Worksheet 1 - Answer

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Worksheet (1)

1) Water is an example of:


A. a heterogeneous mixture
B. a homogeneous mixture
C. an element
D. a compound

2) The density of a piece of gold with a mass of 301 g and a volume of 15.6
cm3 is:
A. 19.3 kg/m3
B. 19.3 g/m3
C. 19.3 g/cm3
D. 19.3 kg/cm3
d = m/V
m = 301 g, V = 15.6 cm3
d = 301 / 15.6 = 19.3 g/cm3

3) SI Base Unit for length is:


A. Meter
B. Kilometer
C. Mile
D. foot

4) Express 500 centimeters in megameters.


A. 5.0 × 106 Mm
B. 5.0 × 10-6 Mm
C. 5.0 × 10-8 Mm
D. 5.0 × 10-9 Mm

First, convert from cm to m :


500 × 10-2m
Then from m to Mm
500 × 10-2 × 10-6 = 500 × 10-8 = 5.0×102 ×10-8 = 5.0 × 10-6 Mm

Page 1 of 16
Worksheet (1)
5) Atoms with the same number of protons and with different number of
neutrons are called:
A. Ions
B. neutral atoms
C. isotopes
D. different atoms

6) Which of these pairs of elements would be most likely to form an ionic


compound?
A. P and Br
B. Cu and K
C. C and O
D. O and Zn

Page 2 of 16
Worksheet (1)
7) How many grams of SF4 (g) can theoretically be prepared from 6.00 g of
SCl2 (g) and 3.50 g of NaF(s)? The equation of the reaction is:
3 SCl2 (g) + 4 NaF (s) → SF4 (g) + S2Cl2 (l) + 4 NaCl (s)
A. 21.0 g SF4
B. 210 g SF4
C. 2.10 g SF4
D. 0.210 g SF4
We have to determine the limiting reagent:
First start with SCl2 second start with NaF
1- Convert g to mole: 1-Convert g to mole:
n = Mass / molar mass n = Mass / molar mass
molar mass of SCl2 molar mass of NaF
= (1 × 32) + (2 × 35.5) = 103 g mol = (1 × 23) + (1 × 19) = 42 g mol-1
-1

n = 6 / 103 = 0.058 mol n = 3.5 / 42 = 0.083mol


2- from the chemical equation 2- from the chemical equation
3 mole SCl2 ==➔ 1 mole SF4 4mole NaF ==➔ 1 mole SF4
0.058 mole SCl2 ==➔ ? mole SF4 0.083 mole NaF ==➔ ? Mole SF4
1 × 0.058 = 3 × ? 1 × 0.083 = 4 x ?
Mole of SF4 = (0.058 × 1) / 3 Mole of SF4 = (0.083 ×1) / 4
= 0.019 mole = 0.02 mole
The limiting reagent is SCl2 because it produced the least amount of SF4
molar mass of SF4 = (1 × 32) + (4 × 19) = 108 g mol-1
Mass (SF4) = n x molar mass = 0.019 x 108 =2.052 g ≈ 2.1g

Page 3 of 16
Worksheet (1)
8) Calculate the percent composition by mass of C in picric acid (C6H3N3O7).
A. 1.3 %
B. 18.3 %
C. 31.4 %
D. 48.9 %
𝑛 × 𝑚𝑜𝑙𝑎𝑟 𝑚𝑎𝑠𝑠 𝑜𝑓 𝑒𝑙𝑒𝑚𝑒𝑛𝑡
%𝐶 = × 100
𝑚𝑜𝑙𝑎𝑟 𝑚𝑎𝑠𝑠 𝑜𝑓 𝑐𝑜𝑚𝑝𝑜𝑢𝑛𝑑

Molar mass of C = 12 g mol-1 (from the Periodic Table)

Molar mass of C6H3N3O7 = (6×12) + (3×1) + (3×14) + (7×16) = 229 g mol-1

𝑛𝑢𝑚𝑏𝑒𝑟 𝑜𝑓 𝑐𝑎𝑟𝑏𝑜𝑛 𝑎𝑡𝑜𝑚𝑠 × 𝑚𝑜𝑙𝑎𝑟 𝑚𝑎𝑠𝑠 𝑜𝑓 𝑐𝑎𝑟𝑏𝑜𝑛


%𝐶 = × 100
𝑚𝑜𝑙𝑎𝑟 𝑚𝑎𝑠𝑠 𝑜𝑓 𝑝𝑖𝑐𝑟𝑖𝑐 𝑎𝑐𝑖𝑑

6 × 12
%𝐶 = × 100 = 31.4 %
229

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Worksheet (1)
9) The empirical formula of an organic compound with 85.7% C and 14.3%
H is:
A. CH
B. CH2
C. C2H
D. CH4

