Safety Data Sheet

MAPEFER 1K ZERO
Safety Data Sheet dated: 16/02/2024 - version 1

1. Identification
GHS Product Identifier
Mixture identification:
Trade name: MAPEFER 1K ZERO
Trade code: 9027662
Recommended use of the chemical and restrictions on use
Recommended use: Ready prepared cement mortar
Uses advised against: N.A.
Supplier's details
Company: MAPEI CONSTRUCTION CHEMICALS L.L.C
P.O. BOX 73869 DUBAI - United Arab Emirates
Office: 00971 4 8156666
Factory : 00971 4 8858428
Responsable: [email protected]
Emergency phone number
Office: 00971 4 8156666

2. Hazard identification
Classification of the substance or mixture

Skin irritation, Category 2 Causes skin irritation.

Serious eye damage, Category 1 Causes serious eye damage.
Skin Sensitisation, Category 1B May cause an allergic skin reaction.
Specific target organ toxicity — single exposure, Category 3 May cause respiratory irritation.
Acute aquatic hazard, category 3 Harmful to aquatic life
Adverse physicochemical, human health and environmental effects:
No other hazards
GHS label elements, including precautionary statements
Hazard pictograms and Signal Word

Danger

Hazard statements
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H335 May cause respiratory irritation.
H402 Harmful to aquatic life

Precautionary statements
P261 Avoid breathing dust.
P264 Wash hands thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves/clothing and eye/face protection.
P302+P352 IF ON SKIN: Wash with plenty of water.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P33 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy
8 to do. Continue rinsing.

P312 Call a POISON CENTER if you feel unwell.

P333+P313 If skin irritation or rash occurs: Get medical advice/attention.
P362 Take off contaminated clothing.
P501 Dispose of contents/container in accordance with applicable regulations.

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Other hazards which do not result in a classification
No other hazards

Prolonged exposition and/or intensive inhalation of respirable free crystalline silica (average diameter less than 10 micron in accordance with
ACGIH) can cause pulmonary fibrosis commonly referred to as silicosis.
This preparation contains cement. Contact between cement and body fluids (e.g. sweat and eye fluids) may cause irritation or burns.

3. Composition/information on ingredients
Substances
Not Relevant
Mixtures
Mixture identification: MAPEFER 1K ZERO

Hazardous components within the meaning of GHS and related classification:

Qty Name Ident. Numb. Classification Registration Number
≥50 - <75 portland cement, Cr(VI) < 2 ppm CAS:65997-15-1 Skin Irrit. 2, H315; Skin Sens. 1B,
% EC:266-043-4 H317; Eye Dam. 1, H318; STOT
SE 3, H335

4. First-aid measures
Description of necessary first-aid measures
In case of skin contact:
Immediately take off all contaminated clothing.
OBTAIN IMMEDIATE MEDICAL ATTENTION.
Remove contaminated clothing immediately and dispose of safely.
After contact with skin, wash immediately with soap and plenty of water.
In case of eyes contact:
After contact with the eyes, rinse with water with the eyelids open for a sufficient length of time, then consult an opthalmologist
immediately.
Protect uninjured eye.
In case of Ingestion:
Do not induce vomiting, get medical attention showing the SDS and the hazard label.
In case of Inhalation:
In case of inhalation, consult a doctor immediately and show him packing or label.
Most important symptoms/effects, acute and delayed
Eye irritation
Eye damages
Skin Irritation
Erythema
Indication of immediate medical attention and special treatment needed, if necessary
In case of accident or unwellness, seek medical advice immediately (show directions for use or safety data sheet if possible).
Treatment:
(see paragraph 4.1)

5. Fire-fighting measures
Extinguishing media
Suitable extinguishing media:
Water.
Carbon dioxide (CO2).
Unsuitable extinguishing media:
None in particular.
Special hazards arising from the chemical
Do not inhale explosion and combustion gases.
Burning produces heavy smoke.
Hazardous combustion products: N.A.
Explosive properties: ==
Oxidizing properties: N.A.
Special protective actions for fire-fighters
Use suitable breathing apparatus.
Collect contaminated fire extinguishing water separately. This must not be discharged into drains.
Move undamaged containers from immediate hazard area if it can be done safely.

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6. Accidental release measures
Personal precautions, protective equipment and emergency procedures
Wear personal protection equipment.
Wear breathing apparatus if exposed to vapours/dusts/aerosols.
Provide adequate ventilation.
Use appropriate respiratory protection.
Environmental precautions
Do not allow to enter into soil/subsoil. Do not allow to enter into surface water or drains.
Methods and material for containment and cleaning up
Take up mechanically and dispose of according to local/state/federal regulations
Scoop into containers and seal for disposal.
Retain contaminated washing water and dispose it.

7. Handling and storage

Precautions for safe handling
Avoid contact with skin and eyes, inhalation of vapours and mists.
Do not use on extensive surface areas in premises where there are occupants.
Use localized ventilation system.
Don't use empty container before they have been cleaned.
Before making transfer operations, assure that there aren't any incompatible material residuals in the containers.
Contaminated clothing should be changed before entering eating areas.
Do not eat or drink while working.
See also section 8 for recommended protective equipment.
Conditions for safe storage, including any incompatibilities
Keep away from food, drink and feed.
Incompatible materials:
None in particular.
Instructions as regards storage premises:
Adequately ventilated premises.

