THE BODHI ACADEMY

GCET
2022-2023
Chemistry

Contact: 9028150028 / 7028071514

Address: 103, Gera Imperium Green Building, Near
Jairam Complex, Neugi Nagar, Mala Panjim Goa
 GCET SET-I
CHEMISTRY
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1. In an FCC unit cell, an atom located on any of the faces of the unit cell contributes:

(A) half an atom per unit cell

(B) one atom per unit cell
(C) one fourth atom per unit cell
(D) one eighth atom per unit cell

2. In amorphous solids, there is/are:

(A) irregular shapes
(B) sharp melting points
(C) long range order

M Y
E
(D) anisotropy

3. The packing efficiency in a close packed body centered cubic unit cell is:

A D
C
(A) 74 percent
(B) 68 percent
(C) 52 percent
(D) 33 per cent
I A
D H
4. In a ferrimagnetic material, on applying a magnetic field, the magnetic moments of
the domains:

B O
(A) are randomly oriented
(B) are oppositely oriented and cancel out each other

H E
(C) are aligned in parallel and antiparallel directions in unequal numbers
(D) are parallel to one another

T
5. In a hexagonal close pack, the first three layers of atoms are placed in such a way that,
the atoms of the third layer

(A) cover the octahedral and tetrahedral voids created by the first two layers.
(B) cover the tetrahedral voids created by the first two layers.
(C) cover the octahedral voids created by the first two layers.
(D) are directly above the atoms of the second layer.

6. In a crystal of group 14 elements, n-type semiconductivity can be introduced by replacing

some atoms by other atoms of the group:
(A) 12
(B) 13
(C) 15
(D) 14
7. The order of packing efficiency in fcc, bcc and simple cubic unit cells is:
(A) bcc > simple cubic > fcc
(B) fcc > simple cubic > bcc
(C) bcc > fcc > simple cubic
(D) fcc >bcc > simple cubic

8. In ZnS crystal the defect is defined as:

(A) Schottky defect
(B) Frenkel defect
(C) Metal excess defect
(D) Impurity defect

9. For obtaining a p - t type semiconductor, Germanium has to be doped with

(A) Si
(B) As
M Y
(C) Al
(D) Both As and Al

D E
10. Which of the statements is TRUE for interstitial compounds?

C A
(A) They have a higher melting point than that of pure metals

(C) They are chemically inert

I A
(B) They have a lower melting point than that of pure metals

H
(D) both (A) and (C )

11. F-centres in a crystal are

(A) Frenkel defects

O
(B) Interstitial defects
D
B
(C) Anionic sites occupied by unpaired electrons

H E
(D) Schottky defects

12. The number of octahedral voids in a cubic closed packed structure is

T (A) 8
(B) 4
(C) 6
(D) 1

13 .An element has a body-centered cubic structure with a cell edge of 300 pm. The density
of the element is 4.0 g cm³. The number of atoms present in 108 g of the element are
(A) 2.0 × 1024
(B) 1.0 x 1024
(C) 2.5 x 1024
(D) 1.5 x 1024
14.Amorphous solids

(A) are anisotropic and have only short range order

(B) are isotropic and have only short range order
(C) are anisotropic and have long range
(D) are isotropic and have long range order

15.SiO2, is
(A) a covalent solid
(B) an ionic solid
(C) a metallic solid
(D) a molecular solid

16.A primitive unit cell has

(A) 4 atoms per unit cell
(B) 3 atoms per unit cell
M Y
(C) 2 atoms per unit cell
(D) 1 atom per unit cell

D E
A
17.In square close packing in two dimensions, each sphere is in contact with

C
(A) 6 of its neighbours
(B) 3 of its neighbours

I A
H
(C) 4 of its neighbours
(D) 2 of its neighbours

O D
18. In a BCC unit cell, the length of a side a is related to the diameter of the spheres
(atoms) d by

