Chem 251

mcq
1-carbohydrate contain 3 carbon atoms and the second carbon is a
carbonyl group is ..................
a)tetrose b)aldotriose
c)triulose d)ketotetrose
2-if the OH gp in last carbon atom in the carbohydrate in the right side
so it.s from ….................
A)D-family b)L-family
C)s-family d)can.t tell
3- The great majority of the sugars in humans are ….......... sugars
A)D b)L

4-
-the given compound is .....................
A)carbohydrate b)optically acitive
c)optically inactive d)none
5- Glucose is sometimes called dextrose due to it.s …..........
a)number of carbons b)structure in space
c)optical activity d) none
6-if the sugar is D-sugar so it will rotate the light to …...........
A)Right b)left
C)both d)can.t tell

by: Eslam kamal

 7-
the given compound can have .................. streoisomer
a)2 b)4
c)8 d)16

8- these compounds are ...............

a)enantiomers b)sterioisomers
c)both a and b d)epimers

9- these compounds are .......................

A)sterioisomers b)diasteriomers
c)epimers d)all of these
10-D-ribose and D-arbinose are ...................
A)epimers b)enantiomars
c)both d)none

by: Eslam kamal

 11-carbohydrates are found usually in …........... form
a)open chain b)cyclic
12-the cyclic aldoses are …............
A)acetals b)ketals
c)hemiacetals d)hemiketal
13-a-glucose has a …........... optical activity than B-glucose
a)same b)different

14- the number of asymmetric carbons in this compound

after cyclization is ................
a)3 b)4
c)5 d)6
15- the change in specific optical rotation in α-D-glucose and β-D-
glucose is …..............
A)sterioisomerism b)anomerism
b)isomarism d) mutarotation
16-when glucose dissolves in water the percent of B-glucose wll be
a)64% b)36%
c)73% d97%
17- ….................substituents sterically hinder each other if they emerge
on the same side of the ring
a)axial b)equatorial

by: Eslam kamal

 18-structures with axial substituents are ............. stable than thes with
equatorial
a)more b)less
c)same d)none

19-
(a) (b)
-the most stable structure of the following is ..................
A)a b)b
c)both have the same stability d)can.t tell
20-the chair form of glucose is ............... stable than the boat form
a)more b)less
c)same d)none
21-in haworth representation All atoms or groups located on the left
side of Fischer’s are written ..............
a)upward b)downward
22-in a Carbohydrate of L–series For α–anomer –OH group. is ........ at
anomeric carbon
a)up b)down
23-succrose is a disachride composed glucose + fructose the fructose in
sucrose is copmosed of ..................
A)6 memberd ring b)furanose form
c)pyranose form d)a and c
24-cyclic fructose is .......................
a)acetal b)ketal c)hemi acetal
d)hemiketal

by: Eslam kamal

 24-in the reaction of Formation of Glycosides the reaction occurs on
carbon .....................
A)3 b)4
c)anomeric d)enantiomeric

25)
-this reaction gives ...........................
A)monosaccride c)acetal
c)ketal d)diascchride
26-glycosides are not stable in PH.................
A)2 b)7 c)9 d)8

27) this reaction will occurs on ...............

A)anomeric carbon b)enantiomeric carbon
c)all carbons d)no rxn

28- the benzyl groups in this compund can be

removed by ..............
A)glycolysis b) hydrogenolysis
c)hydration d)none

29-................... can be used to prove that glucose exists in the pyranose

by: Eslam kamal

 (6-membered ring) form
a)glycoside formation b)hydrolysis
c) Exhaustive methylation d)hydrogenolysis
30- Carbohydrates react with............... presence of weak base to
convert all hydroxyl groups to acetate esters
a)alcohol b)acetic anhydride
c)alkyl halide d)all of these

