STOICHIOMETRY

Relative rates of rxn :

-rA-rBA [
I
Vis

b C &
for strich table: A +
a
Bz)
A
2 +
D
note: "A denotes the limiting reactant (LR).

to Find UP :
Given : 5 mol of N2 + a mol of the rxn : Ng +
#z
>
-

NHL

Balanced Eqn : Na + 3H2 >

-

INMy
For Wy : 5 mol/1mol 5 mol N
=
,
For I: 9 mollymol :
3 molt : M is UR

=> To determine CP, Given more

; UP > ER
stoichiometric coefficient

& Stoichiometric Feed

6: -1- +
=>
delta or +

*
3 =

Yar S
E =
1
if Equimolar
I can only be applica on

reactants)
 Initial +
change =

remaining
BAGH REACTOR CONCENTRATION :
For non-constant volume : For constant volume:

CA =
NA
v
CA :
=mol/dm
NA NAo(1 X)
NAo(l-x)
-

Ca = =

j v CA =

Vo
and so On...

CA =
(A0(1 -

X]

condition for constant volume :

·
if liquid phase
If
gas phase occurs in rigid (2 g. steel)
·

a -

batch reactor
 ·
Ap:

E
-
CAO Yar

since , liquid is constant volum :

V =
Vo
EXAMPLES :

Given
Redid
CH =
10mildm : Co =
<molldms + (p & X =
0 20

a
.

solution :
St Cp &X =
0 90 .

rxn : 3A + 1 >
-
32 +D

(optimia
at

C =

<(t- ) = Cho

= 1 mol/dm >

- :

10 m/dm3(0 02 +

C = 1 33
.
mol/dms CD =
0 . 67 mol/dm3
b)

<= Cho (tB- ) (p =

Cr (op + =)
=
10 mol/dm ( -

) =
10m/dms(0 Gal +

Ciz = -1 mold m C =
3 hol/dm3
EXAMPLE GAS-PHASE FA
FA FAOXA
:
: -

solution:(STR & To =
T& Po : P

1. ) more balance : Ero-Fa V

FAOXA
V=
=
=
-

rA
-

VA
-

2) rate law : Va KCC

--
-
=

ca =

Cro(ix) ↓ ar

6 =
-1 -

! y + = 1 ; 4
=
6 Ya - =
(1)( 5)
- =
05
.

Ca =

c) , x) Back to Rak law :

ra
[Co()]? ((0)
-
=

CB <A
=

(JBXAI ra = k CAS
RTEx)
op =

8
 continuation…
=>
am
awl-f (3)3

ra = k CAS
n
RTEx)
Co
= YAPo =
10 .
5) [16 % atm)
.

= 0 2
.
mondms
(0 082 im(sook)
RTo .

Jam')(go os(1)
M

(10am /mols)(0 >

>

VA
-
=
.

VA =
0 0058
.
unl/am's
FAOXA
V * di masolve bulary any given
=
-

rA
-