B
E
(A) (1/√2)d

H
T
(B) (√3/2)d

(C) (2 /√3)d

(D) (√2/3)d

19. In an NaCl crystal, a sodium ion is substituted by a strontium ion. This leads to the
formation of

(A) a stoichiometric defect

(B) a Frenkel defect
(C) a Schottky defect
(D) an impurity defect

20. In an insulator, the empty conduction band

 (A) lies a little above the valence band
(B) lies far above the valence band
(C) overlaps with the valence band
(D) lies a little below the valence band

21.In allylic and vinyl alcohols, the - OH groups are attached to:

(A) sp³ hybridized carbon atoms in both cases

(B) sp² hybridized carbon atoms in both cases
(C) sp² hybridized carbon in allylic and sp³ hybridized carbon in vinyl
(D) sp³ hybridized carbon in allylic and sp² hybridized carbon in vinyl

22.Among the following,

(i) C(H)(OH)(CH3)(Br)
M Y
(ii) C(H)(OH)(CH3)CH2CH2CH3
(iii) CH3CH2C(H)(OH)CH2CH3

D E
A
(iv) CH3C(H)(Br)(CH3)

two molecules that are NOT optically active are:

(A) (i) and (ii)

A C
(B) (ii) and (iv)
(C) (iii) and (iv)
(D) (i) and (iv)
H I
O D
23.The final product P formed in the following reaction is

B
C6H5NH2 + NaNO2 + 2HCl (at 273-278 K) →X + NaCl + H₂O;

H E
X + KI → P+N2 + KCl is

T (A) Iodobenzene
(B) Phenol
(C) Benzenediazonium chloride
(D) Benzene

24.Which are the chiral molecules in the following set of compounds?

 M Y
D E
(A) a and b
(B) a and c
C A
(C) a, b and d
(D) only d
I A
D H
25.Select the correct product X formed in the following reaction

C6H5CH=CH2 + HBr

B O X

E
(A) C6H5CH2CH2Br
(B) C6H5CH=CHBr

T H
(C) C6H5CHBrCH3
(D)C6H5CBr=CH2

26. What is the correct IUPAC name for the following compound?

(A) 2-bromo-3-methylpent-3-ene
(B) 4-bromo-3-methylpent-2-ene
(C) 2-bromo-3,4-dimethylbut-3-ene
(D) 1-bromo-1,3-dimethylbut-2-ene
27.In methyl halide the length of the carbon halogen bond CH3 - X is shortest in

(A) CH3I
(B) CH3CI
(C) CH3Br
(D) CH3F

28.The main addition product X formed in the following reaction

peroxide
C6H5CH2CH = CH2 + HBr X is

(A) C6H5CH2CH=CHBr
(B) C6H5CH2CHBr-CH3
(C) C6H5CH2CH2 - CH2Br
M Y
(D) C6H5CHBrCH = CH2

D E
anhydrous AICI3, the products are
C A
29.In Friedel Crafts reaction of chlorobenzene with acetyl chloride in the presence of

I A
(A) 2-chloroacetophenone (major) and 4-chloroacetophenone (minor)
(B) 2-chloroacetophenone (minor) and 4-chloroacetophenone (major)

D H
(C) 2-chloroacetophenone (minor) and 3-chloroacetophenone (major)
(D) 2-chloroacetophenone (major) and 3-chloroacetophenone (minor)

O
30. The hydroxyl group (-OH) attached to an sp2 carbon occurs in

B
E
(A) CH3OH
(B) C6H5CH2OH

T H
(C) C6H5OH
(D) CH2O

31.When an optically active halide (C6H13)(CH3)HCBr is hydrolysed by -OH in an SN2

reaction, the alcohol product that is N formed is

(A) accompanied by optical inversion

(B) accompanied by retention of configuration
(C) accompanied by racemization
(D) mediated by the formation of an sp² carbocation
32. Which one of the following molecule is optically active?