31- the hydrolysis of this compound will

occur in ....................
a)all carbons b)anomeric carbon
c)3rd carbon d)none
32- Carbohydrates form cyclic acetals when react with ............
A)acetic anhydride b)alcohol
c)acetone d)none
33-the reaction in the previous question yield compounds called
............
a)carboacetons b)hydated carbohydrates
c)ketons d) acetonides
34- Reduction of aldose by catalytic hydrogenation (H2/Pd) gives
a)one alditol b)2 alditols
c)3alditols 4)4 alditols
35- A sugar with a a hemiacetal group have a .............. properties
a)reducing b)oxidizing
36-when a reducing sugar react with bindict reagent it gives ................
A)silver mirror ppt b)brick red ppt
blue color d)none

by: Eslam kamal

 37-the oxidation of glucose with bindict reagent gives................
A)gluconic acid b)glutaric acid
a)glycolic acid d)ketoglutaric acid
38-ketoses are converted to aldoses and react with tollen.s reagent in
.............. medium
a)acidic b)basic
c)neutral d)all
39-suppose that we have to tubes A and B and we add bromine water
to both of them A discharge the color of the bromine water while B not
so
-A can be .............
a)glucose b)fructose c)xylulose d)ribulose
-B can be
a)glucose b)ribose c)mannose d)fructose
40-........... can eact with bromine water
a)aldoses b)ketoses c)alcohols d)all
41-the oxidation of aldoses with nitric acid gives ............
A)mono carboxylic acid b)dicarboxylic acid
c)alcohol d)all
42-......... lead to the cleavege of the carbohydrate to aldehydes,
ketones or carboxylic acids
a)Br2 b)HNO2
c)HNO3 d)HIO4
43-the reaction of dihydroxy acetone with periodic acid gives ...........
A)CO2 b)formaldhyde C)a and b d)formic acid

by: Eslam kamal

 44- the reaction of this compund with periodic acid
gives.................
A)CO2 b)formaldhyde c)formic acid d)none
45-aldoses needs ......... equivilant phenyl hydrazine to form the
corresponding ozasone
a)1 b)2 c)3 d)4

46-
the type of tautomerism in this reaction is.........
a)keto enol b)imine enamine
c)both d)none
47-which of the folowing carbohydrates gives the same ozasone
a)glucose and mannose b)glucose and fructose
c)glucose and ribose d)a and b
48- Epimerization reaction occurs in .......... medium
a)acidic b)basic
c)nuetral d)none
49- The Kiliani–Fischer Synthesis for D erythrose gives
a)1 product b)2products c)3product

50-The Kiliani–Fischer Synthesis gives a mixture of ................

by: Eslam kamal

 A)enantimers b)C-1epimers
c)C-2 epimers d)C-3epimers

51- to prepare this compound from ribose we use.....

A)CN-/HCL b)Br2 c)Br2+H2O+Fe2(SO4)3 +H2O2
52-in maltose the bond between the to sugar units is .........
a)hydrogen b) α-1,4`-glycosidic bomd
c)B-1,4`-glycosidicbond d)none
53-lactose composed of .................
A)D-glucose+D-galactose b)D-glucose+Lglactose
c)l-glucose+l-galactose d)D-glucose+D-lactose
54-the suger units which form sucrose are all of thes except…..........
A)reducing sugars
b)bind together by glycocydic bonds
C)both from D series
d)both from L series
55-the amount of amylose in starch is …......
A)20% b)30%
C)70% d)80%
56- Formation of glycogen from glucose is called.............
A) glycogenesis b) glycogenolysis
a)hydrogenolyses d)hydrogenation

by: Eslam kamal

 A)maltose b)succrose c)fructose

d)cellulose e)glycogen f)octulose

j)glucaric acid h) i)aldooctose

j)mannose

1-a sugar contain a and B glycosydic linkage

2-a ketose contain 8 carbons
3-a sugar gives the same ozasone like glucose
4-represent haowarth represntation
5- disacchride composed of 2 glucose units
6-resulted from the reaction of glucose with nitric acid
7-is a component of sucrose
8-non digestable sugar
9-major carbohydrate storage in human

by: Eslam kamal

 Chem 251
mcq
1-carbohydrate contain 3 carbon atoms and the second carbon is a
carbonyl group is ..................
a)tetrose b)aldotriose
c)triulose d)ketotetrose
2-if the OH gp in last carbon atom in the carbohydrate in the right side
so it.s from ….................
A)D-family b)L-family
C)s-family d)can.t tell
3- The great majority of the sugars in humans are ….......... sugars
A)D b)L

