Ioninc Assignmengt

Important questions from ionic equilibrium chapter
Answer the given questions:

1. What do you mean by equilibrium state in a 15. Define: a. ionic product of water. b. pH of
reversible reaction? solution.
2. How strong electrolytes differ from weak 16. pH value of boiling water is less or more than or
electrolytes? equal to 7. Justify your answer.
3. What are the conjugate acid and conjugate base 17. State Ostwald’s dilution law. What is its limitation?
of NH3, H2O, CH3COOH, HCO3- and HSO4- ? 18. Derive the mathematical equation for Ostwald’s
4. Show that water and ammonia is an amphoteric dilution law.
substance. 19. Define pH of solution and derive the relation
5. Write the conjugate acid and base of NH3. between pH and pOH.
6. Write a compound which is Arrhenius acid as well 20. Is the solution acidic, basic or neutral in which
as Bronsted acid. concentration of hydroxyl ion is 3.33 x 10-10 molL-
1
7. Write a compound which is not Arrhenius acid but ? Justify with reason.
is Bronsted acid. 21. What happens when HCl gas is passed through a
8. Write a compound which is not Arrhenius base but saturated solution of NaCl? Explain.
is Bronsted base. 22. Whether aqueous solution of CaCl2 is acidic, basic
9. Write a compound which is Arrhenius base but is or neutral?
not Bronsted base. 23. Predict whether the aqueous solution of CuSO4 is
10. Write suitable example to show water act as acidic, basic or neutral. Water is Lewis base as well
Bronsted- Lowry acid and base. as Bronsted acid. Justify.
11. Water is lewis base as well as Bronsted acid. 24. Explain the fact that aqueous solution of sodium
Explain. carbonate is basic, while the aqueous solution of
12. Identify lewis acid and base in the following sodium chloride is neutral.
reaction. 25. Why is aqueous solution of FeCl3 acidic?
Ag+ (aq.) + 2NH3 (aq.) → [Ag(NH3)2]+ 26. Explain why sodium chloride precipitate from a
13. CO2 is lewis acid. Justify. saturated salt solution of when hydrogen chloride
14. What are ionization constant and degree of gas is passed into the solution?
ionization of weak electrolyte? How do they vary 27. What is common ion effect? What are its main
with temperature? applications
Numerical questions:
A. Problems involving calculation of pH of strong acid or base solution having concentration greater than 10-
7M:
1. What is pH of 1 x 10-6 M H2SO4? (ans:5.698)

2. Calculate the pH of 1 x10-3 M KOH. (ans:11)
3. Calculate the pH of solution formed by dissolving 1g of NaOH in 1 liter of its solution. (ans: 12.4)
4. 4.9 g of pure H2SO4 is dissolved in 500 ml solution. Find the pH value of the solution. (ans: 0.699)
5. Potassium hydroxide solution having pH 8 is diluted 1000 times. Calculate the pH of the diluted base.
6. Calculate the pH of 0.04N H2SO4 solution. (ans:1.398)
7. What will be the H+ ion concentration of a solution having pH 5.5?
8. Calculate the hydroxyl ion concentration of a solution having pH 10.5. (ans: 3.16 x 10-4M)
9. Calculate the pH of 1g/L NaOH solution. (ans:12.4)
10. Calculate H+, OH- ion concentration, and pH at 25 ℃ of 0.05 M H2SO4 solution. (ans: 1)
11. Calculate H+, OH- ion concentration, and pH at 25 ℃ of 0.04 M NaOH solution. (ans: 12.60)
12. Calculate the strength in g/L of NaOH whose pH value is 11. (ans: 0.04g/L)
13. 10-2 mole of KOH is dissolved in 10 liters of water. What will be the pH of the solution?
14. What mass of KOH should be dissolved in one liter of solution to prepare a solution having pH 12 at 25℃? (ans:
0.56g)
15. The pH of solution of KOH is 10. Calculate the hydroxyl ion concentration. (ans: 10-4M)
16. The pH of a solution is 6. If hydrogen ion concentration is increased 1000 times. What is the pH of the resulting
solution? (ans: 3)
17. What is the new pH if 100 ml of a solution of HCl with pH = 0.52 is diluted by the addition of 200ml of pure
water? (ans: 1)
18. Calculate H+, OH- ion concentration, and pH in a solution in which 2.0 g of NaOH is dissolved in a 2 liter solution.
(ans: 11.39)
B. Problem involving calculation of pH of strong acid or strong base solution having concentration equal or
less than 10-7 M:
19. Find the pH of 10-9 M solution of NaOH. (ans: 7.002)
20. Calculate the pH of aqueous solution containing 10-7 moles of NaOH per liter. (ans: 7.302)
21. Calculate the pH of 1.0 x 10-8 M HCl solution. (ans:6.955)
C. Problem involving the calculation of pH of weak acid or weak base solution.