8. Exposure controls/personal protection

Control parameters

Community Occupational Exposure Limits (OEL)

OEL Country Occupational Exposure Limit
Type
portland cement, Cr(VI) < 2 COL COLOMBIA Long Term: 1 mg/m3
ppm
CAS: 65997-15-1

IND INDIA Long Term: 10 mg/m3

A4 - Not Classifiable as a Human Carcinogen;pulmonary function;respiratory
symptoms;asthma

IDN INDONESIA Long Term: 10 mg/m3; Short Term: 30 mg/m3

5 mg/m3 TWA (containing <1% of free Silica, respirable dust);10 mg/m3 TWA
(containing <1% of free Silica, total dust)

IDN INDONESIA Long Term: 10 mg/m3

10 mg/m3 PEL

IDN INDONESIA Long Term: 10 mg/m3

MEX MEXICO Long Term: 1 mg/m3; Short Term: 30 mg/m3
PAN PANAMA Long Term: 5 mg/m3; Short Term: 30 mg/m3
10 mg/m3 PEL

PAN PANAMA Long Term: 10 mg/m3; Short Term: 10 mg/m3

PAN PANAMA Long Term: 5 mg/m3; Short Term: 10 mg/m3
PAN PANAMA Long Term: 10 mg/m3; Short Term: 20 mg/m3
PER PERU Long Term: 10 mg/m3
ZAF SOUTH Long Term: 10 mg/m3
AFRICA

ZAF SOUTH Long Term: 5 mg/m3

AFRICA

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 ARE UNITED Long Term: 10 mg/m3
ARAB A4 - Not Classifiable as a Human Carcinogen;pulmonary function;respiratory
EMIRATES symptoms;asthma

ARE UNITED Long Term: 10 mg/m3

ARAB
EMIRATES

Appropriate engineering controls: N.A.

Individual protection measures, such as personal protective equipment (PPE)
Eye protection:
Use close fitting safety goggles, don't use eye lens.
Protection for skin:
Use clothing that provides comprehensive protection to the skin, e.g. cotton, rubber, PVC or viton.
Protection for hands:
Suitable materials for safety gloves; EN ISO 374:
Polychloroprene - CR: thickness >=0,5mm; breakthrough time >=480min.
Nitrile rubber - NBR: thickness >=0,35mm; breakthrough time >=480min.
Butyl rubber - IIR: thickness >=0,5mm; breakthrough time >=480min.
Fluorinated rubber - FKM: thickness >=0,4mm; breakthrough time >=480min.
Nitrile gloves are suggested (1,3 mm; 480 min). Not recommended gloves: not waterproof gloves
Use protective gloves that provides comprehensive protection, e.g. P.V.C., neoprene or rubber.
Respiratory protection:
Personal Protective Equipment should comply with relevant CE standards (as EN ISO 374 for gloves and EN ISO 166 for goggles),
correctly maintained and stored. Consult the supplier to check the suitability of equipment against specific chemicals and for user
information.
A dust mask (P2) should be worn if above exposure limits (EN 149)
Use respiratory protection where ventilation is insufficient or exposure is prolonged.

9. Physical and chemical properties

Physical state Solid
Color: Blue
Appearance: powder
Odour: cement like
Odour threshold: N.A.
pH: N.A.
pH (water dispersion, 10%): 12.50
Melting point / freezing point: N.A.
Initial boiling point and boiling range: N.A.
Flash point: N.A.
Evaporation rate: N.A.
Solid/gas flammability: N.A.
Upper/lower flammability or explosive limits: N.A.
Vapour pressure: N.A.
Vapour density: N.A.
Relative density: N.A.
Solubility in water: partly soluble
Solubility in oil: insoluble
Partition coefficient (n-octanol/water): N.A.
Auto-ignition temperature: N.A.
Decomposition temperature: N.A.
Viscosity: N.A.

10. Stability and reactivity

Reactivity
Stable under normal conditions
Chemical stability
Data not available.
Possibility of hazardous reactions
None.
Conditions to avoid
Stable under normal conditions.
Incompatible materials
None in particular.
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 None in particular.
Hazardous decomposition products
None.

11. Toxicological information

Information on toxicological effects
Contains cement. Cement gives a strong alkaline reaction with water and body fluids (e.g. sweat and eye fluids), therefore the
contact with skin and eyes should be carefully avoided.