M Y
D E
C A
I A
H
33.Which of the following bromides would undergo SN2 reaction faster?
(A) CH3CHBrCH2CH3
(B) (CH3)2CH2Br
(C) (CH3)3CBr

O D
B
(D) CH3CH2CH2CH2Br

H E
34.The conversion of aryl diazonium salts to aryl halides is carried out by
(A) Reimer-Tiemann reaction
(B) Cannizaro reaction

T (C) Sandmeyer's reaction

(D) Kolbe reaction

35.The process of conversion of an enantiomer into a racemic mixture is known as

(A) retention
(B) inversion
(C) isomerisation
(D) racemisation

-1 -1 -¹
36. The rate constants for two reactions are 33 L mol s and 1.3 s . The orders of
the two reactions are, respectively,
(A) 0 and 1
(B) 1 and 2
(C) 1 and 0
(D) 2 and 1
37.In the reaction of SO3 SO2 + O, the concentration of SO3 changes from 1
mol L-1 to 0.9 mol L-1 in 1 minute. The rate of the reaction is:
(A) 0.1 mol L-1 min
(B) 0.1 mol L-1 s-1
(C) 0.1 mol L-1h-1
(D) 0.1 mol L-1 min-1

38. The initial concentration of a reactant undergoing a first order reaction is 2 mol L-1
after 3 half lives, the concentration of the reactant is:
(A) 0.5 mol L-1
(B) 0.25 mol L-1
(C) 0.125 mol L-1
(D) 0.666 mol L-1

M Y
39. A catalyst:

D E
(A) changes the rate of a reaction
(B) alters ∆G (the free energy change) of the reaction
(C) alters both ∆G and the rate of the reaction
C A
(D) alters both∆G and the energy of activation

I A
H
- Ea / RT
40.In the use of the Arrehenius equation k = A e Ink(on y axis) is plotted against
1/T (on x axis). The intercept on the y-axis is:

(A) - In A
O D
(B) In A
(C)Ea/R
B
H E
(D) - Ea/R

41.The rate constant of a first order reaction is 3.465 x 10-3 min-1. The half life of this reaction
is
T
(A) 200 min
(B) 346.5 min
(C) 400 min
(D) 150 min

42.The integrated rate law for a reactionof zero order is

(A) kt = [R]0 - [R]
(B)kt = [R] - [R]0
(C) [R] = [R]0 e-kt
(D) [R] = [R]0 ekt
 43. For a reaction, the half life is directly proportional to the initial concentration of the
reactant. The order of the reaction is
(A) 1
(B) 2
(C) 1.5
(D) 0

44. In the reaction 2NO+O2 2NO2, the initial rate increases by a factor of 4 when
the concentration of NO is doubled. The order of the reaction with respect to NO is

(A) 4
(B) 1
(C) 0
(D) 2

M
45. For a first order reaction, the measured rate constant is 6.93x 10-14 s-1. The half life of
Y
thereaction is

D E
A
13
(A) 1.4 × 10 s
(B) 1013 s
(C) 1013 s-1
(D) 1014 s
A C
H
46. The unit for a second order reaction is: I
(A) mol L-1s-1
(B) mol -1L-1s-1
O D
(C) L mol-1s-1
(D) mol Ls-1
B
H E
47. For the reaction 4O2 + 3S = 2SO3 + SO2, the rate of the reaction is:

T
(A)-4∆[O2]/∆t
(B) -3∆[S]/∆t
(C) 2∆ [SO3]/∆t
(D) ∆ [SO2]/∆t

48. .To get the activation energy from the Arrhenius equation we need to plot

(A) k vs 1/T
(B) In k vs T
(C) In k vs 1/T
(D) In k vs A
 49. A catalyst affects the

(A) entropy of a reaction

(B) enthalpy of a reaction
(C) free energy of a reaction
(D) activation energy

50. The rate constants of a reaction at temperatures T, and T, (in Kelvin), where T₁ =
T+100, are 0.02 s¹ and 0.2 s respectively. The expression for E, of this reaction is
(A) 0.02303 RT1T2
(B) 2.303 RT1T2
(C) 0.2303 R/(T1T2)
(D) 2.303 R/(T1T2)

M Y
D E
C A
I A
D H
B O
H E
T