22. Calculate the pH of 0.1M acetic acid solution having Ka 1.8 x 10-5. (ans: 2.87)
23. Calculate the pH of 0.01 M solution of ammonia. (Kb = 1.8 x 10-5) (ans: 10.623)
24. The pH of 0.1M acetic acid solution is 5.2. What is the value of ionization constant (Ka) of the acid? (ans:3.96 x10-
10
)
25. Calculate the degree of ionization of HCN having concentration 0.01M (Ka of HCN = 4.8 x 10-10). Also calculate H+
ion concentration and pH. (ans:2.2 x 10-6, 5.65)
26. Calculate the pH of 1.0M solution of acetic acid. To what volume one liter of this solution be diluted so that pH
of the solution that is formed will be twice of original value [Ka = 1.8 x 10-5].
27. 50 ml of 1M acetic acid is mixed with 50 ml of 0.2M NaOH. If Ka for CH3COOH is 1.8 x 10-5. Calculate;
a. pH of resulting solution. (ans:2.57)
b. Concentration of salt formed. (ans: 0.1 M)
28. Calculate the concentration of H+ ion in the mixture of 0.02 M CH3COOH and 0.2 M CH3COONa, given that the
ionization constant (Ka) for CH3COOH is 1.8 x 10-5. (ans: 1.8 x 10-6 M)
29. 0.91% of acetic acid is ionized when the molar concentration is 0.5 M. Find the dissociation constant for the acid.
(ans: Ka = 4.14 x 10-5).
30. The dissociation constant for a weak acid is 9 x 10-6. Calculate the percentage of the acid that is ionized when the
concentration of the acid is 0.04 M. (ans: 1.5%)
31. A solution having 0.2 mole of H2S in 500 ml is 0.0616 % ionized. Calculate the dissociation constant of H2S. The
ionization of H2S takes place as, H2S H+ + HS-. Also, calculate pH of the solution. (ans: 3.6)
32. Ka for monoprotic acid is 4.9 x 10-8. For decimolar solution of the acid calculate; (a) % dissociation, (b) OH-
concentration, (c) H+ concentration and (d) pH of the solution. (ans: 0.07%, 1.41 x 10-10, 7.0 x 10-5, 4.15).
D. Problems involving calculation of pH of mixture of acids or bases or the mixture of acid and base:
33. 1 g of CaCO3 was dissolved in 50 ml at N/2 HCl solution. The solution was diluted to 100 ml. calculate the
normality and pH of the diluted acid. (ans: 0.05N, 1.7)
34. 0.41g of NaOH is placed in 100ml of 0.1N H2SO4. Find the pH of the resulting solution. (ans: 11.4)
35. 100 ml of solution having pH 4 is mixed with 400 ml of solution having pH 6. Calculate the pH of the resulting
mixture. (ans: 4.68)
36. 200 ml of 1N HCl, 100 ml of 1 N H2SO4 and 200 ml of 0.8 N HNO3 are mixed together. Calculate the pH of the
resulting solution. (ans: 0.036)
37. 2.3 g of NaOH is mixed with 1.5 ml of 0.005 M H2SO4 solution. Find the pH of the resulting solution. (ans: 12.45)
38. Two liters of 1M HCl is mixed with one liter of 1M NaOH solution. Calculate the strength of the salt formed and
the pH of the resulting solution. (ans: 0.33M, 0.48)
39. If equal volume of two solutions having (pH = 1) and (pH = 12) are mixed together, what will be the pH of the
solution? (ans:1.34)
40. 200ml of an aqueous solution of HCl (pH = 2) is mixed with 300ml of an aqueous solution of NaOH (pH = 12).
What will be the pH of resulting mixture solution? (ans: 11.30)

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Important questions from ionic equilibrium chapter

Answer the given questions:

1. What is pH of 1 x 10-6 M H2SO4? (ans:5.698)

C. Problem involving the calculation of pH of weak acid or weak base solution.

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