4-
-the given compound is .....................
A)carbohydrate b)optically acitive
c)optically inactive d)none
5- Glucose is sometimes called dextrose due to it.s …..........
a)number of carbons b)structure in space
c)optical activity d) none
6-if the sugar is D-sugar so it will rotate the light to …...........
A)Right b)left
C)both d)can.t tell

by: Eslam kamal

 7-
the given compound can have .................. streoisomer
a)2 b)4
c)8 d)16

8- these compounds are ...............

a)enantiomers b)sterioisomers
c)both a and b d)epimers

9- these compounds are .......................

A)sterioisomers b)diasteriomers
c)epimers d)all of these
10-D-ribose and D-arbinose are ...................
A)epimers b)enantiomars
c)both d)none

by: Eslam kamal

 11-carbohydrates are found usually in …........... form
a)open chain b)cyclic
12-the cyclic aldoses are …............
A)acetals b)ketals
c)hemiacetals d)hemiketal
13-a-glucose has a …........... optical activity than B-glucose
a)same b)different

14- the number of asymmetric carbons in this compound

after cyclization is ................
a)3 b)4
c)5 d)6
15- the change in specific optical rotation in α-D-glucose and β-D-
glucose is …..............
A)sterioisomerism b)anomerism
b)isomarism d) mutarotation
16-when glucose dissolves in water the percent of B-glucose wll be
a)64% b)36%
c)73% d97%
17- ….................substituents sterically hinder each other if they emerge
on the same side of the ring
a)axial b)equatorial

by: Eslam kamal

 18-structures with axial substituents are ............. stable than thes with
equatorial
a)more b)less
c)same d)none

19-
(a) (b)
-the most stable structure of the following is ..................
A)a b)b
c)both have the same stability d)can.t tell
20-the chair form of glucose is ............... stable than the boat form
a)more b)less
c)same d)none
21-in haworth representation All atoms or groups located on the left
side of Fischer’s are written ..............
a)upward b)downward
22-in a Carbohydrate of L–series For α–anomer –OH group. is ........ at
anomeric carbon
a)up b)down
23-succrose is a disachride composed glucose + fructose the fructose in
sucrose is copmosed of ..................
A)6 memberd ring b)furanose form
c)pyranose form d)a and c
24-cyclic fructose is .......................
a)acetal b)ketal c)hemi acetal
d)hemiketal

by: Eslam kamal

 24-in the reaction of Formation of Glycosides the reaction occurs on
carbon .....................
A)3 b)4
c)anomeric d)enantiomeric

25)
-this reaction gives ...........................
A)monosaccride c)acetal
c)ketal d)diascchride
26-glycosides are not stable in PH.................
A)2 b)7 c)9 d)8

27) this reaction will occurs on ...............

A)anomeric carbon b)enantiomeric carbon
c)all carbons d)no rxn

28- the benzyl groups in this compund can be

removed by ..............
A)glycolysis b) hydrogenolysis
c)hydration d)none

29-................... can be used to prove that glucose exists in the pyranose

by: Eslam kamal

 (6-membered ring) form
a)glycoside formation b)hydrolysis
c) Exhaustive methylation d)hydrogenolysis
30- Carbohydrates react with............... presence of weak base to
convert all hydroxyl groups to acetate esters
a)alcohol b)acetic anhydride
c)alkyl halide d)all of these

