：2024-01-02 23:10:35

Polyethyl silicate-40 - Use

1. ethyl silicate (TEOS) is a colorless liquid, which is mainly used as heat-resistant coating, chemical-
resistant coating, silane coupling agent, organic synthesis intermediate and precursor of
chemical vapor deposition (CVD)SiO2 thin film in semiconductor field. Ethyl silicate has a melting
point of -77 ℃ and a boiling point of 165.5 ℃. It is slightly soluble in water, soluble in ethanol
and ether.
2. The electronics industry is used as an insulating material, and also as an optical glass processing
and coagulant
3. Used for precision casting as a binder for sand molds; metal surfaces treated with ethyl silicate
vapor can be anticorrosive and waterproof. Ethyl silicate can be used to siliconize metal surfaces,
and processing optical glass can improve the transmittance; the extremely fine silica powder
produced after complete hydrolysis can be used to make phosphors. Ethyl silicate is the raw
material of silicone oil. Ethyl silicate can also be used to make heat-resistant and chemical-
resistant coatings. In Japan, 90% ethyl silicate is used as the base material for anti-corrosion
coatings (zinc-rich paint).
4. is mainly used for chemical-resistant coatings and heat-resistant coatings, silicone solvents and
precision binders. After complete hydrolysis, extremely fine silica powder is produced, which is
used to make phosphors and can also be used as chemical reagents.
5. tetraethoxysilane is mainly used for optical glass, chemical-resistant coatings, heat-resistant
coatings and adhesives; modification of anticorrosive coatings; crosslinking agents, binders,
dehydrating agents; catalyst skeleton, high-purity ultra-fine Silica manufacturing
6. Ethyl orthosilicate is mainly used for optical glass, chemical-resistant coatings and heat-resistant
coatings and adhesives; modification of anticorrosive coatings; crosslinking agents, binders,
dehydrating agents; catalyst skeleton, high purity The manufacture of ultra-fine silica.
7. Insulating materials for the electronics industry, coatings, optical glass treatment agents,
coagulants, organic synthesis, solvents for preparing silicone
8. In the intercalation compound forming H-magadiite, it will react with diamine to study mixed
metal bioactive glass. Commonly used as a precursor for the preparation of xerogels

Last Update：2024-01-02 23:10:35

Polyethyl silicate-40 - Security information

It is obtained by esterification of silicon tetrachloride and ethanol at
production method
room temperature and pressure.
category flammable liquid
toxicity classification Poisoning
acute toxicity oral-rat LD50: 6270 mg/kg; Inhalation-rat LCL0: 85g/m3
skin-rabbit 500 mg/24 hours moderate; Eyes-rabbit 500 mg/24 hours
Stimulus data
mild
explosive hazard
Blowable with air
characteristics
flammability hazard
Flammable; toxic silicon oxide fumes emitted from fire sites
characteristics
storage and transportation The warehouse is ventilated and dry at low temperature; it is stored
characteristics and transported separately from the oxidant
fire extinguishing agent foam, dry powder, carbon dioxide, sand
occupational standards TWA 85 mg/m3; STEL 170 mg/m3

Last Update：2024-01-02 23:10:35

Polyethyl silicate-40 - Security information

dangerous goods mark Xn
hazard category code 10-20-36/37-36/37/38
safety instructions 16-36/37/39-26-24/25
dangerous goods transport
UN 1292 3/PG 3
number
WGK Germany 1
RTECS number VV9450000
auto-ignition temperature 230 °C
TSCA Yes
customs code 2920 90 70
HazardClass 3
PackingGroup III
toxic substance data 78-10-4(Hazardous Substances Data)
LD50 orally in Rabbit: 6270 mg/kg LD50 dermal Rabbit 5860
Toxicity
mg/kg

Last Update：2024-01-02 23:10:35

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