Emission Mechanism

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EMISSION MECHANISM

The photons of a light beam have a characteristic energy, called photon energy, which
is proportional to the frequency of the light. In the photoemission process, when an
electron within some material absorbs the energy of a photon and acquires more energy
than its binding energy, it is likely to be ejected. If the photon energy is too low, the
electron is unable to escape the material. Since an increase in the intensity of low-
frequency light will only increase the number of low-energy photons, this change in
intensity will not create any single photon with enough energy to dislodge an electron.
Moreover, the energy of the emitted electrons will not depend on the intensity of the
incoming light of a given frequency, but only on the energy of the individual photons. [4]

While free electrons can absorb any energy when irradiated as long as this is followed
by an immediate re-emission, like in the Compton effect, in quantum systems all of the
energy from one photon is absorbed—if the process is allowed by quantum mechanics
—or none at all. Part of the acquired energy is used to liberate the electron from its
atomic binding, and the rest contributes to the electron's kinetic energy as a free
particle Because electrons in a material occupy many different quantum states with
different binding energies, and because they can sustain energy losses on their way out
of the material, the emitted electrons will have a range of kinetic energies. The electrons
from the highest occupied states will have the highest kinetic energy. In metals, those
electrons will be emitted from the Fermi level.

When the photoelectron is emitted into a solid rather than into a vacuum, the
term internal photoemission is often used, and emission into a vacuum is distinguished
as external photoemission.

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