1- We change from % to g
85.7 g of C, 14.3 g of H

2- Change from g to mole using


𝑚𝑎𝑠𝑠
𝑛=
𝑚𝑜𝑙𝑎𝑟 𝑚𝑎𝑠𝑠
85.7
𝑛𝐶 = = 7.14 𝑚𝑜𝑙 𝑜𝑓 𝐶
12
14.3
𝑛𝐻 = = 14.3 𝑚𝑜𝑙 𝑜𝑓 𝐻
1
3- Divided by the smallest number of mole which is 7.14
7.14 14.3
𝐶∶ =1, 𝐻: ≈2
7.14 7.14

Thus, the empirical formula is CH2

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Worksheet (1)
10) An empirical formula of an organic compound is C3H4O2, if the
molecular weight of the compound is (360 g/mol), the molecular formula
of the compound will be:
A. C6H8O4
B. C12H16O8
C. C9H12O6
D. C15H20O10

𝑚𝑜𝑙𝑎𝑟 𝑚𝑎𝑠𝑠 𝑜𝑓 𝑐𝑜𝑚𝑝𝑜𝑢𝑛𝑑


𝑅𝑎𝑡𝑖𝑜 =
𝑚𝑜𝑙𝑎𝑟 𝑚𝑎𝑠𝑠 𝑜𝑓 𝑒𝑚𝑝𝑖𝑟𝑖𝑐𝑎𝑙 𝑓𝑜𝑟𝑚𝑢𝑙𝑎

Molecular weight (molar mass) of the compound = 360 g/mol

Molar mass of empirical formula (C3H4O2) = (3×12) + (4×1) + (2×16)


= 72 g mol-1

360
𝑅𝑎𝑡𝑖𝑜 = =5
72

Molecular formula = Ratio × empirical formula = 5 × [C3H4O2] = C15H20O10

11) How many grams are there in 3 moles of SF4?


A. 108 g
B. 2.0 × 1026 g
C. 36 g
D. 324 g
𝑀𝑎𝑠𝑠 = 𝑛 × 𝑚𝑜𝑙𝑎𝑟 𝑚𝑎𝑠𝑠

molar mass of SF4 = (1 × 32) + (4 × 19) = 108 g mol-1

𝑀𝑎𝑠𝑠 = 3 × 108 = 324 𝑔

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Worksheet (1)
12) If you need 1.1 × 1024 molecules of oxalic acid, H2C2O4, how many
grams of the acid should you weigh out in the laboratory?
A. 1.826 g
B. 0.02 g
C. 164.4 g
D. 82.2 g

Number of mole = number of molecules / avogadro’s number

Number of mole = mass / molar mass

number of molecules mass


=
avogadro’s number molar mass

Molar mass of oxalic acid (H2C2O4) = (2×1) + (2×12) + (4×16) = 90 g mol-1

1.1 × 1024 mass


=
6.022 × 1023 90
24
1.1 × 10 mass
=
6.022 × 1023 90
24
(1.1 × 10 ) × 90
𝑚𝑎𝑠𝑠 = = 164.4 𝑔
6.022 × 1023

Page 7 of 16
Worksheet (1)
13) How many grams of Na2CO3 are required for complete the reaction
with 0.144 g HNO3?
Na2CO3(aq) + 2 HNO3(aq) → 2 NaNO3(aq) + CO2(g) + H2O(l)

A. 2.286 × 10-3 g
B. 0.121 g
C. 1.143 × 10-3 g
D. 0.072 g

1-First make sure the equation is balanced


2- Convert g to mole:
mass
number of mole (HN𝑂3 ) =
molar mass of HN𝑂3

Molar mass of HNO3 = (1×1) + (1×14) + (3×16) = 63 g mol-1


mass
number of mole (HN𝑂3 ) =
molar mass of HN𝑂3
0.144
number of mole (HN𝑂3 ) = = 0.0023 𝑚𝑜𝑙
63

3- From the chemical equation:


2 mole HNO3 ==➔ 1 mole Na2CO3
0.0023 mole ==➔ ? mole Na2CO3
(0.0023) × 1
number of mole (𝑁𝑎2 C𝑂3 ) = = 0.00115 𝑚𝑜𝑙
2