Toxicological Information of the Preparation

a) acute toxicity Not classified
Based on available data, the classification criteria are not met
b) skin corrosion/irritation The product is classified: Skin irritation, Category 2(H315)
c) serious eye damage/irritation The product is classified: Serious eye damage, Category 1(H318)
d) respiratory or skin sensitisation The product is classified: Skin Sensitisation, Category 1B(H317)
e) germ cell mutagenicity Not classified
Based on available data, the classification criteria are not met
f) carcinogenicity Not classified
Based on available data, the classification criteria are not met
g) reproductive toxicity Not classified
Based on available data, the classification criteria are not met
h) STOT-single exposure The product is classified: Specific target organ toxicity — single exposure, Category
3(H335)

i) STOT-repeated exposure Not classified

Based on available data, the classification criteria are not met
j) aspiration hazard Not classified
Based on available data, the classification criteria are not met

12. Ecological information

Toxicity
Adopt good working practices, so that the product is not released into the environment.
Eco-Toxicological Information:

List of Eco-Toxicological properties of the product

The product is classified: Acute aquatic hazard, category 3(H402)
Persistence and degradability

N.A.
Bioaccumulative potential

N.A.
Mobility in soil

N.A.
Other adverse effects

No Data found about other evironmental hazard properties.

13. Disposal considerations

Disposal methods
The generation of waste should be avoided or minimized wherever possible. Recover if possible.
Methods of disposal:
Disposal of this product, solutions, packaging and any by-products should at all times comply with the requirements of
environmental protection and waste disposal legislation and any regional local authority requirements.
Dispose of surplus and nonrecyclable products via a licensed waste disposal contractor.
Do not dispose of waste into sewers.
Disposal considerations:
Do not allow to enter drains or watercourses.
Dispose of product according to all federal, state and local applicable regulations.
If this product is mixed with other wastes, the original waste product code may no longer apply and the appropriate code should be
assigned.
Dispose of containers contaminated by the product in accordance with local or national legal provisions. For further information,
Print datecontact your local waste authority.
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 Dispose of containers contaminated by the product in accordance with local or national legal provisions. For further information,
contact your local waste authority.
Special precautions:
This material and its container must be disposed of in a safe way. Care should be taken when handling untreated empty containers.
Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.
Empty containers or liners may retain some product residues. Do not re-use empty containers.

14. Transport information

Not classified as dangerous in the meaning of transport regulations.
UN number
N.A.
UN proper shipping name
N.A.
Transport hazard class(es)
N.A.
Packing group, if applicable
Road and Rail (ADR-RID):
N.A.
ADR-Hazard identification number: NA
Air (IATA):
N.A.
Sea (IMDG):
N.A.
Environmental hazards
Marine pollutant: No
Environmental Pollutant: N.A.
Special precautions for user
N.A.
Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
N.A.

15. Regulatory information

Safety, health and environmental regulations specific for the product in question
This Safety Data Sheet has been prepared according to the Globally Harmonized System of Classification and Labelling of Chemicals (GHS),
Fifth revised edition.
SCAQMD Rule 1113 : 0
SCAQMD Rule 1168: N.A.

16. Other information

Code Description
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H318 Causes serious eye damage.
H335 May cause respiratory irritation.

Code Hazard class and hazard category Description

3.2/2 Skin Irrit. 2 Skin irritation, Category 2
3.3/1 Eye Dam. 1 Serious eye damage, Category 1
3.4.2/1B Skin Sens. 1B Skin Sensitisation, Category 1B
3.8/3 STOT SE 3 Specific target organ toxicity — single exposure, Category 3
This document was prepared by a competent person who has received appropriate training.
Main bibliographic sources:
ECDIN - Environmental Chemicals Data and Information Network - Joint Research Centre, Commission of the European
Communities
SAX's DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS - Eight Edition - Van Nostrand Reinold
Insert here further consulted bibliography
The information contained herein is based on our state of knowledge at the above-specified date. It refers solely to the product indicated and
constitutes no guarantee of particular quality.
It is the duty of the user to ensure that this information is appropriate and complete with respect to the specific use intended.
This SDS cancels and replaces any preceding release.
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This SDS cancels and replaces any preceding release.
Legend to abbreviations and acronyms used in the safety data sheet:
ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road.
RID: Regulation Concerning the International Transport of Dangerous Goods by Rail.
IMDG: International Maritime Code for Dangerous Goods.
IATA: International Air Transport Association.
IATA-DGR: Dangerous Goods Regulation by the "International Air Transport Association" (IATA).
ICAO: International Civil Aviation Organization.
ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO).
GHS: Globally Harmonized System of Classification and Labeling of Chemicals.
CLP: Classification, Labeling, Packaging.
EINECS: European Inventory of Existing Commercial Chemical Substances.
INCI: International Nomenclature of Cosmetic Ingredients.
CAS: Chemical Abstracts Service (division of the American Chemical Society).
GefStoffVO: Ordinance on Hazardous Substances, Germany.
LC50: Lethal concentration, for 50 percent of test population.
LD50: Lethal dose, for 50 percent of test population.
DNEL: Derived No Effect Level.
PNEC: Predicted No Effect Concentration.
TLV: Threshold Limiting Value.
TWATLV: Threshold Limit Value for the Time Weighted Average 8 hour day. (ACGIH Standard).
STEL: Short Term Exposure limit.
STOT: Specific Target Organ Toxicity.
WGK: German Water Hazard Class.
KSt: Explosion coefficient.

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