12.miscellaneous Question

CARBON AND ITS COMPOUNDS
CLASS WORKSHEET-12 SIKANDAR

GURJAR
X Topic –Miscellaneous Questions (PGT CHMEISTRY)
Tutorial – XII Last Date
S.No Questions YEAR

Miscellaneous
01. A compound X is formed by the reaction of a carboxylic acid C2H4O2 and
an alcohol in presence of a few drops of H2SO4. The alcohol on oxidation
with alkaline KMnO4 followed by acidification gives the same carboxylic
acid as used in this reaction. Give the name and structures of
(a) Carboxylic acid
(b) Alcohol and
(c) The compound X.
Also write the reaction.
02. Electrolysis
1. A + H2O → X(caustic soda) + Y↑(Anode) + 2025
.
Z↑(Cathode) SP
Electrolysis
2. A(Molten) → M(Cathode) + Y↑(Anode)
.
3. M + CH3COOH --→ P + Z↑
Conc.
4. CH3COOH + Q H2SO4→ R
5. R + X ----→ P + Q
a) Derive the name of A, Y, Z, M, P and R

b) Improvise an activity to test Z.
c) Name the process in which compounds X, Y and Z are formed from
A. Justify your response.
03. The table given below shows the hints given by the quiz master in a quiz. 2024
S.No HINT SP
(i) Substance
B ‘C’ is used as a preservative.
(ii) ‘C’ has two carbon atoms, ‘C’ is obtained by the reaction of ‘A’
in presence of alkaline Potassium Permanganate followed by
acidification
(iii) Misuse of ‘A’ in industries is prevented by adding Methanol,
Benzene and Pyridine to ‘A’.
(iv) ‘F’ is formed on heating ‘A’ in presence of Conc. Sulphuric
acid.
1
(v) ‘F’ reacts with Hydrogen gas in presence of Nickel and
Palladium catalyst.
Based on the above hint answer the following questions .
a) Give the IUPAC names of A and F.
b) Illustrate with the help of chemical equation the changes taking place.
(A →C and A →F)
c) Name the chemical reaction which occurs in step 2 and 5. Idnetify
their compounds formed in the steps if ‘A’ is replaced with its next
homologue.
04. What is the role of metal or reagents written on arrows in the given chemical
reactions ?
a) (CH3)2 C = C(CH3)2 + H2 Ni → (CH3)2CH – CH(CH3)2
b) CH3COOH + CH3CH2OH Conc.H2SO4→ CH3 COOC2H5 + H2O
c) CH3CH2OH Alk.KMnO4(Heat)→ CH3COOH
05. Match the reaction given in column (A) with the names given in column
(B).
S.No Column A Column B
01. CH3OH + CH3COOH 𝐻+
→ CH3COOCH3 + H2O Addition Reaction
.
02. CH2 = CH2 + H2 𝑁𝑖 → CH3 CH3 Substition Reaction
.
03. CH4 + Cl2 𝑠𝑢𝑛𝑙𝑖𝑔ℎ𝑡→ CH3Cl + HCl Neutralisation Reactinn
.
04. CH3COOH + NaOH --→ CH3COONa + H2O Esterification Reacton
06. An Organic Compound A on heating with concentrated H2SO4 forms a
compound B which on addition of one mole of hydrogen in presence of Ni
forms a compound C. One mole of compound C on combustion forms two
moles of CO2 and 3 moles of H2O. Identify the compounds A, B and C and
write the chemical equations of the reaction involved.
07. Carry out the following conversions, stating the condition(s) for each : 2023
(i) Ethanol → Ethene
(ii) Ethene → Ethane
(iii) Ethnae → Chloroethane
(iv) Ethanol → Ethanoic acid
Ethanoic acid → Ethyl Ethanoate
08. Write chemical equation for the following reactions, giving the conditions 2024
for the reaction in each case :
a) Reaction of ethanol with ethanoic acid .
b) Reaction of an ester with a base(NaOH)
c) Formation of ethene from ethanol.
2
09. Carry out the following conversions giving complete conditions for the 2019
reactions to take place in each case :
(i) Ethanoic acid from Ethanol
(ii) Ethane from Ethene
(iii) Ester from Ethanoic acid and ethanol
Also state the names given to all the above conversion.
10. The forumula of the following compounds are given below : 2020
A - C2H4 SP
B - CH3COOH
C - C2H5OH
D - C2H6/ ?
(i) Which of these compounds A, B, C or D is a saturated hydrocarbon
?
(ii) Identify the organic acid and give its structural formula.
(iii) Which of the above compounds when heated at 443 K in the
presence of concentrated H2SO4 forms ethene as the major product
? What is the role played by concentrated H2SO4 in this reaction ?
Also write the chemical equation involved.
(iv) Give a chemical equation when B and C react with each other in
presence of concentrated H2SO4. Name the major product formed
and mention one of its important uses.
11. What happens when (Write chemical equation of the reaction) 2017
i) A piece of sodium metal is added to water. SP
ii) Ethanoic acid reacts with sodium hydroxide.
12. Complete the following reactions stating the main product formed in each 2011
case. ,
Ni−Catalyst
a) CH3 - CH = CH2 + H2 → 2013
.
b) C2H5OH + Na →
c) CH3 COOH + Na2CO3 →
13. Complete the following reactions : 2013
Cocn.H2SO4
a) CH3 COOH → 2012
𝐻𝑒𝑎𝑡
b) CH3COOH + NaHCO3 SP
c) CH4 + Cl2 → 2011
d) CH2 = CH2 H2 →
𝐴𝑙𝑘.𝐾𝑀𝑛𝑂4
e) C2H5OH + O2
14. Account for the following statement 2015
a) Ethane is a covalent bond.
b) Carbon atoms forms a storng bond.
3
c) Carbon shows catenation property.
d) Pentane has higher boiling point than butane.
e) Alkenes have double bond.
SIKANDAR GURJAR
(PGT CHEMISTRY )
7974314040

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CARBON AND ITS COMPOUNDS

CLASS WORKSHEET-12 SIKANDAR

S.No Questions YEAR

a) Derive the name of A, Y, Z, M, P and R

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