Molar mass of Na2CO3 = (2×23) + (1×12) + (3×16) = 106 g mol-1

Mass of (𝑁𝑎2 C𝑂3 ) = number of mole × molar mass


Mass of (𝑁𝑎2 C𝑂3 ) = 0.00115 × 106 = 0.121 𝑔

Page 8 of 16
Worksheet (1)
14) A glass of water contains 75.96 g of water molecules. How many
hydrogen atoms are in the water?
A. 4.57 x 1025
B. 5.08 x 1024
C. 2.54 x 1024
D. 9.15 x 1025
1- We calculate the number of molecules (H2O)

number of molecules mass


=
avogadro’s number molar mass

Molar mass of H2O = (2×1) + (1×16) = 18 g mol-1

number of molecules 75.96


=
6.022 × 1023 18
(6.022 × 1023 ) × (75.96)
number of molecules =
18
24
= 2.539 × 10 molecules

2- From the chemical formula of water molecule (H2O):


1 molecule of water ===➔ 2 atoms of H
24
2.539 x 10 molecules ===➔ ? atoms of H
(2.539 × 1024 ) × (2)
number of hydrogen atoms =
1
24
= 5.08 × 10 atoms

15) 168𝑂−2 has the correct set of (Z = Atomic number, A = mass number, c
= charge)
A. Z = 16, A = 8, c = 0
B. Z = 8, A = 16, c = 1
C. Z = 8, A = 16, c = -2
D. Z = 8, A = 16, c = 0

Page 9 of 16
Worksheet (1)
16) Phosphorus ion (P-3) with (Z=15 and A= 31) has the correct set of (e =
electrons and n = neutrons)
A. e = 18, n = 16
B. e = 15, n = 16
C. e = 15, n = 18
D. e = 16, n = 18

P = 15, e = 15+3 = 18, n = 31-15 = 16

17) Vanadium (V) has two stable isotopes, (50V and 51V). The average
atomic mass of Vanadium (V) is 50.9415 amu; 50V has a mass of 49.9462
amu with an abundance of 0.25%. The mass of (51V) isotope in amu with
an abundance of 99.75% is:
A. 51.4940
B. 50.9440
C. 50. 4490
D. 50.9404
Average atomic mass
= (atomic mass × abundenace)50V
+ (atomic mass x abundenace)51V
50.9415 = (49.9462 × (0.25 /100))50V
+ (atomic mass × (99.75 /100))51V
50.9415 = 0.125 + (atomic mass of 51V × 0.9975)
50.9415 − 0.125 = (atomic mass of 51V × 0.9975)
50.8166 = (atomic mass of 51V × 0.9975)
50.8166
atomic mass of 51V = = 50.944
0.9975

18) The element that would be most likely to form a cation is:
A. O
B. He
C. F
D. Pb

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Worksheet (1)

19) The element in group 7A and period 6 is:


A. At
B. Po
C. I
D. Rn

20) The empirical formula of C6H8O6 is:


A. C6H8O6
B. C3H4O3
C. C2H4O2
D. C2H4O

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Worksheet (1)
21) The correct name for N2O3 is
A. Dinitrogen monoxide
B. Dinitrogen trioxide
C. Nitrogen dioxide
D. Dinitrogen pentaoxide

22) The systemic name of Cu3(PO4)2 is


A. Cuprous phosphate
B. Copper (II) phosphate
C. Copper (I) phosphate
D. Copper (III) phosphate

23) Ratio of protons to electrons in (O-2) with (Z = 8 and A = 16) is


A. 1:2
B. 2:1
C. 4:5
D. 1:1

24) How many moles of MgCl2 are present in 60.0 mL of 0.100 M MgCl2
solution?
A. 60.0 mol
B. 0.572 mol
C. 6.00 × 10-3 mol
D. 6.00 mol
𝑛𝑢𝑚𝑏𝑒𝑟 𝑜𝑓 𝑚𝑜𝑙
Molarity (M) =
Volume of solution (𝑉𝐿 )
60 𝑚𝐿
𝑉𝐿 = = 0.06𝐿
1000
𝑛𝑢𝑚𝑏𝑒𝑟 𝑜𝑓 𝑚𝑜𝑙 = Molarity (M) × Volume of solution (𝑉𝐿 ) = 0.1 × 0.06
𝑛𝑢𝑚𝑏𝑒𝑟 𝑜𝑓 𝑚𝑜𝑙 = 6 × 10−3 𝑚𝑜𝑙

Page 12 of 16
Worksheet (1)
25) Which of the following solutions contains the largest number of moles
of solute?
A. 26.5 mL of 4.9 M sodium chloride
B. 45 mL of 0.99 M hydrochloric acid
C. 80 mL of 0.5 M nitric acid
D. 100 mL of 1 M sodium hydroxide
𝑛𝑢𝑚𝑏𝑒𝑟 𝑜𝑓 𝑚𝑜𝑙
Molarity (M) =
Volume of solution (𝑉𝐿 )