31- the hydrolysis of this compound will

occur in ....................
a)all carbons b)anomeric carbon
c)3rd carbon d)none
32- Carbohydrates form cyclic acetals when react with ............
A)acetic anhydride b)alcohol
c)acetone d)none
33-the reaction in the previous question yield compounds called
............
a)carboacetons b)hydated carbohydrates
c)ketons d) acetonides
34- Reduction of aldose by catalytic hydrogenation (H2/Pd) gives
a)one alditol b)2 alditols
c)3alditols 4)4 alditols
35- A sugar with a a hemiacetal group have a .............. properties
a)reducing b)oxidizing
36-when a reducing sugar react with bindict reagent it gives ................
A)silver mirror ppt b)brick red ppt
blue color d)none

by: Eslam kamal

 37-the oxidation of glucose with bindict reagent gives................
A)gluconic acid b)glutaric acid
a)glycolic acid d)ketoglutaric acid
38-ketoses are converted to aldoses and react with tollen.s reagent in
.............. medium
a)acidic b)basic
c)neutral d)all
39-suppose that we have to tubes A and B and we add bromine water
to both of them A discharge the color of the bromine water while B not
so
-A can be .............
a)glucose b)fructose c)xylulose d)ribulose
-B can be
a)glucose b)ribose c)mannose d)fructose
40-........... can eact with bromine water
a)aldoses b)ketoses c)alcohols d)all
41-the oxidation of aldoses with nitric acid gives ............
A)mono carboxylic acid b)dicarboxylic acid
c)alcohol d)all
42-......... lead to the cleavege of the carbohydrate to aldehydes,
ketones or carboxylic acids
a)Br2 b)HNO2
c)HNO3 d)HIO4
43-the reaction of dihydroxy acetone with periodic acid gives ...........
A)CO2 b)formaldhyde C)a and b d)formic acid

by: Eslam kamal

 44- the reaction of this compund with periodic acid
gives.................
A)CO2 b)formaldhyde c)formic acid d)none
45-aldoses needs ......... equivilant phenyl hydrazine to form the
corresponding ozasone
a)1 b)2 c)3 d)4

46-
the type of tautomerism in this reaction is.........
a)keto enol b)imine enamine
c)both d)none
47-which of the folowing carbohydrates gives the same ozasone
a)glucose and mannose b)glucose and fructose
c)glucose and ribose d)a and b
48- Epimerization reaction occurs in .......... medium
a)acidic b)basic
c)nuetral d)none
49- The Kiliani–Fischer Synthesis for D erythrose gives
a)1 product b)2products c)3product

50-The Kiliani–Fischer Synthesis gives a mixture of ................

by: Eslam kamal

 A)enantimers b)C-1epimers
c)C-2 epimers d)C-3epimers

51- to prepare this compound from ribose we use.....

A)CN-/HCL b)Br2 c)Br2+H2O+Fe2(SO4)3 +H2O2
52-in maltose the bond between the to sugar units is .........
a)hydrogen b) α-1,4`-glycosidic bomd
c)B-1,4`-glycosidicbond d)none
53-lactose composed of .................
A)D-glucose+D-galactose b)D-glucose+Lglactose
c)l-glucose+l-galactose d)D-glucose+D-lactose
54-the suger units which form sucrose are all of thes except…..........
A)reducing sugars
b)bind together by glycocydic bonds
C)both from D series
d)both from L series
55-the amount of amylose in starch is …......
A)20% b)30%
C)70% d)80%
56- Formation of glycogen from glucose is called.............
A) glycogenesis b) glycogenolysis
a)hydrogenolyses d)hydrogenation

by: Eslam kamal

 A)maltose b)succrose c)fructose

d)cellulose e)glycogen f)octulose

j)glucaric acid h) i)aldooctose

j)mannose

1-a sugar contain a and B glycosydic linkage::::b

2-a ketose contain 8 carbons::::::::f
3-a sugar gives the same ozasone like glucose:::::::j
4-represent haowarth represntation:::::::::::h
5- disacchride composed of 2 glucose units :::::::a
6-resulted from the reaction of glucose with nitric acid::::::::j
7-is a component of sucrose::::::::::c
8-non digestable sugar:::::::d
9-major carbohydrate storage in human::::::::e

by: Eslam kamal