𝑛𝑢𝑚𝑏𝑒𝑟 𝑜𝑓 𝑚𝑜𝑙 (𝑛) = Molarity (M) × Volume of solution (𝑉𝐿 )

A n = 4.9 × (26.5/1000) = 0.13 mol


B n = 0.99 × (45/1000) = 0.044 mol
C n = 0.5 × (80/1000) = 0.04 mol
D n = 1 × (100/1000) = 0.1 mol

26) Calculate the molarity of a solution of 2.50 g of ethanol (C2H5OH) in


545 mL of solution.
A. a-4.59 × 10-3 M
B. 9.96 × 10-2 M
C. 1.36 M
D. 0.218 M
mass 𝑀 × 𝑉𝑚𝐿
=
𝑚𝑜𝑙𝑎𝑟 𝑚𝑎𝑠𝑠 1000

Molar mass of ethanol (C2H5OH) = (2×12) + (6×1) + (1×16) = 46 g mol-1

mass × 1000 2.5 × 1000


𝑀= = = 9.96 × 10−2 𝑀
𝑚𝑜𝑙𝑎𝑟 𝑚𝑎𝑠𝑠 × 𝑉𝑚𝐿 46 × 545

Page 13 of 16
Worksheet (1)
27) Calculate the mass of NaNO3 in grams required to prepare 250 mL of a
0.173 M solution.
A. 3.68 g
B. 15.0 g
C. 43.3 g
D. 3.68 × 103 g

mass 𝑀 × 𝑉𝑚𝐿
=
𝑚𝑜𝑙𝑎𝑟 𝑚𝑎𝑠𝑠 1000

𝑚𝑜𝑙𝑎𝑟 𝑚𝑎𝑠𝑠 × 𝑀 × 𝑉𝑚𝐿


mass of NaN𝑂3 =
1000

Molar mass of NaNO3 = (1×23) + (1×14) + (3×16) = 85 g mol-1

85 × 0.173 × 250
mass of NaN𝑂3 = = 3.68𝑔
1000

28) A 10.0 mL sample of 16.5 M HF is diluted to a final volume of 250 mL.


What is the molarity of the final solution?
A. 1.52 M
B. 0.660 M
C. 0.100 M
D. 1.06 M
𝑀1 × 𝑉1 = 𝑀2 × 𝑉2

16.5 × 10 = 𝑀2 × 250

16.5 × 10
𝑀2 = = 0.66𝑀
250

Page 14 of 16
Worksheet (1)
29) A 10.0 mL of 0.665 M KMnO4 solution is mixed with 16.7 mL of 0.892
M KMnO4 solution. Calculate the concentration of the final solution.
A. 0.778 M
B. 0.807 M
C. 2.37 M
D. 0.411 M
(𝑀1 × 𝑉1) + (𝑀2 × 𝑉2) = 𝑀𝑓 × 𝑉𝑓

M1 = 0.665 M V1 = 10.0 mL

M2 = 0.892 M V2 = 16.7 mL

Mf = ??? M Vf = (10.0 + 16.7) = 26.7 mL

(𝑀1 × 𝑉1) + (𝑀2 × 𝑉2) (0.665 × 10) + (0.892 × 16.7)


𝑀𝑓 = =
𝑉𝑓 26.7

6.65 + 14.90 21.55


𝑀𝑓 = = = 0.807𝑀
26.7 26.7

Page 15 of 16
Worksheet (1)
30) The following reaction describes the combustion of an alkane, the
correct balance will be with
a C5H12 + b O2 → c CO2 + d H2O
A. a = 5, b = 2, c = 2, d = 2
B. a = 12, b = 2, c = 2, d = 2
C. a = 1, b = 8, c = 5, d = 6
D. a = 1, b = 4, c = 5, d = 6

C5H12 + O2 → CO2 + H2O


Element Reactants Products
C 5 1 ×5

C5H12 + O2 → 5 CO2 + H2O


Element Reactants Products
C 5 1 ×5
H 12 2 ×6

C5H12 + O2 → 5 CO2 + 6 H2O


Element Reactants Products
C 5 1 ×5
H 12 2 ×6
O 2 ×8 10 + 6 =16

C5H12 + 8 O2 → 5 CO2 + 6 H2O


Element Reactants Products
C 5 5
H 12 12
O 16 16

Page 16 of 16

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